Sample Paper Class 12

Two Year CRP – 1214, Phase IV – Mains – Set A Page Number 1
FIITJEE - JEE (Mains)

QP. Code : xxxx.x
PHYSICS, CHEMISTRY & MATHEMATICS

Time Allotted: 3 Hours Maximum Marks: 360
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4. The Test Booklet consists of 90 questions. The maximum marks are 360.
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questions in each part of equal weightage. Each question is allotted 4 (four) marks for correct response.
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fourth) marks will be deducted for indicating incorrect response of each question. No deduction from the total score will
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Section 1 (Part A) PHYSICS
1. Two cells of emf’s approximately 5V and 10V are to be accurately compared using a
potentiometer of length 400cm.
(a) The battery that runs the potentiometer should have voltage of 8V
(b) The battery of potentiometer can have a voltage of 15V and R adjusted so that the
potential drop across the wire slightly exceeds 10V.
(c) The first portion of 50 cm of wire itself should have a potential drop of 10V
(d) Potentiometer is usually used for comparing resistances and not voltages.
1
2. A metal rod of Length 10 cm and a rectangular cross-section of 1 cm × cm is connected to
2
a battery across opposite faces. The resistance will be
1
(a) maximum when the battery is connected across 1 cm × cm faces.
2
(b) maximum when the battery is connected across 10 cm × 1 cm faces.
1
(c) maximum when the battery is connected across 10 cm × cm faces.
2
(d) same irrespective of the three faces.
3. Which of the following characteristics of electrons determines the current in a conductor?

(a) Drift velocity alone (b) Thermal velocity alone
(c) Both drift velocity and thermal velocity (d) Neither drift nor thermal velocity.
4. A capacitor of 4F is connected as shown in the circuit.

The internal resistance of the battery is 0.5. The amount
of charge on the capacitor plates will be
(a) 0 (b) 4C (c) 16C (d) 8C
5. The electrostatic potential on the surface of a charged conducting sphere is 100V. Two
statements are made in this regards
S1: At any point inside the sphere, electric intensity is zero.
S2: At any point inside the sphere, the electrostatic potential is 100V.
Which of the following is a correct statement?
(a) S1 is true but S2 is false
(b) Both S1 & S2 are false
(c) S1 is true, S2 is also true and S1 is the cause of S2
(d) S1 is true, S2 is also true but the statements are independent.
6. Equipotentials at a great distance from a collection of charges whose total sum is not zero
are approximately
(a) spheres (b) planes (c) paraboloids (d) ellipsoids.
7. A parallel plate capacitor is made of two dielectric blocks

in series One of the blocks has thickness d1 and dielectric
constant k1 and the other has thickness d2 and dielectric
constant k2 as shown in figure. This arrangement can be
thought as a dielectric slab of thickness d(=d1+d2) and
effective dielectric constant k. The k is
k1d1  k 2d2 k1d1  k 2d2
(a) (b)
d1  d2 k1  k 2
k1k 2  d1  d2  2k1k 2
(c) (d)
 k1d1  k 2d2  k1  k 2
_______________________________________________________________________________________________________________________________________________
8. Five charges q1, q2, q3, q4 and q5 are fixed at their

positions as shown in the figure. S is a Gaussian
q
surface. The Gauss’s law is given by  E.ds  
s 0
. Which
of the following statements is correct?

(a) E on the LHS of the above equation will have a
contribution from q1, q5 and q3 while q on the RHS will
have a contribution from q2 and q4 only.
(b) E on the LHS of the above equation will have a
contribution from all charges while q on the RHS will
have a contribution from q2 and q4 only.
(c) E on the LHS of the above equation will have a
contribution from all charges while q on the RHS will
have a contribution from q1, q3 and q5 only.
(d) Both E on the LHS and q on the RHS will have
contributions from q2 and q4 only.
9. A point charge +q, is placed at a distance d from an isolated conducting plane. The field at a
point P on the plane is
(a) directed perpendicular to the plane and away from the plane
(b)directed perpendicular to the plane but towards the plane.
(c) directed radially away from the point charge.
(d) directed radially towards the point charge.
10. Figure shows electric field lines in which an electric dipole

moment p is placed as shown. Which of the following
statement is correct?
(a) The dipole will not experience any force.
(b) The dipole will experience a force towards right.
(c) The dipole will experience a force towards left.
(d) The dipole will experience a force upwards.
11. A particle of mass m and charge q enters a region of
magnetic field (as shown) with speed v. There is a region in
which the magnetic field is absent, as shown. The particle
after entering the region collides elastically with a rigid
wall. Time after which the velocity of particle becomes anti
parallel to its initial velocity is
m m
(a)    4 (b)    2
2qB qB
m m
(c)    2 (d)  2  3
4qB 4qB
12. A current carrying circular loop of radius R is placed in the x-y plane with centre at the
origin. Half of the loop with x>0 is now bent so that it now lies in the y-z plane.
(a) The magnitude of magnetic moment now diminishes.
(b) The magnetic moment does not charge.
(c) The magnitude of B at (0.0.z),x>>R increases.
(d) The magnitude of B at (0.0.z),x>>R unchanged.
13. A circular current loop of magnetic moment M is in an arbitrary orientation in an

external magnetic field B. The work done to rotate the loop by 30° about an axis
perpendicular to its plane is
MB MB
(a) MB (b) 3 (c) (d) zero.
2 2
_______________________________________________________________________________________________________________________________________________
14. A toroid of ‘n’ turns, mean radius R and cross-sectional radius ‘a’ carries current I. It is
placed on a horizontal table taken as x-y plane. Its magnetic moment M
(a) is non-zero and points in the z-direction by symmetry.
(b) points along the axis of the tortoid M  m  
1
(c) is zero, otherwise there would be a field falling as at large distances outside the
r3
toroid.
(d) is pointing radially outwards.
15. A block of mass m and charge q is connected to a point O with help of an inextensible
string. The system is on a horizontal table. An electric field is switched on in direction
perpendicular to string. What will be tension in string when it becomes parallel to
electric field?
qE qE 3qE
(a) (b)3qE (c) (d).
2  5
16. A loop carrying current I lies in the x-y plane as shown in

y
the figure. The unit vector k̂ is coming out of the plane of
the paper. The magnetic moment of the current loop is
  I
(A) a2I kˆ (B)   1 a2I kˆ a x
2 
a
 
(C)    1 a2I kˆ (D) (2  1)a2I kˆ
2 
17. The figure shows two infinite semi-cylindrical shells: shell-

1 and shell-2. Shell-1 carries current i1 in inward direction
normal to the plane of paper, while shell-2 carries same
current i1, in opposite direction. A long straight conductor
lying along the common axis of the shells is carrying
current i2 in direction same as that of current in shell-1.
force per unit length on the wire is
0 i1i2 20 i1i2 20 i1i2
(a) zero (b) (c) (d)
2r r 2 r
18. A meter bridge is set up as shown, to determine an

unknown resistance ‘X’ using a standard 10 ohm resistor.
The galvanometer shows null point when tapping-key is at X 10 
52 cm mark. The end-corrections are 1 cm and 2 cm
respectively for the ends A and B. The determined value of
‘X’ is A B
(a)10.2 ohm (b) 10.6 ohm
(c) 10.8 ohm (d) 11.1 ohm
19. A parallel plate capacitor C with plates of unit area and

separation d is filled with a liquid of dielectric constant K = C
d R
d d
2. The level of liquid is initially. Suppose the liquid level 3
3
decreases at a constant speed V, the time constant as a
_______________________________________________________________________________________________________________________________________________
function of time t is
6  0R (15d  9Vt)0R
(a) (b)
5d  3Vt 2d2  3dVt  9V 2 t 2
6  0R (15d  9Vt)0R
(c) (d)
5d  3Vt 2d2  3dVt  9V 2 t 2
20. A wire of length L and 3 identical cells of negligible internal resistance are connected in
series. Due to the current, the temperature of the wire is raised by T in a time t. A number
N of similar cells is now connected in series with a wire of the same material and cross
section but of length 2L. The temperature of the wire is raised by the same amount T in
the same time t. The value of N is
(A) 4 (B) 6 (C) 8 (D) 9
21. The resultant capacitance of given circuit is

C
(a) 3C (b) 2C (c) C (d)
3
22. A and B two concentric spheres. If A is given a charge Q

while B is earthed as shown in figure:
(a) the charge density of A and B are same
(b) the field inside and outside A is zero
(c) the field between A and B is not zero
(d) the field inside and outside B is zero.
23. n small drops of the same size are charged to V volt each. If they coalesce to form a single
large drop, then its potential will be
(a) (V/n) (b) Vn (c) Vn1/3 (d) Vn2/3

24. An electric field is given by E  yi  x j   CN . The work done by the E in moving 1 C charge
 
 
from rA  2i  2j m to rB  4i  j m is  
(a) +4 J (b) –4 J (c) +8 J (d) zero
25. In a certain region of space, the potential field depends on x and y coordinates as V=(x 2–y2) .
The corresponding electric field lines in x–y plane are correctly represented by:
26. In a permanent magnet at room temperature

(a) magnetic moment of each molecule is zero.
(b) the individual molecules have non-zero magnetic moments which are all perfectly
aligned.
(c) domains are partially aligned.
(d) domains are all perfectly aligned.
27. A paramagnetic sample shows a net magnetization of 8 Am–1 when placed in an external
magnetic field of 0.6T at a temperature of 4K. When the same sample is placed in an
external magnetic field of 0.2T at a temperature of 16K, the magnetization will be
_______________________________________________________________________________________________________________________________________________
32 2
(a) Am–1 (b) Am–1 (c) 6Am–1 (d) 2.4Am–1.
3 3
28. Find charge on capacitor in steady state in given circuit
(a) 9.6 C (b) 7.2C (c) 4.8C (d) 2.4C.
29. Plates of a parallel plate capacitor C have charges CV

and 3 CV on its plates. If switch is closed at t=0. Then
initial rate at which heat energy is produced in
resistance R is
V2 4V 2
(a) (b)
R R
9V 2 16V 2
(c) (d)
R R
30. Two wires are of same length and same area of cross-section. If first wire has resistivity
1 and temperature coefficient of resistance 1 but second wire has resistivity 2 and
temperature coefficient of resistance 2. Their series equivalent resistance is
independent of small temperature changes. Then
(a) 1+2=0 (b) 11=22 (c) 11+22=0 (d) 12+21=0
Section 2 (Part A) CHEMISTRY
1. Propanone and propanal are:

(a) geometrical isomers (b) chain isomers
(c) functional isomers (d) position isomers
2. Which type of isomerism is shown by diethyl ether and methyl propyl ether?
(a) chain (b) functional (c) metamerism (d) position
3. Which of the following is chiral carbon ?

(a) CH4 (b) CH3I (c) CH2Cl2 (d) CHIBrCl
4. Which of the following is optically active ?

(a) Butane (b) 4-methyl heptanes
(c) 3-methyl heptane (d) 2-methyl heptane
5. The correct statement about the compounds (A), (B) and (C) is
COOCH 3 COOH COOH
H C OH H C OH H C OH
H C OH H C OH HO C H
COOH COOCH 3 COOCH 3

(A) (B) (C)
(a) A and B are identical (b) A and B are diastereomers
(c) A and C are enantiomers (d) A and B are enantiomers.
_______________________________________________________________________________________________________________________________________________
6. Which of the following pairs of structures represent enantiomers ?
COOH CH3 COOH COOH
(a) HO C H and H C OH (b) CH 3 C OH and HO C CH 3

H3C COOH H H
COOH OH CH3 OH
(c) H C CH3 and CH3 C H (d) HOOC C OH and HOOC C H
HO COOH H CH3
7. The most stable conformer of 2, 3-dimethylbutane is

CH CH3 CH CH3 H3C H
H
3 CH3 H 3 CH3
CH3
(c) (d)
(a) (b)
CH3
H CH3 H CH3 H CH3 H3C
CH3 CH3 CH3
H H
8. Which of the following carbocation is most stable?

+ + +
CH 2 CH 2 CH 2 +
CH 2
(b) (c)
(a) (d)
NO 2 OH OH
9. Which of the following shows maximum enol content
(a) O (b) O (c) O (d) O
10. The compound, whose stereochemical formula is written below, exhibits x-geometrical
isomers and y-optical isomers.
H
CH 3
OH
Br
CH3
H
(a) 4 and 4 (b) 2 and 2 (c) 2 and 4 (d) 4 and 2
11. An organic compound, C3H6O does not give a precipitate with 2, 4-dinitrophenylhydrazine
reagent and does not react with metallic sodium. It could be
(a) CH3 – CH2 – CHO (b) CH2 = CH – CH2OH
(c) CH3 – CO – CH3 (d) CH2 = CH – O – CH3
OH +
Ag (aq.)
12.
22. H3C CH2 Cl ?
CH3
The major product formed is
OH
O
(b) CH3 C CH2 OH
(a) CH 3 C CH 2 CH3 H3C
H O HO
(c) CH3 C (d) CH3 C CH2 CH3
H3C H3C
_______________________________________________________________________________________________________________________________________________
13. Which products of the following reactions give iodoform test ?

O
H2 O / H 

?
||
(a) Ph – C  CH Hg2 (b) CH 3  C  Cl  H 2 
Pd / BaSO4

CN (i) CH3MgBr
(c)
?
(ii) H3O+
(d) All of them
14. In the given reaction:

O
CH3MgBr
CH3 C CH2 CH2 CH2 CH2 Cl (P)
(P) will be :
CH3 (b) CH3

(a)
O CH3 O CH3
MgBr OH
(c) CH3 C CH2 CH2 CH2 CH2Cl (d) CH3 C CH2 CH2 CH2 CH2 Cl
CH3 CH3
15. Which of the following is not a resonating form of benzaldehyde ?

+ H C O
H C O H C O H C O
+ (d)
(a) (b) (c)
+
16. How will you convert butan-2-one to propanoic acid ?

(a) Tollen’s reagent (b) Fehling solution (c) NaOH/I2/H+ (d) NaOH/NaI/H+
O
NaBH4
(A)
17.
27. OC 2H5
H3C
O LiAlH4
A & B are respectively (B)
HO
HO
(a) OC 2H5
H3C and OC 2H5
H3C
OH
HO
HO O
(b)
OH
H3C and OC 2H5
H3C
HO O
(c) HO
OC 2H5
H3C and OH
H3C + C2H5OH
O
(d) None
_______________________________________________________________________________________________________________________________________________
18. Ph – C  C – CH3 
 A, A is: Hg2+ /H+
O OH
(a) Ph Ph Ph
Ph (c)
(b) O
(d) OH
H3C H3C H3C H3C
19. When m-chloro benzaldehyde is treated with 50% KOH solution; the product(s) obtained is
(are)
COO CH 2OH COO CH 2OH
(a) + (b) +
OH OH Cl Cl
OH OH OH OH
CH CH CH CH
(c) (d)
Cl OH OH OH
MgBr
(i) CO2
20.
30.
(ii) H3+O
P
In the above reaction, product P is
CHO
COOH
(a) (b)
OH
O
(c)
(d) C6H5 C C6H5
21. Which of the following does not give canizarro reaction :
(a) CHO (b) CH 2CHO
(c) H3C CHO (d) O2N CHO
22. The product(s) obtained via oxymercuration (HgSO4 + H2SO4) of 1-butyne would be
(a) CH3CH2COCH3 (b) CH3CH2CH2CHO
(c) CH3CH2CHO + HCHO (d) CH3CH2COOH + HCOOH
23. In the Cannizaro’s reacting given below:

2Ph – CHO  Ph - CH2OH + PhCO2
OH
The slowest step is:

(a) the attack of OH at the carbonyl group
(b) the transfer of hydride to the carbonyl group
(c) the abstraction of proton from the carboxylic acid
(d) the deprotonation of Ph-CH2OH
24. Which of the following will react with water to form stable hydrate
(a) HCOOH (b) Cl3C.CHO (c) CCl4 (d) CH3CHO
_______________________________________________________________________________________________________________________________________________
25. Compound A (molecular formula C3H8O) is treated with acidified potassium dichromate to
form a product B (molecular formula C3H6O). B forms a shining silver mirror on warming
with ammonical silver nitrate. B when treated with an aqueous solution of H2NCONHNH2 and
sodium acetate gives a product C. Identify the structure of C:
(a) CH3CH2CH = N.NHCONH2 (b) CH3  C  N.NHCONH 2
|
CH3
(c) CH3  C  N.CONHNH 2 (d) CH3CH2CH = N.CONHNH2
|
CH3
26. Which of the following is inert towards SN-1 reaction ?
(a) Ethyl chloride (b) Isopropyl chloride

Cl
(c)
(d)
Cl
COO
30. B
27. N2
+
The product (B) is
(a) (b)
(c) (d)
C N
MgBr
Ether H3O+
31.
28. + A B.
O N- MgBr
C
C
(a) (b)
N-H N- OH
C C
(c) (d)
29. At isoelectric point pH of the compound below is
(a) 3.22 (b) 6.96 (c) 8.05 (d) 5.93
_______________________________________________________________________________________________________________________________________________
CH3 OH
30. NH 2
NaNO2 + HCl
33. ?
The product formed is

CH OH 3
O CH3
O
(a) (b)
CH3 OH
COOH
(d)
(c)
CH2NH2 O
Section 3 (Part A) MATHEMATICS
1. Which of the following have same graph.

a b bx
I.  1 II. bx+ ay = xy III . y 
x y xa
 a  I & II only  b  II & III only
 c  I & III only  d  none havethe same graph
 x 2  x  x3  x 2  x  1
2. The function f : R  1,1   0,   , defined as f  x   cos   , is
 x 1  x 1
 a  even function  b  onto function  c  periodic function  d  invertible
 cos x 
3. The range of f  x     ; where 
  Fractional part function, is
 11 
 a [0,1 11]  [10 11,1)  b [0,1 11)  [10 11,1)  c [0,1 11]  (10 11,1)  d [0,1 11)  (10 11,1)
4. Which of the following is an identical function
a f  x    sin x sin 2 x

x ; g  x   x2
2
b f  x   ; g  x 
1  tan 2 x 2
 c  f  x   sin1x  cos 1x ; g  x   tan1x  cot 1x  d  f  x   cos 2 x  sin4 x ; g  x   cos 4 x  sin2 x
5. If g  x   f  x   0; x   0,   ; then which of the following is true

x x
 a    g  t   f  t   dt is decreasing  b    g 1 t   f 1 t   dt is decreasing
0 0
1x 1x
 c    g  t   f  t   dt is decreasing  d    g 1 t   f 1 t   dt is increasing
0 0
_______________________________________________________________________________________________________________________________________________
 tanx , when x is rational ,

6. f  x    tan 2 x  tan x
 , when x is irrational ,
1  tanx  tan 2 x
Then in   ,   , the number of points where f  x  is discontinuous is
a 0 b 2 c 4 d  6
7. If
d
dx
 f  ax    x 2 , then f '  bx  
x2 b2 x2 b2 x2 b2 x 2
a b c d 
b a3 a2 a
  sin x 
2

   x  .  x  1  x  1  2 
3
3 x ln 
 x 
8. lim  
x 0 x .  x  sin x  . 1  cos x 
a0 b 2 c 4 d 6
 sin x  sin t 
2
9. Let lim    f  sinx  . Then the range of f  x  is

t x
 x t 
 a  (,1]  b   1,0  c  0,1  d [1, )
9 x 2  11x  1  4 x 2  13x  3
10. The value of lim
x x
a5 b 3 c  3 d   5
11. Let R be a relation on the set A = {1,2,3,4,…..,2013}. If { (1,2), (2,3), (4,5), (6,6) }  R and n be
the number of ordered pairs in R, then the least possible value of n, for R to be symmetric
and transitive but not reflexive is
(a) 16 (b) 14 (c) 12 (d) 10

12. Let  e
1 x
 dx  a – ln a, where [.] → Greatest Integer Function then ' a ' equal to  a  N 
0
 a 1 b 2 c3 d  4
x5 x 4 x3 x 2 x
13. Let f  x        1 then value of
5 4 3 2 1
d
dx
 f 1  x   at x  1 is
 a 1 b 2 c3  d  not exist

x x 1
1   1
14. Let f  x   1   & g  x   1   ; x   0,   . Then which of the following is increasing
x   x
function for positive x
a g  x  f  x b g  f  x   c  g  f  g  x    d  f  f  g  x  
_______________________________________________________________________________________________________________________________________________
15. Let y =f(x) be a continuous function with f(0)=0, say. Given below is the graph of its derivative
function y= f '  x  . Let a, b, c & d denotes the number of points of maximum, minimum,
inflexion & critical points of y=f(x) respectively in (0,11). Then
a a  3 b b  4 c c  5 d  d  7

d 1
16. Let f : [1,5] →[2,4] be a bijective function such that
dx
 f (x)  0  x  [1,5] , then
5 4
 f(x)dx   f
1
(x)dx 
1 2
(a) 12 (b) 16 (c) 18 (d) 24
b
x2
17. Let f  x   , x  0 & f  0   0; a, b  R such that a  b then the value of  f  x  dx is
x a
(a) a–b (b) a  b (c) b  a (d) b–a
x 4 1  x 
1 4 1
x6
18. If 
1
1  x2
dx  A and 0 1  x2 dx  B then value of 3 A 12B , where   Greatest Integer
function.
a0 b 1  c 1  d  noneof these
  1 
1
6 f  x  dx   f  0   4 f  
  2 
19. Let f  x  be a quadratic polynomial where f 1  0 . Then 0 
f 1
 a 1 b 2 c3 d  4
20. Consider the function f  x   x 2  7 x  12 .  x 2  4 x  3 .  x  2  .  x  5 . Then Rolle’s Theorem for
f(x) is NOT applicable in the interval
(a) [1,3] (b) [2,4] (c) [3,5]  d  noneof these
21. The range of the interval f:  1,3 →R under the mapping f  x   4 x  12 x is

3
(a) [–72,8] (b) [–8,72] (c) [–8,8] (d) [8,72]
22. Let f(x+T)=f(x), where T>0, The minimum possible value of T for
f(x) = sin2x – cot2x + sec2x.cosec2x – tan2x + cos2x.
(a)1 (b)  /2 (c)  (d) None of these.
_______________________________________________________________________________________________________________________________________________
x  x
2 a
  x  1  2 x  x 7  dx   c then value of ' a ' is

7
23. If 8
a
a 2 b 4 c 6  d 8
 x 
tan 1   dx
x 1 
1
24. The value of   =
0 1  1  2 x  2 x 2

tan  
 2 
(a) 0 (b) 1/2 (c) 1 d  2
2x
25. If f  x    t  2t  4  dt then f ' 1 has the value
3
x 1
a 4 b8  c 12  d 16
 16
26. Let f be the function such that f    x 2  x  1; x  0. Then f 8 equals
 1 x 
 
(a) 1 (b) 7 (c) 73 (d) 91
1 4
27. A continuous real function f ( x) satisfiy f  4 x   2 f  x   x  R . If  f  x  dx  2 , then  f  x  dx 
0 1
 a 10  b 12  c 14  d 16

28. The function f : R  R defined as f  x   2 tan 1 e x    2
is
 a  odd  b  even  c  onto  d  many one & into
29. The integral values of n, the value of lim

n     
n2  n  1   n2  n  1 , where [.] → Greatest
Integer Function
1
a  b 1 c 2 d 3
2
30. Let f  x   100  99 x  x then set of values of x satisfying the inequality

3
100  99 f  x    f  x    f 100 1  x   is
3
 a  99,0  99,    b  , 1   0,1  c  1,0  1,    d  100,0  100,  
_______________________________________________________________________________________________________________________________________________
FIITJEE - JEE (Mains)

ANSWER KEY
Physics:
5. c
1. b 2. a 3. a 4. d
10. c
6. a 7. c 8. b 9. b
15. b
11. a 12. a 13. d 14. c
20. c
16. b 17. d 18. b 19. c
25. d
21. a 22. c 23. d 24. d
30. c
26. c 27. b 28. a 29. c
Chemistry:
1 2 3 4 5 6 7 8 9 10
C C D C D B B D B C
11 12 13 14 15 16 17 18 19 20
D A D B B C C A B B
21 22 23 24 25 26 27 28 29 30
B A B B A C A A A B
MATHEMATICS
1 2 3 4 5 6 7 8 9 10
D A A D C D B A C D
11 12 13 14 15 16 17 18 19 20
B B A D D C C C A C
21 22 23 24 25 26 27 28 29 30
B B D B C D C A A C
_______________________________________________________________________________________________________________________________________________
FIITJEE
CPT1 - 1 CODE: Set- A PAPER - 1

BATCHES – 1214
 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before th e end of the test.
_______________________________________________________________________________________________________________________________________________
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into two sections: Section-A & Section-C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for
rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in any
form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment No. and
write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.
(i) Section-A (01 – 10) contains 10 multiple choice questions which have only one correct answer. Each question
carries +3 marks for correct answer and – 1 mark for wrong answer.
Section-A (11 – 15) contains 5 multiple choice questions which have one or more than one correct
answer. Each question carries +4 marks for correct answer. There is no negative marking.
(ii) Section-C (01 – 05) contains 5 Numerical based questions with single digit integer as answer, ranging from 0 to
9 and each question carries +4 marks for correct answer. There is no negative marking..
_______________________________________________________________________________________________________________________________________________
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
_______________________________________________________________________________________________________________________________________________
Useful Data Chemistry:
Gas Constant R = 8.314 J K1 mol1
= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56, Mn=55,
Pb=207, Au=197, Ag=108, F=19, H=2, Cl=35.5, Sn=118.6
Useful Data Physics:
Acceleration due to gravity g = 10 m / s2
_______________________________________________________________________________________________________________________________________________
P
PA RTT –– II :: P
AR PHHY
YSSIIC
CSS
SECTIONA
Single Correct Choice Type
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.
1. An ideal ammeter and an ideal voltmeter are connected as

A V
shown. The ammeter and voltmeter reading for R1
R2 R3
R1 = 5, R2 = 15, R3 = 1.25 and E = 20V are given as
(a) 6.25 A, 3.75 V (b) 3.00 A, 5 V
(c) 3.75 A, 3.75 V (d) 3.75 A; 6.25 V
E
2. Two spheres of radii r and R carry charges q and Q respectively. When they are connected by a wire, there will
be no loss of energy of the system if
2 2 2 2
(a) qr = QR (b) qR = Qr (c) qr = QR (d) qR = Qr

3. An electric field given by E  4iˆ  3(y2  2)jˆ pierces Gaussian cube of side 1m placed at origin such that its three
sides represents x, y and z axes. The net charge enclosed within the cube is
(a) 40 (b) 30 (c) 50 (d) zero
4. A dipole of dipole moment p is kept at the centre of a ring of radius R and charge q. The dipole moment has
direction along the axis of the ring. The resultant force on the ring due to the dipole is
pq
(a) zero (b)
40R3
pq pq
(c) (d) only if the charge is uniformly distributed on the ring.
20R3 40R3
5. A conductor in the form of a right angle ABC with AB = 3 cm and BC = 4 cm carries a current of 10 A. There is a
uniform magnetic field of 5 T perpendicular to the plane of the conductor. The force on the conductor will be
(a) 1.5 N (b) 2.0 N (c) 2.5 N (d) 3.5 N
Space for Rough Work
_______________________________________________________________________________________________________________________________________________
6. A parallel plate capacitor of capacitance C = 2F (without dielectrics) is filled by dielectric slabs as shown in
figure. Then the new capacitance of the capacitor is :
K3  6 d
(a) 7.8 F (b) 3.9 F K1  2 K2  4 d
(c) 2.4 F (d) 8 F
w w
7. A long straight wire, carrying current I, is bent at its midpoint to form an angle of 45°. Magnetic field at point P,
distance R from point of bending is equal to :
( 2  1)0I ( 2  1)0I P
(a) (b)
4R 4R R 45° I
I
( 2  1)0I ( 2  1)0I
(c) (d)
4 2R 2 2R
8. Figure shows an amperian path ABCDA. Part ABC is in vertical T

plane PSTU while part CDA is in horizontal plane PQRS.
Direction of circulation along the path is shown by an arrow near U
 
point B and at D.   B.d  for this path according to Ampere’s law i2
will be : i1 B A S
R
i1
i3 C D
P Q
(a) (i1  i2  i3 )0 (b) (i1  i2 )0 i3 i2
(c) i3 0 (d) (i1  i2 )0
9. Five conducting plates are placed parallel to each other, Separation between them is d and area of each plate
is A. Plate number 1, 2 and 3 are connected with each other and at the same time through a cell of emf E. The
charge on plate number 1 is : 1
2
3
E 4
E 0 A E 0 A 5
(a) (b)
d 2d
2E0 A
(c) (d) zero
d
_______________________________________________________________________________________________________________________________________________
10. Half part of ring is uniformly positively charged and other half is E0
uniformly negatively charged. Ring is in equilibrium in uniform – – ++
electric field as shown and free to rotate about an axis passing – +
– +
through its centre and perpendicular to plane. The equilibrium is
– +
– +
–
–– + +
(a) stable (b) unstable
(c) neutral (d) can be stable or unstable
_______________________________________________________________________________________________________________________________________________
SECTION - B
(Multi Correct Choice Type)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
11. In the circuit shown in figure: S1 S2

(a) i =2.5 A when S1is closed and S2 is open
20 1 2 10V 3
(b) i  A when S1 is open and S2 is closed
3
i 20V
5
(c) i  A when S1 and S2 both are open
3
(d) i =20A when both S1 and S2 are closed
12. An observer A and a charge Q are fixed in a stationary

frame F1 . An observer B is fixed in a frame F2 , which is
moving with respect to F1 : A B
F1 •Q F2
(a) both A and B will observe electric field
(b) both A and B will observe magnetic field
(c) neither A nor B will observe magnetic field
(d) B will observe magnetic field but A will not
13. Two plates of a parallel plate capacitors carry charges q and –q and
V0
are separated by a distance x from each other. The capacitor is
connected to a constant voltage source V0 . The distance between the
plates is changed to x  dx. Then in steady state.
+q –q
Udx
(a) change in electrostatic energy stored in the capacitor is ,
x x
where U is initial potential energy.
Ux
(b) change in electrostatic energy stored in the capacitor is 
dx
1
(c) attraction force between the plates is qE
2
(d) attraction force between the plates is qE. (where E is electric field between the plates)
14. When some potential difference is maintained between A

and B, current I enters the network at A and leaves at B. 20  5
C
(a) The equivalent resistance between A and B is 8 .
A B
(b) C and D are at the same potential.
5 D 20 
(c) no current flows between C and D.
3I
(d) current flows from D to C.
5
_______________________________________________________________________________________________________________________________________________
15. A charged particle moves in a gravity-free space without change in velocity. Which of the following is/are
possible?
(a) E = 0, B = 0 (b) E = 0, B  0 (c) E  0, B = 0 (d) E  0, B  0
_______________________________________________________________________________________________________________________________________________
SECTIONC
Integer Answer Type
1 The following curve represents the variation of y

V
potential of points along x-axis due to two-point
charges q1 and q2 separated by a distance 2a. Find
the ratio of magnitude of two charges (point O is x
q1 P q2
a 
origin and coordinates of point P is  , 0  (-a,0) O (a,0)
3 
2. The region between X = 0 and X = Lm is filled with uniform steady magnetic field 2Tkˆ . A particle of mass 2
kg, positive charge 1C and velocity 2(m/s) î travels along x-axis and enters the region of the magnetic field
(neglect gravity). Find the value of L if the particle emerges from the region of magnetic field with its final
0
velocity at an angle 30 to its initial velocity.
3. In the diagram there are four conducting plates A, B, C and D placed parallel to each other at equal separation
L. If plate C starts moving towards plate B with velocity v. Find the current (in mA) flowing in the wire connecting
A and D. (assume all other plates to be fixed)
(Given: q2 = 2C, q3 = 3C, v = 30 m/s, L = 0.05 m )
+q1 +q2 –q3 +q

3
–q1 –q2
A B v C D
4. The figure shows a RC circuit with a parallel plate capacitor. –Q0

Before switching on the circuit, plate A of the capacitor has a
charge –Q0 while plate B has no net charge. Now, at A B
t = 0, the circuit is switched on. How much time (in second) will R
elapse before the net charge on plate A becomes zero. (Given C = S
2  10 6
1F, Q0 = 1mC,  = 1000 V and R  ) 
ln3
5. A thin insulated wire forms a plane spiral of N = 100 tight turns

carrying a current I = 8 mA. The radii of inside and outside turns
as shown in figure are equal to a = 50 mm and b = 100 mm.
Find the magnetic induction (in micro tesla) upto the nearest
integer at the centre of the spiral;
_______________________________________________________________________________________________________________________________________________
P
PA RTT –– IIII :: C
AR CHHE
EMMIIS
STTR
RYY
SECTIONA
1. The correct IUPAC NAME of the following compound is

NO 2
Cl
CH3
(a) 4-Methyl-5-chloronitrobenzene (b) 2-chloro-1-methyl-4-Nitrobenzene
(c) 3-chloro-4-methyl-1-nitrobenzene (d) 1-chloro-2-methyl-5-nitrobenzene
2. Allyl isocyanide has

(a) 9 & 4 bonds (b) 8 and 5 bonds
(c) 9,3 bonds & 2-nonbonded electrons (d) 8,3, bonds and 4  non bonded electrons.
3. In the following groups

OAC, OMe OSO2Me OSO2CF3
(I) (II) III IV
The order of leaving groups ability is
(a) I > II > III > IV (b) IV > III > I > II
(c) III > II > I > IV (d) II > III > IV > I
4.
Column-I (Comp.) Column – II (Ka)
(a) Benzoic acid (p) 3.3  105
(b) p-nitrobenzoic acid (q) 10.2  105
(c) p-chlorobenzoic acid (r) 30.6  105

(d) p-methoxy benzoic acid (s) 6.4  105
(e) p-methyl benzoic acid (t) 4.2  105
_______________________________________________________________________________________________________________________________________________
Which is correct match for acids in column I with their ka’s in column II
a b c d e
A T P Q R S
B S R P Q T
C R S P T Q
D S R Q P T
5. Among the following compounds I, II & III

CH3 CH3 CH3
H OH HO H HO H
HO H HO H H OH
CH3 CH3 CH3
I II III
Which of the following statement is incorrect
(a) I & III are enantiomers
(b) I & II are diastereomers
(c) II & III are diastereomers
(d) All are incorrect
6. In the given reaction
2 CHO 
KCN/EtOH
H2 O
Product
O
O OH
+
(a) C OK & CH2OH (b) 2 C H
O O O
CN
O O O
(c) C C (d) C CH
O O O O
OH

O
OH
_______________________________________________________________________________________________________________________________________________

7. 
OH

 Product (major)
Product in the above reaction
O O O
-
(a) (b) (c) O (d) None
CH3
8. When phenol is reacted with CHCl3 and NaOH followed by acidification, salicylaldehyde is obtained, which of
the following species are involved in the above mentioned reaction as intermediate.
-
O OH O O
H CHCl 2 H CHCl 2
OH CHCl
(a) (b) (c) (d)
OH
9. The reaction of CH3 CH CH OH with HBr gives
Br
(a) CH3 CHBrCH 2 OH (b) CH3 CH2 CH OH
Br
(c) CH3 CHBrCH 2 Br (d) CH3 CH2 CH Br
10. When benzene sulphonic acid and p-nitrophenol is treated with NaHCO3 , the gases released respectively are
(a) SO2 ,NO2 (b) SO2 ,NO (c) SO2 ,CO2 (d) CO2 ,CO2
_______________________________________________________________________________________________________________________________________________
SECTION - B
O
C H CH2OH
O O
11. 

Identify the reagents that can perform this conversion successfully
(a) H2 , Raney Ni (b) Mg,THF,H2O

O
||
(c) NaBH4 ,H2O (d) H  C  H , OH
12. The correct statement(s) about solvent effect is/are
(a) Decreasing solvent polarity causes a large increase in the rate of the SN2 attack by ammonia on an alkyl
 
RNH3  X
halide R  X  NH3 
(b) Increasing solvent polarity causes a large decrease in the rate of the SN2 attack by hydroxide ion on
trimethyl sulphonium ion.
HO  (CH3 )3 S   CH3OH  (CH3 )2 S
Trimethyl sulphoniumion DMS
(c) Increasing solvent polarity causes a small decrease in the rate of the SN2 attack by trimethyl amine on
trimethyl sulphonium ion
  
(CH3 )3 N (CH3 )3 S 
 CH3 N(CH3 )3  (CH3 )2 S
(d) All are incorrect.
_______________________________________________________________________________________________________________________________________________
N
13. CHCl3 
KOH
X  Y
H
X & Y are
N CHO N CHCl 2
H H
(a) X = (b) X =
Cl
Cl
N
N
(c) Y = (d) Y =
14. In the given reaction
CH3
 
t BuO K

B2H6 ,THF
 
H2 O2 ,NaOH
 
TsCl
  (Y)
(X)
The product ‘Y’ is
(a) Position isomer of X (b) Identical to X

(c) Chain isomer of X (d) An oxidation product of (X)
15. Which of the following reactions give alkylation product.
_______________________________________________________________________________________________________________________________________________
OH
 
(a) + 
H
(b) + 
H
(c) CH3COCl 

AlCl3
 (d) Me3CCOCl 
AlCl3

_______________________________________________________________________________________________________________________________________________
SECTIONC
Integer Answer Type
1. The sum of total stereoisomers and fractions on the fractional distillation of 2,3-Dichloropentane is
OH
HO OH

2. CH3  CHO  nHCHO 
OH

HO
in the preparation of final product if aldol formed is (x) then what is (x + n)?
3. Total no. of chiral centres present in the following compounds is
CH 2OH
O
H H
H
OH H
OH
O
H OH
CH 2OH
O
H H HO CH 2OH
OH H
_______________________________________________________________________________________________________________________________________________
4. Observe the following reaction and find out that how many number of reactant stereoisomers can be reduced to
optically inactive meso products
CHO
CHOH
CHOH
CHOH
CH 2OH
CHOH
(CHOH) 4
CH 2 OH
CH 2OH

NaBH4


5. How many CHI3 will be released from the given compound.
O O

I2 /NaOH

_______________________________________________________________________________________________________________________________________________
P
PA RTT –– IIIIII :: M
AR MAATTH
HEEM
MAATTIIC
CSS
SECTIONA
|x| |x|
1. Let f(x)  e{e sgn x}
and g(x)  e[e sgn x]
,x  R where { x } and [ ] denotes the fractional part and integral part
functions respectively. Also h(x)  ln(f(x))  ln(g(x)) then for all real x, h (x) is
(A) an odd function (B) an even function
(C) neither an odd nor an even function (D) both odd as well as even function
2. Which of the following function is surjective but not injective
(A) f : R  R f(x)  x 4  2x3  x2  1 (B) f : R  R f(x)  x3  x  1
(C) f : R  R f(x)  1  x 2 (D) f : R  R f(x)  x3  2x2  x  1
3. If f(x)  2x3  7x  5 then f 1(4) is
(A) equal to 1 (B) equal to 2 (C) equal to 1/3 (D) non existent
 x  b,x  0
4. The function g(x)   can be made differentiable at x = 0.
cos x,x  0
(A) if b is equal to zero (B) if b is not equal to zero
(C) if b takes any real value (D) for no value of b
d2 y dy
5. If y is a function of x then y  0 . If x is a function of y then the equation becomes
dx 2 dx
3
d2 x dx d2 x  dx 
(A) 2
x 0 (B) 2
 y   0
dy dy dy  dy 
2 2
d2 x  dx  d2 x  dx 
(C) 2
 y   0 (D) 2
 x   0
dy  dy  dy  dy 
_______________________________________________________________________________________________________________________________________________
6. Which one of the following statement is true?
(A) If Limf(x)  g(x) and Limf(x) exist, then Limg(x) exists.

x c x c x c
(B) If Limf(x)  g(x) exists, then Limf(x) and Limg(x) exist.

(C) If Lim(f(x)  g(x)) and Limf(x) exist, then Limg(x) exist.

(D) If Lim(f(x)  g(x)) exists, then Limf(x) and Limg(x) exist.

_______________________________________________________________________________________________________________________________________________
1 n  2 (n  1)  3 (n  2)  .....  n .1
2 2 2 2
7. Lim is equal to :
n 13  23  33  .....  n3
1 2 1 1
(A) (B) (C) (D)
3 3 2 6
x 2  bx  25
8. If f(x)  for x  5 and f is continuous at x = 5, then f (5) has the value equal to
x 2  7x  10
(A) 0 (B) 5 (C) 10 (D) 25
2x  23  x  6
if x  2
2 x  21 x
9. Let f(x)  then
x2  4
if x  2
x  3x  2
(A) f(2)  8  f is continuous at x = 2 (B) f(2)  16  f is continuous at x = 2
(C) f(2 )  f(2 )  f is discontinuous (D) f has a removable discontinuity at x = 2
x  ex  cos2x
10. If f(x)  ,x  0 is continuous at x = 0, then
x2
5
(A) f(0)  (B) [f(0)] = – 2 (C) {f(0)} = –0.5 (D) [f(0)] . {f(0)} = –1.5
2
where [x] and {x} denotes greatest integer and fractional part function
_______________________________________________________________________________________________________________________________________________
SECTION - B
1
11. The function f(x)  x ln x
(A) is a constant function (B) has a domain (0,1)  (e, )
(C) is such that Limf(x) exist (D) is aperiodic

x 1
12. The function f(x) = (sgn x) (sin x) is
(A) discontinuous no where. (B) an even function
(C) aperiodic (D) differentiable for all x
13. Which of the following function(s) has/have the same range?
1 1 1 1
(A) f(x)  (B) f(x)  (C) f(x)  (D) f(x) 
1 x 1  x2 1 x 3x
x 1
14. Let f(x)  . Then:
2x 2  7x  5
1 1
(A) Limit f(x)   (B) Limit f(x)   (C) Limit f(x)  0 (D) Limit does not exist
x 1 3 x 0 5 x  x 5/ 2
| x  3 | ,x  1

15. The function f(x)   x 2   3x   13  is :
  ,x  1
 4   2   4 

(A) continuous at x = 1 (B) diff. at x = 1
(C) continuous at x = 3 (D) differentiable at x = 3
_______________________________________________________________________________________________________________________________________________
SECTIONC
Integer Answer Type
(x  y  z)(xy  xz  yz)
1. Let f be the function defined by f(x,y,z)  for all positive real numbers x, y and z. The
xyz
smallest possible value of f, is
n
 1 
2. The value of lim   1  2n  is
n0  2 
n 
3. f(x)  | x  2 | 3 is not differentiable at number of points = ?
2
 x 
x
4. Evaluate : e
0
2
sin    dx
2 4
1 1 x x 1
5. Let f1(x)  x,f2 (x)  1  x;f3 (x)  ,f 4 (x)  ;f5 (x)  ;f 6(x) 
x 1 x x 1 x
Suppose that f6 (fm (x))  f4 (x) and fn (f4 (x))  f3 (x) then n is ________
_______________________________________________________________________________________________________________________________________________
FIITJEE COMMON TEST

Paper Code
CODE: Set- A XXXX.X
PHASE TESTI (PAPER1)

ANSWER KEY WITH Concept Code
PART – I (PHYSICS) PART – II (CHEMISTRY) PART –III (MATHS)
SECTIONA SECTIONA SECTIONA
Q.N. Ans. Con. Code Q.N. Ans. Con. Code Q.N. Ans. Con. Code
1. B P120212,213 1. B C121201 1. A M120321
2. B P120103 2. C C121207 2. D M120308
3. B P120108 3. B C121202 3. A M120311
4. B P120113 4. D C121207 4. D M120311
5. C P120306 5. D C121203 5. C M120516
6. A P120114 6. D C121206 6. C M110602
7. A P120302 7. A C121206 7. A M110611
8. D P120303 8. D C121205 8. A M120404
9. D P120115 9. B C121202 9. C M120401
10. A P120113 10. D C121205 10. D M120404
SECTION-B SECTION-B SECTION-B
11. ABCD P120205,206 11. CD C121206 11. ABC M120319
12. AD P120305 12. BC C121202 12. ABC M120322
13. AC P120114 13. AC C121206 13. BC M120317
14. ABD P120207 14. A C121202 14. ABCD M110602
15. ABD P120305 15. ABD C121206 15. ABC M120408
_______________________________________________________________________________________________________________________________________________
SECTION –C SECTION -C SECTION -C
1. 2 P120105 1. 6 C121202 1. 9 M120323
2. 1 P120305 2. 7 C121206 2. 2 M110606
3. 1 P120114 3. 9 C121209 3. 3 M120410
4. 2 P120216 4. 4 C121209 4. 0 M120701
5. 7 P120302 5. 0 C121206 5. 5 M120323
_______________________________________________________________________________________________________________________________________________
HINT & SOLUTIONS-PHYSICS
SECTION – A CPT1-1 SET-A
(Single Correct Choice Type)
R1  R2 5
1. Req of the circuit =  R3 A V
R1  R2 R1
R2 R3
15 1.25
5  15 125 75 5
=     5
5  15 100 20 4
20V
E 20
I  =4A
Req 5
IR2
Current in R1   3A
R1  R2
P.D. across R3  IR3  5V
 (b)
2. There will be no loss of energy if the potential of the spheres is the same i.e. if
q Q q Q
V  or 
40r 40R r R
 (b)
3. Net flux in x-direction = 0

y
Net flux in y-direction  A[3(1)2  2]  A[3(0)  2]
q
  3A x
0
 q  3 0 A  3 0 , (as A  1 m2 ) z
(b)
p
4. The electric field due to the dipole on the circumference of the ring E  and it is directed normal to the
40R3
plane of charged ring.
pq
Hence force on the charged ring F  qE 
40R3
 (b)
5. Force on the conductor ABC A A
 10A 
= Force on the conductor AC 10A × B × B
3cm 3cm 
–2
= 5 × 10 × (5 × 10 ) = 2.5 N F
B 4cm C B 4cm C
 (c)
6. (A)
_______________________________________________________________________________________________________________________________________________
as the potential difference across dielectric of dielectric constant 2 & 4 is not same.
K3  6 d K3  6 K3  6
K1  2 K2  4 d K1  2 K2  4
w w
7. (A)
8. (D)

 B.d   (i
0 1  i3  i2  i3 )  0 (i1  i2 )
Since for the given direction of circulation i3 entering at PSTU is positive while i3 at PQRS is negative]
9. (D)
 
10. Assuming ring as dipole, then dipole moment P and E are in same direction, so potential energy U = –PE
 (A)
20  10
11. S1  closed , S2  opened , i  = 2.5 A
4
20
S1  opened, S2  closed , i  A
3
20  10 5
S1 and S2 both open , i   A
6 3
S1 and S2 both closed, i = 20 A
 (a) (b) (c) (d)
12. For frame F1, the charge Q is at rest and for frame F2, the charge Q is in motion. Charge at rest or in motion
produces electric field. So both A and B will observe electric field.
Hence, choice (a) is correct.
Only moving charges produces magnetic field. So B will observe magnetic field but A will not observe any
magnetic field.
_______________________________________________________________________________________________________________________________________________
Hence, choice (d) is correct and choices (b) and (c) are wrong.
 (a) and (d)
1 0 AV02
13. Initial stored energy Ui 
2 x
1 0 AV02
Final stored energy Uf 
2 (x  dx)
1  1 1
so U  Uf  Ui  0 AV02   
2  x  dx x 
1  x  x  dx  1 0 AV02 1  AV 2 dx Udx
 0 AV02    dx   0 0 . 
 x(x  dx) 
2
2 2 x 2 x x x
dU U
So, choice (a) is correct and choice (b) is wrong. F 
dx x
1 0 A V02 1  A  V 1
F .    0 .V0  . 0   qE
2 x x 2 x  x 2
1
So magnitude of attractive force is qE.
2
So, choice (c) is correct and choice (d) is wrong.
 (a) and (c)
20 5
14. VA  VD  VA  VC or 20i  5 I  i or i = I/5
C
A B
2I I D
 I  2i  I   5
5 5 20
20 i C 5 1-i
Current flowing from D to C.
 (a) (b) (d) A 1-2i B
5 D 20
15. (a) (b) (d)
SECTION–C
(Integer Type)
1. Since potential is decreasing, so q 1 is +ve and q 2 is –ve
Kq1 Kq2 q1 2
 ,  , q1 : q2  2 : 1
 a  a q2 1
  
3   3 
a a

_______________________________________________________________________________________________________________________________________________
L       
2. sin300 
300   r   

r
       2m/s
1 L
 r
       300
2  mv 0 
 qB        
 
2m/s       
mv 0 2 2       
L   1m  L=1
2qB 2  1 2       
X=0 X=L
2q1L 2q2 x 2q3 (2L  x) I

3.   0 … (i)
2A 0 2A 0 2A 0
+q1 +q2 –q3 +q
dq dq3 dq2 3
I 1   … (ii) –q1 –q2
dt dt dt
From (i), q1L  q2 x  2q3L  q3 x  0 v
L x 2L–x
dq1 dq dx dq dq dx
 L  x 2  q2  2 3 L  x 3  q3 0
dt dt dt dt dt dt
v
 I (q2  q3 ) = 1 mA
3L
4. Let at any time t charge flown through the plate B to plate A is q and instantaneous current is I.
–Q0+q –q
A B
I
R 
 2q  Q0 
From loop theorem    IR    0
 2C 
dq 2q  2C  Q0
 R 
dt 2C
dq dt
 
2C  Q0  2q 2RC
Now for charge on plate A to be zero q = Q0.
Q0 t
dq dt
Integrating 
0

2C  Q0  2q 0 2RC
 2C  Q0 
= t  RCln  
 2C  Q0 
Putting the value of C, Q0,  and R
We get t = 2 seconds.
_______________________________________________________________________________________________________________________________________________
 INln (b / a)
5. B= 0  7 T ;
2(b  a)
Chemistry  Hint and solutions
SECTION – A
1. (B)
 
2. (C) CH2  CH  CH2  N  C
3. (B)
4. (D) Acid character
NO 2 Cl CH3 OCH 3
> > > >
COOH COOH COOH COOH COOH
5. (D)
6. (D) This is abnormal benzoin.
-
O O OH
  -
H Exchange
H    
CN
C C H C
O O O
CN CN
- -
O OH O
-
C H C C H
O + O O
+ CN 
 HO C CN
H  Exchange
_______________________________________________________________________________________________________________________________________________
O
C CH  CN
 
O O
OH
7. (A)
Sol. This is retro aldol
O O O
O
-
- CH3 C CH
OH
OH 
 O 
 
Intramolecular
aldol
 H2 O
CH2 OH
CH2
C O O
CH3
8. (D)

CHCl3  OH HOH : CCl3 
  Cl  : CCl2
- - -
OH O O O OH
CHCl 2 CHO CHO
 

OH
 
:CCl2
 
2NaOH
H2 O
 
H
2NaCl
 +
9. (B) CH3 CH CH OH 
H
CH3 CH2 CH OH
Stable Carbocation
10. (D)
11. (C,D)
_______________________________________________________________________________________________________________________________________________
12. (B,C) Polar forms are more stable in polar solvents.
13. (A, C)
Sol. CHCl3  OH 

CCl
2
Cl Cl
  Cl

OH
 
 CCl2
 

N
N N
(Y)
H
Cl
Cl 
& 
 H 
H

KOH

CHCl 2 CHO
N N CCl 2 N N
H H
(X)
14. (A)
CH3 CH3
CH3 CH3

(i)B2H6 ,THF H 

Tscl

 t BuO
(ii)H2O2 ,NaOH H H H
H
OH
OTs
syn addition Anti elimination
TsOh+t BuOH+
15. (A,B,D)
OH
Sol. (a) + 
 (b) + 

_______________________________________________________________________________________________________________________________________________
COCH 3
(c) + MeCoCl 
 CMe3

 CO
(d) Me3C  COCl 
3
Me3C  CO 
AlCl
Me3C 

SECTION–C
(Integer Type)
CH3 CH3 CH3 CH3

H Cl Cl H H Cl Cl H
H Cl Cl H Cl H H Cl
1. (6) + + +
CH2CH3 CH2CH3 CH2CH3 CH2CH3
I II III IV
Fractional Distillation
(I+II) III & II
st nd
Fraction 1 + Fraction II
2. (7) CH3CHO  OH 

H2O
  CH2  CHO
OH
OH O HO
C CHO
O H C CH 2 C H
H C O
+ CH2 C H→ H Aldol 
repeat infor 2more timer

H OH
Aldol
OH
HO
_______________________________________________________________________________________________________________________________________________
OH West Bengal - 713216. Ph : 03432542642, 03436450238, 9679997745
FIITJEE Limited, DURGAPUR CENTRE: A-3, Nandalal Bithi, City Centre, Durgapur,
National Admissions Office : FIITJEE Ltd., FIITJEE House, 29-A,
HOKalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph-46106000, 26569493, Fax 26513942
HCO 
HCHO
Cannizaro reaction
So, 3-Aldol & 4 HCHO
3+ 4 =7
3. (9) CH 2OH
* O
H H
H
* *
OH H
OH * *
O
H OH
CH 2OH
O
* *
H H HO CH 2OH
*
*
OH H
_______________________________________________________________________________________________________________________________________________
4. (4)
CH 2OH
CHO
H OH
H OH
H OH
H OH
H OH
H OH
H OH
H OH


NaBH4
CH 2OH
CH 2OH
(I) Meso
()
CHO CH 2OH
H OH H OH
HO H HO H
HO H HO H
H OH H OH
CH 2OH CH 2OH
(II) Meso


_______________________________________________________________________________________________________________________________________________
()
So, in total 4 stereoisomers are reduced to meso products.
5. (0)
MATHS  Hint and solutions
SECTION – A PAPER - 1
1. h(x)  ln(f(x)  g(x))  lne{y}  {y}  {y}  [y]  y  e|x| sgnx
e x if x  0

 h(x)  e|x| sgn x  0 if x  0
 e  x if x  0

e x if x  0

h(  x)  0 if x  0
 e x if x  0

h(x)  h(x)  0 for all x
2. (A) f(x)  x 4  2x3  x2  1 → A polynomial of degree even will always be into say
f(x)  a0 x2n  a1x2n1  a2 x 2n2  .....  a2n
 a a a    if a0  0
Limit f(x)  Limit [x 2n  a0  1  22  .....  2n 
x  x 
 x x x 2n    if a0  0
Hence it will never approach  / 
(B) f(x)  x3  x  1  f '(x)  3x 2  1 - injective as well as surjective

_______________________________________________________________________________________________________________________________________________
(C) f(x)  1  x  neither injective nor surjective (minimum value =1)
2
f(x)  x3  2x2  x  1  f '(x)  3x2  4x  1  D>0
Hence f(x) is surjective but not injective.
3. Note that f is bijective hence f 1 exist
When y  4
2x3  7x  9  0
2x2 (x  1)  2x(x  1)  9(x  1)  0
(x  1)(2x2  2x  9)  0
x  1 only  A ; as 2x2  2x  9  0 has not other roots.
cosh 1
4. g'(0 )  lim 0
h 0 h
h  b  1
g'(0 )  lim for existence of line b  1 thus g'(0)  1
h 0 h
Hence g can not be made differentiable for any value of b.
d2 y dy
5. Given 2
y 0
dx dx
   
dy 1 d2 y d  1  d  1  dy 1 d2 x 1
now         .   . .
dx dx dx 2 dx  dx  dy  dx  dx 2
 dx  dy dx
2
 dy   dy   
dy      dy 
dy
d2 x
d2 y dy 2
 (putting in (1))
dx 2  dx 
3
 
 dy 
d2 x
 2
d2 y dy  dx  d2 x
3
y 0  y   2  0 C
 dx  dx  dy  dy
 
 dy 
_______________________________________________________________________________________________________________________________________________
6. (A) This is false . f(x)  x;g(x)  cosecx
now lim f(x)  g(x) exists =1 also Limf(x)  0 exist but Limg(x) does not exist.
x 0 x 0 x c
 1 if x  0
(B) This is false. Let f be defined as f(x)   . Let g(x)  0 . Then, f(x)g(x)  0 , and so
2 if x  0
Limf(x)  g(x) exits, while Limf(x) does not.
x 0 x 0
(C) This is true. Notice that g  (f  g)  f. Therefore, by the limit theorem,
Lim g(x)  Lim(f(x)  g(x))  Limf(x)

(D) This is false.
12 n  22 (n  1)  32 (n  2)  .............  n2 (n  (n  1))
7. lim
n
 n3
Nr  n(12  22  ....n2 )  (1.22  2.32  3.42  ......  (n  1)n2 )
n
 n n2   (r  1).r 2
r 2
n
 n n2   (r 3  r 2 )  n n2   n3   n2 
r 1
(n  1) n2   n3
 (n  1)n2  n3    Lim
n 
n 3
(n  1)n(n  1)(2n  1)
lim 1
n   6n(n  1)n(n  1) 
 
 4 
4 1
1 A
3 3
12 n  22 (n  1)  .....  n2 .1 12 (n  1)  22 (n  1)  .....  n2 (n  1)
Alternatively   1 1  1
1  2  3
3

3 2
.....  n3
  n3
(n  1) n2
l 1
n 3
x 2  bx  25
8. f(x)  . for existence of limit 25  5b  25  0  b  10
(x  2)(x  5)
(x  5)(x  5)
now f(x)  and Limf(x)  0  (A) s
(x  2)(x  5) x 5
_______________________________________________________________________________________________________________________________________________
9. f(2 )  8; f(2 )  16
x  ex  1  (1  cos2x) 1 5 5
10. Lim 2
  2   ; hence for continuity f(0)  
x 0 x 2 2 2
 5 1 3
 [f(0)]  3; {f(0)}     hence [f(0)]{f(0)}    1.5
 
2 2 2
SECTION-B
11. y  xlogx e  e (constant)  A and C
as Limf(x)  e
x 1
 sin x x  0
12. f(x)  
  sin x x  0
13. Domain is R  {1}; Range = R  {0}
Domain is x  R; Range  (0,1]
Domain is [0, ); Range  (0,1]
Domain is ( ,3); Range  (0, )]
14. (A,C,D)

x  3 if x  3

15. f(x)  3  x if 1  x  3
 2
 x  3x  13 if x  1
 4 2 4
f(1  h)  f(1) 3  (1  h)  2
f '(1 )  Limit  Limit  1
h0 h h0 h
_______________________________________________________________________________________________________________________________________________
(1  h)2 3 13
 (1  h)  2
(1  h)2  6(1  h)  5
f '(1 )  Limit 4 2 4  Limit
h 0 h h 0 4h
h2  2h  6h
 Limit  1
h 0 4h
 f is continuous at x=1
SECTION–C
(Integer Type)
(x  y  z)(xy  xz  yz)  1 1 1 x y y z z x
1. f(x,y,z)   (x  y  z)      3            
xyz x y z y x z y x z
 f(x,y,z)min  9 ]
 1  1  1  1   1  1
 1  2  1  2  1  2   1  22  .....  1  2n  1  nn1
2. lim    2  2   2   lim 2  2 Ans. ]
n   1 n 
1
1
1  2 
  2
3. -1 2 5
x 
2x x
x
4. I e
0
2
sin    dx
2 4
put
2
t
  
    
I  2 et sin  t   dt  2 et  sint cos  cos t sin  dx  2  et (sint  cos t)dt
0  4  0  4 4  0

 2 et sint   0 Ans.]
0
x 1
5. Given f6 (x)  ……….(1)
x
1
f6 (fm (x))  f4 (x)  (given)
1 x
fm (x)  1 1 x 1
 f6 (fm 9x))   (using given relation f6 (x)  )
fm (x) 1 x x
_______________________________________________________________________________________________________________________________________________
Put fm (x)  k
k 1 1

k 1 x
x 1 x 1
k  kx  1 x  k  k  fm (x)   f6 (x)  m=6
x x
1
again fm (f4 (x))  f3 (x) 
x
 1  1 1 t 1
fm    ; let t  t  tx  1  x
 1 x  x 1 x t
t x
 fm (t)   fn (x)   f5 (x)
t 1 x 1
Hence n  5 Ans.]
FIITJEE
CPT1 - 2 CODE: Set - A PAPER - 2

BATCHES – 1214
 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
_______________________________________________________________________________________________________________________________________________
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
before attempting the paper. Wrong CODE or no CODE will give wrong results.
C. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into one section: Section-A
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided for
rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices, in
any form, are not allowed.
D. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment No. and
write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.
(i) Section-A (01 – 08) contains 8 multiple choice questions which have only one correct answer. Each question
carries +3 marks for correct answer and – 1 marks for wrong answer.
Section-A (09 – 14) contains 3 paragraphs. Based upon paragraph, 2 multiple choice
questions have to be answered. Each question has only one correct answer and carries +3 marks for correct
answer and – 1 mark for wrong answer.
Section-A (15 – 20) contains 6 multiple choice questions which have one or more than one correct
answer. Each question carries +4 marks for correct answer. There is no negative marking.
_______________________________________________________________________________________________________________________________________________
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
_______________________________________________________________________________________________________________________________________________
Useful Data Chemistry:
Gas Constant R = 8.314 J K1 mol1
= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56, Mn=55,
Pb=207, Au=197, Ag=108, F=19, H=2, Cl=35.5, Sn=118.6
Useful Data Physics:
Acceleration due to gravity g = 10 m / s2
_______________________________________________________________________________________________________________________________________________
P
PA RTT –– II :: P
AR PHHY
YSSIIC
CSS
SECTIONA
of which ONLY ONE is correct.
1. A point charge + q is fixed at point B. Another point charge + q at A of +q A

mass m vertically above B at height h is dropped from rest. Choose the
correct statement h
(a) It will collide with B
(b) It will execute S.H.M +q B
2
q 2
(c) It will go down only if < mgh
40
(d) go down up to a point and then come up.
2. In the given diagram, the potential difference between A and Q0 Q0

B is V1, when switch is open. The potential difference + – S – +
between A and B when switch is closed is V2. Then A + – – + B
+ – – +
+ – C – + 2C
Q0 Q
(a) V1  , V2  0 (b) V1  zero , V2  zero
2C C
Q0 Q0 Q
(c) V1  , V2  zero (d) V1  , V2  0
2C 2C 2C
3. There is a uniform magnetic field perpendicular to the       

plane of paper. A positive charged particle enters in the   Q O N   
region, perpendicularly and collides inelastically at point Q M
to the rigid wall MN. If Co-efficient of restitution e = ½ then  
 a/2  a/2   
particle a
      
(a) Retraces its path (b) Strikes at point O
      
(c) Strikes at point M (d) strikes at point N
_______________________________________________________________________________________________________________________________________________
4. The potentiometer wire AB is 600 cm long. At what distance E r
from A should the jockey J touch the wire to get zero deflection
in the galvanometer?
R=15r
A B
J
(a) 320 cm (b) 120 cm
G
(c) 20 cm (d) 450 cm E/2 r
5. A miliammeter of range 10mA and resistance 9  is joined in a 9 ,10mA

circuit as shown. The meter gives full scale deflection for current I
when A and B are used as its terminals, i.e. current enters at A and
leaves at B (C is left isolated). The value of I is 0.1 0.9
(a) 100 mA (b) 900 mA
(c) 1 A (d) 1.1 A
A B C
6. A capacitor of capacitance ‘C’ is connected with a battery of emf ε as shown. After full charging a dielectric of
same size of capacitor and dielectric constant k is inserted then choose correct statements. (capacitor is always
connected to battery) C
(a) electric field between plates of capacitor remain same
(b) charge on capacitor is Cε
(c) energy on capacitor decreased 
(d) electric field between plates of capacitor increased.

7.  
The electric field in a region is given by E  4iˆ  ˆj N/C. Work done by this field is zero when a particle is
moved along the line
(a) y + 4x = 2 (b) 4y + x = 6 (c) x + y = 5 (d) x – y = 5
8. The time constant of an RC circuit shown in the figure is

(a) 0 (b) 2/3 RC E R
(c) 6RC/5 (d) 2 RC C

R
_______________________________________________________________________________________________________________________________________________
SECTIONB
Comprehension Type
This section contains 3 paragraphs. Based upon each paragraph 2 multiple choice questions have to be
answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
Paragraph for Question 9 to 10
Read the paragraph carefully and answer the following questions:
A hollow cube of side L has two parallel sides conducting and L

remaining four sides are non-conducting. It is filled with a liquid of
dielectric constant k. A small hole of area A at the bottom of the
cube is opened at t = 0 and liquid starts leaking through it. The two
conducting sides are connected by a battery of emf .
18 2
(Take: L = 9 m, A  m , k = 10,  = 81 V, g = 10 m/s )
2
20
9. The capacitance of the capacitor as a function of time is

0 2 0 2
(a) (t  54t  64) (b) (t  54t  810)
9 9
0 2 0 2
(c) (t  54t  810) (d) (t  54t  64)
9 9
10. The current through the connecting wire as a function of time is

0
(a) 0 (54  2t) (b) 9 0 (54  2t) (c) 9 0 (54  2t) (d) (54  2t)
9
_______________________________________________________________________________________________________________________________________________
A charge particle of charge 1C and mass 10gm is moving with  

B E A
velocity 10 iˆ m/s in horizontal plane consisting of magnetic field –
A
3   
0.1 k̂ T of width m and electric field –0.1 ĵ N/C of width d.
2   
Particle enters the magnetic field at t = 0 perpendicularly and 
  
follows the path as shown in the figure and strikes the wall AB
perpendicularly at A (neglect gravity) y   
O x
  
B
3 d
m
2
11. The time t after which it strikes the wall
(a) 1.2 s (b) 0.97 s (c) 1.07 s (d) 1.98 s
12. Taking O as origin y-coordinate of A will be
(a) 3.75 m (b) 0.50 m (c) 4.25 m (d) 3.25 m
A capacitor of capacitance C  0.1F is charged by a battery of 100V 1

e.m.f. E1 = 100 V and internal resistance r1 = 1  by putting switch
S in position 1 as shown in figure. E1 r1
0.1F 99 1
R
2
50V 1
E2 r2
13. Find out heat generated in R = 99 till steady state

(a) 500 J (b) 495 J (c) 1000 J (d) 485 J
14. Now switch is thrown to position 2. Find the work done on the battery till steady state
(a) 250 J (b) 300 J (c) 275 J (d) 325 J
_______________________________________________________________________________________________________________________________________________
SECTIONC
Multiple Correct Answers Type
This section contains 6 multiple correct answer(s) type questions. Each question has 4 choices (A), (B), (C) and
(D),
15. A charged particle enters a region which offers some resistance against its
motion and a uniform magnetic field exists in the region. The particle traces
a spiral path as shown. Then:
(a) angular velocity of particle remains constant
(b) speed of particle decreases continuously
(c) total mechanical energy of the particle remains conserved
(d) net force on the particle is always perpendicular to its direction of motion
16. Four charges, all of the same magnitude, are placed at the four corners of a square. At the centre of the square,
the potential is V and the field is E. By suitable choices of the signs of the four charges, which of the following
can be obtained?
(a) V = 0, E = 0 (b) V = 0, E  0
(c) V  0, E = 0 (d) V  0, E  0
17. In the network shown, points A, B and C are at potentials of 70 V, zero and 10 V respectively.
B(0 V)
(70 V) 10  20 
A
D
30 
C (10 V)
(a) Point D is at a potential of 40 V.

(b) The currents in the sections AD, DB, DC are in the ratio 3 : 2 : 1
(c) The currents in the sections AD, DB, DC are in the ratio 1 : 2 : 3
(d) The network draws a total power of 200 W
_______________________________________________________________________________________________________________________________________________
18. In the circuit shown in figure C1  C2  2μF . Then charge stored in
1 2 3
(a) capacitor C1 is zero
C1 C2
(b) capacitor C2 is zero
(c) both capacitors is zero 2 1 3
(d) capacitor C1 is 40 C
120V
19. Figures shows the lines of force of the electric field of a positive charge (+q) and a negative charge (-q)
respectively.
Which of the following statements are correct?
Q B
+q P –q A
O O
(a) (b)
(a) potential at P is greater than that at Q.

(b) potential at A is greater than that at B.
(c) potential energy at P is less than that at Q
(d) potential energy at A is greater than that at B.
+ + ++
20. H , He and O ions having same kinetic energy pass through a region of space filled with uniform magnetic
+ + ++
field B directed perpendicular to the velocity of ions. The masses of the ions H , He and O are respectively in
the ratio 1 : 4 : 16. As a result
+
(a) H ions will be deflected most
++
(b) only O ions will be deflected least
+ ++
(c) He and O ions will suffer same deflection
(d) All ions will suffer the same deflection
_______________________________________________________________________________________________________________________________________________
P
PA RTT –– IIII :: C
AR CHHE
EMMIIS
STTR
RYY
SECTIONA
1. Compound A (molecular Formula C3H8O) is treated with acidified K 2Cr2O7 to form a product B (MF  C3H6O) . B
forms a shining silver mirror on warning with ammonical AgNO3 . B when treated with an aqueous solution of
H2NCONHNH2 . HCl and sodium acetate gives a product C. Identify the structure of C.
(a) CH3CH2CH  NNHCONH2 (b) CH3 C NNHCONH 2
CH3
(c) CH3 C NCONHNH 2 (d) CH3CH2CH  NCONHNH2
CH3
2. CH3NH2  CHCl3  KOH 

 Nitrogen containing compound is
 
(a) CH3  C  N (b) CH3  NH  CH3 (c) CH3  N  C (d) CH3 N  C
3. Among cellulose, poly (vinyl chloride), nylon and natural rubber, the polymer in which the intermolecular force of
attraction is weakest is
(a) Nylon (b) Poly (vinyl chloride) (c) Cellulose (d) Natural rubber.
4. The two forms of D-glucopyranose obtained from the solution of D-glucose are called.
(a) Isomers (b) Anomers (c) epimers (d) enantiomers
5. The product of acid hydrolysis of P and Q can be distinguished by

OCOCH 3 CH3
P→ H2C Q→
CH3 OCOCH3
(a) LUCAS Reagent (b) 2, 4 –DNP

(c) Fehling’s solution (d) NaHSO3
_______________________________________________________________________________________________________________________________________________
6. Which of the following is true for SN1 when solvent is 50% water & 50 % acetone.
Cl
(a) Ph Cl > Cl > > Cl
Cl
(b) > Ph Cl > > Cl
Cl
Cl
Cl Cl
(c) > > Ph Cl >
Cl
Cl Ph Cl
(c) > > > Cl
 CH3 COONa
7. Me CHO + (X) H3 O
 Me CH CHCOOH
The compound (X) is
(a) CH3COOH (b) BrCH2  COOH (c) (CH3CO)2 O (d) HC  C  COOH
8. When propionic acid is treated with aq NaHCO3 ,CO2 is liberated. The carbon of CO2 comes from
(a) Methyl group (b) Carboxylic group (c) Methylene group (d) bicarbonate
_______________________________________________________________________________________________________________________________________________
SECTIONB
Comprehension Type
A water insoluble organic mixture contained following compounds.
1. Benzoic acid
2. Salicylaldehyde
3. p-hydroxybenzaldehyde
4.   Naphthylanine
5. Naphthalene
The following sequence of reagents are used to separate this mixture
1+2+3+4+5
(step X) aq HCl
[Insoluble] [soluble]*
(step-Y) aq NaHCO3
[Insoluble] [soluble] *
(step-Z)
aq NaOH
[Insoluble]*
[soluble]
_______________________________________________________________________________________________________________________________________________
(step-W) Steam distillation
[distilled]* [left behind]
Fill up the serial No. of starred comp. obtained in steps X, Y, Z, W respectively and answer the following
questions
X Y Z W
_______________________________________________________________________________________________________________________________________________
9. Soluble compound at step – Y is
(a) Benzoic acid (b) p-hydroxybenzaldehyde

(c)   naphthylamine (d) Naphthalene
10. Insoluble compound at step-Z is
(a) p-hydroxybenzaldehyde (b) Salicylaldehyde

(c)   Naphthylamine (d) Naphthalene

Observe the esterificaiton mechanisms for primary and tertiary alcohols.
O
||
Type- 1 CH3 COOH  CH3CH2  CH2  OH 
 CH3  C OCH2  CH2  CH3
conc.H2 SO4
OH
O +
OH OH CH 3 C OH
+ 
pr  O H +
CH3 C
Mechanism : CH 3 C OH 
H
step I
 OH  CH3 C 
step  2
 O
OH
Pr H
O
Step  3
CH3 C OCH2 CH2 CH3 
H

H2 O
Type – 2
O CH3 CH3
CH3 C + CH 3 C OH 
conc. H2SO4
 CH3 C O C CH3
OH
CH3 CH3 O
Mechanism
CH3 CH3

OH   CH 3
H
CH 3 C Step 1 C+ + H2O
CH3 CH3
CH3 C O H
O
CH3
CH3 C O C CH3
CH3 O
_______________________________________________________________________________________________________________________________________________
18
11. CH3COOH  C2H5OH 
conc. H2SO4
(P)
18
CH3COOH  (CH3 )3 C  OH 
conc.H2 SO4
(P)
In the above reactions (P) & (Q) are respectively
O O CH3
18
(a) CH3 C OC2H5 , CH3 C O C CH3
CH3
O O CH3
18
(b) CH3 C OC2H5 , CH3 C O C CH3
CH3
O O CH3
18
(c) C2H5 C O CH3 , CH3 C O C CH3
CH3
O O CH3
18 18
(d) CH3 C O C2H5 , CH3 C O C CH3
CH3
H
CH3COOH  D OH  (X)
conc.H SO
12. 2 4
CH3
CH3
CH3COOH  Ph OH  (Y)
conc.H2SO4
C
C 2H 5
(a) (X) solution is optically active while (Y) solution is optically inactive
(b) Both (X) & (Y) solutions are optically active
(c) Both (X) & (Y) solutions are optically inactive
(d) (X) solution is optically inactive while (Y) solution is optically active
_______________________________________________________________________________________________________________________________________________
Read the following reaction sequence

NaOEt / 

H
P 
Cl2
hv
 Q  R 
NBS
 S 
NaOH
T
Then answer the following question.

13. Compounds ‘T’ is
OH OH OH OH
(a) (b) (c) (d)
HO OH
OH
OH
14. When ‘S’ is treating with strong base, product obtained is
OH OH OH OH
(a) (b) (c) (d)
Br
_______________________________________________________________________________________________________________________________________________
SECTIONC
(D),
15. The correct statement(s) about the following reaction sequence is/are
conc.HNO3  conc.H2 SO4 , NH2  NH2 ,


Cl2 /FeCl3
1
 
Conc.HNO3 /Conc.H2 SO4
2
  3
(P)  4
(Q) 
(R)
5

O 2N
CH N NH NO 2
(a) ‘R’ gives an aldol condensation reaction on heating with NaOH solution
(b) The compounds ‘Q’ gives a yellow p.pt in acetone
(c) step (4) is an aromatic nucleophillic substitution reaction
(d) the end product is a mixture of three compounds.
16. Which of the following products is/are correctly mentioned in the following reactions
(a) HCHO 
NaOD
HCOONa  CH3OD
(b) HCDO 

NaOH
DCOONa  CH2DOH
(c) HCDO 

NaOEt
DCOOEt  DCH2ONa
(d) D2CO 

NaOD
DCOONa  CD3OD
17. trans-2-methyl cyclohexanol + acetyl chloride 

X

X  NaOH(aq)   Y  sodium acetate
(a) X is CH3 H (b) X is H H
H OCOCH3 CH3 OCOCH3
(c) Y is H H (d) Y is CH3 H
CH3 OH H OH
_______________________________________________________________________________________________________________________________________________
18. The correct statements about peptides are
(a) A dipeptide has one peptide linkage between two amino acids.
(b) By convension N-Terminus is kept at left and C-terminus at right in the structure of a peptide.
(c) If only one amino acid is available for reaction, than only one dipeptide can be formed.
(d) A polypeptide with more than hundred amino acid (mol. Mass > 10,000) is called a protein
19. Salicin (structure given below) is a glycoside, found in the bark of willow tree, used in relieving pain.
Observe the following reaction of salicin.
CH 2OH
O CH 2OH
H O
H
OH H
OH
H OH

dil HCl
P Q
Carbohydrage
The correct statement(s) is (are) :
(a) P is D-Glucose
(b) Q is 2-hydroxybenzyl alcohol
(c) Q can be converted to a modern analgesic (pain-killer), aspirin
(d) The above reaction occurs through a carbocation
20. Lysine a amino acid has pKa1  2.18, pKa2  8.95, pKa3  10.53
The isoelectric point of Lysine will be
(a) 6.35 (b) 9.74 (c) 2.77 (d) 10.76
_______________________________________________________________________________________________________________________________________________
P
PA RTT –– IIIIII :: M
AR MAATTH
HEEM
MAATTIIC
CSS
SECTIONA
tan1 x
1
1. 
0
x
dx 
/ 4 / 2 / 2 / 4
sin x x 1 x 1 x
(A)  0
x
dx (B) 
0
sin x
dx (C)
2 
0
sin x
dx (D)
2 
0
sin x
dx
 4
2
2. The set of values of 'a' which satisfy the equation  (t  log
0
2 a)dt  log2  2  is
a 
(A) a  R (B) a  R (C) a  2 (D) a  2
x
3. The value of the function f(x)  1  x   (ln2 t  2ln t)dt where f’ (x) vanishes is :
1
(A) e 1 (B) 0 (C) 2e1 (D) 1 + 2 e 1
(2x  1)
4.  (x 2
 4x  1)3/2
dx
x3 x
(A) C (B) C
(x 2  4x  1)1/2 (x  4x  1)1/2
2
x2 1
(C) C (D) C
(x  4x  1)1/2
2
(x 2  4x  1)1/2
x4  x2  1 dy
5. If y  and  ax  b then the value of a + b is equal to
x  3x  1
2
dx
5 5 5 5
(A) cot (B) cot (C) tan (D) tan
8 12 12 8

_______________________________________________________________________________________________________________________________________________
y"
6. If x2  y2  R2 (R  0) then k  where k in terms of R alone is equal to
 
3
1 y ' 2
1 1 2 2
(A)  (B)  (C) (D) 
R2 R R R2
t  3x  x 2
7. If the function f(x)  , where 't' is a parameter has a minimum and a maximum then the range of
x4
values of 't' is
(A) (0, 4) (B) (0,  ) (C) (–  , 4) (D) (4,  )
8. A particle moves along the curve y  x3/2 in the first quadrant in such a way that its distance from the origin
increases at the rate of 11 units per second. The value of dx/dt when x = 3 is
9 3 3
(A) 4 (B) (C) (D) none
2 2
SECTIONB
Comprehension Type
Read the paragraph carefully and answer the following questions:
1
If , (where    ) are the points of discontinuity of the function g(x)  f(f(f(x))), where f(x)  , and
1 x
P(a,a2 ) is any point on xy-plane.
9. The points of discontinuity of g(x) is
(a) x  0, 1 (b) x  1 only (c) x  0 only (d) x  0,1
10. The domain of f(g(x)) is
(a) x  R (b) x  R  {1} (c) x  R  {0,1} (d) x  R  {0,1, 1}
_______________________________________________________________________________________________________________________________________________
If f(x)  (x  )n g(x), then f '()  f "()  ....  f n1()  0 where f(x) and g(x) are polynomials.
For a polynomial f(x) with rational coefficients, answer the following questions.
11. If f(x) touches x-axis at only one point, then the point of touching is
(a) always a rational number (b) may or may not be a rational number
(c) never a rational number (d) none of these
12. If f(x) is of degree 3 and touches x-axis, then
(a) all the roots of f(x) are rational (b) only one roots is rational
(c) both (a) and (b) may be possible (d) none of these
 
1/2
Let us consider the integrals of the following forms f x, mx 2  nx  p
Case 1 : If m  0 , then put mx2  nx  p  u  x m
Case 2 : If p  0 , then put mx2  nx  p  ux  p
Case 3 : If quadratic equation mx2  nx  p  0 has real roots  and  there put mx2  nx  p  (x  )u or
(x  )u
dx
13. If I   to evaluate I, one of the most proper substitution could be
x  9x 2  4x  6
(a) 9x2  4x  6  u  3x (b) 9x2  4x  6  3u  x

1 1
(c) x  (d) 9x 2  4x  6 
t t
x  
15
1  x2
14.  1  x2
dx is equal to
x   x  
16 15
1  x2 1 15 1  x2
c c c c
   
(a) (b) (c) (d)
10 15 1  x2  x 1  x2  x 15
_______________________________________________________________________________________________________________________________________________
SECTIONC
(D),
15.  1  cosec x dx equals
(A) 2sin1 sin x  c (B) 2 cos1 cos x  c
(C) c  2sin1(1  2sin x) (D) cos1(1  2sin x)  c
16. A continuous and differentiable function ' f ' satisfies the condition ,
 f(t)dt  f (x)  1 for all real ‘x’. Then :

2
(A) ' f ' is monotonic increasing x  R
(B) ' f ' is monotonic decreasing x  R
(C) ' f ' is non monotonic
(D) the graph of y = f (x) is a straight line.
x
sint
17. Let f(x)   dt(x  0) then f (x) has :
0
t
(A) Maxima if x  n where n = 1, 3, 5,.....
(B) Minima if x  n where n = 2, 4, 6,......
(C) Maxima if x  n where n = 2, 4, 6,......
(D) The function is monotonic
2x 2  3x  3
1
18. The value of  (x  1)  x
0
2
 2x  2 
dx is :
  1
(A)  2ln2  tan1 2 (B)  2ln2  tan1
4 4 3

(C) 2ln2  cot 1 3 (D)   ln 4  cot 1 2
4
_______________________________________________________________________________________________________________________________________________
/ 2
sin5x
19. The value of the definite integral, 
0
sin x
dx is

(A) 0 (B) (C)  (D) 2
2
1 1
20. The extremum values of the function f(x)   , where x  R is :
sin x  4 cos x  4
4 2 2 2 2 4 2
(A) (B) (C) (D)
8 2 8 2 4 2 1 8 2
_______________________________________________________________________________________________________________________________________________
FIITJEE COMMON TEST

Paper Code
XXXX.X
CODE: Set - A
PHASE TESTI (PAPER2)

ANSWER KEY WITH Concept Code
PART – I (PHYSICS) PART – II (CHEMISTRY) PART –III (MATHS)
SECTIONA SECTIONA SECTIONA
Q.N. Ans. Con. Code Q.N. Ans. Con. Code Q.N. Ans. Con.
Code
1. C P120101 1. A C121206 1. C M120702
2. D P120105 2. D C121208 2. B M120704
3. D P120305 3. D C121211 3. D M120606
4. A P120208 4. B C121209 4. B M120702
5. C P120212 5. C C121206 5. B M120307
6. A P120214 6. B C121202 6. B M120516
7. A P120104 7. C C121207 7. C M120608
8. A P120216 8. D C121207 8. A M120508
SECTION B SECTION B SECTION B
9. B P120115 9. A C121212 9. D M120405
10. C P120115 10. D C121212 10. C M120316
11. B P120313 11. B C121207 11. A M120307
12. C P120313 12. A C121207 12. A M120318
13. B P120216 13. B C121203,204 13. A M120701
14. A P120216 14. B C121203,204 14. D M120705
_______________________________________________________________________________________________________________________________________________
SECTION –C SECTION –C SECTION –C
15. AB P120305 15. BC C121202,206 15. AD M120705
16. ABCD P120104,P120105 16. ABCD C121206 16. AD M120604
17. ABD P120207 17. AD C121203 17. AB M120607
18. BD P120205,P120215 18. ABCD C121210,211 18. ACD M120704
19. A P120105 19. ABCD C121209,205 19. B M120702
20. AC P120305 20. B C121210 20. AC M120612
HINT & SOLUTIONS-PHYSICS
SECTION – A
1. For charge + q at A to come down, Fe < mg
q2
  mg
40h2
 (c)
Q0
2. Charge flow is zero after closing the switch, so, V1  V2 
2C
 (d)
3. After collision velocity becomes v/2 so radius becomes a/2 and hence diameter is a and O will be the centre. So
particle strikes at point N.
 D
4. In case of zero deflection in galvanometer
E E  E  15r  E
VAJ  , iR AJ  ,  15r  r  600  AJ  2
2 2   
AJ = 320 cm
 (a)
_______________________________________________________________________________________________________________________________________________
5. 10  103  9.9  0.1 i  10  103 9 10mA
or I = 1A
0.1 0.9
 (c)
A B C
6. P.D. same and electric field same
 (a)
7. Work done will be zero when displacement is perpendicular to the field. The field makes an angle
 1
1  tan1   with positive x-axis
4
while the line y + 4x = 2 makes an angle
2  tan1  4  with positive x-axis
 1  2  900

i.e. the line y + 4x = 2 is perpendicular to E .
 (a)
8. (a)
Comprehension #1
 dy 
9. L2     A 2gy (y is height of liquid)
 dt 
y 1 t
 A
  y 2 dy  2g  dt
L L2 0
2
 A 2g t   t
2
y L    3  
 2L2   9
0 (L  y)L k 0 yL 
C  = 0 (L  y  ky) = 0 (t 2  54t  810)
L L 9
 (b)
dq
10. q  C , i   , i  9 0 (54  2t)
dt
 (c)
Comprehension #2
_______________________________________________________________________________________________________________________________________________
SOLUTION
In magnetic field A
mv R
R  1m R/2
qB 300 600
P
3
2m R/2 R
T  0.2  2 R/2
qB
In electric field O
qE
Acceleration a 
2
=10 m/s
m
v 2 sin2 
Now, PA '  maximum height   3.75m
2a
 y-co-ordinate of A ' is 4.25 m
 v sin  3
T '  time elapsed in E is half the time of flight  
a 2
T
 time t =  T '  0.97 sec
6
11. (b)
12. (c)
Comprehension #3
13. When switch in position 1 and steady state is reached

q0 = CE1 = 10 C
W1 = Energy supplied by battery = q0E1 = 1000 J
q2
Energy stored on the capacitor U1  0 = 500 J
2C
H1 = W1 – U1 = 500 J
99
H99   500 = 495 J
100
 (b)
14. Position (2), in steady state

q =5C
W2  E2 (q0  q) = 250 J
 (a)
Multiple Choice Questions
2m
15. Time period of revolution of particle in magnetic field is given by T 
qB
Since for a given particle, m and q are constant. So, in constant magnetic field T is constant
_______________________________________________________________________________________________________________________________________________
2
Angular velocity  
T
Hence, angular velocity of particle is constant.
Hence, choice (a) is correct.
Due to resistive force, particle experiences a retardation and an energy is lost during motion against it. Hence
speed and total mechanical energy, both decrease continuously.
Hence, choice (b) is correct and (c) is wrong.
Since, speed of electron is decreasing continuously, therefore it is experiencing a tangential retardation. It is

possible only when the component of resultant force opposite to the direction of motion has non-zero values.
This implies, net force on electron cannot be perpendicular to its direction of motion.
Hence, choice (d) is wrong.
 (a) and (b)
16. (a) (b) (c) (d)
17. Let VD be the potential of D, then
VA  VD VB  VD VC  VD
   0  VD = 40 V
10 20 30
70  40 40 40  10
Also, ratio of current in AD, DB and DC are : :
10 20 30
i.e. 3 : 2 : 1
Also total power network draws, P  I2R  200 W
 (a) (b) (d)
18. Now, potential difference across C1 is 20 V and across C2 is zero. 20V 40V 60V
 charge stored in C1 is 40 C and in C2 is zero. 1 C12 C2 3
 (b) and (d) 2 1 3

40V 20V 60V
120V
19. (a)
m 1 4 16
20. r  rH : rHe : r0  : :  1: 2 : 2
q 1 1 2
+
Radius is smallest for H , so it is deflected most
(a)(c)
_______________________________________________________________________________________________________________________________________________
HINT & SOLUTIONS-CHEMISTRY
SECTION – A CPT1-2 SET-A
1. (A)
2. (D)
3. (D)
4. (B)
5. (C)
6. (B) The stability of carbocation
3° > benzylic > 2° > 1°
7. (C) Perkin reaction
8. (D)
Comprehension #1
9. (A)
10. (D)
Comprehension #2
11. (B) P is by type 1, Q is type – 2
12. (A) X→ Type 1 , Y=Type-2
↓ ↓
Hence configuration racemic product
is retained is obtained.
Comprehension #3
13. (B)
14. (B)
+
OH
OH OH OH OH
+ Cl
+
H
(P) (Q)
_______________________________________________________________________________________________________________________________________________
Sol. 
 
Ring
 
 
 Cl2
hv
Expansion
-
EtO
OH OH OH
OH Br
(T) (S) (R)

NaOH
 
NBS

Multiple Choice Questions
15. (B,C)
16. (A,B,C,D) See mechanism of cannizaro reaction

17. (A,C)
18. (A,B,C,D)
Dipeptide is formed by iamide linkage b/w 2-amino acid moleculus.
_______________________________________________________________________________________________________________________________________________
19. (A,B,C,D)
CH 2OH CH 2OH
O CH 2OH O CH 2OH
+
H O H O
H H
H Cl
 H
OH H OH H
OH OH
H OH H OH
CH 2OH
CH 2OH
O CH 2OH
O
H
H H H OH
H
+
  D  Glucose 
H2O
 OH H +
OH H OH
OH OH
Q
H OH
H OH
  D  Glucose Carbocation
20. (B)
pKa2  pKa3 8.95  10.53
Pl    9.74
2 2
_______________________________________________________________________________________________________________________________________________
HINT & SOLUTIONS-MATHEMATICS
tan1 x
1
1. I dx x  tan ;dx  sec 2 d
0
x
/ 4 / 4 / 4
.sec 2   2
I 
0
tan 
d  
0
sin  cos 
d  
0
sin2 
d ; 2  y
 /2  /2
1 y 1 x

2 
0
sin y
dy 
2  sin x dx
0
 (C)
2
t2
2.  log2 a  t  2  log2 (a2 )
2 0
(2  2log2 a)  2  2log2 a
2log2 a  2log2 a  a  R
1
3. f '(x)  1  ln2 x  2lnx  0  (1  ln x)2  0 
e
1
1
e
 1 
e
1 1 1 1
Hence f    1    (ln2 t  2ln t)dt  1   t ln2 t   1    1  2e 1  (D)
e e 1 e

e e
1
2x  1 2x  1 2x 2  x 3
4.  (x 2
 4x  1)3/2
dx  
 4 1
3/2
dx  
 4 1
3/2
dx
x 1   2 
3
1  x  2 
 x x   x 
1 4
Now put   1  t2
x2 x
(x 2  1)2  3x 2 (x 2  1  3x)(x 2  1  3x)

5. y 
x 2  3x  1 x 2  1  3x
_______________________________________________________________________________________________________________________________________________
dy
 2x  3  a2 & b 3
dx
 5
a  b  2  3  tan  cot
12 12
6. 2x  2yy'  0
x
x  yy '  0  y'   …...(1)
y
1  yy'' (y')2  0
1  (y ')2
y ''  
y
y '' 1  (y ')2 1 1 1 1
now k       
(1  (y ')2 )3/2 y 1  (y ')2
3
y 1  (y ')2
x2
y x
2 2 R
y 1
y2
t  3x  x 2 (x  4)(3  2x)  (t  3x  x 2 )
7. f(x)  ; f '(x) 
x4 (x  4)2
for maximum or minimum, f '(x)  0
2x2  11x  12  t  3x  x2  0
x2  8x  (12  t)  0
For one M and m,
D0
64  4(12  t)  0
16  12  t  0  4  t or t  4
dr dx dy
8. r 2  x2  y2 ; r x y
dt dy dt
dx dy
where x  3;y  3 3 and r  6 ; hence 6  11  3 3 3
dt dt
dy 3 dx 3 3 dx
but  x 
dt 2 dt 2 dt
_______________________________________________________________________________________________________________________________________________
Comprehension #1
9. (d)
1 x 1
Sol f(x)   x  1  f(f(x))   x  0,1.
1 x x
Hence points of discontinuity are x  0,1 .
10. (c)
Sol g(X)  f(f(f(x)))  x,x  R  {0,1}
1
 f(g(x))   x  0,1.
1 x
Comprehension #2
11. (a)
Sol If f(x) touches x-axis at only one irrational point, then f(x)  (x  )2 g(x), where  is irrational.
 coefficients of f(x) can’t be rational
 for f(x) with rational coefficients, then point of touching is rational.
12. (a)
Sol. The point of touching has to be rational
 the two roots of f(x)  0 are rational  third root is also rational.
Comprehension #3
13. (a)
Sol. As m  9  0 , hence we can substitute 9x2  4x  6  u  3x .

14. (d)
Sol. Here as per notations given, we can substitute 1  x2  (u  x) as m  1  0 and p  1  0 .
u15
 
15
1 15 1
 I du  u14 du  u c  x  1  x2  c.
u 15 15
Multiple Correct Type
(1  sin x)(1  sin x) cos x cos x dt

15. I   
sin x(1  sin x) sin x(1  sin x) 1 1 
2
 1
2
  sin x  2  t
2
4  2   
1
16. Differentiating f(x)  2f(x).f '(x)  f '(x)  ; f(x)  0
2
x
Hence f(x)   c. Put x  0 ; f(0)  c; but f 2 (0)  1
2
_______________________________________________________________________________________________________________________________________________
 f(0)  1
x
Hence f(x)  1
2
sin x x cos x  sin x

17. f '(x)  ; f ''(x) 
x x2
Now f ''(2m) we have f ''(x)  0 & f ''((2m  1)) we have f ''(x)  0
18. Numerator  2(x2  2x  2)  (x  1)
19. sinnx  sin(n  2)x  2cos(n  1)x sinx
sinnx sin(n  2)x

 sin x
dx   2cos(n  1)dx  
sin x
dx
 /2  /2  /2  /2  /2
sin5x sin3x sin3x 
 
0
sin x
dx  
0
2cos 4xdx  
0
sin x
dx  0  
0
sin x
dx   dx  2
0
20. f '(x)  0  (sinx  cos x)(non zeroquantity)  0
 tanx  1  x  3 / 4 or 7 / 4 .
Global Min = x  2n  (3 / 4); global max  x  2n  (7 / 4)
4 4
M ; m
8 2 8 2
*****
_______________________________________________________________________________________________________________________________________________

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Two Year CRP – 1214, Phase IV – Mains – Set A Page Number 1

FIITJEE - JEE (Mains)

PHYSICS, CHEMISTRY & MATHEMATICS

3. The test is of 3 hours duration.

Name of the Candidate (in Capital Letters) :_____________________________________

Enrolment Number :_________________________________________________________

Batch :________________________ Date of Examination : ________________________

3. Which of the following characteristics of electrons determines the current in a conductor?

4. A capacitor of 4F is connected as shown in the circuit.

7. A parallel plate capacitor is made of two dielectric blocks

8. Five charges q1, q2, q3, q4 and q5 are fixed at their

of the following statements is correct?

10. Figure shows electric field lines in which an electric dipole

13. A circular current loop of magnetic moment M is in an arbitrary orientation in an

16. A loop carrying current I lies in the x-y plane as shown in

17. The figure shows two infinite semi-cylindrical shells: shell-

18. A meter bridge is set up as shown, to determine an

19. A parallel plate capacitor C with plates of unit area and

21. The resultant capacitance of given circuit is

22. A and B two concentric spheres. If A is given a charge Q

26. In a permanent magnet at room temperature

29. Plates of a parallel plate capacitor C have charges CV

Section 2 (Part A) CHEMISTRY

1. Propanone and propanal are:

3. Which of the following is chiral carbon ?

4. Which of the following is optically active ?

COOH COOCH 3 COOCH 3

(a) HO C H and H C OH (b) CH 3 C OH and HO C CH 3

(c) H C CH3 and CH3 C H (d) HOOC C OH and HOOC C H

7. The most stable conformer of 2, 3-dimethylbutane is

8. Which of the following carbocation is most stable?

9. Which of the following shows maximum enol content

(a) O (b) O (c) O (d) O

13. Which products of the following reactions give iodoform test ?

14. In the given reaction:

CH3 (b) CH3

15. Which of the following is not a resonating form of benzaldehyde ?

16. How will you convert butan-2-one to propanoic acid ?

21. Which of the following does not give canizarro reaction :

(a) CHO (b) CH 2CHO

(c) H3C CHO (d) O2N CHO

23. In the Cannizaro’s reacting given below:

The slowest step is:

26. Which of the following is inert towards SN-1 reaction ?

(a) Ethyl chloride (b) Isopropyl chloride

29. At isoelectric point pH of the compound below is

(a) 3.22 (b) 6.96 (c) 8.05 (d) 5.93

The product formed is

Section 3 (Part A) MATHEMATICS

1. Which of the following have same graph.

4. Which of the following is an identical function

a f  x    sin x sin 2 x

5. If g  x   f  x   0; x   0,   ; then which of the following is true

a 0 b 2 c 4 d  6

9. Let lim    f  sinx  . Then the range of f  x  is

 a 1 b 2 c3  d  not exist

a a  3 b b  4 c c  5 d  d  7

(a) 12 (b) 16 (c) 18 (d) 24

(a) a–b (b) a  b (c) b  a (d) b–a

21. The range of the interval f:  1,3 →R under the mapping f  x   4 x  12 x is

(a) [–72,8] (b) [–8,72] (c) [–8,8] (d) [8,72]

  x  1  2 x  x 7  dx   c then value of ' a ' is

a 4 b8  c 12  d 16

 a 10  b 12  c 14  d 16

Batch : Date of Examination :

Batch :__ Date of Examination :_