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Mole Fractions from ASTM D-1945 @ 60°F & 1 atm ASTM D-3588
Natural Gas Chemical Mole Specific Net Heat Val ASTM D-1945
Constituents Formula Fraction Gravity B.t.u./cu.ft. Data Source
Methane CH4 0.89 0.637866827 946.51965 name the source of data <--- enter data into italics cell
Ethane C2H6 0.045
Propane C3H8 0.01 Cylinder: description
I-Butane C4H10 0.0025 description
N-Butane C4H10 0.0025 description
I-Pentane C5H12 0.0025 description
N-Pentane C5H12 0.0025
Hexanes C6H14 0.00035 §86.113-94 (e) Natural gas fuel. (1) Natural gas fuel having the following specifications
Heptanes C7H16 0.00035 will be used for exhaust testing of natural gas-fueled vehicles.
Octanes C8H18 0.00035 Methane min, mole pct. 89.0 Pass
Nonanes C9H20 0.00035 Ethane max. mole pct. 4.5 Pass
Hydrogen H2 0 C3, and higher max. mole pct. 2.3 Pass
Helium He2 0 C6, and higher max. mole pct. 0.2 Pass
Nitrogen N2 0.01 Oxygen max. mole pct. 0.6 Pass
Oxygen O2 0 Inert gases: Sum of CO2 and Nmax. mole pct. 4.0 Pass
Carbon Dioxide CO2 0.03 Odorant
Constituent 1.008 4.003 12.011 14.007 15.999999 Gram Mole % Mole % Mole % Mole % X
Chemical Mole % # H Atoms # He Atoms # C Atoms # N Atoms # O Atoms Molecular X X X # C Atoms X
Component Formula of Fuel per molecule per molecule per molecule per molecule per molecule Weights Mole weight # H Atoms # C Atoms C g mole wght 0.912
Methane CH4 89.0000% 4 0 1 0 0 16.043 14.27827 3.56 0.89 10.68979 0.0455
Ethane C2H6 4.5000% 6 0 2 0 0 30.07 1.35315 0.27 0.09 1.08099 0.0112
Propane C3H8 1.0000% 8 0 3 0 0 44.097 0.44097 0.08 0.03 0.36033 0.002
I-Butane C4H10 0.2500% 10 0 4 0 0 58.124 0.14531 0.025 0.01 0.12011 0.0017
N-Butane C4H10 0.2500% 10 0 4 0 0 58.124 0.14531 0.025 0.01 0.12011 0.0008
I-Pentane C5H12 0.2500% 12 0 5 0 0 72.151 0.1803775 0.03 0.0125 0.1501375 0.0004
N-Pentane C5H12 0.2500% 12 0 5 0 0 72.151 0.1803775 0.03 0.0125 0.1501375 0.0005
Hexanes C6H14 0.0350% 14 0 6 0 0 86.178 0.0301623 0.0049 0.0021 0.0252231 0.0005
Heptanes C7H16 0.0350% 16 0 7 0 0 100.205 0.03507175 0.0056 0.00245 0.02942695 0.0006
Octanes C8H18 0.0350% 18 0 8 0 0 114.232 0.0399812 0.0063 0.0028 0.0336308 0
Nonanes C9H20 0.0350% 20 0 9 0 0 128.259 0.04489065 0.007 0.00315 0.03783465 0
Hydrogen H2 0.0000% 2 0 0 0 0 2.016 0 0 0
Helium He2 0.0000% 0 2 0 0 0 4.003 0 0 0.0098
Nitrogen N2 1.0000% 0 0 0 2 0 28.014 0.28014 0 0
Oxygen O2 0.0000% 0 1 0 0 2 32 0 0 0.0151
Carbon Dioxide CO2 3.0000% 0 0 1 0 2 44.009 1.32027 0.03 0.36033
Sum of All Constituents 99.64% 18.4742809
Sum Carbon Bearing Constituents 98.64% 13.1580505
Sum of HC Constituents 95.64% 4.0438 1.0655 12.7977205
Sum of Non-CH4 HC Constituents 6.64% 0.4838 0.1755
Mole Fractions from ASTM D-1945 @ 60°F & 1 atm ASTM D-3588
Natural Gas Chemical Mole Specific Net Heat Val ASTM D-1945
Constituents Formula Fraction Gravity B.t.u./cu. ft. Data Source
Methane CH4 0.8900000 0.637866827 946.51965 name the source of data
Ethane C2H6 0.0450000
Propane C3H8 0.0100000 Cylinder: description
I-Butane C4H10 0.0025000 description
N-Butane C4H10 0.0025000 description
I-Pentane C5H12 0.0025000 description
N-Pentane C5H12 0.0025000
Hexanes C6H14 0.0003500 §86.113-94 (e) Natural gas fuel. (1) Natural gas fuel having the following specifications
Heptanes C7H16 0.0003500 will be used for exhaust testing of natural gas-fueled vehicles.
Octanes C8H18 0.0003500 Methane min, mole pct. 89.0 Pass
Nonanes C9H20 0.0003500 Ethane max. mole pct. 4.5 Fail
Hydrogen H2 0.0000000 C3, and higher max. mole pct. 2.3 Pass
Helium He2 0.0000000 C6, and higher max. mole pct. 0.2 Fail
Nitrogen N2 0.0100000 Oxygen max. mole pct. 0.6 Pass
Oxygen O2 0.0000000 Inert gases: Sum of CO2 and Nmax. mole pct. 4.0 Fail
Carbon Dioxide CO2 0.0300000 Odorant
Den Air @ 68°F & 1 atm gr/cu ft = 28.316847 liters per cu ft * Den Air @ 68°F & 1 atm gr per 1.015 - relates density of gases to standard conditons.
Fuel Den gr/cu ft =Spec Grav * Den Air @ 68°F & 1 atm gr per cu ft
1.1771787701 =1000/(24.05497*35.314475403467)
.9 is the conversion between lower and higher - its not an exact number.
for 100 % methane the heat of vaporization of water may be found in a table (about .9 but not exactly .9)
of course real NG is not pure methane
we could compute the exact value using a thermodynamic table.
bc
42160
Send comments to courtois.william@epamail.epa.gov Derivation of Natural Gas Fuel Properties from ASTM D-1945 Input
399185284.xls
Table 1 Properties of natural Gas Components at 60°F and 14.696 psia
Molar Molar Ideal Gross Heating Value Ideal Net Heatin
12.0110 1.0079 15.9994 32.0600 ### ### ### ### Mass mass Hid Hid Hid hid
Compound Formula M Ratio n m v n
C H O S N He Ar Air gr/mole d id kJ/mole Btu/lbm Btu/cu ft kJ/mole
Hydrogen 2 2.016 0.06960 286.2 61022.00 342.20 324.41 241.79
Helium 1 4.003 0.13821 0 0.00 0.00 0.00 0
Water 2 1 18.015 0.62202 44.409 1059.80 50.31 50.35 0
Carbon Monoxide 1 1 28.010 0.96713 282.9 4342.00 320.50 320.74 282.9
Nitrogen 2 28.013 0.96723 0 0.00 0.00 0.00 0
Oxygen 2 31.999 1.10484 0 0.00 0.00 0.00 0
Hydrogen Sulfide 2 1 34.076 1.17655 562.4 7094.20 637.10 637.51 517.99
Argon 1 39.948 1.37930 0 0.00 0.00 0.00 0
Carbon Dioxide 1 2 44.010 1.51954 0 0.00 0.00 0.00 0
Air 1 28.963 1.00000 0 0.00 0.00 0.00 0
Methane 1 4 16.043 0.55391 891.63 23891.00 1010.00 1010.77 802.71
Ethane 2 6 30.070 1.03823 1562.06 22333.00 1769.70 1770.99 1428.13
Propane 3 8 44.097 1.52254 2220.99 21653.00 2516.10 2518.04 2043.3
Iso-Butane 4 10 58.123 2.00685 2870.45 21232.00 3251.90 3254.48 2648.4
n-Butane 4 10 58.123 2.00685 2879.63 21300.00 3262.30 3264.90 2657.6
Iso-Pentane 5 12 72.150 2.49116 3531.5 21043.00 4000.90 4003.92 3265
n-Pentane 5 12 72.150 2.49116 3535.8 21085.00 4008.90 4011.91 3269.3
n-Hexane 6 14 86.177 2.97547 4198.1 20943.00 4755.90 4759.60 3887.2
n-Heptane 7 16 100.204 3.45979 4857.2 20839.00 5502.50 5506.83 4501.9
n-Octane 8 18 114.231 3.94410 5515.9 20759.00 6248.90 6253.60 5116.2
n-Nonane 9 20 128.258 4.42841 6175.9 20701.00 6996.50 7001.88 5731.8
n-Decane 10 22 142.285 4.91272 6834.9 20651.00 7742.90 7748.88 6346.4
Neopentane 5 12 72.150 2.49116 3517.27 20958.00 3985.00 3987.75 3250.8
2-Methylpentane 6 14 86.177 2.97547 4190.43 20905.00 4747.00 4750.97 3879.6
3-Methylpentane 6 14 86.177 2.97547 4193.03 20918.00 4750.00 4753.92 3882.2
2,2-Dimethylbutan 6 14 86.177 2.97547 4180.63 20856.00 4736.00 4739.83 3869.8
2,3-Dimethylbutan 6 14 86.177 2.97547 4188.41 20895.00 4745.00 4748.70 3877.5
Cyclopropane 3 6 42.081 1.45294 2092.78 21381.00 2371.00 2372.74 1959.6
Cyclobutane 4 8 56.108 1.93725 2747.08 21049.00 3112.12 3114.53 2569.4
Cyclopentane 5 10 70.134 2.42156 3322.04 20364.00 3764.00 3766.47 3100
Cyclohexane 6 12 84.161 2.90587 3955.84 20208.00 4482.00 4485.13 3689.4
453.59327 Grams/lb
0.0763793261 Air lbs / cu ft
1.2633649121 cu ft / mole
252.122 cals / B.t.u.
1055.05585262 Joules / B.t.u.
ASTM D-3588 Example of calculation of gas Properties for Dry Gas and Dry Air at 60°F and 14.696 psia
Compo- Ideal GrossIdeal Net Ideal Ideal Gross Ideal Net Ideal
sition Heating Heating Relative Ideal Summ- Heating Heating Relative Ideal Summ-
Mole HydrogenValue HidValue hid DensityDensity ation Value Value Density Density ation
Compound Fraction Atoms v v did pid Factor Fraction Fraction Fraction Fraction Fator
xi b Btu/cu ft Btu/cu ft did lb/cu ftsqrt(beta) xi X b xi X Hid v xi X hid v xi X didi xi X pi xi X sqrt(beta)
Methane 89.0000% 4 1010 909.4 0.5539 0.042 0.0116 3.56 898.9 809.366 0.49299 0.03762 0.010324
Ethane 4.5000% 8 1769.7 1618.7 1.0382 0.079 0.0239 0.36 79.6365 72.8415 0.04672 0.003566 0.0010755
Propane 1.0000% 8 2516.1 2314.9 1.5226 0.116 0.0344 0.08 25.161 23.149 0.01523 0.001162 0.000344
Isobutane 0.2500% 10 3251.9 3000.4 2.0068 0.153 0.0458 0.025 8.12975 7.501 0.00502 0.000383 0.0001145
Butane 0.2500% 10 3262.3 3010.8 2.0068 0.153 0.0478 0.025 8.15575 7.527 0.00502 0.000383 0.0001195
iso-Pentane 0.2500% 12 4000.9 3699 2.4912 0.19 0.0581 0.03 10.00225 9.2475 0.00623 0.000475 0.00014525
Pentane 0.2500% 12 4008.9 3703.9 2.4912 0.19 0.0631 0.03 10.02225 9.25975 0.00623 0.000475 0.00015775
Hexane 0.0350% 14 4755.9 4403.9 2.9755 0.227 0.0802 0.0049 1.664565 1.541365 0.00104 7.95E-05 0.00002807
Den Air @ 68°F & 1 atm gr/cu ft = 28.316847 liters per cu ft * Den Air @ 68°F & 1 atm gr per liter (HCP) = 28.316847 * 1.2047
Fuel Den gr/cu ft =Spec Grav * Den Air @ 68°F & 1 atm gr per cu ft
1.1771787701
.9 is the conversion between lower and higher - its not an exact number.
for 100 % methane the heat of vaporization of water may be found in a table (about .9 but not exactly .9)
of course real NG is not pure methane
we could compute the exact value using a thermodynamic table.
The density of air is 1.2047 gr/l (0.075206 lb/cu ft) @68°F & 1atm
28.316847 liters per cubic foot
0.9 is the conversion between lower and higher heating values (actual value varies slightly).
ASTM Rounding was applied to Specific Gravity, Net Heating Value, and CWF's as required.
16.04315
al Net Heating Value SummationIdeal Gross Heating Value %¯ %¯ Ideal Net Heating Value
hid hid Factor Hid Hid Hid Hid Hid Hid Hid hid hid hid hid hid
m v sqrt(beta)/RT n n m m v m v n n m m v
Btu/lbm Btu/cu ft psia^-2 kJ/mole Btu/mole kJ/gram Btu/lbm Btu/cu ft Btu/lbm Btu/cu ft kJ/mole Btu/mole kJ/gram Btu/lbm Btu/cu ft
51566.00 273.93 0 286.2 0.2712653 0.1345642 ### 324.49 15.41 -17.71 241.79 0.2291727 ### ### 274.14
0 0 0 0 0.0000000 0.0000000 0.00 0.00 0.00 0.00 0 0.0000000 ### 0.00 0.00
0 0 0.0623 44.409 0.0420916 0.0023364 1059.79 50.35 -0.01 0.04 0 0.0000000 ### 0.00 0.00
4342.2 320.5 0.0053 282.9 0.2681375 0.0095728 4342.15 320.75 0.15 0.25 282.9 0.2681375 ### 4342.15 320.75
0 0 0.0044 0 0.0000000 0.0000000 0.00 0.00 0.00 0.00 0 0.0000000 ### 0.00 0.00
0 0 0.0073 0 0.0000000 0.0000000 0.00 0.00 0.00 0.00 0 0.0000000 ### 0.00 0.00
6534 586.8 0.0253 562.4 0.5330523 0.0156431 7095.60 637.64 1.40 0.54 517.99 0.4909598 ### 6535.30 587.29
0 0 0.0071 0 0.0000000 0.0000000 0.00 0.00 0.00 0.00 0 0.0000000 ### 0.00 0.00
0 0 0.0197 0 0.0000000 0.0000000 0.00 0.00 0.00 0.00 0 0.0000000 ### 0.00 0.00
0 0 0.005 0 0.0000000 0.0000000 0.00 0.00 0.00 0.00 0 0.0000000 ### 0.00 0.00
21511 909.4 0.0116 891.63 0.8451022 0.0526781 ### ### 3.43 0.92 802.71 0.7608223 ### ### 910.10
20429 1618.7 0.0239 1562.06 1.4805472 0.0492373 ### ### 0.70 1.34 1428.13 1.3536061 ### ### ###
19922 2314.9 0.0344 2220.99 2.1050923 0.0477383 ### ### 0.77 2.03 2043.3 1.9366747 ### ### ###
19590 3000.4 0.0458 2870.45 2.7206617 0.0468084 ### ### -0.04 2.57 2648.4 2.5101989 ### ### ###
19658 3010.8 0.0478 2879.63 2.7293626 0.0469581 ### ### -0.14 2.58 2657.6 2.5189188 ### ### ###
19456 3699 0.0581 3531.5 3.3472162 0.0463923 ### ### 0.23 3.06 3265 3.0946229 ### ### ###
19481 3703.9 0.0631 3535.8 3.3512918 0.0464488 ### ### -16.15 -0.06 3269.3 3.0986985 ### ### ###
19393 4403.9 0.0802 4198.1 3.9790311 0.0461727 ### ### 0.62 3.85 3887.2 3.6843547 ### ### ###
19315 5100.3 0.0944 4857.2 4.6037373 0.0459436 ### ### 0.72 4.52 4501.9 4.2669779 ### ### ###
19256 5796.2 0.1137 5515.9 5.2280645 0.0457675 ### ### 0.83 4.95 5116.2 4.8492220 ### ### ###
19213 6493.6 0.1331 6175.9 5.8536238 0.0456395 ### ### 0.78 5.65 5731.8 5.4326982 ### ### ###
19176 7189.9 0.1538 6834.9 6.4782352 0.0455301 ### ### 1.15 6.41 6346.4 6.0152266 ### ### ###
19371 3683 0.08 3517.27 3.3337287 0.0462053 ### ### 0.43 2.83 3250.8 3.0811639 ### ### ###
19355 4395 0.08 4190.43 3.9717613 0.0460883 ### ### 0.36 4.05 3879.6 3.6771513 ### ### ###
19367 4398 0.08 4193.03 3.9742256 0.0461169 ### ### 0.33 4.00 3882.2 3.6796156 ### ### ###
19306 4384 0.08 4180.63 3.9624727 0.0459805 ### ### 0.47 3.94 3869.8 3.6678627 ### ### ###
19344 4393 0 4188.41 3.9698467 0.0460661 ### ### 0.28 3.76 3877.5 3.6751609 ### ### ###
20020 2220 0 2092.78 1.9835727 0.0471374 ### ### 0.22 1.76 1959.6 1.8573424 ### ### ###
19688 2911 0 2747.08 2.6037295 0.0464061 ### ### 0.48 2.48 2569.4 2.4353213 ### ### ###
19003 3512 0 3322.04 3.1486864 0.0448950 ### ### 0.09 2.48 3100 2.9382331 ### ### ###
18847 4180 0 3955.84 3.7494129 0.0445503 ### ### -0.27 3.07 3689.4 3.4968765 ### ### ###