PROBLEMA 102 DEL PROBLEMARIO.

UTILIZANDO LA ECUACION SRK Y LA REGLA DE MEZCLADO

DATOS DEL PROBLEMA:
Temp: 160 °F = 620 R
Presión: 4000 psia
R: 10.732
Dato Dato Tabla A-1 Tabla A-1 Cálculo Cálculo Fórmula Fórmula Tabla A-1 Fórmula
xi yj wj Tc Tc
COMPONENTE Fraccion Fracciòn Factor
°F °R Tr m α Pc ac
liquida vapor acèntrico
METANO 0.45 0.86 0.0104 -116.67 343.33 1.81 0.4945 0.6888 666.40 8,708.95
ETANO 0.05 0.05 0.0979 89.92 549.92 1.13 0.6324 0.9234 706.50 21,074.83
PROPANO 0.05 0.05 0.1522 206.06 666.06 0.93 0.7155 1.0510 616.00 35,458.73
N-BUTANO 0.03 0.02 0.1995 305.62 765.62 0.81 0.7870 1.1638 550.60 52,416.43
N-PENTANO 0.01 0.01 0.2514 385.80 845.80 0.73 0.8646 1.2642 488.60 72,087.34
N-HEXANO 0.01 0.005 0.2994 453.60 913.60 0.68 0.9355 1.3568 436.90 94,060.50
PEPTANO PLUS 0.40 0.005 0.5200 700.00 700.00 0.89 1.2509 1.1527 285.00 84,650.27
total 1.00 1.00

Propiedades del Heptano plus: Peso molecular: 215 lbm-mol Cálculo de las densidades
Presiòn crìtica (Pc) 285 lb/pg2 abs
Temp. Crìtica (Tc) 700 R FACTOR RT 6653.84
Factor acentrico 0.52 Fase líquida

FORMULAS:
Tr = T/Tc Fase vapor

Fórmulas para la Ecuación de estado de SRK

Para la fase líquida Para la fase Vapor

Donde Ωa= 0.42748 A= 3.2764 A= 0.8076

 Donde Ωb= 0.08664 B= 0.7754 B= 0.3376

Ejemplo para calcular aT y b (tanto para la fase líquida como para la fase vapor) de acuerdo a las reglas de

Fase líquida Fase v

XI XJ aTi aTj aTi*aTj Fórmula parcial YI YJ aTi
0.45 0.45 5,999.15 5,999.15 35,989,791.88 1,214.83 0.86 0.86 5,999.15
0.05 19,459.48 116,740,322.97 243.10 0.05
0.05 37,267.06 223,570,675.08 336.43 0.05
0.03 61,001.35 365,956,219.32 258.25 0.02
 0.01 91,130.01 546,702,528.08 105.22 0.01
0.01 127,625.86 765,646,559.85 124.52 0.005
0.40 97,577.96 585,384,748.19 4,355.05 0.005
0.05 0.45 19,459.48 5,999.15 116,740,322.97 243.10 0.05 0.86 19,459.48
0.05 19,459.48 378,671,348.00 48.65 0.05
0.05 37,267.06 725,197,658.84 67.32 0.05
0.03 61,001.35 1,187,054,578.58 51.68 0.02
0.01 91,130.01 1,773,342,560.73 21.06 0.01
0.01 127,625.86 2,483,532,746.45 24.92 0.005
0.40 97,577.96 1,898,816,330.70 871.51 0.005
0.05 0.45 37,267.06 5,999.15 223,570,675.08 336.43 0.05 0.86 37,267.06
0.05 19,459.48 725,197,658.84 67.32 0.05
0.05 37,267.06 1,388,834,003.82 93.17 0.05
0.03 61,001.35 2,273,341,265.02 71.52 0.02
0.01 91,130.01 3,396,147,820.88 29.14 0.01
0.01 127,625.86 4,756,240,848.06 34.48 0.005
0.40 97,577.96 3,636,444,016.26 1,206.06 0.005
0.03 0.45 61,001.35 5,999.15 365,956,219.32 258.25 0.02 0.86 61,001.35
0.05 19,459.48 1,187,054,578.58 51.68 0.05
0.05 37,267.06 2,273,341,265.02 71.52 0.05
0.03 61,001.35 3,721,165,015.42 54.90 0.02
0.01 91,130.01 5,559,053,826.50 22.37 0.01
0.01 127,625.86 7,785,349,837.72 26.47 0.005
0.40 97,577.96 5,952,387,554.86 925.82 0.005
0.01 0.45 91,130.01 5,999.15 546,702,528.08 105.22 0.01 0.86 91,130.01
0.05 19,459.48 1,773,342,560.73 21.06 0.05
0.05 37,267.06 3,396,147,820.88 29.14 0.05
0.03 61,001.35 5,559,053,826.50 22.37 0.02
0.01 91,130.01 8,304,678,593.35 9.11 0.01
0.01 127,625.86 11,630,545,441.19 10.78 0.005
0.40 97,577.96 8,892,280,422.00 377.20 0.005
0.01 0.45 127,625.86 5,999.15 765,646,559.85 124.52 0.005 0.86 127,625.86
0.05 19,459.48 2,483,532,746.45 24.92 0.05
0.05 37,267.06 4,756,240,848.06 34.48 0.05
0.03 61,001.35 7,785,349,837.72 26.47 0.02
0.01 91,130.01 11,630,545,441.19 10.78 0.01
0.01 127,625.86 16,288,359,114.56 12.76 0.005
0.40 97,577.96 12,453,470,698.62 446.38 0.005
0.40 0.45 97,577.96 5,999.15 585,384,748.19 4,355.05 0.005 0.86 97,577.96
0.05 19,459.48 1,898,816,330.70 871.51 0.05
0.05 37,267.06 3,636,444,016.26 1,206.06 0.05
0.03 61,001.35 5,952,387,554.86 925.82 0.02
0.01 91,130.01 8,892,280,422.00 377.20 0.01
0.01 127,625.86 12,453,470,698.62 446.38 0.005
0.40 97,577.96 9,521,458,321.90 15,612.47 0.005
SUMATORIA TOTAL 36,264.44
 Fórmula Fórmula Tabla A-1 Fórmula Fórmula
Peso Ma Ma
aTi bi Molecular x
líquido vapor
Componente

5,999.15 0.4790 16.043 7.219 13.797

19,459.48 0.7237 30.070 1.504 1.504
37,267.06 1.0054 44.097 2.205 2.205
61,001.35 1.2929 58.123 1.744 1.162
91,130.01 1.6096 72.150 0.722 0.722
127,625.86 1.9443 86.177 0.862 0.431
97,577.96 2.2838 215.000 86.000 1.075
100.255 20.895

des de la fase líquida y fase vapor:

50.5339

13.4792

Para la fase líquida

Donde:
Z= 1.19264
Para la fase Vapor
 Donde:
Z= 0.9319

de mezclado:

Fase líquida
YI bj Fórmula
0.45 0.4790 0.2156
0.05 0.7237 0.0362
0.05 1.0054 0.0503
0.03 1.2929 0.0388
0.01 1.6096 0.0161
0.01 1.9443 0.0194
0.40 2.2838 0.9135
SUMATORIA TOTAL 1.2899
Fase vapor
YI bj Fórmula
0.86 0.4790 0.4120
0.05 0.7237 0.0362
0.05 1.0054 0.0503
0.02 1.2929 0.0259
0.01 1.6096 0.0161
0.005 1.9443 0.0097
0.005 2.2838 0.0114
SUMATORIA TOTAL 0.5615
ase vapor
aTj aTi*aTj Fórmula parcial
5,999.15 35,989,791.88 4,436.97
19,459.48 116,740,322.97 464.60
37,267.06 223,570,675.08 642.95
61,001.35 365,956,219.32 329.04
 91,130.01 546,702,528.08 201.08
127,625.86 765,646,559.85 118.98
97,577.96 585,384,748.19 104.04
5,999.15 116,740,322.97 464.60
19,459.48 378,671,348.00 48.65
37,267.06 725,197,658.84 67.32
61,001.35 1,187,054,578.58 34.45
91,130.01 1,773,342,560.73 21.06
127,625.86 2,483,532,746.45 12.46
97,577.96 1,898,816,330.70 10.89
5,999.15 223,570,675.08 642.95
19,459.48 725,197,658.84 67.32
37,267.06 1,388,834,003.82 93.17
61,001.35 2,273,341,265.02 47.68
91,130.01 3,396,147,820.88 29.14
127,625.86 4,756,240,848.06 17.24
97,577.96 3,636,444,016.26 15.08
5,999.15 365,956,219.32 329.04
19,459.48 1,187,054,578.58 34.45
37,267.06 2,273,341,265.02 47.68
61,001.35 3,721,165,015.42 24.40
91,130.01 5,559,053,826.50 14.91
127,625.86 7,785,349,837.72 8.82
97,577.96 5,952,387,554.86 7.72
5,999.15 546,702,528.08 201.08
19,459.48 1,773,342,560.73 21.06
37,267.06 3,396,147,820.88 29.14
61,001.35 5,559,053,826.50 14.91
91,130.01 8,304,678,593.35 9.11
127,625.86 11,630,545,441.19 5.39
97,577.96 8,892,280,422.00 4.71
5,999.15 765,646,559.85 118.98
19,459.48 2,483,532,746.45 12.46
37,267.06 4,756,240,848.06 17.24
61,001.35 7,785,349,837.72 8.82
91,130.01 11,630,545,441.19 5.39
127,625.86 16,288,359,114.56 3.19
97,577.96 12,453,470,698.62 2.79
5,999.15 585,384,748.19 104.04
 19,459.48 1,898,816,330.70 10.89
37,267.06 3,636,444,016.26 15.08
61,001.35 5,952,387,554.86 7.72
91,130.01 8,892,280,422.00 4.71
127,625.86 12,453,470,698.62 2.79
97,577.96 9,521,458,321.90 2.44
SUMATORIA TOTAL 8,938.64
 XI XJ aTi aTj aTi*aTj Fórmula parcial
0.43 0.43 5,837.17 5,837.17 1,079.29 6.07
0.43 0.15 5,837.17 19026.76 679.74
0.43 0.42 5,837.17 196,934.51 6,123.22
0.15 0.43 19,026.76 5,837.17 679.74
0.15 0.15 19,026.76 19026.76 428.10
0.15 0.42 19,026.76 196,934.51 3,856.42
0.42 0.43 196,934.51 5,837.17 6,123.22
0.42 0.15 196,934.51 19026.76 3,856.42
0.42 0.42 196,934.51 196,934.51 34,739.25
57,565.40

FASE LIQUIDA
0.81 0.81 5,837.17 5,837.17 3,829.77
0.81 0.14 5,837.17 19026.76 1,195.08
0.81 0.05 5,837.17 196,934.51 1,373.15
0.14 0.81 19,026.76 5,837.17 1,195.08
0.14 0.14 19,026.76 19026.76 372.92
0.14 0.05 19,026.76 196,934.51 428.49
0.05 0.81 196,934.51 5,837.17 1,373.15
0.05 0.14 196,934.51 19026.76 428.49
0.05 0.05 196,934.51 196,934.51 492.34
10,688.46