11/8/10

Class 32
Section 8.4,5
Finish up latent heat H1 = air at 50o C = .71
Heats of solution H2 = air at 20oC = -.144

References: Air at 25oC and 1 atm

Water(l) at 20oC
Substance nin Hin nout Hout

Air (v) 89 0.71 89 -.144

H2O (l) 0 ----- 8.9 -----

H2O(v) 11 44.987 2.1 43.98

Q = -478.5 kJ

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References: Air at 25oC and 1 atm Water(l) at 20oC References: Air at 25oC and 1 atm Water(l) at 20oC
Substa nin Hin nout Hout Substa nin Hin nout Hout
nce nce
Air (v) 89 0.71 89 -.144 Air (v) 89 0.71 89 -.144
H2O (l) 0 ----- 8.9 ----- H2O (l) 0 ----- 8.9 -----
H2O(v) 11 44.987 2.1 43.98 H2O(v) 11 44.987 2.1 43.98

Calculate kg H2O condensed/m3 of air and Calculate kg H2O condensed/m3 of air and
kJ transferred/m3 air fed. kJ transferred/m3 air fed.

References: Air at 25oC and 1 atm Water(v) at 25oC

Mixing and Solution

Substance nin Hin nout Hout
Ideal mixture – no heat of mixing or solution
Air (v) 89 .71 89 -.14

H2O (l) 0 ----- 8.9 -40.8 For non-ideal mixtures, you look up heat of
solution (or mixing), as function of r (moles of
H2O(v) 11 .85 2.1 -.17 solvent/moles of solute)

Table B-11 lists values of heats of solution at

What if we use the ideal gas table for water? 25 °C of HCl and NaOH in water, and heat of
mixing for H2SO4 at 25 °C with water
Q = 449

2

2.00 moles of 100% sulfuric acid is diluted
with enough water to produce a 30 mole %
aqueous solution. The acid and water are
initially at 25o C. How much heat would have
to be removed to keep the final solution at
25oC?
2.00 moles of 100% sulfuric acid is diluted
with enough water to produce a 30 mole %
aqueous solution. The acid and water are
initially at 25o C. How much heat would have
to be removed to keep the final solution at
25oC?
11/8/10
2.00 moles of 100% sulfuric acid is diluted
with enough water to produce a 30 mole %
aqueous solution. The acid and water are
initially at 25o C. How much heat would have
to be removed to keep the final solution at
25oC? What do you need to do first?
a) Calculate r
b) Find moles of water
c) Find mass of sulfuric acid
d) Look sulfuric acid up in Table B-11
2.00 moles of 100% sulfuric acid is diluted
with enough water to produce a 30 mole %
aqueous solution. The water is initially at 25o
C. Calculate the heat produced when the acid
is at 15oC and the solution is at 45oC.
What will happen to the Q?
a) It will increase
b) It will decrease
c) We don’t have enough information
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2.00 moles of 100% sulfuric acid is diluted
with enough water to produce a 30 mole %
aqueous solution. The water is initially at 25o
C. Calculate the heat produced when the acid
is at 15oC and the solution is at 45oC.
Consider the heat capacity of the solution to
be identical to that of water. What should the
reference state for the acid be?
a)  15oC
b)  25oC
c)  45oC
2.00 moles of 100% sulfuric acid is diluted
with enough water to produce a 30 mole %
aqueous solution. The water is initially at 25o
C. Calculate the heat produced when the acid
is at 15oC and the solution is at 45oC.
Consider the heat capacity of the solution to
be identical to that of water.

Reference: all substances at 25o C

2.00 moles of 100% sulfuric acid is diluted
Substance nin Hin nout Hout with enough water to produce a 30 mole %
H2O (l)
aqueous solution. The water is initially at 25o
C. Calculate the final temperature if the acid
H2SO4 (l) is at 15oC and the system is adiabatic.
H2SO4 (aq) ---- Consider the heat capacity of the solution to
be identical to that of water.

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2.00 moles of 100% sulfuric acid is diluted

with enough water to produce a 30 mole %
aqueous solution. The water is initially at 25o
C. Calculate the final temperature if the acid
is at 15oC and the system is adiabatic.
Consider the heat capacity of the solution to
be identical to that of water.