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INORGANIC CHEMISTRY

TARGET : JEE (ADVANCED) 2018


 

INFORMA TIO
E EST
DPPDAILY PRACTICE PROBLEMS

Course : VIJETA & VIJAY (ADP & ADR) Date : 16.04.2018


NO. 2
TEST INFORMATION
DATE : 17.04.2018 PART TEST (PT)-02
Syllabus: Inorganic Nomenclature, Periodic table, Chemical Bonding & Coordination Compounds.
DPP Syllabus : Inorganic Nomenclature, Periodic table, Chemical Bonding & Coordination Compounds.

DPP No. # 2
Total Marks: 177 Max. Time: 118 min.

Single correct Objective ('–1' negative marking) Q.1 to Q.7 (3 marks, 2 min.) [21, 14]
One or more correct objective (no negative marking) Q.8 to Q.20 (4 marks, 2 min.) [52, 26]
Assertion and Reason ('–1' negative marking) Q.21 to Q.23 (3 marks, 3 min.) [09, 09]
Comprehension ('–1' negative marking) Q.24 to Q.32 (3 marks, 2 min.) [27, 18]
Integer type ('–1' negative marking) Q.33 to Q.41 (4 marks, 3 min.) [36, 27]
Match the Following (no negative marking) Q.42 to Q.45 (8 marks, 6 min.) [32, 24]

1. What is the maximum number of electrons which can be accommodated in an atom in which the
highest principal quantum number of subshell is 4?
(A) 10 (B) 18 (C) 36 (D) 54

2. The ligand N(CH2CH2NH2)3 is :


(A) tridentate (B) tetradentate (C) didentate (D) pentadentate

3. The correct IUPAC name for the complex [Pt(NH3)2Cl4], which has maximum planes of symmetry is :
(A) cis-platinum tetrachlorodiammine (B) trans-platinum tetrachlorodiammine
(C) trans-Diamminetetrachloroplatinum(IV) (D) cis-Diammine tetrachloroplatinum (IV)

4. The correct electronic configuration for [CrF6]4– will be :


(A) t2g4eg° (B) eg2 t2g2 (C) t2g3 eg1 (D) eg4 t2g°

5. 4-nitrophenyl hydrazine is an example of :


(A) a tridentate ligand (B) a bidentate ligand (C) a monodentate ligand (D) a tetradentate ligand

6. What is the coordination number of La in the compound [La(EDTA) (H2O)4]. 3H2O


(A) 6 (B) 8 (C) 10 (D) 12

7. Which among the following will be named as dibromobis(ethylenediamine)chromium (III) bromide ?


(A) [Cr(en)2Br2] Br2 (B) [Cr(en)2Br2]Br3 (C) [Cr(en)2 Br2] Br (D) [Cr(en)2Br3]
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8.* During the complete combustion of ethene C2H4, which of the following do not represent change in
hybridisation of carbon atom?
(A) sp3 to sp (B) sp3 to sp2 (C) sp2 to sp (D) sp2 to sp3

9.* Which of the following substances exhibit H-bonding with water?


O
(A) CH3CH2OH (B) CH3–C–OH (C) CH3 – CH2 – CH3 (D) N(CH3)3

10.* In which of the following pairs, the number of lone pair(s) over central atom and molecular geometry
is/are different?
(A) TeCl4, PCl4+ (B) CIF3, PCl3 (C) SiCl4, BF4– (D) BrF5, XeF5–

11.* In which of the following, the -bonds cannot lie in same plane?

(A) Cl–CC–Cl (B) O=C=O (C) N2 (D)

12.* Which of the following pairs of coordination compound show same type of isomerism?
(A) [Co(NH3)5Br] SO4 and [Ni(dmg)2] (B) [Pt(NH3)2Cl2] and [Co(en)2BrCl]Cl
(C) [Co(NH3)6][Cr(CN)6] and K[PtCl3(C2H4)] (D) [Ni(en)3]2+ and [Co(ox)3] 3 –

O O

13.* C6H5–C–CH–C–CH3 is called benzoylacetonato. Bis(Benzoylacetonato)beryllium will show :
(A) structural isomerism (B) geometrical isomerism
(C) optical isomerism (D) None of thesea

14.* In which of the following pairs of elements the electronegativity of the first element is more than that of
second element?
(A) Al, Ga (B) Li, K (C) Cl, S (D) F, Cl

15.* Which of the following can show linkage isomerism?


NH2

(A) (B) NO2– (C) OCN– (D) N3–

S–

16.* Which among the following is stronger lewis bases than HN(SiH 3)2?

(A) NH3 (B) H2N(CH3) (C) H2N(SiH3) (D)

17.* In which of following silicate(s), the number of corners shared per tetrahedron is  2?
(A) Four membered cylic silicate (B) Pyrosilicate
(C) Chain silicate (D) 2-D silicate

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18.* Which of the following is/are correct?
(A) vander Waal’s radius of iodine is more than its covalent radius
(B) All isoelectronic ions belong to the same period of periodic table
(C) First ionisation energy of Be is more than that of C
(D) Electron affinity of N as well as noble gases is negative.

19.* How many nodal suface can be present in the molecular orbital formed by the overlap of s and px
(X axis is the molecular axis)?
(A) 2 (B) 1 (C) 3 (D) None of these

20.* Which of the following show intramolecular hydrogen bonding?


(A) salicylaldehyde (B) o-nitrotoluene
COOH
(C) p-nitrophenol (D) hydrogenpthalate ion
COO–

21. Statement-1: K3[Fe(CN)6] is an inner orbital complex where as K3[FeF6] is an outer orbital complex.
Statement-2: CN– being a strong ligand, pairs electrons of Fe3+ and we get d2sp3 hybridization. But F–
being weak ligand do not pair electrons in Fe3+.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.

22. Statement-1 : H2S is less acidic than H2Te.


Statement-2 : As the size of Te is more than S, the bond Te–H is weaker than S–H.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.

23. Statement-1 : Atomic size in Na is larger than Al.


Statement-2 : Number of shells in Na are more than in Al.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.

Comprehension # 1 (One or more than one correct options)


Answer the questions based on the following reactions :
CuSO4 + NH3 (excess)  X ; CuSO4 + KCl (excess)  Y

24.* Which of the following is/are correct ?


(A) color of X = Deep blue (B) color of X = sky blue
(C) hybridization of Cu2+ in X = sp3 (D) hybridization of Cu2+ in X = dsp2
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25.* IUPAC name of Y is:
(A) Potassium (tetrachloride) disulphate copper (II)
(B) Potassium tetrachloridocuprate (II)
(C) Potassium tetrachloridocopper (II)
(D) Dipotassiumcuprate(II) chloride

26.* To Y, excess KCN is added due to which:


(A) A highly stable complex [Cu(CN)4]2– is formed which remains in solution even after long time
(B) A gas is produced
(C) A highly stable complex[Cu(CN)4]3– is formed which remains in solution even after long time
(D) The products are diamagnetic

Comprehension # 2 (One or more than one correct options)


Sulphur forms numerous compounds and show variety of oxidation states. It also exhibit a good
tendency of catenation. It forms variety of oxoacids and oxoanions also. Sulphur also occur in several
biomolecules and is also used in chemotherapy as sulphadrugs.

27.* Sulphapyridine was shown to be effective drug against pneumonia


NH2

SO2NH N (Sulphapyridine)

What is the hybridization of ‘S’ in this compound.


(A) sp2 (B) sp3d (C) sp3 (D) sp3d2

28.* NH2–SO3H is called as sulphamic acid.NH 2–CO2H is called as carbamic acid. Using this knowledge,
find which formula/formulae is/are correctly matched with name ?
(A) Calcium sulphamate  Ca(N–SO3H) (B) Aluminum pyrophosphate  Al2(P2O7)3
(C) Sodium carbamate  Na(NH2–COO) (D) Ammomium thiosulphate  (NH4)S2O3

29.* Among the following compounds of sulphur, which contain sulphur–sulphur bond?
(A) H2S2O5 (B) H2S2O3 (C) Na2S4O6 (D) CaS2O7

Comprehension # 3
Electronegativity is a feature which is relative and depends on several factor like oxidation number,
hybridizations etc. For instance, the electronegativity of differently hybridized carbon are :
sp 2.99
sp2 2.66
sp3 2.48

30. Which of the following contain all carbon of equal electronegativity?


(A) Propene (B) Propadiene (C) Cyclopropene (D) Cyclopropane

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31. Which of the following is correct?
H3C – CH3 , H2C = CH2 , HC  CH
(a) (b) (c)
(A) The C–C bond is of equal strength in (a) and (b)
(B) The C–C bond is stronger in (a) than (c)
(C) The C–C bond is stronger in (b) than (c)
(D) The C–C bond is stronger in (c) than (a)

32. The direction of dipole of C  O is from O to C. This means there is slight positive charge on O. This
can be explained by:
(A) higher electronegativity of O (B) sp hybrization of C
(C) positive formal charge on O (D) All of these

O O
33. How many types of C–O bond length are present in CH3–C–CH2–CH–C–O ?
O

34. How many of the following compound can be optically active?


(a) [Co(en)2ClBr] (b) [Co(en)(NH3)2Cl2]+ (c) [Cr(NH3)4Cl2]+ (d) [Co(NH3)3Cl3] (e) [Co(en)3]3+
(f) [Ni(dmg)2] (g) [Pb(EDTA)]2– (h) [Cr(ox)2(dmg)]2– (i) [Cr(dmg)3]

35. The sum of oxidation state of Co and Cr in the following complex is [Co(NH 3)6] [Cr(NH3)2Cl4]3.

36. How many of the following species use dz 2 orbital in their hybridization?

(a) [Ni(CN)4]2– (b) [CoBr4]2– (c) NH4Cl (d) XeF4


(e) [Cr(NH3)6]2+ (f) [Cu(NH3)4]2+ (g) [FeF6]3– (h) I3–

37. Find total number of N-Cr-O angles in tris(glycinato)chromium (III).

38. Find the value of x + y where x and y indicate number of H atoms in H xFe(CO)4 and HyRe(CO)5
respectively. (EAN rule is followed).

39. How many of the following relations is/are correct?


(a) Mg > Al (electropositive character) (b) Al > Ga (electronegativity)
(c) N+ > N (Ionization energy) (d) Se > S (magnitude of egH)

(e) He+ > H (Atomic size) (f) O2–


2 < O2 (paramagnetic nature)

(g) C2 > N2 (Number of  bonds) (h) F2 > B2 (bond order)

(i) B2 > F2 (bond length) (j) NO2– > NO3– (bond angle)

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40. How many N atoms in cyanuric amide (melamine) are sp2 hybridized?

Me O Me
controlled Si
41. a (Si(Me)xCly) + water   Me Si Me . What is the value of a + x + y?
condition
O O
Si
Me Me
42. Match the following:
Column-I Column-II

(A) XeO2F4 (p) Central atom is sp3 hybridized with no lone pair on it.

(B) SO2Cl2 (q) Central atom is sp2 hybridized.

(C) COCl2 (r) Central atom involves dx2 –y2 orbital in hybridization.

(D) HClO3 (s) Contain central atom in oxidation state, two less than the highest.

43. Match the following:


Column-I Column II

(A) Na3[Co(ox)3] (p) Show geometric isomerism.

(B) [RhCl(CO)(PPh3)(NH3)] (q) Low spin complex.

(C) K[Cr(NH3)2(CN)4] (r) Paramagnetic with more than two unpaired electrons.

(D) Ba[CoBr2Cl2] (s) Show colligative property corresponding of two particles


per formula.
(t) Electrically conducting.

44. Match the following:


Column-I Column-II

(A) MnO4– (p) Paramagnetic and colored.

(B) MnO42– (q) Diamagnetic and colored.

(C) [Cu(CN)4]3– (r) Diamagnetic and colorless

(D) Ni(dmg)2 (s) Tetrahedral complex.

(t) Square planar complex.

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45. Match the following:
Column-I Column-II

(A) B > Be > Li (p) Electronegativity

(B) Na < K < Rb (q) Ionization energy

(C) Zn > Ca (r) Atomic radius

(D) S > Se (s) Metallic nature.

(t) Acidic nature of oxide

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