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1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses All in one solution, restores lost refrigerant and oil, contains leak sealer to help stop most
common leaks in rubber hoses, gaskets and o-rings.
Physicochemical Containers can burst violently or explode when heated, due to excessive pressure build-up.
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Pictogram
Hazard statements H280 Contains gas under pressure; may explode if heated.
3.2. Mixtures
1,1,1,2-tetrafluoroethane 50 - 100%
CAS number: 811-97-2 EC number: 212-377-0 REACH registration number: 01-
2119459374-33-XXXX
Substance with National workplace exposure limits.
Classification
Press. Gas, Liquefied - H280
Classification
Carc. 2 - H351
Classification
Flam. Liq. 3 - H226
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Acute Tox. 4 - H332
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
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Methanol <0.025%
CAS number: 67-56-1 EC number: 200-659-6
Classification
Flam. Liq. 2 - H225
Acute Tox. 3 - H301
Acute Tox. 3 - H311
Acute Tox. 3 - H331
STOT SE 1 - H370
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Ingestion Rinse mouth thoroughly with water. Move affected person to fresh air and keep warm and at
rest in a position comfortable for breathing. Keep affected person under observation. Get
medical attention if any discomfort continues.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Do not use
organic solvents. Get medical attention if any discomfort continues.
Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15
minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation Vapours may cause headache, fatigue, dizziness and nausea.
Skin contact Prolonged skin contact may cause redness and irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Hazardous combustion Thermal decomposition or combustion products may include the following substances: Oxides
products of carbon. Toxic gases or vapours.
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Protective actions during Use water to keep fire exposed containers cool and disperse vapours.
firefighting
Special protective equipment Use air-supplied respirator, gloves and protective goggles.
for firefighters
Advice on general Avoid contact with eyes and prolonged skin contact. Good personal hygiene procedures
occupational hygiene should be implemented. Wash hands and any other contaminated areas of the body with soap
and water before leaving the work site.
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Long-term exposure limit (8-hour TWA): WEL 200 ppm 266 mg/m³
Short-term exposure limit (15-minute): WEL 250 ppm 333 mg/m³
Sk
WEL = Workplace Exposure Limit
Sk = Can be absorbed through the skin.
Eye/face protection No specific eye protection required during normal use. Eyewear complying with an approved
standard should be worn if a risk assessment indicates eye contact is possible.
Hand protection The most suitable glove should be chosen in consultation with the glove
supplier/manufacturer, who can provide information about the breakthrough time of the glove
material.
Hygiene measures No specific hygiene procedures recommended but good personal hygiene practices should
always be observed when working with chemical products.
Colour Amber.
Odour Ether.
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Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.
10.1. Reactivity
Reactivity Strong acids. Strong alkalis.
Skin corrosion/irritation
Animal data Based on available data the classification criteria are not met.
Respiratory sensitisation
Respiratory sensitisation Based on available data the classification criteria are not met.
Skin sensitisation
Skin sensitisation Based on available data the classification criteria are not met.
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Genotoxicity - in vivo Based on available data the classification criteria are not met.
Carcinogenicity
Carcinogenicity Based on available data the classification criteria are not met.
Reproductive toxicity
Reproductive toxicity - fertility Based on available data the classification criteria are not met.
Aspiration hazard
Aspiration hazard Not anticipated to present an aspiration hazard, based on chemical structure.
1,1,1,2-tetrafluoroethane
Genotoxicity - in vivo DNA damage and/or repair: Negative. REACH dossier information.
Carcinogenicity
Reproductive toxicity
Reproductive toxicity - One-generation study - NOEL 50000 ppm, Inhalation, Mouse P REACH dossier
fertility information.
Reproductive toxicity - Maternal toxicity: - NOEL: 2500 ppm, Inhalation, Rabbit REACH dossier
development information.
dichloromethane
Notes (oral LD₅₀) > 2000 mg/kg, Rat REACH dossier information.
Notes (dermal LD₅₀) > 2000 mg/kg, Rat REACH dossier information.
Species Mouse
Skin corrosion/irritation
Animal data Based on available data the classification criteria are not met.
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Serious eye Based on available data the classification criteria are not met.
damage/irritation
Skin sensitisation
Skin sensitisation Local Lymph Node Assay (LLNA) - Mouse: Not sensitising. REACH dossier
information.
Carcinogenicity
Reproductive toxicity
Reproductive toxicity - Two-generation study - NOAEC ≥ 1500 ppm, Inhalation, Rat P, F1 REACH dossier
fertility information.
Reproductive toxicity - Maternal toxicity: - LOAEC: 1226 ppm, Inhalation, Rat, Mouse REACH dossier
development information.
cyclohexanone
Species Rat
Notes (dermal LD₅₀) Converted acute toxicity point estimate (cATpE) Acute Tox. 4 - H312
Notes (inhalation LC₅₀) Converted acute toxicity point estimate (cATpE) Acute Tox. 4 - H332
Genotoxicity - in vitro DNA damage and/or repair: Negative. REACH dossier information.
Carcinogenicity
Reproductive toxicity
Reproductive toxicity - Maternal toxicity: - NOAEL: 250 mg/kg/day, Oral, Rabbit REACH dossier
development information.
Methanol
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Notes (oral LD₅₀) International Programme on Chemical Safety (IPCS) (1997) Environmental Health
Criteria 196: Methanol. Geneva, World Health Organization. Acute Tox. 3 - H301
Notes (dermal LD₅₀) Converted acute toxicity point estimate (cATpE) Acute Tox. 4 - H312
Notes (inhalation LC₅₀) Converted acute toxicity point estimate (cATpE) Acute Tox. 4 - H332
Skin corrosion/irritation
Animal data Dose: 2.5 x 2.5 cm, 1, 5, 15 minutes, Rabbit Erythema/eschar score: No erythema
(0). Oedema score: No oedema (0). REACH dossier information. Not irritating.
Serious eye Dose: 0.05 ml, 1 hour, Rabbit REACH dossier information. Not irritating.
damage/irritation
Skin sensitisation
Skin sensitisation Guinea pig maximization test (GPMT) - Guinea pig: Not sensitising. REACH dossier
information.
STOT - single exposure STOT SE 1 - H370 Causes damage to organs (Eyes, Central nervous system).
REACH dossier information.
12.1. Toxicity
Toxicity Not considered toxic to fish.
1,1,1,2-tetrafluoroethane
Acute toxicity - fish LC₅₀, 24 hours: 560 mg/l, Onchorhynchus mykiss (Rainbow trout)
LC₅₀, 48 hours: 450 mg/l, Onchorhynchus mykiss (Rainbow trout)
LC₅₀, 72 hours: 450 mg/l, Onchorhynchus mykiss (Rainbow trout)
LC₅₀, 96 hours: 450 mg/l, Onchorhynchus mykiss (Rainbow trout)
REACH dossier information.
Acute toxicity - EC₁₀, EC₅₀, 6 hours: > 730 mg/l, Pseudomonas putida
microorganisms REACH dossier information.
dichloromethane
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Acute toxicity - fish LC₅₀, 96 hours: 193 mg/l, Pimephales promelas (Fat-head Minnow)
REACH dossier information.
Chronic toxicity - fish early NOEC, 28 days: 142 mg/l, Pimephales promelas (Fat-head Minnow)
life stage REACH dossier information.
cyclohexanone
Acute toxicity - fish LC₅₀, 96 hours: 527 - 732 mg/l, Pimephales promelas (Fat-head Minnow)
REACH dossier information.
Methanol
Acute toxicity - fish LC₅₀, 96 days: 15400 mg/l, Lepomis macrochirus (Bluegill)
EC₅₀, 96 hours: 12700 mg/l, Lepomis macrochirus (Bluegill)
REACH dossier information.
1,1,1,2-tetrafluoroethane
dichloromethane
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cyclohexanone
Methanol
1,1,1,2-tetrafluoroethane
dichloromethane
Bioaccumulative potential BCF: 2.0 - 5.4, Cyprinus carpio (Common carp) REACH dossier information.
cyclohexanone
Methanol
1,1,1,2-tetrafluoroethane
Henry's law constant 10220 Pa m³/mol @ 25°C REACH dossier information. Calculation method.
dichloromethane
Henry's law constant 0.00115 atm m³/mol @ 9.6°C 0.00131 atm m³/mol @ 17.5°C 0.00219 atm m³/mol
@ 24.8°C 0.00326 atm m³/mol @ 34.6°C REACH dossier information.
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cyclohexanone
14.1. UN number
UN No. (ADR/RID) 2037
Proper shipping name (IMDG) RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES)
Proper shipping name (ICAO) RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES)
Proper shipping name (ADN) RECEPTACLES, SMALL, CONTAINING GAS (GAS CARTRIDGES)
Transport labels
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Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations EH40/2005 Workplace exposure limits.
EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Commission Regulation (EU) No 2015/830 of 28 May 2015.
Council Directive of 20 May 1975 on the approximation of the laws of the Member States
relating to aerosol dispensers (75/324/EEC) (as amended).
Revision 1
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The information supplied here is accurate to the best knowledge and belief of Armored Auto UK Ltd, it is however, not
intended as a warranty or representation, and should not be construed as such, for which Armored Auto UK Ltd assumes any
legal responsibility. Any information or advice obtained from Armored Auto UK Ltd other than by means of this publication,
and whether relating to Armored Auto UK Ltd's products or other materials is also given in good faith. It remains at all times
the responsibility of the customer, and user, to ensure that the materials are suitable for the particular purpose intended.
Materials not manufactured, or supplied, by Armored Auto UK Ltd when used instead of, or in conjunction with materials
supplied by Armored Auto UK Ltd, it is the customer's responsibility to ensure that all technical, and other information related
to such materials is obtained from the manufacturer or supplier. Armored Auto UK Ltd accepts no liability for the data
contained within this document, as the information herein may be applied under conditions beyond our control, and in
situations with which we may be unfamiliar. The information contained within this document is furnished upon condition that
the customer and user of this product makes his own determination of the suitability of the product for his particular purpose.
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