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Table 1 lists some basic information regarding elements that an environmental chemist
may encounter. Certain groupings of atoms act together as a unit in a large number of
compounds. These are referred to as radicals and are given special names. The most
common radicals are listed in table 2. The information regarding the valence and ionic
charge given in the tables can be used to write formulas of compounds by balancing
+ive and-ive charges. For example, sodium chloride will be written as NaCl, but sodium
sulphate will be Na 2SO4.
Most inorganic compounds when dissolved in water ionise into their constituent ionic
species. Na 2SO4 when dissolved in water will dissociate in two positively charged
sodium ions and one negatively charged sulphate ion. Note that the number of +ive
and-ive charges balance and the water remains electrically neutral.
Example 1
Write the molecular formula for aluminium sulphate (alum) given that the
aluminium ion is AI3+, the sulphate ion is SO42- and that each molecule has 18
molecules of water of crystallisation. Calculate its molecular weight. What is the
percentage of sulphur in the compound?
As the total number of +ive and -ive charges must be the same within a molecule,
the lowest number of AI++ and SO42- ions which can combine together is 2 and 3
respectively so that:
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Name Symbol Atomic Common Equivalent
Weight Valence Weight
Aluminium AI 27.0 3+ 9.0
Arsenic As 74.9 3+ 25.0
Barium Ba 137.3 2+ 68.7
Boron B 10.8 3+ 3.6
Bromine Br 79.9 1- 79.9
Cadmium Cd 112.4 2+ 56.2
Calcium Ca 40.1 2+ 20.0
Carbon C 12.0 4-
Chlorine CI 35.5 1- 35.5
Chromium Cr 52.0 3+ 17.3
6+
Copper Cu 63.5 2+ 31.8
Fluroine F 19.0 1- 19.0
Hydrogen H 1.0 1+ 1.0
Iodine I 126.9 1- 126.9
Iron Fe 55.8 2+ 27.8
3+
Lead Pb 207.2 2+ 100.3
Magnesium Mg 24.3 2+ 12.2
Manganese Mn 54.9 2+ 27.5
4+
7+
Mercury Hg 200.6 2+ 100.3
Nickel Ni 58.7 2+ 29.4
Nitrogen N 14.0 3-
5+
Oxygen O 16.0 2- 8.0
Phosphorus P 31.0 5+ 6.0
Potassium K 39.1 1+ 39.1
Selenium Se 79.0 6+ 13.1
Silicon Si 28.1 4+ 6.5
Sliver Ag 107.9 1+ 107.9
Sodium Na 23.0 1+ 23.0
Sulphur S 32.1 2- 16.0
Zinc Zn 65.4 2+ 32.7
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Table 2 Common radicals in water
Name Formula Molecular Weight Electrical Equivalent Weight
+
Ammonium NH4 18.0 1+ 18.0
Example 2
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A balanced chemical equation is a statement of combining ratios that exist between
reacting substances. Consider the reaction between NaOH and H2SO4.
It is seen that 2 mole (80g) of NaOH react with 1 mole (98g) of H2SO4. In terms of
equivalents, the number of equivalents of NaOH (80 {molecular weigh of 2 mole}
divided by 40 {equivalent weight}=2) is the same as that of H2SO4 (98 {molecular
weight} divided by 49 {equivalent weight}=2). Stated differently, in balanced chemical
reaction the number of equivalents of combining reactants is the same. This concept is
utillised in determination of unknown quantities in titrimetric analyses described in the
following section.
The strength of standard solutions is defined in terms of either normality (N) or molarity
(M). A 1.0/N solution contains one equivalent weight of the substance in 1L of the
solution. For a given reaction, if one is fixed the other is also known. A 0.05M H2SO4
will be 0.1 N (2 equivalents/ mole), since one mole of sulphuric acid combines with two
moles of hydroxyl ion, Equation (1).
Example 3
One of the requirements of titrimetric analyses is that it should be possible to know the
exact volume of the standard consumed by the unknown substance in the sample. This
is achieved by using an indicator in the reaction mixture. The indicator causes a visual
change in the appearance of the mixture as soon as the reaction is complete. .
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Example 4
Calculate the concentration of alkali present in a sample when 50 mL aliquot of the sample
consumed 12.4 mL of 0.1 N standard H2SO4. Express your result in meq/L, mg NaOH/L, mg
CaCO3/L.
5 Significant figures
If individuals in a group are asked to measure a line exactly 6 cm and 4 mm long using
a scale marked in cm graduations only, they may report the result as 6.3, 6.2, 6.5, 6.4,
6.6 cm, etc. To avoid ambiguity in reporting results or in presenting directions for a
procedure, it is the custom to use significant figures only. In a significant figure all digits
are expected to be known definitely, except the last digit, which may be in doubt. Thus
in the above example there are only two significant figures (the figure before the
decimal point is certain, after the decimal point the figure is based on an estimation
between to graduations of the scale). If more than a single doubtful digit is carried, the
extra digit or digits are not significant.
Round off by dropping digits that are not significant. If digits greater than 5 are dropped
increase the preceding digit by one unit; if the digit is less than 5, do not alter preceding
digit. If the digit 5 is dropped, round off the preceding digit to the nearest even number:
thus 2.25 becomes 2.2 and 2.35 becomes 2.4.
The digit 0 may at times introduce ambiguity. If an analyst calculates total residue of
1146 mg/L, but realises that 4 is somewhat doubtful and therefore 6 has no
significance, he may round off the result and report it as 1150 mg/L. Obviously he can
not drop the digit 0, although it has no significance. The recipient of the result will not
know if the digit 0 is significant or not.
Zeros bounded by other digits only on the right side only are never significant. Thus, a
mass of 21.5 mg has three significant figures. Reported in g, the value will be 0.0215,
which will again have 3 significant digits.
In most other cases, there will be no doubt as to the sense in which the digit 0 is used.
It is obvious that the zeros are significant in such numbers as 104, 5.000 and 40.08.
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For multiplication or division, round off the result of the calculation to as few significant
figures as are present in the factor with the fewest significant figures. For example, for
the calculation (56 x 0.003462 x 43.22)/1.684, the result 4.975740998, may be rounded
off to 5.0, because one of the components, 56, has only two significant figures.
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