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This paper discusses the utilisation of coal-ash (CA) mixtures (bottom ash (BA) and fly ash (FA)) as aggregates for
concrete. An optimised mix of BA to FA of 60:40 could produce a basic dense mix of CA suited for aggregates. The
aggregates were prepared by pelletisation followed by cold bonding, using the optimised mix blended with cement
as a binder. The influence of chemical activators – namely, sodium sulfate and calcium hydroxide – for enhancing,
respectively, the reactivity of the CA mix and the pelletisation efficiency was explored in the study. For comparison,
two types of aggregates were produced with a higher proportion of either BA or FA. Aggregates were tested for
physical and mechanical properties; microstructural and mineralogical aspects were explained through scanning
electron microscopy and X-ray diffraction analysis. The performance of CA aggregate concrete and normal concrete
were investigated using compressive strength testing. The curing sensitivity of CA aggregate concrete was assessed
under different curing regimes – namely, water, air and sealed.
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Waste and Resource Management Performance evaluation of
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in concrete
Menon, Anand and Sharma
shown improved strength (Kayali, 2004) and enhanced tensile normal aggregate replaced with ash aggregate (Park et al.,
strain capacity (Wishwesh and Anand, 2017). 2009). In cold-bonded FA aggregates with high water-absorp-
tion capacity, moisture migration from the aggregate to the
Studies reported that CA – mainly FA – can be utilised in the cement paste phase in concrete assists in the formation of
production of lightweight aggregates as well as lightweight hydrated products even in the absence of normal water curing
concrete (Baykal and Döven, 2000; Bijen, 1986). The pelletisa- (Joseph and Ramamurthy, 2010). The use of BA fine aggre-
tion process adopted for producing lightweight coarse aggre- gates (produced by cold bonding) for high-strength mortar
gate involves agglomeration of moisturised fines in a rotating also exhibited internal curing efficiency (Kim et al., 2016).
drum or disc (Bijen, 1986; Harikrishnan and Ramamurthy,
2006). Pelletisation is generally followed by any of the 3. Materials and methodology
following three types of hardening processes: cold bonding, In the following sections, the evaluation of materials has been
autoclaving and sintering. Autoclaved and steam-cured FA carried out as per codes of practice and specifications from
aggregates showed inferior properties (water absorption, 10% both Indian Standards (IS) and British Standards (BS).
fines value) as compared with normal water-cured aggregates
(Manikandan and Ramamurthy, 2008).
3.1 Material characteristics
Pelletised aggregates using FA of higher specific surface, Coal ash. BA and FA, the two types of CA used in the study,
lower calcium oxide (CaO) content and lower specific gravity were procured from a nearby lignite coal-based thermal power
show enhanced engineering properties (Gesoğlu et al., 2007). plant. The specific gravity of BA was 2·42, and that of FA was
Pelletisation has also been carried out with the inclusion of a 2·61. The chemical compositions of the two types of CA are
binder to improve the property of aggregates. The binders used shown in Table 1.
in several studies include lime and cement (Baykal and Döven,
2000), bentonite (Manikandan and Ramamurthy, 2009) and Cement. Locally available 53 grade ordinary Portland cement
also kaolinite (Manikandan and Ramamurthy, 2007). The conforming to IS 12269 (BIS, 2013) was used in small
influence of these binders on the properties of the aggregates amounts as an activator to enhance the pozzolanic reaction.
depended on the blend quantity during pelletisation as well as
the hardening process adopted. The addition of cement and Chemical additives. Laboratory-grade calcium hydroxide and
lime significantly improved the strength of FA aggregates sodium sulfate were used as chemical additives in CA mixtures
(Baykal and Döven, 2000). for property enhancement.
Coarse BA has been utilised as a coarse aggregate in concrete 3.2 Experimental programme
(Park et al., 2009). It is reported that such coarse aggregates sat- Trials were conducted on mixtures with the aim of utilising
isfied the American Society for Testing and Materials (ASTM) larger proportions of low-value BA along with FA having
requirements for soundness and abrasion resistance. BA in fine binding properties. After optimising the mixture, the effects of
particle form has been used to prepare cold-bonded aggregates binder and chemicals on the mix for property enhancement
(Geetha and Ramamurthy, 2010a). The geo-polymerisation were studied. The pelletisation process was used for the
method of low-calcium BA aggregate preparation has also been
reported; it involves activating in an alkaline medium and curing
Table 1. Chemical composition of CA
at moderate temperatures (Geetha and Ramamurthy, 2013).
Ash type
In the pelletisation process, chemical additives such as calcium
BA FA
chloride, sodium sulfate and calcium sulfate are incorporated
Oxide (proportion in %) (proportion in %)
in order to enhance the strength of the aggregates. The
addition of sodium sulfate increases the reactivity of BA to Aluminium oxide 22·20 25·16
produce the hydrated product ettringite, thereby enhancing Silicon dioxide 51·20 21·23
Sulfur trioxide 0·23 9·28
the aggregate’s strength (Geetha and Ramamurthy, 2010a). In Calcium oxide 1·20 32·86
the preparation of BA aggregates, a dosage of 2% calcium Ferric oxide 20·30 4·86
hydroxide along with the mixing water increased pelletisation Magnesium oxide 0·80 4·95
efficiency and decreased the binder requirement (Geetha and Sodium oxide 0·25 0·43
Ramamurthy, 2010b). Phosphorus pentoxide 0·35 0·58
Potassium oxide 2·26 Nil
Titanium dioxide 1·10 0·62
Studies on concrete using BA aggregate showed a reduction in Loss on ignition 0·11 0·03
the compressive strength with the increasing amount of
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Waste and Resource Management Performance evaluation of
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in concrete
Menon, Anand and Sharma
preparation of aggregates, which were tested for physical and 4.2 Influence of chemical additives
mechanical properties. Later, CA aggregate concrete was pre- The two aspects that were considered for the preparation of
pared and its properties were assessed at different ages and aggregates are: (a) the aggregate strength and (b) the efficiency
with different methods of curing. of pelletisation. Chemical additives were incorporated to acti-
vate the reaction.
It was observed that, when the amount of BA was increased, 4.2.2 Effect of sodium sulfate on strength
the rolling efficiency gets reduced. For BA-to-FA proportions Sodium sulfate was trialled as a chemical activator to enhance
of 80:20 and 70:30, the efficiency to become a pellet was found the strength of the pellet, based on the approach of enhancing
to be lower compared with the proportion 60:40. It was also the pozzolanic reactivity of FA through chemical activation
observed that increasing the BA resulted in the pellets having and thus improving strength (Shi and Day, 1995). Sodium
a rough surface when compared to pellets with lower BA sulfate dosages of 2–4% by weight of CA was adopted. The
content. Hence, in terms of rolling efficiency, a BA:FA pro- effect of sodium sulfate was studied for the optimised mix of
portion of 60:40 was satisfactory. BA, FA and cement (60:30:10) and the results are shown in
Table 3.
When the strength result was analysed, the proportion
60:40 showed higher strength when compared with the 70:30 The results show that sodium sulfate helps in improving
and 80:20 proportions. Among the selected proportions of the strength of the optimised mix. Significant differences
CA, the variation in the water-absorption value was only in strength were not observed while using either 2 or 4% of
marginal. Considering the three aspects, the proportion of BA sodium sulfate. Hence, the lower dosage of 2% of sodium
and FA in the ratio of 60:40 was selected as the optimised mix sulfate was chosen.
and adopted for the next stage of the study on improving
aggregates’ properties through the binder and chemical The proportion 60:30:10 BA, FA and cement, respectively,
additives. with the incorporation of 2% each of calcium hydroxide and
sodium sulfate was selected for the preparation of aggregates.
The inclusion of cement as binder was done by replacing Concurrently, another mix was also selected for the prep-
a portion of FA from the optimised mix, as this study aration of aggregates, with the same proportion but of higher
mainly focused on the higher quantity utilisation of BA. FA content – that is, 60:30:10 FA, BA and cement, respect-
Consequently, the proportion 60:30:10 of BA:FA:cement was ively. The properties of aggregates prepared with both these
selected as the optimised mix for the preparation of aggregates. mixes are discussed in the next section.
1 60:30:10 0 33 50 35
2 60:30:10 2 23 15 70
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Waste and Resource Management Performance evaluation of
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Waste and Resource Management Performance evaluation of
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A: Quartz
B: Ettringite
C: Calcium silicate hydate
D: Calcium aluminium silicate hydrate
E: Mullite
Intensity: counts
A E
A B
D
C A
Type B B D B E E
10 20 30 40 50 60 70 80
(a)
Position: 2θ
(b)
The sample was subjected to an electron beam from a Zeiss
EVO 18 scanning electron microscope. SEM images from
Figure 2. SEM image of (a) type B aggregate, (b) type F
samples of types B and F aggregates are shown in Figures 2(a) aggregate
and 2(b), respectively. The micrographs were captured to include
the pores inherently present in the aggregate and also the for-
mation of hydration products (Bae et al., 2014; Xu and Sarkar,
1994). The SEM image of type B aggregate indicates the rela-
bulk density compared with the normal aggregates. The CA
tively larger share of distributed smaller pores, whereas in type F aggregate concretes prepared with aggregate types B and F have
aggregate, larger pores predominate. The larger pore size of
been referred as BC and FC, respectively. Normal aggregate
type F aggregate leads to a higher rate of water absorption when
concrete (NC) consisting of natural granite coarse aggregate
compared with type B. Also, a better-interconnected matrix is and sand as fine aggregate was also prepared. The nominal
seen in the case of type B, which results in better mechanical
size (20 mm) of coarse aggregate was adopted for all mixes.
properties (Ghosh and Subbarao, 2001). In case of type F aggre-
gates, there is a lack of bonding which may be the reason for The main aim at this stage was to prepare moderate-strength
their lower strength. The inference made from the SEM analysis
concrete using the low-density CA aggregate and compare its
supports the properties observed in the two aggregate types.
strength with similarly proportioned concrete using normal
aggregate. Curing sensitivity of CA aggregate concrete was
5. Concrete with CA aggregates analysed under different curing regimes to assess the self-
Due to the lower specific gravity of CA aggregates, the con- curing efficiency. Water sorptivity of CA aggregate concrete
crete made by using CA aggregates will have a lower value of was also checked for all the selected curing regimes.
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Waste and Resource Management Performance evaluation of
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5.1 Mix proportioning expressed as a percentage of the oven-dried mass of the aggre-
The concrete mix was proportioned according to IS 10262 gate. The aggregates were extracted from 15 mm below the
(BIS, 2009) for M20 grade with a slump of 100 mm. As the outside layer of concrete because these aggregates were not in
CA aggregates were round in shape, water correction was contact with the outside atmospheric conditions. About 100 g
applied as per standards. In the case of CA aggregates, the of aggregates was extracted from samples of each curing
initial water absorption was high, as observed in Table 4, and regime at different ages of curing. Compressive strength results
this is bound to affect the concrete workability unless precau- and moisture migration from aggregates under different curing
tions are taken in mix proportioning. To avoid the water cor- regimes were considered together for assessing the self-curing
rection, the aggregates were presoaked in water for 30 min and capacity of CA aggregate concretes.
the excess water allowed to drain for 10 min before mixing.
The CA concrete was mixed in two stages, in order to obtain 5.2.3 Sorptivity
good homogeneity and blend between mortar and aggregate. Properties like sorptivity and absorption influence the dura-
Cement, water and fine aggregates were initially mixed for bility of concrete. As building materials are rarely saturated
2 min and after addition to CA aggregate for another 3 min. during use, sorptivity is the more appropriate parameter to
Normal aggregate concrete (NC) was also proportioned in the explain moisture movement. The water sorptivity test helps to
same ratio. Trial batches were prepared in order to arrive at determine water absorption of the concrete by measuring the
the desired workability. The workability of both the CA aggre- water entering concrete through capillary suction at different
gate concretes was checked in terms of slump and compaction intervals of time. The test was conducted according to the pro-
factor test. Since types B and F aggregates were round in shape vision of ASTM C1585 (ASTM, 2004). Sorptivity, expressed
in contrast to normal angular aggregates, BC and FC had in terms of absorption, I, is the change in mass divided by the
workability higher than NC. product of the cross-sectional area of the test specimen and
the density of water. The initial rate of water absorption is the
5.2 Tests on concrete slope of the best-fit line of I plotted against the square root of
time. The water sorptivity test was conducted at 28 d of curing
5.2.1 Strength
for all the three curing regimes for both types of concrete, BC
The compressive strength was determined by tests according to
and FC.
IS 516 (BIS, 1959) after 7, 28 and 56 d of curing. The test
specimens of concretes BC, FC and NC were cast and cured
5.3 Results and discussion
in water.
5.3.1 Strength comparison
5.2.2 Effect of curing regimes on strength Compressive strength after curing of 7, 28 and 56 d is sum-
The CA aggregates showed higher values of water absorption marised in Figure 3. The density of CA aggregate concrete
than normal aggregates. This may help types B and F aggre- was found to be lower than that of normal concrete. The
gates to release the moisture held in their pores to the cement strength value of BC was higher than that of FC. An increase
matrix during the hydration process. To assess the hydration in strength of concrete is also observed as the age of curing
reaction capacity of CA aggregates the concrete specimens increases. BC and FC had compressive strength lower
were exposed to different curing regimes. Three curing regimes by 17 and 26%, respectively, when compared with NC after
were selected: water curing, sealed curing and air curing. 28 d of water curing. There was an increase in strength of
The strength variation of concretes under different regimes and about 5–15% for all concretes at 56 d compared with 28 d
also the curing sensitivity of the cold-bonded aggregates were curing.
evaluated. The test specimens were cured under the three
regimes and tested for compressive strength after curing for By analysing the tested concrete specimens, it was found
7, 28 and 56 d. By assessing the strength variation of BC and that the aggregate phase of concrete, rather than the cement
FC under different regimes, the curing sensitivity was ident- paste interfacial zone, was the predominant cause of failure.
ified. The self-curing efficiency was assessed by studying Hence, the strength of the concretes was governed by the type
the moisture movement from aggregates at different stages of aggregates utilised. The compressive strength of BC was
of curing. found to be higher than FC due to the higher strength of type
B aggregates when compared with type F aggregates.
5.2.2.1 MOISTURE MOVEMENT FROM AGGREGATE
This test was done by extracting the aggregate from the interior 5.3.2 Influence of curing regimes on strength
of concrete at different ages of curing. The residual moisture The compressive strength variation of CA aggregate
was estimated as the change in mass among as-extracted aggre- concretes BC and FC under three curing regimes is shown in
gates and the mass after 24 h oven drying at 100 ± 5°C, Figures 4(a) and 4(b), respectively. In the case of BC it was
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Waste and Resource Management Performance evaluation of
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Menon, Anand and Sharma
30 25
7d 7d
28 d
28 d 56 d
25
20
56 d
20
15
15
10
10
5
0
Water cured Air cured Sealed cured
0
NC BC FC (a)
25
Figure 3. Comparison of compressive strength
7d
20 28 d
56 d
Compressive strength: MPa
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Waste and Resource Management Performance evaluation of
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in concrete
Menon, Anand and Sharma
24 0·04
Water cured
22 Air cured
20 Sealed cured
Residual moisture content: %
18 0·03 BC FC
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Waste and Resource Management Performance evaluation of
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Menon, Anand and Sharma
(a) CA proportion 60:40 of BA and FA, respectively, through chemical activation. Journal of Cleaner Production 18(15):
produces a denser mixture suitable for coarse 1563–1569.
Geetha S and Ramamurthy K (2010b) Reuse potential of low-calcium
aggregate preparation.
bottom ash as aggregate through pelletization. Waste Management
(b) Artificial aggregates prepared with CA mixtures come 30(8): 1528–1535.
under the category of lightweight aggregates, as their Geetha S and Ramamurthy K (2013) Properties of geopolymerised
specific gravity and bulk density values are low. low-calcium bottom ash aggregate cured at ambient temperature.
(c) XRD pattern and SEM analysis indicate that a larger Cement and Concrete Composites 43: 20–30.
Gesoğlu M, Özturan T and Güneyisi E (2007) Effects of fly ash
proportion of BA in aggregates results in the formation
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of hydrated products with fewer pores and thereby lightweight aggregates. Construction and Building Materials
achieves enhanced aggregate properties. 21(9): 1869–1878.
(d) Based on compressive strength attained under different Ghosh A and Subbarao C (2001) Microstructural development in
curing conditions, it is concluded that concrete prepared fly ash modified with lime and gypsum. Journal of Materials in
Civil Engineering 13(1): 65–70.
using CA aggregates exhibits a self-curing property.
Harikrishnan K and Ramamurthy K (2006) Influence of pelletization
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( f ) The strength development and sorptivity characteristics Joseph G and Ramamurthy K (2010) Autogenous curing of cold-bonded
of sealed-cured CA aggregate concrete indicate its fly-ash-aggregate concrete. Journal of Materials in Civil
Engineering 23(4): 393–401.
potential for application in precast component
Kayali O (2004) Effect of high volume fly ash on mechanical properties
production. of fiber reinforced concrete. Materials and Structures 37(5):
318–327.
Kim H, Ha K and Lee H (2016) Internal-curing efficiency of cold-bonded
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