Forward osmosis (FO) membrane designs and
materials
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Asymmetric cellulose acetate and cellulose triacetate based forward
‘osmosis membranes formed by phase inversion (both support membrane
and active layer)
Before proceeding with the main content sections of this article, we would like to note that
the information presented below is based - in part - on the excellent forward osmosis review
article by Zhao et. al. (2012)
“RECENT DEVELOPMENTS IN FORWARD OSMOSIS:
OPPORTUNITIES AND CHALLENGES”, ZHAO ET. AL. 2012
‘Asymmetric cellulose acetate and cellulose triacetate (CTA) membranes were some of the
first polymeric membranes used by researchers in forward osmosis applications. And from a
commercial point of view, a CTA based membrane was for a long time the only commercially
available forward osmosis membrane product and is still produced and sold by Hydration
Technology Innovations today.
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One of the advantages of cellulosic membranes is that the support and active rejection layer
are formed in the same process ~ phase inversion of a precursor dope solution followed by
hot water annealing. In addition, cellulosic membranes are quite hydrophilic (.¢. good water
flux performance and low propensity to fouling), have good mechanical strength, and
membrane components are readily available commodities.
On the negative side, cellulosic membranes must be kept within a narrow operational
window (pH 4-6 and temperature below 30° Celcius) in order to maintain operational
integrity. This excludes cellulosic membranes from being used for treatment of harsh
industrial waste waters.
When it comes to determining the performance characteristics of cellulose acetate or
cellulose triacetate membranes forward osmosis membranes, research groups have directed
thelr focus towards the CTA based membrane from HII. Below is a short summary of some
representative work. tis evident that the CTA membrane has some performance variation
from batch to batch, or alternatively, that research groups have different ways of determining
A.B, and S values.
Reverse draw solute permeation in forward 0,44 0265481,
osmosis: modelling and experiments, Philip
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