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PRODUCT AND SOLUTION HIGHLIGHTS
Overview of Coatings Light Stabilizers for Light Stabilizers for Polymer Additives
Light Stabilization Waterborne Coatings Solventborne Coatings for Powder Coatings
AUTOMOTIVE APPLICATION
OEM & REFINISH
4 Confidential – Mouhcine Kanouni / Jean-Yves Desrats, BU Additives, Business Line Polymer Additives – Technical Marketing Coatings
SB Coatings Powder
- Auto refinish
Coatings
- Processing
- Industrial
- Tribo enhancing
• Hostavin 3206 liq. - Plastic - Gas oven • Hostanox P-EPQ
• Hostavin 3212 liq. - Weathering • Hostavin VSU P
• Hostavin 3058 liq. • Hostavin 3330 P
• Hostavin 3070 Pwd • Hostavin 3070 P
• Hostavin TB-03 liq. • AddWorks LXR 537
• Hostavin TB-04 liq. • AddWorks LXR 1251
• AddWorks LXR 308
5
1. UV Absorbers Additives
Principle: absorption (filter effect) of damaging UV light
(coating thickness and dosage dependent – Beer Lambert principle)
Suggested dosage:
• Clearcoat: from 1.0% to 2.5%
• Monocoat pigmented: none to 1.0%
H H
O O H O H O
N O R
N N R
O N N N O
R
O H N N
R
BENZOPHENONES OXALANILIDES BENZOTRIAZOLES TRIAZINES
ADVANTAGES
DISADVANTAGES
PRODUCTS
• Hostavin ARO 8 • Hostavin VSU • Hostavin 3310, 3326, 3311 liq. • Hostavin 3330, 3340 liq.
• Hostavin 3042 disp. • Hostavin 3206 liq. • Hostavin 3310 disp., 3326 disp. • Hostavin 3330 disp.
7
0.7
Triazine
Absorption
0.6
0.6
0.5
Benzotriazole
0.4
0.4
0.3 Halogen. Benzotriazole
0.2
0.2
0.1 Natural sunlight
00
250 275 300 325 350 375 400 425
Wavelength [l in nm]
8
UVCON-B Xenon
Irradiation [W · m-2 nm-1]
1.2
1.2
Oxalanilide
0.8
0.8
Benzotriazole
0.4
0.4
too low film thickness optimal film thickness too low concentration
and concentration
Minimum film thickness needed to provide optimum UV protection of the coating ( > 30 μm )
10
Mechanisms of stabilization –
Selection criteria for HALS
pH (basicity)
R' R'' basic (pH) HALS
R= -H not substituted
liquid or solid
- CH3 methylated
compatibility
N non-basic HALS
R R= - O - R’ etherified migration
- C - CH3 acylated
tetra-methyl-piperidine
=
cost
O
-H - CH3
- CH3 - O - R’
Public
BZT 1130
14
Hrfiog hce
NEW Pe
rm n
a
automotive clearcoats
plastic coatings
Low color
Classification
1:1 mixture of triazine UV absorber + HALS
Hrfiog hce
NEW Pe
rm n
a
plastic coatings
Low color
Classification
2:3 mixture of triazine UV absorber + non-basic HALS
8
AddWorks LXR 308
7
in Solventborne 2K-PU
6
5
4
3
2
1
0
No additives AddWorks LXR 2% STD BZT +
308 eq. (2% STD 1% STD HALS
UVA + 1% HALS
Procedure: SB Acrylic clear coat (base resin) was prepared in the lab, Total solid content was determined to be 54%.
For each formulation the right amount of LS (1% HALS and 2% UVA based on solid content of the resin)
was weighed and mixed with Acrylic resin by Dispermat mixer (2000rpm, 5min) – color of wet paint measured after 24hrs.
20
Evaluation details
80 8
ΔE
60 6
40 4
20 2
0 0
Unstabilized Best alternative AddWorks LXR 308 Unstabilized Best alternative AddWorks LXR 308
(2:1 UVA/HALS) (2:1 UVA/HALS)
500 hrs 1000 hrs 1500 hrs 2000 hrs 500 hrs 1000 hrs 1500 hrs 2000 hrs
80 1
0.8
ΔE
60
0.6
40
0.4
20 0.2
0 0
Unstabilized Best alternative AddWorks LXR 308 Unstabilized Best alternative AddWorks LXR 308
(2:1 UVA/HALS) (2:1 UVA/HALS)
500 hrs 1000 hrs 1500 hrs 2000 hrs 500 hrs 1000 hrs 1500 hrs 2000 hrs
Light stabilizers for
Mouhcine Kanouni / Jean-Yves Desrats
BU Additives - Business Line Polymer
Additives
water-based coatings
Technical Marketing Coatings
Jan 2017
23
HALS/UVA DW
• Products are encapsulated light
stabilizers additives dispersed
in water (25-35% active),
outperform BZT 1130 & HALS
292 at significantly highest cost
Radical
UV Absorber
scavenger
Benzophenone Benzotriazole Benzotriazole Triazine hindered
Hostavin 3042 Hostavin 3310 Hostavin 3326 Hostavin 3330 amine
Disp Disp Disp Disp* Hostavin 3070
NEW Disp *
- low - good - good best - low tox
photopermance photopermance photopermance photopermance profile
Properties
- low color - high absorbance - high & broad - low
absorbance extraction
Active 40% 52% 52% 52% 52%
content
Restriction none none solubility compatibility none
max 1.0-1.5% poor in clear
acrylic
0.6
0.5
0.1
0.1
Hostavin 3311-BZT 1130
0
0
300 325 350 375 400
Wavelength [nm]
No stabilization
Hostavin 3311
+ Hostavin 3065
Substrate: pine wood, Coating: WB acrylic clearcoat, WOM exposure: according to ISO 4892-2
27
No stabilization
Substrate: pine wood, Coating: WB acrylic clearcoat, WOM exposure: according to ISO 4892-2
28
3000 hr
2.0% UVA/HALS 53DW
2500 hr
2.0% HPT 400 DW +
HALS 123DW 2000 hr
0 2 4 6 8 10 12
E after hrs. in WoM
Substrate: pine wood, Coating: WB stain based on modifed alkyd, WOM exposure: according to ISO 4892-2
29
2000
Hours in WoM
1500
1000
500
0
Hostavin 3330 Disp Hostavin 3326 Disp 2%UVA/HALS
UVA/HALS5151
51DW HPTHPT
400DW + HALS
400-DW UVA/HALS 53-DW
UVA/HALS 53DW
Hostavin 3070 Disp Hostavin 3070 Disp 123 123-DW
HALS DW
Substrate: pine wood, Coating: WB stain based on modifed alkyd, WOM exposure: according to ISO 4892-2
30
∆E (Colour change)
Gloss at 60° [%]
90 3.0
90
80
80 2.0
80
70
70 1.0
70
60
60 0
60
500 1000 1500 2000 2500 3000 500 1000 1500 2000 2500 3000
Exposure time [hrs] Exposure time [hrs]
UV ABSORBER
Hostavin 3041 disp. UV Absorber for moderate durability, most cost effective
Hostavin 3045 disp.
Hostavin 3310 disp. UV Absorber for good performance
Hostavin 3326 disp. UV Absorber with broad UV absorbance, best for wood coatings
Hostavin 3326-2 disp. Maximum dosage level 3% as is (dispersion) of binder solid
Hostavin 3070 disp. Low migration polymeric HALS for plastic & wood coatings
UVA + HALS
Good weathering LS package (UVA + HALS) for WB coatings
Hostavin 3225-2 disp. (ex. Industrial exterior wood finishes )
(2 parts Hostavin 3326 DISP + 1 part of Hostavin 3051-2 DISP)
Powder Coatings
Technical Marketing Coatings
Jan 2017
33
Improved UV protection
Standard
Reduced thermal yellowing during processing (overbaking) Performance
Extended Long term heat stability in high end applications, e.g. for architectural coatings
35
Hostanox P-EPQ –
High performance processing and heat stabilizer
Key benefits
3
• Reduced thermal yellowing during
processing > see graph AO-1: phenolic AO10
3 AO-2: Hostanox O 3
AO-5: thioether AO
2
200°C, 30 min
1
200°C, 60 min
0 230°C, 30 min
No additives Stab 1 Stab 2 Stab 3 Stab 4
4
b
1
10 min
0 30 min NOx
No additives AO-1 AO-3 AO-4
PC system: white pigmented, PES/Primid, cured at 200°C, [AO] = 0.5% on total formulation
39
Hostavin 3330 P –
High performance UV Absorber
Key benefits HPT Absorbance 10mg/L in Acetonitrile
1.8
• Innovative and cost effective triazine
UV absorber for demanding outdoor 1.6
durability of powder coatings
1.4
UV Absorbance
• High UV absorptivity for superior 1.2
protection of thin layers
1
• Superior thermal stability 0.8
• Excellent photo-permanence 0.6
0.4
0.2
0
250 275 300 325 350 375 400
nm
Hostavin 3330
CPT HPT 05
42
Hostavin 3330 P –
High performance UV Absorber
Superior weathering performances in powder coatings
• Weathering: QUV-B exposure according to ASTM G 154-05
Powder Coating Stabilized with 0.65% Powder Coating Stabilized with 1.5%
UV Absorber UV Absorber
100 5
80 4
Gloss
60 3
E
40 2
20 1
0 0
0 500 1000 1500 2000 0 400 800 1200 1600 2000
Hrs in QUV-B Hrs in QUV-B
No Stabilization COMP-BZT No Stabilizer BZT competitor
Hostavin 3330 pwd. XP COMP-HPT Hostavin 3330 pwd. XP HPT competitor
Jan 2017
44
UV Curable Coatings –
Non-interacting Light Stabilizers Additives
HALS: Hostavin 3058 liq.
Key benefits
Non interacting HALS during UV curing
Non-basic HALS with high compatibility with broad range of resins
Excellent performance for coatings on plastics
UV Curable Coatings –
Non-interacting Light Stabilizers Additives
Synergistic Solution: Hostavin TB-04 liq. (Triazine + HALS)
Combining excellent performance of Triazine UV absorber with non-basic & non
interacting HALS
Compatible with both SB and WB UV formulations
Xylene-free and low color
Standard
Performance
BZT 1130
46
ABUV 13-03 97 3
ABUV
ABUV 13-04 96 HPT UVA 4
13-01
ABUV 13-05 95 5
ABUV 13-06 90 10
2. Hardness measurement
47
Thickness
Inconsistency in coating thickness but clear trend
with increased level of HPT UVA
Significant decrease of Hardness
49
UV Absorbance Profile
UV-C UV-B UV-A visible
visible
0,8
Minimize
interaction
0,6
with Photo-
Absorption
Oxalanilide
initiator HP Triazine
0,4
Benzotriazole
0,2
– UV Stabilized Formulations
ABUV 13-29b ABUV 13-54b ABUV 13-30b ABUV 13-31b ABUV 13-57b ABUV 13-32b
1% 2% 3% 5% 7.5% 10%
H 3206 liq. H 3206 liq. H 3206 liq. H 3206 liq. H 3206 liq. H 3206 liq.
Thickness
3% HPT 3% HPT 3% HPT 3% HPT 3% HPT 3% HPT 3% HPT
1% H.3206 2% H.3206 3% H.3206 5% H.3206 7.5% H.3206 10% H.3206