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1. Determining mmolHClinitial
mmol = N HCl x V HCl = 0.02 x 10 ml = 0.2 mmol
2. Determining mmolNaOHinitial
mmol = N NaOH x V NaOH = 0.02 x 2.22 ml= 0.0444 mmol
Based on the reactiobelow, the mmol of NaOH titration = the mmol of NaOH residue. Or we can
say that NaOH titration is (b-x)
So (b-x) = x mmol
1. First titration
V NaOH = 5.1 ml t = 3 menit 20detik = 200s
ln(𝑎−𝑥) ln 𝑎
(𝑏−𝑥)
−
𝑏
𝐾1 = 𝑡
(𝑏(𝑎−𝑥)−𝑎(𝑏−𝑥))
𝑙𝑛 (0.1132) ln 0.0556
(0.102)
− 0.0444
𝐾1 =
200 (0.0444(0.1132) − 0.0556(0.102))
2. Second titration
ln(𝑎−𝑥) ln 𝑎
(𝑏−𝑥)
−
𝑏
𝐾2 = 𝑡
(𝑏(𝑎−𝑥)−𝑎(𝑏−𝑥))
𝑙𝑛 (0.1272) ln 0.0556
(0.116)
− 0.0444
𝐾2 =
520 (0.0444(0.1272) − 0.0556(0.116))
3. Third titration
V NaOH = 6.2 ml t = 15 menit 25detik = 925s
ln(𝑎−𝑥) ln 𝑎
(𝑏−𝑥)
−
𝑏
𝐾3 = 𝑡
(𝑏(𝑎−𝑥)−𝑎(𝑏−𝑥))
𝑙𝑛 (0.1352) ln 0.0556
(0.124)
− 0.0444
𝐾3 =
925 (0.0444(0.1352) − 0.0556(0.124))
4. Fourth titration
V NaOH = 6.5 ml t = 25 menit 55detik = 1555s
ln(𝑎−𝑥) ln 𝑎
(𝑏−𝑥)
−
𝑏
𝐾4 = 𝑡
(𝑏(𝑎−𝑥)−𝑎(𝑏−𝑥))
𝑙𝑛 (0.1412) ln 0.0556
−
(0.13) 0.0444
𝐾4 =
1555 (0.0444(0.1412) − 0.0556(0.13))
5. Fifth titration
V NaOH = 6.2 ml t = 15 menit 25detik = 925s
ln(𝑎−𝑥) ln 𝑎
(𝑏−𝑥)
−
𝑏
𝐾3 = 𝑡
(𝑏(𝑎−𝑥)−𝑎(𝑏−𝑥))
𝑙𝑛 (0.1352) ln 0.0556
(0.124)
− 0.0444
𝐾3 =
925 (0.0444(0.1352) − 0.0556(0.124))
6.