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Study
dy of Polyaniline Coated Fabrics for Electromagnetic
Shielding Properties
N. Thukkaiappan
Lecturer Senior Grade
Grade, Department of Textile Technology,
Nachimuthu Polytechnic College, Pollachi
Pollachi, Tamil Nadu, India
ABSTRACT
The interference of Electromagnetic among the conductivity is higher. As metals are heavier and
appliances is one of the major problems to be solved doesn’t bend, it is better to go for textiles as they are
at present. Electro-conductive
conductive media can generate and flexible and light weight. But electromagnetic
transport free charges, which can act as an shielding property i.e. conductivity of the textiles is
electromagnetic shielding material. For light weigweight generally lower than metals. So to impart conductivity
and flexible applications, here we prefer conductive to a fabric there are many methods
ethods like metalizing the
polymer coating over textile instead of metals which textile, carbon composites, coating conductive
are preferred traditionally. In this study electrically polymers, etc. Here we have chosen polyaniline
conductive cotton, polyester and polypropylene which is an intrinsic conductive polymer. Out of the
fabrics were made by coating polyaniline. Th The three commonly used conductive polymers,
conductive fabrics were prepared by in in-situ chemical Polyaniline has the advantage of having the t most
oxidative polymerization of aniline using ammonium inexpensive monomer, which is desired for
per sulphate as the oxidant by a process of diffusion commercial feasibility. Polyaniline has a complex
polymerization in a mixed bath.. The surface structure which provides a possibility of creating
resistivity study shows that the treated fabrics shshow conductive polymers with a diverse range of
better conductivity. There are no significant properties from chemical to electrical can be
differences between the treated and untreated fabrics manipulated to produce materials with different
with respect to thickness, air permeability and conductivities. Polyaniline can be obtained either
stiffness test results. But washing and rubbing fastness chemically or electrochemically.
results show significant degradation of coating with
loss of conductive polymer. II. NEED OF STUDY
In the past few years, the modernization in field of
Keywords: Polyaniline, Intrinsically conductive science and technology has created a new kind of
polymer, Electromagnetic Experiments for EMI SE pollution, i.e. electromagnetic interference (EMI). The
advances in electronics reduce the component size
I. INTRODUCTION and placing more number of electrical parts in limited
Electrical and electronic systems in various fields space. Placing more number of components in a very
emit electromagnetic radiations in various wavelength confined space builds the problem of keeping
and frequencies. These radiations can interfere with electromagnetic interference of these systems from
other electronic devices and humans which can cause interfering with other systems through radiation.
various problems. Electromagnetic shielding iis a These radiations intentionally or unintentionally affect
process of limiting the penetration of electromagnetic the activity of the other system, resulting in reduced
fields into a space, by blocking them with a barrier performance or damage of the exposed systems. For
which must be a conductive material. Traditionally example, interference of signal of television and
such shields are made of metallic materials as their
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International Journal of Trend in Scientific Research and Development (IJTSRD) ISSN: 2456-6470
evaluated by means of polyaniline fading and Polypropylene shows lower air permeability value
polyaniline staining according to the gray scale. even before coating, which is due its fabric structure.
Electrical Resistivity
The electrical resistance measurements were
performed on all samples after conditioning the
samples in a standard atmosphere. The resistance was
measure ten times in each side of the sample and the
average values were taken. The American association
of textile chemists and colourists test method 76-1995
was used to measure the resistance of the samples and
the surface resistivity of the fabric was calculated as
follows
R=Rs(I/w)
Where, R is the resistance in ohms, RS is the sheet
resistance or surface resistivity in ohms / square, I is
the distance between the electrodes in cm, w is the From the analysis it is evident that there is no
width of each electrode in cm. significant difference in air permeability between the
coated and uncoated fabrics as (4.48 < 18.51) null
VII. TEST RESULTS hypothesis is accepted, there is only minimal decrease
Air Permeability in air permeability value but there is no significant
difference. There is significant difference in air
permeability between the fabrics as (248.2277 > 19).
This variation is because that all the three fabrics are
of different types and also different structures, the
cover factors vary high leading to large variations in
the results and thus these variations should not be
taken into significant considerations as they are not of
same specifications.
Stiffness Results
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International Journal of Trend in Scientific Research and Development (IJTSRD) ISSN: 2456-6470
The above graph shows the stiffness difference Rubbing Fastness Results
between the coated and uncoated fabrics. It is
surprising that cotton alone shows a different
behaviour apart from the other two synthetic fabrics.
For synthetic fabrics there is a general increase in
bending length due to coating, but for cotton the
uncoated fabric has higher bending length compared
to polyaniline coated fabric. The reason behind this is
that the polymer accumulates in fibre interstices or the
polymer coating is thick enough it causes fibres to
make contact with each other over a longer length. So
it is evident that cotton fabric after coating was stiff as
it deformed under its own weight. But for other two
synthetic fabrics the uncoated fabrics were stiff which
is due to their inherent in-extensibility property.
Bending Length (cm) From the graph it is evident that there is degradation
FABRICS BEFORE AFTER in coating with loss of part of the conductive polymer.
COATING COATING Comparatively, polyester fabric had resistance against
COTTON 3.1 2.9 rubbing as polyaniline had better adherence with
POLYESTER 2.9 2 polyester. Polypropylene showed a very poor
POLYPROPYLENE 3 3.9 resistance against rubbing as after ten cycles, almost
the whole coating was degraded.
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International Journal of Trend in Scientific Research and Development (IJTSRD) ISSN: 2456-6470
Electrical resistivity results conductive polymer coated fabrics can even be used
in other areas.
IX. REFERENCES
1. Anupama J. and Suwarna D., “Carbon
Nanostructure Composite for Electromagnetic
Interference Shielding”, Pramana - Journal of
Physics, Vol. 84, No. 6/2015, pp. 1099- 1116.
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with polyanline is shown in the above graph. The Ananjan B., “Electromagnetic Shielding
results show that polyaniline can be coated over Behaviour of Conductive Filler Composites and
cotton, polyester and polypropylene fabrics and thus Conductive Fabrics - A Review”, Indian Journal
provide electrical conductivity. Comparatively of Fibre and Textile Research, Vol. 39, No.
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VIII. CONCLUSION 4. Cochrane C., Vladan K., Maryline L. and Claude
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resistivity of electrically conductive polyaniline Sensor for Textile Structures Based on a
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