Escolar Documentos
Profissional Documentos
Cultura Documentos
stainless steels
Lecture 15:
Duplex and Other Steels
Mmat 380
1
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
Topics to be covered
• Duplex stainless steels
• Precipitation hardened steels
• Precipitation/age hardening
mechanisms
• Mechanical properties/applications
2
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
3-9% Ni ↑toughness
& workability 5
3
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
Pseudo-Binary Diagram
Avesta 2205
4
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
Avesta 2205
Mechanical properties
5
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
12
6
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
Good properties
• Ease of fabrication
• High strength
• Relatively good ductility
• Excellent corrosion resistance
13
Strengthening mechanisms:
14
7
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
Slow cooled
Quenched
96%Al – 4%Cu alloy, 15
precipitates are still submicroscopic at time of max hardness
8
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
B
C
17
Martensitic PH steels
Example with 17-4 PH (17%Cr, 4%Ni)
• Solution treat @ 1040oC, air cool to RT
– Martensite forms above room temp.
• Age at 480oC (~4hrs)
– Martensite tempers (softens slightly)
– Precipitates form, increase strength
– Y.S. increases from 760 Mpa to 1240 Mpa
– %elongation increases from 10-12%
– Ductility and stress corrosion resistance increase with
aging
• Precipitate fine NbC
– Golf club heads
• Aging (strengthening); tempering (softening) 18
9
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
Forms ppt’s
19
20
10
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
Semi-austenitic PH steel
• 17-7 PH (approx. same composition as 301 SS but with
1-2% Al for PPT)
• Duplex structure at RT (~10% α + γ)
– Softer than martensite YS~275 MPa
– Can be formed to desired shape in this soft condition
• High T “conditioning” 750oC and sub-zero quench
converts γ to martensite
• Martensite then aged (450-510oC) to ppt Ni3Al and Ni3Mo
– YS increases from 275 MPa to 1275-1725 MPa
– (depends on alloy and heat treatment)
21
Semi-austenitic PH steel
Martensite can be formed by:
2) Cold deformation
22
11
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
12
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
ferrite
13
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
27
TH1050
RH-950 28
14
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
29
30
15
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
31
16
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
33
Hot Strength
Characteristics
for Stainless
Steels
34
17
MMAT380: L14 Austenitic, Duplex, PH 10/03/2004
stainless steels
35
18