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INGENIERIA
FACULTAD DE INGENIERIA QUIMICA Y TEXTIL
𝑁 = 𝑁𝑜 + ∑𝑗 𝑉𝑗𝜀 𝑗
Reacción numero 1
2H2 + CO CH3OH
Vi
H2 3.249 0.422 0 0.083 0 0 0 -2
CO 3.376 0.557 0 -0.031 -110525 -137169 89.409396 -1
CH3OH 2.211 12.216 -3.45 0 -200660 -161960 -129.865772 1
-90135 -24791 -219.275168 -2
∆A -7.663
∆B 0.010815
∆C -0.00000345 T IDCPH IDCPS
∆D -13500 550 33557.5314 -97914.4191 -239.03991 -935.701124 -2.39055331
t 1.844709039 K 0.00064992
to 298.15
T°C 276.85
Reacción numero 2
H2 + CO2 CO + H2O
Vi
H2 3.249 0.422 0 0.083 0 0 0 -1
CO2 5.457 1.045 0 -1.157 -393509 -394359 2.85234899 -1
H2O 3.47 1.45 0 0.121 -241818 -228572 -44.4496644 1
CO 3.376 0.557 0 -0.031 -110525 -137169 89.409396 1
41166 28618 42.1073826 0
∆A -1.86
∆B 0.00054
∆C 0 T IDCPH IDCPS
∆D 116400 550 17075.4703 37750.8814 37.5916565 -410.767211 -0.54059919
2H2 + CO CH3OH
𝑌𝐶𝐻3𝑂𝐻
= 1002 𝑥0.000649915
𝑌𝐶𝑂𝑥(𝑌𝐻2)2
𝜀𝑖
1 − 2𝜀𝑖 = 6.499150273
0.12 − 𝜀𝑖 + 𝜀𝑖𝑖 0.75 − 2𝜀𝑖 − 𝜀𝑖𝑖 2
1 − 2𝜀𝑖 𝑥( 1 − 2𝜀𝑖 )
Reacción numero 2
H2 + CO2 CO + H2O
𝑌𝐶𝑂𝑥𝑌𝐻20
= 0.023891786
𝑌𝐶𝑂2𝑥𝑌𝐻2
0.12 − 𝜀𝑖 + 𝜀𝑖𝑖 𝜀𝑖𝑖
𝑥
1 − 2𝜀𝑖 1 − 2𝜀𝑖 = 0.023891786
0.08 − 𝜀𝑖𝑖 0.75 − 2𝜀𝑖 − 𝜀𝑖𝑖
𝑥
1 − 2𝜀𝑖 1 − 2𝜀𝑖
Resultados finales usando Solver Excel:
ni VI V II nf Yi
H2 0.75 -2 -1 0.52248965 0.65904848
CH3OH 0 1 0 0.10360302 0.13068089
H2O 0 0 1 0.02030431 0.02561108
CO2 0.08 0 -1 0.05969569 0.07529786
N2 0.05 0 0 0.05 0.06306809
CO 0.12 -1 1 0.03670129 0.0462936
Total 0.79279396 1
𝑍 3 + (𝐵 − 1)𝑍 2 + [𝐴 − 2𝐵 − 3𝐵2 ]𝑍 − 𝐴𝐵 + 𝐵2 + 𝐵3 = 0
𝐴 𝑍 + 2.414𝐵
ln(𝜙𝑖) = 𝑍 − 1 − ln(𝑍 − 𝐵) − ln( )
2√2𝐵 𝑍 − 0.414𝐵
Tc Pc Tr Pr w L M N A B Alfa Z Phy
H2 33.19 13.13 16.5712564 7.61614623 -0.216 0.44091 1.48784 0.52 0.00083782 0.03575503 0.06606732 1.0350232 1.03559099
CO 132.9 34.99 4.138449962 2.85795942 0.048 0.13058 0.85502 1.72 0.02125579 0.0537249 0.27858465 1.0360575 1.03494321
CO2 304.2 73.83 1.808021039 1.35446296 0.224 1.03473 0.88695 0.65 0.11904748 0.05828018 0.6283774 0.95347608 0.94768157
CH3OH 512.6 80.97 1.072961373 1.23502532 0.266 0.50694 0.87277 2.18629 0.44717328 0.08954659 0.91165117 0.58465882 0.68140402
H2O 547.1 220.55 1.005300676 0.45341192 0.345 0.3831 0.8701 1.97288 0.20414337 0.03508765 0.99516437 0.81370529 0.83791032
T 550
P 100 Z phy
-1.1367E-08 0
-1.2669E-08 3.4943E-08
-3.7751E-08 -5.2318E-08
-2.7526E-07 -3.186E-07
-5.9725E-08 3.1086E-15
Resultados:
Reacción numero 1
2H2 + CO CH3OH
𝑌𝐶𝐻3𝑂𝐻𝑥𝜙𝐶𝐻3𝑂𝐻
= 1002 𝑥0.000649915
𝑌𝐶𝑂𝑥𝜙𝐶𝑂𝑥(𝑌𝐻2𝑥𝜙𝐻2)2
𝜀𝑖
𝑥0.681404
1 − 2𝜀𝑖 = 6.499150273
0.12 − 𝜀𝑖 + 𝜀𝑖𝑖 0.75 − 2𝜀𝑖 − 𝜀𝑖𝑖
𝑥1.0349𝑥( 𝑥1.03559)2
1 − 2𝜀𝑖 1 − 2𝜀𝑖
Reacción numero 2
H2 + CO2 CO + H2O
𝑌𝐶𝑂𝑥𝜙𝐶𝑂𝑥𝑌𝐻20𝑥𝜙𝐻2𝑂
= 0.023891786
𝑌𝐶𝑂2𝑥𝜙𝐶𝑂2𝑥𝑌𝐻2𝑥𝜙𝐻2
0.12 − 𝜀𝑖 + 𝜀𝑖𝑖 𝜀𝑖𝑖
1 − 2𝜀𝑖 𝑥1.0349𝑥 1 − 2𝜀𝑖 𝑥0.8379
= 0.023891786
0.08 − 𝜀𝑖𝑖 0.75 − 2𝜀𝑖 − 𝜀𝑖𝑖
1 − 2𝜀𝑖 𝑥0.94768𝑥 1 − 2𝜀𝑖 𝑥1.03559
ni VI V II nf Yi
H2 0.75 -2 -1 0.48712415 0.638384836
CH3OH 0 1 0 0.1184714 0.155258871
H2O 0 0 1 0.02593306 0.033985729
CO2 0.08 0 -1 0.05406694 0.07085569
N2 0.05 0 0 0.05 0.065525887
CO 0.12 -1 1 0.02746166 0.035988987
Total 0.7630572 1