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XI Chemistry Ch. # 1

04-01-2016 40 1 hour

Q.No.1. Encircle the best option. 1x12=12

(i) The efficiency of reaction is expressed in the form of:
(A)Theoretical yield (B)actual yield (C)fractional yield (D)percentage yield
(ii) If we are given the volume of one substance, we can calculate the mass of other substances (product), then
relation is called…..relation.
(A)volume mole (B)volume mass (C)mass volume (D)mole volume
(iii) The volume occupied by one mole of an ideal gas at standard temperature and pressure is called:
(A)molecular volume (B)molar volume (C)molal volume (D)normal volume
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(iv) The mass of 1.2046X10 atoms of sodium metal is:
(A)23g (B)34.5g (C)46g (D)11.5g
(v) For the sake of convenience the atomic mass may be given in …… Units of measurement.
(A)grams/mole (B)kilogram/mole (C)pounds/mole (D)all of these
(vi) The molar weight of compound is 110 g/mole and empirical formula is C 3H3O then molecular formula of
compound is:
(A) C3H3O (B)C6H6O2 (C)C9H9O3 (D)C12H12O4
(vii) Isotopes differ in
(A)properties which depend upon mass (B)arrangement of electrons in orbitals
(C)chemical properties (D)the extent to which they may be affected in electromagnetic field.
(viii) Many elements have fractional atomic masses. This is because:
(A)the mass of the atom is itself fractional (B)atomic masses are average masses of isobars
(C)atomic masses are average masses of isotopes.
(D) atomic masses are average of isotopes proportional to their relative abundance.
(ix) The mass of one mole of electrons is:
(A)1.008mg (B)0.55mg (C)0.184mg (D)1.673mg
(x) The number of moles of CO2 which contain 8.0 g of oxygen:
(A)0.25 (B)0.50 (C)1.0 (D)1.50
(xi) The volume occupied by 1.4 g of N2 at S.T.P is:
(A)2.24 dm3 (B)22.4dm3 (C)1.12dm3 (D)112cm3
(xii) A limiting reactant is the one which:
(A)is taken in lesser quantity in grams as compared to other reactants.
(B)is taken in lesser quantity in volume as compared to the other reactants.
(C)gives the maximum amount of the product which is required.
(D)gives the minimum amount of the product under consideration.
Q.No.2. Write short answer of the following. 𝟏𝟎 × 𝟐=20
i. 180 g of glucose and 342 g of sucrose have the same number of molecules but different number of atoms present in them.
Justify ?
ii. One mg of K2CrO4 has thrice the number of ions than the number of formula units when ionized in water.
iii. Calculate mass in grams of 2.74 moles of KMnO 4
iv. Many chemical reactions taking place in our surrounding involve the limiting reactants. Justify?
v. N2 and CO have the same number of electrons protons and neutrons. Justify?
vi. What is efficiency of reaction? How it is expressed?
vii. Define molar volume with example.
viii. What is the justification of two strong peaks in the mass spectrum for bromine; while for iodine only one peak at 127 amu is indicated?
ix. What are molecular ions? How they are produced?
x. How limiting reactants are identified?
Q.No.3. (a)Write a note on stoichiometry. Also explain its relationships. 4
(b) NH3 gas can be prepared by heating together two solids NH4Cl and Ca(OH)2.If a mixture containing 100g of each solid is heated then.
(i) Calculate the number of grams of NH3 produced. 2
(ii) Calculate the excess amount of reagent left unreacted.2NH4Cl(s)+Ca(OH)2(s) CaCl2(s) + 2NH3(g) + 2H2O 2