TM

JEE-MAIN TEST DATE

TARGET : JEE 2013 31 - 03 - 2013
Path to success KOTA (RAJASTHAN)
Kota | Chandigarh | Ahmedabad

FULL SYLLABUS
ANSWER KEY
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

Ans. 2 3 4 4 4 1 3 2 3 2 2 4 4 4 3 2 3 4 2 1
Que. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40

Ans. 3 2 1 2 3 2 1 4 4 2 4 2 3 2 1 4 4 2 2 4
Que. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Ans. 2 2 2 2 2 1 1 1 2 2 1 1 2 1 2 4 2 2 4 3
Que. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80

Ans. 3 2 1 3 3 1 3 1 2 2 4 4 4 1 3 4 3 2 2 2
Que. 81 82 83 84 85 86 87 88 89 90

Ans. 2 2 1 4 1 4 3 2 2 2

HINT – SHEET

1. |z1 + z2| = |z1| – |z2| (a + 3) (a – 1) < 0 and a  R

2 2
|z1| + |z2| + 2|z1| |z2| cos (1 – 2) a  (–3, 1) and a  R
= |z1|2 + |z2|2 – 2|z1| |z2| So a  (–3, 1)
cos(1 – 2) = –1 3. Four couples = 4 Men, 4 women
1 – 2 =  Possible cases
4
arg (z1) – arg(z2) =  (i) All 4 men = C4 = 1
4 1
(ii) 3 Men, 1 Woman = C3 × C1 = 4
4
 z1  (iii) 2 Men, 2 Women = C2 × 2 C2 = 6
arg  z  =  (iv) 1 Man, 3 Women = 4
C1 × 3 C3 = 4
 2  4
(v) All 4 Women = C4 = 1
z1 16
 purely negative real number
z2
4. Let Both A & B are having daughters = x
2. |z–a2| + |z + 2a| = 3
for an ellipse x C3 1
3 > |a + 2a| 2 So required probability = 
2x C3 20
|a2 + 2a| < 3
–3 < a2 + 2a < 3  x = 0, 3 but x  0
a2 + 2a – 3 < 0 and a2 + 2a + 3 > 0 So x = 3.

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 MAJOR TEST

LEADER & ENTHUSIAST COURSE 31–03–2013

5. tan2 + ptan + q = 0 For two distinct values of m

tan + tan = –p D = (–1)2 – 4(2b) (b) > 0
tan tan = q  1 – 8b2 > 0
p p 1 1
tan(  )    b2 < |b| <
1 q q 1 8 2 2
n1
[2a  (n1  1)d] 
2S1
 2a  (n1  1)d 
6. S1 = n1 11. a.b  0
2
 x2 + 2x – 1 + a > 0
n2 2S2  x2 + 2x + (a – 1) > 0
S2 = [2a  (n 2  1)d]   2a  (n 2  1)d
2 n2
 D = 4 – 4 (a – 1) < 0
2S3 a>2
n3  2a  (n 3  1)d
S3 = [2a  (n 3  1)d]   a  (2, )
2 n3
12. Eq of will is given by
S1 S2 S3
 n (n 2  n 3 )  n (n 3  n1 )  n (n1  n 2 )  0 (x – 3)2 + (y – 2)2 +  (3x + 8y – 25) = 0 ...(i)
1 2 3

n–1
It passes through (8, –3)
7. C 0. n C2 + n–1 C1 . nC3 +....+n–1 Cn–2 . nC n
=2
 n–1 C0 . n Cn–2 + n–1 C 1. nC n–3 +....+n–1 Cn–2 . n C 0
So we have to find coefficient of xn–2 in expansion Put  = 2 in (i)
of (1 + x)n–1.(x + 1)n i.e. (1 + x)2n–1 = 2n–1 Cn–2 x2 + y2 + 12y – 37 = 0
8. We have
[A(A + B)–1 B]–1 = B–1 [(A + B)–1 ]–1 A–1 r= 36  37 = 73 .
= B–1(A + B) A–1 = (B–1 A + I) A–1 14. Let ABCD be the given tetrahedron. Then,
ˆ 
 B–1 I + IA–1 = A–1 + B–1 .  ˆ ˆ  ˆ ˆ ˆ
AB = j , AC = j  k and AD = i  3j  k
2
x1 y1 1 1
9.  x2 y 2 1 =(a+b+c)(b+c–a)(c+a–b)(a+b–c) Now, volume =
6
x3 y3 1
1    1
 [AB AC AD] =
 4 2 = 16 s(s – a) (s – b) (s – c) 6 6
 4 2 = 16 2   
 [AB AC AD] = 1
 4 = 16   = 4
  
10. Eq of any tangent to y2 = 4x in terms of m is  (AB  AC).AD  1

1  ˆi.(iˆ  3jˆ  k)

ˆ = 1, which is true for all values
y = mx + .......(i)
m of .
2
Eq of any normal to x = 4by in terms of m is
y
b 17.  1  y2
dy  x  c
y = mx + 2b + .......(ii)
m2
Equation (i) and (ii) represent the same line   1  y2  x  c
1 b  1 – y2 = (x + c)2
 = 2b + 2
m m  (x + c)2 + y2 = 1
which represents a family of circle with fixed
or 2bm2 – m + b = 0
radius 1 and variable centres along the x-axis.

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 MAJOR TEST

JEE-MAIN 2013 31–03–2013

32. Vander Waal's, gas equation for µ mole of real
x 1  x
–1
cot gas
Lim x 1  x cot –1 (0)
23. =  µ2a  µRT
x 
sec –1{(2)} sec –1 () P  µ 2a
 2  (V – µb) = µRT P = –
V  V  µb V2
/2 on comparing the given equation with this
=
/2 1
standard equation we get µ = .
= 1. 2
26. St.-1 : (n + 1)7 – n7 – 1 m
7 Hence µ =  mass of gas
C0n7 + 7C1n6 + ...... + 7C6n1 + 7C7 – n7 – 1 M
7
C1n6 + ....... + 7C6n which are 1
m = µM = × 44 = 22 g
multiple of 7. So St.-1 is true 2
St.-2 : f(n) = n7 – n by P.M.I. 3 5
µ1C v1  µ 2 C v 2 1 R 1 R
n = 0  f(0) = 0  Div. by 7 33. (CV)max = = 2 2
µ1  µ 2 11
n = k  f(k) = k7 – k = 7I (let)
n = k + 1  f(k + 1) = (k + 1)7 – (k + 1)  3 5 
= 2R  (CV ) mono  R,(C V ) di  R
= (k + 1)7 – (k + 1) – k7 + k7 2 2

 (k  1) 7  k 7  1  k 7  k
3RT
 34. vrms = T1V1–1 = T2V 2–1
M
(St.-1) + 7I  1
(v rms )1 T1 T1  V2 
So f(k + 1) is also divisible by 7    
(v rms ) 2 T2 T2  V1 
St.-1, 2 both are true and St.-2 is a correct
 1
explanation of St.-1 (v rms )1  V2  2
 
27. Statement-1 : |Ar| = r2 – (r – 1)2 = 2r – 1 (v rms ) 2  V1 
 |A1| + |A2| +....+|A2013 |
7
1 2 1
5  1/ 5
2013
2 v V  2
 V2  5 2  V2 
=  (2r  1)  (2013)  v
 2  2=   =  
r 1  V1  V   V1 
1
2
Statement-2 : Using properties
 V2  5
|Adj A| = |A|n–1   V   2  32
 1
 |Adj A| = |A|2 = 22
 Statement–1 is true & Statement–2 is true  
35.  
but not correct explanation. 2 5
PM /5
3

31. = 10
RT 
Density  remains constant when P/T or 36.  = constant
volume remains constant.   1 2
In graph (i) Pressure is increasing at constant    1t  t
2
temperature hence volume is decreasing so   
density is increasing. Graphs (ii) and (iii)   2  1  t
volume is increasing hence, density is 2 2 
v  u  2  t r
decreasing. Note that volume would had been
constant in case the straight line in graph (iii) (r2 )2 – (r1)2 = 2r . r
had passed through origin. 2 2 – 1 2 = 2 constant

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 MAJOR TEST

LEADER & ENTHUSIAST COURSE 31–03–2013

37. A stops for purchasing. 54. E = W0 + Kmax. From the given data E is 6.78 eV
  (for  = 1824 Å) or 10.17 eV (for  = 1216 Å)
38. p initial  pfinal
 W0 = E – Kmax = 6.78 – 5.3 = 1.48 eV
 
0  0    mv B   mv C or W0 = 10.17 – 8.7 = 1.47 eV.
 
vC  v B n 1/ 3
N 1 1
  55. Here    
vC  v B  v N0  2   2 
39. Released gradually
1
mg where n = Number of half lives =
kd = mg  d  3
k
N 1 NU 1
realeased suddenly    
N0 1.26 N Pb  N U 1.26
1 2
mgx = kx N Pb
2  NPb = 0.26 NU  N  0.26
U
2mg
 x  2d 56. for 'NAND' gate C  A.B
k
i.e. 0.0  0  1 , 0.1  0  1
1
45.
1.0  0  1 , 1.1  1  0
6V 2 x 57. ie = ib + ic  ic = ie – ib
58. We can change the temperature of a body
without giving (or taking) heat to (or from) it.
x2 For example in an adiabatic compression
+1=x
2x temperature rises and in an adiabatic expansion
on solving x = 2 temperature falls althrough no heat is given or
taken from the system in the respective
6
i= = 3A changes.
11
61. According Bohr's theory
3
as x = 2 so i2 = = 1.5 A nh
2 angular momentum (mvr) =
2
51. Reflection from deuser medium causes a phae
where n = 1, 2, 3, ........
change of .
62. Ni(s) + 2Ag+  Ni+2 + 2Ag(s)
Since rays reflected from p and q undergo a
phase change so n3 > n2 > n1 [Ni 2 ] .16
Q= =
52. For reflected rays  2
[Ag ] (0.002) 2
 
2n2t cosr – = (2n – 1) .16 .16
2 2 = =
3 2
(2  10 ) 4  10 6
2n2t cos r = n
53. For transmitted rays .16  10 6 16  10 4
Q= = = 4 × 104
 4 4
2n2t cos r – = n
2
0.059
E cell = E°cell – log Q (From nernst
  n
2n2 t cos r = (2n + 1) or (2n – 1)
2 2 equation)
where value of n may change from different
values.
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 MAJOR TEST

JEE-MAIN 2013 31–03–2013

0.06 SoCl 2 C 6H6

Ecell = 1.05 – log(4 × 104) 83. CH3COOH CH3–C–Cl AlCl3
Ph–C–CH 3
2 O
O
= 1.05 – 0.03 {log4 + log104}
HCN
= 1.05 – 0.03 {0.6 + 4 log10}
= 1.05 – 0.03 {4.6} = 0.912V COOH FN
H3O 
Ph–C–CH 3 Ph–C–CH 3
1    1000 OH OH
63.  eq    
R  A N 84. HCl does not show peroxide effect even in
presence of peroxide.
1 1000
= 2  100s cm 2eq 1
200 0.1 85. CH3–CH 2–CH2–CCH BH 3/THF
CH3–CH2–CH 2–CH=CH 3B

65. According to Le Chatelier's principle by H2O2 /OH

doubling the volume of container, pressure CH3–CH2–CH 2–CH=CH

decreases, so reaction goes in backward OH
tautomerism
direction, number of moles of Cl2 increases.
CH3–CH2–CH2–CH2–C–H
66. For precipitation
O
[Ca+2] [SO–2
4
] > Ksp
67. Ax By  xAy+ + yBx– 86. Terminal alkynes [Ethyne, Propyne, 1-butyne]
 i = 1 + (n – 1) gives white ppt with ammonical silver nitrate
solution.
here, n = x + y
O NaBH4 HO
88. COOCH 3 COOCH3
3a
68. rcs  rBr  
2

nM
70. d = N  a3
A

71. Enthalpy of ionisation of NH 4 OH

= 55.90 – 51.46 = 4.44 kJmol–1

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