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Callidus Oxidizer Systems

Thermal and Catalytic


Oxidizer Systems
Fume Thermal Oxidizers Fume Thermal

Meet the Thermal Oxidizer Experts


Honeywell UOP Callidus Fume Thermal Oxidizer Oxidizer Typical Typical Waste Typical
thermally treat organic fumes in air or inert gas Equipment Streams Installation
streams at temperatures between 1400˚F and • Low emissions • VOC streams • 5 to 100 MM BTU/
1600˚F. Destruction efficiencies typically range burner hr burner
• Process vents
from 99 to 99.99 percent. • Ceramic fiber • 1 second residence
Wide Range of Applications • Pharmaceutical
Honeywell UOP Callidus is an industry leader in environmental combustion refractory vents time
Catalytic Oxidizers
technology. We have provided incinerators for a wide variety of gas and • Forced draft • Dryer exhausts • 1500˚F operating
Our Catalytic Oxidizers can be used in cases
liquid wastes including inorganic particulate, various acids and hard- operation temperature
where the organic level is low and the fume
to-burn organic compounds. Our experience extends to development • Heat recovery
stream is free from dust or substances
and implementation of Thermal Oxidizer systems for Fume, Tail Gas, equipment
potentially poisonous to the catalyst. Catalytic
Halogenated Waste, Bound Nitrogen, Catalytic Oxidizers and Downfired • B
urner management
oxidation is generally carried out at 550˚F to
Incinerators including units with ratings of more than 400 MM BTU/hr. system
850˚F and requires substantially less fuel than
• Stack
thermal systems.

Destruction efficiencies greater than 99.99 Tail Gas Thermal Oxidizer


percent may be required for some organic
Typical Equipment Typical Waste Typical Installation
wastes. This is achieved by operating the oxidizer
All of our products - Burners, Flares, Selective Catalytic Reduction systems Leading the Way With • L
ow emissions Streams • Refineries
at a higher temperature with minimal auxiliary
and Thermal Oxidizers - are engineered and designed by combustion burner • Sulfur plant tail gas • Natural Gas
Engineering Excellence fuel. Waste heat boilers or hot oil heaters can
experts who have years of experience and are focused on customer • Castable or brick • Carbon black tail Processing Plants
Honeywell UOP Callidus focuses on meeting each be used downstream to recover heat for other
satisfaction and emission compliance. refractory gas • 20 to 150 MM
customer’s individual requirements, resulting in plant operations.
• N
atural draft/ BTU/hr burner
a custom-designed solution for every project.
Dedication to our customers is proven by the performance of our forced draft • 1 second residence
On average, each engineer has 15 years Tail Gas Thermal Oxidizers
thermal oxidizer group. The engineers in this group are second to none time
experience designing thermal oxidizers. Tail Gas from Sulfur Recovery Units contains a • H
eat recovery
in oxidizer experience and technical capabilities. We have been involved (optional) • 1200˚F-1500˚F
variety of sulfur compounds, which are destroyed
in the successful design, fabrication, and startup of hundreds of thermal operating
Advanced Manufacturing and in our Tail Gas Thermal Oxidizer. Typical oxidizing • Stack
oxidizers worldwide. temperature
Fabrication Capabilities temperatures vary from 1200˚F to 1500˚F,
We Pride Ourselves on Quality Upgrading our manufacturing and fabrication with residence times of 0.6 to 1.0 second.
Our manufacturing facility employs the highest standards in the industry. facilities is an ongoing process, and our facilities System designs for both natural or forced
Like many companies, our manufacturing techniques use state-of-the-art employ the latest manufacturing practices draft are available.
equipment; but, what truly sets us apart is our people. We take great care and equipment.
Generally, regulations require H2S in the flue
to ensure that highly trained individuals perform our special requirements.
As a global leader in the thermal oxidizer market, gas to be 10 ppmv or less; but in certain cases,
Ongoing and regularly scheduled training through our research and 9.5 MM BTU/hr fume
much of our fabrication occurs in strategic levels as low as 2 ppmv can be achieved. incinerator
development group assures that a high level of quality is maintained.
locations around the world while proprietary items
Our quality assurance personnel thoroughly inspect each assembly are fabricated in our own facilities. This approach
prior to shipment, thus reducing installation, and our fabrication and makes good economic sense, and provides you
manufacturing are certified ISO 9001:2008 in the USA and China. the best value for your combustion system.

20 MM BTU/hr sulfur
plant tail gas incinerator

8 MM BTU/hr brominated waste 35 MM BTU/hr downfired system 15 MM BTU/hr fume incinerator 22 MM BTU/hr tail gas unit
Downfired Thermal Oxidizer Systems Halogenated Waste Thermal Oxidizer Systems
Thermal destruction of aqueous or organic waste We have extensive experience in halogenated organic waste oxidation.
streams containing inorganic or organic alkali The most common halogen is chlorine. Thermal oxidation of chlorinated
metal salts requires that the thermal oxidizer be hydrocarbons produces hydrogen chloride gas (HCl) and some free
downfired to prevent accumulation of molten chlorine, which must be removed. The quantity of HCl in the flue gas
salts in the oxidizer furnace. Because molten determines whether a single or two-stage HCl removal system is used.
salts tend to destroy refractory, our design Either an HCl absorber or a caustic scrubber is used when a small quantity
minimizes salt contact with refractory lining, of HCl is present. A two-stage system is often used to reduce caustic
which improves refractory life. usage when the flue gas contains a significantly large quantity of HCl.

Honeywell UOP Callidus Halogenated Waste Thermal Oxidizer Systems


Particulates entrained in the flue gas are
are capable of destruction efficiencies up to 99.99 percent. Operating
removed by either a wet or dry flue gas clean-up
temperatures can range from 1500˚F to 2200˚F with residence times of
system depending on the required emissions
1.0 to 2.0 seconds depending on the destruction efficiency required.
rate. In our wet system, salt or ash-laden flue gas
from the oxidizer first enters the quench system
located directly below the thermal oxidizer.
Here the hot gas is quenched to its adiabatic Halogenated Waste Thermal Oxidizer
saturation temperature by water injection or by
Typical Equipment Typical Waste Stream Typical Installation
a Callidus high efficiency submerged quench
• Medium intensity • PVC plant vents • Chemical plant
system (patent pending).
burner
• VCM waste liquids • 10 to 50 MM BTU/
Then, the saturated flue gas flows through a wet
Downfired unit • Forced draft hr burner
venturi scrubber and/or WESP (Wet Electrostatic • Pharmaceutical
Precipitator) before being sent to a packed • High alumina brick vents • 2.0 seconds
column scrubber, if required, or vented to the Downfired Thermal Oxidizer refractory residence time
• Bromine liquid
atmosphere through a stack.
Typical Equipment Typical Waste Stream Typical Installation • H
eat recovery wastes • 1800˚F operating
• Low emission • Ethylene plant • Chemical plant equipment temperature
In the dry system design, flue gas from the
oxidizer is typically cooled by air and/or water burner blowdown
• 20 to 80 MM • HCl recovery/
injection before being sent to a baghouse or an scrubber Halogenated Waste Thermal Oxidizer
• Low porosity brick • Caustic waste BTU/hr burner
electrostatic precipitator for particulate removal. refractory streams
• 2.0 seconds
• Forced draft residence time
Destruction efficiencies greater than 99.99
percent are routinely achieved for most • Adiabatic quench • 1650˚F-1800˚F
organic waste components at temperatures of operating
• Particulate removal
approximately 1800˚F. Particle matter emission temperature
rates may vary from as low as 0.005 to 0.08
grains/DSCF, depending on the particle
removal equipment selected to meet the
customer’s requirements.

deNOxidizer/tail gas unit 80 MM BTU/hr low NOx system


The Best in Design, Quality, Performance We Exceed the Expectations
Quality assurance and customer satisfaction are our top priorities. Each step of a project is reviewed

and Delivery to meet or exceed our customers’ requirements and standards. Where applicable, equipment is
pre-assembled and tested. Fabrication is accomplished either in-house or by certified, experienced,
and our rigorous quality inspection program is evident by our ISO 9001:2008 certification.
Low NOx deNOxidzer Systems The combustion process is completed in
Thermal oxidation of nitrogen-bearing wastes stage three where the flue gas is oxidized at a
require a specialized combustion approach. temperature of 1700˚F to 2000˚F with excess
Unequaled Research
Single-stage combustion of these wastes oxygen present. NOx in the final flue gas typically
and Development
can produce NOx emissions in excess of ranges from 80 to 200 ppm, depending on the
Our industrial scale Thermal Oxidizer R&D
those allowed by most regulatory agencies. waste composition. A destruction efficiency of
facility is fully instrumented and utilizes process
To maintain NOx emissions within acceptable 99.99 percent can be achieved
control and data logging systems. The facility
limits, Honeywell UOP Callidus uses a for most compounds.
is devoted to research and development of
three-stage combustion process to destroy
new products, new combustion processes,
these wastes.
improvement of existing equipment processes,
The waste is burned in the first stage under and problem-solving efforts. The center also
substoichiometric, or reducing conditions. The serves as a research facility for regulatory
high temperatures and lack of oxygen in the first agencies as well as private clients.
stage cause the nitrogen-bearing compounds
The Thermal Oxidizer R&D facility currently
to form elemental nitrogen rather than NOx.
consists of two major combustion systems: a
In the second stage, flue gas from the first stage vertical, downfired salt type unit with complete
is cooled to approximately 1400˚F by injection of wet quench system, and a three-stage, low
water, steam, or cooled recycled flue gas. NOx horizontal deNOxidizer system. Both
units are designed to be easily reconfigured
to allow numerous process configurations.
The computer control system and its leading
edge data acquisition system also enhance the
Three stage combustion system at Honeywell UOP Callidus research facility capabilities of the test facility. A separate pad,
complete with stack, utility hook-ups, and flue
gas sampling equipment, is also available for
Low NOx Thermal Oxidizer
equipment checkout and specialty combustion
Typical Equipment Typical Waste Representative testing for our customers.
• High intensity Streams Installation
burner • Ammonia vents • Petrochemical Our R&D facility investment and capabilities,
plant in India along with our dedication to quality and
• Brick lined furnace • Acrylonitrile vents continually improving training options,
• 10 to 60 MM underscore our commitment to being the
• Forced draft • Nitrogen bound BTU/hr leader in the worldwide environmental and
organic wastes
• Heat recovery combustion industry.
• 2.0 seconds
equipment
residence time
• Three stage process Reducing furnace burner at our research facility
• 2200°˚F/1600˚F
operating
temperatures

Downfired oxidizer in Honeywell UOP Callidus


research facility
Honeywell UOP Callidus headquarters - Honeywell UOP Callidus combustion test Honeywell UOP Callidus 82,000 sq. ft.
Tulsa, Oklahoma. USA facility - China manufacturing and fabrication facility in USA

Global Coverage Test Facility In Addition to Oxidizer Systems,


Honeywell UOP Callidus reaches the Honeywell UOP Callidus’ test facilities Honeywell UOP Callidus Offers:
global market through our headquarters in the U.S. and China are used for • Ultra-low NOx burners
located in Tulsa, Oklahoma, USA, with combustion technology research and
• Flares, flare systems and flare gas
regional direct sales offices and development, as well as for customer recovery systems
independent sales representation demonstrations. Our array of test
• Thermal oxidizer systems
around the world. Meeting our systems allow us to closely match actual
customers’ expectations and setting field operating conditions, providing • Field services and parts
the standards for the combustion results that will more accurately predict • CFD Modeling
industry have always been our goals. actual measured performance. • Training and schools
Each burner, flare, thermal oxidizer
and catalyst system we design and
ISO 9001:2008 Certification
manufacture is built with those goals
in mind.

USA Certification China Certification


High-Performance Combustion Solutions
Service — Parts — Installation
Contact us–we’re here to help.
CallidusHelp@Honeywell.com

For more information


For more information, please visit
www.callidus.com to find a local
sales representative

Corporate Headquarters
Callidus Technologies
7130 South Lewis Ave.
Suite 335
Tulsa, Oklahoma. 74136 UOP7326-7
March 2016
Tel: +1-918-496-7599 Printed in U.S.A.
www.callidus.com © 2016 UOP LLC. All rights reserved.

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