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JEE-M-2015/XI/29-04-2015
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ATOMIC STRUCTURE

1. Correct set of four quantum numbers for the valence 9. The quantum numbers +1/2 and -1/2 for the electron
(outermost) electron of rubidium (Z = 37) is : spin represent :
(a) 5, 0, 0, + 1/2 (b) 5, 1, 0, + 1/2 (a) rotation of the electron in clockwise and
(c) 5, 1, 1, + 1/2 (d) 6, 0, 0, + 1/2 anticlockwise direction respectively
(b) rotation of the electron in anticlockwise and
2. The radius of an atomic nucleus is of the order of : clockwise direction respectively
(a) 10-10 cm (b) 10-13 cm (c) magnetic moment of the electron pointing up
-15
(c) 10 cm (d) 10-8 cm and down respectively
(d) two quantum mechanical spin states which
3. Which one of the following sets of quantum numbers have no classical analogue
represents an impossible arrangement ?
n l ml ms 10. If the ionization energy of hydrogen atom is
(a) 3 2 -2 1/2 13.6 eV, the expected third ionization energy of
(b) 4 0 0 1/2 the lithium atom is :
(c) 3 2 -3 1/2 (a) 13.6 x 3 eV (b) 13.6 x 2 eV
(d) 5 3 0 -1/2 (c) 13.6 x 6 eV (d) 13.6 x 9 eV

4. Electronic configuration has 11. If the shortest wavelength of H-atom is Lyman

violated : series is , then longest wavelength in Balmer series
(a) Hund’s rule (b) Pauli’s principle of He+ ion is:
(c) Aufbau principle (d) (n+l) rule 9 36
(a) (b)
5 5
5. The outermost electronic configuration of the most
electronegative element is : 5
(a) ns2np3 (b) ns2np4 (c) (d)
4 9
(c) ns2np5 (d) ns2np6
12. Hydrogen atoms are excited to n = 4 state. In the
6. The correct ground state electronic configuration spectrum of emitted radiation, number of lines in
of chromium atom is : the ultraviolet and visible regions are respectively :
(a) [Ar] 3d54s1 (b) [Ar] 3d44s2 (a) 3 : 1 (b) 1 : 3
6
(c) [Ar] 3d 4s 0 (d) [Ar] 4d54s1 (c) 2 : 3 (d) 3 : 2

7. The correct set of quantum numbers for the unpaired 13. A ball of mass 200g is moving with a velocity of 10
electron of chlorine atom is : sec-1. If the error in the measurement of velocity is
n l m 0.1%, the uncertainty in its position is :
(a) 2 1 0 (a) 3.3 x 10-31m (b) 3.3 x 10-27 m
(b) 2 1 1 -25
(c) 5.3 x 10 m (d) 5.3 x 10-32m
(c) 3 1 1
(d) 3 0 0 14. Two particles of masses ‘m’ and ‘2m’ have equal
kinetic energies. Their de Broglie wavelengths are
8. The electrons, identified by quantum numbers n and in the ratio of :
l, (i) n =4, l=0, (ii) n = 4, l = 0, (iii) n = 3, l = 2 and (a) 1 : 1 (b) 1: 2
(iv) n = 3, l = 1 can be placed in order of increasing
energy, from the lowest to highest, as : (c) 1 : 2 (d) 2:1
(a) (iv) < (ii) < (iii) < (i) (b) (ii) < (iv) < (i) < (iii)
(c) (i) < (iii) < (ii) < (iv) (d) (iii) < (i) < (iv) < (ii)

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15. Which of the following violates the Aufbau principle 21. If the electron in hydrogen atom jumps from the
? third orbit to second orbit, the wavelength of the
emitted radiation is given by :
(a) (b)
2s 2p 2s 2p
36 5R
(a) (b)
(c) (d) 5R 36
2s 2p 2s 2p
5 R
(c) (d)
16. The momentum of a hydrogen atom is given by : R 6
hv
(a) p mvr (b) p 22. Which of the following equations was suggested by
mc 2 de Broglie ?
mv hv P
(c) p (d) p (a) 2 r (b)
h c n
h

17. The respective values of orbital angular momentum nh

(c) r2 n (d) 2
of an electron is 1s, 2s, 3d and 3p-orbitals are :
h h h h
(a) 0,0, 6 , 2 (b) 1,1, 4 , 2 23. The kinetic energy of an electron, particle and
2 2 2 2 proton are represented by E1, E2 and E3 respectively.
h h h h These particles have same di Broglie wavelength
(c) 0,1, 6 , 3 (d) 0,0, 20 , 6 then :
2 2 2 2
(a) E1 = E2 + E3 (b) E1 > E2 > E3
18. Select the correct relation between azimuthal (c) E1 > E3 > E2 (d) E3 > E2 > E1
quantum number (l) and magnetic quantum number
(m) : 24. The de Broglie wavelength of neutron at 27oC is
. The wavelength at 927OC will be
m 1
(a) l (b) m l 2
2 (a) (b)
(c) m 2l 2 1 (d) l 9 4
2m 1
(c) (d)
19. 3d4 configuration may have the exchange of : 2 3
(a) four electrons (b) three electrons
(c) sixteen electrons (d) six electrons 25. The ratio of time periods (T 1/T2) in second orbit of
hydrogen to third orbit of He+ ion is :
20. Which of the following electronic configurations have (a) 8/27 (b) 32/27
spin multiplicity equal to zero? (c) 27/32 (d) 24/36

(a) (b)

(c) (d)

Note : Answer key will be displayed on Saturday (30th April 2016)

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