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Gerak Gempur SPM Chemistry paper 1

1 Which of the following substances is made up of atoms?


Antara berikut, bahan yang manakah terdiri daripada atom?

A Iron
Ferum

B Oxygen gas
Gas oksigen

C Naphthalene
Naftalena

D Sodium chloride
Natrium klorida

2 The equation below shows the reaction between magnesium and hydrochloric acid,
Persamaan di bawah menunjukkan tindakbalas antara magnesium dan asid hidroklorik

Mg(s) + 2HCl(aq) MgCl2(aq) + H2(g)

Which of the following statements is true?


Antara pernyataan berikut, yang manakah benar?

[Relative atomic mass of H = 1. Mg = 24, Cl = 35.5]


[Jisim atom relatif H = 1, Mg = 24, Cl = 35.5]

A 1 g magnesium react with 2 g hydrochloric acid to produce 1 g magnesium chloride and


1 g hydrogen gas
1 g magnesium bertindak balas dengan 2 g asid hidroklorik menghasilkan 1 g
magnesium klorida dan 1 g gas hidrogen

B 24 g magnesium react with 36.5 g hydrochloric acid to produce 95 g magnesium chloride


and 2 g hydrogen gas
24 g magnesium bertindak balas dengan 36.5 g asid hidroklorik menghasilkan 95 g
magnesium klorida dan 2 g gas hidrogen

C 1 mol magnesium react with 2 mol hydrochloric acid to produce 1 mol magnesium
chloride and 1 mol hydrogen gas
1 mol magnesium bertindak balas dengan 2 mol asid hidroklorik menghasilkan 1 mol
magnesium klorida dan 1 mol gas hidrogen

D 1 magnesium atom reacts with 2 hydrochloric acid molecule to produce 1 magnesium


chloride molecule and 1 hydrogen gas molecule
1 atom magnesium bertindak balas dengan 2 molekul asid hidroklorik menghasilkan 1
molekul magnesium klorida dan 1 molekul gas hidrogen
Gerak Gempur SPM Chemistry paper 1

3 Which of the following chemists arranged the elements in order of increasing atomic mass in The
Periodic Table ?
Antara ahli kimia berikut, yang manakah menyusun unsur-unsur dalam Jadual Berkala
berdasarkan pertambahan jisim atom?

A Dmitri Mendeleev

B Johann Dobereiner

C John Newlands

D Henry Moseley

4 Element J has 11 electrons


Unsur J mempunyai 11 elektron.

Which of the following electron arrangements represent ion J?


Antara susunan elektron berikut, yang manakah mewakili ion J?

A C

B D

5 The ions that are present in copper(II) sulphate solution are


Ion-ion yang wujud dalam larutan kuprum(II) sulfat ialah

A Cu2+, SO42-

B Cu2+, SO42-, H+

C Cu2+, SO42-, OH-

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Gerak Gempur SPM Chemistry paper 1

D Cu2+, SO42-, H+, OH-

6 Which of the following is a strong acid?


Antara yang berikut, yang manakah asid kuat?

A Alkyl sulphonic acid


Asid Alkil sulfonik

B Ethanoic acid
Asid etanoik

C Palmitic acid
Asid palmitik

D Nitric acid
Asid nitrik

7 Which of the following is a salt ?


Antara berikut, yang manakah merupakan garam?
A Lead (II) oxide
Plumbum(II) oksida

B Barium hydroxide
Barium hidroksida

C Aluminium nitrate
Aluminium nitrat

D Hydrogen sulphate
Hidrogen sulfat

8 Which of the following is true about manufactured substance in industry and its uses?
Antara yang berikut,,yang manakah benar tentang bahan buatan dalam industri dengan
kegunaannya?

Manufactured substance in industry Uses


Bahan Buatan Industri Kegunaan
A Polythene Lenses
Politena Kanta
B Lead glass Mirror
Kaca Plumbum Cermin
C Photochromic glass Optical lenses
Kaca fotokromik Kanta cermin mata
D Plastic reinforced with glass Test tube
Plastik yang diperkukuhkan dengan kaca Tabung uji

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Gerak Gempur SPM Chemistry paper 1

9 Which of the following statements best explain the decrease in rate of decomposition of
hydrogen peroxide with time?
Antara pernyataan berikut,yang manakah menerangkan pengurangan kadar penguraian
hidrogen peroksida dengan masa ?

A Product of reaction decreases


Hasil tindak balas berkurang

B Temperature of hydrogen peroxide decreases


Suhu hidrogen peroksida berkurang

C Volume of hydrogen peroxide decreases


Isipadu hidrogen peroksida berkurang

D Concentration of hydrogen peroxide decreases


Kepekatan hidrogen peroksida berkurang

10 Which of the following chemicals is used to keep latex in its liquid state?
Antara bahan kimia berikut, yang manakah digunakan untuk mengekalkan lateks dalam keadaan
cecair?

A Aqueous ammonia
Ammonia akueous

B Ethanoic acid
Asid ethanoik

C Methanol
Metanol

D Water
Air

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Gerak Gempur SPM Chemistry paper 1

11 Diagram 1 shows the set up of apparatus for a chemical reaction.


Rajah 1 menunjukkan susunan radas bagi satu tindak balas kimia.

Iron strip Magnesium strip


Kepingan ferum Kepingan magnesium

Agar solution
Larutan agar-agar
DIAGRAM 1
RAJAH 1
Which of the following statements is true for the reaction?
Antara pernyataan berikut, yang manakah benar mengenai tindak balas itu?

A Iron is reduced
Ferum diturunkan

B Iron is an oxidising agent


Ferum adalah agen pengoksidaan

C Magnesium releases electron


Magnesium membebaskan elektron

D The oxidation number of magnesium decreases


Nombor pengoksidaan magnesium berkurang

12 What is the meaning of heat of reaction?


Apakah maksud haba tindak balas?

A The energy needed to break the chemical bond


Tenaga yang diperlukan untuk memecahkan ikatan kimia

B The energy needed to start a reaction


Tenaga yang diperlukan untuk memulakan tindak balas

C The energy involved when change of state of matter occurs


Tenaga yang dibebaskan apabila perubahan keadaan bahan berlaku

D The change in the energy contained in the products and in the reactants
Perubahan kandungan tenaga dalam hasil tindak balas dan bahan tindak balas

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Gerak Gempur SPM Chemistry paper 1

13 The body of an aeroplane is made up of alloy X.


Badan sebuah kapalterbang dibina dari sejenis aloi X.

What is the alloy X?


Apakah aloi X itu?

A Pewter
Piuter

B Brass
Loyang

C Bronze
Gangsa

D Duralumin
Duralumin

14 Which of the following is true about the charges of an electron, a neutron and a proton?
Antara yang berikut, yang manakah benar tentang cas-cas bagi elektron, neutron dan proton?

Electron Neutron Proton


Elektron Neutron Proton
Negative Positive Neutral
A
Negatif Positif Neutral
B Positive Neutral Negative
Positif Neutral Negatif
C Positive Negative Neutral
Positif Negatif Neutral
D Negative Neutral Positive
Negatif Neutral Positif

15 Which of the following pair of compounds and formulae is correct?


Antara berikut, yang manakah pasangan sebatian dan fomulanya betul?

Compound Formula
Sebatian Formula

A Sodium sulphate NaSO4


Natrium sulfat

B Copper(II) oxide Cu2O


Kuprum(II) oksida

C Iron(III) chloride FeCl3


Ferum(III) klorida

D Zinc nitrate Zn(NO2)3


Zink nitrat

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Gerak Gempur SPM Chemistry paper 1

16 Astatine is below iodine in Group 17 of Periodic Table.


Astatine terletak di bawah iodin dalam Kumpulan17 Jadual Berkala.

Which of the following statements is true for astatine?


Antara pernyataan berikut, yang manakah benar tentang astatine?

A Form basic oxide


Membentuk oksida alkali

B Exists as monoatom
Wujud sebagai monoatom

C Solid at room temperature


Pepejal pada suhu bilik

D More electronegativity than iodine


Lebih elektronegatif daripada iodin

17 The diagram 2 shows the electron arrangement of a molecule of water ,H2 O


Rajah 2 menunjukkan susunan elektron bagi molekul air ,H2O

H O H

DIAGRAM 2
RAJAH 2
Which of the following statements is true about the molecule?
Antara pernyataan berikut, yang manakah benar tentang molekul itu ?

A The compound has high melting point


Sebatian mempunyai takat lebur yang tinggi

B Oxygen atom ,O has four pairs of electrons to share


Atom oksigen, O mempunyai empat pasang elektron untuk di kongsi

C The bonding between molecules of water, H2 O is of Van der Waals forces


Ikatan antara molekul air, H2 O ialah daya Van der Waals

D Each oxygen atom , O receives two electrons to form an oxide ion


Setiap atom oksigen, O menerima dua elektron untuk membentuk satu ion oksida.

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Gerak Gempur SPM Chemistry paper 1

18 The diagram 3 shows the set up of the apparatus of a simple chemical cell.
The reading on the voltmeter is 0.5 V.
Rajah 3 menunjukkan satu radas bagi satu sel kimia yang ringkas.
Bacaan pada voltmeter ialah 0.5 V.
0.5V

Iron plate
Zinc plate Kepingan
Kepingan zink ferum

Iron(II) sulphate solution


Larutan ferum(II) sulfat

DIAGRAM 3
RAJAH 3

Which of the following will give the biggest increment in the reading on the voltmeter?
Antara berikut, yang manakah akan meningkatkan bacaan paling tinggi pada voltmeter?

A Increase the volume of iron(II) sulphate solution


Tambahkan isipadu ferum(II) sulfat

B Substitute the iron plate with a silver plate


Gantikan kepingan ferum dengan kepingan argentum

C Use a more dilute iron(II) sulphate solution


Gunakan larutan ferum(II) sulfat yang lebih cair

D Substitute the zink plate with an aluminium plate


Gantikan kepingan zink dengan kepingan aluminium

19 Which of the following is true about alloy and its major component?
Antara berikut yang manakah benar tentang aloi dan juzuk utamanya

Alloy Major component


Aloi Komponen utama
A Duralumin Magnesium
Duralumin Magnesium
B Steel Tin
Keluli Stanum
C Bronze Copper
Gangsa Kuprum
D Pewter Zinc
Piuter Zink

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Gerak Gempur SPM Chemistry paper 1

20 Which of the following solutions contain the same number of hydrogen ion, H+?
Antara larutan berikut, yang manakah mengandungi bilangan ion hidrogen, H+ yang sama?

[Avogadro number = 6.02 x 1023 mol-1 ]


[Nombor Avogadro = 6.02 x 1023 mol-1 ]

I 50 cm3 of 1.0 mol dm-3 of nitric acid


50 cm3 of 1.0 mol dm-3 acid nitrik

II 100 cm3 of 0.5 mol dm-3 of hydrochloric acid


100 cm3 of 0.5 mol dm-3 acid hidroklorik

III 25 cm3 of 1.0 mol dm-3 of sulphuric acid


25 cm3 of 1.0 mol dm-3 acid sulfurik

IV 200 cm3 of 0.5 mol dm-3 of ethanoic acid


200 cm3 of 0.5 mol dm-3 acid etanoik

A I and III only


I dan III sahaja

B II and IV only
II dan IV sahaja

C I, II and III only


I, II dan III sahaja

D II, III and IV only


II, III dan IV sahajay

21 Which of the following explains the meaning of effective collision?


Antara pernyataan berikut, yang manakah menjelaskan maksud perlanggaran berkesan?

A The collision that causes a reaction


Perlanggaran yang menghasilkan tindak balas

B The collision that has a low energy


Perlanggaran yang mempunyai tenaga yang rendah

C The collision which takes place before a reaction


Perlanggaran yang berlaku sebelum sesuatu tindak balas

D The collision where its energy is less than the activation energy
Perlanggaran yang tenaganya kurang daripada tenaga pengaktifan

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Gerak Gempur SPM Chemistry paper 1

22 Diagram 4 shows the set of apparatus of an experiment.


Rajah 4 menunjukkan susunan radas bagi satu eksperimen.

Zinc chloride solution Aluminium chloride solution


Larutan zink klorida Larutan Aluminium klorida

DIAGRAM 4
RAJAH 4
Which of the following can be used to differentiate these solutions?
Antara yang berikut, yang manakah boleh digunakan untuk membezakan larutan-larutan
tersebut ?

A Ammonia solution
Larutan ammonia

B Barium nitrate solution


Larutan barium nitrat

C Silver nitrate solution


Larutan argentum nitrat

D Sodium hydroxide solution


Larutan natrium hidroksida

23 Diagram 5 represents the structural formula of a carbon compound


Rajah 5 menunjukkan formula struktur satu sebatian karbon

H H O H H
| | || | |
H–C–C– C–O–C–C–H
| | | |
H H H H

DIAGRAM 5
RAJAH 5
Name of the above carbon compound is
Nama sebatian karbon di atas ialah

A Ethyl ethanoate
Etil etanoat

B Propil ethanoate
Propil etanoat

C Ethyl propanoate
Etil propanoat

D Diethyl methanoate
Dietil etanoat

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Gerak Gempur SPM Chemistry paper 1

24 Which of the following reactions shows that tin is a reducing agent?


Antara tindak balas kimia berikut, yang manakah menunjukkan stanum sebagai agen
penurunan?

I Reaction of tin with silver oxide


Tindak balas stanum dengan argentum oksida

II Reaction of tin with lead(II) nitrate solution


Tindak balas stanum dengan larutan Plumbum(II) nitrat

III Electrolysis of tin(II) nitrate solution using tin electrodes


Elektrolisis larutan stanum(II) nitrat dengan menggunakan elektrod stanum

IV Chemical cell with tin and zinc electrodes in sodium sulphate solution.
Sel Kimia yang menggunakan elektrod stanum dan zink dalam larutan natrium sulfat.

A I and II only
I dan II sahaja

B II and IV only
II dan IV sahaja

C I, II and III only


I, II dan III sahaja

D I, III and IV only


I, III dan IV sahaja

25 The following chemical equation shows the reaction of the formation of lead (II) sulphate
precipitate.
Persamaan kimia berikut menunjukkan tindak balas pembentukan mendakan plumbum (II) sulfat.

Pb2+ (ak) + SO4 2- (ak) → PbSO4 (p) ∆ H = - 42 kJ mol -1

Which of the following is true about the reaction?


Antara yang berikut, yang manakah benar tentang tindak balas itu?

Heat change Type of reaction


Perubahan haba Jenis tindak balas
A Heat is released Endothermic
Haba dibebaskan Endotermik
B Heat is absorbed Exothermic
Haba diserap Eksotermik
C Heat is released Exothermic
Haba dibebaskan Eksotermik
D Heat is absorbed Endothermic
Haba diserap Endotermik

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Gerak Gempur SPM Chemistry paper 1

26 Which of the following molecules is soap?


Antara molekul berikut, yang manakah merupakan sabun?

A CH3(CH2)14COOH

B CH3(CH2)2COONa

C CH3(CH2)14COONa

D CH3(CH2)14COOCH3

27 The diagram 6 shows the cooling curve for a sample of a pure substance X
Rajah 6 menunjukkan lengkuk penyejukan bagi satu contoh bahan X yang tulin.
Temperature/oC

Time/s

DIAGRAM 6
RAJAH 6

Which of the following statements is true about the arrangement of particles at time t?
Antara berikut, yang manakah pernyataan yang benar tentang susunan zarah-zarah pada
masa t?

A All the molecules move freely


Semua zarah bergerak bebas

B All the molecules only vibrate and rotate at their fixed position
Semua zarah hanya bergetar dan berputar pada kedudukan yang tetap

C Some of the molecules move from one point to another and the others move randomly
Sebahagian zarah bergerak dari satu tempat ke tempat yang lain dan yang lainnya
bergerak bebas

D Some of the molecules vibrate and rotate at their fixed positions and the others move
from one point to another
Sebahagian zarah bergetar dan berputar pada kedudukan yang tetap dan yang lainnya
bergerak dari satu tempat ke tempat yang lain

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Gerak Gempur SPM Chemistry paper 1

28 Diagram 7 shows the molecular formulae of two compounds, X and Y


Rajah 7 menunjukkan formula molekul bagi dua sebatian, X dan Y.

C2H6 C5H10

Compound X Compound Y
Sebatian X Sebatian Y
DIAGRAM 7
RAJAH 7

Which of the following statements are similar for compound X and Y?


Antara pernyataan berikut, yang manakah sama bagi sebatian X dan Y?

A The empirical formula


Formula empirik

B Reaction with bromine water


Bertindak balas dengan air bromine

C Hydration to produce an alcohol


Penghidratan menghasilkan suatu alkohol

D Complete combustion in oxygen to produce water and carbon dioxide gas


Pembakaran sempurna dalam oksigen menghasilkan air dan gas karbon dioksida

29 Table 1 shows the proton number of elements W,X,Y and Z.


The letters used are not the actual symbol of the elements.
Jadual 1 menunjukkan nombor proton bagi unsur-unsur W,X,Y ,dan Z.
Huruf yang digunakan bukan simbol sebenar unsur itu.

Element Proton number


Unsur Nombor proton
W 11
X 13
Y 17
Z 19

TABLE 1
JADUAL 1
Which of the following shows the ascending order of the atomic size of the elements?
Antara ynag berikut yang manakah menunjukkan susunan menaik saiz atom bagi unsur-unsur
itu?

A W,X,Y,Z
B Z,W,X,Y
C Y,X,W,Z
D Z,Y,X,W

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Gerak Gempur SPM Chemistry paper 1

30 Which of the following is true about covalent compound?


Antara berikut, yang manakah benar tentang sebatian kovalen?

A Conduct electricity in molten or aqueous state


Mengalir elektrik dalam keadaan lebur atau akueus

B Low melting point


Takat lebur rendah

C Soluble in water
Larut dalam air

D Not volatile
Tidak meruap

31 Diagram 8 shows a set up of chemical cell using a pair of zinc and copper as electrodes.
Rajah 8 menunjukkan susunan radas sel kimia menggunakan pasangan elektrod zink dan
kuprum.

Zinc
Copper Zink
kuprum

Copper(II) sulphate solution


Larutan kuprum(II) sulfat

DIAGRAM 8
RAJAH 8

The blue copper(II) sulphate solution turns pale.


Warna biru larutan kuprum(II) sulfat luntur

Which of the following explains the observation?


Antara pernyataan berikut yang manakah menerangkan pemerhatian itu?

A Zinc atom ionizes


Atom zink mengion

B Copper atom ionizes


Atom kuprum mengion

C Sulphate ion is discharged


Ion sulfat dinyahscas

D Copper(II) ion is discharged


Ion kuprum(II) dinyahcas

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Gerak Gempur SPM Chemistry paper 1

32
The pH value of 0.1 mol dm-3 hydrochloric acid,HCl is smaller than
the pH value of 0.1 mol dm-3 ethanoic acid, CH3COOH
Nilai pH bagi 0.1 mol dm-3 asid hidroklorik, HCl adalah lebih kecil berbanding
dengan nilai pH bagi 0.1 mol dm-3 asid etanoik, CH3COOH

Which of the following explains the above statement?


Antara berikut, yang manakah menerangkan pernyataan di atas?

A Hydrochloric acid is a weak acid while ethanoic acid is a strong acid


Asid hidroklorik ialah asid lemah sementara asid etanoik ialah asid kuat

B Hydrochloric acid dissociates partially while ethanoic acid dissociates completely in


water
Asid hidroklorik bercerai separa sementara asid etanoik bercerai sempurna di dalam
air

C The number of hydrogen atom in hydrochloric acid is smaller than in ethanoic acid
Bilangan atom hidrogen di dalam asid hidroklorik lebih kecil berbanding di dalam asid
etanoik

D The concentration of hydrogen ion in hydrochloric acid is higher than in ethanoic acid
Kepekatan ion hidrogen di dalam asid hidroklorik adalah lebih tinggi berbanding di
dalam asid etanoik

33 The following equation shows the preparation of salt R.


Persamaan berikut menunjukkan penyediaan garam R

Solution P + Solution Q Solid R + Solution S


Larutan P + Larutan Q Pepejal R + Larutan S

Which of the following set represents compound P,Q,R and S?


Antara set berikut, yang manakah merupakan sebatian P,Q,R dan S?
P Q R S
I Pb NaBr PbBr2 Na
II Ca(NO)3 K2SO4 CaSO4 KNO3
III AgNO3 NaCl AgCl NaNO3
IV NH4OH HCl NH4Cl H2O

A I and II only
I dan II sahaja

B I and IV only
I dan IV sahaja

C II and III only


II and III sahaja

D III and IV only


III and IV sahaja

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Gerak Gempur SPM Chemistry paper 1

34 The manufacturing of sulfuric acid involves several reactions.


Pembuatan asid sulfurik melibatkan beberapa tindak balas.

Which of the following equations represents the sulfuric acid reaction that uses a catalyst?
Antara persamaan berikut, yang manakah mewakili tindak balas asid sulfurik yang
menggunakan mangkin?

A S + O2 → SO2

B 2SO2 + O2 → 2SO3

C SO3 + H2SO4 → H2S2O7

D H2S2O7 + H2 O → 2H2SO4

35 Diagram 9 shows the graph of volume of oxygen gas against time . Curve P is obtained from an
experiment of the decomposition of 25 cm3 of 0.1 mol dm-3 hydrogen peroxide solution.
Rajah 9 menunjukkan graf isipadu gas oksigen melawan masa. Lengkung P diperolehi daripada
tindak balas penguraian 25 cm3 larutan hidrogen peroksida 0.2 mol dm-3.

Volume of O2 gas/cm3
Isipadu gas O2 /cm3

Time/s
Masa/s
DIAGRAM 9
RAJAH 9
Which of the following solutions will produce curve Q?
Antara larutan berikut, yang manakah akan menghasilkan lengkung Q?

A 25 cm3 hydrogen peroxide 0.15 mol dm-3


25 cm3 hydrogen peroxide 0.15 mol dm-3

B 20 cm3 hydrogen peroxide 0.15 mol dm-3


20 cm3 hydrogen peroxide 0.15 mol dm-3

C 15 cm3 hydrogen peroxide 0.15 mol dm-3


15 cm3 hydrogen peroxide 0.15 mol dm-3

D 10 cm3 hydrogen peroxide 0.25 mol dm-3


10 cm3 hydrogen peroxide 0.25 mol dm-3

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Gerak Gempur SPM Chemistry paper 1

36 The equation below shows the chemical equation of the combustion of ethanol in excess oxygen
Persamaan di bawah menunjukkan persamaan kimia bagi pembakaran etanol dalam oksigen
berlebihan

2C2H5OH + 7O2 4CO2 + 6H2O

What is the volume of carbon dioxide gas released when 9.20 g ethanol reacts completely?
Berapakah isi padu gas karbon dioksida terbebas apabila 9.2 g etanol bertindak balas lengkap?

[Relative atomic mass of H = 1, C = 12, O = 16, 1 mol of gas occupies 24 dm3 at room
condition]
[Jisim atom relatif H = 1, C = 12, O = 16, 1 mol of gas memenuhi 24 dm3 pada keadaan bilik]

A 4.8 cm3
B 9.6 cm3
C 96.0 cm3
D 9600 cm3

37 Diagram 10 shows the set up of the apparatus to study the redox reaction .
Rajah 10 menunjukkan susunan radas untuk mengkaji tindak balas redoks.

Carbon X
Karbon X Carbon Y
Karbon Y

Solution Y
Solution X Larutan Y
Larutan X
Porous pot
Pasu telap
DIAGRAM 10
RAJAH 10
Carbon X is a negative terminal.
Karbon X merupakan terminal negatif.

Which of the following are solution X and solution Y?


Antara berikut, yang manakah merupakan larutan X dan larutan Y?

Solution X Solution Y
Larutan X Larutan Y
A Iron(II) sulphate Bromine water
Ferum(II) sulfat Air bromin
B Iron(III) sulphate Potassium bromide
Ferum(III) sulfat Kalium bomida
C Acidified potassium dicromate(VI) Potassium chloride
Kalium dikromat(VI) berasid Kalium klorida
D Acidified potassium manganat(VII) Iron(II) sulphate
Kalium manganat(VII) berasid Ferum(II) sulfat

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Gerak Gempur SPM Chemistry paper 1

38 The reaction between 25.00 cm3 of hydrochloric acid and 25.00 cm3 of sodium hydroxide
solution releases the heat of 2100 J.
[Specific heat capacity of a solution = 4.2 J g-1 oC -1
Assume that 1 cm 3 of a solution is equal to 1 g of the solution ]
Tindak balas antara 25.00 cm3 asid hidroklorik dan 25.00 cm3 larutan natrium hidroksida
membebaskan haba sebanyak 2100 J.
[Muatan haba tentu larutan = 4.2 J g-1 oC -1
Anggap 1 cm 3 larutan sama dengan 1 g larutan ]

What is the temperature change of the mixture ?


Berapakah perubahan suhu campuran itu?

A 1 OC
B 2 OC
C 10 OC
D 20 OC

39 Which of the following is true about soap or detergent ?


Antara yang berikut, yang manakah benar tentang sabun atau detergen ?

A Soap forms scum in soft water


Sabun membentuk kekat dalam air lembut

B Detergent forms scum in hard water


Detergen membentuk kekat di dalam air liat

C The presence of magnesium ions in detergent forms scum


Kehadiran ion magnesium di dalam detergen membentuk kekat

D Scum decreases the effectiveness of the cleansing action of a soap


Kekat mengurangkan keberkesanan tindakan pencucian sabun

40 Bromine-79 has 44 neutrons.


Bromin-79 mempunyai 44 neutron

Which of the following symbols represent the bromine atom?


Antara simbol berikut, yang manakah mewakili atom bromin?

35
A Br
79
44
B Br
35

79
C Br
35
79
D Br
44

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Gerak Gempur SPM Chemistry paper 1

41 2.0 g metal oxide J contains 1.2 g of element J


2.0 g oksida logam J mengandungi 1.2 g logam J
What is the empirical formula of metal oxide J?
Apakah formula empirik bagi oksida logam J?

[Relative atomic mass of J = 24, O = 16 ]


[Jisim atom relatif: J = 24, O = 16 ]

A JO
B JO2
C J2O
D J2O2

42 In the Periodic Table, element X is in group 1 and element Y is in group 17


The letters used are not the actual symbol of the elements.
Dalam Jadual Berkala Unsur, unsur X berada dalam kumpulan I dan unsur Y berada dalam
kumpulan 17.
Huruf yang digunakan bukan simbol sebenar unsur itu.

Which of the following chemical equation is true for the reaction between element X and element
Y?
Antara persamaan kimia berikut, yang manakah benar bagi tindak balas antara unsur X dan
unsur Y?
A 2X + Y2 2 XY
B X + Y2 XY2
C 2X + Y X2Y
D X + Y XY

43 The table 2 shows the electron arrangements of elements R, S, T dan U.


Jadual 2 menunjukkan susunan elektron bagi unsur R, S, T dan U

Elements
R S T U
Unsur
Electron arrangement
2.4 2.8 2.8.7 2.8.8.2
Susunan elektron

Which of the following pair of elements can form ionic compound?


Antara pasangan unsur berikut, yang manakah boleh membentuk sebatian ion?
A R and S
R dan S

B S and U
S dan U

C T and U
T dan U

D R and T
R dan T

19
Gerak Gempur SPM Chemistry paper 1

44 The reaction between hydrochloric acid and calcium carbonate produces carbon dioxide gas. The
reaction is complete in 50 seconds and the maximum volume of gas produced is 25 cm 3.
Tindakbalas antara asid hidroklorik dengan kalsium kabonat menghasilkan gas karbon dioksida.
Tindak balas lengkap dalam masa 50 saat dan isipadu maksimum gas ialah 25 cm3.

What is the average rate of reaction?


Berapakah kadar tindak balas purata?

A 0.5 cm3 s-1


B 1.0 cm3 s-1
C 2.0 cm3 s-1
D 4.0 cm3 s-1

45 Diagram 11 shows the set-up of apparatus for the titration of sodium hydroxide solution with
sulphuric acid.
Rajah11 menunjukkan susunan radas bagi titratan larutan natrium hidroksida dengan asid
sulfurik

0.5 mol dm-3 of sulphuric acid solution


Larutan 0.5 mol dm-3 asid sulfurik

25 cm3 of 0.5 mol dm-3 sodium hydroxide +


phenolphthalein
25 cm3 0.5 mol dm-3 larutan natrium hidroksida
+ fenolftalein
DIAGRAM 11
RAJAH 11
What is the volume of 0.5 mol dm-3 of sulphuric acid solution required to completely neutralize
25 cm3 of 0.5 mol dm-3 sodium hydroxide solution?
Berapakah isi padu 0.5 mol dm-3 asid sulfurik diperlukan untuk meneutralkan lengkap 25 cm3
0.5 mol dm-3 larutan natrium hidroksida?

A 12.50 cm3

B 25.00 cm3

C 50.00 cm3

D 75.50 cm3

20
Gerak Gempur SPM Chemistry paper 1

46 The following chemical equation shows the reaction of preparation lead(II) iodide salt.
Persamaan kimia berikut menunjukkan tindak balas penyediaan garam plumbum(II) iodida.

Pb (NO3)2 (aq) + 2KI(aq) PbI2 (s) + 2KNO3(aq)


Pb (NO3)2 (ak) + 2KI(ak) PbI2 (p) + 2KNO3(ak)

What is the volume of potassium iodide 0.5 mol dm-3 solution needed to produce 4.61 g lead(II)
iodide salt?
Berapakah isipadu larutan kalium iodida 0.5 mol dm-3 yang diperlukan untuk menghasilkan
4.61g garam plumbum(II) iodida?
[Relative atomic mass of Pb= 207, I= 127]
[Jisim atom relatif P= 207, I= 127]

A 20 cm3

B 40 cm3

C 400 cm3

D 1440 cm3

47 Diagram 12 shows the stages I, II, III and IV in the Contact Process during the preparation of
sulphuric acid.
Rajah 12 menunjukkan peringkat I, II, III dan IV bagi penyediaan asid sulfurik melalui proses
Sentuh.

S I SO2 II SO3 III H 2S 2O 7 IV H2SO4

Which of the following chemicals is used at each stage?


Antara bahan kimia berikut, yang manakah digunakan pada peringkat itu?

I II III IV
A O2 O2 H 2O H2SO4
B O2 O2 H2SO4 H 2O
C O2 H 2O O2 H2SO4
D H 2O O2 H2SO4 O2

21
Gerak Gempur SPM Chemistry paper 1

48 Diagram 13 shows the set up of the apparatus for an experiment to determine the rate of reaction
between sodium thiosulphate solution and sulphuric acid solution.
Rajah 13 menunjukkan susunan radas bagi eksperimen untuk menentukan kadar tindak balas
antara natrium tiosulfat dengan asid sulfurik.

Sodium thiosulphate solution and sulphuric acid


Larutan natrium tiosulfat dan asid sulfurik

DIAGRAM 13
RAJAH 13

Which of the following combination of conditions take the longest time for the mark X to disappear
from sight?
Antara kombinasi keadaan berikut, yang manakah mengambil masa paling lama untuk tanda X
hilang daripada penglihatan?

Sulphuric acid solution Sodium thiosulphate solution


Larutan asid Sulfurik Larutan natrium tiosulfat
Temperature/ 0C
Concentration/ Concentration/
Suhu/0C
mol dm-3 mol dm-3
Volume/cm3 Volume/cm3
Kepekatan/ Kepekatan/
Isipadu/cm3 Isipadu/cm3
mol dm-3 mol dm-3

A 10 1.0 50 0.5 30

B 10 1.0 50 0.5 40

C 10 0.5 50 0.5 30

D 20 0.5 40 0.5 40

22
Gerak Gempur SPM Chemistry paper 1

49 Diagram 14 shows the structural formula of carbon compound J


Rajah 14 di bawah menunjukkan formula struktur sebatian karbon J

H H H H
| | | |
H–C–C– C = C– H
| |
H H

DIAGRAM 14
RAJAH 14

Which of the following statements are true?


Antara pernyataan berikut, yang manakah benar?
[Relative atomic mass of H = 1, C = 12 ]
[Jisim atom relatif H = 1, C = 12 ]

I Empirical formula of J is C4H8


Formula empirik J ialah C4H8

II Name of the compound J is but-1-ene


Nama sebatian J ialah but-1-ena

III Hydration of compoud J produce butan-1ol


Penghidratan sebatian J menghasilkan butan-1-ol

IV Complete combustion of compound J produce carbon dioxide gas and water


Pembakaran lengkap sebatian J menghasilkan gas karbon dioksida dan air

A I and II only
I dan II sahaja

B III and IV only


III dan IV sahaja

C I, II and III only


I, II dan III sahaja

D II, III and IV only


II, III dan IV sahaja

23
Gerak Gempur SPM Chemistry paper 1

50 Metal W is between iron and copper in the reactivity series of metal.


The letters used are not the actual symbol of the elements.
Logam W berada di antara ferum dan kuprum dalam siri kereaktifan logam.
Huruf yang digunakan bukan simbol sebenar unsur itu

Which of the following metal oxides can be reduced by metal W?


Antara oksida logam berikut, yang manakah boleh diturunkan oleh logam W?

A Zinc oxide
Zink oksida

B Silver oxide
Argentum oksida

C Magnesium oxide
Magnesium oksida

D Aluminium oxide
Aluminium oksida

END OF QUESTION PAPER


KERTAS SOALAN TAMAT

24
Gerak Gempur SPM Chemistry paper 2 2
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1. Table 1 shows proton number and nucleon number for atom W, X and Y.
Jadual 1 menunjukkan nombor proton dan nombor nukleon bagi atom W, X dan Y.

Atom Proton number / Nucleon number /


Nombor Proton Nombor Nukleon
W 11 23
X 17 35
Y 17 37
TABLE / JADUAL 1

(a) (i) What is meant by proton number?


Apakah yang dimaksudkan dengan nombor proton ?

...............................................................………………………………...............
[1 mark]
(ii) What is the number of neutron in atom W ?
Apakah bilangan neutron dalam atom W?

.........................................………………………………………................
[1 mark]
(b) Which atoms are isotopes? Explain why.
Atom – atom yang manakah adalah isotop? Jelaskan mengapa.

..................................................................................................................................

..................................................................................................................................
[2 marks]
(c) Write the electron arrangement of atom X .
Tuliskan susunan elektron bagi atom X.

................................................................................................................................
[1 mark]

(d) (i) Draw the electron arrangement of atom Y. In your diagram , show the
number of proton and the number of neutron in the nucleus.
Lukiskan susunan elektron atom Y. Dalam rajah anda, tunjukkan
bilangan proton dan bilangan neutron dalam nukleus.

[2 marks]
Gerak Gempur SPM Chemistry paper 2 3
4541/2

(ii) What is the number of valence electron of atom Y?


Apakah bilangan elektron valen bagi atom Y?

................................................................................................................
[1 mark]
(iii) Write the formula of ion Y.
Tuliskan formula ion Y.

....................................................................................................................
[1 mark]

(e) Write the symbol of atom X in the form of A


Z X.
Tuliskan simbol bagi atom X dalam bentuk A
Z X.

.................................................................................................................................
[1 mark]

2 Diagram 2 shows the symbols of atom for element U, V, W and X.


Rajah 2 menunjukkan simbol- simbol atom bagi unsur U, V, W dan X.

7 12 19 20
3 U 6 V 9 W 10 X
DIAGRAM / RAJAH 2

(a) Write the electron arrangement of atom W.


Tuliskan susunan elektron bagi atom W.

............................................................................................................................................
[1 mark]

(b) (i) Element U, V, W and X are placed in the same period in the Periodic Table.
State the period.
Unsur U, V, W dan X berada dalam kala yang sama dalam Jadual Berkala.
Nyatakan kala itu.

..................................................................................................................................
[1 mark]

(ii) Compare the atomic size of element V and X.


Bandingkan saiz atom unsur V dan X.

..................................................................................................................................
[1 mark]
Gerak Gempur SPM Chemistry paper 2 4
4541/2

(iii) Explain your answer in (b) (ii)


Terangkan jawapan anda dalam (b) (ii).

...................................................................................................................................

...................................................................................................................................
[2 marks ]

(c) Element V can react with element W to form a compound.


Unsur V boleh bertindak balas dengan unsur W membentuk satu sebatian.

(i) Write the chemical formula for the compound.


Tuliskan formula kimia bagi sebatian itu.

.................................................................................................................................
[1 mark ]

(ii) State one physical property for the compound formed.


Nyatakan satu sifat fizikal bagi sebatian yang terbentuk.

……………………………………………………………………………...............
[1 mark ]

(d) When element U react with element W, a compound is produced.


Apabila unsur U bertindak balas dengan unsur W, satu sebatian terhasil.

(i) State the type of the compound produced.


Nyatakan jenis sebatian yang terhasil.

………......................................................................................................................
[1 mark ]

(ii) Draw the electron arrangement for the compound in (d) (i).
Lukiskan susunan elektron bagi sebatian dalam (d) (i).

[2 marks]
Gerak Gempur SPM Chemistry paper 2 5
4541/2

3 Diagram 3 shows the set-up of apparatus of a voltaic cell.


Rajah 3 menunjukkan susunan radas satu sel kimia.

Zinc
Plate /
Kepingan Copper plate / Kepingan kuprum
zink
Copper (II) nitrate solution /
Larutan kuprum (II) nitrat

DIAGRAM / RAJAH 3.1

Based on Diagram 3 , answer the following questions.


Berdasarkan Rajah 3, jawab soalan- soalan berikut:

(a) What is the energy change that occurs in the voltaic cell?
Apakah perubahan tenaga yang berlaku dalam sel kimia?

..................................................................................................................................
[1 mark]
(b) Write the formula of all ions in copper (II) sulphate solution.
Tuliskan formula semua ion dalam larutan kuprum (II) sulfat.

..................................................................................................................................
[1 mark]
(c) (i) Name the negative terminal of the voltaic cell.
Namakan terminal negatif bagi sel kimia.

.....................................................................................................................
[1 mark]

(ii) Explain your answer in (b)(i).


Terangkan jawapan anda dalam (b)(i).

.....................................................................................................................
[1 mark]

(d) (i) State one observation at copper plate.


Nyatakan satu pemerhatian pada kepingan kuprum.

.....................................................................................................................
[1 mark]
Gerak Gempur SPM Chemistry paper 2 6
4541/2

(ii) Write the half equation for the reaction occur at the copper plate.
Tuliskan persamaan setengah bagi tindak balas yang berlaku pada
kepingan kuprum.

.....................................................................................................................
[1 mark]

(e) What is the colour change of the copper(II)sulphate solution? Explain your
answer.
Apakah perubahan warna larutan kuprum (II) sulfat ? Jelaskan jawapan anda.

..................................................................................................................................

..................................................................................................................................
[2 marks]

(f) Another experiment is carried out by replacing the zinc plate with P , Q and R
metals.
Table 3.2 shows the results.
Eksperimen lain dijalankan bagi menggantikan kepingan zink dengan logam P,
Q dan R.
Jadual 3.2 menunjukkan keputusannya.

Pair of metal/ Voltage/ Negative terminal/


Pasangan logam Voltan (V) Terminal negative
P/Cu 2.7 P

Q/Cu 2.0 Q

R/Cu 0.5 R

TABLE/ JADUAL 3.2

(i) Arrange P, Q, R and Cu metal in accending order of electropositivity.


Susunkan logam P, Q, R dan Cu mengikut tertib menaik keelektropositifan.

..................................................................................................................................
[1 mark]
(ii) Predict the voltage for pair of Q/R.
Ramalkan nilai voltan bagi pasangan Q/R

..................................................................................................................................
[1 mark]
Gerak Gempur SPM Chemistry paper 2 7
4541/2

4 (a) Diagram 4.1 shows the set-up of apparatus to prepare soap.


Rajah 4.1 menunjukkan susunan radas untuk menyediakan sabun.

Distilled water / Air suling


+
Sodium chloride / Natrium klorida
Palm oil /
Minyak sawit Soap/
+ Sabun
Solution/ Larutan P Cool/ Sejukkan
Mixture/
Larutan
Heat /
Panaskan
DIAGRAM / RAJAH 4.1

(i) Name the process of preparing soap.


Namakan proses penyediaan sabun.

…………………………………………………………………………….
[1 mark]
(ii) Name the solution P.
Namakan larutan P.

…………………………………………………………………………….
[1 mark]

(iii) State the purpose of adding sodium chloride to the reaction mixture in
the experiment.
Nyatakan tujuan menambahkan natrium klorida kepada campuran
tindak balas dalam eksperimen itu.

…………………………………………………………………………….
[1 mark]

(iv) Diagram 4.2 shows the structure of a soap ion.


Rajah 4.2 menunjukkan struktur satu ion sabun.

CH3 CH2 CH2 CH2 CH2 CH2 CH2 CH2

C-O-
CH 2 CH2 CH2 CH2 CH2 CH2 CH2
||
O

Part / Bahagian X Part/ Bahagian Y

DIAGRAM/RAJAH 4.2

Which part is soluble in the water and grease based on Diagram 4.2?
Bahagian manakah yang larut dalam air dan gris berdasarkan
Gerak Gempur SPM Chemistry paper 2 8
4541/2

Rajah 4.2?

Water/air: …………………………………………………………………

Grease/gris: ……………………………………………………………….
[1 mark]

(b) Glass and ceramic are widely used in our daily life.
Kaca dan seramik digunakan secara meluas dalam kehidupan harian.

(i) Name a chemical of the main component of glass and ceramic


Namakan bahan kimia yang menjadi bahan utama dalam kaca dan
seramik

…………………………………………………………………………….
[1 mark]

(ii) State a reason why glass is used as laboratory apparatus instead of metal.
Nyatakan satu alasan mengapa kaca digunakan sebagai radas makmal
bukannya logam.

……………………………………………………………………………
[1 mark]

(iii)

Test tube Beaker Combustion tube


Tabung uji Bikar Tiub Pembakaran

DIAGRAM/RAJAH 4.3

State the type of glass that used in making the apparatus in Diagram 4.3
Nyatakan jenis kaca yang digunakan untuk membuat alat radas dalam
Rajah 4.3

……………………………………………………………………………
[1 mark]

(c) Photo chromic glass is a composite material.


Kaca fotokromik adalah salah satu bahan komposit

(i) What is composite material?


Apakah bahan komposit?

…………………………………………………………………………….
[1 mark]
Gerak Gempur SPM Chemistry paper 2 9
4541/2

(ii) Name one of the component in photo chromic glass?


Namakan salah satu daripada komposisi dalam kaca fotokromik?

…………………………………………………………………………….
[1 mark]

(iii) State one of the characteristic of lenses made from photo chromic glass.
Nyatakan satu ciri lensa yang diperbuat daripada kaca fotokromik.

…………………………………………………………………………….
[1 mark]

5 Table 5 shows the formulae of three organic compounds.


Jadual 5 menunjukkan formula bagi tiga sebatian organik

Organic compound Formula


Sebatian organik Formula
Butan-1-ol
C4H10O
Butan-1-ol
Butanoic acid
C4H8O2
Asid Butanoik
But-1-ene
C 4H 8
But-1-ena

TABLE / JADUAL 5

Use the information in Table 5 to answer the following questions.


Gunakan maklumat dalam Jadual 5 untuk menjawab soalan berikut.

(a) Name the homologous series for butan-1-ol.


Namakan siri homolog bagi butan-1-ol

……………………………………………………………………………………..
[ 1 mark ]

(b) (i) Draw the structural formula of butan-1-ol


Lukiskan formula struktur bagi butan-1-ol
Gerak Gempur SPM Chemistry paper 2 10
4541/2

[ 1 mark ]
(ii) The following structural formula is isomer of butanol.
Formula struktur berikut ialah isomer bagi butanol

CH3

CH3 - C - CH3

OH

Name the isomer.


Namakan isomer itu.

…………………………………………………………………………….
[ 1 mark ]

(c ) Butan-1-ol can react with butanoic acid to form compound X and water.
Butan-1-ol boleh bertindak balas dengan asid butanoik untuk menghasilkan
sebatian X dan air.

(i) What is the name of this reaction?


Apakah nama tindak balas ini.

…………………………………………………………………………….
[ 1 mark ]
(ii) Write the chemical equation for the reaction.
Tuliskan persamaan kimia bagi tindak balas itu.

…………………………………………………………………………….
[ 1 mark ]

(iii) State one physical property of compound X.


Nyatakan satu sifat fizik bagi sebatian X.

…………………………………………………………………………….
[ 1 mark ]

(d) Dehydration of butan-1-ol using porous pot chips produce but-1-ene.


Draw the set up of apparatus used in the dehydration.
Pengdehidratan butan-1-ol menggunakan serpihan pasu berliang menghasilkan
but-1-ena. Lukiskan susunan radas yang digunakan dalam pengdehidratan itu.
Gerak Gempur SPM Chemistry paper 2 11
4541/2

[ 2 marks ]

(e) When but-1-ene is mixed with bromine water , a reaction occur.


Apabila but-1-ena dicampurkan dengan air bromin , satu tindak balas berlaku.

(i) Name the reaction .


Namakan tindak balas itu.

…………………………………………………………………………….
[ 1 mark ]
(ii) State one observation in the reaction.
Nyatakan satu pemerhatian dalam tindak balas itu.
…………………………………………………………………………….
[ 1 mark ]

6 Diagram 6 shows the set- up of apparatus to investigate the reaction between potassium
iodide solution and chlorine water through the transfer of electrons at a distance..
Rajah 6 menunjukkan susunan radas untuk menyiasat tindak balas di antara larutan kalium
iodide dan air klorin melalui pemindahan elektron pada satu jarak.

Electrode P Electrode Q

Potassium iodide Chlorine water


solution

Dilute sulphuric acid

DIAGRAM / RAJAH 6

(a) What is the function of dilute sulphuric acid?


Apakah fungsi asid sulfurik cair?

……………………………………………………………………………………………
[1 mark ]

(b) On the diagram 6, draw the direction of the flow of electrons.


Gerak Gempur SPM Chemistry paper 2 12
4541/2

Pada rajah 6, lukiskan arah pengaliran elektron – elektron.


[1 mark ]

(c) (i) What is the colour change in the solution around electrode P?
Apakah perubahan warna dalam larutan di sekitar elektrod?

..................................................................................................................................
[1 mark ]

(ii) Describe a chemical test to determine the product formed in the solution at
electrode P.
Huraikan satu ujian kimia untuk menentukan hasil yang terbentuk dalam larutan
di elektrod P.

……………………………………………………………………………..............

……………………………………………………………………………...............
[2 marks ]

(d) What is the substance that is being oxidised in the experiment? Explain why.
Apakah bahan yang dioksidakan dalam eksperimen?Terangkan mengapa.

………………………………………………………………………………………….....

………………………………………………………………………………………….....
[2 marks ]
(e) Write a half equation for the reaction that occurs at electrode Q.
Tuliskan satu persamaan setengah bagi tindak balas yang berlaku di elektrod Q.

…………………………………………………………………………………………....
[1 mark ]

(f) Suggest another reagent that can replace chlorine water.


Cadangkan reagen lain yang boleh menggantikan air klorin.

………………………………………………………………………………....................
[1 mark ]
(g) What is the change in oxidation number of chlorine in the reaction?
Apakah perubahan nombor pengoksidaan bagi klorin dalam tindak balas?

…………………………………………………………………………………………......
[1 mark ]
Gerak Gempur SPM Chemistry paper 2 13
4541/2

Section B
[20 marks]

Answer any one question.


The time suggested to answer this section is 30 minutes.

7 (a) Table 7 shows the incomplete observation for two experiments to


construct balanced chemical equation.
Jadual 7 menunjukkan pemerhatian yang tidak lengkap bagi dua eksperimen
untuk membina persamaan kimia yang seimbang.

Experiment Procedure Observation


Eksperimen Prosedur Pemerhatian
A Copper(II)carbonate is heated Green solid turns black.
and the gas produced is passed The lime water turns milky.
through lime water. Pepejal hijau menjadi hitam.
Kuprum(II)karbonat Air kapur menjadi keruh.
dipanaskan dan gas yang
terhasil dialirkan melalui air
kapur.
B Potassium iodide solution is
added to lead(II) nitrate
solution.
Larutan kalium iodida
ditambah kepada larutan
plumbum(II)nitrat.

TABLE / JADUAL 7

(i) Based on the observation, name the products in experiment A and write
the chemical equation for the reaction.
Berdasarkan pemerhatian , namakan hasil tindak balas dalam
eksperimen A dan tuliskan persamaan kimia bagi tindak balas itu.
[ 3 marks ]

(ii) State one observation in experiment B and name the product.


Write the chemical equation for the reaction.
Nyatakan satu pemerhatian dalam eksperimen B dan namakan
hasil tindak balas itu. Tuliskan persamaan kimia bagi tindak balas
itu.
[ 4 marks ]
Gerak Gempur SPM Chemistry paper 2 14
4541/2

(b) The reaction between acid , HX and ionic compound , QY2 can be represented
by chemical equation below.
Tindak balas antara asid , HX dan sebatian ion , QY2 boleh diwakili oleh
persamaan kimia di bawah.

2HX(aq) +QY2(aq)→ QX2(s) + 2HY(aq).

State three statement to describe the chemical equation above.


Suggest an acid of HX and an ionic compound of QY2.
Nyatakan tiga pernyataan untuk menghuraikan persamaan kimia di atas.
Cadangkan asid HX dan sebatian ion QY2.

[ 5 marks]

(c) The information below is regarding substance X


Maklumat di bawah berkaitan dengan bahan X

 Carbon 85.70%
Karbon

 Hydrogen 14.30%
Hidrogen

 Relative molecular mass = 56


Jisim molekul relatif

(i) Determine the empirical formula of substance X.


[Given that the relative atomic mass of C = 12 , H = 1]
Tentukan formula empirik bagi sebatian X
[Diberi jisim atom relatif C = 12 , H = 1]

(ii) Determine the molecular formula of substance X.


Tentukan formula molekul bagi bahan X.

(iii) Based on the answers in (a)(i) and (a)(ii) , compare and


contrast the empirical formula and the molecular formula.
Berdasarkan jawapan dalam (a)(i) dan (a)(ii), banding dan
bezakan formula empirik dan formula molekul.

[ 8 marks]
Gerak Gempur SPM Chemistry paper 2 15
4541/2

8 (a) State three factors affecting the rate of reaction.


Nyatakan tiga faktor yang mempengaruhi kadar suatu tindak balas.
[3 marks]

(b) An experiment is carried out to study the rate of reaction between magnesium
and hydrochloric acid. The time taken by magnesium to dissolve in acid in each
experiment is recorded in Table 8.
Satu eksperimen dijalankan untuk mengkaji kadar tindak balas antara
magnesium dan asid hidroklorik. Masa magnesium larut di dalam asid dalam
setiap eksperimen dicatat seperti dalam jadual 8

Temperature Time
Experiment Reactant
suhu masa
Eksperimen Bahan tindak balas
(0C) (s)
20 cm3 of 0.5 mol dm-3 hydrochloric acid +
2 g of magnesium strip
I 30 120
20 cm3 asid hidroklorik 0.5 mol dm-3 +
2 g pita magnesium
20 cm3 of 1.0 mol dm-3 hydrochloric acid +
2 g of magnesium strip
II 30 60
20 cm3 asid hidroklorik 1.0 mol dm-3 +
2 g pita magnesium
20 cm3 of 1.0 mol dm-3 hydrochloric acid +
2 g of magnesium powder
III 30 40
20 cm3asid hidroklorik 1.0 mol dm-3 +
2 g serbuk magnesium
20 cm3 of 1.0 mol dm-3 hydrochloric acid +
2 g of magnesium strip +
5 drops of copper(II) sulphate solution
IV 30 45
20 cm3 asid hidroklorik 1.0 mol dm-3 +
2 g pita magnesium + 5 titik larutan kuprum(II)
sulfat

TABLE/JADUAL 8

(i) Write an ionic equation for the reaction between magnesium and acid.
Tuliskan persamaan ionik yang berlaku antara magnesium dan asid.
[1 mark]
Gerak Gempur SPM Chemistry paper 2 16
4541/2

(ii) Compare the rate of reaction for


 experiment I and experiment II,
 experiment II and experiment III.
 experiment II and experiment IV

Explain your answer based on the collision theory.

Bandingkan kadar tindak balas antara


 eksperimen I dan eksperimen II
 eksperimen II dan eksperimen III
 eksperimen II dan eksperimen IV

Terangkan jawapan andaberdasarkan teori perlanggaran


[9 marks]

(iii) If experiment II is repeated at 40 0C, predict the time taken for the 2 g
magnesium to dissolve completely. Explain your answer.
Jika eksperimen II diulangi pada suhu 40 0C, cadangkan masa yang
diambil untuk 2 g magnesium larut sepenuhnya. Jelaskan jawapan anda.
[3 marks]

(c) Based on the collision theory, explain why we need to store fresh milk in a
refrigerator.
Berdasarkan Teori Perlanggaran, terangkan mengapa kita perlu menyimpan
susu segar dalam peti sejuk.
[4 marks]
Gerak Gempur SPM Chemistry paper 2 17
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Section C
[20 marks]

Answer any one question.


The time suggested to answer this section is 30 minutes

9 (a) Diagram 9 shows the reactions involved in the preparation of soluble salts.

 Sodium salts /
Garam natrium
 Potassium salts / Asid + alkali  salt + water
Garam kalium Asid + alkali  garam + air
 Ammonium salt /
Garam ammonium

Soluble salts /
Garam larut Reaction / Tindak balas X

Other salts / Reaction / Tindak balas Y


Garam lain

Reaction / Tindak balas Z

DIAGRAM/ RAJAH 9

(i) Sodium, potassium and ammonium salts can be prepared using reaction
between acid and alkali. State the reaction X, Y and Z.
Garam natrium, kalium dan ammonium dapat disediakan melalui tindak
balas antara asid dan alkali. Nyatakan tindak balas X, Y dan Z.
[3 marks]

(ii) By choosing one of the reactions in (a) (i), suggest example of reactants
used and products formed.
Write the chemical equation for the reaction based on your suggestion.
Dengan memilih satu daripada tindak balas dalam (a) (i), cadangkan
contoh bahan- bahan tindak balas yang digunakan dan hasil-hasil
tindak balas yang terbentuk.
Tuliskan persamaan kimia bagi tindak balas berdasarkan cadangan
anda itu.
[3 marks]
Gerak Gempur SPM Chemistry paper 2 18
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(b)
Magnesium sulphate is a soluble salt.
Magnesium sulfat adalah garam terlarutkan.

Answer the following questions based on the above statement.


Jawab soalan- soalan berikut berdasarkan pernyataan di atas.

(i) Describe a laboratory experiment to prepare a dry magnesium sulphate.


In your description, include the chemical equation involved.
Huraikan satu eksperimen makmal untuk menyediakan garam
magnesium sulfat yang kering. Dalam huraian anda sertakan persamaan
kimia bagi tindak balas yang terlibat.
[10 marks]
(ii) Describe a simple chemical test of how you could differentiate between
magnesium sulphate and magnesium nitrate.
Huraikan satu ujian kimia ringkas bagaimana anda membezakan antara
larutan magnesium sulfat dan magnesium nitrat.
[4 marks]

10 Table 10 shows the molecular formula and heat of combustion of three types of alcohol.
Jadual 10 menunjukkan formula molekul dan haba pembakaran bagi tiga jenis alkohol.

Haba pembakaran /
Alcohol/ Molecular formula /
Heat of combustion
Alkohol Formula molekul
(kJ mol -1)
Methanol CH3OH 725

Ethanol C2H5OH 1 376

Propan-1-ol C3H7OH 2 015

TABLE / JADUAL 10

(a) (i) What is the meaning of the ‘heat of combustion of an alcohol’?


Apakah yang dimaksudkan dengan ‘haba pembakaran alkohol’?
[ 1 mark]

(ii) Explain why there are differences in the value of heat of combustion of
the alcohols in Table 10.
Terangkan mengapa terdapat perbezaan nilai haba pembakaran bagi
alkohol-alkohol dalam Jadual 10.
[ 3 marks]
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(b) Describe an experiment that you can carry out in your school laboratory to
determine the heat of combustion of one of the alcohol in Table 10. Your
description should include precautionary steps and the steps involved in the
calculation.
Huraikan satu eksperimen yang anda boleh jalankan di makmal sekolah anda
bagi menentukan haba pembakaran salah satu alkohol dalam Jadual 10.
Huraian anda perlu mengandungi langkah berjaga-jaga dan langkah-langkah
perhitungan yang terlibat.
[12 marks]

(c) In another experiment to determine the heat of precipitation of lead (II) sulphate,
50.0 cm3 of 2.0 mol dm-3 lead(II) nitrate solution is reacted with 50.0 cm3 of 2.0
mol dm-3 sodium sulphate solution. Increment of the temperature in the mixture
is 10 oC.
Dalam satu eksperimen lain bagi menentukan haba pemendakan plumbum(II)
sulfat, sejumlah 50 cm3 larutan plumbum(II) nitrat 2.0 mol dm-3 dicampur
dengan 50 cm3 larutan natrium sulfat 2.0 mol dm-3. Kenaikan suhu campuran
ialah 10 oC.

The equation for the reaction is :


Persamaan bagi tindak balas tersebut adalah :

Pb(NO3)2 + Na2SO4  PbSO4 + 2NaNO3

Calculate the value of the heat of precipitation of lead(II) sulphate in this


reaction.
Hitungkan haba pemendakan plumbum(II) sulfat dalam eksperimen ini.

[Use the information that the specific heat capacity of water is 4.2 J g -1 oC-1 ]
[Gunakan maklumat muatan haba tentu larutan adalah 4.2 J g -1 oC-1 ]
[4 marks]

END OF QUESTION PAPER


Gerak Gempur SPM Chemistry paper 3 3
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Answer all questions For


The time suggested to complete Question 1 and Question 2 is 45 minutes Examiner’s
Use
1 A student carried out two experiments to determine the concentration of HX acid solution.
Seorang pelajar menjalankan dua eksperimen untuk menentukan kepekatan larutan asid HX.

Experiment I
Eksperimen I

Titration of HX acid solution of unknown concentration with 20cm3 of sodium hydroxide


solution 1.0 mol dm-3 using phenolftalein as indicator.
Pentitratan larutan asid HX yang tidak diketahui kepekatannya dengan 20cm3 larutan
natrium hidroksida 1.0 mol dm-3 menggunakan penunjuk fenolftalein.

Experiment II
Eksperimen II

Titration of similar HX acid solution of difference concentration with 20cm3 of sodium


hydroxide solution 1.0 mol dm-3 using phenolftalein as indicator.
Pentitratan larutan asid HX lain yang tidak diketahui kepekatannya dengan 20cm3 larutan
Natrium Hidroksida 1.0 mol dm-3 menggunakan penunjuk fenolftalein.

Diagram 1 shows the initial and final burette readings for both experiments.
Rajah 1 menunjukkan bacaan awal dan bacaan akhir buret bagi kedua-dua eksperimen.

Experiment 1
Eksperimen 1

0 20

1 21

Initial burette reading Final burette reading


Bacaan awal buret Bacaan akhir buret

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Gerak Gempur SPM Chemistry paper 3 4
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Experiment II For
Eksperimen II Examiner’s
Use

15 25

16 26

Initial burette reading Final burette reading


Bacaan awal buret Bacaan akhir buret

Diagram 1
Rajah 1

(a) Construct a table to record the initial and final burette readings and the volumes of the acid
used for both experiments.
Bina jadual dan catat bacaan awal dan bacaan akhir buret serta isipadu asid yang digunakan
bagi kedua-dua eksperimen di atas.

1(a)

[ 3 marks]

(b) State the colour change of phenolftalein in the titration.


1(b)
Nyatakan perubahan warna fenolftalein dalam titratan tersebut.

…………………………………………………………………………………..
[ 3 marks]

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Gerak Gempur SPM Chemistry paper 3 5
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(c) The chemical equation for the reaction in the experiment is : For
Persamaan kimia bagi tindak balas dalam eksperimen ini ialah : Examiner’s
Use

HX + NaOH NaX + H2O

Calculate the concentration of HX acid solutions used in both experiments.


Hitung kepekatan larutan asid HX yang digunakan dalam kedua-dua eksperimen.

Experiment I
Eksperimen I

Experiment II
Eksperimen II

1(c)

[ 3 marks]

(d) State the hypothesis in this experiment.


Nyatakan hipotesis bagi eksperimen ini. 1(d)
………………………………..…………………………………………………………………

……….. …………………………………………………………………………………………
[ 3 marks]

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Gerak Gempur SPM Chemistry paper 3 6
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(e) If HX acid is replaced with sulphuric acid of the same concentration, it is found that the volume
of the sulphuric acid used in the titration is half of the volume of HX acid. Explain why. For
Jika asid HX digantikan dengan asid sulfurik yang mempunyai kepekatan yang sama, didapati Examiner’s
isipadu asid sulfurik yang digunakan dalam titratan ialah separuh daripada isipadu asid HX. Use
Terangkan mengapa.

………………………………………………………………………………………… 1(e)

…………………………………………………………………………………………

…………………………………………………………………………………………

[ 3 marks] Total

2 Diagram 2 shows the apparatus set-up for an experiment to compare the heat of combustion of
methanol and ethanol. 200 cm3 of water is used in this experiment.
Rajah di bawah menunjukkan susunan radas bagi eksperiment untuk membandingkan
Haba pembakaran antara metano dengan etanol. 200 cm3 air digunakan dalam ekperimen ini.

Thermometer
Thermometer

Wind shield
Penghadang

Copper container
Bekas kuprum
Water
Air
Tripod stand
Tungku kaki tiga
Spirit lamp
Alcohol Pelita
Alkohol
Wooden block
Blok kayu

Diagram 2
Rajah 2

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Gerak Gempur SPM Chemistry paper 3 7
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The table below shows the results obtained from the experiment I the heat of combustion of
methanol and experiment II the heat of combustion of ethanol. For
Jadual di bawah menunjukkan keputusan eksperimen I haba pembakaran methanol Examiner’s
dan eksperimen II haba pembakaran etanol. Use

Experiment I Experiment II
Eksperimen I Eksperimen II

25 25

20 20

15 15

Initial temperature of water: …….................. Initial temperature of water: .........................


Suhu awal air Suhu awal air

65 65

60 60

55 55

Highest temperature of water: ........................... Highest temperature of water: ..........................


Suhu tertinggi air Suhu tertinggi air

150.50 151.35

Initial mass of spirit lamp and methanol: .............g Initial mass of spirit lamp and ethanol: …....... g
Jisim awal pelita dan metanol Jisim awal pelita dan metanol

149.37 150.50

Final mass of spirit lamp and methanol: ……......g Final mass of spirit lamp and ethanol: ............. g
Jisim akhir pelita dan metanol Jisim akhir pelita dan etanol

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Gerak Gempur SPM Chemistry paper 3 8
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For
(a) Write the readings of the temperature and the mass of spirit lamp and alcohol in the spaces above. Examiner’s
Tuliskan bacaan suhu dan jisim pelita dan alkohol dalam ruangan di atas. Use
[3 marks] 2(a)

(b) Based on the information above, complete the table below.


Berdasarkan kepada maklumat di atas lengkapkan jadual di bawah.

Name of variables Action to be taken


Nama pemboleh ubah Tindakan yang dibuat
(i) Manipulated variable: (i) The way to manipulate variable:
Pemboleh ubah dimanipulaskan: Cara mengubah pemboleh ubah
dimanipulasi:
………………..........……………………..
……………..................…………………………..
………………….........…………………..
………….................……………………………...

(ii) Responding variable: (ii) What to observe in the responding variable:


Pemboleh ubah bergerak balas: Apa yang diperhatikan bagi menentukan
pemboleh ubah gerak balas:
……………………………………………
…………………..................……………………..
……………………………………………
…………………..................……………………..

(iii) Fixed variable: (iii) The way to maintain the controlled variable:
Pemboleh ubah yang dimalarkan: Cara menetapkan pemboleh ubah dimalarkan :

……………………………….………….. ……………………………………………………
2(b)
……………………………………….….. ……………………………………………………

[3 marks]

(c) (i) Calculate the energy change in the experiment I and II.
Hitungkan perubahan tenaga dalam eksperimen I dan II
[Given: Energy change = mc, specific heat capacity of water, c = 4.2 Jg-1oC]
[Diberi: perubahan tenaga = mc, muatan haba tentu air, c = 4.2 Jg-1oC]

2(c)(ii)

[3 marks]

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Gerak Gempur SPM Chemistry paper 3 9
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(ii) Calculate the number of moles of methanol and ethanol burnt in this experiment.
Hitungkan bilangan mol methanol dan etanol yang terbakar dalam eksperimen ini. For
[Molar mass of methanol = 32 g mol-1] [Molar mass of ethanol = 46 g mol-1] Examiner’s
[Jisim molar metanol = 32 g mol-1] [Jisim molar etanol = 46 g mol-1] Use

2(c)(ii)

[3 marks]

(iii) Calculate the heat of combustion of methanol in this experiment.


Hitungkan haba pembakaran metanol dalam eksperimen ini.

2(c)(iii)

[3 marks]

(d) Predict the heat of combustion of ethanol compare to the heat combustion of methanol.
Ramalkan haba pembakaran etanol berbanding dengan haba pembakaran methanol.
2(d)
………………………………………………………………………………………………………

………………………………………………………………………………………………………

[3 marks]
Total

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Gerak Gempur SPM Chemistry paper 3 10
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The further the distance between two metals in the electrochemical series,
the bigger the potential difference.
Semakin jauh kedudukan pasangan logam dalam siri elektrokimia,
semakin besar nilai voltan.

You are given the copper strip, lead strip, iron strip, zinc strip, aluminium strip, magnesium strip
and copper(II) sulphate solution.Referring to the statement above, plan a laboratory experiment to
construct the electrochemical series of the potential differences using different pair of metals.
Your explanation should include all the followings:
Anda dibekalkan dengan kepingan kuprum, kepingan plumbum, kepingan ferum, kepingan zink,
kepingan aluminium, kepingan magnesium dan larutan kuprum(II) sulfat. Merujuk kepada situasi
di atas, rancangkan satu eksperimen dalam makmal untuk membina siri elektrokimia .
Penerangan anda hendaklah mengandungi perkara-perkara berikut:

(a) Aim of the experment


Tujuan eksperimen

(b) All the variables


Semua pemboleh ubah yang terlibat

(c ) Statement of the hypothesis


Pernyataan hipotesis

(d) List of materials and apparatus


Senarai bahan dan alat radas

(e) Procedure of the experiment


Prosedur eksperimen

(f) Tabulation of data


Penjadualan data

[ 17 marks ]

END OF QUESTION PAPER

4541/3 [Next page


SPM Chemistry skema gerak gempur paper 1

1 A 21 A 41 A
2 C 22 A 42 A
3 A 23 C 43 C
4 C 24 C 44 A
5 D 25 C 45 A
6 D 26 C 46 B
7 C 27 D 47 B
8 C 28 D 48 C
9 D 29 C 49 D
10 A 30 B 50 B
11 C 31 D
12 D 32 D
13 D 33 C
14 D 34 B
15 C 35 C
16 C 36 D
17 C 37 A
18 B 38 C
19 C 39 D
20 C 40 C
Gerak Gempur SPM Chemistry skema paper 2 1
4541/2

Section A

1 (a) (i) The number of protons in an atom 1


(ii) 12 1

(b) X and Y 1
Because same proton number/the number of proton but difference
number of neutron/nucleon number 1

(c) 2.8.7 1

(d) (i)

17p

18n

Electron arrangement 1
Label 17p & 18n 1
(ii) 7 1
(iii) Y- 1

(e) 35
X 1
17
10

2 (a) 2.7 1

(b) (i) Period 2 1


(ii) Atomic size of X is smaller than V // Atomic size of V bigger than 1
X.
(iii) The number of proton in atom X is more than V. 1
The attraction by the nucleus on electron in atom X is stronger than 1
V.
or
The number of proton in atom V is less than X. 1
The attraction by the nucleus on electron in atom V is weaker than 1…...……2
X.

(c) (i) VW4 1


(ii) has low melting / boiling point // cannot conduct electricity
in any state // soluble in organic solvent 1

(d) (i) Ionic compound 1

(ii)

U W
Gerak Gempur SPM Chemistry skema paper 2 2
4541/2

[Number of electron each shells are correct] 1


[Number of charge symbol are correct] 1

10

3 (a) Chemical to electrical 1

(b) Cu2+, H+, OH- and SO42- 1

(c) (i) Zinc 1


(ii) Zinc atom releases electrons//Zinc more electropositive // Zn above
in electrochemical series 1

(d) (i) Brown solid deposited 1


(ii) Cu2+ + 2e  Cu 1

(e) Blue to colourless// Blue become fade/ paler // The intensity of 1


blue colour decreases.
The number of copper(II) ions decreases //The concentration of
copper(II) ions decr 1

(f) (i) Cu, R, Q, P 1


(ii) 1.5 V 1

10

4 (a) (i) Saponification 1


(ii) Concentrated sodium hydroxide solution 1
(iii) to lower the solubility of soap 1
(iv) Water: x Grease: y 1

(b) (i) silicon dioxide 1


(ii) inert towards chemicals 1
(iii) Borosilicate glass 1

(c) (i) Structural material that is formed by combining two or more


different subtances. 1
(ii) silver bromide / Copper(I) chloride 1
(iii) darken when exposed to sunlight
10
5 (a) (i) alcohol 1

(b) (i) H H H H 1

H C C C C-O-H
Gerak Gempur SPM Chemistry skema paper 2 3
4541/2

H H H H
(ii) 2-methylpropan-2-ol 1

(c) (i) Esterification 1


(ii) C4H9OH + C3H7COOH→ C3H7COOC4H9 + H2O 1
(iii) Insoluble in water // sweet smell // volatile 1

(d) [Functional diagram] 1


[Label] 1

(e) (i) Addition reaction 1


(ii) The colour of bromine water change from brown to colourless 1

10

6 (a) To allow the movement of ions. 1


(b)
e G e
e e
Electrode P Electrode Q

Potassium iodide
Chlorine water
solution

Dilute sulphuric acid


1

(c) (i) Colourless change to brown 1


(ii) Place a few drops of starch solution. 1
A blue precipitate is formed. 1

(d) Iodide ion // potassium iodide 1


Loss electron//increase in oxidation number 1

(e) Cl2 + 2e  2Cl- 1

(f) Bromine water // acidified KMnO4 solution // acidified K2Cr2O7 1


solution

(g) 0 to -1 1
10
Section B

7 (a) (i) Copper(II)oxide 1


Carbon dioxide 1
CuCO3→ CuO + CO2 1………...3
Gerak Gempur SPM Chemistry skema paper 2 4
4541/2

(ii) Yellow precipitate 1


Lead(II) iodide 1

2KI + Pb(NO3)2 → PbI2 + 2KNO3


Formula of reactants and products are correct 1
Balance 1………...4

(b) XH react with QY2 to produce QX2 and HY //


Reactants : XH and QY2 Products : QX2 and HY 1

HX aqueous solution react with QY2 aqueous solution to


produce QX2 solid and HY aqueous solution 1

2 mole of HX react with 1 mole of QY2 to produce


1 mole of QX2 and 2 mole of HY. 1

HX : Hydrochloric acid / HCl 1


QY2 : Lead (II)nitrate / Pb(NO3)2 1………...5
(c) (i) C H
85.70 14.30
12 1 1

7.14 14.30
7.14 7.14

1 2 1

The empirical formula CH2 1………..3

(ii) ( CH2 )n = 56

[ 12 + 2(1) ]n = 56 1

56 // 4 1
14
The molecular formula C4H8 1………..3
(iii) Empirical formula Molecular formula
The formula shows that carbon The formula shows that carbon
and hydrogen are present and hydrogen are present
The formula shows that the The formula shows that one
ratio of carbon to hydrogen is molecule of X consists of 4
1:2 carbon atoms and 8 hydrogen
atoms 1 + 1……2
20

8 (a) Size of solid particles


Concentration of solution 1
Temperature 1
Catalyst 1……3
[any three]
Gerak Gempur SPM Chemistry skema paper 2 5
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(b) (i) Mg + 2H+  Mg2+ + H2 1

(ii) Comparing experiment II and experiment I

The concentration of hydrochloric acid in experiment II


is higher than experiment I . 1

The frequency of collision between H+ ions and


magnesium atom increases. 1

The frequency of effective collision increases. 1

Comparing experiment II and experiment III

The total surface area of magnesium in experiment III


is larger than experiment II. 1

The frequency of collision between H+ ions


and magnesium atom increases. 1

The frequency of effective collision increases. 1

Comparing experiment II and experiment IV

Copper(II) sulphate solution is a catalyst 1


It lower the activation energy 1
The number of effective collision increases. 1….. 9

(iii) The time taken becomes shorter / less than 60s 1

When the temperature increases, the kinetic energy of H+


ions increases / H+ ions move faster. 1

The frequency of effective collision between H+ ions and magnesium


atom increases // The number of effective collision increases. 1........3

(c) The temperature inside the refrigerator is lower 1


Bacteria are not active at low temperature 1
Decomposition of milk caused by bacteria will slow down 1
This will keep the milk fresh for a longer period 1…...4
20
Section C

9.
(a) (i) 1. acid and metal oxide 1
2. acid and reactive metal 1
Gerak Gempur SPM Chemistry skema paper 2 6
4541/2

3. acid and metal carbonate 1 …3

(ii) Sample answer


[ Name any acid ] and [ Name any metal / metal oxide / metal carbonate ] 1
[ Name equivalent salt and water// water + CO2 // water + H2] 1
[ Balanced equation ] 1… 3

(b) (i) [chemical substances - 1 mark]


[ apparatus - 1 mark]
[procedure - 7 marks]
[chemical equation - 1 mark]

Sample answer :
1. [chemical substances]
magnesium powder /magnesium oxide(Hydroxide, carbonate)
and sulphuric acid 1
2. [ apparatus]
Beaker, filter funnel, filter paper, glass rod 1
3. [procedure]
[20 – 100] cm3 sulphuric acid [0.5 – 2.0 ] mol dm-3 is poured into a beaker 1
4. magnesium powder is added to sulphuric acid until undissolved /excess /
no more effervescence 1
5. Stir
6. the mixture is filtered 1
7. the filtrate is evaporated until saturate (one-third of it original volume) 1
8. the saturated solution is then allowed to cool to room temperature. 1
9. crystals is dried between filter paper 1
10. [chemical equation]
Mg + H2SO4 → MgSO4 + H2 // MgO + H2SO4 → MgSO4 + H2O//
MgCO3 + H2SO4 → MgSO4 + CO2 + H2O 1.... 10

(ii) [ test for sulphate ]

1. Each of solution is filled into a two test tube 1


2. Lead (II) nitrate/ Silver nitrate is added to both of test tube 1
3. If no change occur  magnesium nitrate solution 1
4. If white precipitate is formed magnesium sulfat solution 1.... 4

OR [test for nitrate]

1. Each of solution is filled into a two test tube 1


2. [Add] dilute sulphuric acid, Iron (II) sulphate solution, concentrated
sulphuric acid to both of test tube 1
3. if brown ring is formed  magnesium nitrate solution 1
4. If no changes occur  magnesium nitrate solution 1... 4
20

10 (a) (i) The heat given off when one mole of an alcohol is burnt completely in an
excess of oxygen. 1
(ii) As the number of carbon atom increase, the value of heat combustion 1
increase.
Gerak Gempur SPM Chemistry skema paper 2 7
4541/2

The greater the number of carbon atoms, the more products will be 1
obtained.
More heat is released for the formation of bonds 1
(b) Procedure :
1. Measure [100 -250] cm3 of water and pour it into the copper
container /aluminium can 1
2. Measure and record the initial temperature of the water. 1
3. Fill the small lamp with alcohol* then weigh it and record the
initial mass. 1
4. Light the wick of the lamp. 1
5. Place the lamp as near as possible to the copper container.//
[ Diagram : Using wooden block ] 1
6. [The apparatus is protected by a wind shield] // [Diagram] 1
7. Stir the water continuously. 1
8. Put out / blown out the flame when the temperature rises [ 10 –
30 ] oC and record the highest temperature of the water. 1
9. Weigh the lamp as quickly as possible and record the final mass. 1
Result :
Initial temperature of the water/ oC = T1
Highest temperature of the water/ oC = T2
Temperature rise of the water/ oC = T2 – T1 1

Initial mass of lamp + alcohol* / g = m1


Final mass of lamp + alcohol* / g = m2
Mass of alcohol that was burnt / g = m1 – m2
Calculation :
Energy chage/heat given off = 200 × 4.2 × (T2 – T1) 1

m1 – m2
Number of mole of alcohol = 1
Mr of alcohol*

Energy change
Heat of combustion of alcohol*, ΔH =
Number of mole of alcohol

200 × 4.2 × (T2 – T1)


= 1
m1 – m2
Mr of alcohol* 13
Max
12

(c)
50 x 2
Number of mole of lead(II) nitrate = 1000 = 0.1 mol
or
Gerak Gempur SPM Chemistry skema paper 2 8
4541/2

50 x 2
Number of mole of sodium sulphate = = 0.1 mol 1
1000

Ratio of mole :
1 mol Pb(NO3)2 / Na2SO4 → 1 mol PbSO4
 0.1 mol Pb(NO3)2 / Na2SO4 → 0.1 mol PbSO4 1

Energy chage/heat given off = 200 × 4.2 × 10


= 4200 J 1

Heat of precipitation of PbSO4 = 4200


0 .1
= 42000 J mol-1 / 4.2 kJ mol-1
1…4

20

END OF MARKING SCHEME


Gerak Gempur SPM Chemistry skema paper 3

Question Rubric Score


Number
[Able to exhibit the tabulation of data correctly]

Tabulation of data has the following element :


 3 columns and 4 rows
 Table contains topics, labeled with two decimal place and unit
Example : 3
Experiment I II
1(a) Initial reading/ cm3 0.45 15.45
Final reading / cm3 20.45 25.45
Volume of HX /cm3 20.00 10.00
[Able to exhibit the tabulation of data less accurately, without unit/ one
2
decimal place]
[Able to state an idea about tabulation of data] 1
Table contains at least two columns and two rows
[ No response or wrong response] 0

Question Rubric
Score
Number
[Able to state one observation accurately]
Example : 3
Red/Pink to colourless
[Able to state one observation less accurately]
1(b) Example : 2
colourless
[Able to state an idea about the observation]
1
The colour changes // pink
[ No response or wrong response] 0

1
Gerak Gempur SPM Chemistry skema paper 3

Question Rubric
Score
Number
[Able to show the calculation of HX acid concentration with the unit for both
experiment correctly]

Example :
Experiment I
The concentration of HX acid = (1)(20) / 20
= 1.0 moldm-3
or
(i) Number of mole for NaOH = (1)(20)/1000)
= 0.02 mol
(ii) Based on the equation,
1 mol of NaOH reacts with 1 mol of HX acid,
0.02 mol of NaOH reacts with 0.02 mol of
HX acid.
3
(iii) Concentration of HX acid = ( 0.02 x 1000 ) / 20
= 1.0 moldm-3
1(c) Experiment II
The concentration of HX acid = (1)(20) / 10
= 2.0 moldm-3
or
(i) Number of mole for NaOH = (1)(20)/1000)
= 0.02 mol
(ii) Based on the equation,
1 mol of NaOH reacts with 1 mol of HX acid,
0.02 mol of NaOH reacts with 0.02 mol of HX acid.

(iii) Concentration of HX acid = ( 0.02 x 1000 ) / 10


= 2.0 moldm-3
[Able to show the calculation of HX acid concentration without unit for both
experiment less correctly] 2

[Able to show an idea to calculate the concentration] 1


[ No response or wrong response] 0

2
Gerak Gempur SPM Chemistry skema paper 3
Question Rubric
Number

Score

[Able to state hypothesis correctly ]


Example :
The higher/lower the concentration of HX acid, the lower/higher the volume of the 3
acid to neutralize the sodium hydroxide solution / alkali.

[Able to state hypothesis almost correct ]


1(d) Example : 2
The lower/higher the volume of the acid to neutralize the alkali, the higher/lower the
concentration of HX acid.
[Able to state an idea about the hypothesis]
Example: 1
Concentration of the acid affects the volume of acid
[ No response or wrong response] 0

Question Rubric
score
Number
[Able to compare HX acid with sulphuric acid correctly]
Example :
 HX acid is a monoprotic/monobasic acid
3
 Sulphuric acid is a diprotic/dibasic acid
 Number of hydrogen ion in 1 mol of sulphuric acid is double of HX acid//
1(e) total number of hydrogen ions in both solution are the same
[Able to state any two of the above mentioned answers less correctly]
2
[Able to state any one of the above mentioned answers ]
1
[ No response or wrong response] 0

Question
Rubric Score
Number
[Able to write initial and final temperature with one decimal, initial and final
mass of spirit lamp and methanol and ethanol with two decimal in
experiment I and II with unit accurately]
Answer :
o
Experiment I : Initial temperature of water : 25.0 C
o
Highest temperature of water : 65.0 C
2(a) Initial mass of spirit lamp and methanol: 150.50 g 3
Final mass of spirit lamp and methanol : 149.37 g
o
Experiment II : Initial temperature of water : 25.0 C
Highest temperature of water : 65.0 oC
Initial mass of spirit lamp and ethanol: 151.35 g
Final mass of spirit lamp and ethanol : 150.50 g

3
Gerak Gempur SPM Chemistry skema paper 3

[Able to write initial and final temperature of water with one decimal without
unit, initial and final mass of spirit lamp and methanol and ethanol with two 2
decimal in experiment I and II accurately]
[Able to write at least one initial or final temperature of water without unit,
initial or final mass of spirit lamp and methanol and ethanol in experiment I 1
and II ]
[ No response / wrong response ] 0

Question
Rubric Score
Number
[ Able to state three variables and the way to control them correctly ]
Example :
Manipulated variable :
Types of alcohol//ethanol and Using difference alcohol
methanol
Responding variable : 3
Heat of combustion The different of mass of difference
2 (b) alcohol
Fixed variable :
Volume of water// same increment Using the same volume of water //
of temperature same increment of temperature
[ Able to state any pair of variable and action correctly ] ] 2
[ Able to state any variable and any action correctly // any two variables
1
correctly // any two action correctly]
[ No response or wrong response] 0

Question
Rubric Score
Number
[ Able to show the calculation correctly with unit ]
Example :
Experiment I
Energy change = 200 x 4.2 x 40 = 33 600 J 3
Experiment II
Energy change = 200 x 4.2 x 40 = 33 600 J
2(c)(i)
[ Able to show the calculation correctly without unit ]
2
[ Able to state an idea the calculation the energy change]
1
[ No response or wrong response] 0

4
Gerak Gempur SPM Chemistry skema paper 3

Question
Rubric Score
Number
[ Able to show the calculation correctly with unit]
Example :
The number of moles methanol = 1.13 = 0.035 mol
32 3
The number of moles ethanol = 0.85 = 0.018 mol
46
2(c)(ii)
[ Able to show the calculation correctly without unit]
2
[ Able to state an idea the calculation the number of mole]
1
[ No response or wrong response] 0

Question
Rubric Score
Number
[ Able to show the calculation correctly with unit ]
Example :
The heat combustion of methanol = 33 600 J
3
0.035
= 960 000 J mol-1 = 960 kJ mol-1
2(c)(iii)
[ Able to show the calculation correctly without unit]
2
[ Able to state an idea the calculation the heat of combustion of methanol]
1
[ No response or wrong response] 0

Maxi
Question
Rubric mum
Number
Score
[Able to predict the heat combustion of ethanol correctly]
Example: 3
Higher than heat combustion of methanol
[Able to state the heat combustion of ethanol]
Example: 2
2(d)
1818 kJ mol-1[The heat combustion of ethanol from calculation ]
[Able to state an idea the heat combustion of ethanol]
Example: 1
same
[ No response or wrong response] 0

5
Gerak Gempur SPM Chemistry skema paper 3

Question
Rubric Score
Number
[ Able to give the aim of the experiment correctly ]
Example :
3
To construct the electrochemical series based on the potential differences
between metals
[ Able to give the aim of the experiment incorrectly ]
Example :
3(a) 2
To construct the electrochemical series //How to construct an electrochemical
series based on the potential difference between metals?
[ Able to state an idea the aim of the experiment]
Example : 1
To study the potential difference between the metals
[ No response or wrong response] 0

Question
Rubric Score
Number
[ Able to state All variables correctly ]
Example :
Manipulated variable : Pairs of different metals//Different types of metals
3
Responding variable : Potential differences
3(b) Constant variable : Concentration of Copper(II) sulphate
// positive terminal
[ Able to state any two variables correctly ] 2
[ Able to state any one variables correctly ] 1
[ No response or wrong response] 0

Question
Rubric Score
Number
[ Able to give the hypothesis correctly]
Example :
3
The distance between two metals increase/decrease, the potential difference
will increase/ decrease
[ Able to give the hypothesis almost correct]
Example : 2
3(c)
The potential difference will increase if the distance between two metals
increase
[ Able to state an idea of the hypothesis ]
Example : 1
The potential difference affects the position of the metals
[No response or wrong response] 0

6
Gerak Gempur SPM Chemistry skema paper 3

Question
Rubric Score
Number
[ Able to give the list of the apparatus and materials correctly and
completely]
Example :
List of apparatus and materials 3
Copper strip, lead strip, iron strip, zinc strip, aluminium strip, magnesium
strip, copper (II) sulphate solution, sand paper, voltmeter, beaker, connecting
wires with crocodile clip
[ Able to give the list of the apparatus and materials correctly and but not
3(d) completely]
Example : 2
List of apparatus and materials
Copper strip, lead strip, zinc strip, magnesium strip[at least 4 metal strips],
copper (II) sulphate solution, voltmeter, connecting wires
[ Able to give an idea about the list of the apparatus and materials correctly]
Example : 1
Any one apparatus and one material
[No response or wrong response] 0

Question
Rubric Score
Number
[ Able to state all procedures correctly ]
Example :
1. Clean the metals with sand paper
2. Fill a beaker with copper(II)sulphate solution
3. Dip the magnesium strip and copper strip into the copper(II)sulphate
solution 3
4. Complete the circuit//switch-on the circuit
5. Record the potential difference between the metals
3(e)
6. Determine and record which metal strip is the negative terminal
7. Repeat steps 1 to 6 using other metals to replace magnesium strip

[ Able to state 4 steps of procedures correctly ]


2
Steps 2,3,5,7
[ Able to state 2 steps of procedures correctly ]
1
Steps 3,5
[No response or wrong response] 0

7
Gerak Gempur SPM Chemistry skema paper 3

Question
Rubric Score
Number
[ Able to exhibit the tabulation of data correctly ]
Tabulation of data has the following element :
1. 3 columns and 6 rows
Example :
Pair of metals Potential difference (V) Negative terminal
3
Mg and Cu
Al and Cu
Zn and Cu
Pb and Cu
Fe and Cu
3(f) [ Able to exhibit the tabulation of data almost correctly ]
Example :
Pair of metals Potential difference
2

[ Able to state an idea about the tabulation of data ]


1

[No response or wrong response] 0

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