125. Which of the following pairs is / are correctly matched?

Reaction Product

I. RX + AgCN RNC

II. RX + KCN RCN

III. RX+KNO2 R – NO2

IV. RX+AgNO2 R–O–N=O

Select the correct answer using the codes given below.

1) I alone 2) I and II

3) III and IV 4) I, II, III and IV

126. Identify the end product (C) in the following Sequence:

KCN  alc 
C2 H5  OH 

SOCl2
Pyridine
A   B 
2H 2 O / H
C

1)
C2H5  CH2 NH2

2)
C2H5  CONH2

3)
C2H5  COOH

4) 2 5 NH2 HCOOH
CH

127. An organic halide with formula C16H13Br on heating with alcoholic caustic potash gives two isomeric alkenes A

and B with formula C6H12. On reductive ozonolysis of mixture of A and B, the following compounds were

obtained.
CHCOCH
3 3, CHCHO,
3 CHCH
3 2CHO and (CH3)2CHCHO. The organic halide is

1) 2-Bromohexane

2) 3-Bromo-2methylpentane

3) 2, 2-dimethyl-1-bromohexane

4) None of these

128. An unknown alkyl halide (A) reacts with alcoholic KOH to produce a hydrocarbon (C 4H8). Ozonolysis of

hydrocarbon gives one mole of propionaldehyde and one mole of formaldehyde. Suggest which organic structure
among the following is the correct structure of the above alkyl halide (A).

1) CH3 (CH2)3 Br

2) CH3CH(Br)CH(Br)CH-3
 3) CH3CH-2CH(Br)CH3

4) Br(CH2)4Br

129. An organic compound A (C4H9Cl) on reaction which Na and diethyl ether gives a hydrocarbon which upon

monochlorination gives only one chloroderivative. The compound (A) is

1) tert-butyl chloride 2) sec-butyl chloride

3) iso – butyl chloride 4) n-butyl chloride

130. An alkyl halide on reaction with sodium in the presence of ether gives 2, 2, 5, 5-tetramethylhexane. The alkyl

halide is

1) 1-Chloropentane

2) 1-Chloro-2, 2-dimethylpropane

3) 3-Chloro-2, 2-dimethylbutane

4) 2-Chloro-2-methylbutane

138. Which of the following is the correct order of decreasing reactivity towards nucleophilic substitution?

1) Vinyl chloride > Allyl chloride > propyl chloride

2) Propyl chloride > Vinyl chloride > Allyl chloride

3) Allyl chloride > Vinyl chloride > Propyl chlorine

4) Allyl chloride > Propyl chloride > Vinyl chloride

SN2
141. An reaction at an asymmetric carbon of a compound always gives

1) an enantiomer of a substance

2) a product with opposite optical rotation

3) a mixture of diastereomers

4) A single isomer
14. Phenol is most easily soluble in

1) both NaOH solution and Na2CO3 solution

2) sodium bicarbonate solution

3) sodium hydroxide solution

4) dilute HCl
19. An aromatic acyl chloride reacts with phenol in the presence of base such as NaOH or pyridine to form an ester. The
reaction is known as:
 1) Kolbe reaction 2) Perkin reaction 3) Sandmeyer reaction

4) Schotten-Baumann reaction
23. Phenol reacts with bromine water to give

1) 2, 4-Dibromophenol

2) 4-Bromophenol

3) 2, 4, 6-Tribromophenol 4) 2-Bromophenol
24. Which one among the following compounds will not give effervescence with sodium carbonate?

1) C6H6CO2H 2) 3) C6H5OH 4)

29. Decarboxylation of sodium salicylate with soda lime gives

1) salicylic acid 2) phenol

3) benzene 4) none of these

30. Phenol on treatment with conc. HNO3 gives

1) Picric acid 2) Styphinic acid

3) Both of these 4) None of these

34. Phenol is more acidic than alcohol because

1) phenoxide ion is stablised by resoannce

2) phenols are more soluble in polar solvents

3) phenoxide ion does not exhibit resonance

4) alcohols do not lose H atoms at all

41. Which is an incorrect statement?

1) Phenol turns blue litmus red.

2) Phenol gives white ppt. with bromine water

3) Phenol gives effervescence with NaHCO3 solution

4) Phenol gives characteristic colour with FeCl3 solution

– – – –
36. What is the decreasing order of strength of the bases OH , NH2 , H-CC and CH3-CH2 (IIT 1993)

1) CH3 - CH2 > NH2 > H - C  C > OH

– – – –

2) H - C  C > CH3 - CH2 > NH2 > OH

– – – –

3) OH > NH2 > H - C  C > CH3 - CH2

– – – –

4) NH2 > H - C  C > OH > CH3- CH2

– – – –
 + _
57. Glycine exists as the zwitter ion , NH3 CH2COO . Its conjugate base is
 
1) NH2CH2 COOH 2) NH2CH2 COO
–
3)
NH3CH2COOH 4) NH3CH2COOH

85. At some high temperature the value of Kw is equal to 10–12M2. Then the H+ ion concentration of water at
that temperature is
1) 10–7 M 2) 10–6 M 3) 10–8 M 4) 10–12 M
100. When 100 ml of N/10 NaOH are added to 50 ml of N/5 HCl, thepH of the resulting solution is
(Pb. CET 1985)
1) 7 2) greater than 7 3) less than 7 4) Zero
101. What is the pH
of a solution obtained by dissolving 0.0005 mole of the strong electrolyte, calcium
hydroxide, Ca(OH)2 to form 100 ml of a saturated solution (aqueous) ?(Kw = 1.010–14 mole2litre–2)
(AFMC 1999)
1) 9.8 2) 11.7 3) 12.0 4) 3.0
102. Equal volumes of two solutions with PH=3 and PH = 11 are mixed. Then the PH of resulting solution is

1) 8 2) 7 3)6 4) 0
122. The first and second dissociation constants of an acid H2A are 1.010–5 and 5.010–10 respectively. The
overall dissociation constant of the acid will be (AIEEE 2007)
1) 5  1015 2) 5.0  10–15 3) 0.2  105 4) 5.0  10–5
125. 100 ml of 0.015 M HCl solution is mixed with 100 ml of 0.005 M HCl. What is the pH of the resultant
solution ?
(EAMCET 2004M)
1) 2.5 2) 1.5 3) 2.0 4) 1.0
-4
140. The dissociation constant of a weak base is 10 . The concentration ratio of salt to base to be maintained to
keep the PH of buffer solution as 9 is
1) 10 : 1 2) 1 : 10 3) 1 : 2 4) 2 : 1
146. The pKa of a weak acid, HA is 4.8. The pKb of a weak base, BOH is 4.78. The PH is an aqueous solution
of the corresponding salt, BA, will be [AIEEE - 2008] 1)
4.79 2) 7.01 3) 9.22 4) 9.58
152. The solubility of CaF2 is 2 10–4 mole/litre. Its solubility product is
(NCERT 1981; CBSE PMT 1999; Kerala 2003)
1) 2.010–4 2) 4.010–8 3) 48.010–12 4) 3.210–4
158. The Ksp of a salt, having the general formula MX2, in water is 410–12. The concentration of M2+ ions in the
aqueous solution of the salt is (AIEEE 2005)
1) 210–6 M 2) 110–4 M 3) 1.610–4 M 4) 410–10 M
160. What is the minimum concentration of SO42- required to precipitate BaSO4 in a solution containing 1.0 10-
4 mol of Ba2+ ? ( K -10
sp of BaSO4 = 4 10 ) (MP PMT 2000)
1) 210-5 M 2) 410-10 M 3) 410-6 4) 210-3 M
162. A solution wich is 10-3 M each in Mn2+, Fe2+, Zn2+ and Hg2+ is treated with 10–16M sulphide ion. If Ksp of
MnS. FeS, ZnS and HgS are 10–15,10–23,10-20 and 10–54 respectively. Which of the following will be
precipitated first ?
1) FeS 2) MnS 3) HgS 4) ZnS
2. One mole of A(g) is heated to 200 C in a 1 litre closed flask, till the following equilibrium is reached. .
0

A g   B g 
The rate of forward reaction at equilibrium is 0.02 mole.lit-1.min-1. What is the rate (in
mole.lit-1.min-1) of the backward reaction at equilibrium ? (Eamcet 2002)
1) 0.04 2) 0.01 3) 0.02 4) 1
47. The process 2SO2+O22SO3 is started with 2 mole SO2 & 1 mole O2 in 1 lit flask. If the eq. mixture requires
0.4 mole KMnO4/H+, KC = ? (given 2 mol 5 mol SO2)

1) 4 2) 2 3) 8 4) 27/8
61. PCl5 dissociates as follows in a closed reaction vessel . If total pressure at equilibrium of the reaction
mixture is P and degree of dissociation of PCl5 is x, the partial pressure of PCl3 is
(AIEEE 2006)

 x P  x P  x P  2x  P
       
1)  x  1 2) 1  x  3)  x  1 4) 1  x 
14. Which among the following compounds is most acidic in character ;
OH
CH 3  C  OH 3

a) HOH b)
CH3  OH c)
CH3  CH2  OH d)
CH3

19. An unknown compound (A) having

MFC6 H12O6 on acetylation gives acetylated product whose MW is
390. The number of hydroxyl groups in (A) is
a) Four b) Five c) Six d) Three

39. Dehydration of alcohol into alkene by conc. involves which among the following reaction intermediate ?
a) Free radical b) Carbocation c) Carbanion d) Carbene
43. The reaction of Lucas reagent is fastest with :
a) Tertbutyl alcohol b) Isopropyl alcohol c) n-Butyl alcohol d) Ethyl alcohol
OH
COOH
CH COCI

3  A;
64. NaOH ‘A’ is
OCOCH3 OCOCH3 OH OH
COCH3 COOH COOCOCH3 COOCH3

a) b) c) d)
66. Which of the following will react with 5% solution of NaHCO3 ?

OH OH OH
O2 N NO2 NO2
OH

a) NO2 b) NO2 c) NO2 d)

15. Consider the following reaction

o
CH3  CH 2  O  H  CH3  C  OH 
 o
(a) (b) CH3  CH 2  O  C  CH 2  CH3  HOH
In the above reaction ester formation takes place by ;
a) Breacking of O-H bond(a)and O-H bond of (b)
b) Breacking of C-O bond of (a) and C-O bond of (b)
c) Breacking of O-H bond of (a) and C-O bond of (b)
d) Breacking of C-O bond of (a) and O-H bond of (b)