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ABSTRACT
Lo. Y.C., Herbst, J.A., Rajamani, K. and Arbiter, N., 1988. Design considerations for large di-
ameter ball mills. Int. J. Miner. Process., 22: 75-93.
Large mill (D > 5.0 m (16.5 ft)) performance has been successfullypredicted from small scale
batch experiment for grinding kinetics and an RTD correlation for transport using population
balance models. The effect of ball size must be properly taken into account in the scale-up. A
design method that combined the kinetic scale-up findings and the transport of material through
the mill has been developed.A computer program involving kinetic and transport considerations
has been tested and found to be satisfactory for mill design purposes.
INTRODUCTION
The size discretized population balance model for breakage kinetics has been
presented by several authors (Reid, 1965; Herbst et al., 1971; Austin,
1971-1972 ). In brief, a mass balance for the material in the ith size interval at
time t yields the kinetic model:
d(Hmi(t)) i-1
dt -SiHmi(t) + ~ bljSiHmj(t) (1)
j=l
where mi (t) is the mass fraction in the ith size interval and H is total mass of
material being ground. In eq. 1, Si, the size-discretized selection function for
the ith interval, denotes the fraction rate at which interval is broken out of the
ith size interval, and bii, the size-discretized breakage function, represents the
fraction of the primary breakage product of material in the j t h size interval
which appears in the ith size interval. Eq. i is referred to as the size-discretized
batch grinding model.
In order to apply the population balance model equations for scale-up the
dependence of the kinetic parameters (Si, bij) on mill dimensions and oper-
ating conditions must be known. According to findings presented by Herbst
and Fuerstenau (1973), the size-discretized selection functions are to a good
approximation proportional to the specific power delivered to the mill (P/H),
that is:
Si =S~(P/H) (2)
where S E termed the "specific selection function" is essentially independent
of mill dimensions. In addition the breakage functions bit have been found to
be to a good approximation invariant with respect to design and operating
variables over a wide range of conditions. Incorporating these findings into eq.
i yields the energy normalized form:
77
dmi(/~) i-1
SEmi(E) + ~, bijSEmj(E) (3)
dE j=l
where/~ is the specific energy input to the mill, given by JE=Pt/H. The nor-
malized form of the model can be extended to continuous grinding using resi-
dence time distribution (RTD) information (Herbst et al., 1971). The mill
product size distribution for a continuous mill is given by:
1.O 10
Breakage
nction
O.1
F
O,O1 9.1
100 1OOO
PARTICLE SiZE,microns
Fig. 1. Breakage function and specific selection function for Pinto Valley ore wet grinding.
10(
SELECTION FUNCTIONS
~1.0
I- b'°h'lsln l
-- - continuous 118ttl
95% confidence
interval
//7, .
1OO 1OOO
PARTIGLE SIZE, microns
100
. . . . . . . . . . . . . . . . . . ..,..o..~.o....~..~. ,-
1o 0 ~
PREDICTIONS O~'O <z
FOR 5.SxS.4m MILL O/o C~
o/
o/O / c
o/ o
o/ O
ZlO
0.~ K~a/TY / 0
Q
O
FEED 0
o Experimental, 76.2 mm bails
-- Predicted from 76.2mm ~ l l s
10 100 1000
PARTICLE SIZE ,microns
Fig. 3. Comparison of experimental product size distribution and predictions for copper ore wet
grinding.
A procedure has been developed in which batch tests are performed with the
same ball size distribution as that of the plant, which yields excellent predic-
tions as described above. In some cases reasonably accurate predictions of large
mill performance can also be obtained based on batch tests involving different
size balls. In other cases the accuracy of such predictions is not satisfactory.
In early studies concerned with the application of population balance models
to scale-up (Herbst and Fuerstenau, 1980; Herbst et al., 1982) it was believed
that the ball size per se was of minor importance and that changes in grinding
rates were merely reflected in changes in power draw of the different ball
charges. This view is corroborated by data such as that shown in Fig. 4 where
relatively accurate predictions of limestone grinding with top ball sizes ranging
from 38.1 m m (1.5 inch) to 76.2 m m (3.0 inch) could be obtained based on
batch data collected with 38.1 m m (1.5 inch ) top size balls. Subsequent studies
with other materials in larger mills (see Fig. 5) show that significant errors
were made in predicting the mill performance using laboratory data obtained
with different top size balls. These later results indicated the criticality of
properly accounting for actual plant ball size distribution in the scale-up
procedure.
80
100
PREDICTIONS ~'~"~
FOR 0.91x1.;~lm MILL i~ "~'~
Z 10
1 , , , . . . . . . . . . . . . . . .
10 100 1000
PARTICLE SiZE,microns
Fig. 4. Comparison of experimental product size distribution and predictions for limestone wet
grinding in the 0.91 X 1.21 m (3 X 4 ft) mill.
100 . . . . . . ,,.
. . . . . . . . . ~ o ~ ?._~ .,,...,m.
j o
.1.1. o /"
1.7" o o
FEED J "
o E x p e r i m e n t a l , 3"baJIs
-- - Predicted Iroml.5"balls
1 J , , . . . . . , , , , J , . . . . . i , i , , , ,
10 100 1000
PARTICLE SIZE, MICRONS
Fig. 5. Comparison of experimental product size distribution and predictions for copper ore wet
grinding in the 5.5×6.4 m (18)<21 ft) mill.
Z
E
_~10
//
Ill
0.1 1.0 10
BALL SIZE d , inches
bution to another has been proposed by Lo and Herbst (1986). Batch tests
were performed with different top size balls (Fig. 6) for different monosize
and full size distribution materials of various hardness, i.e., quartz, limestone,
magnetite, copper ore and phosphate ore. In all experiments power measure-
ments were made and several levels of energy input to grinding were evaluated.
As examples, the specific selection functions estimated from batch data for
quartz, and copper ore are shown in Fig. 7 and 8, respectively. In all cases the
specific selection functions variation with ball size appears to exhibit a pivotal
point (or pivotal region) indicating that, for particles coarser than that size,
the selection function increases with increasing ball size, and for particles finer
QUARTZ
SPECIFIC SELECTION FUNCTION
0.1 i i i , i i L i i ih i
50 100 10o0
Fig. 7. Specific selection functions for quartz wet grinding with different size balls.
82
1.O,
O.t
1OO 1OOO
PARTIGLE SiZE,microns
Fig. 8. Specific selection functions for copper ore wet grinding with different size balls.
than that size, the selection function decreases with increasing ball size. The
pivotal point and the rate of change of the slope depend on the properties of
the material. Considering the fact that breakage rates can decrease sharply in
coarse size range for hard materials, an empirical log-polynomial selection
function of second order is used for converting experimental data from one ball
size distribution to another. T h a t is:
Xi (X-11)ln(Xi/X1)
SE=kSpIv(Xp) XiE
(6)
In most cases it was found that the exponent ~2 was approximately the same
for different size balls, k = 1/(Xp/X1 ~21n is constant. The exponent ) (Xp/XI),
~ depends on ball size dB, i.e. ~ = adB + b, where a, b are constant for a given
material, and can be determined by an arbitrary set of "ball size tests". As an
example, in the case of quartz and copper ore grinding the following expres-
sions result:
[ - ~, 0 . 8 9 4 d B - 1"423
By knowing the pivotal point (Xp) and value of S~iv, the specific selection
function can be converted from one ball size to another for a given material.
In all cases examined it was observed that only a slight change in the break-
age function occurs when different ball size distributions are used for the grind-
ing media. Fig. 9 shows a combined plot of the normalized breakage function
for quartz wet grinding with 19.1, 25.4 and 38.1 m m (0.75, 1.0 and 1.5 inch)
83
1.0
/~
QUARTZ /I
BRE A KAGE FU N C T IO N S //. 501'1
.4s
.45
0.1
top size balls. As shown in Fig. 9, for the values of the three parameters in
functional form ~3 is almost exactly the same for different ball sizes, and ~2 is
approximately the same for different ball sizes. Only ~1 changeswith changing
ball size even if these changes are very small. Therefore, the change of selection
functions should be the primary consideration in converting kinetic parame-
ters from one ball size to another.
This method is illustrated here with an example for copper ore grinding. The
specific selection functions for copper ore were converted from 38.1 mm (1.5
inch) balls to 76.2 mm (3.0 inch) balls with eq. (8). The converted specific
selection functions are shown in Fig. 10, It has been found that accurate scale-
up predictions are possible using this ball size-correction method. As is shown
in Fig. 11, the scale-up procedure (Herbst et al., 1985 ) with the specific selec-
tion function converted from 38.1 (1.5 inch) to 76.2 mm (3.0 inch) balls gives
accurate predictions of 5.5 × 6.4 m (18 × 21 ft) mill performance. The product
size distribution error is about 2% with a volume scale-up factor of 9500 to 1.
The scale-up procedure associated ball size-correction suggests that the most
accurate predictions will be obtained using the same ball size distribution in
the laboratory test as that of the plant. When it is inconvenient to run labo-
ratory experiments with the expected plant ball size distribution, scale-up can
be done from an arbitrary set of "ball size tests" in a small batch mill. The
population balance scale-up procedure with converted specific selection func-
tions also provides accurate predictions of large mill performance. This pro-
cedure is also very useful in analysis of grinding circuit performance with a
view toward determining alternatives for increasing mill capacity. The capac-
ities of large mills can be predicted by simulation using parameters obtained
from a limited number of batch ball size tests.
84
COPPER ORE
1.0 SPECIFICSELECTIONFUNCTIONS
i
/ /
~- /~////////// ~_---~_
-- E x p e r i m e n t a l , 3 8 . 1 m m balls
/
0.1 . . . . . . . . . . . . |, , i
10 100 1000
P A R T I C L E SIZE , microns
Fig. 10. Conversion of specific selection function from 38.1 mm (1.5 inch) to 76.2 mm (3.0 inch)
balls.
100 . . . . . . . . . . . . . . . . . . o~O~o~. ~o
J"
/o.1°/./ o
.=,
zlo 39S K~/T I"
o.I.o.I° / / "
/
/"
FEED "
o Experimental, 7 6 . 2 rnm balls
-- Predlcted,withconversion,38.1 rnmbal
1 i i i . . . . . . . . . , , .... , , , L , ,,,
10 100 1000
PARTICLE SIZE, MICRONS
Fig. 11. Comparison of experimental product size distribution and predictions for copper ore wet
grinding in the 5.5 × 6.4 m (18 × 21 ft) mill, with converted specific selection functions.
I r I ] I
Pinto Valley
15 closed circuit RTD
1G
• Experimental
-- Fitted
5 10 15 20 25
Time,rain
Fig. 12. Closed circuit RTD model fit of the experimentally determined residence time distribu-
tion, 31=2.0 min, N~=2.2.
where N is the mixing parameter which gives the equivalent number of mixers-
in-series and T is the mean residence time for material in the mill. Based on
this model a "RTDUNEQW" program (Rajamani et al., 1983) has been de-
veloped for analyzing the residence time distribution.
Recently, a mathematical method for analyzing the closed circuit material
residence time in the continuous mill has been developed (Rogovin et al., 1986).
The residence time model parameters can be calculated using the relationships
between mean value and variance of tracer response to the mean residence
time and the degree of mixing in each of the circuit components ( Mann et al.,
1979; Mann and Rubinovitch, 1981). In both plants examined, the lithium
chloride tracers were injected into the mill inlet and detected at the mill outlet
before the sump. Component 1 is the mill while component 2 is the sump.
Considering ~2 (the mean residence time of the sump) and N2 (the number of
mixers-in-series in the sump) as equal 1 (full mixed) and all the plug-flow
times as negligible, the mean ~r and the variance a~ of the RTD are as follows:
86
oo
f t c ( t ) dt oo
c(t) dt o
0
T1
a2=R(I+R)['c, +z2]2+-~I+R T1 +z 2
(;: )
oo
--
f t2c(t)dt
0
oo
¢yo
f c(t)dt
0
o
where c(t) is the concentration of the tracer at the detection point at time t
after the injection, zl and z2 are the mean residence time of the mill and sump,
N 1 is the number of mixers-in-series in the mill, R, ratio of recycle flow of the
tracer, p = R/1 + R, Hi (t) is the RTD density function in component i of the
circuit.
Figs. 12 and 13 show the experimental measurements and model fits for
intermediate feed rates (425 T / H with 380% circulating load and 405 T / H
with 550% circulating load) for the Chino and Pinto Valley mills. The values
of mean residence time ~1 are 2.2 and 2.0 min, the values of N1 are 3.5 and 2.2
for Chino 5.0 m (16.5 ft) mill and Pinto Valley 5.5 m (18 ft) mill, respectively.
This data indicates that the mean residence time is not too different for the
two mills but that the mixing parameter decreases as the mill diameter increases.
There have been some attempts presented in the literature to describe the
RTD of the mill for different L/D ratios and feed rates. Karra and Fuerstenau
87
5.0
CHINO
4.0 closed circuit RTD
3.o
E
J i
2.0
1.O
• Experimental
5 10 15
T i m e , min
(1977) described the RTD of dry grinding with an axial dispersion model.
Rogers and Gardner (1979) applied a finite-stage transport model to phos-
phate ore wet grinding in 2.7X1.8 m, 5.2X3.8 m and 9.1X4.6 m mills; they
argued that the parameters of the finite-stage model were the same for the
three mills. Marchand et al. (1980) used a plug flow plus mixers-in-series model
to analyze RTD in 2.1X3.0 m and 2.4X3.0 m mills. They argued, based on
their data and others, that the dimensionless volumetric hold-up varies line-
arly with the dimensionless volumetric feed rate. None of these previous in-
vestigators made an attempt to correlate RTD data with wet mill characteristics
and operating conditions to account for the effect of percent solids, ball size
and L/D ratio. Such a correlation is needed for the scale-up design of large ball
mills. In order to accomplish such a correlation we analyzed not only our own
RTD data, but also the data of others. The data includes mill diameters ranging
from 0.4 to 5.5 m (1.3 to 15 ft) and lengths ranging from 0.4 to 9.8 m (1.3 to
32 ft) with ball sizes ranging from 38.1 to 76.2 mm (1.5 to 3.0 inches).
The development of this correlation was based on consideration of the tur-
bulence level in a mill and its influence on the extent of dispersion (back-
mixing) of material as it is transported through the mill. In this regard it was
assumed that the mixing parameter N could be correlated directly with the
Peclet number for the mill:
QL
Pe oc - - (13)
A De
with the dispersion coefficient, De, which is proportional to power input per
unit volume to the mill. In addition, studies of transport through packed beds
have shown that the Peclet number is also related to Reynolds number for
88
transport through the bed. The flow behavior through the dynamic ball mass
is somewhat akin to that of the flow through a packed bed. The comparison is
exact if the entire slurry stream passes through the ball mass and if the voidage
remains constant. Considering these factors and recognizing for N-mixers-in-
series description N is related to the Peclet number by:
1
N~- (14)
2 2
Pe pe 2 ( 1 - e -Pe)
The regression line fits most of the data very well. There seems to be some
deviation for few data. However, this deviation is not significant when used in
the context of population balance model. Fig. 15 shows a comparison of exper-
imental product size distributions and predictions obtained with mixing pa-
rameter N= 2.2 (as determined from closed circuit RTD model) and N= 1.8
(as calculated from RTD correlation for 5.5 X 6.4 m (18 X 21 ft) mill at Pinto
Valley. The size distributions are virtually identical (error less than 0.2%)
indicating that the RTD correlation (eq. 16) is valid for accurate predictive
purposes.
EXAMPLE APPLICATION
In order to apply the above findings for large mills, a design method based
on SCALEMILL (Herbst and Rajamani, 1982 ) has been developed. The basis
of this computer program is:
(1) Population balance model with Si--SE(p/H), bij--constant and ball
size correlation.
(2) Transport using the N-mixers in series model with parameters corre-
lated with mill dimensions, slurry rheology and mill speed.
( 3 ) Power equation as given by Rowland and Kjos (1978) :
89
° jo/O ~
• o
~ v
v
[~
+
D(ft)
1.33
1.33
L (ft)
1.33
2.66
o 1.30 4.00
• 2.50 1.50
• 3.00 4.00
~. 12.50 17.00
• 14.00 32.00
V 15.50 18.00
O 16.50 19.00
• 18.00 21.00
0 2 4 6 8 10
N L 1
R. I~-I ~ifl
100
O~-,'O
PREDICTIONS ~ f <:
FOR 5 . 5 x 6 . 4 m MILL ~0"~ t/
/-
jo o
I/oj ° <>
0 ~0~ ©
ZlO
E 0.96KWH,~>~/~ <>
o
FEED 0
0 Experimental
-- Predicted, N=1.8
--- Predicted, N~2.2
m , , , , , , , , , , , m k m bl"O00
10 100
PARTICLE SIZE , m i c r o n s
L
P=2.7pba..(-~)D " M~(3.2-3M~)N*(1-O.i/29-1°N*) + S.
33 *
Design calculations can either be done for open circuit or closed circuit. The
program gives as output the calculated mill length, mill diameter, mill speed,
ball load, hydrocyclone number and the size distribution in all of the circuit
streams.
As an example: Select a mill to grind 425 tph of copper ore from a feed size
of 80% passing 2360/~m to a product of 80% passing 210 ttm. The mill is to be
loaded to 37 % of its volume with 76.2 m m ( 3 inch) to size balls and rotated at
a speed of 72% of its critical speed.
According to the scale-up procedure, batch experiments were conducted in
90
TABLE I
1
10 100 1000
Particle Size, microns
Fig. 16. Comparison of plant experimental size distribution and predictions for copper ore grinding
circuit.
a 380 X 290 mm (15 X 11.5 inch ) mill with a B L H torque sensor for power de-
termination. The ball size distribution approximated that of an "equilibrium
charge" with top size of 76.2 mm (3 inch). The mill speed was kept at 72% of
its critical speed. Size distributions of feed and product, and power data were
input to the E S T I M I L L to estimate breakage parameters. In turn, the esti-
mated breakage parameters, R T D correlation data plus the design require-
ments were input to the computer program. The results from the program of
the power ( P ) , the diameter (D) and the length (L) required for this task are
shown in Table I. Also shown are the actual values obtained from the Chino
plant. Fig. 16 shows a comparison of the predictions and the experimental size
distributions obtained for the plant. The agreement between predictions and
actual performance is very close. In this case prediction errors are only 3.3%
on power and 2% on product size distributions.
CONCLUSIONS
In this paper the correlation of breakage kinetics and transport with mill
design and operating variables has been described for large mills.
Large mill ( D > 5 . 0 m (16.5 ft)) performance has been successfully pre-
dicted from small scale batch test for kinetics and an R T D correlation for
91
ACKNOWLEDGEMENTS
T h e a u t h o r s g r a t e f u l l y a c k n o w l e d g e t h e f i n a n c i a l s u p p o r t of t h e U S B M ,
G r a n t No. 1125149, G e n e r i c M i n e r a l T e c h n o l o g y C e n t e r for C o m m i n u t i o n .
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