Escolar Documentos
Profissional Documentos
Cultura Documentos
Thermodynamics is a field of science which deals with the relationships of heat, work, and
properties of systems. It is a science in which the storage, the transformation, and the transfer of
energy are studied. Energy is stored as internal energy, kinetic energy, potential energy and
chemical energy; it is transformed from one of the these forms to another. There are four laws of
thermodynamics known as zeroth, first, second and third law of thermodynamics.
The name thermodynamics stems from the Greek workds therme (heat) and dynamics (power). So,
the full form is power obtained with the help of heat. Today the same name is broadly interpreted to
include all aspects of energy and energy transformations, including power generation, refrigeration,
and relationships among the properties of matter.
Applications of Thermodynamics
There is a wide range of applications of thermodynamics in engineering. Some applications of
thermodynamics are given as below:
1. All types of air and gas compressors, blowers, fans, run on various thermodynamic cycles.
2. All the refrigerators, deep freezers, industrial refrigeration systems, all types of air-
conditioning systems, heat pumps, etc work on the basis of the second law of
thermodynamics.
3. All types of vehicles that we use, cars, motorcycles, trucks, ships, aeroplanes, and many
other types work on the basis of second law of thermodynamics and Carnot Cycle.
4. One of the important fields of thermodynamics is heat transfer, which relates to transfer of
heat between two media. There are three modes of heat transfer: conduction, convection and
radiation. The concept of heat transfer is used in wide range of devices like heat exchangers,
evaporators, condensers, radiators, coolers, heaters, etc.
5. Thermodynamics also involves study of various types of power plants like thermal power
plants, nuclear power plants, hydroelectric power plants, power plants based on renewable
energy sources like solar, wind, geothermal, tides, water waves etc.
Open System: It is a system in which energy as well as mass transfer take place between the
system and its surroundings.
Examples of an open system:
1. Air compressor
2. A steam boiler
3. Water heater
Closed System: It is a system in which mass remains constant i.e.
there is no transfer of mass across the boundary of the system but
there may be transfer of energy between the system and its
surroundings.
Examples of closed system:
1. Piston-Cylinder arrangement
2. A rubber balloon filled with air and tightly closed is an
example of closed system
Isolated system: It is a system in which no mass as well as energy transfer takes place.
Examples of isolated system:
1. The universe can be considered as isolated system
2. Thermos flask
PHASE
Phase is a quantity of matter that is uniform throughout in physical structure and in chemical
composition. The matter is either all solid or all liquid or all gas in case of physical uniformity. The
chemical composition does not vary from one part of system to another in case of uniformity of
chemical composition. There are three kind of phases of the system i.e., solid, liquid and gas.
Depending upon the phases of the system, systems may be classified as:
1. Homogeneous system
2. Heterogeneous system
1. Homogeneous system: The system which has only one phase, is called as homogeneous system.
Examples are mixture of air and water vapours, solution of ammonia in water etc
2. Heterogeneous system: The system which has more than one phase, is called as heterogeneous
system. Examples are water and oil, ice and water etc
THERMODYNAMIC PROPERTIES
The properties which describe the physical conditions of a system, are called thermodynamic
properties. For example: pressure, volume, temperature etc. Thermodynamic properties are of two
types. These are:
1. Extensive properties
2. Intensive properties
1. Extensive Properties: The properties which are dependent upon the mass of a system, are called
extensive properties. For example: enthalpy, entropy, mass etc.
2. Intensive Properties: The properties which are independent upon the mass of a system, are called
intensive properties. For example: specific entropy, specific enthalpy, specific volume etc.
THERMODYNAMIC EQUILIBRIUM
In thermodynamic equilibrium, there is no change in any thermodynamic properties of a system. A
system will be in a state of thermodynamic equilibrium, if the conditions for the following three
types of equilibrium are satisfied:
1. Mechanical Equilibrium
2. Thermal Equilibrium
3. Chemical Equilbrium
1. Mechanical Equilibrium: When there are no unbalanced forces within the system and between
the system and the surrounding, the system is said to be under mechanical equilibrium. Whenever
some unbalance forces exist within the system, they will get neutralized to attain the condition of
equilibrium.
2. Thermal Equilibrium: When the temperature of the system is uniform and not changing
throughout the system and also in the surroundings, the system is said to be thermal equilibrium.
Two systems are said to be thermal equilibrium with each other if their temperatures are same.
3. Chemical Equilibrium: When there is no chemical reaction taking place in any part of a system,
the system is said to be in chemical equilibrium
For the system to be thermodynamic equilibrium it is necessary that it should be under mechanical,
chemical and thermal equilibrium. If any one of the above condition are not fulfilled, the system is
said to be in non-equilibrium.
STATE, PATH, PROCESS AND CYCLE
State: It is the condition of a system as defined by the values of all its properties. It gives a complete
description of the system.
Path: The succession of states passed through during a change of state is called the path of the
system.
Process: When a path is completely specified then the change of the state is called a process.The
figure of a process is given as: