Espectroscopia

infravermelho
Jan Schripsema
UENF
X-ray spectroscopy

UV spectroscopy

Vis spectroscopy

IR spectroscopy

Microwave spectroscopy

NMR spectroscopy
IR spectrum
 Espectroscopia infravermelho

-wavelength 1 μm – 1 mm

- Near IR – Mid IR – Far IR

- Near IR: 14000 cm-1 to 4000 cm-1 (0.8–2.5 μm wavelength)

- Mid IR: 4000 cm-1 to 400 cm-1 (2.5–25 μm)
- Far IR: 400 cm-1 to 10 cm-1 (25–1000 μm)

- Wavenumber:

-
Transmitância - Absorbância

Transmitância :

Absorbância:
Lei de Beer- Lambert
 Lei de Beer- Lambert
Descoberto por:

No Picture

Pierre Bouguer (1698-1758) Johann Heinrich Lambert August Beer (1825-1863)

(1728–1777)
Vibrational modes
 Hooke’s law

f single bond 5 X 105 dyne/cm

1 u = 1,64 X 10-24 g
FT IR Spectrometer
 Amostras
- Gases
- Liquidos
- Solidos
Fonte: LC Speital –
FTIR analysis of
combustion gases.
DOT/FAA/AR-01/88
-Liquidos

Fonte: http://www.shimadzu.com/an/ftir
Fonte: http://www.shimadzu.com/an/ftir
Silverstein – Spectrometric identification of organic compounds. Ed. VI
 -Solidos
- KBr pellet
- KCl pellet

Fonte: http://www.shimadzu.com/an/ftir
 -Solidos
- Nujol method

Fonte: http://www.shimadzu.com/an/ftir
Silverstein – Spectrometric identification of organic compounds. Ed. VI
Silverstein – Spectrometric identification of organic compounds. Ed. VI
Silverstein – Spectrometric identification of organic compounds. Ed. VI
Silverstein – Spectrometric identification of organic compounds. Ed. VI
Silverstein – Spectrometric identification of organic compounds. Ed. VI
Silverstein – Spectrometric identification of organic compounds. Ed. VI