Review Test Acids, Bases & Buffers1

1/27/2018 Review Test Submission: Part 2: Acids, Bases & Buffers –...
CHEM 600 (3B4) Content Review Test Submission: Part 2: Acids, Bases & Bu ers
Review Test Submission: Part 2: Acids, Bases & Bu ers
User KRISTINA MOIRA ARENAS

Course CHEM 600 (3B4)
Test Part 2: Acids, Bases & Bu ers
Started 1/26/18 11:00 PM
Submitted 1/26/18 11:56 PM
Status Completed
Attempt Score 53.00000 out of 55.00000 points
Time Elapsed 56 minutes out of 1 hour
Results Displayed Correct Answers
Question 1 1.00000 out of 1.00000 points
What happens to the solution if sodium acetate is added to a solution of acetic acid?
CH3COOH(aq) H+(aq) + CH3COO–(aq)
Correct Answer: There is an increased concentration of acetate ions.
Which may be used to prepare a bu er having a pH of 8.8?

Ka= 7 × 10–3 for H3PO4; 8 × 10–8 for H2PO4–; 5 × 10–13 for HPO42–
Correct Answer: NaH2PO4 and Na2HPO4
Indicators are weak acids that are one color in acidic solution and another color in basic
solution.
Correct Answer: True
When the concentration of the conjugate base of a weak acid is less than the concentration
of the weak acid in a bu er solution, the pH of the solution is
Correct Answer: less than the pKa.
A 10.0-mL sample of 0.75 M CH3CH2COOH is titrated with 0.30 M NaOH. What is the pH of

the solution after 22.0 mL of NaOH have been added to the acid?
[Ka(CH3CH2COOH) = 1.3 × 10–5]
Correct Answer: 5.75
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A 35.0-mL sample of 0.20 M LiOH is titrated with 0.25 M HCl. What is the pH of the solution
after 23.0 mL of HCl have been added to the base?
What is the [H3O+] in a bu er that consists of 0.30 M HCOOH and 0.20 M HCOONa?
[Ka(HCOOH) = 1.7 × 10–4]
Correct Answer: 2.6 × 10–4 M
Which best describes the pH at the equivalence point of a titration of a weak base with a
strong acid?
Correct Answer: Between 0 and 7
Increasing the concentrations of the components of a bu er solution will increase the

bu er capacity.
A 20.0-mL sample of 0.30 M HClO was titrated with 0.30 M NaOH. The following data were
collected during the titration. Determine to Ka for HClO.
2
1
5
5
0
.
mL NaOH added .
0
0
0
0
1
6
7
0
.
pH .
4
9
3
8
6
3
1
Correct Answer: 3.5 × 10–8
If the pH of a bu er solution is greater than the pKa value of the bu er acid, the bu er will
have more capacity to neutralize added base than added acid.
Correct Answer: False
What is the pH of a solution that consists of 0.50 M H2C6H6O6 (ascorbic acid) and
0.75 M NaHC6H6O6 (sodium ascorbate)?
[Ka(H2C6H6O6) = 6.8 × 10–5]
A bu er is prepared by adding 1.00 L of 1.0 M HCl to 750 mL of 1.5 M NaHCOO. What is the

pH of this bu er? [Ka(HCOOH) = 1.7 × 10–4]
Which best describes the pH at the equivalence point of a titration of a weak acid with a
strong base?
Correct Answer: Between 7 and 14
Which results in a bu ered solution?
Correct Answer: A solution containing a weak acid and its conjugate base
Calculate the pH of the solution resulting from the addition of 10.0 mL of 0.10 M NaOH to
50.0 mL of 0.10 M HCN (Ka = 4.9 × 10–10) solution.
40.0 ml of an acetic acid of unknown concentration is titrated with 0.100 M NaOH. After

20.0 mL of the base solution has been added, the pH in the titration ask is 5.10. What was
the concentration of the original acetic acid solution?
(Ka(CH3COOH) = 1.8 × 10–5)
Correct Answer: 0.072 M
Which is the best choice for preparing a bu er with a pH of 3.5?
Correct Answer: C6H4(COOH)2, Ka = 2.9 × 10–4
Increasing the concentrations of the components of a bu er solution will increase the

bu er range.
Correct Answer: False
The amount of strong acid added to a bu er solution cannot exceed the original amount of
conjugate base present in order for the bu er to still work.
What is the pH at the equivalence point in the titration of 100 mL of 0.10 M HCl with
0.10 M NaOH?
Correct Answer: 7.0
A bu er is prepared by adding 300.0 mL of 2.0 M NaOH to 500.0 mL of 2.0 M CH3COOH.

What is the pH of this bu er? [Ka(CH3COOH) = 1.8 × 10–5]
You have 500.0 mL of a bu er solution containing 0.30 M acetic acid (CH3COOH) and

0.20 M sodium acetate (CH3COONa). What will the pH of this solution be after the addition
of 20.0 mL of 1.00 M NaOH solution?
[Ka(CH3COOH) = 1.8 × 10–5]
An acetic acid bu er containing 0.50 M CH3COOH and 0.50 M CH3COONa has a pH of 4.74.

What will the pH be after 0.0020 mol of HCl has been added to 100.0 mL of the bu er?
A 20.0-mL sample of 0.25 M HNO3 is titrated with 0.15 M NaOH. What is the pH of the

solution after 30.0 mL of NaOH have been added to the acid?
What is the e ect on equilibrium when sodium acetate is added to a solution of acetic
acid?
CH3COOH(aq) H+(aq) + CH3COO–(aq)
Correct Answer: The equilibrium shifts to the left.

A 50.0-mL sample of 0.50 M HCl is titrated with 0.50 M NaOH. What is the pH of the

Calculate the pH of a bu er solution prepared by dissolving 0.20 mole of sodium cyanate

(NaCNO) and 1.0 mole of cyanic acid (HCNO) in enough water to make 1.0 liter of solution.
[Ka(HCNO) = 2.0 × 10–4]
The pH of a solution that is 0.20 M CH3COOH and 0.20 M CH3COONa should be higher than

the pH of a 0.20 M CH3COOH solution.
What is the pH of a solution prepared by mixing 500.mL of 0.10 M NaOCl and 500. mL of

0.20 M HOCl?
[Ka(HOCl) = 3.2 × 10–8]
What molar ratio of CH3COOH to CH3COONa should be used in order to prepare an acetic
acid / sodium acetate bu er solution with a pH of 4.00 ± 0.02?
[Ka(CH3COOH) = 1.8 × 10–5]
Correct Answer: 5.6
What is the pH of a solution that is 0.410 M in HOCl and 0.050 M in NaOCl?

[Ka(HOCl) = 3.2 × 10–8]
Below is a titration curve for the titration of 50.0 mL of a 0.100 M solution of the weak acid
HA with a 0.100 M solution of NaOH.


What is the approximate pKa of HA?
Correct Answer: 6
Calculate the pH at the equivalence point for the titration of 50.0 mL of 0.20 M NH3 with
0.20 M HCl.
[Kb(NH3) = 1.8 × 10–5]
What is the pH of a bu er that consists of 0.20 M NaH2PO4 and 0.40 M Na2HPO4?
[Ka(NaH2PO4) = 6.2 × 10–8]
You have 500.0 mL of a bu er solution containing 0.20 M acetic acid (CH3COOH) and

0.30 M sodium acetate (CH3COONa). What will the pH of this solution be after the addition
of 20.0 mL of 1.00 M NaOH solution?
[Ka(CH3COOH) = 1.8 × 10–5]
What is the pH of a bu er solution prepared by dissolving 0.20 mole of cyanic acid (HCNO)
and 0.80 mole of sodium cyanate (NaCNO) in enough water to make 1.0 liter of solution?
[Ka(HCNO) = 2.0 × 10–4]
A bu er is prepared by adding 150 mL of 1.0 M NaOH to 250 mL of 1.0 M NaH2PO4. How
many moles of HCl must be added to this bu er solution to change the pH by 0.18 units?
Correct Answer: 0.025 mol HCl
What is the Henderson-Hasselbach equation?
Correct Answer:
pH = pKa + log
What is the [H3O+] in a solution that consists of 1.5 M NH3 and 2.5 M NH4Cl?
Kb = 1.8 × 10–5
Correct Answer: 9.3 × 10–10 M
A mixture made of 100 mL of 0.5 M CH3COOH and 100 mL of 0.5 M CH3COONa is classi ed

as a bu er solution.
What is the pH of a bu er that consists of 0.45 M CH3COOH and 0.35 M CH3COONa?
[Ka(CH3COOH) = 1.8 × 10–5]
A 50.00-mL solution of 0.10 M HNO2 is titrated with a 0.10 M KOH solution. After 25.00 mL

of the KOH solution is added, what is the pH in the titration ask?
[Ka(HNO2) = 4.5 × 10–4]
Which is the best acid to prepare a bu er with the lowest pH?
Correct Answer: HOC6H4OCOOH, Ka = 1.0 × 10–3
What is the e ect on the equilibrium when sodium formate is added to a solution of formic
acid?
HCOOH(aq) H+(aq) + HCOO–(aq)
Correct Answer: The equilibrium shifts to the left.
A 20.00-mL sample of 0.3000 M HBr is titrated with 0.15 M NaOH. What is the pH of the

What is the name is used to describe the situation when a compound containing an ion in
common with a dissolved substance is added to a solution at equilibrium which shifts the
equilibrium?
Correct Answer: Common ion e ect
Which of the following is correct for the equivalence point in an acid-base titration?
Correct
Answer: The amounts of acid and base combined are in a stoichiometric ratio at the equivalence point in an
acid-base titration.
Which of the following acids is the best acid to prepare a bu er with the highest pH?
Correct Answer: HBrO, Ka = 2.3 × 10–9
Which pair of substances cannot form a bu ered aqueous solution?
Correct Answer: HNO3 and NaNO3
Which pair of substances could form a bu ered aqueous solution?
Correct Answer: H3PO4, NaH2PO4
When a strong acid is titrated with a strong base, the pH at the equivalence point
Correct Answer: is equal to 7.0.
Calculate the pH of a bu er solution that contains 0.25 M benzoic acid (C6H5CO2H) and

0.15 M sodium benzoate (C6H5COONa).
(Ka = 6.5 × 10–5 for benzoic acid)
Which pair of substances is capable of forming a bu er in aqueous solution?
Correct Answer: CH3COOH, CH3COONa
Which of the following is an exact or approximate value of the pH at the equivalence point
of a titration of a strong acid with a strong base?
Correct Answer: 7.0
Friday, January 26, 2018 11:56:46 PM PHT
← OK

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1/27/2018 Review Test Submission: Part 2: Acids, Bases & Buffers –...

Review Test Submission: Part 2: Acids, Bases & Bu ers

User KRISTINA MOIRA ARENAS

Question 1 1.00000 out of 1.00000 points

Correct Answer: There is an increased concentration of acetate ions.

Question 2 1.00000 out of 1.00000 points

Which may be used to prepare a bu er having a pH of 8.8?

Correct Answer: NaH2PO4 and Na2HPO4

Question 3 1.00000 out of 1.00000 points

Question 4 1.00000 out of 1.00000 points

Correct Answer: less than the pKa.

Question 5 1.00000 out of 1.00000 points

A 10.0-mL sample of 0.75 M CH3CH2COOH is titrated with 0.30 M NaOH. What is the pH of

Correct Answer: 5.75

Question 6 1.00000 out of 1.00000 points

Correct Answer: 12.33

Question 7 1.00000 out of 1.00000 points

What is the [H3O+] in a bu er that consists of 0.30 M HCOOH and 0.20 M HCOONa?

[Ka(HCOOH) = 1.7 × 10–4]

Correct Answer: 2.6 × 10–4 M

Question 8 1.00000 out of 1.00000 points

Correct Answer: Between 0 and 7

Question 9 1.00000 out of 1.00000 points

Increasing the concentrations of the components of a bu er solution will increase the

Question 10 1.00000 out of 1.00000 points

Correct Answer: 3.5 × 10–8

Question 11 1.00000 out of 1.00000 points

Question 12 1.00000 out of 1.00000 points

What is the pH of a solution that consists of 0.50 M H2C6H6O6 (ascorbic acid) and

[Ka(H2C6H6O6) = 6.8 × 10–5]

Correct Answer: 4.34

Question 13 1.00000 out of 1.00000 points

A bu er is prepared by adding 1.00 L of 1.0 M HCl to 750 mL of 1.5 M NaHCOO. What is the

Correct Answer: 2.87

Question 14 1.00000 out of 1.00000 points

Correct Answer: Between 7 and 14

Question 15 1.00000 out of 1.00000 points

Which results in a bu ered solution?

Question 16 1.00000 out of 1.00000 points

Correct Answer: 8.71

Question 17 1.00000 out of 1.00000 points

40.0 ml of an acetic acid of unknown concentration is titrated with 0.100 M NaOH. After

Correct Answer: 0.072 M

Question 18 1.00000 out of 1.00000 points

Which is the best choice for preparing a bu er with a pH of 3.5?

Correct Answer: C6H4(COOH)2, Ka = 2.9 × 10–4

Question 19 1.00000 out of 1.00000 points

Increasing the concentrations of the components of a bu er solution will increase the

Question 20 1.00000 out of 1.00000 points

Question 21 1.00000 out of 1.00000 points

Correct Answer: 7.0

Question 22 1.00000 out of 1.00000 points

A bu er is prepared by adding 300.0 mL of 2.0 M NaOH to 500.0 mL of 2.0 M CH3COOH.

Correct Answer: 4.92

Question 23 1.00000 out of 1.00000 points

You have 500.0 mL of a bu er solution containing 0.30 M acetic acid (CH3COOH) and

Correct Answer: 4.71

Question 24 1.00000 out of 1.00000 points

An acetic acid bu er containing 0.50 M CH3COOH and 0.50 M CH3COONa has a pH of 4.74.

Correct Answer: 4.71

Question 25 1.00000 out of 1.00000 points

A 20.0-mL sample of 0.25 M HNO3 is titrated with 0.15 M NaOH. What is the pH of the

Correct Answer: 2.00

Question 26 1.00000 out of 1.00000 points

Review Test Acids, Bases & Buffers1

Review Test Acids, Bases & Buffers1