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41Che Kanyakumari District Common Examinations (| {_[_) Quarterly Examination, September - 2013 : TVK www.tnschools.co.in Standard 11 Time: 3.00 Hrs. CHEMISTRY Marks: 150 Part-I Answer all the questions. Choose and write the correct answer: 30x1=30 1) The number of atoms present in 0.5 grams - atoms of nitrogen is same as atoms in a) 12g of C b) 32g of S ¢) 8g of Oxygen 4) 24 g of magnesium, 2) 5L of 0.1 M solution of sodium carbonate contains a) 53.9 of Na,CO, b) 106 g of Na,CO, ¢) 10.6 g of Na,CO, d) 5x10? millimoles of Na,CO, 3) The oxidation number of phosphorous in PO,?- is equal to a) +3 b)-3 ) +5 d)-5 4) Equivalent weight of KOH is a) 49 b) 56 ) 98 d) 31.6 5) Which one of the following metal occur in native form? a) tin b) zinc ¢) platinum d) calcium 6) Heating the ore in the absence of air is called a) roasting b) smelting ¢) calcination d) reduction 7) The percentage of carbon in steel a) 0.15-13 b)0.1-2 ¢) 0.15-1.5 4) 0.5-1 8) Which one of the following is called Felspar? a) Na,AtF, b) Na,SiO, c) K,0.A0,05 d) NaF 9) When the 3d orbital is complete, the new electron will enter the a) 4p orbital b) 4f orbital c) 4s orbital 4) 4d orbital 10) The atomic number of an element is 17 and its mass number is 37. The number of protons, electrons and neutrons present in the neutral atom are a) 17, 37, 20 b) 20, 17, 17 ¢) 17, 17, 20 d) 17, 20, 17 11) The splitting of spectral lines by magnetic field into multiple lines is known as a) photo electric effect b) stark effect c) zeeman effect d) spectro effect 12) Each unit cell of NaC¢ consists of 4 chloride ioris and a) 13 Na ions b) 4.Na ions c) 6 Na ions d) 8 Na ions 13) Which one of the following is a anisotropic solid? a) glass .b) plastic c) rubber d) sodium chloride 14) Ina simple cubic unit cell, the angle between each of axes is a) 120° b) 60° c) 90° d) 180° 15) A curve drawn at constant temperature is called an isotherm. This shows relationship between a) P and b) PV and V c) Pandv d) Vand Vv 16) The value of normal atmospheric pressure a) 10 atm pressure b) 1.013x10-5 Nm? c) 1.013x105 Nm? d) 1.013% 10-3 Nm-? 11Che 2 TVK 17) What is the low temperature produced by adiabatic demagnetisation? a) 10K b) 10-4 ¢) 107K d) 10-6K 18) The compound which contains both ionic and covalent nature is a) CH, b) Hy c) KCN 4) Kce 19) Homonuclear diatomic molecules possess a) ionic bond b) covalent bond c) metallic bond 4) co-ordinate covalent bond 20) The bond angle in water molecule is a) 104°.5' b) 109°.28" <) 107° d) 90° 21) The functional group of aldehyde is a) -OH b) -o- ¢) -COOH d) -CHO 22) Which is the IUPAC name of isopropyl methyl ether? a) 1-methoxy propane b) Ethoxy ethane c) propoxy methane d) 2-methoxy propane 23) Identify the electrophilic reagent among the following a) NH, b) AEC, ) H,0 d) RNH, 24) Nitrobenzene and benzene can be seperated by the method of a) simple distillation b) crystallisation c) fractional crystallisation d) chromatography 25) Column chromatography is based on the principle of a) adsorption b) partition ¢) absorption d) distribution’ 26) Which organic compound is purified by distillation under reduced pressure? a) Glycerol b) Camphor ¢) Diethylether —_d) Ethanol 27) Organic compounds are insoluble in a) ether b) alcohol c) water d) benzene 28) Which element in the organic compound is detected indirectly? a) nitrogen b) sulphur c) hydrogen d) oxygen 29) In Liebig's combustion method, which compound is used to absorb CO,? a) Anhydrous CaCé, b) Anhydrous AéCe, ¢) Quick lime d) Caustic Potash 30) The colour of sodium nitropruside a) red b) purple c) yellow d) green Part-II Answer any fifteen questions: 15x3=45 31) Define Mole fraction. 32) Balance the following equations: i) KMnO, + H,SO, + K,SO, + MnSO, + H,0 + 0, il) _K,Cr,0, + H,SO, > K,SO, + Cr,(SO,), + H,0+0, 33) Define equivalent mass of a salt. 34) Distinguish between ore and mineral. 35) What is anode mud? 36) What is gravity seperation? 37) Define - orbital. 38) Define Zeeman effect. 39) What is meant by ‘Unit cell’ in crystallography? 40) What is Miller indices? 41) Find out the number atoms present in FCC crystal. 42) What is meant by inversion temperature? 43) 44) Define Charles law. What is octet rule? www.tnschools.co.in 11. Che 3 TVK 45) 46) 47) 48) 49) 50) 51) Explain the co-ordinate bond formation between BF, and NH;. What is catenation? How are free radicals formed by photochemical fission and thermal fission? Define chromatography. What are the different stages followed during crystallisation? How will you detect oxygen in organic compound? How will you prepare Lassaigne's filtrate? Part - III 7x5=35 Answer any seven questions atleast two questions from each secton: 52) 53) 54) 55) 56) 57) 58) 59) 60) 61) 62) 63) Question number 70 is compulsory and Answer any three from remaining questions: 64) 65) 66) Section - A Explain chloride method of determination of equivalent mass of an element. Calcualte the no. of moles present in the following: a) 3.43 g of C b) 76 g of CyHig What is zone refining? Describe the principle involved in the purificataton of the metal by this method. Describe about the limitations of Bohr's theory. Section - B Draw a neat diagram for Cesium Chloride structure and describe it accordingly State Dalton’s law of partial pressure. How is partial pressure calcualted? What are the characteristics of ionic compounds? What are the basic concepts of VSEPR'theory? Section - ¢ Write the IUPAC names of the following compounds: a] CH,-CH,-CH-CH,-OH b) GH,-CH,-CHO | CH, c) CHy-CH,~CH,-COOH 4) C)Hs~O-C;Hy e) CH,-CH-CH,~CH,-CH, I Br Explain about column chromatography. What are the characteristics of homologous series? Explain Kjeldahl method of estimation of nitrogen. Part - IV axt a] Write the general rules for assigning oxidation number of an atom. b] (i) Defing Mole ~ (ii) Define equivalent mass of acid a] Explain the various quantum numbers which completely specify the electron of an atom. b] How Nickel is extracted by Mond's Process? Write the various reaction involved in the process. a] Derive critical constants Tc, Pe and V_ from Vanderwall's constants. b] Give the distinguishing features of crystalline Solids and amorphous solid= www.tnschools.co.in 11 Che 67) 68) 69) 70) a] qd 4 wownw.tnschools.co.in TYK Calculate the lattice energy of NaCé using Born-Haber Cycle. Explain the hybridisation of ethylene. Explain different types of structural isomerism. Explain polymerisation reaction and addition reaction with suitable example. Explain steam distillation. How will you detect carbon and hydrogen in an organic compound? Acompound contains 32% carbon, 4% hydrogen and rest oxygen. Its vapour density is 75. Calcualte the emprical and molecular formula. 0.635 g of a metal gives on oxidation 0.795 g of its oxide. Calculate the equivalent mass of the metal. (OR) The critical temperature of hydrogen gas is 33.2°C and its critical pressure is 12.4 atm, Find out the values of ‘a’ and ‘b' for the gas. 0.15 g of iodoform gave 0.2682 g of AgI. Calcualte the percentage of iodine.

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