divya. 2016 @itsesb. ac-in Mid-Sem: BES-303 (Geochemistry) Date: Sept. 20, 2017 Venue: L 11 ‘Time: 3:00 pm to 5:00 pm Duration: 2 hour Maximum marks (mm): 40 All questions are compulsory. QI. What are lithophile, siderophile, chaleophile and atmophile elements? Give a minimum of two examples of each group. (mm) Q2. What is lanthanide contraction? Explain why LREE and HREE behave differently during geochemical reactions. (mms) Q3. What is a dielectric medium? How does a higher dielectric constant (~80) for water affect the solvation of salts? (mms) Q4. Standard oxidation and reduction potentials of Hz and O; are 0 V and 1.23 V, respectively. Calculate the Standard reduction potential of the following reaction 2H) +0: 2H2O (mm5) QS. Calculate the concentration of HPO, in an aqueous solution of HPO, (1M) having pH 3.5. Given are the apparent first and second dissociation constants as 7.52 10 and 7.52 10° and the subsequent dissociation constants as zero, (mm 10) Q6. Write charge balance, proton balance and carbonate conservation equations for a solution made by dissolving completely CaCO; in water under the closed system assumptions. Also write an expression for the alkalinity using conservative ions. (mms) Q7. What are phyllosilicate minerals? Illustrate the basic structures of Kaolinite and Chlorite group of clay minerals. (mm 5) I4\Vo 28fall Woo TOOT Gi. rasae Sees ee THeSe clam Neato ouside by Goldsmith wa Lithophile + “These elements ane found ner eanth owst and weadily undo goes reaction with ewygenand silicgtte to for ide and silicates - Sodfomn (Na), aleium (ca) ek. gt Lidhfom CL)» a Siderophilee these elements ana ound th metal go core of the eamth. 4oution wee mon (Fe), CBba\t (Co), Nicleel Wifetch, nile These elevnenrts cow found nean crus undenge 20action orth Folphols and they muadiley to-form sotbpr i te), lpr ovo) » Die -there elements ore volatile fn nature. ear canbon CC) ¢ Nitros Didactic mediums aio Ae medium vee 4ecs not conduct check taty by fem sald Rit polarize, Shemadh tr Pee gue, oy eae x piece Piles ee $12. pelo ihc Weahon Lhe electrostal pete between 2 4one- % > Dielectnte ep ee medium « ts eee |e re A = photos Wats. and ain axe seme gowk examples of Aeletate medium Higher dtelectat amt a wakkn, incur aeos the yoluation Balle. Due Fo the Diclectyte consta cy walk electuoatatre poi betucen Kbe Tens af walt decnoases BO times - oan makes fens avoilokle for nyaration fa awation . Herne. Ct Innoases salvation of bolts +Q4y : Eo cu O° f ae oven - Co tory= f23v Tofind +- EF, =? DHo + Op —» 2Heo- ne es ees selution*> Ho. —> 2H — pee Sa, a pa above eq” bg Diy we ols => GAs Ger oe apo © cen RoE AGty= WEES Change because it is State function by Similedy , L ; e ; ‘ Yy O24 aH*+20—» Ho0 Ecwus ty Alnos “PFE 2 2 | cen Hem —> pill2o daira egr@ & oy ee = se DH, + O2 ZH2O e+ Peaquieadl 69,” - = ° = AQ equ = Abi + G2 6 -nfe. - —n fe Pm fer - \pe = wile, + Mee, 7 } nr , ny System moe OveJo ‘Ed hut losilicate rnin Oe cl oninw aly Aotog 7 Gluet About Avove Chemical nn 6 q Al, $1, 05H), Se (pr heebicles o% ilalerlee! borcle ow comply Ka oleait ¢ Cy me Gleel teat host Clammaeel emul Al fo Qg(OH in Ea ate ng dy mw Colleel 1% cla tee Gra —orel ache clee en ae ‘om Blut Ghee a udiel. anotle Hl Al\ac one rmferual fontly = slag of — another - 4 xs 3 Ch te T:0 Le of [eke ft ° fetaok ie T - 0 Chlostle aie a an ly Gtlrraty + Awa om Oclahedes B Sanchsicby oe dite berabece dl the kay Pelibatbin. Bleak Alaina Clb ; hie Poe halk \ctlioke tT Teo eG os a ioe ee a Chee an oat tLe alow A Aphe 38 —— 2 tnt): 2 [ntje Croc) = es (ante Lol a (re Pee] “L( pz = 0O-46eM (iy for") = [ Ma I { fe Ol fees ae Le ee he ee ee Se ne oe —— 2 eS en PM = a yo pha — Avy (nT) agp ae 23 dag (4) = es ae \0 nig (09 att {d B16KIS 4 === Ss. Palate. A aia t Taye “gio 5 THe 3 3a) GMs tae