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Theory:
Another typical application of linear systems to chemistry is balancing a chemical
equation. The rationale behind this is the Law of conservation of mass which states the
following:
“Mass is neither created nor destroyed in any chemical reaction. Therefore balancing of
equations requires the same number of atoms on both sides of a chemical reaction. The
mass of all the reactants (the substances going into a reaction) must equal the mass of
the products (the substances produced by the reaction).”
Example:
Balancing this chemical reaction means finding values of x, y, z and t so that the number
of atoms of each element is the same on both sides of the equation:
Since we are looking for whole values of the variables x, y z, and t, choose x=2 and get
y=7, z= 4 and t=6. The balanced equation is then:
Theory:
Coupled oscillations is a linear chain of identical non-interacting bodies connected to
each other and to fixed endpoints by identical springs.
Example:
Case 1:
Consider two identical bodies joined up with identical springs on a frictionless track as
follows:
Here A and B represent the equilibrium positions of the two masses. Let x1(t) and x2(t) be
the distances from the equilibrium positions of the two masses at time t and let k be the
spring constant.
The force acting on the first body has two parts by Hooke’s law: the first part is –kx1 due
to the leftmost spring and the second part is k(x2-x1) due to the center spring. The net
force acting on the first mass is then
Applying the second Newton’s of motion gives the following system of differential
equations:
Recall that the eigenvalues of A are those values of λ satisfying the equation:
is a basis for the eigenspace corresponding to 1. Similarly, one can show that the vector
Now let
then where
so,