Escolar Documentos
Profissional Documentos
Cultura Documentos
BRAUN, SMITH*
AND
A. STOLTE**
Center for
National -· uw-&.B:IJIN
Washington, D. C.
Keywords: cigarettes; cotton batting; fabrics; flammability; ignition; polyester batting; poly
urethane foam; pyrolysis products; smoldering; toxicity; upholstered furniture.
*Dr. Smith was a Research Associate at NBS. Present address: B.F. Goodrich Chemical Group,
Technical Center, Avon lake, OH 44012.
**Present address: Anesthesiology Department, George Washington University Medical Center,
Washington, DC 20037. ·
Note: This work was funded by the U.S. Consumer Products Safety Commission at the National
Bureau of Standards; it is not subject to copyright.
Journal of Consumer Product Flammability, Vol. 9 (December 1982), p. 167
0362-16nia2/04 0167-17 $04.50/0
©1982 Technomic Publishing Inc.
E. Braun, J. Krasny, D. Peacock, M. Paabo, A. Stolte
after cigarette
toxicity deleterious affects contemporary"
II
*This work was sponsored by the U.S. Consumer Product Safety Commission to obtain answers to
specific questions raised by the upholstered furniture industry and CPSC staff.
**The term "technical failure" was introduced because such assemblies fail tests .based on char
length measured on the fabric surface but were believed to have low injury potential, because
of non-involvement of the filling materials.
168
Cigarette Ignition of Upholstered
taminant [5]. A C02 level of 40,000 ppm is reported [6] to be capable of caus-
ing increased respiration rate, headache and weakness in man. Total hydro-
carbon concentration has not been related to physiological response.
Jin studied the effect of smoke obscuration on escape potential of humans
[7 ,8]. He found that humans would be slowed down to a walking speed below
that of a blindfolded person in a smoke free environment by an optical density
level of 0.5 OD/m for non-irritating smoke and 0.2 00/m for irritating smoke.
The layout of the burn room is shown in figure 1. The dimensions were
3 x 3 x 2.4 m (approximately 10 x 10 x 8 ft). The walls and ceiling con-
sisted of two layers of gypsum board. The door was closed during all tests, but
had a 25 mm ( 1 in) high opening at the bottom of the door.
Sampling ports for the gas analysis equipment were located at 2.3, 1.7, 0.8,
and 0.3 m (7'9", 5'6", 30'', and 12'1 above the floor. sampling lines were
heated, except the one at 0.8 m, and provided with cold traps and filters. Ther-
mocouples were located at the same positions except at 0.8 m, and smoke
V=21.6m3
3.0m
CLG\'J
OUT 2.4m
PAIJEl
TC - thermocouples
A,B,C - ports
Figure 1. Configuration of test room.
169
E. Braun, J. F. Krasny, R. D. Peacock, M. A. Stolte
170
Table 1. Smolder/ Burn Behavior of Six Upholstered Chairs
Chair
1 2 3 4 6 8
Seat cushion foam w. foam res. treated PE batting PE batting PE batting cotton
topper PE batting over foam batting
over foam
-...!
4000 - 63 79 95 - 33
-
-....!
N
Table 1. (Continued)
Chair
1 2 3 4 6 8
CO (ppm-min)
20,000 - 63 57 51 - 31
40,000 - 65 69 61 - 35
60,000 - 67 75 69 - 39
80,000 - 69 81 75 - 41
100,000 - 73 85 83 - 43
150,000 - 78 93 95 - 58
C02 (ppm)
10,000 - 63 71 63 52 29
20,000 - 63 97 105 91 33
Total HC (ppm)
1,000 - 53 47 43 39 29
2,000 - 59 61 n 56 35
Oa (%)
18 - 61 87 95 69 33
Temperature ( °C)
40 - 59 75 80 60 26
60 - 60
Optical density (00/m)
at 1.7 m-0.2 29 30 18 14 23 12
-0.5 40 39 23 25 26 18
at 0.8 m-0~2 45 41 22 17 26 21
-0.5 50 46 31 39 29 23
ature,
function
obtained
generally
The initial """"""'~nr.!31fl'~
After the " 1
'"'!:!11r'.ell"l:lli
thick smoke,
and 6 occurred corner 'II'II"U''II'nil:•n
173
E. Braun, J. F. Krasny, R. D. Peacock, M. Paabo, G. F. Smith and A. Stolte
25 ~--------~,----------~.----------r-,---------,r---------.
-----, ~~1
' - - CHA:~ e
', ·······•···· CHA:R 3
·- · - · - ·--. , - · - · - · - CHA:~ 4 -
23 - • --"-) -·-·-CHA:'< 5
,_.._
t:n
c.
....._----:- • - -
·-- ...__
- - - - - CIIA~l (j
t-
:r.: 19
0
-
··························
. ··········....
..
-·-·- .. -
w \_·=··..- - -
3
17 r- -
15 ~-----------~'----------~'----------._---------'~-------~
1
0 30 60 90 120 150
TIME (rnln)
10000~------~.~------~~------~.---------T,--------~
// I I
I ..--·-·-
8000 f-
// I / __,.
E
c.
8 / I //
z
~
<(
6000 r-
/ I ·1/
0::
t-
z
w
:
I
I
I
I
.. /,
.
~ 4000-
6
u / I . .r .,. /..,.
(/)
<(
2000 - I
I
r. .-...::.·', • =·=· ~~ ~
-·-·-·-CHAIR 4
.,...·".· .. : .
(!) -·-·-CHAIR 5
I -----CHAIR 6
I ,. 1
/ .~·:.::;.·:;;-·-·
// .... ~,-; ..• ·__.. I I I
0~----~~~~----~b-------~--------~--------~
0 30 60 90 120 150
TIME (min)
174
Cigarette Ignition of Upholstered Chairs
---CHAIR :1.
--CHAIR 2
............ CHAIR 3
'2 I
-·-·-·-CHAlK 4
~
- - - - - CHAIR 6
300000 - I
E
0.
I
..._,
0. I
I
z I /
0
·t=: I /
< 200000 /
0:: I
1- I
z
UJ I
0
z
0
I
I
(.) 100000 I
(./)
<( I
(.!) I
I
/
---CHJI.iR :1.
--CHAIR e
•••••••••••• CHAAR 3
- · - · - · - CHAiR 4
80000 -·-·-CHAIR 5
'E
0.
-----CHAIR 6
a
z
0
;:: 60000 -
<
0::
1-
z
w
0
z 40000 -
0
0
(./)
<(
(.!)
20000
30 60 go 120 150
TIME (min)
175
E. Braun, J. Krasny, R. D. Peacock, M. A. Stolte
Chairs
Chairs 1 and 2 were contemporary, commercial chairs, carrying UFAC
labels; experimental chair 3 was built with had the
same cover fabric and configuration as chairs 4, 5
chairs ( 1 and were covered rayon velvets
and construction, and contained considerable
foam. They mainly in the filling material
rounded cushion (barrel chair), the other had a
Considering these differences, the behavior of chairs 1
and flaming was remarkably similar. Rates of '"'' 10
'Rd"''llr'!IT
176
Cigarette Ignition of Upholstered Chairs
5000--------~--------~~------~--------~------~
I
I
I
I
,...... 4000 I
E
0.. I
8 I
z
0
I
3000 I
t=
<(
~
I
t- I
z
w I
z 2000
(.)
I
0 I
(.)
(/)
..:(
(!')
1000 lI
0~--------~--------~--------~--------~--------~
0 30 60 90 120 150
TIME (min)
! ' I ;, .
21
18
,......
~ 15
z
0
;:::
<(
~
12
t-
z
w
(.)
z 9 -
0
c.>
---CHAIR 1
(/) 6 - - - CHA!R e
<(
(.!)
............ cw..:R :;
-·-·-·- CHJ.:K 4
-·-·-Ct!Jj~ 5
3 - - - - -CttJ.JR 6
0
0 30 60 90 120 150
TIME (min)
Figure Z Smoldering chair tests, oxygen concentration at 168 em.
177
E. Braun, J. F. Krasny, R. D. Peacock, M. Paabo, G. Smith and A. Stolte
300
---CHA!r11
- - CtlAii~ 2
••••••••.••• O.i;..:=< 3
250 - · - · - · - CHA!K 4
-·-·-CHAL=< 5
-----CHAL~ 6
,.......
~
...._, 200
w
0:
:::::>
t- 150
<C
0:
w
0..
~
w 100
t-
50
0
0 30 60 90 120 150
TIME (min)
Figure 8. Smoldering chair tests, temperature at 168 em.
Chair 6 had the same configuration and cover fabric as chair 3, but its filling
material consisted entirely of cotton batting (except springs in the cushion). In
this manner, the burn characteristics of chair 6 constructed of materials
popular 20 to 30 years ago could be compared with the polyurethane foam and
polyester batting filling type of construction commonly used today.
Flaming ignition occurred at about 22 min, much earlier than in the two
commercial chairs which flamed, chairs 1 and 2. Consequently, the various
product levels listed in table 1 were reached much earlier in chair 6 than in any
of the other chairs. However, no HCN was detected. After flaming ignition,
the rates of increase for weight loss, CO and C02 concentration, and oxygen
depletion were lower for chair 6 than the same rates for the urethane-contain-
ing chairs 1 and 2. Similarly, the highest temperature measured was con-
siderably below that found for the other flaming chairs. This is in accordance
with earlier findings [ 15].
178
Cigarette Ignition of Upholstered Chairs
J •
---CHAlR 1
!I •J --CHAIR f
........... • Ct';..R 3
-·-·-·- CHJ..~~ 4
4
~
;/ --·-·MCII,',;,( ti
- - - - - CHAlK 6
.......
a
0
.._, .,n·
>- 3 I;
t:
(/)
z
w ( /
}······x····· .
0
....J2
~
t-
n..
0 1 / :.ifi ...
I ·;·
•\
,,.
I ::
~·::d.
':"'.
0 ."'
0 30 60 90 120
TIME (min)
Figure 9. Smoldering chair tests, optical density at 168 em.
as a Function
. The above discussion was based mostly on time from placement of the
179
E. Braun, J. F. Krasny, R. D. Peacock, M. Paabo, G. F. Smith and A. Stolte
cigarette on the chairs. Table 2 shows the values the various parameters at
250 g weight loss. All chairs were fully involved in smoldering or burning at this
point. It was reached in 31 to 53 minutes in the chairs which only smoldered,
and 28 to 70 minutes, i.e., after flaming ignition, in the others. Footnotes in
the tabla indicate whether the 250 g weight loss occurred during a rapid in-
crease of the measured property.
Table 2 shows that no chair was consistently better or worse than the otr.ers
in all of the measured properties when compared in this manner; e.g., this
weight loss occurred about 6 minutes after ignition in chair 6, and it produced
a relatively high (and rapidly increasing) CO concentration, as well as relatively
high temperature. On the other hand, the OD (smoke) values and C02 and
total . hydrocarbon concentrations were relatively low. Oxygen depletion
results for all chairs were similar, as were temperatures for those chairs which
did not flame before 250 g weight loss.
Potentially life threatening conditions, i.e., low visibility and high pyrolysis
1 2 3 4 5 16
Weight loss of 70 59 53 46 31 28
260 g reached
in min.
Ignition time 65 58 none none none 22
(min.)
Pyrolysis products
at 1.7 m
CO (ppm) 1,0701 1,025 1,145 1,63()2
Co (ppm~min) 10,3201 14,530 13,350 11,390
C02 (ppm) 3,450' 4,600 4,935 2,995 1,4352
Total HC (ppm) 2,0151 1,335 950 665 35()2
02 (%) 191 20 28 20 20
Temperature ( °C) 8()2 271 30 34 30 652
Optical density
(00/m)
at 1.7 m 2.42 3.03 2.44 5.()3 1.53 0.34
at .am 2.()2 2.53 2.84 1.6 3 1.2 3 1.12
1
Flame ignition and rapid increase occurred about 1 min. later.
2
Rapid increase at this time (after flame ignition).
3Rapid increase in OD at this time, independent of flame ignition.
4
00 leveled out or decreased before this time.
180
product lf"nl"-f/"'II.:lln+ra.+·iinru:~
cigarette RRII"'l,ft'li'ld"';ll"'l
chairs were fr'IIM>II.OI!i:JA!F ....nl
contained a
not.
time
chairs IIADII"llBII"'ft TH!:I!lii'Y'lJCI,,;
smoldered li".tl!:ll!CU'•II"ll•.a.d""''
181
E. Braun, J. and Stolte
1. Braun, E., Peaoock, R., Smith, G., and Stolte, Cigarette Ignition of Upholstered
Chairs, letter report by the Center for Fire Research, National Bureau of Standards, to the U.S.
Consumer Product Safety Commission (1981).
2. Alarie, Y.C., University of Pittsburgh, Pittsburgh, PA, in preiparl!lltton.
3. Packham, S.C., Toxic Gas Tenability limits in Fire Environments, Annual Progress Report to the
National Bureau of Standards (August 1980).
4. Lieu, Magill, J.H., and Alarie, Y.C., Toxicity of the Degradation Prod4cts from
Polyphosphazene Copolymers, J. Combustion Toxicology, 7, 143-156 1980).
5. Levin, B.C., Center for Fire Research, National Bureau of Standards, personal communication.
6. Packham, S.C., Flammability and Toxicological Aspects Pertaining to the Combustion of
Douglas Fir, Flammability Research Center, University of Utah, Salt Lake City, Utah 84112
(1975).
1. Jin, T., Visibility Through Fire Smoke. Part 2, Report of Fire Research Institute of Japan, 33,
31-48 (1971). Part 5, Report of Fire Research Institute of Japan, 42, 12-18 (1975).
8. Jin, T., Vmibility through' Fire Smoke. In: Main Reports on Production, Movement and Control
of Smoke in Buildings, 100-153, Japanese Association of Fire Science and Engineering (1974).
9. UFAC (Upholstered Furniture Action Council) Program Participant Guide, UFAC Central, High
Point, North Carolina 27261.
182
Cigarette Ignition of Upholstered Chairs
10. State of California, Department of Consumer Affairs, Bureau of Home Furnishing, Flammability
Information Package (Jan. 1980).
11. The Business and Institutional Furniture Manufacturer's Association First Generation Voluntary
Upholstered Furniture Flammability Standard for Business and Institutional Markets, BIFMA,
2335 Burton, S.E., Grand Rapids, Michigan 49506 (May 22, 1978).
12. Loftus, J.J., Bock-up Roport for tho Proposod Stundurd for tho Flummubitity (Ciourutto lonition
Resistance) of Upholstered Furniture, PFF 6-76 appendix C, NBSIR 78-1438, Center for Fire
research, National Bureau of Standards, Washington, D.C. 20234 (June 1978).
13. McCarter, R.J., Smoldering Combustion of Cotton and Rayon, J. Consumer Product Flam-
mability, 4, 346-354 (December 19n).
14. Damant, G.H., Krasny, J.F., and Williams, S.S., Cigarette Ignition Behavior of Commercial
Upholstery Cover Fabrics, J. Consumer Product Flammability, in preparation.
15. Babrauskas, V., Full-scale Burning Behavior of Upholstered Chairs, Technical Note 1103, Na-
tional Bureau of Standards, Washington, D.C. (1979).
16. Pressler, P.l. and Oakley, M.S., Upholstered Furniture Flammability· Tests- Methods and Data
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Washington, D.C.
183