FIITJEE CHEMICAL BONDING CLIP

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1. Among the following bonds which has the most polar character ?
(A) C–O (B) C–Br (C) C–F (D) C–S
1. C
C–F bond has more electronegativity difference

2. A molecule which cannot exist theoretically is

(A) SF4 (B) OF2 (C) OF4 (D) O2F2
2. C
Oxygen cannot expand its octet due to absence of d–orbitals

3. Which has the largest distance between the C and H atoms ?

(A) Ethane (B) Ethene (C) Ethyne (D) Benzene
3. A
Decrease in S character increases bond length

4. Among of the following molecule, which is the most ionic ?

(A) CaCl2 (B) SnCl2 (C) NaCl (D) CuCl
4. C
Among these pairs, the difference in electronegativity between Na and Cl atoms is the greatest.

5. In which molecule the van der waals’ force is likely to be the most important in determining the M.P
and B.P ?
(A) Br2 (B) CO (C) H2S (D) HCl
5. A
In CO, H2S and HCl dipole–dipole forces also exist

6. Which are true statements among the following ?

(A) PH5 and BiCl5 does not exist (B) Pp - ddp bonds are present in SO2
(C) SeF4 and CH4 has same shape (D) I3+ has bent geometry
6. A, B, D

7. According to Fajan’s rules, covalent bond formation is favoured when there is a

(A) large cation and a small anion (B) large cation and a large anion
(C) small cation and a small anion (D) small cation and a large anion
7. D

8. An atom of element A has 3 electrons in its outermost shell while one of element X has 6 electrons in
its outermost shell. The formula of the compound formed by A and X is
(A) A2X4 (B) A2X3 (C) A3X2 (D) A2X
8. B

9.

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 FIITJEE CHEMICAL BONDING CLIP
Cl

The dipole moment of is 1. 5 D.

Cl
Cl
The dipole moment of is

Cl Cl
(A) 0D (B) 1.5 D (C) 2.86 D (D) 2.25 D
9. B

10. Which of the following have been arranged in increasing order of bond order as well as bond
dissociation energy ?
(A) O2-2 < O-2 < O +2 < O2 (B) O2-2 < O2- < O2 < O2+
(C) O2 < O2+ < O22- < O2- (D) O2+ < O22 - < O2- <2
10. B

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