Prediccion de presion de poro en carbonatos

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10.1190/GEO2013-0277.1

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ABSTRACT and porosity were changed, and X-ray diffraction tests were

used to measure mineral components. The small-scale fluctua-

Accurate prediction of pore pressure can assist engineers to tions of the P-wave velocity can be extracted and amplified

better work out and optimize an oilfield development plan. Be- using wavelet transformation. We found that the small-scale

cause the P-wave velocity only experiences small-scale fluctu- fluctuations of the P-wave velocity were caused by pore-

ations for pore-pressure change in carbonate rocks, existing pressure change in carbonate rocks and the large-scale fluctua-

well-known pore-pressure prediction methods are incapable of tions of the P-wave velocity depended on the rock framework.

predicting pore pressure in carbonate rocks with field-required Overpressure formation can be identified by the high-frequency

accuracy. We evaluated a new method based on the P-wave detail of wavelet transformation of P-wave velocity. A pore-

velocity decomposition and wavelet transformation to predict pressure prediction model relating the contribution from the

pore pressure in carbonate rocks. The P-wave velocity was pore fluid to the P-wave velocity was developed. This model

decomposed into contributions from the pore fluid and the rock is an improvement over existing pore-pressure prediction

framework using Biot’s theory. The effect of lithology, pore methods that mainly rely on empirical relations between the

structure, porosity, and pore pressure on P-wave velocity was P-wave velocity and the pore pressure. This new method was

studied by theoretical analysis and experiments. Rapid successfully applied to carbonate rocks in Tazhong Block,

triaxial rock-system tests were carried out to measure the P- Tarim oilfield, demonstrating the feasibility of the proposed

and S-wave velocities when pore pressure, pore structure, pore-pressure prediction method.

based on the theory of undercompaction of argillaceous sediment

Pore pressure in subsurface formations varies from hydrostatic (Smith, 1971; Goulty, 2004; Goulty et al., 2012). Identification

pressure to as high as 95% of the overburden stress. Normal pore of overpressure formation can be made through the differences

pressure is the hydrostatic pressure caused by the column of pore between the recorded and the normal trend in P-wave velocity

fluid from the surface to the depth of interest. When pore pressure and other parameters. Empirical or semiempirical prediction tech-

exceeds the normal pressure, it is termed overpressure. Poor knowl- niques such as the Eaton’s method (Eaton, 1975) have been used

edge of pore pressure often leads to high costs and unsafe condi- to predict pore pressure in clastic rocks. When these methods are

tions such as fluid influx and well blowouts from drilling operations applied to carbonate rocks, however, they can lead to significant,

(Fertl, 1976; Flemings and Lupa, 2004). For example, in the deep- and potentially dangerous, errors, such as predicting normal pres-

water of the Gulf of Mexico, incidents associated with pore pressure sure in a highly overpressured formation. This is due to the fact

and wellbore instability accounted for 5.6% of drilling time in non- that the mechanism of pore-pressure generation for carbonate

subsalt wells (York et al., 2009). It has been well recognized that rocks is different from that for clastic rocks (Atashbari and Tingay,

pore-pressure prediction is critically important for drilling planning 2012). Measured logging data show that P-wave velocity

and operations. experiences some small fluctuations when pore-pressure changes

Manuscript received by the Editor 23 July 2013; revised manuscript received 14 January 2014; published online 10 July 2014.

1

China University of Petroleum, State Key Laboratory of Petroleum Resources and Prospecting, Beijing, China. E-mail: yufu03137@126.com; jiny@

cup.edu.cn; chenmian@vip.163.com.

2

Arizona State University, School for Engineering of Matter, Transport & Energy, Tempe, Arizona, USA. E-mail: k.p.chen@asu.edu.

© 2014 Society of Exploration Geophysicists. All rights reserved.

D243

D244 Yu et al.

(Goldhammer, 1997; Zhang, 2011), and the normal trend cannot ANALYSIS OF THE P-WAVE VELOCITY

be defined. Thus, the well-established pore-pressure prediction EQUATION

methods cannot be applied to carbonate rocks (Han et al., 1986;

Li et al., 2000). In this case, precisely predicting pore pressure Acoustic wave in the formation propagates through the rock

in carbonate rocks with conventional acoustic logging data becomes framework and the pore fluid (Geertsma and Smit, 1961). Wyllie

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difficult. The central reason for the difficulty of predicting pore et al. (1958) propose the time-average equation showing the rela-

pressure in carbonate rocks is the inability to identify key param- tionship of P-wave velocity and the rock framework velocity, the

eters linking the P-wave velocity response to the pore-pressure pore fluid velocity, and porosity based on the two-phase medium

change. model. Wyllie’s equation, however, is not rigorous. Meanwhile, the

Recently, wavelet transformation has been frequently used to effect factors of the pore fluid and rock framework velocity have not

similar problems (fracture identification, fracture quantity calcula- been given; furthermore, the trend of P-wave velocity, which de-

tion, etc.) in geophysical well logging by many researchers pends on the pore fluid or rock framework, is not certain. A P-

(Sahimi and Hashemi, 2001; Tokhmechi et al., 2009). Yue and wave-velocity equation including the contributions from the pore

Tao (2006) apply wavelet transformation on resistivity logs and fluid and rock framework can be more accurately established by

extracted reservoir fluid properties. Dutta (2002) proposes that Biot’s poroelastic theory, which will provide the theoretical basis

overpressure is associated with the high-frequency component for the analysis of P-wave velocity fluctuations.

of P-wave velocity. Similarly, an original P-wave-velocity signal Based on the Biot’s poroelastic theory for fluid-saturated porous

represents the comprehensive response of all information from media, the P-wave-velocity equation takes the form of

the subsurface, which can be decomposed into a series of compo- sﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃ

nents containing different information about rock characteristics K þ 4G∕3

VP ¼ ; (1)

such as lithology, porosity, pore structure, and pore pressure (Jiao ϕρf þ ð1 − ϕÞρs

et al., 1999; Lu and Horne, 2000; Rivera et al., 2004). We show a

way to distinguish, capture, and use the components containing where V P is the P-wave velocity, K is the bulk modulus of the fluid-

pore-pressure information from P-wave velocity by such methods saturated rock or the bulk modulus of the porous rock in undrained

because wavelet transformation provides the key for pore-pressure condition, G is the shear modulus of the porous rock, ϕ is the poros-

prediction in carbonate rocks. ity, ρf and ρs are the densities of the pore fluid and the solid grains,

To use wavelet transformation to predict pore pressure, the respectively. Because there are no shear forces associated with the

effect of pore pressure on the characteristics of the fluctuations pore fluid, the shear modulus of the pore fluid is equal to zero. Thus,

of P-wave velocity needs to be studied. The factors affecting the porous rock and the rock framework have the same shear modu-

P-wave velocity can be divided into three categories (Wyllie et al., lus of

1956; Liu et al., 1991): The first is lithology, such as mineral

composition, cementation type, grain density, and porosity; the G ¼ Gfr ; (2)

second is physical factors, such as pore pressure; and the third is

where Gfr is the shear modulus of the rock framework.

the petroliferous factor (hydrocarbon), such as fluid saturation,

The bulk modulus of the saturated rock is related to the bulk

and fluid density. The P-wave velocity properties of hydrocarbon

modulus of the rock framework, the solid grains, and the pore fluid

have been studied as a function of pressure and temperature (Rao

by the Gassmann equation (Gassmann, 1951),

and Rao, 1959). In addition, the effects of pressure, temperature,

and composition on the P-wave velocity of hydrocarbon gases 2

K

and oils have been examined (Batzle and Wang, 1992). However, Kf 1 − Kfrs

K ¼ K fr þ ; (3)

for the specific case considered in this study, the changes of hydro- ϕ 1þ Kf K fr

carbon composition, density, and temperature are relatively small ϕK s 1 − ϕ − K s

for the reservoir, and these changes can be ignored. Thus, for the

pore fluid, it is reasonable to consider only the effect of pressure on where K f , K s , and K fr are the bulk modulus of the pore fluid, solid

P-wave velocity. It is noted that for carbonate rocks, P-wave veloc- grains, and rock framework, respectively.

ity is particularly affected by rock framework (porosity and pore When equation 3 is substituted into equation 1, the P-wave veloc-

structure) (Eberli et al., 2003) in addition to pore pressure (Wang, ity equation becomes

1997). vﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃ

u 2

In this paper, we first apply Biot’s theory (Biot, 1962) to express u K

u K fr þ4Gfr ∕3 K f 1− Kfrs 1

the P-wave velocity in terms of the contributions from the pore fluid VP ¼ t þ .

and the rock framework. The effects of lithology, porosity, pore ϕρf þð1−ϕÞρs ϕ 1þ K f 1−ϕ− K fr ϕρf þð1−ϕÞρs

ϕK s Ks

structure, and pore pressure on P-wave velocity fluctuations are

then analyzed for carbonate rocks based on poroelasticity and (4)

experiments. The small fluctuations of P-wave velocity due to

the pore-pressure change are obtained from P-wave velocity decom- Equation 4 can be rearranged to

position using wavelet transformation, which is then used to build a

vﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃ

2 ﬃ

new pore-pressure prediction model. This new model is applied to u K

uK þ 4 G 1 − Kfrs

u fr 3 fr K fr þ 43 Gfr ϕρf 1 Kf

predict pore pressure of carbonate rocks in Tazhong Block, Tarim VP ¼ t − þ .

ð1 − ϕÞρs ð1 − ϕÞρs ð1 − ϕÞρs þ φρf ð1 − φÞρs þ ϕρf ϕ 1 þ Kf 1 − ϕ − Kfr

ϕK s Ks

oilfield. The results demonstrate the viability of the proposed pre-

diction model. (5)

Pore pressure and wavelet transformation D245

When the porous rock is dry, ρf ¼ 0, K f ¼ 0, equation 5 gives P- and S-waves were measured after 30 min to equilibrate pressure.

the P-wave velocity in the rock framework as The test results were shown in Figures 1 and 2.

sﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃ

K fr þ 43 Gfr Experimental result and theory

V P;dry ¼ . (6)

ð1 − ϕÞρs The contribution from the rock framework to P-wave velocity

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With equation 6, the P-wave velocity in a saturated porous rock, there is no unique model relating the rock framework modulus to

equation 5, can be written as the solid grain modulus. Commonly used empirical models are

mainly Krief et al. model (Krief et al., 1990), Nur model (Nur,

vﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃ

2

u K 1992), and Pride model (Pride and Berryman, 2004). We can use

u 1− Kfrs K fr þ 43 Gfr

u 2 1 Kf ϕρf

t

V P ¼ V P;dry þ − . one of these three models and the Biot-Gassmann theory to calcu-

ð1−ϕÞρs þϕρf ϕ 1þ K f 1−ϕ− K fr ð1−ϕÞρs þϕρf ð1−ϕÞρs

ϕK s Ks late the wave velocity. Comparison with test measurement data

(7) shows that the Pride model is more accurate (Zhang et al., 2010).

The Pride model takes the following form:

In equation 7, the first term on the right side in the radical sign

denotes the contribution from the rock framework to the P-wave

K s ð1 − ϕÞ Gs ð1 − ϕÞ

velocity and the sum of the last two terms denote the contribution K fr ¼ ; Gfr ¼ ; (10)

from the pore fluid to the P-wave velocity, which can be expressed 1 þ Cϕ 1 þ 1.5Cϕ

as Δ:

where C is a constant that denotes the coefficient of consolidation.

K fr 2 The value of C varies from 2 to 20 for sand rock, but it is greater for

1 Kf 1− Ks

Δ¼ carbonate rocks.

ð1 − ϕÞρs þ ϕρf ϕ 1 þ Kf K

1 − ϕ − Kfrs The solid grain modulus can be calculated with the equivalent

ϕK s

medium theory and a commonly used equation is the VRH model

ϕρf K fr þ 43 Gfr (Voigt, 1928; Reuss, 1929; Hill, 1952), which can be expressed as

− . (8)

ð1 − ϕÞρs þ ϕρf ð1 − ϕÞρs

X

n X

n

X i −1

M s ¼ 0:5 Mi Xi þ ; (11)

i¼1 i¼1

Mi

Thus, the P-wave velocity equation can be fi-

nally written as

qﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃﬃ Table 1. X-ray diffraction analysis result of a carbonate sample.

VP ¼ V 2P;dry þ Δ: (9)

Potassium

CONTRIBUTIONS TO THE Depth (m) Quartz feldspar Anorthose Calcite Dolomite Clay mineral (%)

P-WAVE VELOCITY

4127 0.2 / / 99.3 / 0.5

Experiments 4139 0.3 / / 99 / 0.7

A set of rock samples was gathered from a 4256 0.6 / / 97.7 / 1.7

wellbore taken in a carbonate formation in Taz- 4275 0.5 / / 98.7 0.2 0.6

hong Block at approximately 4–5-km depth. The

mineral composition of the carbonate sample

was examined using X-ray diffraction, and the results are listed

in Table 1. It is concluded from Table 1 that the calcite content ac-

counts for more than 97% of the rock, and the clay mineral content

is lower than 2%. Thus, the effect of lithology change on the veloc-

ity does not need to be considered.

Two core plugs (2.5 cm in diameter and 5 cm long) were carefully

selected to give a representative spread of porosity variations (7%

and 2%) from this set of six samples. The underground conditions

can be simulated using the GCTS RTR-1500 rapid triaxial rock

system. The P- and S-wave velocities were measured for various

pore pressures (increasing from 0 to 70 MPa) at a constant confining

pressure (90 MPa) and temperature (120°C) by using an ultrasonic

pulse-echo technique. Measurements were made at a frequency of

750 kHz for P- and S-waves, starting at 0 MPa pore pressure, rising Figure 1. P-wave velocity and S-wave velocity versus pore pressure

in steps to 70 MPa. For each pressure level, two-way traveltimes of when the porosity is 2%.

D246 Yu et al.

where Mi is the modulus of each mineral (the bulk modulus or the and

shear modulus) in GPa, Xi is the percentage of each mineral.

ϕ

The contribution from the rock framework to P-wave velocity Gfr ¼ Gs 1− ; (13)

depends on the rock framework modulus, porosity, and the solid ϕc

grains’ density. The rock framework modulus is related to the

where Gs is the shear modulus of solid grains.

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If equations 12 and 13 are substituted into equation 8, we have

and Cheng, 1993). For stiff framework such as carbonate rocks,

the rock framework structure has no obvious changes even in

ϕ Kf 1 1 − ϕ∕ϕc

overpressured formations (Assefa, 1994). Thus, the rock framework Δ¼ 1−m ;

modulus is basically unchanged under the same lithology character- ð1 − ϕÞρs þ ϕρf ϕ2c 1 þ Kf 1−ϕc 1−ϕ

K s ϕc

istics and rock framework structure conditions. This indicates that (14)

the contribution from the rock framework to the P-wave velocity

remains about the same. If the lithology characteristics and rock with

framework structure have small changes, then the modulus will

have large changes and the contribution from the rock framework ρf K s þ 43 Gs 2 K f 1 − ϕc

to the P-wave velocity will have large-scale fluctuations. In other m¼ ϕc 1 þ . (15)

ρs Kf K s ϕc

words, the large-scale trend of the P-wave velocity is determined

by the contribution from the rock framework to the P-wave velocity.

Figures 1 and 2 show the measured P- and S-wave velocities for The value of function 1−ϕ∕ϕc

varies between 0 and 1. It can be

1−ϕ

the carbonate rock samples with the same lithology characteristics shown that for m > 1:

but different porosities, 2% and 7%, respectively. The sample with

low porosity shows much higher wave velocities than the sample Δ < 0; for ϕ < ϕ~ Δ > 0; for ϕ > ϕ;

~ (16)

with a higher porosity. A porosity change corresponds to a rock

framework structure change, which causes large-scale velocity where

changes.

m−1

ϕ~ ¼ . (17)

The contribution from the pore fluid to P-wave velocity m∕ϕc − 1

It has been shown that when the porosity or pore-pressure Thus, when m > 1, the contribution from the pore fluid to the P-

changes, the P- and S-wave velocities of saturated rock can be larger wave velocity Δ can be positive, negative, or zero, depending on the

or smaller than or equal to that of the dry rock frame (Fjaer et al., porosity, the densities, the bulk compressibility of the pore fluid,

2008). The hypothesis is that the fluid-saturated porous media can and the rock framework. On the other hand, when m < 1, Δ > 0

be divided into two classes by the critical porosity (Nur et al., 1995; for all ϕ∶0 ≤ ϕ ≤ ϕc .

Mavko et al., 1998). When the porosity reaches a critical value ϕc , Figures 1 and 2 show that when the rock sample has the same

the porous media becomes a suspension of solid grains in a fluid lithology characteristics and porosity, the S-wave velocity experien-

and the bulk modulus of rock framework becomes zero. On the ces only 0.5% and 0.9% variation with pore pressure, respectively,

other hand, when the porosity is zero, the material is 100% of when pore pressure is between 0 MPa and 70 MPa. It is noted that,

the solid grains and the rock framework bulk modulus is the solid for carbonate rocks, the rock framework structure (porosity, pore

grain bulk modulus. Thus, the simplest linear model of the bulk structure, etc.) does not alter much when the pore pressure is varied.

modulus and shear modulus satisfying these requirements is However, the P-wave velocity decreases slightly when the pore pres-

sure increases, which implies that the P-wave velocity has small-

ϕ scale fluctuations under formation condition when the pore pressure

K fr ¼ Ks 1 − ; (12) changes. Thus, the small-scale fluctuations in the P-wave velocity

ϕc

are related to the pore-pressure change.

Commonly, the pore fluid density and rock density are about 1.0

and 2.5 g∕cm3 , respectively, and the range of porosity is from 0% to

10%. Thus, the biggest change in Δ value is about 0.04V 2P;dry . Even

in the overpressured formation, the P-wave velocity in carbonate

rocks has only small-scale fluctuations. In other words, overpres-

sure results in only small-scale fluctuations in P-wave velocity,

which equals to the contribution from the pore fluid to the P-wave

velocity.

Therefore, based on the measurement data and theoretical analy-

sis of the velocities, it can be concluded that the contribution from

the rock framework to the P-wave velocity depends on the lithology

characteristics and rock framework structure; and the change in the

rock framework will result in large-scale fluctuations of the P-wave

Figure 2. P-wave velocity and S-wave velocity versus pore pressure velocity. The contribution from the pore fluid to the P-wave veloc-

when the porosity is 7%. ity, on the other hand, depends on the pore pressure, and the change

Pore pressure and wavelet transformation D247

in pore pressure will result in small-scale fluctuations of the P-wave ψ j;k ðtÞ ¼ aj∕2 j

0 ψða0 t − kb0 Þ; (20)

velocity.

form is defined as

WAVELET TRANSFORM ANALYSIS THEORY

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Z þ∞

A significant amount of information on the subsurface formation

characteristics including pore pressure can be obtained from the P- Wfðj; kÞ ¼ fðtÞψ j;k ðtÞdt ¼ hfðtÞ; ψ j;k ðtÞi. (21)

−∞

wave velocity. The characteristics of overpressure in carbonate

rocks can be revealed by considering the contribution from the pore

fluid to the P-wave velocity using the analysis of the previous sec-

Wavelet multiresolution analysis

tion. The wavelet transformation with multiresolution analysis has

the ability to reveal local information in the time-frequency domain, Meyer (1993) proposes a smooth function with certain attenua-

to detect transient components of signals, and to analyze and extract tion properties that is a standardized orthogonal basis formed by the

signals’ local features. Because a pore-pressure change results in scale and translation. Mallat (1989) develops a multiresolution

small-scale fluctuations in P-wave velocity as discussed above, wave- analysis and provides a fast algorithm of the wavelet transform

let transformation will be used to process P-wave velocity to extract called the Mallat algorithm. In the binary discrete wavelet trans-

and amplify the small-scale fluctuations and high-frequency detail. form, the signal is divided into a low-frequency approximation

and a high-frequency detail. Then, another low-frequency approxi-

Wavelet transformation mation is made and further division of high-frequency detail is car-

ried out. This procedure is done repeatedly until the desired

The basic concept of wavelet transformation is based on the

stretching and translation of a function (Rucka and Wilde, 2006; processing results are achieved. For example, a multiscale analysis

Lee et al., 2011). Mathematically, the wavelet transformation of chart with three layer numbers is shown in Figure 3. The S is the

a signal is the crosscorrelation of the signal with a wavelet of vary- original signal, caðjÞ, and cdðjÞ are low-frequency approximation

ing central frequency. Thus, its physical meaning is to identify simi- and high-frequency detail of the jth scale, respectively, that suggest

larities between the signal and the wavelet kernel, which represents a simple relationship in the form of

the time-shifted wavelet along the signal. For a given original signal

fðtÞ, where the variable t is time or space, the continuous wavelet S ¼ ca3 þ cd3 þ cd2 þ cd1. (22)

transform is obtained by integrating the product of the signal func-

tion and the wavelet functions (Goupillaud et al., 1984):

Z The ca3 is the low-frequency approximation that denotes the

1 þ∞ t−b

Wfða; bÞ ¼ pﬃﬃﬃﬃﬃﬃ fðtÞψ dt trend value of the P-wave velocity during wavelet transformation.

jaj −∞ a From the P-wave velocity equation developed above and the wave-

let multiresolution analysis equation 22, the contribution from the

¼ hfðtÞ; ψ a;b ðtÞi; (18)

pore fluid to the P-wave velocity can be defined as cd, and the for-

mula for computing cd is

where ψ ðtÞ is the complex conjugate of the wavelet function. The

real numbers a and b are the scale and translation parameters, re-

spectively; ψ a;b ðtÞ is a family of wavelets; and Wfða; bÞ is called cd ¼ cd3 þ cd2 þ cd1. (23)

the wavelet coefficient for wavelet ψ a;b ðtÞ, and it measures the varia-

tion of signal in the vicinity of b whose size is proportional to a.

The real or complex-valued function ψðtÞ localized in time and Based on the above analysis, the selection of an appropriate type

frequency domains is used to create a family of wavelets ψ a;b ðtÞ, of wavelet function and the decomposition layer number is essential

which is a dilated or stretched version of the mother wavelet ψðtÞ, for effective use of the wavelet transformation.

defined as (Daubechies, 1990)

1 t−b

ψ a;b ðtÞ ¼ pﬃﬃﬃﬃﬃﬃ ψ ; a ∈ Rþ ; b ∈ R. (19)

jaj a

This correlation between the signal and the wavelet is in the sense

of frequency content. With decreasing values of a, the wavelet

becomes more compressed, observes a smaller time window and

captures increasingly higher frequencies that are stored as partial

observations (Peng and Chu, 2004; Li et al., 2007).

The discrete form of the wavelet transformation is of practical

importance. The discrete formulas of scale parameter a and trans-

lation parameter b are given by a ¼ a−j −j

0 and b ¼ ka0 b0 , respec-

tively. Thus, the discrete wavelet is called the binary wavelet, which Figure 3. Three-layer-number structure chart of multiresolution

is defined as analysis.

D248 Yu et al.

PORE-PRESSURE PREDICTION METHOD Figure 4 shows that ca4 is the low-frequency approximation;

cd1, cd2, cd3, and cd4 are the high-frequency details of the four

Overpressured formation identification layer numbers with the wavelet transformation associated with

The P-wave velocity curve in actual logging data is less sensitive small-scale fluctuations. The sum of ca4 and cd (cd1 þ cd2 þ

to overpressure formation and it merely contains small-scale fluc- cd3 þ cd4) is equal to the P-wave velocity. It can be seen that

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tuations. Thus, an overpressured formation cannot be identified the trend of the low-frequency approximation (ca4) is basically

using unfiltered logging data directly. The use of a wavelet trans- consistent with the trend of the P-wave velocity and the value of

formation can help us to decompose the P-wave velocity, and to ca4 has large-scale fluctuations. Thus, based on the P-wave velocity

extract and amplify the characteristics of overpressure hidden in decomposition equation proposed in this paper and the wavelet

P-wave velocity measurements. A key to P-wave velocity decom- transformation, the low-frequency approximation (ca4) is the

position is to select the appropriate wavelet-basis function and de-

composition layer number using the wavelet transformation. The Table 2. Measured pore pressure and cd value in TZ-A.

selection principle is that the trend of the low-frequency approxi-

mation is basically consistent with the trend of the P-wave velocity.

According to the previous empirical results, symmetrical biorthog- Depth (m) cd (m∕s) Pore-pressure gradient (g∕cm3 )

onal wavelet base function and certain near-symmetrical orthogonal

wavelet base function are useful. Based on equation 21, taking into 4158 −15.25 1.22

account characteristics of carbonate rocks in the Tazhong Block, 4169 −27.23 1.24

db3 wavelet base function of Daubechies wavelet (Daubechies, 4200 211.52 1.20

1990) is selected to decompose the P-wave velocity with four layer 4207 94.93 1.23

numbers in the TZ-A well through screening.

Figure 4. P-wave velocity decomposition chart using the wavelet transformation and overpressure formation chart based on the measured data

in TZ-A well. The black zones show the overpressure formation, ca4, the low-frequency approximation of the fourth-layer number, denotes the

contribution from the rock framework to the P-wave velocity; cd1, cd2, cd3, and cd4 are the high-frequency details; and cd is the contribution

from the pore fluid to the P-wave velocity.

Pore pressure and wavelet transformation D249

to the P-wave velocity, ca4, the low-frequency ap-

proximation of the fourth-layer number, denotes the

contribution from the rock framework to the the

P-wave velocity, and the black zones show the over-

pressure formations that can be identified using the

fluctuation characteristic of the high-frequency de-

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to the P-wave velocity, ca4, the low-frequency

approximation of the fourth-layer number, denotes

the contribution from the rock framework to the

P-wave velocity, and the black zones show the over-

pressure formations that can be identified using the

fluctuation characteristic of the high-frequency de-

tail (cd4) in carbonate rocks in ZG-C.

D250 Yu et al.

contribution of the rock framework to the P-wave velocity. The last where a and t are constants; i ¼ 1; 2; : : : ; n; m ¼ 1; 2; : : : ; n; m is

column in Figure 4 denotes the measured pore-pressure value using the nearest point from the prediction point that the contribution

the select formation tester. The dramatic fluctuations in the part of value from the pore fluid to the P-wave velocity turns from positive

cd4 indicate the overpressured formation, which is based on the to negative or negative to positive; V fðmÞ ; V fðmþ1Þ are two actual

comparison of the fluctuation characteristic of the high-frequency measurements of the contribution value from the pore fluid to

Downloaded 07/24/14 to 149.169.148.211. Redistribution subject to SEG license or copyright; see Terms of Use at http://library.seg.org/

detail obtained from P-wave-velocity decomposition with the mea- the P-wave velocity; Ppðmþ1Þ ; PpðmÞ are those of pore pressure;

sured pore-pressure value. In other words, in the overpressured for- V fðiÞ is the prediction point of the contribution from the pore fluid

mation, the high-frequency detail (cd4) has dramatic fluctuations. to P-wave velocity; and PpðiÞ is the prediction point of the pore

In summary, an overpressured formation cannot be identified pressure.

directly using the original P-wave velocity for carbonated rocks. Parameters of this model can be identified using regression

The high-frequency detail extracted from the P-wave velocity de- analysis:

composition, however, is a better indicator for overpressured forma-

tion. Thus, the variation of the high-frequency detail of the P-wave a ¼ −0.0041; t ¼ 2.0665. (25)

signal can serve as a tool for overpressure formation identification.

In this study, it is found that the decomposed signal curve cd4 has

some corresponding characteristics with overpressured formation. CASE STUDIES

Pore-pressure prediction model Tarim Basin, located in southern Xinjiang in northwestern China,

is a composite superimposed basin. Tazhong Block, where carbon-

From the actual drilling data, the measured pore pressure and the ate rocks are the main reservoir with mainly limestone, dolomite

corresponding cd value in TZ-A are listed in Table 2. A model for that fractures, and pores are relatively well developed, is located

pore-pressure prediction using the finite difference is proposed in the central uplift belt in Tarim Basin. Geologists and drilling

based on the data from Table 2: engineers noted the phenomenon of overpressure of carbonate rocks

PpðiÞ ¼ Ppðmþ1Þ in the Tazhong Block. However, estimation accuracy is not satisfac-

tory using the existing prediction model. To solve this problem, the

V fðiÞ − V fðmþ1Þ t

þ aðPpðmþ1Þ − PpðmÞ Þ ; (24) proposed method in this paper has been applied in the Tazhong

V −V

fðmþ1Þ fðmÞ Block in the Tarim oilfield to verify its applicability.

Data from two wells (TZ-B and ZG-C) in

the Tazhong Block were used to demonstrate

the effectiveness of the wavelet transformation

method. The prediction results are compared

with the measured data. The following procedure

for pore-pressure prediction of carbonate rocks in

the Tazhong Block based on wavelet transforma-

tion method is used:

1) Use the db3 wavelet base function to decom-

pose the P-wave velocity with four layer

numbers. Extract the high-frequency detail

and the contribution value from the pore fluid

to the P-wave velocity.

2) The overpressured formation can be identi-

fied using the high-frequency detail (cd4) for

this block. The portion of the high-frequency

detail (cd4) with dramatic fluctuations re-

flects the overpressured formation that can

be shown using the black zone. The results

are shown in Figures 5 and 6.

3) The pore pressure can be predicted using the

proposed model by the contribution value

from the pore fluid to the P-wave velocity.

The prediction results and the measured data,

which can be from the drill stem tester were

compared, as shown in Figure 7 and Table 3.

sured and the predicted values of pore-pressure

gradient shows that the relative error is within

Figure 7. (a) Pore-pressure gradient prediction in carbonate rocks using the proposed

model in TZ-B. (b) Pore-pressure gradient prediction in carbonate rocks using the pro- 10%. This demonstrates the validity of the pro-

posed model in ZG-C. posed approach.

Pore pressure and wavelet transformation D251

Table 3. Comparing the predicted value and the measured value of the pore- REFERENCES

pressure gradient.

Assefa, S., 1994, Seismic and petrophysical properties

of carbonate reservoir rocks: Ph.D. thesis, University

Pore-pressure Pore-pressure gradient (g∕cm3 ) of Reading.

measured Atashbari, V., and M. R. Tingay, 2012, Pore pressure

prediction in a carbonate reservoir: Presented at

Downloaded 07/24/14 to 149.169.148.211. Redistribution subject to SEG license or copyright; see Terms of Use at http://library.seg.org/

Well no. Depth (m) value (Mpa) Measured value Predicted value Error SPE Oil and Gas India Conference and Exhibition,

SPE 150836.

TZ-B 4306 52.6 1.22 1.12 8.9% Batzle, M., and Z. Wang, 1992, Seismic properties of

4335 52.5 1.21 1.12 7.6% pore fluids: Geophysics, 57, 1396–1408, doi: 10

.1190/1.1443207.

4430 51.4 1.16 1.26 8.3% Biot, M. A., 1962, Generalized theory of acoustic

propagation in porous dissipative media: Journal

ZG-C 5843 67.2 1.15 1.23 6.8% of the Acoustical Society of America, 34, 1254–

6085 64.5 1.06 1.15 7.5% 1262, doi: 10.1121/1.1918315.

Daubechies, I., 1990, The wavelet transform, time-

6113 67.9 1.11 1.21 8.4% frequency localization and signal analysis: IEEE

Transactions on Information Theory, 36, 961–1005,

doi: 10.1109/18.57199.

Detournay, E., and A. H-D. Cheng, 1993, Fundamen-

tals of poroelasticity, in C. Fairhurst, ed.,Comprehensive rock engineer-

CONCLUSIONS ing: Principles, practice and projects: Vol. II, Analysis and design method:

Pergamon Press, 113–171.

1) A P-wave velocity decomposition equation including the con- Dutta, N. C., 2002, Geopressure prediction using seismic data: Current sta-

tributions from the pore fluid and rock framework is proposed tus and the road ahead: Geophysics, 67, 2012–2041, doi: 10.1190/1

.1527101.

and analyzed. For carbonate rocks, pore pressure and rock struc- Eaton, B. A., 1975, The equation for geopressure prediction from well logs:

ture (porosity, pore structure) are the main contributing factors. Presented at Fall Meeting of the Society of Petroleum Engineers of AIME,

SPE 5544.

It is found that the small-scale fluctuations of the P-wave veloc- Eberli, G. P., G. T. Baechle, F. Anselmetti, and M. Incze, 2003, Factors con-

ity are caused by pore-pressure change in carbonate rocks; and trolling elastic properties in carbonate sediments and rocks: The Leading

the large-scale fluctuations of the P-wave velocity depended on Edge, 22, 654–660, doi: 10.1190/1.1599691.

Fertl, W. H., 1976, Abnormal formation pressures: Elsevier.

the rock framework (rock structure). The condition under which Fjaer, E., R. M. Holt, A. M. Raaen, R. Risnes, and P. Horsrud, 2008, Petro-

the contribution from the pore fluid to the P-wave velocity be- leum related rock mechanics: Elsevier Science Publishers.

comes positive, negative, or zero is obtained. This condition Flemings, P. B., and J. A. Lupa, 2004, Pressure prediction in the Bullwinkle

Basin through petrophysics and flow modeling (Green Canyon 65, Gulf of

provides the theoretical basis to predict pore pressure in carbon- Mexico): Marine and Petroleum Geology, 21, 1311–1322, doi: 10.1016/j

ates using wavelet transformation. .marpetgeo.2004.09.005.

Gassmann, F., 1951, Elastic waves through a peaking of spheres: Geophys-

2) Overpressured formation can be identified by the high- ics, 16, 673–685, doi: 10.1190/1.1437718.

frequency detail of the P-wave velocity obtained from the wave- Geertsma, J., and J. C. Smit, 1961, Some aspects of elastic wave propagation

let transformation. The contribution from the pore fluid to the in fluid-saturated porous solids: Geophysics, 26, 169–181, doi: 10.1190/1

.1438855.

P-wave velocity can be used to predict pore pressure in carbon- Goldhammer, R. K., 1997, Compaction and decompaction algorithms for

ate rocks. The results illustrate that if the P-wave-velocity con- sedimentary carbonates: Journal of Sedimentary Research, 67, 26–35,

tribution from the pore fluid changes from negative to positive, doi: 10.1306/D42684E1-2B26-11D7-8648000102C1865D.

Goulty, N. R., 2004, Mechanical compaction behaviour of natural clays

then the pore pressure will be reduced, with the amount of re- and implications for pore pressure estimation: Petroleum Geoscience,

duction proportional to the positive value. On the other hand, if 10, 73–79, doi: 10.1144/1354-079302-552.

the P-wave velocity contribution from the pore fluid changes Goulty, N. R., A. M. Ramdhan, and S. J. Jones, 2012, Chemical compaction

of mudrocks in the presence of overpressure: Petroleum Geoscience, 18,

from positive to negative, the pore pressure will be increased, 471–479, doi: 10.1144/petgeo2012-018.

with the increment proportional to the magnitude of the nega- Goupillaud, P., A. Grossman, and J. Morlet, 1984, Cycle-octave and related

transforms in seismic signal analysis: Geoexploration, 23, 85–102, doi: 10

tive departure in P-wave velocity. .1016/0016-7142(84)90025-5.

3) The model discussed in this paper was applied to two wells in Han, D. H., A. Nur, and D. Morgan, 1986, Effect of porosity and clay con-

Tazhong Block of Tarim oilfield. These case studies show that tent on wave velocities in sandstone: Geophysics, 51, 2093–2107, doi: 10

.1190/1.1442062.

pore pressure in carbonate rocks can be accurately predicted Hill, R., 1952, The elastic behavior of a crystalline aggregate: Proceedings of

using this new model with the necessary calibrations. the Physical Society, London, 65, 349–354, doi: 10.1088/0370-1298/65/

5/307.

Jiao, C. H., H. Q. Li, B. Li, and H. Zhang, 1999, Application of wavelet

The trend of the contribution of the rock framework to the P-wave transform to enhancing the vertical resolution of acoustic log: Well Log-

velocity depends on the change of the rock framework character- ging Technology, 23, 15–18.

istics. It is worthy of noting that if the dipole sonic log is also avail- Krief, M., J. Garat, and J. Stellingwerff, 1990, A petrophysical interpretation

using the velocities of P and S waves (full waveform sonic): The Log

able, such rock framework characteristics can be obtained from the Analyst, 31, 355–369.

S-wave velocity, which is helpful for selecting the wavelet function Lee, S. W., K. H. Park, and J. G. Lee, 2011, Blast-induced damage

identification of rock mass using wavelet transform analysis: Procedia

and decomposition layer number for the wavelet transformation of Engineering, 14, 3142–3146, doi: 10.1016/j.proeng.2011.07.395.

the P-wave velocity. Li, L., L. S. Qu, and X. H. Liao, 2007, Haar wavelet for machine fault

diagnosis: Mechanical Systems and Signal Processing, 21, 1773–1786,

doi: 10.1016/j.ymssp.2006.07.006.

Li, Q., L. Zhao, and Y. Chen, 2000, Abnormal pressure detection and

ACKNOWLEDGMENTS wellbore stability evaluation in carbonate formations of East Sichuan: Pre-

sented at IADC/SPE Drilling Conference, SPE-59125.

This work is funded by the National Natural Science Foundation Liu, Z., H. Zhang, and W. Zhang, 1991, Application of extended time

of China (51174217). The authors thank the editors and the anony- average equation in the prediction of porosities of clastic reservoir rocks:

Acta Petrolei Sinica, 12, 21–26, doi: 10.7623/syxb199104003.

mous reviewers for their valuable comments and suggestions.

D252 Yu et al.

Lu, P. B., and R. N. Horne, 2000, A multiresolution approach to reservoir Sahimi, M., and M. Hashemi, 2001, Wavelet identification of the spatial

parameter estimation using wavelet analysis: Presented at 2000 SPE distribution of fractures: Geophysical Research Letters, 28, 611–614,

Annual Technical Conference and Exhibition, SPE62985. doi: 10.1029/2000GL011961.

Mallat, S. G., 1989, A theory for multiresolution signal decomposition: The Smith, J. E., 1971, The dynamics of shale compaction and evaluation of

wavelet representation : IEEE Transactions on Pattern Analysis and pore-fluid pressure: Mathematical Geology, 3, 239–263, doi: 10.1007/

Machine Intelligence, 11, 674–693, doi: 10.1109/34.192463. BF02045794.

Mavko, G., T. Mukerji, and J. Dvorkin, 1998, The rock physics handbook: Tokhmechi, B., H. Memarian, V. Rasouli, H. Ahmadi, A. Noubari, and B.

Downloaded 07/24/14 to 149.169.148.211. Redistribution subject to SEG license or copyright; see Terms of Use at http://library.seg.org/

Cambridge University Press. Moshir, 2009, Fracture detection from water saturation log data using a

Meyer, Y., 1993, Wavelets: Algorithms and applications: SIAM. Fourier-wavelet approach: Journal of Petroleum Science and Engineering,

Nur, A., 1992, Critical porosity and the seismic velocities in rocks: EOS, 69, 129–138, doi: 10.1016/j.petrol.2009.08.005.

Transactions American Geophysical Union, 73, 43–66. Voigt, W., 1928, Lehrbuch der kristallphysik: Teuvner.

Nur, A., G. Mavko, J. Dvorkin, and D. Galmundi, 1995, Critical porosity: Wang, Z., 1997, Seismic properties of carbonate rocks, in I. Palaz, and K. J.

The key to relating physical properties to porosity in rocks: 65th Annual Marfurt, eds., Carbonate seismology: SEG, 29–52.

International Meeting, SEG, Expanded Abstracts, 878–881. Wyllie, M., A. Gregory, and G. Gardner, 1956, Elastic wave velocities

Peng, Z. K., and F. L. Chu, 2004, Application of wavelet transform in in heterogeneous and porous media: Geophysics, 21, 41–70, doi: 10

machine condition monitoring and fault diagnostics: A review with bib- .1190/1.1438217.

liography: Mechanical Systems and Signal Processing, 18, 199–221, doi: Wyllie, M. R. J., A. R. Gregory, and G. H. F. Gardner, 1958, An experimen-

10.1016/S0888-3270(03)00075-X. tal investigation of factors affecting elastic wave velocities in porous me-

Pride, S. R., and J. G. Berryman, 2004, Seismic attenuation due to wave- dia: Geophysics, 23, 459–493, doi: 10.1190/1.1438493.

induced flow: Journal of Geophysical Research Solid Earth, 109, B01201, York, P., D. Prithard, J. K. Dodson, T. Dodson, S. Rosenberg, D. Gala, and

doi: 10.1029/2003JB002639. B. Utama, 2009, Eliminating non-productive time associated drilling

Rao, K. S., and B. R. Rao, 1959, Study of temperature variation of ultrasonic trouble zone: Presented at 2009 Offshore Technology Conference,

velocities in some organic liquids by modified fixed-path interferometer OTC20220.

method: Journal of the Acoustical Society of America, 31, 431–439, doi: Yue, W. Z., and G. Tao, 2006, A new method for reservoir fluid identi-

10.1121/1.1907731. fication: Applied Geophysics, 3, 124–129, doi: 10.1007/s11770-006-

Reuss, A., 1929, Berechnung der Fließgrenze von Mischkristallen auf Grund 0019-y.

der Plastizitätsbedingung für Einkristalle: Zeitschrift für Angewandte Zhang, J., 2011, Pore pressure prediction from well logs: Methods, modi-

Mathematik und Mechanik, 9, 49–58, doi: 10.1002/zamm.19290090104. fications, and new approaches: Earth-Science Reviews, 108, 50–63, doi:

Rivera, N. A., S. Ray, J. L. Jensen, A. W. Chan, and W. B. Ayers, 2004, 10.1016/j.earscirev.2011.06.001.

Detection of cyclic patterns using wavelets: An example study in the Orm- Zhang, J. J., H. B. Li, H. S. Liu, and X. F. Cui, 2010, Accuracy of dry frame

skirk sandstone, Irish Sea: Mathematical Geology, 36, 529–543 , doi: 10 models in the study of rock physics: Progress in Geophysics, 25, 1697–

.1023/B:MATG.0000037735.34280.42. 1702, doi: 10.3969/j.issn.1004-2903.2010.05.024.

Rucka, M., and K. Wilde, 2006, Crack identification using wavelets on ex-

perimental static defection profiles: Engineering Structures, 28, 279–288,

doi: 10.1016/j.engstruct.2005.07.009.

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