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www.modernsoapmaking.com /lye-solution-in-soapmaking/
Kenna
One of the most common issues I run into with soapmakers is not understanding how the lye solution in
soapmaking works. For instance, a soapmaker might take one of our recipes and incorrectly use the “water as a
percentage of oils” option instead of the “lye concentration” option and think there is something wrong with the
formula. Or misunderstand how to partially replace the water in a recipe, like the Lemon Zest & Blueberry Yogurt
Recipe.
Even bigger issues crop up when a soapmaker tries to scale up and doesn’t understand the lye solution when
trying to masterbatch or when they reach out for recipe help because the recipe is soft, traces too quickly, or
takes a long time to cure!
Many soap calculators compound the issues by presenting the default options of calculating the water as a
percentage of the oils, so newer soapmakers are missing out on this vital information!
Let’s talk about the elephant in the room first: what’s wrong with calculating your water amount based on the
oils?
Simply put, you end up with a large variety of solution strengths! Different oils need varying amount of lye of to
saponify, but the amount of water won’t change based on the lye. Since the amount of water present helps
determine both your speed of trace and your cure time, this can create inconsistent results from batch to batch.
For instance, if calculating your water amount based on a percentage of the oils, these two formulas are wildly
different:
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16 ounces of Olive Oil
2.06 ounces of Lye
38% of oils: 6.08 ounces of water
results in a 25.3% lye solution
The olive oil soap will trace slower and cure slower than the coconut oil soap, due to the varying lye solution
strength from batch to batch, even if you made the soaps on the same day! However, the coconut oil soap
will saponify even faster and enter gel phase at a much higher temperature (though the gel phase will be shorter
duration).
The bigger problem with this is that olive oil saponifies slower than coconut oil anyways! It would be better to
have a stronger lye solution and less water for the olive oil soap (so that it doesn’t take a year to cure and an
hour to trace). Since coconut oil saponifies more quickly on its own, it would be more beneficial to have a weaker
lye solution and more water so the lack of water isn’t compounding the issue.
If this is news to you, you might want to read up on controlling trace and the various factors that affect trace!
My biggest concern with calculating your water as a percentage of oils is that you might accidentally discount
your water too much! If you aren’t keeping your lye in mind by calculating your water based on your lye, you
could do something like this:
The coconut oil soap’s lye solution is too concentrated! Lye cannot dissolve into a solution with less liquid than
its own weight. If you were to make this soap, it would be lye heavy and unevenly saponified, with free particles
of lye in the bar.
In order to master water discounts and water replacements or alternative liquids, you must be able to understand
your water in relation to the lye instead. The easiest way to do this is to look at your lye solution as a whole
ingredient and calculate your water as a ratio of the lye.
When most recipes refer to full water, they are usually calculating a lye solution strength between 25% and 28%,
which means that 25% to 28% of the solution is lye and the remainder (72% to 75%) is water.
It’s important to remember that your lye solution A 25% lye solution is made of 25% lye and 75% water.
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Using a lye solution where the lye is no longer dispersed in the liquid or water can cause uneven saponification
and lye pockets. As such, I tend recommend using a weaker solution strength (40% lye solution) as the
maximum water discount in most cases.
The table below covers the full range of multipliers from a 25% solution to a 50% solution, and highlights the
most commonly used concentrations:
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Lye Amount Water Multiplier Lye Solution Notes
Weight of Lye x 1 = Water Amount 50% lye solution maximum water discount
Weight of Lye x 1.5 = Water Amount 40% lye solution strong water discount
Weight of Lye x 2 = Water Amount 33.3% lye solution moderate water discount
Weight of Lye x 2.5 = Water Amount 28.6% lye solution mild water discount
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It doesn’t matter which way you decide to conquer the beast, as long as you are calculating your water amount
based on your lye!
When it comes to my own soapmaking, I prefer 33% lye solutions in smaller batches ( five pounds or less) and
40% lye solutions in larger batches (more than five pounds). Do you have a favorite lye solution strength in
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your soapmaking? If so, leave a comment below and tell me why! I think it’ll be interesting to see what other
soapmakers use as their go-to!
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