Você está na página 1de 22

Sri Chaitanya IIT Academy, India

2018
JEE - MAINS
QUESTIONS PAPER
KEY
SOLUTIONS
Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper

Ans. (1)

PART-A PHYSICS V dr
3 ,
V r
1. It is found that if a neutron suffers an elastic collinear mg
collision with deuterium at rest, fractional loos of its k
v
a
energy is pd ; while for its similar collision with carbon v
nucleus at rest, fractional loss of energy is pc . The r mg
 
values of p d and pc are respectively: r 3ak
4. Two batteries with e.m.f. 12V and 13 V are connected
(1) (0,0) (2) (0,1) in parallel across a load resistor of 10 the internal
(3) (.89, .28) (4) (.28, .89) resistance of two batteries are 1 and 2
Ans. (3) respectively. The voltage across the load lies between:
k 4m1m2 4m  2m 8 (1) 11.4 V and 11.5V
 Pd  2
   0.89 (2) 11.7 V and 11.8V
k ( m1  m2 ) (m  2m)2 9
(3) 11.6 V and 11.7 V
k 4 m1m2 4 m  12 m (4) 11.5 V and 11.6 V
 Pc  2
 Ans. (4)
k ( m1  m2 ) ( m  12m ) 2
1r2   2 r1 12  2  13 1 37
48 v  
  0.28 r1  r2 1 2 3
169
2. The mass of a hydrogen molecule is 3.32 1027 kg. r1r2 2 32
Req = r  r  R  3  10  3
If 1023 hydrogen molecules strike, per second, a 1 2

fixed wall of area 2cm 2 at an angle of 45o to the  37  3 37


I = R  3  32  32
normal, and rebound elastically with a speed of eq

103 m / s , then the pressure on the wall is nearly: 37


(1) 2.35 102 N . / m 2 (2) 4.70 102 N / m 2 V= 10  11.56V
32
(3) 2.35  103 N / m 2 (4) 4.70 103 N / m 2 5. A particle is moving in a circular path of radius a
Ans. (3) k
under the action of an attractive potential U   .
F dN 2mv cos45 o
2r 2
p= =
A dt A Its total energy is:

10 23  2  3.32 1027  103 3 k


= (1) Zero (2) 
2  104  2 2 a2
k k
 2.35 103 N / m2 (3)  2 (4)
3. A solid spherer of radius r made of a soft material of 4a 2a 2
bulk modulus K is surrounded by a liquid in a Ans. (1)
cylindrical container. A massless piston of area a floats dU k d (r 2 ) 2k 3 k
on the surface of the liquid, covering entire cross F  ( )    r  3
dr 2 dr k r
section of cylindrical container. When a mass m is
placed on the surface of the piston to compress the k mv 2 k
 F    2  mv 2
liquid, the fractional decrement in the radius of the r 3
r r
 dr  1 2 k
sphere,   , is: K.E = mv  2
 r  2 2r
mg mg
(1) (2) k k
3Ka Ka E total = U  k .E   2  2 = 0
2r 2v
Ka Ka
(3) (4)
mg 3mg

2018 JEE-MAINS_CODE – B Page 2


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper

6. Two masses m1  5kg and m2  10 kg , connected (1) 45o (2) 60o


by an inextensible string over a frictionless pulley, (3) 0o (4) 30o
are moving as shown in the figure. the coefficient of Ans. (1)
friction of horizontal surface is 0.15. The minimum
Let   angle between A & C
weight m that should be put on top of m2 to stop the
I
motion is : Ic = cos 2 
2
m T
I B  I C cos2 (90   )
m2
T I I
 cos 2  cos 2 (90   )
m1 8 2
1
m1g  cos sin 
2
(1) 43.4kg (2) 10.3 kg 1  sin 2  2  90o    45o
(3) 18.3 kg (4) 27.3 kg 9. An electron from various excited states of hydrogen
Ans. (4) atom emit radiation to come to the ground state. Let
m1 g   ( m  m2 ) g n , g be the de Broglie wavelenght of the electron
m1   m2 in the nth state and the ground state respectively..
m

Let  n be the wavelength of the emitted photon in
5  0.15  10 the transition from the emitted photon from n th

0.15 state to the ground state. For large n, (A,B are
= 23.3 kg constants)
so (4) is correct (1) 2n  A+Bλ 2n (2) 2n  
7. If the series limit frequency of the Lyman series is
vL , then the series limit frequency of the Pfund series B
(3)  n  A   2 (4)  n  A  Bn
is: n

(1) vL /16 (2) vL / 25 Ans. (3)


(3) 25 v L (4) 16 v L KZe 2 mvn2
 | En | KE n .  
Ans. (2) 2r 2

1 v  1 1  h h
  R 2  2  n   Vn 
 c mvn mn
 n1 n2 
r1 R h2 h2
 ( n2  ) En   2 and Eg  
c (1) 2 2mn 2m g 2

v1  CR E  Fn  Eg

CR v1 hC h2  1 1  h2  g2 
v2        1  
25 25 n 2m   g 2 n2  2m g 2   n 2 
8. Unpolarized light of intensity I passes through an ideal
polarizer A. Another ideantical polarizer B is placed c h  g 2 
 1  
behind A. identical polarizer B is placed behind A.  n 2mg2   n 2 
I
The intensity of light beyond B is found to be . Now 2 m c g 2   g2 
2 n   1  2 
h  n 
another identical polarizer C is placed between A
and B. The intensity beyond B is now found to be 2mc g 2 2mcg
4
B
  , n  A 
I h  n2  n2
. The angle between polarizer A and C is:
8

2018 JEE-MAINS_CODE – B Page 3


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper

10. The reading of the ammeter for a silicon diode in the 13. For an RLC circuit driven with voltage of amplitude
given circuit is :
1
 and frequency o  the current exibits
200 m
LC
resonance. The quality factor, Q is given by:
R CR
(1) ( C ) (2) 
3V o o

(1) 11.5 mA (2) 13.5 mA o L o R


(3) 0 (4) 15mA (3) (4)
R L
Ans. (1) Ans. (3)
30.7 VL o L
I 11.5mA Q 
200 VR R
11. An electron, a proton and an alpha particle having
14. A telephonic communication service is working at
the same kinetic energy are moving in circular orbits
carrier frequency of 10 GHz. Only 10% of it is utilized
of radii re rp r respectively in a uniform magnetic for transmission. How many telephonic channels can
be transmitted simultaneously if each channel
field B. The relation between re rp r is :
requires a bandwidth of 5 kHz?
(1) re  rp  r (2) re  r  rp (1) 2 105 (2) 2 106
(3) re  rp  r (4) re  rp  r (3) 2 103 (4) 2 104
Ans. (4) Ans. (1)
10 109
2 k . E .m m N  2  105
 r qB
 const.
q 10  5 103
15. A granite rod of 60 cm length is clamped at its middle
me point and is set into longitudinal vibrations. The density
 re  const .
e of granite is 2.7  103 kg / m3 and its Young's modulus
mp is 9.27  1010 Pa. What will be the fundamental
rp  const. frequency of the longitudinal vibrations?
e
(1) 10 kHz (2) 7.5 kHz
4mp mp (3) 5 kHz (4) 2.5 kHz
r  const.  const. Ans. (3)
2e e
 re  rp  r v v v 1 
     4.88 103  5kHz
12. A parallel plate capacitor of capacitance 90 pF is  2l 2l 2l 
connected to a battery of emf 20V. If a dielectri 16. Seven identicla circular planar disks, each of mass
M and radius R are welded symmetrically as shown.
5
material of dielectric constant K  is inserted The moment of inertia of the arrangement about
3 the axis normal to the plane and passing through the
between the plates, the magnitude of the induced point P is :
charge will be
(1) 2.4 nC (2) 0.9 n C P
(3) 1.2n C (4) 0.3 n C
O
Ans. (3)
q i  q  q 0  kc  c
 ce(k  1)

5  73 181
(1) MR 2 (2) MR 2
901012 20  3  1 2 2
 
 1.2nC 19 55
(3) MR 2 (4) MR 2
2 2

2018 JEE-MAINS_CODE – B Page 4


Sri Chaitanya IIT Academy, India JEE-M AI NS Question Paper
Ans. (2) r1 r1
2 2 (3)  r  4 (4)  r  2
mR  mR  55 2 2
Io   6  m(2 R ) 2   mR 2
2  2  2 Ans. (1)
 
E2  Eo 2 x cos  k 2 z  (ct )
181 2
I p  I o  7m(3R) 2  mR
2   2 
17. Three concentric metal shells A,B and C of respective  Eo2x cos  (2 z  ct ) 
 c 
radii a,b and c ( a < b < c) have surface charge
densities  ,  and  respectively. The potential   2 z 
 Eoxˆ cos  2 v   t  
of shell B is:   c 
  b2  c2    b2  c 2  C
(1)   b  a  (2)   c  a   C2 
0   0   2
  a2  b2    a2  b2  1 1 1
 
(3)   a  c  (4)   b  c   0  0  r2  0  0  r1 2
0   0  
Ans. (4)  r1 1

1  q A qB qc  r2 4
VB    
4 0  b b c 20. The angular width of the central maximum in a single
slit diffraction pattern is 60o . The width of the slit is

1   4 a 2 o4 b 2  4 C 2   a2  b2  1μm. The slit is illuminated by monochromatic plane


       c waves. If another slit of same width is made near
4 o  b b c  0  b 
it, Young's fringes can be observed on a screen placed
18. In a potentiometer experiment, it is found that no at a distance 50 cm from the slits. If the observed
current passes through the galvanometer when the fringe width is 1 cm, what is slit separation distance?
terminals of the cell are connected across 52 cm of (i.e. distance between the centres of each slit.)
the potentiometer wire. If the cell is shunted by a
(1) 75  m (2) 100 m
resistance of 5 , a balance is found when the cell
is connected across 40 cm of the wire. Find the (3) 25 m (4) 50  m
internal resistance of the cell. Ans. (3)
(1) 2 (2) 2.5 d sin   
(3) 1 (4) 1.5 106 sin30o  
Ans. (4)   0.5 106
    52
r    1 R   1  1 R    1 5 
D
v   2   40  d
 1.5 D
d
19. An EM wave from air enters a medium. The electric 
fields are
0.5  0.5 106
   z    25 m
E1  E01 xˆ cos  2 v   t   in air and 102
  c  21. A silver atom in a solid oscillates in simple harmonic
 motion in some direction with a frequency of
E2  E02 xˆ cos  k (2 z  ct )  in medium, where the
wave number k and frequency v refer to their values 1012 / sec. What is the force constant of the bond
connecting one atom with the other? (Mole wt. of
in air. The medium is non-magnetic. If r1 and r 2
refer to relative permittivities of air and medium silver = 108 and Avagadro number  6.02 1023 gm
respectively, which of the following options is correct? mole-1 )
r 1 1 r 1 1 (1) 2.2 N/m (2) 5.5N/m
(1)  r  4 (2)  r  2 (3) 6.4 N/m (4) 6.4N /m
2 2

2018 JEE-MAINS_CODE – B Page 5


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper

Ans. (4) Ans. (4)


1 k mv1  mv2  mvo
f 
2 m v1  v2  vo (1)
k 1 2 1 2 3 1 2
4 2 f 2  mv1  mv2   mv0
m 2 2 2 2
k  4 2 mf 2 3
v12  v22  v02 (2)
3 2
108  10
 4 2  1024 Squaring (1)
6.02 1023
2
v12  v22  2v1v2  v02
4  108
 102  7.1N / m 3 2
6.02 v0  2v1v2  v02 (by (2))
22. From a uniform circular disc of radius R and mass 2
R v02
9M, a small disc of radius is removed as shown 2v1v2  
3 2
in the figure. The moment of inertia of the remaining
v02
disc about an axis perpendicular to the plane of the v1v2   (3)
4
disc and passing through centre of disc is :
v1  v2  ( v1  v2 ) 2  4v1v2
2R/3
v1  v2  v02  v02
R v1  v2  2vo
24. The dipole moment of a circular loop carrying a
current I, is m and the magnetic field at the centre of
37 the loop is B1 . When the dipole moment is doubled
(1) 10MR 2 (2) MR 2 by keeping the current constant, the magnetic field
9
B1
40 at the centre of the loop is B2 . The ratio B is:
(3) 4MR 2 (4) MR 2 2
9
Ans. (3) 1
(1) 2 (2)
I remaining =I Total -I removed 2
(3) 2 (4) 3
1 1 R2 4R2 
=  9m  R 2   m   m Ans. (1)
2 2 9 9 
m  I   R 2 .....(1)
9mR 2 mR 2 0 I o I
  B1   By(1)
2 2 2R m
2
 4mR 2 I
23. In a collinear collision, a particle with an initial speed
3
o strikes a stationary particle of the same mass. If  I2
B1  o (2)
the final total kinetic energy is 50% greater than the 2 m
original kinetic energy, the magnitude of the relative
3
velocity between the two particles, after collision, is :
 II2
o o B2  o (3)
(1) (2) 2 2m
2 2
B1
  2
(3) o (4) 20 B2
4

2018 JEE-MAINS_CODE – B Page 6


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper

25. The density of a material in the shape of a cube is  


determined by measuring three side of the cube and i = 20 sin  30t  
 4
its mas.s If the relative errors in measuring the mass
and length are respectively 1.5% and 1%, the In one cycle of a.c., the average power consumed
maximum error in determining the density is : by the circuit and the wattless current are,
(1) 4.5% (2) 6% respectively:
(3) 2.5% (4) 3.5% 50
Ans. (1) (1) ,0 (2) 50,0
2
m
  ml 3 1000
v (3) 50,10 (4) ,10
2
 M l Ans. (4)
 100 =  100  3 100
 M l
1
 1.5  3  1 Pav = Eo I o cos 
2
 4.5%
26. On interchanging the resistances, the balacne point 1 
  100  20cos
of a meter bridge shifts to the left by 10 cm. The 2 4
resistance of their series combination is 1k . How
1
much was the resistance on the left slot before  1000 
2
interchanging the resistances?
(1) 550 (2) 910 1000

(3) 990 (4) 505 2
Ans. (1)
Pav = I wattless V0 sin 
x 100-x
1000 
 I wattless 100  sin
2 4
1000 1
R 1 R  I wattless 100 
x  10 110  x 2 2
R x I wattless  10 Amp
 (1)
1  R 100  x 28. All the graphs below are intended to represent the
1 R R
same motion. One of them does it incorrectly. Pick it
R 110  x up.
 (2)
1  R x  10 position velocity
By (1) and (2)
x 110  x (1) (2)
 time time
100  x x  10
x 2  10 x  11000  100 x  110 x  x 2
200 x  11000  x  55 velocity
putting value of x in (1)
R 55 11
  position
1  R 45 9 (3)
9R = 11 - 11R
20R = 11
11 11000
R k   550 distance
20 20
27. In an a.c. circuit, the instantaneous e.m.f and current
are given by (4)
e = 100 sin 30 t time

2018 JEE-MAINS_CODE – B Page 7


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper

Ans.(4)
PART-B MATHEMATICS
31. If the tangent at (1, 7) to the curve x2 = y – 6 touches
Distance the circle x2 + y2 + 16x + 12y + c = 0 then the value
Time of c is:
(1) 85 (2) 95
So, option (4) is wrong
29. Two moles of an ideal monoatomic gas occupies a (3) 195 (4) 185
volume V at 27 o C . The gas expands adiabatically Ans. (2)
to a volume 2 V. Calculate (a) the final temperature Equation of tangent at (1, 7) for x2 = y – 6 is given by
of the gas and (b) change in its internal energy. y7
x 6
(1) (a) 189 K (b) -2.7 kJ 2
(2) (a) 195 K (b) 2.7 kJ 2x  y  5  0
(3) (a) 189 K (b) 2.7 kJ
(4) (a) 195 K (b) -2.7 kJ Centre of circle (–8, –6)
Ans. (1)   is from center = Radius
T2V21  TV
1 1
1
1  16  6  51
 | 64  36  c |
5 5 5
 3
1  3
1
T2  2V   300V
  5 100  c 
2
c = 95.
3
T2 2 300 32. If L 1 is the line of intersection of the planes
2x – 2y + 3z – 2 = 0, x – y + z + 1 = 0 and L2 is the
300 line of intersection of the planes x + 2y – z – 3 = 0,
T2  2
3
3x – y + 2z – 1 = 0, then the distance of the origin
(2) from the plane, containing the lines L1 and L2, is :
 189 k 1 1
(1) (2)
U  nCv (T2  T1 ) 2 2 2
3R 1 1
 2  (189  300)  3  8.31  11 (3) (4)
2 4 2 3 2
= - 2768  2.7kJ Ans. (4)
30. A particle is moving with a uniform speed in a circular Vector || to L1
orbit of radius R in a central force inversely
iˆ ˆj kˆ
proportional to the nth power of R. If the period of 
rotation of the particle is T, then: n1  2 2 3  2iˆ  2  3  ˆj  2  3  kˆ  2  2 
(1) T  R ( n 1)/2 (2) T  R n /2 1 1 1
n
(3) T  R3/2 for any n. (4) T  R 2 1 = iˆ  ˆj
Ans. (1) Vector || to L2

mv 2 K k iˆ ˆj kˆ
 n ,  
R R mR n 1 n2  1 2 1  3iˆ  5 ˆj  7kˆ
R 3 1 2
T Vector  to plane
2 R 1
T , 1
 2 iˆ ˆj kˆ
R

n1
n  1 1 0  7iˆ  7 ˆj  10kˆ
2
T  R R 3 5 7
n1 Equation of plane
T R
2 x + 2y – 3 = 0

2018 JEE-MAINS_CODE – B Page 8


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper
3x – y – 1 = 0
 3 9x
2  3 5 9a1 8 m1  , m2  
x  ; y  y by
1 6 7 1  6 7 m1m2 = – 1
 5  8 3 9x
7  x    7  y    8z  0
7  7    1 ; 27x  by 2 ; y 2  27x
 y by b
7 x  7 y  8z  3  0
27 x 27 x 9
 6x ; b  ; b
1 b 6x 2
 distance from origin 
3 2 36. If the system of linear equations
33. If ,   C are the distinct roots, of the equation x + ky + 3z = 0
x2 – x + 1 = 0, then 101  107 is equal to: 3x + ky – 2z = 0
(1) 1 (2) 2 2x + 4y – 3z = 0
xz
(3) –1 (4) 0 has a non-zero solution (x, y, z), then is equal to:
y2
Ans. (1) (1) –30 (2) 30
Roots of x2 – x + 1 = 0 are  and 2 then (3) –10 (4) 10
Let   ,   
2 Ans. (4)
101 107 for non-zero sol.
101  107     
 2  0
 101  214 1 k 3
 [2  ]   3 k 2  0
= – [–1] = 1. 2 4 3
34. Tangents are drawn to the hyperbola 4x2 – y2 = 36 at
1 . (8 – 3x) – k (–5) + 3 (12 – 2x) = 0
the points P and Q. If these tangents intersect at the
8 – 3k + 5k + 36 – 6k = 0
point T(0, 3) then the area (in sq. units) of PTQ is:
4k = 44
(1) 60 3 (2) 36 5 k = 11
(3) 45 5 (4) 54 3 Let z = t
Ans. (3) Solving x + 11y + 3t = 0
Chord of contact at (0, 3) 3x + 11y – 2t = 0
y = –12 5t t
x ,y
x   45 2 2
2
5t
P   
45, 12 Q  45, 12 T  0,3  xz
 22  10
0 3  yz t .
1 45 12 4
 35 45  45 5 37. Let S  {x  R : x  0 and
Area = 2  45 12
0 3 2| x 3| x   
x  6  6  0 . Then S :

35. If the curves y2 = 6x, 9x2 + by2 = 16 intersect each (1) contains exactly two elements
other at right angles, then the value of b is: (2) contains exactly four elements
9 (3) is an empty set
(1) 4 (2) (4) contains exactly one element
2
7 Ans. (1)
(3) 6 (4)
Ans. (2)
2 2| x  3|  x  
x 6 60
put x t
y 2  6 x,9 x 2  by 2  16
6 18 x 2 | t  3 | t  t  6   6  0
m1  , m2  when t > 3
2y 2by

2018 JEE-MAINS_CODE – B Page 9


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper
2 t – 6 + t2 – 6t + 6 = 0 this ball along with two additional balls of the same
t2 – 4t = 0 colour are returned to the bag. If now a ball is drawn
t = 0 neglect as t > 3 at random from the bag, then the probability that this
t = 4. drawn ball is red, is:
when 1 3
(1) (2)
t<3 5 4
–2t + 6 + t2 – 6t + 6 = 0 3 2
(3) (4)
t2 – 8t + 12 = 0 10 5
Ans. (4)
(t – 6) (t – 2) = 0
4 red ball and 6 black ball
t = 6 as t < 3.
Case -1 probability when first ball is drawn is red
t=2
4 6
Now x  4 = 
10 12
and x  2 Case-2 : probability when first drawn ball is black
 x = 16, 4 6 4
= 
exactly two element. 10 12
38. If sum of all the solutions of the equation 4 6 6 4
PE    
     1 10 12 10 12
8cos x    x  cos   x     1 in  0,  is k ,
 6  6  2 48 2
then k is equal to:   .
120 5
8 20
(1) (2) 1 1
9 9 40. Let f  x   x2  and g  x  x  ,
x2 x
2 13
(3) (4) f  x
3 9 x  R  1,0,1 . If h  x   , then the local
Ans. (4) g  x
minimum value of h(x) is:
     1
8cos x  cos   x  cos   x     1 (1) (2)
2 2 2 2
 6  x  2
(3) 3 (4) –3
     
4cos x  2cos   x  cos   x   1  1 Ans. (2)
 6  6   2
 1  1
 
4cos x  cos  cos 2 x  1  1 f  x   x2  2
x  2
3 x  x
 
1
 1 g  x  x 
4cos x  cos 2 x    1 x
 2 2
4cos x cos 2 x  2cos x  1  1
x  2
x
2 cos x  cos3x  2cos x  1 h  x  
 1
2 cos 3 x  1 x 
 x
1  5 7  
cos3x  3x  , , 
2 3 3 3 1 2 
h  x   x  
 5 7  x  1
x , ,  x 
9 9 9   x
0x  1  2  1 
h ' x   1  2   2 
1 2 
Sum of sol.  x   1  x 
x 
 5 7  13 13  x
     k
9 9 9 9 9 for maxima or minima
39. A bag contains 4 red and 6 black balls. A ball is drawn h ' x  0
at random from the bag, its colour is observed and

2018 JEE-MAINS_CODE – B Page 10


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper

  Ans. (4)
  Equation of tangent : x – y + 16 = 0
 1  2 0
 1  2 
1 
 x   1
2 Equation of normal = 2x + y – 48 = 0
 x   A (–16, 0), B (24 , 0)
  x  
2 C is the mid point of AB (4, 0)
 1
x  2 4
 x Slope of PC :
3
1 Slope of PB : – 2. P(14,16)
x  2
x
minimum value at 4
2= 2 2 = 2 2. 2 
B(24, 0)
3 A(-16,0) C(4,0)
41. Two sets A and B are as under:  tan   2
8
A   a, b  R  R :| a  5| 1 and |b – 5| < 1}: 1
3
B=  a, b   R  R : 4  a  6 2

 9(b  5)2  36] x  4 2x
2x
2x
x4 2x
Then : 44. If = (A + Bx) (x – A)2, then
(1) A  B   (an empty set) 2x 2x x4
(2) neither A  B nor B  A the ordered pair (A, B) is equal to:
(3) B  A (1) (–4, 5) (2) (4, 5)
(4) A  B (3) (–4, –5) (4) (–4, 3)
Ans. (4) Ans. (1)
for set A : x4 2x 2x
–1 < a – 5 < 1 and –1 < b – 5 < 1 2
2x x4 2 x   A  Bx  x  A 
 4 < a < 6 and 4 < b < 6 2x 2x x4
for set B:
R1  R1  R2  R3
 a  6  2  b  5 2 5x  4 5 x  4 5x  4
 1
9 4
2x x4 2x
(a, b) lies inside or on the boundary of the ellipse
whose centre is(6, 5) 2x 2x x4
hence A  B 1 1 1
42. The Boolean expression ~  p  q    ~ p  q  is  5x  4 2 x x4 2x
equivalent to: 2x 2x x4
(1) q (2) ~q C1  C1 – C2
(3) ~p (4) p C2  C2 – C3
Ans. (3)
0 0 1
~  p  q  ~ p  q
 5x  4  x  4 x  4 2x
=  ~ p ~ q    ~ p  q  0 x4 x4
~ p  ~ q  q (5x – 4) × (x + 4)2 = (A + Bx) (x – A)2
~ p  t ~ p B=5
43. Tangent and normal are drawn at P (16, 16) on the A=–4
parabola y2 = 16x, which intersect the axis of the (–4, 5)
parabola at A and B, respectively. If C is the centre 45. The sum of the co-efficients of all odd degree
of the circle through the points P, A and B and terms in the expansion of
CPB   then a value of tan  is : 5 5

4
   
x  x3  1  x  x3 1 ,  x  1 is :
(1) 3 (2) (1) 1 (2) 2
3
1 (3) –1 (4) 0
(3) (4) 2 Ans. (2)
2

2018 JEE-MAINS_CODE – B Page 11


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper
5 5
 2m  3 
 x  x3  1    x  x3  1  P
 m
,0 

0
 2
 2  5 C0  x 

5
 x2  1   C  x  x
5
2
3 2
  
 1  5 C3  x  x 2  1 

Q  0, 3  2m

 5.42 5  2m  3
 2  x5 
1, 2
 
x  x 3  5.x x 4  1  2 x 2    h
m
 
k  3  2 m , 2m  3  k
 2 1  10  10  5  5  10  =2
46. Let a1, a2, a3,,,,,, a49 be in A.P. such that 3k
m
12 2
a 4 k 1  416 and a + a = 66. If
9 43 3
k 0 2h 
a12 
a22  .....  a17
2
 140m , then m is equal to: m
3
(1) 34 (2) 33 m
(3) 66 (4) 68
2h
3k 3
Ans. (1)  
2 2h
a1 + a5 + a8 + a13 + a17 + a21 +.....+a49 = 416
6  2 k  3k  6 h  2 k  hk
a + (a + 4d) + a + 8d) + (a + 12d) + (a + 16d) + (a
+ 20d) + (a + 48d) = 416 3x  2 y  xy
13a + 4d (1 + 2 + 3 + 4......+12) = 416 
2
12  13 sin 2 x
13a + 4d
2
 416 48. The value of 1  2 x

dx 
is:

13a + 4d × 78 = 416 2

13a + 78 × 4d = 416 
(1) 4 (2)
Using a9 + a43 = 66 we get a = 33 – 25d 4
416  312d  
 33  25d (3) (4)
13 8 2
416 – 312 = 429 – 325d Ans. (2)
325d – 312d = 429 – 416

13d = 13 2
s in 2 x
d = 1, a = 8 Let I   dx ......(1)
 1 2x

a12  a22  .......  a17
2 2

 82  92  .......  242 
= 140 m, on solving m = 34. 2
sin2 xdx
47. A straight line through fixed point (2, 3) intersects I   1 2
x .....(2)
the coordinate axes at distinct points P and Q. If O is 
2
the origin and the rectangle OPRQ is completed, then
the locus of R is: (1) + (2)
(1) 3x + 2y = xy (2) 3x + 2y = 6xy  
2 2
(3) 3x + 2y = 6 (4) 2x + 3y = xy 2
2I   sin x dx ; 2 I  2 sin 2 x dx .....(3)

Ans. (1)  0
2
Q R(4, k)
A(2,3k) 
2
I  2 cos2 xdx
 .......(4)
(3,0) P
0

y  3  m x  2

mx  y   3  2m   0

2018 JEE-MAINS_CODE – B Page 12


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper

9 9
2 2

2I   dx I 51. If   xi  5  9 and   x  5i  45 then the
4 i 1 i 1
0
standard deviation of the 9 items x1, x2......x9 is:
49. Let g(x) = cos x2, f (x) = x , and ,       be (1) 2 (2) 3
the roots of the quadratic equation (3) 9 (4) 4
18 x  9x    0 . Then the area (in sq. units)
2 2 Ans. (2)
9 9
bounded by the curve y   gof  x  and the lines i 1
 xi  5  9  x
i 1
2
i  25  10 xi  45 
x  , x   and y = 0, is : 9 95
2
1 1
 xi  45  9 x i  225  10  xi  45
(1)
2
 3 2  (2)
2
 2 1  i 1 i 1

 xi  54  xi2  225  540  45


1 1  xi2  45  540  225
(3)
2
 3 1 (4)
2
 
3 1
= 585 – 225 = 360
Ans. (3) 2
 xi2   xxi 
6   
18 x 2  9x  2  0 9  4 
9  2
    360  54 
18 2    40  36  2
9  9 
81 2  722 3  52. The integral
|    |  
18 18 6 sin 2 x cos2 x
2
 2
dx
is
    
  sin 5 x  cos3 x sin 2 x  sin 3 cos 2 x  cos5 x 
18 2 equal to:

   1 1
6 (1) C (2) C
y = cos |x| = cos x 1  cot3 x 1  cot 3 x
  1 1
 ,  (3) C (4) C
3 6 3(1  tan 3 x ) 3(1  tan 3 x )
3 1 (where C is a constant of integration)
integrating we get  .
2 Ans. (4)
50. For each t  R let [t] be the greatest integer less
than or equal to t. Then sin 2 x cos 2 x dx
 2
1 2  15  
lim x        .....      sin 5
x  cos3 x cos 2 x  sin 3 x cos 2 x  cos5 x 
x 0 
 x  x  x 
(1) is equal to 120 sin 2 x cos2 xdx
 2
(2) does not exist( in R)  sin 3

x  cos3 x sin 2 x  cos2 x 
(3) is equal to 0
sin 2 x cos2 x dx
(4) is equal to 15.  2
Ans. (1)  sin 3
x  cos3 x 
 1  2  3  ...  15  1  2 15   tan 2 x sec 2 x dx
x   lim x       ......     2
 x  x0   x   x   x  1  tan x  3

 120  put 1 + tan3 x = t.


(using sandwich theorem)
x 0 1
 x 
tan2x sec2 x dx = dt.
3

2018 JEE-MAINS_CODE – B Page 13


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper

1 dt 1 2 2

3 t2
 y
2
2 
36 2
1 y 2 2  2  9 2
 dc   

3 1  tan 3 x  . 2 18 2 18
| x|

53. Let S = | t  R : f  x  | x   | . e  1 sin | x | is not 82
y
differentiable at t}. Then the set S is equal to: 9
55. Let u be a vector coplanar with the vectors
(1)  (2) 0,   
a  2iˆ  3 ˆj  kˆ and b  ˆj  kˆ . If u is perpendicular
  
(3)  (an empty set) (4) {0} to a and u.b = 24, then | u |2 is equal to:
Ans. (3)
(1) 256 (2) 84

f  x  | x   | e|x|  1 sin | x |  (3) 336 (4) 315
Ans. (3)

 
  x    e x  1 sin x , x  
  
 a  2iˆ  3 ˆj  kˆ , b  ˆj  kˆ , u .a  0
= 
x
 
   x  e  1 sin x, 0  x      
u  xa  yb , u .b  24

    x  e x  1 sin x, x  0    
 u .a  xa.a  ya.b  0
f(x) is differentiable at x = 0,  . 14 x  2 y  0
Hence it is differentiable at x  R  
u .b  xa.b  y | b |2
54. Let y = y (x) be the solution of the differentiable
24 = 2a + 2y
dy
equation sin x  y cos x  4 x, x   0,   . If x + y = 12
dx
 x = – 2, y = 14
    
y    0 then y   is equal to:
 2 6 u  2 a  14b  4iˆ  6 ˆj  2kˆ  14 ˆj  14 kˆ

8 2 4 2 u  4iˆ  8 ˆj  16 kˆ
(1)   (2)   
9 9 | u | 16  64  256  336
4 2 8 2
(3)  (4)  56. The length of the projection of the line segment joining
9 3 9 3 the points (5, –1, 4) and (4, –1, 3) on the plane
Ans. (1) x + y + z = 7 is :
dy
sin x  y cos x  4 x 1 2
dx (1) (2)
3 3
dy
 y cos x  4 x cos ec x 2 2
dx (3) (4)
3 3
I.F. = e  cot x dx  e logsin x  sin x
Ans. (2)

y.sin x  4 x dx

y sin x  2 x 2  c C B(5,-1,4)

2  2 A(4,-1,3)
0 c
4
A’ B’
2
c
2
AC
2 2
AC  AB.
 y sin x  2 x  | AC |
2
iˆ  ˆj  kˆ 2

Now y    
 iˆ  kˆ .
3

3
6

2018 JEE-MAINS_CODE – B Page 14


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper
Ans. (3)
2 2 4 2
A ' B '  BC  AB  AC  2   No. of ways of chosing = 6 C4 3 C1
3 3
No. of arrangements with dictionary in middle = 4!
2
Length of projection  . Total ways = 6 C4 3 C1  4! 36 P4  1080 .
3
59. Let A be the sum of the first 20 terms and B be the
57. PQR is a triangular park with PQ = PR = 200m. A
sum of the first 40 terms of the series 12 + 2.22 + 32
T.V. tower stands at the mid point of QR. If the angles + 2.42 + 52 + 2.62 .... If B – 2A = 100  , then  is
of elevation of the top of the tower at P, Q and R equal to:
respectively 45°, 30 ° and 30°, then the height of the (1) 464 (2) 496
tower (in m) is: (3) 232 (4) 248
Ans. (4)
(1) 100 3 (2) 50 2
12 + 32 + 52 + ......+202 + [22 42 + 62 + ......+202]
(3) 100 (4) 50
22 [12 + 22 + 32 + ......+102]
Ans. (3)
E 26  21 41 4  16 11 21
R A 
63 63
2870 + 220 × 7 = 4410
0m

D
40  41  81 20  21  41
20

B  = 33620
63 63
P Q
200 m B – 2A = 24800 = 100 
DPE  45 , DQE  30 , DRE  30 60. Let the orthocentre and centroid of a triangle be
DE = PD A (–3, 5) and B(3, 3) respectively. If C is the
DE 1 circumcentre of this triangle, then the radius of the
 tan 30  , DQ  3DE circle having line segment AC as diameter, is:
DQ 3
DE 1 5 3 5
 tan 30  , DR  3DE (1) 3 (2)
DR 2 2 2
DQ = DR (3) 10 (4) 2 10
PQ  3PD Ans. (1)
2 1
 PQD  30 O
G C
PD 1 (-3,5) (3,3) (x’, y’)
 sin 30 
PQ 2 Let circumcentre  x ', y '
PQ 200
PD  DE    100 2 x ' 3
2 2 3
3
58. From 6 different novels and 3 different dictionaries,
x'  6
4 novels and 1 dictionary are to be selected and
arranged in a row on a shelf so that the dictionary is 5  2y'
3
always in the middle. The number of such 3
arrangements is: y'  2
(1) at least 500 but less than 750 circumcentre (6, 2)
(2) at least 750 but lesst han 1000 AC  81  9
(3) at least 1000 AC  90
(4) less than 500 5
Radius = 3 .
2

2018 JEE-MAINS_CODE – B Page 15


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper

Part - C (CHEMISTRY) (a) (b)


Multiple choice questions with only ONE option correct.
61. Total numbers of lone pair of electrons in I3 ion is
(1) 9 (2) 12 (c) (d)
(3) 3 (4) 6
Ans. (1) (1)
It is sp3d-hybridised and has linear stucture so it
has total 9 lone pairs. (2)
62. Which of the following salts is the most basic in (3)
aqueous solutin?
(1) FaCl 3 (2) Pb(CH3COO)2 (4)
(3) Al(CN)3 (4) CH3 Cook Ans. (1)
Ans. (4) Due to conjugation of loan pair of electron with pie-
CH3COOK bond (c) is more basic than (d).
It is Salt of WA and SB so due to hydrolysis (d) is secondary amine whereas (a) is primary
its solution will be strongly basic. amine.
63. Phenol reacts with methyl chloroformate in the (b) is least basic because NH is attached with sp2-
presence of NaOH to form product A. A reacts hybridised carbon.
with Br2 to form produt B, A and B are respectively 65. A alkali is titrated against an acid with methyl orange
as indicator, which of the following is a correct
combination?
(1) Base Acid End point
(1) Weak Strong Yellow to pinkish red
(2) Strong Strong Pink to colourless
(3) Weak Strong Colour to pink
(2) (4) Strong Strong Pinkish red to yellow
Ans. (1)
Methyl orange is red pink when ph is less than 3.1
and yellow when ph is more than 4.4.
With SA and SB and point will be at ph = 7 and thus
(3)
it will not indicate the end point.
With WB and SA, it will give end point and its colour
will change from yellow to red.
66. The trans-alkenes are formed by the reduction of
alkynes with
(4)
(1) Na/ tiq. NH3 (2) Sn – HCl
(3) H2 . Pd/C BaSO4 (4) NaBH4
Ans. (1) Ans. (1)
NaOH
Phenol + methyl chloroformate  Birch reduction.
67. The ratio of mass percent of C and H of an organic
Br2
compound (Cx HY OZ) is 6 : 1. If one molecular of
 the above compound (Cx HY OZ) contains half as
much oxygen as required to burn one molecule of
A B compound CXHY completely to CO2 and H2O. The
64. The increasing order of basicity of the following emporical formula of compound CXHYOZ is
compounds is : (1) C3 H4 O 2 (2) C2 H4O3
(3) C3 H6 O 3 (4) C2H4 O

2018 JEE-MAINS_CODE – B Page 16


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper

Ans. (2)
Combustion equation is
CXHY + (x + y/4)O2  x CO2 + y/2 H2O
(1) (2)
Given is molecule contains half as much oxygen as
required for combustion.

 y  1
Thus   x   2    z
 4  2
4x + y = 4z ...(i) (3) (4)
Also given that the ratio of masses of C and H is
x  12 6
 Ans. (2)
y 1 1
2x = y ...(ii)
x:y=1:2
from (i) and (ii)
4x + 2x = 4z
70. How long (approximate) should water by
6x = 4z
electrolysed by passing through 100 ampres current
x:z=2:3 so that the oxygen released can completely burn
Therefore x : y : z = 2 : 4 : 3 27.66 g of diborane?
and thus the formula is C2H4O3. (Atomic weight of B = 10.8 u)
68. Hydrogen peroxide oxidies [Fe (CN) 6 ] 4– to (1) 3.2 hours (2) 1.6 hours
[Fe(CN) 6 ] 3 in acidic medium but reduces (3) 6.4 hours (4) 0.8 hours
[Fe(CN)6]3– to [Fe(CN)6]4– in alkaline medium. The
other products formed are, respectively: Ans. (1)
(1) H2O and (H2O + O2) B2H6 + 3O2  B2O3 + 3H2O
(2) H2O and (H2O + OH–) (2  20.8+6  1) (3  2  16)
(3) (H2O + O2) and H2O = 27.6 gm = 96 gm
(4) (H2O + O2) and (H2O + OH–) 27.66 gm of B2H6 = 96 gm of O2
Ans. (1) E
W= i t
In Acidic Medium :- 96500
2[Fe(CN)6]4– + 2H+ + H2O2  2[Fe (CN)6]3– +
8
2H2 O 96 =  100  t
96500
In Alkaline Medium :-
[Fe(CN)6]3– + 2OH– + H2O2  [Fe (CN)6]4– + O2 96  96500
+ 2H2O  t= sec
8  100
69. The major product formed in the following reaction
96  96500
is = hrs = 3.21 hrs.
8  100  60  60
71. Which of the following lines correctly show the
temperature dependence of equilibrium, K, for an
exothermic reaction

2018 JEE-MAINS_CODE – B Page 17


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper
Ans. (3)
CHO
|
K I/ 
(C H O H ) 4  CH 3  CH 2  CH 2  CH 2  CH 2  CH 2
|
CH 2OH

74. Consider the following reaction and statements



 Co  NH 3  Br2   Br  
 4 
(1) C and D (2) A and D
(3) A and B (4) B and C  Co  NH 3  Br3   NH 3
 3 
Ans. (3)
I. Two isomers are produced if the reactant
K = Ae H / RT complex ion is a cis-isomer.
For Exothermic reaction H = -ve II. Two isomers are produced if the reactant
complex ion is a transisomer.
Therefore K = Ae  H / RT
III. Only one isomer is produced if the reactant
Taking ln on both sides complex ion is a transiomer
H  1  IV. Only one isomer is produced if the reactant
ln K = ln A +   complex ion is a cis-isomer.
R T
The correct statements are:
Comparing with equation of line
(1) (III) and (IV) (2) (II) and (IV)
y = C + mx
(3) (I) and (II) (4) (I) and (III)
Thus slope is +ve
Ans. (4)
Therefore Ans is (3) A and B.
[Co(NH3)4 Br2]+ + Br–
72. At 518° C, the rate of decomposition of a sample of
Cis  2 Isomers [Fac and mer]
gaseous acetaldehyde, initially at a pressure of 363
Torr, was 1.00 Torr s–1 when 5% had reacted and trans  1 Isomer..
0.5 jTorr s–1, when 33% had reacted. The order of 75. The major product of the following reaction is
the reaction is
(1) 1 (2) 0
(3) 2 (4) 3
Ans. (3)
According to rate law = R = K[A0]n
 at 5%  R1 = K[95]n ...(i)
at 33%  R2 = K[67]n ...(ii)
Dividing (i) by (ii) (1) (2)
R1 (95) n

R 2 (67) n

n
1  95 
 
0.5  67  (3) (4)
2 = (1.42)n
n = 2. Ans. (4)
73. Glucose on prolonged heating, with HI gives:
(1) Hexanoic acid (2) 6-iodohexanal
(3) n-Hexane (4) 1-Hexene

2018 JEE-MAINS_CODE – B Page 18


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper
76. Phenol of treatment with CO2 in the presence of [Ba2+] = 1 10 10  10  1  10 9
NaOh followed by acidification produced compound
X as the major product. X on treatment with (CH3 1  109  500
CO)2O in the presence of catalytic amount of [Ba2+]initial =
(500  50)
H2SO4 produced
1  109  500
=  1.1  109
450
78. Which of the following compounds will be suitable
for Kjeldahl’s method for nitrogen estimation?

(1) (2)
(1) (2)

(3) (4)

(3) Ans. (4)


Organic compound + conc. H2SO4  (NH4)2SO4
79. When metal ‘M’ is treated with NaOH, a white
gelatinous precipitate ‘X’ is obtained with is soluble
in excess of NaOH. Compound ‘X’ when heated
strongly gives an oxide which is used in
chromatography as an adsorbent. The metal ‘M’ is
(1) Al (2) Fe
(3) Zn (4) Ca
(4) Ans. (1)
excess
Al + NaOH  Al(OH)3  Na[Al(OH)4]
NaOH

(White gelotinous ppt.)


Ans. (3)

77. An aqueous solution contains an unknown Al(OH)3  Al2O3
concentration of Ba 2+. When 50 mL of a 1 M used as absorbent in Chromatography.
solution of Na2SO4 is added, BaSO4 just begins to
80. An acqueous solution contain 0.10 M H2S and 0.20
precipitate. The final volume is 500 mL. The
M HCl. If equilibrium constants for the formation
solubility product of BaSO3 is 1×10–10. What is the
of HS– from H2S is 1.0 × 10–7 and that of S2– from
original concentration of Ba2+?
HS– ions is 1.2×10–13 then the concentration of S2–
(1) 1.1  10 9 M (2) 1.0  10 10 M ions in aqueous solution is
(1) 6 × 10–21 (2) 5×10–19
(3) 5  10 9 M (4) 2  10 9 M
(3) 5 × 10–8 (4) 3× 10–20
Ans. (1)
Ans. (4)
Ba2+ + Na2SO4  BaSO4 + 2Na+
50 ml of [H  ][HS ]
H2S  H+ + HS–, K1 =  1.0  107
1M [H 2S]

Ksp for BaSO4 = [Ba2+] [ SO 24  ] [H  ][S2  ]


HS–  H+ + S2–, K2 = 
 1.2  10 13
50  1 [HS ]
1 1010  [Ba 2 ] 
500

2018 JEE-MAINS_CODE – B Page 19


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper

[H  ]2 [S2  ]
 K1  K2 =
[H 2S]
(4)
2 2
1.0  10–7  1.2  10–13 = (0.2)  [S ]
0.1
Ans. (2)
20 20
1.0 1.2 10  0.1 12 10 Fact Based
 [S2–] =   31020
(0.2)2 4 84. The oxidation states of
81. The recommended concentration of fluoride ion in Cr in [Cr(H 2 O) 6 ]Cl 3 , [Cr(C 6 H 6 ) 2 ], and
dirinking water is up to 1 ppm as fluoride ion is K2[Cr(CN)2(O)2(O2)(NH3 )] respectively are:
required to make teeth enarmel harder by converting (1) +3, 0, and +6 (2) +3, 0 and +4
[3Ca3(PO4)2 . Ca(OH)2 to] :
(3) +3, +4 and +6 (4) +3, +2, and +4
(1) [3Ca3(PO4 )2 . CaF2 ]
Ans. (1)
(2) [3{Ca(OH2)} . CaF2]
For [Cr(H2O)6]Cl3
(3) [CaF 2 ]
x + 6  0 + 3  (  1) = 0
(4) [3(CaF2) . Ca(OH)2]
x = +3
Ans. (1)
For [Cr(C6H6)2 ]
Fact Based
x+2  0=0
82. The compound that does not produce nitrogen gas
x=0
by gas by the thermal decomposition is :
For K2[Cr(CN)2(O)2(O2)(NH3 )]
(1) NH4 NO2 (2) (NH4)2 SO4
2  (+1) + x + 2  (  1) + 2  (  2) + (  2) +
(3) Ba(N3 ) (4) (NH4) Cr2O7
0=0
Ans. (2)
x = +6

NH4NO2  N2 + 2H2O 85. Which type of ‘defect’ has the presence of cations
in the interstitial sites?

(NH4)2SO4  2NH3 + 2H2SO4 (1) Frenkel defect (2) Metal deficiency defect
(3) Schottky defect (4) Vacancy defect

Ba(N3)2  Ba + 3N2 Ans. (1)
 In Frenkel defect usually cations are dislocated from
(NH4)2Cr2O7  N2 + Cr2O3 + 4H2O Lattice site to the interstitial site.
83. The predominant form of histamine present in human 86. The combustion of benzene (I) gives CO2(g) and
blood is (pKa, Histidine = 6.0) H2O(I). Given that heat of combustion of benzend
at constant volume is –3263.9 kJ mol–1 at 25°C;
heat of combustion (in kJ mol–1 ) of benzen at
constant pressure will be:
(1) (R = 8.314 JK–1 mol–1)
(1) 3260 (2) –3267.6
(3) 4152.6 (4) –452.46
Ans. (2)
C6H6(l) + 15/2O2(g) = 6CO2(g) + 3H2O(l)
(2)
15 3
n(g) =  n p (g )   n R (g)  6  
2 2

H  U  n (g) RT

(3)  3 3
= 3263.9 KJ      8.314  10  298 KJ
 2 

2018 JEE-MAINS_CODE – B Page 20


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper
=  3 2 6 3 .9  3  4 .1 5 7  0 .2 9 8 Ans. (2)
= 3267.6 KJ
Tf  ik f  m
87. Which of the following are Lewis acid?
(1) PH3 and SiCl4 (2) BCl3 and AlCl3 Tfo  Tfs  ik f m
(3) PH3 and BCl3 (4) AlCl3 and SiCl4
Tfo  ik f m  Tfs
Ans. (2)
Electron deficient species are Lewis acids. Tfs  Tfo  ik f m
88. Which of the following comounds contain(s) no
covalent bond(s)? Tfo , K f and ‘m’ are same
KCl, PH3, O2, B2H6, H2SO4 Mone is the ‘i’, less will be Tfs
(1) KCl (2) KCl, B2H6
(3) KCl, B2H6, PH3 (4) KCl, H2SO4 and less is the ‘i’, more will be ‘ Tfs ’
Ans. (1) Ans is (2) because for (1), (2), (3) and (4) ‘i’ is 2, 1,
KCl is formed by the complete transfer of electron 4, 3 respectively.
from K to Cl. 90. According to molecular orbital theory, which of the
89. For 1 molal aqueous solution of the following following will not be a vaiable molecule?
compounds, which one will show the highest (1) H 2 (2) H 22 
freezing point?
(3) He 22  (4) He 2
(1) [Co  H 2 O 4 Cl 2 ]Cl.2H 2 O
Ans. (2)
(2) [Co  H 2 O 3 Cl3 ]Cl.3H 2 O
H 22  (1  2 + 2)
(3) [Co  H 2 O 3 Cl]Cl.H 2 O =4
2 2
 1s  *1s
(4) [Co  H 2 O 5 Cl]Cl 2 .H 2 O
Nb  Na 22
B.O = = =0
2 2
Zero bond order can’t be possible for existance of
a compound.

2018 JEE-MAINS_CODE – B Page 21


Sri Chaitanya IIT Academy, India JEE-MAINS Question Paper

ANSWER KEY

PHYSICS
1. (3) 2. (3) 3. (1) 4. (4) 5. (1)
6. (4) 7. (2) 8. (1) 9. (3) 10. (1)
11. (4) 12. (3) 13. (3) 14. (1) 15. (3)
16. (2) 17. (4) 18. (4) 19. (1) 20. (3)
21. (4) 22. (3) 23. (4) 24. (1) 25. (1)
26. (1) 27. (4) 28. (4) 29. (1) 30. (1)

MATHEMATICS
31. (2 ) 32. (4) 33. (1) 34. (3) 35. (2)
36. (4) 37. (1) 38. (4) 39. (4) 40. (2)
41. (4) 42. (3) 43. (4) 44. (1) 45. (2)
46. (1) 47. (1) 48. (2) 49. (3) 50. (1)
51. (1) 52. (4) 53. (3) 54. (1) 55. (3)
56. (2) 57. (3) 58. (3) 59. (4) 60. (1)

CHEMISTRY
61. (1) 62. (4) 63. (1) 64. (1) 65. (1)
66. (1) 67. (2) 68. (1) 69. (2) 70. (1)
71. (3) 72. (3) 73. (3) 74. (4) 75. (4)
76. (3) 77. (1) 78. (4) 79. (1) 80. (4)
81. (1) 82. (2) 83. (2) 84. (1) 85. (1)
86. (2) 87. (2) 88. (1) 89. (2) 90. (2)

2018 JEE-MAINS_CODE – B Page 22

Você também pode gostar