Avanti-C-13-Chapter Test General Organic Chemistry- Set A

Time:- 40Marks Test Code : MH-C-13-17 Marks :- 80

SET A

1.Given are cyclohexanol (I) acetic acid (II), 2, 4, 6 – trinitrophenol (III) and phenol (IV). In these the order of
decreasing acidic character will be :
(a) III > II > IV > I (b) II > III > I > IV
(c) II > III > IV > I (d) III > IV > II > I
2.Which of the following compounds exhibits stereoisomerism?
(a) 2-methylbutene-1
(b) 3-methylbutyne-1
(c) 3-methylbutanoic acid
(d) 2-methylbutanoic acid
3. Structure of the compound whose IUPAC name is 3-ethyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid is :

4. Arrange the following in increasing order of stability

(A) (CH3 )2 C+ CH2CH3 (B) (CH3 )3 C+ (C) (CH3)2CH+ (D) CH3CH2+ (E) CH3+
(a) E < D < C < B < A (b) E < D < C < A < B
(c) D < E < C < A < B (d) A < E < D < C < B
5.The correct order of increasing bond length of C – H, C – O, C – C and C = C is :
(a) C – H < C = C < C – O < C – C
(b) C – C < C = C < C – O < C – H
(c) C – O < C – H < C – C < C = C
(d) C – H < C – O < C – C < C = C

6.Which one of the following pairs represents stereoisomerism?

(a) Structural isomerism and Geometrical isomerism (b) Optical isomerism and Geometrical isomerism
(c) Chain isomerism and Rotational isomerism. (d) Linkage isomerism and Geometrical isomerism

7. Which of the following is not chiral ?

(a) 2, 3- Dibromopentane (b) 3-Bromopentane (c) 2-Hydroxypropanoic acid (d) 2-Butanol

8.In Duma's method of estimation of nitrogen 0.35g of an organic compound gave 55 mL of nitrogen collected at
300 K temperature and 715 mm pressure. The percentage composition of nitrogen in the compound would be :
(Aqueous tension at 300 K = 15 mm)
(a) 15.45 (b) 16.45 (c) 17.45 (d) 14.45
9.Nitrogen detection in an organic compound is carried out by Lassaigne’s test. The blue colour formed corresponds to
which of the following formulae?
(a) Fe3[Fe(CN)6]3 (b) Fe3[Fe(CN)6]2 (c) Fe4[Fe(CN)6]3 (d) Fe4[Fe(CN)6]2

10.The state of hybridization of C2, C3, C5 and C6 of the hydrocarbon is in the following sequence:

(a) sp3, sp2, sp2 and sp (b) sp, sp2, sp2 and sp3 (c) sp, sp2, sp3 and sp2 (d) sp, sp3, sp2 and sp3

11.If there is no rotation of plane polarised light by a compound in a specific solvent, though to be chiral, it may mean
that (a) the compound is certainly meso
(b) there is no compound in the solvent
(c) the compound may be a racemic mixture
(d) the compound is certainly a chiral.
12. For (i) I–, (ii) Cl–, (iii) Br–, the increasing order of nucleophilicity would be
(a) Cl– < Br– < I– (b) I– < Cl– < Br– (c) Br– < Cl– < I– (d) I– < Br– < Cl–

13. How many stereoisomers does this molecule have ? CH3CH=CHCH 2CHBrCH3
(a) 4 (b) 6 (c) 8 (d) 2

14. The decreasing order of nucleophilicity among the

(a) eclipse, gauche, anti (b) gauche, eclipse, anti (c) eclipse, anti, gauche (d) anti, gauche, eclipse.

15. The reaction :

(a) elimination reaction (b) substitution reaction (c) free radical reaction (d) displacement reaction

16.

17. Identify the compound that exhibits tautomerism :

(a) 2-Butene (b) Lactic acid (c) 2-Pentanone (d) Phenol

18.The IUPAC name of neopentane is

(a) 2, 2 dimethylpropane (b) 2 methylpropane (c) 2, 2 dimethylbutane (d) 2- methylbutane

19.Which one of the following has the minimum boiling point ?

(a) 1 – Butene (b) 1 – Butyne (c) n- Butane (d) isobutane
20.Out of the following, the alkene that exhibits optical isomerism is
(a) 3-methyl-2-pentene (b) 4-methyl-1-pentene (c) 3-methyl-1-pentene (d) 2-methyl-2-pentene
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