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1
Institute of Materials Research, Slovak Academy of Sciences, Watsonova 47, 040 01 Košice, Slovak Republic
2
Department of Materials, University of Oxford, Parks Road, Oxford OX1 3PH, United Kingdom
Received 24 February 2010, received in revised form 19 October 2010, accepted 16 November 2010
Abstract
The indentation load-size effect (ISE) in Vickers hardness of Al2 O3 and Al2 O3 + SiC
nanocomposites has been investigated using Meyer’s law, the proportional specimen resist-
ance (PSR) model and the modified proportional specimen resistance (MPSR) model. The
strongest ISE was found for alumina. It is suggested that the smaller ISE in the nanocompos-
ites is associated with the large thermal residual stresses and pre-existing dislocations in these
materials, both of which would help the initiation of plastic deformation. Both the PSR and
MPSR models described the ISE well, but the MPSR model resulted in slightly lower true
hardness values for all materials investigated. There was no evidence of an effect of machining
stresses on the ISE.
W = a1 d (2)
Peff = P − W = P − a1 d = a2 d2 , (3)
P = P0 + a1 d + a2 d2 , (4)
Fig. 4. Dependence of logP on logd according to Meyer‘s Fig. 5. Dependence of P/d on d according to the PSR
law for tested materials. model for tested materials.
trated. According to the results for all investigated gions with locally different microstructures, e.g. alu-
materials the hardness increased with decreasing in- mina grains with less or more than the average con-
dentation load and with increasing volume fraction tent of SiC nanoparticles, or alumina grains with dif-
of SiC. The lowest hardness was found for the alu- ferent orientations, which will influence the resulting
mina but with decreasing load its hardness increased hardness significantly. The evidence here is that the
faster in comparison to those of the composites, and at nanocomposites showed smaller scatter in hardness
the lowest indentation load the hardness values of all than pure alumina which indicates that inhomogeneit-
materials were very similar. The highest scatter was ies in particle distribution do not significantly affect
found in the case of alumina and the scatter for all the hardness. The better defined hardness in the nano-
materials seems to be approximately constant for all composites may be a consequence of the suppression
applied loads. of surface microcracking in these materials by the SiC
The load-dependence of the Vickers hardness can particles within the alumina grains [9, 10]. The smaller
be described quantitatively by Meyer’s law, Eq. (1). scatter of measured hardness values in nanocompos-
Figure 4 illustrates the Meyer’s law parameters de- ites (mainly at low loads) can be explained by their
termined by the regression analyses of the results. Ac- fine grained microstructure, too.
cording to the results, the most significant ISE was Figure 5 shows the plot of P/d versus d for the
found in alumina (n = 1.83) and the ISE observed in materials investigated, with the slope of the straight
the composites (n = 1.92 and n = 1.93) was much less lines of a2 and an intercept equal to a1 (see Eq. (3)).
pronounced. These values lie within the range for n of The correlation for all plots is high although a slight
1.748 to 1.979 obtained for a variety of ceramics and systematic curvature is evident with the same sense
glasses with indentation loads from 5 to 50 N by Gong in all three materials. According to Li and Bradt [12]
et al. [19]. Like Gong et al., we found radial cracking who investigated the microhardness indentation load
at the corners of the indents for tested materials in size effect in TiO2 and SnO2 single crystals, if the fact
the range of applied loads from 5 N to 50 N. Gong et that the power-law exponent, n < 2, is the result of
al. pointed out that this may affect the hardness val- not taking the proportional specimen resistance of the
ues obtained but since it is difficult to suppress this test specimen into account, then there must exist an
cracking, the extent of its influence on hardness is not inverse correlation between n and the a1 values that
clear [19]. describe the PSR model. An inverse correlation exists
It seems to be impossible to avoid the effect of mi- in our results between the n and a1 values for the alu-
crostructure on the hardness values in the low-load mina and the nanocomposites, and extrapolating lin-
range, in which the ISE is significant. In the case of early to a1 = 0 gives a value for n of 2.02, close to the
these materials, for a Vickers indentation with a load ideal value of 2 required mathematically by a compar-
of 10 N the indent area is approximately 600 µm2 , in- ison of Eqs. (1) and (3) for materials with similar un-
cluding approximately 100 grains, which is sufficient derlying hardness. This shows that both Meyer’s law
for the characteristic of the material as a whole. With and the PSR model give reasonable mathematical fits
decreasing indentation load the indent size decreased to data exhibiting an ISE but there is nothing in this
and the indentation may then be able to sample re- analysis supporting any particular physical interpret-
E. Csehová et al. / Kovove Mater. 49 2011 119–124 123