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Kayansayan, Nuri
TERMODYNAMICS Principles & Applications / Prof. Dr. Nuri Kayansayan
1. Baskı, X + 526 s., 195x275 mm
Kaynakça ve dizin yok
ISBN 978-605-133-493-6
1. Heat 2. Energy 3. Exergy 4. Entropy
!"#$%&'()'*+,)-
.#'/(*%(0*'('12#'/(*%(0/'*')
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“Thermodynamics is a funny subject. The first time you
go through it, you don’t understand it at all. The second
time you go through it, you think you understand it,
except for one or two small points. The third time you go
through it, you know you don’t understand it, but by that
time you are so use to it, it doesn’t bother you anymore.”
-Arnold Sommerfield-
C O N T E N T S
P1 BASIC CONCEPTS & DEFINITIONS P4 ENERGY ANALYSIS OF SYSTEMS
1.1 Introduction ..................................................... 1 4.1 Introduction ................................................... 91
1.2 Dimensions and Units ...................................... 2 4.2 Energy of a system ........................................ 92
1.3. The System Concept ........................................ 3 4.3 Forms Of Energy Transfer ............................ 96
1.4 The Property Concept ...................................... 6 4.4 Heat Transfer ................................................. 97
1.5 The Pressure and Temperature of a System .... 8 4.5 Work Transfer ............................................. 101
1.6 The State Concept ......................................... 18 4.6 Mechanical Work Transfer .......................... 102
1.7 The Equilibrium Concept .............................. 19 4.7 Other Forms Of Quasistatic Work
1.8 The Process Concept ..................................... 20 Transfer ....................................................... 107
References ..................................................... 21 4.8 Convective Transfer Of Energy ................... 108
Problems ....................................................... 21 4.9 The Energy Equation ................................... 110
4.10 Steps In Problem-Solving ............................ 112
P2 THERMODYNAMIC PROPERTIES OF 4.11 Closed Systems ........................................... 112
SYSTEMS 4.12 Constant pressure process of closed
2.1 Introduction ................................................... 27 systems ........................................................ 118
2.2 The State Principle ........................................ 28 4.13 An Introduction To Thermodynamic
Cycles.......................................................... 119
2.3 The p-v-T Behavior Of Systems .................... 29
4.14 Steady State Flow Systems .......................... 124
2.4 The Use Of Thermodynamic Tables .............. 35
4.15 Transient flow systems ................................ 135
2.5 The Specific Heats of a Pure Substance ......... 39
References ................................................... 142
2.6 Gaseous Behavior of a Pure Substance .......... 40
Problems ..................................................... 142
2.7 The Ideal Gas Model ..................................... 45
True and False ............................................. 158
2.8 The Specific Heats of Ideal Gases .................. 51
Check Test 4 ................................................ 159
References ..................................................... 54
Problems ....................................................... 55
P5 SECOND LAW EXERGY ANALYSIS OF
SYSTEMS
P3 MASS ANALYSIS OF SYSTEMS
5.1 Introduction ................................................. 161
3.1 Introduction ................................................... 63
5.2 Equilibrium of Systems ............................... 164
3.2 The Equation Of Continuity .......................... 63
5.3 Exergy of a System ...................................... 165
3.3 The Mass Change Of a System ...................... 67
5.4 Exergy Loss of a System ............................. 167
3.4 Integral Formulation Of The Continuity
Equation ........................................................ 69 5.5 Equation of Exergy ...................................... 172
3.5 Velocity Measurements ................................. 77 5.6 The exergy transfer by work ........................ 173
3.6 Flow Rate Measurements............................... 80 5.7 The Exergy Transfer by Heat ....................... 175
References ..................................................... 83 5.8 Entropy ........................................................ 182
Problems ....................................................... 84 5.9 The Entropy Change of a System................. 184
True and False ............................................... 88 5.10 The General Equation of Exergy ................. 185
Check Test 3 .................................................. 88 5.11 Exergy Analysis of Closed Systems............. 186
v
vi CONTENTS
This book is written for an introductory and intermediate level course in the subject of thermodynam-
ics for engineering curricula. The approach followed in the text is to emphasize the physical concepts of
thermodynamics and the method of analysis that starts with identifying the underlying principles and defi-
nitions. The primary objective of the text is to help students develop an orderly approach in understanding
the obscure concepts such as the energy and the exergy of a system. In doing so, a total of two hundred
illustrative sample problems are provided, and on the average eighty unsolved problems with engineering
emphasis are contained at the end of each chapter. Example problems are set apart in a format different
from the text so that they are easy to identify and follow.
In solving the end chapter problems,
Students should be able to incorporate with the meaning of physical principles associated with the
subject.
Students should be able to use the control volume approach to identify the system.
Students should be able to state the related assumptions.
Students should be able to relate the mathematical results to the corresponding physical behavior,
and draw conclusions concerning the process or the system design from attendant analysis.
In addition, each chapter contains True-False and a Multiple Choice Test sections. Both of these tests
are aimed for self-check of student’s weakness or strength on the highlights of the related chapter.
Special care has been given to illustrations of both the main text and of the problems, and if necessary,
figures in color are used for making the subject more understandable. Further facilitate comprehension of
the subject, especially for students taking an elementary thermodynamics course in engineering curricula
for the first time, systems like flow machines or heat exchangers have been illustrated with their essential
components without going into unnecessary complexity.
The material has been selected carefully to include a broad range of topics suitable for two-semester
engineering thermodynamics course at the junior level. The material in the manuscript has been organized
around the following topics:
Introductory concepts and definitions for system property, state, process, and equilibrium (Chapter 1)
Methods of measuring pressure and temperature (Chapter 1)
State principle, p-V-T behavior of a pure substance, the ideal gas behavior, specific heats (Chapter 2)
Development and application of control volume approach to mass analysis (Chapter 3)
Methods and instruments for measuring velocity and flow rate (Chapter 3)
Development and application of control volume approach to energy analysis, steady and transient
flow systems (Chapter 4)
Heat transfer analysis and overall heat transfer coefficient of systems (Chapter 4)
Work transfer analysis (Chapter 4)
Energy analysis of thermodynamic cycles (Chapter 4)
Exergy of a system, the exergy change and the exergy loss of a system (Chapter 5)
Application of control volume approach to exergy analysis, the exergy equation, exergetic ef-
ficiency of flow systems and cyclic devices (Chapter 5)
Application of control volume approach to entropy analysis, fundamental equation of thermody-
namics, isentropic flow, isentropic efficiencies of steady flow devices (Chapter 6)
Applications of Maxwell’s relations, the Clausius-Clapeyron equation, the phase equilibria (Chapter 6)
vii
viii CONTENTS
The use of entropy in design of thermal systems, specific applications for channel flow and for
wind turbine design (Chapter 6)
Partial properties of a gas mixture component, ideal gas mixtures, rules for estimating the p-V-T
behavior of gas mixtures, the Orsat apparatus (Chapter 7)
Moist air properties, the psychrometric chart, air conditioning processes, cooling tower basics (Chapter 7)
Classification of power producing systems, cyclic properties of internal and external combustion
systems (Chapter 8)
Efficiency analysis of Otto, Diesel, Brayton, Stirling, and Rankine cycles, low temperature ap-
plications of Rankine cycle, cogeneration (Chapter 8)
Vapor compression refrigeration systems, and analysis of multi-pressure systems (Chapter 9)
Refrigeration compressors, expansion devices, design of refrigerant condensers and evaporators,
properties of refrigerants, heat pump systems, basics of absorption refrigeration systems (Chapter 9)
The first part of the book (Chapters 1-5) contains material suitable for a Basic Course in Thermody-
namics that can be taken by engineering students of all majors. The second part of the book (Chapters
6-9) is designed for an Applied Thermodynamics Course or for Thermodynamics II course in mechanical
engineering programs.
Due to industrialization and growth of world population, the increase in per capita energy consumption
is one of the prime causes of the need for efficient use of available energy resources in today’s world.
The book considers this fact in the selection and sequential presentation of the subject material
throughout the book. The conservation of mass, energy, and the non-conservation of exergy are covered
in sequence in Chapters 3, 4, and 5. A student, taking an introductory course in Thermodynamics, should
be able to calculate the amount of energy of a system as well as the maximum portion of that energy that
is available for use. Moreover, the efficiency of energy conversion systems is defined in two different
ways as the exergy-based efficiency and the energy-based efficiency. First, the exergy-based efficiency is
introduced. The energy-based efficiency of flow machines needs a substantial background in entropy and
is covered in Chapter 6. Moreover, subjects like reversible shaft work, multi-stage compression, incom-
pressible and adiabatic flow processes and isentropic flows are applications of entropy and are studied in
Chapter 6. Similarly, the use of Maxwell’s relations in entropy-based design is exemplified by case studies.
The p-V-T behavior of gas mixtures, ideal and real, and properties of moist air are provided in Chapter 7.
As an introduction to air conditioning engineering, processes related to moist air are exemplified and the
design methods for cooling towers are illustrated. Chapter 8 deals with work producing cyclic systems as
predominantly used in today’s industrial applications, and explains system modifications for increasing the
cyclic efficiency. Special attention is given to low temperature applications of Rankine cycle for which the
temperature of heat source is in the range from 160°C to 200°C. Chapter 9 is about refrigeration systems,
and covers vapor compression refrigeration, heat pumps and the essentials of absorption refrigeration.
In this chapter, the thermodynamic analysis of compressors and expansion devices is explained, and the
design methodology for condensers and evaporators are provided. Special attention is given to thermal
design of cooling towers.
Where appropriate and especially in Chapters 7, 8, and 9 open-ended type design problems are in-
cluded. Students could be assigned to work in teams to solve these problems. Design problems encourage
the students to spend more time exploring applications of thermodynamic principles to devices and flow
systems.
The book is well suited for independent study by students or practicing engineers. Its readability and
clear examples help to build confidence. When students finish the text, I expect them to be able to apply
the related principles and derived equations to a variety of systems including those they have not encoun-
tered previously.
Last but not least, my sincere appreciation goes to Dr. Mehmer Akif Ezan for his endless effort in
drawing the figures and reviewing the manuscript.
1.1 Introduction
Why thermodynamics ? Thermodynamics is an engineering tool for many branches of
engineering and is used to describe processes that involve energy interaction. Thermody-
namics can be stated as a generalization of an enormous body of empirical evidence with
no hypotheses concerning the type and the structure of systems. In short, thermodynamics
provides unique answers to such questions as following:
1. What is the maximum amount of work that may be obtained per liter of gasoline or
per kilogram of coal?
2. What is the ultimate efficiency or “the maximum ever possible efficiency” of an au-
tomobile engine or a power plant operating between two given temperature levels?
3. Under what conditions and how the natural way of heat flow can be reversed so
that heat can be transferred from a low temperature level to a higher temperature
level?
4. What general relations exist between the equilibrium properties of materials? includ-
ing those for which there may be no experimental data or theoretical models?
A wide variety of other questions can be answered by thermodynamics, as evidenced
by the fact that a course on thermodynamics is found in the curricula of almost all branches
of engineering.
In performing engineering analysis on a real phenomenon, it is necessary that engineer
has the capability to describe the phenomenon he seeks to control. A complete description
generally needs geometric as well as dynamic similarity between the phenomenon and
its model. Due to minor effect of certain parameters, however, those parameters might
be ignored in the analysis. For instance, in analyzing the trajectory of a soccer ball by the
laws of classical mechanics, we completely ignore the molecular structure of the ball even
though there are events occurring at the molecular level. Therefore, a basic principle may
be expressed as follows,
1
2 THERMODYNAMICS
Thus, the conclusions drawn by means of a particular model for the real phenomenon largely
depends upon the appropriateness of the model. The question, “how appropriate the model is?” is in
the context of the art of engineering and such a question is often answered by appealing to experience.
Thus, there are two fundamental models for the matter of the universe: a. The macroscopic model,
and b. The microscopic model. Even though each model is important and provides its own charac-
teristics, the macroscopic model of matter will be discussed and employed in this text. In addition,
the thermodynamic analysis of mechanical systems may successfully be completed by the systematic
application of the following fundamental principles: a. The conservation of mass, b. The conservation
of energy, c. The non-conservation of exergy. The objective of this book is to develop and employ
these principles to the problems encountered in mechanical engineering applications.
m
N (1.1)
M
In Eq. (1.1), M is the molar mass. The molar mass of a substance is equal to its molecular mass.
For example, the molecular mass of oxygen gas is 32 kg/kmol.
All other SI units are secondary ones and are derivable in terms of these seven primary units. The
SI units of force is the Newton (N) and it is derived from Newton’s second law, F ma . Thus, a net
force of 1N accelerates 1 kg of mass at one meter per second. In conjunction with the definition of
force, weight always refers to a force of attraction between the body and the Earth,
W mg (1.2)
where g is the acceleration of gravity and varies with the location of the body on the Earth.
Thus, the weight of a substance may vary but the mass is always constant. Force interactions have
two principal effects: They tend to alter the motion of the objects, and to deform the shape of objects.
In Figure 1.1a, the applications of a force F to a transitional spring tends to stretch it. Similarly, in
Fig. 1.1b, the attraction of the Earth has a tendency to alter the motion of the airplane from a level
flight to a vertical dive. An ideal transitional spring is a one-dimensional spring of zero mass that
can experience only transitional displacements along its axis. As shown in Figure 1.1a, for an ideal
spring, the relation between the applied force, F and the spring displacement, x is a linear one, and
expressed as,
F Kx (1.3)
where K is called the spring constant and has the units of N/m.
Definition: (a) A system is a three-dimensional region of universe, not necessarily of constant volume
or mass, is set for purposes of analysis. (b) Everything that is apart from the system is referred to as
the surroundings. (c) The actual or the imaginary envelope separating the system and the surround-
ings is the boundary.
4 THERMODYNAMICS
Example 1.1: Consider a fluid flowing through a pipe of length L. Taking the pipe as a system, define the boundary of the
system.
Solution:
The boundary of the system is defined by dash line in Figure 1.2.
It should be noted that the thermodynamic system is merely an analytical model. However, the
specification of a system comprises the first step in the analysis. As shown in Fig. 1.3, the boundary
of a system may be rigid or moveable. A system with rigid boundaries is said to have a constant
volume.
The analysis of thermodynamic processes includes the study of the transfer of mass and energy
across the boundaries of a system. Thus, selection of an appropriate boundary makes the analysis
less difficult. The system described in Fig. 1.3 belongs to an important class of systems called open
system.
Definition: An open system is a system for which mass as well as energy may cross the boundaries
of the system.
CHAPTER 1 BASIC CONCEPTS & DEFINITIONS 5
The boundary used to define an open system is a surface called a control surface. The region of
space enclosed by this surface is called a control volume and actually is the open system itself. When-
ever there is a mass transfer to or from the system, an energy transfer also simultaneously takes place.
However, energy transfer to or from the system may also be accomplished without mass transfer. As
shown in Fig. 1.4, another important class of systems in engineering consists of closed systems.
Definition: A closed system is a system for which no mass crosses the boundary. Although the quantity
of matter is fixed in a closed system, energy is allowed to cross the boundaries.
The closed system may be regarded as special case of the open system in the sense that mass and
energy cross the boundary of the open system, while energy but no mass crosses the boundary of the
closed system. A special form of the closed system is called an isolated system.
Definition: A system having fixed mass and energy is called isolated system. Neither mass nor energy
is allowed to cross the boundaries of an isolated system.
Example 1.2: Consider 1 kg of water being heated in a container open at the top. Define the boundaries of the system, and
classify the system as open or closed.
Solution:
It is obvious that as the liquid water heated, some portion of it will be evaporated. The vapor particles will cross the imaginary
boundary. Thus, assuming the system to be open or close mainly depends what percentage of the original mass evaporates
during the process. Therefore, for some instances, the system may be regarded as closed, in others, it may be taken as an open
system. To decide which model is more appropriate for a particular problem is part of the art of engineering analysis.
6 THERMODYNAMICS
Solution:
To represent the system as open or close depends upon the portion of the
mechanical cycle that the compressor undergoes. For instance, during
a compression stroke, both valves are closed and the system may be
regarded as closed. However, if the overall cycle is considered, since
air enters and leaves through the valves, the system must be regarded
as open.
Examples of properties include pressure, temperature, mass, volume, density, electrical con-
ductivity, acoustic velocity, thermal coefficient of expansion. The distinction between properties and
non-properties is of outmost importance. Mass is a property, but the amount of mass entering to the
system through a flow port, say in one hour, is not a property, because it depends on the history of the
system. Similarly, the population of Chicago at a particular time t is a property. However, the num-
ber of babies born in the last 24 hours is not a property, because this number may not be established
without a historical record. Regardless of the method of measurement, the value of the property is
unique and fixed by the condition of the system at the time of measurement. Thus, one may state that
a system characteristic is a property if it is a function of other properties.
In performing thermodynamics analysis, properties may be grouped into two different categories.
Those are called; 1.The extensive properties, 2.The intensive properties.
Definition: Thermodynamic properties whose values depend on the size of the system are called
extensive properties.
For instance, volume, mass, energy, exergy, and entropy of a system are extensive properties. If
a system is subdivided into a group of smaller sub-systems, the value of any extensive property for
each sub-system will depend on the size of the sub-system. The value of the same extensive property
for the composite system is simply the sum of the values of the extensive property for the constituent
sub-systems.
It is important to note that the independent variable for an extensive property is time. At a particular
time t, there is only one value for the system volume, mass, and energy, etc. Thus symbolically,
In engineering analysis of systems, one is usually interested in time rate of change of a particular
extensive property. The extensive property rate equation may be written as follows,
CHAPTER 1 BASIC CONCEPTS & DEFINITIONS 7
Time rate of change The rate at which P The net rate at which P is
of P contained within is produced in the + transported into the system through
a system system at time t the boundaries at time t
P (t )
P (t ) cv PT t
(1.5)
t
Thus, at a particular time t, if P (t ) <0, it indicates that the amount of P in the system is decreasing
(t ) 0 , the amount of P contained in the system is being transported
at that instant. Similarly, if PT
outside of the system at that instant.
The net change in the amount of property P for a specified time interval (t1, t2) may be calculated
by the integration of Eq. (1.5).
t2 t2 t2
P
P t2 P t1 P (t )dt
dt PT
(t )dt (1.6)
t1 t1 t t1
cv
The net change in the amount The net amount of P produced within
+
of property P of the system the system at the specified time interval
The net amount of P
transported into the system at the specified
time interval
The transfer of an extensive property into or from the system may be accomplished at some regions
of the boundary where there is a mass flow. If the transfer of an extensive property is due to flow of
mass, then it is called convective transfer.
There are certain other properties which do not change with the size of the system.
Definition: The thermodynamic properties whose values are fixed at an instant of time t and at each
point within the system are called intensive properties.
and its surroundings. b) At an instant of time t, determine if (i) mass of the system (ii) balloon’s age (iii) velocity of helium
flowing into the balloon (iv) the amount of helium entering to the balloon at a particular time interval are properties or not?
If so, specify the type of property.
Solution:
a. The balloon is taken to be the system, and its boundaries and the surroundings are shown in the figure.
b. (i) extensive property, (ii) not a property, (iii) intensive property, (iv) not a property.
A change in an intensive property is determined by the end states and is independent of the
details of the change. In other words, the amount of change in an intensive property can be computed
without any knowledge about the process causing the change or the details of the path between the
end states. Hence,
2
1
d 2 1 (1.7)
As we know from Calculus, the integration of an exact differential is independent of path of the
integration and the integration result is simply the difference between the end values of the function.
Thus an infinitesimal change of a property can be represented by an exact differential. However,
every infinitesimal change may not be an exact differential. In accord with Calculus, if the relation
d Mdx Ndy is an exact differential, then the following condition must hold,
M N
(1.8)
y x
This is a key relation in questioning whether a function is a property or not. The intensive proper-
ties are further classified into two groups:
a. Specific properties are the locally estimated limit values of extensive properties for a unit
mass or a volume. For instance, density of a substance is defined as,
m
lim V V (1.9)
V
Although mass and volume are both extensive properties, the ratio yields a specific property called
density. The specific volume v has been defined as the volume per unit mass of the matter. Thus, it
is the reciprocal of the density.
V 1
v (1.10)
m
b. Pure intensive properties are those intensive properties which are not specific. Temperature,
pressure, and velocity are examples of pure intensive properties.
Fn
p lim A A (1.11)
A
CHAPTER 1 BASIC CONCEPTS & DEFINITIONS 9
The SI unit for pressure is the Pascal Pa. Considering the definition of pressure, 1 Pa=1 N/m2,
since Pascal is relatively a small unit of pressure, multiples of Pascal, 1kPa (kilopascal)= 103 Pa, and
1MPa (mega-pascal)=106 Pa, are also used. Although not being within the Internationale System e
, two other units are widely used in industrial applications. These are the bar, 1 bar=105 Pa, and the
standard atmosphere, 1 atm 101325 Pa .
The thermodynamic pressure at a particular point in a system is called absolute pressure, and
measured relative to absolute zero pressure. However, most pressure measuring instruments indicate
the difference between the absolute pressure and the atmospheric pressure existing at the gage. This
reading is referred to as gage pressure. Instruments for measuring pressures above and below atmo-
spheric level are respectively called manometer and vacuum meter.
Referring to Fig 1.8, the relation between the absolute pressure, p, and the pressure value indicated
by a manometer, pm, or a vacuum meter, pv, is as follows,
p po pm (1.12)
p po pv (1.13)
Pressure is usually measured by transferring its effect to a deflection through the use of a pressur-
ized area and either a gravitational or elastic restraining element. Therefore the pressure measuring
instruments may be classified as following: 1.Direct acting elastic types, 2.Gravitational types, and
3.Electrical pressure transducers.
1. Direct acting gauges.The most common direct acting elastic type gauges are the aneroid ba-
rometer and the Bourdon gage.
10 THERMODYNAMICS
As shown in Figure 1.9, an aneroid barometer has a vacuum chamber with an elastic surface.
When pressure imposed on its surface, it deflects inward, and the needle rotates accordingly. Hence
it measures the absolute pressure. A Bourdon gage manometer, as presented in Figure 1.10, is a thin
walled metal tube bent into a form of C, and one end of C is fixed, the other end is closed but it is free
to move. When pressure is applied at the fixed end, the tube deflects like the deflection of the snake
like paper whistle and the pointer at the free end indicates the gage pressure.
The Bourdon gauge is a highly accurate but rather delicate instrument. It may be easily damaged.
In addition, it malfunctions if the pressure varies very rapidly.
2. The Gravity Type Manometers. As shown in Figure 1.11, the gravitational type manometers
are basically three types:
a. The simple type, b. The differential type, and c. The inclined type. One end of these manometers
is connected to a point where the pressure has to be determined. The other end is either open to atmo-
sphere or has a connection to a point where the pressure difference to be measured. Depending upon
the pressure difference, liquid column rises in one direction. When equilibrium is reached, the force
balance on the manometer yields the following relations,
CHAPTER 1 BASIC CONCEPTS & DEFINITIONS 11
Case a: p A po gh
Case c: p A pB gh sin
Equation (1.14) also provides a method for measuring the pressure in terms of a liquid column
height. For instance, it might be shown that 1 bar of pressure difference corresponds to 9.8 meters of
water column.
3. The pressure Transducers. The electrical pressure transducer, Figure 1.12a, is a device that
converts displacement of a diaphragm to an electrical signal from which a reading can ultimately be
derived. For industrial applications, strain gage is more popular technology applied to this type of
transducers. The strain gage is constructed from either a metal foil or a semiconductor and bonded
to a pressure gathering diaphragm by using high strength epoxies. Generally four strain gages are
configured into a Wheatstone bridge, Figure 1.12b, on the diaphragm. When the voltage is applied
across points A, and C, the resistance change in the strain gages due to pressure causes a change
in the voltage output between B, and D. This voltage output is linearly proportional to the applied
pressure. As shown in Figure 1.12c, the pressure gathering diaphragm can be steel or ceramic and
is circular in shape. Since the response time of these instruments is very small, they are especially
suitable for applications at which pressure varies rapidly. The outputs of these transducers can be
recorded electronically.
Example 1.5: The vacuum tank in Figure 1.13 is fitted with a mercury manometer. When the tank is pumped down, the
manometer reads 745 mm. Inside the vacuum tank, there is a chamber which is divided into two compartments, and the
installed pressure gages read pA=4 atm, pB=1.5 atm. The atmospheric pressure is 1 atm.
a. Determine the absolute pressures in two compartments
b. Find the reading of gage C in atm.
c. Determine the minimum force required to lift the lid up.
12 THERMODYNAMICS
Solution:
a. Applying Eq.(1.12) to the manometer, p0-p3=745, and since 1 atm=760 mmHg, then p3=0.019 atm. Similarly, for gages
A and B, pA=p1-p3, pB=p1-p2, and the absolute pressures of the compartments are: p1=4.019atm, p2=2.519atm.
b. Gage C indicates the pressure difference between 2 and 3. Thus, pC=p2-p3, pC=2.5 atm.
d2
c. The force to be applied to the upper lid is F= ( p p3 ) , and substitution of numerical values yields
4 0
F=1560.2 kgf
Example 1.6: To keep the gate in its vertical equilibrium position of Figure 1.14, what must be the density of the liquid
on the left tank for the given dimensions? Take the width of the plate W=1m.
Solution:
To keep the gate in its vertical equilibrium position, the torque created by hydrostatic forces on both sides of the plate must
be balanced. Hence,
5.5 5.5
1.5 g x 1.5dxW x 2.5 w g x 2.5dxW x
After simplification of the above expression, and completing the integrals for the indicated limits, one may obtain the
following,
Definition: Thermal equilibrium of systems is characterized by the equality and uniformity of tem-
perature.
K= °C + 273.15 (1.15)
The following instruments are used for industrial applications of temperature measurements:
1.Thermistors, 2.Thermocouples, 3.RTD (Resistance Temperature Detectors), 4.IC Sensors,
5.Bimetalik Indicators, 6.Optical Sensors: a. Poyrometers, b. Infrared detectors, c. Liquid crystals,
7.Liquid Bulb Thermometers, 8.Gas Bulb Thermometers. Among these, the most versatile ones are
the thermistors, the thermocouples, the RTD’s, and the IC sensors.
Example 1.7: The density of mercury changes approximately linearly with temperature as, m 14277.5 2.5T ( K ) . Due
to influence of temperature, the same pressure difference will be measured by different manometer heights. Suppose in New
York City, on a hot summer day the temperature is 40C and the pressure is the same as the pressure measured on a cold
Winter day of -10C. What will be the percent deviation in the manometer reading?
Solution:
h2 1
Since we measure the same pressure for both cases, in accord with Eq. (1.14), 1gh1 2 gh2 , and . On the other
h1 2
h1 h2
hand the percent deviation in height may be expressed as, Err% 100 1 1 100 . Since T1=313K, and
h1 2
T2=263K, by stated formula, 1/2=0.9908. Then the percent error becomes, err%=0.91% which is less than 1-percent.
1.Thermistors.A thermistor, Figure 1.15a, is a semiconductor material with a well defined variation
of electrical resistance with temperature. The relationship between the temperature and the resistance
change is given as,
T K R (1.16)
As shown in Figure 1.15c, for most of thermistors, the temperature coefficient ( K 0 ) is negative
(NTC). That is the resistance decreases as the temperature increases.
14 THERMODYNAMICS
Since the thermistor output is directly related to the absolute temperature, there is no need for a
reference junction, and a calibration curve as given in Figure 1.15c is sufficient to convert the resistance
measured by the circuitry in Figure 1.15b to the temperature. The main disadvantage of a thermistor
is the possible self heating error in case of repeated measurements. Due to slow response, they are
more difficult to apply to transient processes.
2.Thermocouples.As shown in Figure 1.16, any two unlike conducting materials could be used
to form a thermocouple.
The net electromotive force generated on the circuit is due to the temperature gradient along the
wire, and is called the Seebeck effect. The Seebeck coefficient, for a thermocouple wire is defined
as,
d
dT
(1.17)
T T
i 0
where indicates the electromotive force difference measured by a voltmeter, and To is the
reference junction temperature. In Eq.1.17, the nominal values of Seebeck coefficients () for certain
combinations of materials and the corresponding temperature ranges are provided in Table 1.2.
Table 1.2 The most common thermocouples and their temperature limits
Since the values of thermocouples are small, the voltage outputs are also small. The output values
are typically in the milli-volt range. The size of the thermocouple wire is of some importance. Usually
the higher the temperature to be measured, the heavier should be the wire. As the size is increased,
however, the time response of the wire to temperature change increases and the couple becomes bulky.
Hence, some compromise between the response and the thermocouple life is required.
The thermocouple calibration data is used for determining the temperature corresponding to a
particular measured potential difference. As shown in Table 1.3, the experimental data for a particular
couple is tabulated and, in Figure 1.17a, the curve fit is used for temperature determinations.
Thermocouples are only capable of measuring the temperature difference. To measure the tem-
perature of an object, we need a known reference temperature. As shown in Figure 1.17b, the refer-
ence temperature is taken to be the temperature of ice and water mixture at sea level and is called
“ice point reference junction”. The use of large number of thermocouples in a particular application
is shown in Figure 1.18. This figure also describes the use of a single recording system by the zone
box application to the circuitry.
16 THERMODYNAMICS
Example 1.8: The temperatures at four points of an air-conditioning unit are measured by using copper-constantan thermo-
couples. The reference junction temperature is recorded as 20oC. If emf outputs in mV of these thermocouples are -1.620,
-1.053, +0.181, +2.215, determine the corresponding temperatures.
Solution:
Temperatures may be determined either by using Eq. (1.17) or by calibration curve values in Table 1.3. Since for large
temperature differences thermocouple behavior is nonlinear, the results will be more dependable, if the values in Table 1.3
are used.
From Table 1.3, (1)=2.035mV corresponds to a temperature difference of 50oC, and employing the linear interpola-
tion method for
1=-1.620mV, one may find, T1 To 39.803 , where To, is the reference temperature of 20oC, and the measured
temperature becomes, T1=-19.803 oC.
CHAPTER 1 BASIC CONCEPTS & DEFINITIONS 17
Since the following two measurements are in same range of temperature calibration, the temperature values can be
determined by applying the same method and the corresponding temperatures become, T2=-5.87 oC, T3=24.44 oC.
For the last temperature, 4=2.215mV > 2.035mV, the difference has to be evaluated by the second calibration value
in Table 1.3. 4-(1)=2.215-2.035=0.18mV, on the other hand, (2)- (1)=4.278-2.035=2.243mV. Hence, 0.18mV cor-
respond to 4.012oC. T4 To 50 4.012 , T4=74.012oC.
RTD’s are positive temperature coefficient (PTC) sensors whose resistance increases with tem-
perature. The platinum resistance thermometers can cover a temperature range -200oC to +800oC, and
they are the most accurate sensors for industrial applications.
As explained above there are several different temperature-sensing technologies available for the
applicant to select the appropriate one. To find out the right technology, however, depends on the
characteristics of the target temperature (for instance; the number of measurement points, steady or
unsteady measurement, etc.), and on the system requirements such as cost, circuit size and design
time. In Figure 1.20, a comparison of the advantages and the disadvantages of these three temperature
measurement systems is presented and discussed as following:
Advantages
1. Thermocouple: 2. Thermistor: 3. RTD:
a. Self powered High output Most stable
b. Simple Fast Most accurate
c. Inexpensive Two-wire ohm measurement More linear than thermocouple
d. Variety of physical forms
18 THERMODYNAMICS
Disadvantages
1. Thermocouple: 2. Thermistor: 3. RTD:
a. Nonlinear for a wide range Nonlinear Expensive
b. Low voltage Limited temperature range Slow
c. Reference required Fragile Current source required
d. Least stable Current source required Small resistance change
e. Least sensitive Self heating
Definition: The intensive state is the state of a point (x, y ,z) at time t, and is specified by all intensive
properties at that instant.
Homogeneous system. The system is said to be homogeneous at time t, if its intensive state is
the same throughout the system. Thus, for a homogeneous system, the intensive properties are inde-
pendent of location. Hence, the pressure, the temperature, the density, etc. are all uniform throughout
the system. For instance, in transient temperature analysis of a copper block, a homogeneous system
model may appropriately be employed.
Steady-state system. If all properties of a system are independent of time, then the system is
called a steady-state system. In this case, the intensive properties of the system are time invariant,
but they may vary with position.
Example 1.9: Consider the heat exchanger of Fig.1.21, the cold water flows through the tubes of the exchanger and steam
condenses on the shell side. Both fluids are at constant flow rate. Define the system and the state whether the system is
steady or unsteady.
Solution:
Defining the exchanger as a system, it is a steady-state system. For instance, the water pressure assumes the value of p1 at
the inlet, and p2 at the outlet. These pressures are invariant with time. Because of fluid friction, however, the pressure at a
certain point along the flow is always less than the inlet value. Thus, the pressure exhibits a local variation.
CHAPTER 1 BASIC CONCEPTS & DEFINITIONS 19
Principle 4: If two systems are in thermodynamic equilibrium with each other then they
are said to be in mechanical equilibrium (equality of pressures), in thermal equilibrium
(equality of temperatures), and in chemical equilibrium (equality of gibbs function) etc.
Like a ball in gravitational field, as described in Figure 1.22, a system might possess three dif-
ferent equilibrium states. The metastable equilibrium is a state that a finite change of state of the
20 THERMODYNAMICS
system may be produced by an infinitesimal change of state of the environment. There is always a
high possibility that the system might not return to its initial state. Thermodynamics is restricted to a
large degree to systems in stable states.
Definition: A system is said to be in stable equilibrium state if and only if a change of state of the
system is attained by a corresponding finite change in its environment.
In Figure 1.22, the state (3) where the ball is at the bottom of the curved surface is the stable
equilibrium state. The position of the ball can only be changed if it interacts with environment and
finite amount of energy is consumed. The system and its environment may always be return to their
initial states
Solution:
In Figure 1.23, the initial and the final states of the gas is represented by (1) and (2) respectively. Considering the occurrence
of the process from the beginning to the end, all intermediate states are definable, and so is its path. Hence, the gaseous
system undergoes a quasi-equilibrium process.
Processes during which one property remains constant are designated by the prefix iso- before
the property. For example, a process for which the temperature is constant is called iso-thermal,
similarly the constant pressure process is called isobaric, and the constant volume process is called
iso-volumic process.
CHAPTER 1 BASIC CONCEPTS & DEFINITIONS 21
At the compressed state, state 2 in Fig 1.23b, if all the weights are removed at once, a rapid rising
of the piston will result with a spontaneous expansion of the gas. This type of a process is called
a non-equilibrium process. For a non-equilibrium process, the process path is not mathematically
definable, and only the end states before and after the process can be described.
References
1. Y. A. Cengel and M. A. Boles, Thermodynamics An Engineering Approach, 5th edition, McGraw Hill Publications,
ISBN 978-0-07310-7684, 2005.
2. I. Müller, A History of Thermodynamics, The Doctrine of Energy and Entropy, Springer-Verlag, ISBN 978-3-540-
46226-2, 2007.
3. S. J. Blundell and K. M. Blundell, Concepts in Thermal Physics, Oxford University Press, ISBN 978-0-19-856770-7,
2006.
4. P. R. N. Childs, Practical Temperature Measurement, Butterworth-Heinemann, ISBN 0-7506-5080-X, 2001.
5. L. A. Gritzo and N. Alvares, Thermal Measurement: The Foundation of Fire Standards, American Society for Testing
and Materials International (ASTM), ISBN 0-8031-3451-7, 2003.
6. D. J. C. Vazquez, and M. C. Sancho, Thermodynamics of Fluids under Flow, 2nd Edition, Springer Science, ISBN
-978-94-007-0198-4, 2011.
7. “Instrumentation Reference Book, 3rd Edition, Edited by W. Boyes, Butterworth-Heinemann, ISBN -0-7506-7123-8,
2003.
Problems
b. the absolute pressure of point 2 for a pressure 1.25 An inclined manometer in Figure 1.11c is always
reading of 2 atm. on manometer A. much more sensitive than a simple manometer.
Assume the outside pressure to be at 760 mmHg. Determine the angle of inclination for making an
inclined manometer that is ten times as sensitive as
a simple manometer.
Temperature
1.28 Type-T thermocouples are employed for measuring i. It is always possible to define the path
the temperatures at various points in air conditioning of a quasi-equilibrium process.
system of a building. The reference junction tempera-
ture is taken to be 22°C. The following emf output j. To define the end state properties of a
are supplied by various thermo-couples: -1.623 mV, system, the path of a process has to be known.
-1.088 mV, -0.169 mV, and +3.250 mV. Determine
the corresponding junction temperatures by linearizing
k. A thermal equilibrium within systems
the calibration curve given in Figure 1.17a.
is established by the equality of temperatures.
1.29 The temperature difference between the inlet and l. A mechanical equilibrium of two systems
outlet of a heat exchanger has to be measured. The requires the equality of pressures.
measuring and the reference junctions of type T
thermo-couple are embedded within the inlet and m. Two end states are sufficient to identify
outlet sections of the exchanger and an emf of a process
+0.395mV is read.
n. In measuring unsteady pressures usu-
a. Is this a correct way of measuring the temperature
ally electromechanical transducer methods are
difference? Explain.
preferred.
b. What additional information is essential and what
procedure may be followed to get an answer for o. A pressure pick up should be insensitive
the temperature difference? Explain. to temperature change and acceleration.
Check Test 1
Choose the correct answer:
Hence there is a strong relation between the state of a system and the amount of energy
interaction. To determine the new state of a system due to energy interaction, or to find
out the amount of energy transferred due to change of its state, we have to have detailed
information about the properties of the system and cast a methodology for determining the
system properties. The purpose of this chapter is to provide information on the equilibrium
thermodynamic properties of homogeneous systems based on experimental observations.
27
28 THERMODYNAMICS
Among all the thermodynamic properties, there are some which are related by definitions. For
example, enthalpy, H is related to the internal energy U, the volume V, and the pressure p of a sys-
tem as,
H = U+pV (2.1)
Since the specific enthalpy is h = H/m, it may be described by the specific internal energy and
the volume as,
h = u+pv (2.2)
The specific Gibbs free energy and the Helmholtz free energy are accordingly defined as,
g = h-Ts (2.3)
a = u-Ts (2.4)
where “s” is the specific entropy of a simple system. The physical meaning and the use of entropy
is explained later in detail in Chapter 5.
Certain other properties are related as a result of either experimental observations or of the first
and second laws of thermodynamics. These relations are called equations of state. One particular
Example of an equation of state is the relation among the pressure, the temperature, and the specific
volume of a fluid (liquid or gas) and described in alternative forms as following,
p p( v, T )
v v ( p, T ) (2.5)
T T ( p, v )
It has to be reemphasized that these relations are deduced by empirical means and interrelate only
the intensive properties of a system.
As shown in Fig. 2.2, the thermodynamic condition of a point M(x, y, z) in a system at time t is described
by all the intensive properties. Some of these intensive properties are internal (T,p,v,ρ,u,h,...), and some are
external (V, ke, pe, ...). To define the state of a homogenous system, however, it is not necessary to know all
the intensive properties. Some are interrelated by definitions, and some are described by the state equations.
CHAPTER 2 THERMODYNAMIC PROPERTIES OF SYSTEMS 29
The minimum number of independent properties required to define the state of a system is determined by
the state principle. Although this principle is based on experimental observations of so many systems, it is
regarded as a fundamental law of thermodynamics. The state principle stated rather simply as,
Principle 5: Any two independent intensive properties are sufficient to establish the
thermodynamic state of a simple system. For each identifiable departure from the
requirements of a simple system, one additional independent property is necessary.
Considering the state principle for a simple system, an intensive property is a function of two
other independent properties. That is, P1 = f(P2,P3), where P, in general, is any intensive property.
From a mathematical point of view, any equation involving two independent variables (such as P2,
30 THERMODYNAMICS
and P3) can be represented in a Cartesian space as a surface. As a consequence, the equilibrium states
of a simple system can be represented as a surface in space, where geometric coordinates are the
intensive properties of that state. Taking the pressure p, and the entropy s as independent proper-
ties, the enthalpy h of a simple system becomes the function of the pressure and entropy; h = h(p,s).
However, because of exhibiting the basic structure of matter, p-v-T surface of a simple substance will
be studied in this section.
In Fig. 2.3, two unique p-v-T behavior of matter is shown. As in the case of metals, some matter
contract on freezing. In Fig. 2.3a, it may be noted that a step decrease in specific volume takes place
when going from liquid to solid state. Water expands on freezing and Fig 2.3b schematically represents
the p-v-T surface of water. It may be noted that a step increase in specific volume takes place when
going from liquid to solid state.
A detail understanding of the following terms is important in studying the p-v-T surface of matter:
a. Phase (solid, liquid, gas), b. Sublimation, melting, vaporization, c. Triple point, d. Saturated
liquid, saturated vapor, liquid-vapor mixture, e. Critical point, f. Saturation temperature at a given
pressure, h. Superheated vapor, i. Compressed liquid, or sub-cooled liquid, j. Interpolations.
In addition, it is equally important to visualize and locate the states on the three coordinate projec-
tions of the p-v-T surface. Figure 2.4 schematically illustrates p-T, T-v, and p-v plane projections for
a simple system. In these figures, the discrepancy between the contracting and the expanding matter
upon freezing is also indicated. The dashed line in Figure 2.4a represents the melting curve for a
substance which contracts on freezing.
To understand the thermodynamic behavior of substances at various pressures and temperatures,
first, regions of low, medium, and high pressures are to be defined with respect to the critical pressure
of that particular matter under study. After selecting the pressure region to be studied, the state of
matter at different temperatures may be discussed, and also compared. Because of its abundance in
our environment and its importance in many technological and biological processes, water is one of
the most thoroughly studied substances. Hence we will study the thermodynamic behavior of water
and also draw some general rules for certain properties.
Let us start analyzing the low pressure behavior of water by assuming the pressure to be at 0.26
kPa. Consider 1 kg of ice initially at (-20°C, 0.26 kPa) in a piston-cylinder device, the change of state,
as a result of heating the ice at constant pressure, is displayed in Figure 2.4a by line AB . First, the
ice temperature increases to -10°C, and then the ice changes phase directly from solid to vapor. This
process is known as sublimation.
CHAPTER 2 THERMODYNAMIC PROPERTIES OF SYSTEMS 31
It should be pointed out that a simple system may exist in a number of different triple points.
A substance may have two solid phases and liquid phase, or two solid phases and a vapor phase in
equilibrium. Furthermore, three solid phases, like in iron-carbon equilibrium diagram, may coexist.
However, only one triple point involves the equilibrium of solid, liquid, and vapor phases.
32 THERMODYNAMICS
To study the thermodynamic behavior of water at medium pressure range, let us consider 1 kg of
water contained within a piston-cylinder arrangement as shown in Figure 2.6a. The pressure on water
is maintained constant at 100 kPa, and the initial temperature is at 25°C. As heat added to water, the
volume will be measured as a function of water temperature, with water allowed to reach equilibrium
prior to each measurement. The starting value for specific volume is 0.001003 m3/kg at a temperature
of 25°C. As the water temperature increases, the liquid water expands slightly increasing its specific
volume. For instance, at 80°C, the specific volume is 0.00103 m3/kg.
Eventually, the water reaches 99.63°C, and with more heat input the water starts to boil. During
the boiling process, two phases (liquid and vapor) coexist in equilibrium with the temperature constant
at 99.63°C (see Figure 2.6b). At a particular pressure, the temperature of a substance at which boiling
takes place is called the saturation temperature. The saturation temperature for water at 100kPa is
99.63°C. Similarly, at a particular temperature, the pressure at which boiling takes place is called the
saturation pressure. The saturation pressure for water at 99.63°C is 100kPa or 1 bar. On T-v diagram
of Figure 2.6, the point B represents the saturated liquid state. The addition of more heat to water at
saturated condition, the vaporization process will be completed, and saturated vapor at 99.63C will
be obtained (point C on the T-v diagram). The specific volume of water will increase from 0.001043
m3/kg to 1.6940 m3/kg. This is a factor of 1624 times increase in volume.
Under the saturation line BC , liquid and vapor coexist in equilibrium. As displayed in Figure 2.6b,
the two phases may exist in a container at separate locations, or as an intermingling of vapor and small
liquids droplets which is called fog. Table A1, in the appendices, presents the thermodynamic properties
of saturated water. However, to provide a value for v at a state in the region between the saturated liquid
and vapor states, the amount of liquid and vapor present in the mixture has to be known. Thus,
V V f Vg m f v f mg v g
v (2.6)
m m f mg m f mg
In this expression, the subscript “f” refers to saturated liquid, and “g” to saturated vapor. Defin-
ing the quality of the mixture as x which is the ratio of the mass of the vapor to the total mass of the
mixture (x=mg/(mf+mg), equation (2.6) may be rearranged as,
v 1 x v f xvg v f xv fg (2.7)
CHAPTER 2 THERMODYNAMIC PROPERTIES OF SYSTEMS 33
It is obvious that the value of x may vary from zero (saturated liquid state, mg = 0) to unity (saturated
vapor state, mf = 0). In the liquid-vapor region, since the pressure and the temperature are dependent
properties, the state of a simple system is specified by (pressure, a property except temperature), or
by (temperature, a property except pressure). For instance, the value of v is completely specified
by the quality x, and the saturation pressure p, or by the quality x, and the saturation temperature T.
The other thermodynamic properties of a liquid-vapor mixture may also be described in terms of the
properties of saturated liquid and vapor states as following.
enthalpy: h h f xh fg (2.8)
entropy: s s f xs fg (2.10)
Further addition of heat to saturated vapor at 99.63°C causes the temperature to increase above the
saturation temperature. The vapor at a temperature above the saturation temperature is called super-
heated vapor. The curve CD in Figure 2.6 represents this region. In a superheated vapor region, as the
data for water shown in Table A3, pressure and temperature are independent properties. For a fixed
pressure, the temperature, being greater than the saturation temperature, may be varied as desired.
As illustrated in Figure 2.6, performing similar experiments for pressures other than 100kPa,
similar T-v plots will be obtained. However, we know that for pressures below 100kPa, the water will
boil below 99.63°C, and for pressures above 100kPa, as in a pressure cooker, the boiling temperature
will be above 99.63°C. In Figure 2.6, the points B1, B, and B2 etc. correspond to the saturated liquid
states, and C1, C, and C2 etc. correspond to saturated vapor states. The locus of all such saturation
states is called the saturation curve.
In Figure 2.7, the right of saturation line is the superheated region. To the left of saturation line
is the liquid region which is called either compressed liquid region, since the pressure of the liquid
is greater than the saturation pressure at the given temperature, or sub-cooled liquid region, since the
temperature of the liquid is below the saturation temperature at the specified pressure.
Figure 2.7 The saturation curve separates liquid, vapor, and liquid-vapor mixture regions.
34 THERMODYNAMICS
The compressed liquid data for water is shown in Table A4 and the locations are schematically
presented in Figure 2.8. As seen from this figure, the functional dependence of compressed liquid
properties on pressure is rather weak. For instance, by using the saturated liquid data at 100°C as an
approximation for the compressed liquid state of T*=100°C and p*=100 bars, errors of 0.479%, 0.67%,
1.7% and 0.589 percent are made in values of v, u, h, and s respectively. When compressed liquid
data based on experimental information are available, they should be used. In the absence of such
data, however, the above comparison indicates that the compressed liquid state can be approximated
by using the property values of the saturated liquid state at the same temperature.
A careful observation of saturation curve in Figure 2.7 displays that the difference in specific
volume between the saturated liquid and vapor get smaller as the pressure on water increases. At a
pressure of 22.12 MPa liquid and vapor exist indistinguishably at 374.15°C. This point labeled as
“c.p.” in the figure is called the critical point, with the pressure and temperature at this point called
critical pressure and critical temperature. Depending upon the kind of a substance, the pressure and
the temperature assume specific values at the critical point. Hence the critical point is considered as
a property of matter. In Table 2.2, pc, vc,, and Tc values of the critical point for several substances are
given and the critical constants of some more common substances are supplied in the appendices.
The thermodynamic behavior of matter at high pressure region may be analyzed by considering
pressures above the critical pressure. If water at 30 MPa, and 25°C is heated by a constant pressure
process, a curve such as EFG in Figure 2.7 will be obtained. The typical feature of v vs T distribution
in this pressure region is that the curve is continues and no indication of phase change is present.
Therefore, at supercritical pressures, there is no liquid or vapor phase of a simple substance existing
in equilibrium.
TABLE 2.2 Critical point data for several substances
As shown in Figure 2.9, choosing the interval for data to be the same as given in tables, reason-
ably accurate results might be obtained by linear interpolation. For instance, let us approximate the
temperature of superheated steam at (5 bars, 0.4249 m3/kg). In Table A3, the data for this state is
supplied and T=200°C, however, to evaluate the approximation error, the data at 0.4249 m3/kg are
assumed to be missing. The linear interpolation at pi=5 bars requires that,
v vi T Ti
(2.12)
vi 1 vi Ti 1 Ti
where the subscript i represents the data evaluated at 0.4045 m3/kg in Table A3, and i+1 at 0.4646
m /kg. Substitution of table values into equation (2.12) yields the temperature at (5 bars, 0.4249 m3/
3
kg) as 200.36°C which is off by less than 0.1 percent of the tabulated value and is quite accurate.
36 THERMODYNAMICS
Double interpolation has to be applied for cases such as neither the pressure nor specific volume
of the given state correspond to the available data. First, an interpolation carried out for the pressure,
and next the specific volume is interpolated to determine the desired data. As a result, the following
interpolation formula can be derived for determining the temperature at a state (p, v),
T Tij a1 (Ti , j 1 Tij ) a2 (Ti 1, j Tij ) a1a2 (Ti 1, j 1 Ti , j 1 ) a1a2 (Ti 1, j Tij ) (2.13)
where,
p pij v vij
a1 , a2 (2.14)
pi , j 1 pij vi 1, j vij
It should be noted that the double interpolation formula is general in the sense that any other in-
tensive property can be evaluated by replacing T by the desired property in Eq (2.13) The following
examples illustrate the use of tables in solving certain problems of engineering interest.
Example 2.1: Determine the dryness quality (if saturated) or the temperature (if superheated) of the following substances
at given states. a. R22, p=500kPa, v=0.031 m3/kg b. water, p=5 bars, v=0.6 m3/kg
Solution:
a. In determining whether the given state is in saturated or in superheated region, the specific volumes of the given
state and the saturated vapor state may be compared. The given state would be in superheated region for v vg ,
and in saturated region if v vg .
From Table A6, at p 500 kPa , vg 0.0469 m3 /kg , and v vg , a saturated state. By Eq. (2.7), the quality is
v v f / vg v f and due to negligible effect of the pressure on liquid volume, the value of v f at p 497.567 kPa
may be taken. Thus,
x 0.031 0.0007783 / 0.0469 0.0007783 , x = 0.655.
b. From Table A2, specific volume of saturated vapor at 5 bars, vg = 0.3749 m3/kg, v>vg, superheated vapor.
Using Table A3, and applying the linear interpolation method, Ti = 360°C, vi = 0.5796 m3/kg, Ti+1 = 400°C, and
vi+1 = 0.6173 m3/kg.
T 360 0.6 0.5796
, T=381.6°C.
400 360 0.6173 0.5796
Example 2.2: The closed tank of Figure 2.10 contains saturated water at
150°C. Determine the pressure at the base if the liquid water level from the
base is 12m.
Solution:
From Table A1, at a saturation temperature of 150°C, the pressure at sur-
face 1 is: p=475.8kPa, and vf = 0.00109 m3/kg. Since the liquid density,
f 1 / v f , then f 917 kg/m3 . The pressure at the base, by equation
(1.12), p2 p1 f gL , or
9.8 917 12
p2 475.8 , p2 = 583.64 kPa.
1000
Solution:
a. Due to the rigidity of the tank, the heating is a constant volume process, and v2 v1 V / m . For V = 0.002 m3,
m=1kg, the specific volume becomes, v1 0.002 m3 /kg . Since v1 vc , the liquid and vapor mixture will be at a
saturated liquid state at the end of the heating process. Such a result might seem peculiar at a first glance. However,
one should recall that the tank pressure and temperature increase as heat added.
b. In this case, the initial specific volume, v1 0.2 m3 /kg , and v1 vc . Thus, heating at a constant volume will result
with a saturated vapor state.
Example 2.4: A rigid and insulated tank in Figure 2.12 has a volume of 0.0081 m3 and contains 0.05 kg of water at 15 bar.
By a cooling process, the tank loses heat to surroundings at the base and the steam temperature decreases. Determine a. the
initial temperature, b. The temperature at which vapor becomes saturated, c. the quality of water if the final pressure in the
tank is 10bars.
Solution:
V 0.0081 m3
a. The initial specific volume of water, v1 , v1 0.162 m3 /kg
m 0.05 kg
For v1 0.162 m3 /kg , p1 15 bar , from Table A3, T1 = 280°C.
b. If the saturated vapor state represented by 2, v2 v1 0.162 m3 /kg , then Table A1 would yield, vi 0.1565 m3 /kg ,
T i=190°C, and vi 1 0.1941 m3 /kg , Ti 1 180o C . After a linear interpolation, the temperature at 2 is,
o
i 1 188.53 C .
Ti
c. From Table A2, at p3 = 10 bar, v3 = 0.162 m3/kg, vg3 = 0.1944 m3/kg, vf3 = 0.00112 m3/kg, and by Eq. (2.7),
0.162 0.00112
x , 0.8323 .
0.1944 0.00112
Example 2.5: The piston-cylinder apparatus of Figure 2.13 contains 5 kg R22 at 10°C, 80% liquid and 20% vapor by
mass. As the refrigerant heated, the piston rises, and reaches the stops when the cylinder volume becomes 200 L. Estimate
the refrigerant temperature as the piston just touches the stops, and plot the process on p-v diagram.
Solution:
Since the stops don’t exert any force at the final state, the heating is a constant pressure process. From Table A6, at T1 10o C ,
the pressure is p1 354.284 kPa , and p2 p1 .
V2
At state 2, V2 0.2 m3 , the total mass, m = 5 kg, and the specific volume, v2 0.04 m3 /kg which is less than
m
the saturated vapor specific volume of 0.065342m3/kg at 354.284 kPa. Thus the final state is still a saturated state, and the
final temperature remains the same, T2 = 10°C. Including the saturated line, the p-v plot of the process is illustrated in
Figure 2.13.
Example 2.6: Consider the piston-cylinder arrangement in Figure 2.14a, which contains 0.1 kg of saturated vapor at 140°C,
and the piston has a cross sectional area of 0.05 m2. The linear spring, having a spring constant of 100 kN/m, initially
touches to the piston surface and exerts no force. Through a heating process, the pressure in the cylinder becomes 500 kPa.
Determine the final temperature of steam and plot the process on p-v and T-v diagrams.
Solution:
A careful study of the geometry of the systems reveals that due to presence of spring the vapor pressure and volume are
interrelated as,
K V V1
p p1 (2.15)
A2p
This relationship is derived by considering the equilibrium of forces applied on the piston surface for a volume V V1 .
From Table A1, at T1 = 140°C, p1 = 361.3kPa, v1 = 0.508m3/kg, and V1 mv1 , or V1 = 0.0508 m3. For p2 = 500kPa, and
K=100kN/m, Eq. (2.15) yields the final volume, V2 0.05426 m3 , and the specific volume, v2 0.542 m3 /kg . Since
v2 v2g , the final state is in superheated vapor region, and through Table A3, the temperature at (500kPa, 0.5426m3/kg)
may be estimated by linear interpolation as following,
Similarly, the slope of a curve obtained by the intersection of a constant volume plane with a
“u-v-T” surface defines the specific heat at constant volume as following,
u
cv (2.17)
T v
Both of these expressions contain only thermodynamic properties from which one may conclude
that the constant-pressure and the constant-volume specific heats are also thermodynamic properties
of a substance. Moreover, since the enthalpy of a substance has a higher value than internal energy,
cp, has to be numerically greater than cv.
Figure 2.15 displays the distribution of cp for water at 1atm pressure. Notice that although cp var-
ies strongly with T for solid water (ice), it is nearly independent of T for the liquid and vapor phases.
The difference between cp and cv for any substance may be determined by making use of Maxwell
relations and expressed as following,
p v
c p cv T (2.18)
T v T p
If a substance is in solid or in liquid phase, both the thermal expansion coefficient, ( v / T )p,
and the pressure coefficient, ( p / T )v, are very small in value and the difference between cp and cv
is generally insignificant, cpcv. Therefore, for liquids and for solids, a single value for each phase
is assigned to the specific heat and simply indicated by ' c ' without any subscript. Moreover, cp of a
solid or a liquid substance depends only weakly on pressure except states near the critical point. Thus,
40 THERMODYNAMICS
the data shown in Figure 2.15 for solid and liquid water can be safely used for pressures other than 1
atm. On the other hand, cp of water vapor varies significantly with pressure especially for states near
the saturation line and near the critical point.
Example 2.7: Using the data in Table A3, evaluate the specific heats c p , and cv of superheated vapor at 10 bars pressure,
and 200°C temperature.
Solution:
Equation (2.16) may be approximated as,
h h
c p i 1 i and from Table A3, at pi=10 bars, Ti = 200°C, hi = 2827.9 kJ/kg
Ti 1 Ti p pi
Ti+1 = 240°C hi+1 = 2920.4 kJ/kg
Substitution of these data into the defining relation results with c p 2.312 kJ/kgK .
u u
Similarly, cv i 1 i and from Table A3, at vi = 0.206 m3/kg, Ti = 200°C, ui = 2621.9 kJ/kg
Ti 1 Ti v vi
Ti+1 = 400°C ui+1 = 2951.3 kJ/kg
Note that vi+1 = vi, but the pressure at i+1 is 15 bar. Thus, the definition of cv yields, cv 1.647 kJ/kgK .
if possible, to provide relations among the properties that are sufficiently general and accurate. Any
equation that relates the pressure, the temperature, and the specific volume of a substance is called
an equation of state.
As shown in Figure 2.16, experiments performed on numerous gases show that as the absolute
pressure approaches zero (p0), “ pv 1” assumes the same value regardless of the nature of the gas.
The limiting value of pv at zero pressure is the same for all gases at the same temperature. Simi-
lar plots would result for data at other temperatures except that the value of zero pressure intercept
differs for every new temperature.
Consequently, the pv product at zero pressure is proportional to absolute temperature as fol-
lowing,
1
T (lim pv) (2.19)
p 0
where is the constant of proportionality, and is called the universal gas constant. Numerous
experiments performed on various gases at a condition identical with the triple-point of water have
showed that assumes a numerical value of 8.3144 kJ/kmol K. Sometimes, instead of , it is prefer-
able to use the specific gas constant which represented symbolically as R. These two gas constants,
however, are related as following,
MR (2.20)
In Eq. 2.20, M is the molar mass of a gas, and R varies with respect to the molar mass of the gas
concerned. In the appendices, Table A17 provides R values for a number of gases.
Figure 2.16 Experimental data for the variation of p v with pressure at a given
temperature for several gases
1
a bar over a property stands for a molar property.
42 THERMODYNAMICS
Besides this peculiar behavior of gases at low pressure, it is desirable to relate p, v, and T at high
pressures and at regions near the saturation and near the critical point. The p-v-T representation of a
gas may be provided for a wide region of pressures and temperatures by the introduction of a correc-
tion factor called the compressibility factor Z. It is defined as,
pv
Z= (2.21)
T
where, p and T are the absolute pressure and temperature respectively at a given state. As shown
in Fig. 2.17, the plot of experimental data for various gases at different temperatures indicate that Z
assumes a limiting value of unity as the pressure is lowered to zero.
1
lim Z (lim pv ) 1 (2.22)
p 0 T p 0
For all gases, independent of temperature, Z = 1 at very low pressures. However, as indicated in
Fig. 2.17 at high pressures, Z is a function of both pressure and temperature, Z = Z(p,T).
The question of what exactly constitutes the low pressure and the high temperature essentially
depends on the nature of the gas under consideration. For a particular gas, the pressure and the
temperature at a given state is low or high relative to the critical pressure and temperature of that
gas. Referring to Table 2.2, a temperature of “-50°C” is high enough for air which has a critical
temperature of “-140.6°C”, but this temperature is low for carbon dioxide. Therefore, gases behave
differently at a given temperature and pressure, but behave very much the same at temperatures
and pressures normalized with respect to their critical temperatures and pressures.
p T
pr Tr (2.23)
pc , Tc
CHAPTER 2 THERMODYNAMIC PROPERTIES OF SYSTEMS 43
Where pr and Tr are the ratios of absolute pressures and temperatures, and are respectively called
the reduced pressure and the reduced temperature. In Figure 2.18, experimentally determined Z
values of ten gases for reduced isotherms Tr are plotted on a Z vs pr chart.
Through a curve fitting to available data, the p-v-T behavior of gases is estimated by an average
deviation of less than 5-percent. Therefore the following principle may be stated.
This principle is also called the rule of corresponding states, and curve fitting to data for all
gases, the generalized compressibility chart as shown in Figure 2.18 is obtained. Recently, Lee and
Kesler provided an analytical expression which satisfies the generalized compressibility values fairly
accurately for reduced pressures in the range 0 pr 10 , and expressed as following,
A1 A2 A3 A
Z pr vr / Tr 1 2 5 3 4 2 2 exp 2 (2.24)
vr vr vr Tr vr vr vr
where, A1 a11 a21 / Tr a31 / Tr2 a41 / Tr3 A 2 a12 a22 / Tr A 3 a13 a23 / Tr
The aij type constants of this relation for a simple substance are provided in appendices. In Figure
A1, the pseudo reduced volume which is defined as vr pc v / RTc , represents iso-volumetric lines on
“Z vs p” chart. It should be noted that the generalized chart is only an approximation. In the absence
of experimental data, however, the generalized chart yields results that are accurate to within a few
percent, and such an error is considered to be reasonable for many engineering design problems.
Example 2.7: 2 kg of Butane (C4H10) in a piston cylinder assembly undergoes a process from (5 MPa, 500K), to (3 MPa,
450K). Determine the volume change of Butane.
Solution:
From Table A.17, pc=38 bar, Tc=425K, M=58.12 kg/kmol, reduced values at state1 are, pr1 p1 / pc 50 / 38 1.315 ,
Tr1 500 / 425 1.176 , the corresponding, Z1, by Figure 2.18, Z1 = 0.68. Similarly, pr 2 30 / 38 0.789 , Tr 2 450 / 425 1.058 ,
and by Figure 2.18, Z2 = 0.74. The gas constant is, R=8.314/58.12=0.143 kJ/kgK.
RT 0.143 500
The specific volume at state 1 is, v1 Z1 1 0.68 , v1=0.00972 m3/kg
p1 5000
RT2 0.143 450
and at state 2 becomes, v2 Z 2 0.74 , v2=0.0158m3/kg. The total volume change is: V m(v2 v1 )
p2 3000
or V 2 (0.0158 0.00972) 0.012 m3 .
2.6.1 The equations of state. Even though the generalized compressibility chart estimates the
p-V-T behavior of real gases fairly accurately, it is always preferable to have an equation of state that is
applicable to all kinds of gases. Unfortunately there is no such a relation that represents the gas phase
region of all substances accurately. The most of the equations are accurate only for densities less than
the critical density, and a few are reasonably accurate to densities 2.5 times the critical density.
There are two experimental facts that may not be neglected in constructing an equation of state
for real gases. 1. Molucules attract each other with a force which is inversely proportional to the
square of the average distance between them, F 1 / d 2 . 2. Molecules have physical dimensions and
occupy certain volume and this volume usually is not negligible with respect to the volume that the
gas spreads.
Taking into account these two factors, an early
attempt was made by van der Waals in 1873, and
suggested the following equation of state,
a
p 2 ( v b ) T (2.25)
v
272Tc2 Tc
a b= (2.26)
64 pc 8 pc
Eq. (2.25) together with the critical point data of a substance determines a, and b constants of van
der Waals equation. Table 2.3 provides the constants of van der Waals equation of state for several
gases.
a b
Substance (m kPa/kmol2)
6
(m /kmol)
3
The van der Waals equation of state presents deviations in a region especially close to the critical
point. There are other equations of state with better approximation to experimental data but they are
more complex. One of them is Beattie-Bridgeman equation.
RT B A
p (1 C ) 1 2 (2.27)
v v v
a b c
where, A Ao 1 B=Bo 1 C= 3
v v vT
The five adjustable parameters, a, b, c, Ao, and Bo are determined by curve fitting to experimental
data. This equation of state is very accurate if it is used within the range of the data that the adjustable
parameters were derived.
Principle 7: Kinetic theory of gases: a. Gas molecules are small compared with aver-
age distance between them. The volume occupied by the gas molecules themselves is
neglected, b. Gas molecules collide without loss of kinetic energy, c. Gas molecules
exert practically no forces on one another except when they collide.
The gas behavior which closely approximates the above stated conditions is called ideal gas
behavior. In accord with principle 5, the coefficients of van der Waals equation of state (Eq. (2.26))
are both zero; a=b=0, and ideal gas is defined as following.
46 THERMODYNAMICS
Definition: The ideal gas model of a real gas satisfies the following criteria: a. pv T , and b.
u u (T ) .
The first of the defining criteria requires that the compressibility of the gas has to be unity. Re-
ferring to the compressibility chart in Figure 2.18, a. At very low pressures, pr 1 , gases obey the
ideal gas model regardless of temperature, b. At high temperatures, Tr 2 , gases display ideal gas
behavior for reduced pressures in the vicinity of 4, c. The deviation from ideal gas model is greatest
in a region near the critical point.
Let us consider water vapor at pressures lower than 20 kPa, since, pr 0.0009 , the vapor can
be treated as an ideal gas for such pressures. In air-conditioning applications, the pressure of water
vapor in air is very low, and can be treated as ideal gas. In steam power plant applications, however,
due to high pressure, the ideal gas model for vapor yields unacceptable errors.
CHAPTER 2 THERMODYNAMIC PROPERTIES OF SYSTEMS 47
When the equation pv T plotted on a p-v-T coordinate system, the generated surface would
appear as shown in Figure 2.20 where the constant T-plane represents hyperbolas because the product
pv is constant. The p-T projection of the surface, however, represents straight lines and indicates that
absolute pressure linearly varies with absolute temperature at a constant volume.
In applying the relationship, pv T , difficulties usually arise due to failure of properly con-
sidering the units involved. Table 2.4 may be used for the application of ideal gas equation in various
forms and the units involved.
Referring to the second of the ideal gas defining criteria, the internal energy of ideal gas is only a
function of temperature. This result seems contradicting the state principle but it is not. At very low
pressures, the effect of pressure on the internal energy of real gases becomes negligible. One should
also recall that ideal gas model represents the real gas behavior at very low pressures. Furthermore,
the substitution of pv T into enthalpy definition, h u (T ) pv , yields,
h u (T ) T (2.28)
Which shows that the enthalpy of ideal gas is also a function of temperature only, h h(T ) .
Example 2.8: Evaluate the volume occupied by 2 kg of Refrigerant 22 (R22) at 700 kPa, and 50°C by a. the experimental
values in superheated table, b. the principle of corresponding states, c. the van der Waals equation of state, and d. ideal gas
equation of state.
Solution:
a. From Table A7, the specific volume of R22 at (700 kPa, 50°C) is 0.0408 m3/kg, and the total volume occupied,
V mv , V 0.0816 m3.
b. For R22, Table 2.2 yields pc 4977 kPa, Tc 96.01o C , and corresponding reduced pressure and temperature
respectively are pr 0.1406 , Tr 0.875 . The generalized compressibility chart, Figure 2.18, yields Z = 0.92.
From Table A21, R=0.0961 kJ./kgK, and substituting these values into pv ZRT ,
0.92 0.0961 323
v or v = 0.04081 m3/kg which is 0.02% off from the true value.
700
T 8.314 x323
c. The van der Waals equation of state, v b , assume v=2 m3/kmol, v (1) 0.077 , v(1)=3.06
a 797.31
p 2 700
v 22
8.314 x323
m3/kmol, v (2) 0.077 , v(2)=3.497 m3/kmol. Hence v=0.04043m3/kg which is 0.08% off from the
797.31
700
3.062
experimental value.
0.0961 323
d. The equation of state for ideal gas, pv RT , and v or v = 0.0445 m3/kg which is in 9% error
700
for estimating the specific volume.
Equation Units
p:kPa
p= RT V:m3
= V/n n:number of kilomoles
pV = nRT R = 8.3144 kJ/kmolK
48 THERMODYNAMICS
Equation Units
T:K
n = m/M M:kg/kmol
pV = m(R/M)T p:kPa
R = R/M V:m3
pV = mRT m:kg
v = V/m m:kg/kmol
pv = RT R:kJ/kgK
ρ = 1/v T:K
p = ρRT
Example 2.9: A tank having a volume of 5 m3 is filled with methane (CH4) at 8.5 MPa and -23°C. Due to poor insulation,
the gas warms up to 17°C after a period of time. Estimate on the basis of compressibility chart, a. the mass within the tank,
and b. the final pressure in the tank.
Solution:
a. From Table A21, pc 46.4 bar, Tc 190.7 K , R = 0.5183 kJ/kgK, M = 16.04, and pr1 8500 / 4640 1.83 ,
Tr1 250 / 190.7 1.31 . By Figure 2.18, Z1 = 0.73, and the specific volume at state 1 is:
Z1RT1 0.73 0.5183 250
v1 , v1 0.0111 m3/kg. The amount of methane in the tank,
p1 8500
m V/ 450.45 kg .
b. The pseudo reduced volume is constant for the heating process, and
Tc 8.3144 190.7
vc 0.3417 m3/kmol.
pc 4640
The molar specific volume, v1 Mv1 , v1 0.178 m3 /kmol and the pseudo reduced volume at state 2 is
Thus, for Tr 2 1.52 , and vr 2 0.52 , Figure 2.18 yields pr 2 , and the final pressure becomes, p2 10.904 MPa.
Example 2.10: As shown in Figure 2.21, a laterally insulated vertical cylinder with 0.001 m2 cross sectional area initially
contains air at 100 kPa, 20°C, and a frictionless piston of 10 kg mass rests on the first stop. As a result of a heating process,
determine, a. the air temperature at which the piston just starts raising, b. the position of the piston for air temperature of
700 K, and c. the temperature at which the piston touches the second stop.
CHAPTER 2 THERMODYNAMIC PROPERTIES OF SYSTEMS 49
Solution:
a. The required pressure for raising the piston, p2 p1 m p g / Ap which yields p2 200 kPa . At state 2, where
the piston just starts raising, V2 V1 , and the equation of state for ideal gas yields,
p2 T2 p 200
or T2 2 T1 , T2 293 , T2 = 586 K.
p1 T1 p1 100
b. At state 3, where the air temperature is 700 K, if the piston is not at the upper stoppers, then V3 < 0.0004 m3, and
p3 p2 . This condition can be checked by the ideal gas equation, since p3 = p2, , and
V3 0.000238 m3 which is less than 0.0004 m3. Thus the height of the piston from the base is: 0.238 m.
V V V
c. When the piston just touches the upper stopper, p4 p3 p2 , and 4 2 ,T4 T2 4 , T4 = 1172 K.
T4 T2 V2
Example 2.11: A U-tube manometer with a cross sectional area of 5 cm2 contains mercury (ρm=13600 kg/m3). One end of
the manometer is open to the atmosphere while the other end is sealed off and contains air. The manometer initially is in
equilibrium with the environment of 100 kPa, 300 K, and as shown in Figure 2.22, the mercury column is 15 cm high. After
pouring 50 cm3 of mercury into the manometer, determine a. the final volume occupied by air, b. the difference in height of
two mercury columns, c. the final pressure of the trapped air in the sealed column.
Solution:
a. Note that before and after pouring the mercury, the temperature of air is the same, T2 = T1 = 300 K. Thus, for air
the ideal gas equation reduces to p1V1 p2V2 . Air pressures at state 1 and 2are calculated as following:
where according to the figure, L2 = 25-2y cm. Air volumes at state 1 and 2: V1 = 150 cm3, V2 = 5(30-y) cm3.
Thus,
Solving for y yields, y = 1.94 cm. Therefore, the final volume becomes, V2 = 140.3 cm3.
Example 2.12: A vertical and weightless tank with an open bottom has a height of 1 m and submerged into liquid water.
The open end initially just touches the water surface and the tank containment is air at 1bar, 25°C. a. Drive a relation between
the pressure in the cylinder and the height of the cylinder above water surface, b. Determine the height L for air pressure of
1.05 bar, c. Evaluate the air pressure for L=0.
Note: Assume that the temperature of air in the cylinder is always at 25°C.
Solution:
a. Since temperature is constant for the submerging process, the relationship between the pressure and volume of air is:
poVo pV , or po Lo p L y
On the other hand, the air pressure in the tank is p po gy . Solving for y, and substituting into above relation
yields L in terms of pressure p as,
L p p p0
0
L0 p gL0
b. From Table A1, at 25°C, = 997.1 kg/m3, p = 1.05 bars, p0 = 1 bar, L0 = 1 m, and g = 10 m/s2, L/L0 = 0.451, or
L = 0.451 m.
c. Let = p/p0, and for L/L0 = 0, above relation yields the following equation, 2 0.0997 0 , by which
Example 2.13: As shown in Figure 2.24, an insulated vessel of 0.1 m2 cross sectional area is divided into two identical
compartments by a weightless, frictionless, and dia-thermal piston which is initially at rest on stops. The lower compartment
contains 1 kg of liquid water and steam mixture at 10 bar, and the upper one holds air. As a result of a heating process, the
piston moves upward by 10 cm. Determine a. the final pressure and temperature in both compartments, b. the quality of
vapor at the final state.
Solution:
a. Since the piston is weightless and frictionless, both compartments have the same pressure at the initial as well as
the final states, pa1 = pb1 = p1, p1 = 10 bars, and pa2 = pb2 = p2 . Moreover, dia-thermal piston necessitates that Ta1 =
Tb1=T1, T1=179.9°C, and Ta2 = Tb2 = T2. For the ideal gas behavior of air,
V T
p2 a1 2 p1
Va 2 T1
CHAPTER 2 THERMODYNAMIC PROPERTIES OF SYSTEMS 51
Because of saturated conditions at the final state, the pressure p2, and the temperature T2 are dependent variables, and
trial and error method has to be applied. Let p2 = 13 bars, interpolation through Table A2 yields T2 = 464.6 K, and Va1 =
0.05 m3, Va2 = 0.04 m3. Substitution of these values into the relation, as given above, result as, 1312.8, which closely ap-
proximates the final state.
b. The final volume of compartment a, Va2 = 0.06 m3, ma 1 kg , and va2 = 0.06 m3/kg. From Table A2, for p2 = 13
0.06 0.00114
x2 or 2 0.368 .
0.15486
dh
The constant pressure specific heat, c po (2.29)
dT
du
The constant volume specific heat, cvo (2.30)
dT
We know that as the pressure is lowered, the behavior of a real gas approaches ideal gas behavior.
Hence, the symbols c po , and cvo signify values of real gas specific heats at zero pressure.
As shown in Figure 2.25, a typical characteristic of monatomic gases, such as Argon, Helium,
Neon, etc., is that c po of these gases is constant over a wide range of temperature. The kinetic theory
of gases predicts the value of c po for monatomic gases as or 20.8 kJ/kmol K. As one may notice
from Figure 2.25, an appreciable change in c po values for gases having molecules with two or more
atoms takes place when the temperature interval is rather large. For instance, in a temperature range
from 300 K to 1300 K, of carbon dioxide changes by 65 percent.
52 THERMODYNAMICS
Substituting equations (2.29) and (2.30) into (2.31) would result the following relationship between
the specific heats of ideal gases.
c po cvo (2.32)
This simple relationship between c po and cvo is important, because knowing one of them allows
the other one to be calculated. Equation (2.32) also indicates that both of the specific heats the same
functional dependence on temperature, and the c po distribution is just displaced by the amount of
respect to cvo line. Thus, the value of cvo for monatomic gases is or is 12.471 kJ/kmol K.
Sometimes it is preferred to describe the specific heats in terms of their ratio which is defined as,
k T c po / cvo . Then, together with equation (2.32), the constant pressure and the constant volume
specific heats become,
k 1
c po (T ) , cvo (T ) (2.33)
k 1 k 1
The integration of equations (2.29) and (2.30) for a specified temperature interval results as,
T2
h(T2 ) h(T1 ) c po (T )dT
T1
(2.34)
CHAPTER 2 THERMODYNAMIC PROPERTIES OF SYSTEMS 53
T2
u (T2 ) u (T1 ) cvo (T )dT
T1
(2.35)
These equations respectively provide the change of enthalpy and internal energy of ideal gases, and
they are valid for all processes regardless of its path. Besides, through the use of enthalpy definition,
Eq. (2.2), the enthalpy and the internal energy changes for ideal gases may be interrelated as,
h u T (2.36)
Evaluation of h or u for monatomic gases is a straight forward procedure, because c po and cvo
are constants, and can be set outside of integration sign. Thus for monatomic gases,
T2
h c po dT c po T
T1
(2.37)
T2
u cvo dT cvo T
T1
(2.38)
For other types of ideal gases, we need equations for describing in terms of temperature. These
equations are generally in the form of polynomials with undetermined coefficients.
Depending upon the type of a gas, the coefficients may be evaluated by curve fitting to the ex-
perimental data. For a number of gases used in industrial processes, the numerical values of these
coefficients are provided in Table A22. Substituting the coefficients of Table A22 into equation (2.39)
and evaluating it for a particular temperature yield the variation of with respect to temperature. Such
a variation for some common gases is tabulated in Table A23.
In determining the enthalpy change of an ideal gas, after substituting equation (2.39) into (2.34),
the integration has to be carried out. The calculations, especially for repetitive cases, become lengthy
and tiresome. However, a close observation of Figure 2.25 indicates that the specific heat of gases
with single atomic structure is not a function of temperature at all. For di-atomic atomic gases, due
to low slope of c po distribution, it is convenient to use the arithmetic average, c po ,av , evaluated for
the given temperature interval as,
c po (T1 ) c po (T2 )
c po ,av (2.40)
2
Such an approximation especially yields negligible errors when the temperature interval is rela-
tively small, say a few hundreds of Kelvin. If the molecular structure contains more than two atoms
and if the range of integration is greater than a few hundreds of Kelvin, then the integration given in
Eq. (2.34) has to be carried out with temperature dependent specific heat.
A further rough approximation method is that the specific heat at the initial state might be used
as the average value. This method is especially appropriate when the value of the final temperature
is yet unknown.
As a consequence, for gases, the evaluation of h and u may be carried out by one of the fol-
lowing four methods. These methods are in the order of decreasing accuracy.
1. Use tables based on experimental data. This method may require interpolation of data.
2. Use of predetermined equation for c po , and carry out the integration of enthalpy expression
for the specified temperature interval. Specifying the gas temperature, such integration results
are given for air and for carbon dioxide in Tables A24 and A25 respectively.
3. Use an arithmetically averaged specific heat for the specified temperature interval.
4. Use the specific heat at the initial state and assume it to be constant.
Example 2.14: Evaluate the specific enthalpy change of carbon dioxide that is heated from 50°C to 250°C at a pressure
of 1 bar by use of a. tables, b. the specific heat equation, c. the averaged specific heat, d. the specific heat at the initial
temperature.
Solution:
a. From Table A11, at T1 = 50°C, h1 = 417.9 kJ/kg, and T2 = 250°C, h2 = 609.4 kJ/kg, ∆h = h2-h1, ∆h = 191.5 kJ/kg.
b. From Table A22, the coefficients of specific heat equation (Eq. (2.39)) for carbon dioxide, a0 = 2.401, a1 = 8.735x10-3,
a2 = -6.607x10-6, a3 = 2.002x10-9, a4 = 0, and
As can be deduced from these results, the largest error has done by the last method. However, this method still yields
reasonably accurate results if the temperature interval is kept less than a few hundreds of Kelvin.
References
1. R.E. Sonntag, C. Borgnakke, and G.J. Van Wylen, Fundamentals of Thermodynamics, 6th edition, Wiley Publications,
ISBN 0-471-15232-3, 2003.
2. J. H. Gross, Mass Spectrometry, 2nd edition, Springer-Verlag, ISBN 978-3-642-10709-2, 2011.
3. T. Al-Shemmeri, Engineering Thermodynamics, Ventus Publishing ApS, ISBN 978-87-7681-670-4, 2010.
4. M.J. Moran, H.N. Shapiro, D.D. Boettner, and M.B. Bailey, Fundamentals of Engineering Thermodynamics, 7th edition,
John Wiley and Sons, ISBN 13-978-0470-49590-2, 2011.
5. Y.A. Chang and W.A. Oates, Materials Thermodynamics, John Wiley and Sons, ISBN 978-0-470-48414-2, 2010.
CHAPTER 2 THERMODYNAMIC PROPERTIES OF SYSTEMS 55
Problems
Table readings
2.1 Complete the following table for water substance:
2.3 Determine the required data for water for the fol-
lowing specified conditions: e. the temperature and the internal energy at 1 MPa
a. the pressure and the specific enthalpy of saturated and an enthalpy of 3565.6 kJ/kg,
liquid at 25°C, f. the quality and the specific volume at 0.7 bar,
and an internal energy of 1850 kJ/kg,
b. the temperature and the specific volume of
g. the internal energy and the specific volume at
saturated vapor at 6 bar,
300°C and an enthalpy of 2500 kJ/kg,
c. the specific volume and internal energy at 0.5
h. the pressure and enthalpy at 440°C and an internal
bar and 200°C, energy of 2930 kJ/kg,
d. the specific volume and the enthalpy at 10 bars i. the temperature and the specific volume at 6
and quality of 70 percent, MPa, and an enthalpy of 292.98 kJ/kg.
56 THERMODYNAMICS
Applications of table reading as a saturated vapor. Show the path of the process
on a p-v diagram, and determine the change of the
2.4 Consider 2 kg of water at its triple point. The volume
following properties between the initial and the
of liquid phase is equal to that of solid phase, and the
final states: a. the specific enthalpy, b. the specific
volume of the vapor phase is 104 times that of the
volume.
liquid phase. Determine the mass of water in each
phase.
2.9 A piston-cylinder device initially contains carbon
dioxide at 1 MPa, and 25°C, and occupies a volume
2.5 A storage vessel has a volume of 50 Liters and
of 50 L. The fluid is compressed to 10 MPa, and
contains a mixture of liquid and vapor nitrogen at
1 L. Determine the final temperature and enthalpy
1 bar pressure. Due to poor insulation around the
change of carbon dioxide.
tank, heat is transferred from the surroundings at
20 °C, and the content of the vessel passes through
its critical state. Determine,
2.10 A rigid vessel is charged with carbon dioxide at 20°C.
a. the amount of nitrogen in the vessel, If the initial charge contains the correct proportions
b. the initial proportions by volume of liquid and of liquid and vapor, the carbon dioxide will pass
vapor nitrogen in the vessel. through the critical state when heated with the fill-
ing line closed. Determine the proper proportions by
volume of liquid and vapor carbon dioxide so that
2.6 Water contained in a piston-cylinder apparatus ini- the desired change of state will be produced when
tially is at 5 bar, 320°C, and occupies a volume of the mixture is heated.
0.02 m3. It is compressed at constant pressure until
it becomes a saturated vapor. Determine,
a. the mass of water, 2.11 A rigid tank containing saturated water vapor at
b. the final temperature, 200°C has a volume of 0.6 m3. Due to heat transfer
to surroundings, the temperature in the tank drops
c. the amount of enthalpy change of the fluid in
to 80°C in one hour. For the final state, determine
kilojoules.
a. the pressure in the tank,
b. the ratio of liquid mass to the mass of vapor,
c. the quality,
2.7 Complete the following table of properties of Carbon d. show the process on T-v diagram including the
Dioxide. saturation line.
2.13 Consider a system consisting of 1 kg of water vapor, 2.16 A boiling water nuclear reactor contains m kg of satu-
1 kg of liquid, and 1 kg of solid water all in thermo- rated liquid water at 250°C. In case of reactor pressure
dynamic equilibrium. The system is to experience vessel fail, a secondary containment structure has to
heat transfer until all of the mass exists as a vapor. be provided to avoid the spread of radioactive water.
Two different methods of heat transfer are to be Assuming that the space between the reactor and the
considered, one at constant volume, and the other
containment is initially at zero pressure, determine
at constant temperature. Determine,
how many times larger the secondary containment
a. the temperature, the pressure, and the volume
chamber be if the maximum design pressure is 2 bar
of the complete system at the initial state,
and the specific internal energy of water after expan-
b. the proportions by mass of liquid and vapor
sion is 1080 kJ/kg.
when all of the solid has melted for each of the
heat transfer processes,
c. the final temperature, the pressure, and the volume 2.17 The piston-cylinder apparatus shown in Figure 2.27
for each of the two heat transfer processes.
is fitted with a leak proof, frictionless piston upon
which are mounted weights of sufficient magnitude
2.14 A closed and rigid container having an internal volume that a pressure of 60 bar is required to support the
of 0.2 m3 contains 0.5 kg of steam at a pressure of piston and the weights.
0.5 bars. The system is heated quasi-statically until
the final absolute pressure is 3 bars.
a. Including the saturation line of water, show the
process on a T-v diagram,
b. Determine the initial and the final temperatures
of the container,
c. Estimate the quality of steam in the initial and
the final state.
Compressibility chart 2.21 Water at 50 bars and 40°C changes state to 150 bars
and 100°C. Determine,
a. the change in specific volume, and in specific
internal energy on the basis of compressed
liquid data,
2.18 It is claimed that below a pressure of 2 bars, steam
may be assumed to behave as an ideal gas. Consider b. the same quantities by using saturated liquid
a saturated vapor which is at a pressure of 10, 50, and data,
100 kPa respectively. Calculate the specific volume c. the percentage of error involved when the ap-
by using the ideal gas equation of state and compare proximation in b is applied.
with the tabulated values. Evaluate the percentage
of error for each pressure.
2.25 A system having an initial volume of 1 m3 is filled a. the final pressure, and volume of air in the
with steam at 25 bar and 360°C. The system is cooled reservoir,
at constant volume to 200°C. Then, by a constant b. the mercury height, ht, at the tube
temperature process, steam is compressed by heat
rejection until ending with saturated liquid water.
a. Sketch the processes on a p-v diagram relative
to the saturation line.
b. Determine the total internal energy change of
steam.
c. Estimate the constant pressure specific heat at
the initial state by using steam tables.
d. Evaluate the change in cp of steam between the
initial and the final state.
2.30 One kilogram of water at 320°C and 60 bar is con- b. If the pressure of a substance is lower
tained in an insulated cylinder and piston apparatus. than the saturation pressure for a particular tem-
Consider a process in which the water system expands perature of the substance, it is in a compressed
to atmospheric pressure (1 bar) and a final volume liquid state.
of 1 m3.
a. Considering the given information, in what c. If a fluid is at a saturated vapor state,
domain of the property surface (superheated the quality is unity.
vapor, two-phase, sub-cooled liquid) is the final
state located.
d. For an ideal gas, cvo c po R .
b. Determine the temperature and the entropy of
the system at the final state.
e. The universal gas constant expressed
as =8.314 kJ/kmol K.
2.31 The piston-cylinder apparatus shown in Figure
2.31 is separated into two compartments by a rigid
partition. The pressure of the surroundings is 1 bar, f. Specific volume and temperature are
independent properties in two-phase region.
and the piston has a mass of 1000 kg with a cross
sectional area of 0.1 m2. Both compartments contain
the same ideal gas, R=0.15 kJ/kgK, cv=0.83 kJ/kg K, g. For an ideal gas specific volume is a
with identical masses of 0.1 kg, and are initially in function of temperature only.
thermal equilibrium with its environment at 20°C.
The initial pressure of the bottom compartment is
h. At the critical point, solid, liquid, and
4bars. The partition ruptures and the pressure in two
vapor exist in equilibrium.
compartments equalize. The apparatus finally comes
into equilibrium with its environment. Determine,
a. whether the piston moves upward or downward, i. The quality of a two-phase liquid vapor
and how many meters, mixture is defined as the ratio of the mass of
b. the change in internal energy and in the enthalpy vapor to the mass of the liquid.
of the gas.
j. If the temperature of a liquid is higher
than the saturation temperature corresponding
to the pressure of the fluid, it is in a superheated
vapor state.
p. At the critical state, the saturated liquid 3. As the pressure of water increases,
and the saturated vapor specific volumes inter-
a. the boiling temperature of water increases and
cept.
the enthalpy of evaporation increases,
b. the boiling temperature of water increases and
q. The constant volume specific heat for the enthalpy of evaporation decreases,
h c. the boiling temperature of water decreases and
a substance is defined as .
T v the enthalpy of evaporation increases,
d. the boiling temperature of water decreases and
the enthalpy of evaporation decreases.
r. The compressibility factor assumes
approximately the same value for all gases at
the same reduced pressure and temperature.
4. As the pressure of steam increases,
a. the enthalpy of saturated vapor increases,
s. The specific heats of diatomic gases
are independent of temperature. b. the enthalpy of saturated vapor decreases,
c. the enthalpy of saturated vapor remains the
same,
t. The freezing temperature of water
d. the enthalpy of saturated vapor first increases
decreases as pressure increases.
then decreases.
1. The latent heat of vaporization of a substance at the 7. The volume occupied by vapor portion of 1kg of
critical point is water vapor mixture is
a. is a negative number, a. xvg, b. xvf,
b. is a positive number, c. xv d. x2vg.
c. equal to zero,
d. is a very large number.
8. The safety valve of a rigid tank containing 10 kg of
ideal gas at 250 kPa, and 38C suddenly opens, and
after evacuating 25% of the total mass and dropping
2. A 2.5 m3 of rigid vessel contains steam at 10 bar, the pressure to 200 kPa, the valve closes. The final
240°C. The mass of steam is temperature in the tank is
a. 5.3 kg, b. 4.38 kg, a. 58.8C, b. 58.5C,
c. 5.38 kg, d. 3.38 kg. c. 48.8°C, d. -58.8°C.
62 THERMODYNAMICS
9. The internal energy of saturated vapor may be evalu- 12. 5 kg of water at 1 bar, x1=0.5 is heated at constant
ated as, volume to a final state of x2=0.85. The final pressure
becomes
a. h fg pvg ,
a. 1.695 bar, b. 1.895 bar,
b. hg pvg , c. 1.795 bar, d. 1.995 bar,
c. h fg pvg ,
c. h fg 2 h fg 3 h fg1 ,
14. 10 kg of steam at 600C is contained in a 182 L of
d. h fg 3 h fg 2 h fg1 . tank. The tabulated pressure value is represented
by pt , the pressure evaluated by the van der Waals
equation of state is pvw and the pressure computed by
using the compressibility chart is pcf . The relation
11. Sublimation takes place when the pressure of a between these three pressures may be stated as
substance is a. pt pvw pcf ,
a. above the triple point,
b. pvw pcf pt ,
b. below the triple point,
c. pcf pt pvw ,
c. above the critical point,
d. below the critical point. d. pcf pt pvw .
C H
3A P T E R
3.1 Introduction
In this chapter an intensive property rate balance for mass is developed by the conserva-
tion of mass principle. The mass conservation principle, however, is not applicable to all
processes occurring in nature. In nuclear reactions such as fission or fusion related processes,
due to conversion of mass into energy or vice versa, this principle does not imply. For most
events of interest in mechanical engineering field, the mass conservation principle is strictly
appropriate, and provides means of relating time rate of change of system mass with the
mass rate entering and exiting the system.
Time rate of change of mass The net rate of mass transported into the system
(3.1)
contained within a system through the boundaries at an instant time t
63
64 THERMODYNAMICS
As shown in Figure 3.1, for a system enveloped by a control surface, the conservation of
mass principle becomes,
dm
dt
cv
m (t ) m (t )
i
i
e
e (3.2)
dm
where, = Time rate of mass accumulation within the system at an instant time t.
dt cv
m (t ) = The sum of mass rates transported into the system at an instant time t.
i
i
m (t ) = The sum of mass rates transported out of the system at an instant time t.
e
e
The analysis of flow processes begin with selecting a region or space called control volume.
Mass might enter or leave the system at several ports and the boundary or the control surface
around the system should be capable of identifying the stream lines at each port so that a precise
application of Eq. (3.2) can be achieved. For instance, the T-elbow of an ordinary shower in
Figure 3.2a serves as a mixing chamber for hot and cold water flows, and to identify clearly the
mixing phenomenon, three stream lines of the cold water (1), the hot water (2), and the mixed
outlet (3) have to be identified on a schematic for fully describing the process (see Figure 3.2b).
As in Figure 3.2c, some portions of the boundary are impermeable, but some sections permit
bulk mass flow.
CHAPTER 3 MASS ANALYSIS OF SYSTEMS 65
The continuity relation given by equation (3.2) is general in the sense that it is appropriate for open as
well as for closed systems. For closed systems, the mass is invariant with time, that is m cv 0 .
The constant mass condition, however, does not necessarily guarantee that the system is closed.
The mass of an open system may still be time invariant when the sums of mass rates entering and
exiting the system are identical. If the mass of that particular open system is constant, then there
will be no accumulation of mass within the system. The flow processes with the system mass kept
constant are called steady flow processes, and the continuity relation for such processes is:
m (t ) = m (t )
i
i
e
e (3.3)
To assure that the system is closed, the system boundary should be impermeable entirely. Thus,
substituting m i (t ) 0 , and m e (t ) 0 into equation (3.2) results with time invariant mass for closed
systems.
Example 3.1 Two identical tanks of 0.5 m3 in volume contain Hydrogen gas at states of (600 kPa, 20°C) in one and (150
kPa, 30°C) in the other tank. The valve on the line connecting the tanks is opened and tanks come into thermal equilibrium
with the environment at 15°C. Determine the final pressure in the tanks.
66 THERMODYNAMICS
Solution:
For the system in Figure 3.3, there is no flow of mass crossing the control surface. The system is closed, and undergoing process
may be considered as a constant mass process. Thus, m t1 m t2 . The system mass at t t 1 ; p1 A 600 kPa , T1 293 K ,
Example 3.2: As in Figure 3.4, 0.2 m3 of cylindrical rigid tank is subdivided into two sections equal in volume by a parti-
tion. Section A contains refrigerant 22 at 30C, 80% vapor, 20% liquid by volume, while section B is evacuated. The valve
on the line connecting the two sections is opened and the flow of vapor refrigerant is allowed until the pressures at both
sections are the same. For a final temperature of 30C, determine the change in the quality of R22.
Solution:
The initial mass of the system, m 0 m A 0 mB 0 , where mB 0 0 . Considering that VA 0.1 m3 , and V fA 0.02 m3 ,
VgA 0.08 m3 , and the saturation tables of R22 yield v f 0.0008519 m3 /kg , vg 0.01974 m3 /kg . The mass of R22,
0.02 0.08
m A (0) 27.528 kg.
0.0008519 0.01974
m Ag
Thus, the initial quality of the mixture is x1 or x1 0.147 . For a system in Figure 3.4, since the system is
m A ( 0)
closed,
V2
m 0 m A t2 mB t2 m2 , and V2 = 0.2 m3, then v2 0.00726 m3 /kg . Finally, the quality at state 2 is
m2
v2 v2 f
x2 0.339 .
v2 fg
t2 t2
m(t2 ) m(t1 )cv t m i (t )dt t1
m e (t )dt (3.4)
1
in exit
where, m m t2 m t1 cv is the mass change of the system within a time interval ∆t. In
words, equation (3.4) states that the change in the amount of mass contained within a system over
a time interval ∆t equals to the difference between the total of masses flowing into the system and
leaving the system during the same time interval ∆t.
Example 3.3. The cylindrical tank in Figure 3.5 has 0.5 m2 cross sectional area and 2 m height, and contains water vapor and
liquid mixture each of which occupies 50% of the total volume at 250C. A valve located at the bottom of the tank is opened
and liquid water is drawn off. Due to heat transfer from the surroundings, the mixture temperature is kept constant during
the discharging process. If the liquid level of the tank decreases by 200 mm, determine the amount of water drawn off.
Solution:
For the control surface in Figure 3.5, there is no mass flowing into the system. Thus, mi t 0 , and Equation (3.4) be
Vf1 Vg 1
m(t1 )
vf1 v g1
where V f 1 Vg1 0.5 m3, and with the specific volumes of saturated liquid and vapor at 250C, one may obtain
m t1 409.98 kg
For case 2, V f 2 0.5 0.2 0.5 0.4 m3, Vg 2 0.5 0.1 0.6 m3. Since the temperature is kept constant, the specific
volumes for both states are the same and, the final mass is:
68 THERMODYNAMICS
0.4 0.6
m( t 2 ) 331.97 kg . The mass of water flowing out of the tank is, me 409.98 331.97 , or
0.00125 0.0501
me 78 01 kg
Example 3.4: The container in Figure 3.6 has a volume of V (m3) and is initially empty. At time t = 0, the valve on the
connection line opens and the tank liquid of density ρ (kg/m3) flows into the container at a mass rate of m i ct . Determine
the time needed for completely filling the container.
Solution:
Considering the control surface in Figure 3.6, there is no mass flow out of the system, and equation (3.4) reduces to
t2
t*
1 *2
m(t ) ctdt , m(t * )
*
ct
2
0
Letting t1 0 and the time when the filling is completed be t2 t * , the container being empty at t1 = 0, m(0) = 0.
Hence,
Example 3.5: Modeling an automobile tire as a system with a fixed volume, air pressure in the
tire basically depends on the temperature. At a surrounding temperature of 25C, the manometric
pressure of the tire is 250 kPa. For an internal volume of 0.5 m3, determine,
a. the pressure as the tire temperature increases to 50C,
b. the amount of air to be discharged for reducing the pressure to its initial value.
Solution:
a. For ideal gas behavior of air, the initial mass is
b. Let the state of air at (350kPa, 50C) represent the state 3 of air in the tire. Then the amount of air remained be-
comes,
350 0 5
m3 m3 1 887 k
kg Finally
i ll the
h amount off di
discharged
scharged air is
is, m 1 -m
m3 , 0 159 kg.
kg
0 287 323
CHAPTER 3 MASS ANALYSIS OF SYSTEMS 69
As with the lumped analysis given by equation (3.2), the first step in the derivation of an ap-
proximate integral formula is to consider a control volume fixed in space through which mass flows.
In Figure 3.8, the system defined by its boundaries coincides with the control volume boundary at
t=t, and occupies another volume in space during a time interval t. Then the rate of change of mass
within the control volume becomes,
m(t t ) m(t ) dm d
lim
t 0 t
dt cv dt cv
dV (3.5)
m1 m2
lim
t 0 t
t
cs
V .ndA (3.6)
70 THERMODYNAMICS
where V n represents the mass flux transported into the system at time t in a manner per-
pendicular to the system boundary.
Combining equations (3.5) and (3.6), the integral form of the conservation of mass principle
becomes,
d
dt
cv
dV
cs
V .ndA
(3.7)
d
dt
cv
dV
cs
V .ndA 0
This integral has to be carried out along the boundary surface where there is a flow of mass.
Equation 3.7 is actually the application of Reynolds Transport Theorem (RTT) to the principle of
“Conservation of Mass”. In words, the Reynolds Transport Theorem is stated as,
dB dB
dt dt
sys cv
cs
b V .dA (3.8)
Where, b=B/m, is the specific property. For the case of mass balance, B=m, and b=1 and sub-
stituting these values into equation (3.8), one exactly ends up with equation (3.7). In chapter 4, the
Reynolds Transport Theorem will be applied to the energy of a system. For such a case, B=E, and
then the general form of conservation of energy principle will be obtained.
Definition: “One dimensional flow” Flow fields that are characterized by a single component of
velocity are called one-dimensional flows.
For a one-dimensional flow, instead of actual velocity distribution on the system boundary, a mean
value of velocity is used for calculating the mass flow rate. As shown in Figure 3.10, at a particular
location of the system boundary, the mean value of velocity may be determined as,
1
Vm,i
Ai Ai
VdA (3.9)
CHAPTER 3 MASS ANALYSIS OF SYSTEMS 71
For instance, the actual velocity distribution at cross section A-A is illustrated in Figure 3.11a,
and the average value of the velocity corresponding to the same mass flow rate is presented in Figure
3.11b.
72 THERMODYNAMICS
In a manner similar to Equation (3.9), the average values of thermodynamic properties of the flow
such as the pressure, the temperature of a fluid crossing the system boundary may be evaluated.
Definition: For one-dimensional flows, all intensive internal properties such as p, T, ρ, u, etc.,of the
flowing fluid at instant of time t are constant in value across the boundary of the system.
Experience reveals that the use of mean values for the intensive properties at the flow boundaries
mathematically simplifies many engineering analyses. Therefore, the inlet mass flow rate at surface
1 in Figure 3.10 is:
m 1 1V1 A1 (3.10)
where ρ1 and V1 respectively represent the mean values of density and the velocity of the fluid
crossing the boundary. These values are evaluated at the boundary conditions. Similarly, the mass
flow rate at the outlet in Figure 3.10 is:
m 2 2V2 A2 (3.11)
For systems with single inlet and outlet and having one-dimensional flow, substitution of Equation
(3.10) and (3.11) into equation (3.7) results as,
dm
dt 1V1 A1 2V2 A2 (3.12)
cv
dm
At steady-state flow conditions, the term is zero, and ρVA evaluated at any cross-section
dt cv
will be independent of time and location. Thus, for one-dimensional and steady state flows, the con-
servation of mass principle is simplified to
d dV dA
0 (3.14)
V A
The incompressible fluid model is a model of such fluids for which the density does not vary with
D
time and location. For incompressible fluids, 0 and hence, for incompressible, one-dimensional,
Dt
and steady flows the continuity equation reduces to
V VA Constant (3.15)
Solution:
Due to steady flow process, there is no flow accumulation in the system of Figure 3.12. Thus,
p
For ideal gas behavior of air, the densities at each port may be calculated by . Substitu-
RT
tion of the determined densities and volume flow rates into the above relation yields the exit flow
rate as V3 8.653 m3 /min . Considering the definition of volumetric flow rate, the velocity of air at
the exchanger exit is:
V3 8.653
V3 , V3 0.288 m / s
A3 60 x 0.5
Example 3.7: As shown in Figure 3.13, a rigid bottle 0.2 m2 in cross sectional area contains saturated liquid and
vapor mixture of R22 at +5C. As the valve is opened, the saturated vapor flows through a heat exchanger and exits the
exchanger at 500kPa in pressure, 50C in temperature. Meanwhile the temperature in the bottle is kept constant by heat
transfer from the surroundings. It is observed that the liquid level in the bottle drops by 100mm in 30 minutes time dura-
tion of the discharging process. Determine the discharge velocity of the refrigerant for a cross sectional area of 0.01m2
at the exchanger exit.
Solution:
For a control surface in Figure 3.13, the continuity equation requires that
1 1
m(t2 ) m(0)cv V ( )
vg v f
where V Ab L , and vg 0.0395 m3 /kg , v f 0.0007889 m3 /kg , and V 0.02 m3. Thus,
From property tables, v2 0.0586 m3 /kg at the exchanger exit where p2 500 kPa , T2 50o C . In addition, sub-
V2 0.01 1800
stitution of t2 1800 seconds, and A2 0.01 m 2 into the continuity equation yields, 24.846 and the
0.0586
discharge velocity becomes, V2 0 08 m/s .
Example 3.8: As shown in Figure 3.14, refrigerant 22 enters a compressor at a state of 200kPa, 40C with a
mass flow rate of 0.1kg/s. For refrigerant entrance velocity of 6 m/s, determine the inlet pipe diameter of the
compressor.
Solution:
Applying the continuity relationship of one-dimensional flow to the
AV
inlet of the compressor results as, m
v
4 mv
d
V
4 0.1 0.1467
d= , or d 55.8 mm .
6
Example 3.9: As shown in Figure 3.15, air is uniformly distributed into a system by a pipe of 1m in diameter and 5 m in
length. The pipe contains 30 holes of each 3 cm in diameter. The gage pressure in the pipe is 80 kPa, and the outside pres-
sure is atmospheric. The volume flow rate through the holes is estimated by V 0.67 Ah (2p / )0.5 , where Ah(m2), is the
hole cross sectional area, ρ (kg/m3), is the air density, and ∆p (Pa), represents the pressure drop through the hole. If air is at
a temperature of 27oC, determine the velocity of air at the entrance to the distribution pipe.
CHAPTER 3 MASS ANALYSIS OF SYSTEMS 75
Solution:
p 180
For ideal gas behavior of air, the density of air in the pipe is: , 2.09 kg/m3
RT 0.287 300
3.14 0.032
Ah 30 0.0211 m 2 , V 0.67 0.0211 (2 80000 / 2.09)0.5 3.911 m3/s
4
3.911
On the other hand, V ApV , and Ap 0.785m 2 , V or V 4.98 m/s.
0.785
Example 3.10: A horizontal water storage tank of 4m long and 2m in diameter, as shown in Figure 3.16, initially contains
water at a depth 0.5m. The tank has to be emptied by a 5cm diameter discharge hole located at the bottom of the tank.
Since the velocity through the hole is determined as V 2 gh where h (m) is the water depth, and g (m/s2) represents the
gravitational acceleration. Estimate the time required to empty the tank.
Solution:
D2 1
With respect to the geometry in Figure 3.16, the cross sectional area of water is, A sin 2 and the volume oc-
4 2
LD 2 1 2
cupied is V sin 2 , the change in volume for change in time t is: dV LD 1 Cos 2 d VAp dt . Since
4 2 4
d2
V 2 gh and h R (1 Cos ), Ap substituting these values into the differential volume and simplifying results as,
4
2 LD 2 Sin 2 d
dt 2
. Integration and substituting the numerical values yield, t 608.19 s or t=10.13 minutes.
d gD (1 Cos )
76 THERMODYNAMICS
Example 3.11: Saturated water vapor at p=100 kPa flows steadily through a porous plate as shown in Figure 3.17. The
vapor is sucked constantly at the plate surface with velocity of 0.1 mm/s. The velocity profile at section CD is given as
3
u y y 2
3 2 . For a plate width of 1m, evaluate the mass flow rate through section AD.
uo
Solution:
For the specified problem, U o 2.5 m/s , V 0.0001 m/s , b 1 m , L 4 m , 0.002 m , and by Table A1, =0.598kg/m3,
1
(3 2
1.5
The mass flow across CD: m CD b udy b U o )d where = y/, or m CD 0.00209 kg/s
0 0
The mass flow across BC: m BC VA 0.598 0.0001 4 1 0.000239 kg/s
The mass flow across AB: m AB 0.598 2.5 0.002 1 0.00299 kg/s
The mass flow across AD: m AD m AB (m CD m BC ) 0.00299 (0.00209 0.000239) or m AD 0.000661 kg/s
Example 3.12: An air conditioning unit receives outside air-water vapor mixture at 35°C, 100kPa with vapor to air mass
ratio of 0.029. This mixture is cooled to 20°C and the vapor-air mass ratio becomes 0.015 at the same pressure. The volume
flow rate of the mixture and the specific volume at the exit conditions respectively are 0.1 m3/s and 0.85 m3per kilogram of
dry air. For one-hour of process time, determine the mass of condensate.
Solution:
a1 m
For a unit in Figure 3.18 operating at steady state conditions, the mass balance is satisfied by m v1 m
a2 m
v2 m
l2
where m a1 m
a represents dry air mass flow rate and is constant in the process, m l2 m
a 2 . Then, m v1 m
v 2 . Let the mass
ratio of vapor to air be represented by m v / m a , then the mass rate of condensate becomes
l2 m
m a ( 1 2 ) .
V2 0.1
The mass flow rate of dry air, m a , m a 0.1176 kg/s and m liq 2 0.1176 (0.029 0.015) 1.64 103
v2 0.85
kg/s. The amount of mass condensed in one-hour is, mliq 2 m liq 2 t or, mliq 2 5.92 kg .
CHAPTER 3 MASS ANALYSIS OF SYSTEMS 77
In Figure 3.19, structurally two different tubes, Prandtl and Brabbee, are given and the accuracy
of the measurement is found to depend on the shape of the tip. In accord with the measured height,
h, the velocity of the fluid near the tip is,
V C 2 gh( m / 1) (3.16)
Where “C” is the velocity coefficient and has to be determined by calibrating the Pitot tube. For
gas flows, assuming ideal gas behavior, the velocity at a particular point is calculated as,
78 THERMODYNAMICS
2kRT p
V1 C 1
o 1 (3.17)
k 1 p1
Where, po, is the stagnation pressure, and p1, T1 are the pressure and the temperature at a particular
point for which the velocity to be determined.
Example 3.13: The velocity of air in a duct is measured to be 40.1 m/s. The same velocity is measured by a pitot tube and the
recorded pressure is 0.12 m of water column. Take the density of air as 1.2 kg/m3, and calculate the velocity coefficient, C.
Solution:
V 40.1
Applying Eq. (3.16), C , or C , C 0.905
2 gh( m / 1) 2 9.81 0.12 (1000 / 1.2 1)
3.5.2 The Vane Anemometer. As shown in Figure 3.20, the drag force that is caused by the moving
stream on the vanes tends to rotate the vane. As the intensity of the drag force increases due to increase
in air velocity, the rotational speed of the vane anemometer also increases. The vane anemometers
are used to measure air velocity in large flow fields.
The calibration of these anemometers is done by measuring the vane rotational speed at pre-deter-
mined wind velocities. Hence for a particular rotational speed there is a corresponding air velocity.
3.5.3 The hot wire anemometer. Electrically heated thin platinum wire (1mm long and 0.005mm in
diameter) is placed perpendicular into a flow field as in Figure 3.21. The heat transfer rate from the
hot wire anemometry (HWA) to the fluid stream is mainly by convection (see section 4.4).
CHAPTER 3 MASS ANALYSIS OF SYSTEMS 79
If the wire current is kept constant, the wire reaches an equilibrium temperature, Tw, and the fol-
lowing relation holds between the power input to the wire and the temperature difference between
the wire and the fluid, Tw To , as,
I 2R
A B V (3.18)
Tw To
where, R is the resistance of the wire, I, represents the instantaneous current through the wire, ρ
and V are respectively the density and the velocity of the free stream. The constants A and B in Eq.
(3.18) are to be determined by the calibration curve of the probe. The hot wire anemometry is well
suited for measuring velocity fluctuations in turbulent flow. HWA may record velocity fluctuations
with a frequency up to 105Hz, and velocities as small as 0.02m/s. HWA being sensitive to low velocity
flows, it is also used in boundary layer analysis.
Example 3.14: The velocity data of air (ρ = 1.2kg/m3) flowing through a 24 cm pipe are recorded by a HWA and tabulated by
the following table. Determine the mean velocity, the ratio of maximum to mean velocity, and the mass flow rate of air.
Solution:
0 9.7 7 6.8
The velocity at each strip is the average of bottom and the top velocities. Hence the mean velocity is Vm=4.71m/s,
Vmax=9.7m/s,
Vm m =0.2554 kg/s.
max 2.05 and m AVm 1.2 0.0452 4.71 ,
Vm
3.5.4 Laser Doppler Anemometer. In hot wire anemometer applications, dirt in the flow might be
deposited on the wire resulting with an insulation effect, or due to high temperature of the wire, fluid
might be decomposed in the measurement region. Moreover, due to finite size of the probe, the flow
will be disturbed. If these drawbacks become dominant at a particular application then Laser Doppler
Anemometer (LDA) is used and is actually the ideal instrument for non-intrusive measurement of
velocity and turbulence in gas and liquid flows.
As shown in Figure 3.22, a laser of fixed wave length serves as a source of light and optical
components split the laser beam into a reference beam and a secondary beam that intersect at the
measurement particle.
The frequency of light scattered by a moving particle shifts by an amount that is proportional to
the speed of the particle. LDA uses this principle in measuring the velocity of a particle. Both the
80 THERMODYNAMICS
frequency shifted and the unshifted beams are collected at the photo-detector. At the output, a fre-
quency tracking filter locks onto the modulation frequency to get the Doppler frequency. The Doppler
frequency is linearly related to the velocity through the optical system geometry.
This method needs particles for measurements. The particles must be small enough to follow the
flow. In liquid flows such particles are naturally present, but in gas flows, particles 10-6 m in size are
seeded. To transfer the light beam, the fluid medium must be transparent. LDA applications include
pipe flows, flow inside engine cylinders, flow between pump impeller blades, and combustion pro-
cesses.
2p
V CA2 (3.19)
1 4
where, ρ, is the fluid density, and β = D2/D1, for Venturi meters; 0.25 0.50 . “C” represents
the discharge coefficient and varies in the range between 0.935 and 0.988.
The upstream section converges with an angle of 21o from the pipe axis, and the diverging section
has an angle of 5o to 7o. In connecting the Venturi meter to a pipeline, a distance of 10D1 straight pipe
section upstream of the Venturi is required. The overall loss in a Venturi is in between 10% to 20%
of the total pressure drop.
Example 3.15: A venturi meter has to be designed for measuring the water flow rate through a 300 cm diameter horizontal
pipe. The estimated discharge through the pipe is 15 m3/s, and the pressure drop at the venturi is limited to 250 kPa. Calculate
the throat diameter of the venturi. Take the discharge coefficient as 0.95.
Solution:
2 25000
0.95
1 4 1000
Referring to Eq. (3.19), the relation between β and A2 is, 1.416
A2 15
Substituting, D 2 / 4 , for A2 and then rearranging the above relation yields, D2 0.948(1 4 )0.25 . This equation is solved
for D2 by trial and error method. Assume =0.35, find D2, D2=0.944 m, and β=0.314, then finally venture throat diameter
is D2=0.945 m.
b. Flow Nozzles. Flow nozzles operate on the same principle as Venturi meters. As shown in Figure
3.24, there is upstream converging section, but there is no downstream diverging section to reduce the
energy loss of the flow. Therefore, the head loss tends to be much higher than Venturi meter.
The upstream pressure is measured at a distance between 0.5D1 and D1. The downstream pres-
sure measured at the outlet of the nozzle. Equation (3.19) is used to estimate the flow rate through
the duct. The discharge coefficient, C, in this equation, however, varies in the range of 0.7 and 0.9
for nozzles.
c.Orifice Meters. As shown in Figure 3.25, an orifice meter is a thin plate with an opening at the
center. The orifice opening is usually circular. The sudden area of contraction in these instruments
leads to a higher pressure loss compared to other two. The upstream and downstream pressures are
measured respectively at a distance of D1 and 0.5D1 from the plate.
82 THERMODYNAMICS
With respect to flow pressure drop, the measured flow rate through the orifice plate is expressed as,
Example 3.16: A 30cm diameter pipe carries oil, (ρ = 880kg/m3, μ=0.799kg/ms), and to measure the flow rate an orifice of 15cm
diameter is fitted to the pipe. A mercury manometer reads the pressure drop across the orifice as 0.95m. Find the oil flow rate.
Solution:
D2/D1=0.5, and assume high Reynolds number flow. Then, by Fig. (3.26), K=0.62, ∆p = ρmgh = 13.6x9.81x0.95=126.745 kPa.
2 126745
A2=3.14x0.152/4, A2=0.0176m2. Substitute these values into Eq. (3.20), V 0.62 0.0176 0.185 m3/s
880
The Reynolds number condition should be checked. A1 0.07 m 2 , V 0.185 / 0.07 2.645 m/s , and
Re 880 2.645 0.3 / 0.799 874 . Respect to Fig. (3.26), K 0.72 , and the corrected flow rate becomes, V 0.214 m3/s.
Figure 3.26 Variation of K coefficient with respect to orifice plate size and
the flow Reynolds number
CHAPTER 3 MASS ANALYSIS OF SYSTEMS 83
3.6.2 Rotameters. As shown in Figure 3.27, this instrument has a tapered glass tube, and a stainless
steel float moving freely inside the tube. As the fluid flows through the instrument, the forces acting
on the float establishes an equilibrium state for which the float assumes a position inside the tube.
The instrument must be installed vertically, and essentially the float motion is linear with the flow
rate. Rotameters are not suitable for very high pressures and for liquids with large number of particles
in it. Having an uncertainty of 5% of the full scale, the accuracy of a rotameter is less than that Venturi
or Orifice meters. The advantage of rotameters over the other obstruction meters is that the flow rate
capacity may be easily changed by changing the float shape or the glass tube.
Example 3.17: A rotameter is calibrated for water, ρ=998 kg/m3, at standard conditions (p=1atm, T=20oC). However, the
rotameter is used to measure the flow rate of oil (ρ=880 kg/m3) and the scale on the rotameter indicates 12 L/s. Determine
the actual flow rate of oil.
Solution:
The flow rate through the rotameter is V AV , where A is the flow area between the tapered tube and the float. Hence
the flow rate ratio becomes, Vo / Vw Vo / Vw . The aerodynamic suspension of float is obtained by the same pressure drop
across the float, pw po . Considering that the pressure drop is proportional with the square of velocity, wVw2 oVo2
, Vo / Vw w / o ,
References
1. M. E. Gurtin, E. Fried, and L. Anand, The Mechanics and Thermodynamics of Continua, Cambridge University Press,
ISBN 978-0-521-40598-0, 2009.
2. R. B. Bird, W. E. Steward, and E. N. Lightfoot, Transport Phenomena, 2nd Edition, John Wiley & Sons, ISBN 978-0-
471-41077-5, 2001.
3. Roger C. Baker, Flow Measurement Handbook, Cambridge University Press, ISBN 978-0-521-48010-9, 2000.
4. L. Theodore, F. Ricci, and T. Van Vliet, Thermodynamics for Practicing Engineer, John Wiley & Sons, ISBN 978-0-
470-44468-9, 2009.
5. R. P. King, Introduction to Practical Fluid Flow, Butterworth-Heinemann, ISBN 07506-4885-6, 2002.
6. R.S. Brodkey, and H. C. Hershey, Transport Phenomena – A unified Approach, McGrawHill Inc., ISBN 0-07-007963-3,
1988.
84 THERMODYNAMICS
Problems
Mass change of a system 3.7 A boiler feed pump delivers 20 kg/s of water at
250°C, and 50 bars.Determine the volume flow rate
3.1 A 1 m3 tank containing superheated steam at 500 kPa, of flow in m3/s.
200°C is connected to another tank containing 5 kg of
steam at 150°C, 200 kPa. Opening the valve on the 3.8 A cylindrical tank of diameter d0 closed at the bottom
connection line, the entire system is allowed to reach is partially filled with an incompressible fluid. As
an equilibrium temperature of 160°C. Determine, shown in Figure 3.28, a cylindrical rod of diameter
a. the volume of the second tank, di is lowered into the liquid at a velocity of V0. Ex-
b. the final equilibrium pressure. press the velocity V of the liquid escaping through
the clearance between the tank and the rod in terms
of the given parameters.
3.2 A rigid tank 0.2 m3 in volume contains equal vol-
umes of liquid and vapor Refrigerant-22 at 40°C.
Additional R-22 is charged into the tank until the
final mass is 200 kg. For a final temperature of 40°C,
determine
a. the amount of mass entering the tank,
b. the final volume of the liquid.
3.11 As shown in Fig. 3.30, the parallel plates of length 2L and exits at 1bar, 50 m/s. For an area ratio of inlet
are separated by a distance of b0 at t = 0. The upper to exit A1/A2 = 3, and an inlet cross sectional area
plate moves with a constant velocity V downward of 500 cm2. Determine,
direction and the liquid filling the gap between the a. the inlet velocity,
plates is squeezed out. Assuming b<<L, show that b. the temperature and the diameter at the exit
at a particular (x, t), the average velocity in the gap conditions.
Vx
is u . 3.15 An air compressor draws air at a flow rate of 0.2 kg/s
o Vt
b
through an inlet section where the pressure and tem-
perature respectively are 0.9 bar, 20 °C. Determine the
inlet section diameter for an air velocity of 10 m/s.
Figure 3.35
3.19 For the globe valve shown in Fig. 3.36, the dis-
tance between the disc and the seat is 5 mm and
the diameter of the opening is 4 cm. If water is
flowing through the valve at a rate of 40 L/min,
find the velocity of water at the opening section
of the valve.
Figure 3.38
Unsteady flows
Figure 3.36
Figure 3.40
Figure 3.43
pressure difference across the orifice is found to be e. One-dimensional flow fields can be
30Pa. Determine the discharge coefficient of the described by a single component of velocity.
orifice meter.
f. Mean thermodynamic values at a par-
ticular cross-section are the area averages over
3.28 A pitot tube is used to measure the velocity of water
that cross-section.
in a pipeline. If the mercury manometer attached to
it indicates a reading of 8 cm, evaluate the water
velocity in the pipe for a velocity coefficient of g. For one-dimensional steady flow of an
0.92. incompressible fluid, if the flow cross-section is
constant, then the velocity remains constant.
3.29 Oil (ρ=800kg/m3) at a rate of 0.15 m3/s flows through h. The density of an incompressible fluid
a pipe of 30 cm in diameter. In calibrating a ventu- is constant with respect to time but might change
rimeter with 0.15 m throat diameter, the same flow along the flow path.
rate is measured and the mercury manometer attached
to the meter indicates 0.28 m of reading. Evaluate i. An ideal fluid is a good approximation
the discharge coefficient of the venturimeter. of real fluid if the viscosity is small.
2. Water enters a flat channel as shown in the figure 6. An incompressible and inviscid fluid with density of
with a uniform velocity of 3 m/s. For a channel 800 kg/m3 is flowing through a diverging channel
height of h the exit velocity distribution is given as as in the figure. The velocity at section 1 is
u u0 1 2 y / h . Then the velocity u0 at the exit a. 10.5 m/s
centerline is b. 11.5 m/s,
a. 4 m/s, b. 5 m/s, c. 12.5 m/s,
c. 6 m/s, d. 7 m/s. d. 13.5 m/s.
c. u 2 x 2 cy , v 3 y 2
d. u x 2 y , v 2x y
9. A tank with a square cross sectional area (a=1m) 11. The coefficient of discharge of an orifice meter is
contains water as in the figure. At side 1, water in the range of
flowing into the tank through a pipe 0.15 m in
a. 0.85 and 0.9 b. 0.7 and 0.85
diameter, and at side 2, water discharging through
a pipe of diameter 0.05 m. The rate of water level c. 0.92 and 0.98 d. 0.65 and 0.7.
is rising or falling in the tank as
a. 0.011 m/s rising 12. Which one is more accurate in measuring a flow
b. 0.021 m/s falling, rate?
c. 0.021 m/s rising, a. pitot tube b. venturimeter
d. 0.011 m/s falling. c. rotameter d. orifice meter.
Since energy is an extensive property of a system, with respect to Equation (1.5), the energy
conservation of a system may be stated as,
The term on the left hand side of the above expression represents the change in the
system energy, and the term on the right is the energy transferred across the boundaries of
the system.
91
92 THERMODYNAMICS
1
Ek(t) = mV 2(t) (4.2)
2
Where units of m, and V are kg and m/s respectively, and the kinetic energy Ek is in joules.
The potential energy is the energy stored in mass due to its position in the gravitational field with
respect to a reference position. At an instant of time t, a system of mass m elevated by a distance Z
with respect to a reference surface in a gravitational field has the following potential energy,
Where g is the gravitational constant, taking the units of m and Z in kilograms and in meters
respectively, the associated potential energy is measured in Joules.
The internal form of energy is called internal energy, and related to the mass composition of the
system. The portion of the system energy which exceeds the sum of kinetic and potential energies is
named as the internal energy. Therefore, the energies of all sort which can not be classified as kinetic
or potential energies are determined to be the internal energy of a system. In mathematical terms, the
system internal energy at an instant of time t may be defined as,
U t E t Ek t E p t
(4.4)
The following examples illustrate the meaning of internal energy more rigorously.
1. An Automobile Battery
Consider a battery situated on a table and upon closing the circuit
switch, the stationary fan starts turning.
Thus the system causes a change in its surroundings. Since the
potential and kinetic energies of the battery are zero, this change is
provided by the chemical energy consumption. Considering the defini-
tion given by equation (4.4), the stored chemical energy is the internal
energy of the battery. Figure 4.1 Stored energy in an
accumulator is internal energy
2. A compressed gas
Consider a gas compressed in a stationary piston-cylinder apparatus
for which the initial pressure is greater than the pressure of the
surroundings p po . Upon pulling the locking mechanism, the
piston rises up, and pushes the surrounding air to a certain extent.
Since the kinetic and potential energies of the system are zero, the
change in the surroundings is caused by the internal energy of the
gas. For this particular case, the internal energy is the sum of kinetic
and potential energies of all molecules comprising the gas, and for
vapor-liquid mixtures, can be calculated by equation (2.9), and for
an ideal gas, by equation (2.35). Figure 4.2 Compressed gas pos-
sesses internal energy
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 93
Figure 4.3 The stored energy of a compressed spring or an extended bar is internal energy.
1
U (t ) KX 2 (t ) (4.5)
2
Where K is the spring constant in kN/m, and X is the elongation from free length in meters.
Similarly, in extending the elastic bar of Figure 4.3b, the internal energy stored in the bar may
be determined as,
AE
U t ( L )2 (4.6)
2 L0
Where E, A, and L0 are the modules of elasticity in (kN/m2), the cross-sectional area of the bar in
(m ), and the initial length in (m) respectively.
2
As a consequence, the energy of a system at an instant of time t may be determined by the sum
of three energy terms as follows,
Energy, like pressure, volume, and temperature, is a state property of the system, and its numerical
value at an instant of time t is path independent. In other words, the way in which the system arrives
at a particular state at time t is of no concern in determining the system energy. The derivative of
equation (4.7) with respect to time yields the rate of change of system energy at an instant of time t
as follows,
E (t ) U (t ) E k (t ) E p (t ) (4.8)
94 THERMODYNAMICS
As defined in chapter 1, a system which is closed to energy transfer across the boundaries during
a change of state is an isolated system. Thus, for an isolated system, the time rate of energy accumula-
tion at an instant of time t must be zero.
U (t ) E k (t ) E p (t ) 0 (4.9)
For a change of state of an isolated system within a time interval (t1, t2), the integration of equa-
tion (4.9) yields,
U (t2 ) U (t1 ) Ek (t2 ) Ek (t1 ) E p (t2 ) E p (t1 ) 0 (4.10)
or,
U Ek E p 0 (4.11)
As indicated in Figure 4.4, the energy transforms from one form into another within the boundar-
ies during a change of state of an isolated system. A pure mechanical system in which no frictional
interactions occur is a special form of an isolated system. The total energy of a pure mechanical system
consists of kinetic and potential energy and the sum remains constant during a change of state.
For example, if a ball thrown vertically up into the air, the ball leaves thrower’s hand with a
certain velocity, hence, with a certain kinetic energy. When the ball reaches its maximum height, its
velocity vanishes and the ball possesses only potential energy. Thus the initial kinetic energy of the
ball is transformed into gravitational potential energy.
Example 4.1: As shown in Figure 4.5, a 2 kg mass is released from rest in the position 1 and slides along the smooth and
frictionless rod. For a linear spring of K = 400 N/m, having a free length x0 = 50 cm, determine the velocity when the mass
strikes the support at 2.
Solution:
The mass-spring system sliding on a frictionless rod can be considered as an isolated system, and the internal energy change
is due to the elongation of the spring.
1 1
U K ( x12 x22 ) 400 0.36 0.715 71 Joules
2 2
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 95
Solution:
Considering the tank and its constituents as an isolated system, because of no change in kinetic and in potential energies,
equation (4.11) reduces to,
U n U m 0
where Um is the internal energy change of the machine part and calculated as,
For nitrogen, U n mn x2 x1 u fg, since ufg = 176.9 kJ/kg, then the difference in quality becomes,
U m 445.4
x2 x1 0.839
mnu fg 3 176.9
At the final state, nitrogen is in a state of saturated vapor, x2 = 1.0, and by using the above result, x1 = 1 – 0.839 = 0.161.
Thus, at the initial state, 83.9 % of nitrogen by mass must be at liquid state.
Solution:
Considering the system boundary in Figure 4.6, the system composed of
the rigid tank and the glass-flask is an isolated system, and E(t2) = E(t1). Be-
cause of zero change in kinetic and potential energy terms, equation (4.11)
reduces to U2 = U1. From saturated steam tables, the internal energy of water
at 150°C, u1 = 681.68 kJ/kg, the specific volume v1 = 0.00109 m3/kg, and the
V
mass of water becomes, m 1 0.917 kg. The specific volume at state 2,
v1
V
v2 2 0.0218 m3/kg, and because of constant internal energy u2 = u1 = 631.68 kJ/kg.
m
Due to expansion of water to a higher volume, the final pressure in the tank will be less than 7 bars. Assuming liquid-vapor
mixture at the final state, the quality of the mixture may be defined in terms of the specific volume difference and the internal
energy difference as well. Considering the fact that both of these definitions must yield the same result for the quality,
v2 v2 f u2 u2 f
x2
v2 fg u2 fg
96 THERMODYNAMICS
Assuming a pressure, p2 < 7 bars, and through the use of saturated steam tables, the above relation has to be satisfied
by trial and error method. Thus the temperature at the final state becomes 135°C.
Example 4.4: As shown in Figure 4.7, an insulated cylindrical tank 0.05 m2 in cross-sectional area is subdivided into two
equal compartments by a frictionless piston. One section contains 1 kg of air at 10 bars, 200°C, and the other is evacuated.
A linear spring of 100 kN/m spring constant supports the piston at the
evacuated section and initially is at its free length. Upon releasing the
locking mechanism, the air expands and a final equilibrium state is
reached. Determine the final pressure and temperature of the air.
Solution:
The boundary in Figure 4.7 defines the system as an isolated one. The
change in kinetic and potential energy being zero, equation (4.11)
reduces to
U 2 U1 a U 2 U1 b 0
K V2 V1
p2
A2
Together with ideal gas equation of state, pV mRT , defining the constant volume specific heat as cv = R/(k-1), the
internal energy change of air may be transformed into
1 K (V2 V1 )
mcv T2 T1 p1V1 V2 .
( k 1) A2
1 (V2 V1 )2
Finally, the internal energy of spring at state 2 becomes, U 2b K .
2 A2
1 V2 V1
2
1 K (V2 V1 )
Thus, the energy conservation principle requires that K p1V1 V2 .
2 A 2 ( k 1) A2
Substituting p1 = 1000 kPa, V1 = 0.135 m3, k = 1.4, K = 100 kN/m, A = 0.05 m2, into the above relation yields,
V22 0.1575V2 0.00022 0
Solving for V2 results as V2 = 0.1448 m3. Then the final pressure of air is,
T2 = 197.7 K.
The transfer of energy into or out of a system can be performed in three different forms as follows:
a. convective transfer of energy, b. heat transfer of energy, c. work transfer of energy. The convec-
tive transfer of energy is associated with flow processes. Whenever there is a flow of mass across the
boundaries of a system, the energy contained within the mass is also transferred. A certain amount of
mass flowing in or out of a system carries its internal, kinetic, and potential energy in or out of the
system. This is called convective transfer of energy. Besides, the energy transfer may be achieved
either by heat or work transfer.
T
Heat transfer rate in conduction mode is determined by Fourier’s law as Q kA , Where,
n
T
Q (W), is the heat transfer rate, k (W/mK), the thermal conductivity of the material, (K/m), the
n
temperature gradient within the body, and, A (m2), is the cross sectional area perpendicular to the
heat flow direction. Therefore, the heat transfer rate through the brick in Fig. 4.8 can be estimated as,
T
Q kA , T T1 T2 . Hence decreasing the thickness, and increasing the cross sectional area,
L
or the thermal conductivity of the material will increases the heat transfer rate. The thermal conduc-
tivity being a function of temperature plays an important role in conduction heat transfer and is a
property of the material. In Table 4.1, experimentally determined thermal conductivities of various
substances are given.
98 THERMODYNAMICS
Example 4.5: As shown in Fig. 4.8b water heater is covered up with an insulation layer over a total surface area of 2.5 m2.
The inside and the outside surface temperatures of the layer are 82°C and 20°C respectively. For glass wool insulation,
determine the thickness if the heat loss is limited to 250 W.
Solution:
Assuming that the thermal conductivity of the insulation material has not changed appreciably with temperature, then we may
T 62
use Table 4.1. For glass wool, = 0.038W/mK, and the thickness of the insulation is L kA , or L 0.038 x 2.5 ,
q 250
L = 23 mm
The overall effect of convective heat transfer is expressed by Newton’s cooling law as, Q hA(Ts T ) ,
Where, Q , (W), is the heat transfer rate, A (m2), the heat transfer surface area, Ts, and T∞ are the surface
and fluid temperatures respectively, and, h (W/m2K), is the heat transfer coefficient.
Depending upon the nature of the fluid flow, two types of convection occur. If the motion of the
fluid is due to some external means such as a fan, a pump, or a blower, then this type of flow is called
forced convection. If the flow is induced by buoyancy effects caused by the density differences, then
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 99
the flow is called natural convection or free convection. Fig. 4.11a shows the forced convective cool-
ing of a circuit board by a fan, and Fig.4.11b illustrates the cooling of hot circuit components in still
air. Since the hot air on the board surface is lighter than the surrounding air, it moves upward and the
space left behind is filled by cold air and hence free convection of air will be created. The approximate
values of heat transfer coefficients for different modes of convection are provided in Table 4.2.
Table 4.2 Values of convection heat transfer coefficients (h W/m2K) for various convection modes
Natural convection, Condensation of water
Forced convection Boiling of water
∆T = 30°C vapor at 100kpa
Vertical plate in air Air flow over a square plate, V Vertical (plates and tubes)
L = 300mm, = 2 m/s, L = 200 mm surfaces
4.5 12 Boiling in a pool or a 4000-11500
container Lower values are for
Horizontal cylinder in air, Air flow over a square plate, laminar and upper values
2500-35000
D = 50mm V=35m/s, L=750mm Lower values are used are for turbulent film
6.5 75 for film boiling and condensation
Air at p = 200kpa flowing in upper values are for
Horizontal cylinder in nucleate pool boiling
a tube, V = 10m/s,
water, D = 20mm
D = 25mm
890
65
Example 4.6: As shown in Fig. 4.11, annealed steel plates (L = 0.75m) suspended vertically and are at a temperature of
350°C. The plates have to be cooled by air flowing at a speed of 35m/s. If air is at a temperature, To = 25°C. Determine the
initial rate of heat transfer from a single plate.
Solution:
As indicated in Fig.4.11, the heat loss through the surfaces of plates is
due to solely by convection. If we assume that Vc/Va1 then the heat
transfer coefficient of the surface becomes h = 75W/m2K (Table 4.2). The
heat transfer surface is the both sides of the plate, A 2 x (0.75 x 0.75) 1.125
m 2 , and Ts 350 C , To 25 C , then Q 75 x1.125 x (350 25) or
o o
Q 27421.875 W
Solution:
Since the pipe is surrounded by air, due to temperature difference between the pipe surface and air, heat transfer by natural
convection will take place around the horizontal cylinder. Respect to the values of heat transfer coefficients given in Table
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 101
4.2, the value of h may be taken as h 7.0 W/m2K. The reason that the present heat transfer coefficient will be larger than
the listed values in Table 4.2 is due to larger temperature difference and larger pipe diameter. The heat loss by convection,
Q c hA(Ts To ) or Q c 7 2.512 (77 27 ) , Q c 879.2 Watts.
350 310
The heat loss by radiation on the other hand is, Q r 1 A1 (T1 T24 ) or Q r 0.7 x 2.512 x55.668(
4
)4 ( )4 ,
100 100
.
Q r 575.177 Watts. The total heat loss from the pipe becomes Q = 1454.377 Watts.
Even though the surface temperature of the pipe is not very high, the heat loss due to radiation is not negligible and
almost 40 % of the total loss comes from radiation.
As explained above, in all modes, the essential property which causes transfer of heat is the tem-
perature difference, and the transfer process terminates when the equality of temperatures is attained.
Unlike system energy, heat is not a property. For instance, one may not state that a system possesses
10 kiloJoules of heat. The amount transferred depends upon the initial and the final states of interact-
ing systems as well as the path followed. In other words, the way of interaction alters the amount of
heat transferred.
The differential quantity of heat during a process connecting two adjacent states is denoted as Q
and the integration between two end states is:
Q Q
1
12 (4.13)
The symbol indicates that small quantity of heat is path dependent, and integration may not be
carried out without knowledge of the process. By way of sign convention heat added to a system is
taken to be positive, and the heat loss is indicated by a negative sign.
Definition: If the boundaries of a system prevents heat transfer during a change of state, then the
0.
system is called adiabatic, and for the undergoing process, Q
A process taking place in a well insulated container can be considered adiabatic. Similarly, the ther-
modynamic process occurring in a rocket nozzle is adiabatic since the gas travels at very high velocity
and there is little time for heat transfer from the hot gas. In the opposite extreme where the time scale
of the process is considerably larger than the time to reach thermal equilibrium, the boundary can be
modeled as diathermal.
Definition: Diathermal boundary refers to a boundary across which the temperature gradient is
zero even in the presence of heat transfer. If n is the direction normal to the boundary, then for a
diathermal boundary T 0 .
n
For instance, in mechanical systems the intensive property which causes work transfer is the pressure
or stress, and in electrical systems is the voltage potential. To define the work transfer in mathematical
terms, the process must be a quasistatic one. This means that the system be very nearly in equilibrium
at all times. A process proceeding in such a way that only one property kept slightly different at an
102 THERMODYNAMICS
instant of time is called an idealized process. During such a process, the system internally will be
close to the state of equilibrium at all times.
Principle 11: Work transfer across the boundaries of a system for quasis-
tatic processes is product of an intensive property other than temperature
and the difference in an extensive property.
Therefore, the general formula of work interaction for a quasistatic process may be stated as,
X2
W Fk dX k , or W12 F dX
X1
k k (4.14)
Similar to heat transfer, the work transfer is also path dependent, and evaluation of equation (4.14)
requires the process as well as the end states to be known.
As shown in Figure 4.13a, the expansion of a gas by lifting the small masses one by one is a
quasistatic process, and the gas work can be calculated by equation (4.14). It is possible to represent
quasistatic processes on two-dimensional diagrams where the coordinates represent thermodynamic
properties.
As in Figure 4.13b, the area below the process curve represents the amount of work transfer, and
such diagrams are extremely useful in analyzing design problems. The sudden expansion process in
Figure 4.13c which occurs by pulling off the locking mechanism is non quasistatic. During the pro-
cess, the pressure of the gas may not be uniform within the cylinder and the piston may have varying
acceleration. All intermediate states are of non-equilibrium character. Even though the initial and the
final states are the same, due to unknown path in Figure 4.9d, the work done by a sudden expansion
process may not be determined by equation (4.14).
The sign convention of work is that the work done by a system is positive, and the work done
to the system is considered to be negative. Depending upon the type of work transferred across the
boundaries of a system, in equation (4.14), Fk and Xk represent different properties. Several forms of
quasistatic work transfer are discussed in the following sections.
Mechanical work 2 2
transferred by the = p(t ) AdX pdV (4.15)
moving boundary 1 1
where the term “ Adx ” is replaced by dV . The work done by the boundary movement is also called
pdV work, and a method of calculating the work is to know the p-V relationship of the process.
Suppose a gas, in a piston-cylinder arrangement, is expanded or compressed by a polytropic process
defined as pV n = Constant and the mechanical work done by the gas has to be determined for n = 0,
1, , n, and k.
For n = 0, the relation, pV n = Constant, reduces to a constant pressure process, and by equation
(4.15) the work done is:
For n = 1, the pressure and the volume relationship becomes pV = Constant. Thus, at an intermedi-
ate state, the gas pressure p is p1V1/V and substitution into equation (4.15) results in,
V p
W12 p1V1 ln 2 or W12 p1V1 ln 1 (4.17)
V1 p2
Notice that pV = Constant process of an ideal gas requires the temperature of the gas to be constant.
Then the isothermal process of an ideal gas is represented by pV = Constant. It should be emphasized,
however, that isothermal process of a real gas or a vapor does not necessarily obey this relation.
For n = , the gas undergoes a constant volume process. Since dV = 0, by equation (4.15) the
work done becomes zero.
For n = n, the gas pressure at an intermediate state is p1(V1/V)n, and equation (4.15) yields,
104 THERMODYNAMICS
p1V1 p2V2
W12 (4.18)
n 1
where n n. Together with ideal gas equation, the polytropic relation provides a relationship
between the temperatures and the pressures or volumes of the two states as follows,
n 1
T2 p V2 1 n (4.19)
( 2) n ( )
T1 p1 V1
Thus equation (4.18) may be modified and expressed in terms of pressure ratio as,
p1V1 p2 n
n 1
W12 1 ( ) (4.20)
n 1 p1
For n = k in which k represents the ratio of specific heats as c p / cv , then the process is called
reversible adiabatic and is discussed in detail in Chapter 5. Replacing n by k in equation (4.18) or in
(4.20), the work of an ideal gas done by such a process may be calculated.
In Figure 4.15, p-V diagram of the processes discussed above are supplied and the relative steep-
ness of each process is indicated.
Example 4.7: A reciprocating compressor initially contains 0.1 m3 of air at a state of 0.95 bar, and 67°C. The compression
process is quasistatic and represented by pV1.3 = Constant. The final volume is 0.02 m3. Determine the mass of air contained
in the compressor cylinder and the work of compression in kilojoules.
Solution:
Assuming ideal gas behavior for air, p1V1 = mRT1, and the amount of mass in the compressor cylinder becomes,
m= 95 0.1 , or m = 0.097 kg. With respect to relation, p V 1.3 p V 1.3 , the final pressure is
1 1 2 2
0. 287 340
1.3
0.1
p2 0.95 7.697 bars. Together with the polytropic exponent n = 1.3, substitution of the data into equa-
0.02
tion (4.18) provides the work of compression as,
Solution:
The pressure at state 1: p1 = 100kPa. The pressure at state 2:
1000 9.8 10
p2 p1 gZ 100 198 kPa
1000
p1 100
W12 p1V1 ln 100 1 ln , or W12 = –68.3 kiloJoules.
p2 198
The negative sign indicates that the work is done on the air.
Similarly, as shown in Figure 4.17, for the mass flowing out of the system, the rate of mechanical
work done by the system is:
106 THERMODYNAMICS
Thus the net rate of mechanical work of the system due to a flow process is the sum of equation
(4.21) and (4.22).
Example 4.9: Steam enters steadily into a tank as shown in Figure 4.17 at the state of 10 bars, 200°C, and flowing through
a valve at the exit, leaves the tank at a pressure of 1 bar and a temperature of 120°C. For the same mass flow rate of 0.1 kg/s
at both parts, determine the work rate of the system.,
Solution:
i m
From steam tables, vi = 0.206 m3/kg, ve = 0.1793 m3/kg, and m e 0.1 kg / s. With respect to equation (4.23), the flow
work of the system is:
Example 4.10: Due to shear stresses on the blades of a blender, the torque
for turning the blades is provided by an electric motor as shown in Figure 4.19.
Suppose that the shaft rotates at 1000rpm, and draws a power of 200 Watts from
the electric motor. Compute the torque developed by the motor.
Solution:
In equation (4.24), W shaft 200 , n = 16.67 rev/s, and the developed torque
is,
W shaft 200
T or T 1. 91 Joules
2 n 2 3.14 16.67
A
Mechanical work transferred 2
dA (4.25)
by changing surface area A1
Example 4.11: A certain balloon is constructed of a material such that the surface tension is linearly proportional to the
surface area. Initially the surface tension of the balloon is 500 N/m, and contains 0.5 kg of air at 500 kPa, 27°C temperature.
Determine the work done by doubling the surface area of the balloon.
Solution:
mRT1 0.5 0. 287 300
The initial volume of the balloon, V1 = = = 0.0861 m3 , for a spherical balloon the diameter d1 is 0.547
p1 500
m, and the surface area, A1 = 0.939 m2. Because of the relation, = CA, the constant of proportionality C is 532.48 N/m3.
An expression for may be stated as,
532.48 A
Substitution of this relation into equation (4.25) and then integrating we may get,
A
Wsurface 266.24 A12 ( 2 )2 1 ,
tension A1
Thus, whenever there is a flow of electric charge crossing a system boundary, the energy transfer
mode is work, and is calculated by equation (4.26).
e(t ) u (t ) ek (t ) e p (t ) (4.28)
and,
V 2 (t )
ek (t ) , e p (t ) gZ (t ) (4.29)
2
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 109
where V(t) indicates the mass velocity at the system boundary, and Z(t) is the altitude of inlet point
with respect to a reference plane. Thus the convective energy transferred to the system at a mass flow
rate of is:
By similar arguments, the convective energy transferred from the system at a mass flow rate of is:
As a consequence, the net rate of energy accumulation in the system due to mass inlet and outlet
may be expressed as follows,
Example 4.12: Consider the tank given in Example 4.9 where the steam steadily enters the tank at a velocity of 10 m/s,
and exits at a velocity of 1 m/s. At a height difference of 2 meters between the inlet and outlet ports, and for the same ther-
modynamic conditions determine the energy transferred to the system by convection.
Solution:
Having the same mass flow rate at both ports, the rate of energy stored in the system by convection becomes,
By using steam tables, at the inlet conditions (10 bars, 200°C), ui = 2621.9 kJ/kg, similarly at the outlet (1 bar,120°C),
ue = 2537.3kJ/kg. ui – ue = 84.6 kJ/kg.
The differences in kinetic and in potential energy terms are as follows,
1 2 1
2
Vi Ve2
2 1000
100 1 0.0495kJ / kg
1
g Z i Z e 9.8 2 0.0196 kJ / kg
1000
For m 0.1 kg/s, substituting these values into the above expression yields,
Time rate of The net rate The net rate The net rate
energy accumulation of energy of heat of work
within a system = transported into transported transferred (4.33)
at an instant the system by into the system by the system
of time t convection at time t at time t at time t
Because of the sign convention of work, a negative sign appears in front of the work transfer term.
As shown in Figure 4.21, for several inlet and outlet ports on the system, the first term on the right
hand side of equation (4.33) is given as,
convection at time t
The work transfer, the last term on the right hand side of equation (4.33), can be categorized into two:
a. work transfer due to mass flow, b. work transfer at the non-flow boundary regions.
at time t
Revising equation (4.23) for a system with several flow ports, the first term on the right hand side
of equation (4.36) becomes,
at time t
The second term in equation (4.36), on the other hand, describes a non-flow type of work trans-
fer. As in Figure 4.17, this can be either shaft work, electrical work, moving boundary work etc., or
several of them occurring simultaneously. Denoting such a work transfer symbolically as , the net
rate of work transferred by the system may be formulated as,
The net rate of
work transferred
m e ( pv ) e m i ( pv ) i W (4.38)
by the system e i
at time t
Substituting equations 4.8, 34, 35, 38 into 4.33 and recalling the definition of enthalpy (equation
(2.21)), some terms may be combined. As a result, a general energy equation for a system may be
stated a follows,
i
i e
U E k E p Q W m i h ek e p m e h ek e p
e
(4.39)
This relation is appropriate for lumped analysis of systems with mass flowing at discrete points.
For continuous nature of mass flow along the system boundary, similar to the method in section 3.4,
an integral formulation of energy can be derived as follows,
d
dt V
(u ek e p )dV (h ek e p )V ndA Q W
cs
(4.40)
Equation 4.40 is exactly the application of Reynolds Transport Theorem (RTT) to the principle of
“Conservation of Energy”. In equation (3.8), taking B E , and b e and performing the necessary
transformations for flow work, exactly the same result of Eq. (4.40) can be found.
112 THERMODYNAMICS
The first two steps of the above explained procedure are actually restatement of principle 1 and, in
deriving a solution for a problem, have a major importance. It is highly essential to draw a boundary
around the system schematic and to indicate the energy transfer forms crossing the boundary. Be-
sides, synthesis of the given information helps in solving the problem. In step 5, the aim for drawing
a process diagram is to illustrate the change of state in thermodynamic coordinates like p-V plane.
Process diagrams are especially useful for understanding of complex problems.
To exercise the solution methods of energy equation with the guidance of the above explained
steps, in addition to isolated systems, the engineering systems have been classified as closed and open
systems, and the details of applications are presented in the following sections.
U E K E P Q W (4.41)
Integrating this rate equation along the path of a process within a time interval (t1, t2) yields a
relationship between the energy change of a system and the amount of heat or work transfer.
where the change in energy components of internal, kinetic, and potential energy of a system may be
calculated as explained in section 4.2.
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 113
Example 4.13: As shown in Figure 4.22, 1 kg of air at 1 bar in pressure and 30°C in temperature is contained in a rigid
and adiabatic container. Inside the container is a propeller which connected to a shaft. Attached to the shaft is a rope which
is also attached to a mass of 50 kg that is initially held in equilibrium 2 m above the ground level by means of a supporting
plate. Pulling the supporting plate, the mass falls to the ground, turning the shaft, and air assumes a new equilibrium state.
Determine the final temperature and pressure of air.
Solution:
Consider the tank as a system, the kinetic and the potential energy change of the system are zero, and because of no transfer
of heat, Q12 = 0. Equation (4.42) reduces to
U2 – U1 = – W12 .
T2 304.39
p2 p1 1 p2 = 1.004 bar
T1 303
Example 4.14: In Figure 4.23a a laterally insulated piston-cylinder apparatus 0.5 m2 in cross sectional area contains an
ideal gas for which R = 0.5 kJ/kgK. The initial temperature of the gas is 250K and is heated by a resistor of 10 with a
potential difference across the wire being 35 V. Assume that the heater circuitry is left open for one hour, and during this
time interval, as presented in Figure 4.19b the gas pressure varies linearly with respect to piston movement. Determine a.
the heat transfer, b. the work transfer, c. the constant volume specific heat of the gas.
Solution:
a. The gas being a system, by equation (4.26), the rate of heat transfer is,
Q I 35 3.5 122.5 Watts
114 THERMODYNAMICS
400 200
W12 1 5 0.5
1.5 05 12
1 225 kJ.
2
c. With respect to equation (4.42), the internal energy change of the gas is, U = Q12-W12 = 441-225 = 216 kJ.
p1V1 400 0. 25
The mass of the gas in the cylinder, m 0.8 kg,
RT1 0.5 250
By equation (2.35), the internal energy change of the gas may be described as, 216 = 0.8 × cv × (500 – 250), and solving
for cv yields cv = 1.08 kJ/kgK.
Example 4.15: An accordion like device which consists of metal bellows as shown in Figure 4.24a can be used to measure
the strength of a man. The bellows at its free length of 30 cm, the instrument is filled with air at 1 bar and 20°C and sealed
off. The diameter of the device is constant at 5 cm, and the spring constant of the bellows is 2 kN/m. Suppose that 1 kN of
force is exerted on this system and the compression process can be either isothermal or adiabatic.
a. Determine by which process the device will be compressed more, b. Sketch p vs V of both processes on pV diagram,
c. Compute the heat transfer, the work transfer, and the change in internal energy of air. Assume that air can be
modeled as an ideal gas.
Solution:
a. For a quasistatic change of state, the gas pressure, the spring force and the applied force can be interrelated as,
KL0 X F
p ( )
A L0 A
1. Isothermal process: Because of constant cross sectional area, the relation between the gas pressure and the amount of
compression,
Lo
po Lo p Lo X , or, p po
Lo x
KL0 F
Let = X/L0, and = 306.1, = 510.2 then the force balance results with the following equation,
A A
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 115
100
306.1 510.2
1
1
p po
1 k
100
The force balance for this process results as, 306.1 510. 2 by which = 0.577 or Xa = 17.32 cm. Thus,
Xa < Xi (1 )1.4
b. p-V illustration of both processes are given in Figure 4.24b.
c. 1. Isothermal process: Due to constant temperature, the internal energy of air is zero, U = 0. The work transfer
by equation (4.17) is:
V2
W12i p1V1 ln 0.065 kJ
V1
Equation (4.42) reduces to Q12 = W12. Thus the heat transfer is, Q12i = –0.065 kJ.
2. For adiabatic process: Q12 a = 0, and in equation (4.20) taking n = k = 1.4, the adiabatic work transfer, W12a = –0.0059 kJ.
The energy balance requires that U2 – U1 = –W12a = 0.0059 kJ.
Example 4.16: As shown in Figure 4.25, a cylinder with thermally insulated walls is initially divided into two equal compart-
ments of volume V1 by a moveable, frictionless, and insulated piston. Each compartment contains m kilograms of gas which
can be modeled as an ideal gas with a constant specific heat cv, and a gas constant R. Initially the gases at both compartments
are at the same pressure p1 and temperature T1 and the value of k is 1.50. The compartment on the left contains an electrical
27
resistor and due to electrical work transfer, the final pressure of the gas becomes p2 p1 . Determine a. the heat transfer
8
and the final temperatures of gases in each compartment in terms of m, cv, and T1, b. the electrical work transfer.
Solution:
a. Because of thermal insulation, the heat transfer to both compartments is zero, .
Due to adiabatic compression of the gas in compartments B, and referring to Eq. (4.19), the final temperature may be
expressed as,
k 1
p2 3
T2 B T1 ( ) k T1
p1 2
1
p1 k 4
V2 B V1 ( ) V1
p2 9
Since the total volume of cylinder is constant at a value of 2V1, the final volume of compartment A becomes,
14
V2 A 2V1 V2 B V1
9
b. For the entire cylinder as a system, the energy balance requires that U A U B Welectrical
21 17 3 1
where, U A mcv ( T1 T1 ) mcvT1 , and U B mcv ( T1 T1 ) mcvT1 ,
4 4 2 2
19
Then the energy equation yields, Welectrical mcvT1 .
4
Example 4.17: A cylinder of fixed volume V in Figure 4.26a is divided into two compartments of volumes VA and VB by
means of rigid and diathermal wall fitted with a check-valve. The valve opens when the pressure in A exceeds the pressure
in B by 0.5 bars. A frictionless piston is fitted into compartment A and the entire system is in thermal communication with
the surroundings at 30°C. Both compartments are filled with air and initially p1A = p1B = 2 bars, V1A = V1B = 0.05 m3.
a. Determine p-V relation of air for both compartments when the piston moves inward and sketch the variation.
b. Calculate the heat transfer, the work transfer and the change in internal energy of the system for V2A = 0.5 V1A.
Solution:
a. Due to diathermal walls, the temperature of air in both compartments is the same as the surroundings. Because of
the discontinuity when the check valve opens, the problem should be analyzed in two steps.
1. For a pressure in the range, 2 pA 2.5 bars, the check valve is closed and pV relationship for compartment A is pAVA
= 10, and the volume of compartment when valve opens is V2A = 0.04m3.
2. For a pressure pA > 2.5 bars, one should consider the gas equation for the entire system as,
Substituting PB = PA – 50, VB = 0.05m3, R = 0.287 kj/kgK, mA + mB = 0.229 kg into above expression, the p-V relation-
ship for compartment A becomes,
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 117
Thus, at V2A = 0.025 m3, solving this relationship for p2A, yields, p2A = 298.8 kPa. In Figures 4.22b and c, p-V distribution
of gases in compartments A and B are respectively displayed.
b. The work transferred by the system is W13 = (W13)A + (W13)B. Because of constant volume of compartment B,
(W13)B = 0. Similar to analysis in a, the work transfer of compartment A is calculated in two steps.
1. For p A 2.5 bar, and for isothermal compression process, equation (4.17) yields,
3 0.025
dV W112 A 2.23 kJ
(W23 ) A
2
pdV 22.41
0.04
V 0.05
or
22.41
2. For p A 2.5 bar, the relation between pressure and volume is, p A and pdV type of work becomes,
V 0.05
3 0.025
dV
( 2233 ) A 4.086 kJ.
(W23 ) A pdV 22.41
V 0.05
2 0.04
Thus, the work transfer of the system is: W13 = –2.231+(–4.086) = –6.317 kJ.
Since the change in internal energy of the system is zero, the energy equation reduces to Q13 = W13 and the heat transfer
becomes,
Q13 = –6.317 kJ.
Example 4.18: Figure 4.27 represents schematically an air rifle. Air charged into the reservoir of volume V accelerates the
bullet down the barrel when the valve opens quickly. The initial pressure and temperature of air in the reservoir are 40 bars
and 77°C. Assume that the atmospheric pressure is 1 bar and the spherical bullet has a mass of 0.01 kg, and that the barrel
diameter is
Solution:
Considering the bullet and the compressed gas as a system, the kinetic energy change of the system:
1 1
Ek mbVb2 0.001 1002 0.05 kj.
2 2000
Since the final pressure is 1 bar, the final temperature of air due to adiabatic expansion is
k 1
0.285
p k 100
T2 T1 2 350 122.3 K
p1 4000
p 4000
By equation of state, the initial density of air is r 39.82 kg / m3 , then the mass of air in the rifle is,
RT 0.287 350
m rV 39.82V
118 THERMODYNAMICS
The internal energy change of air becomes, U mcv T2 T1 39.82V 0.718 122.3 350 6510.1V
1
p1 k
The final volume occupied by air, V2 V = 13.92V,
p2
The work done by pushing the surroundings by the volume change is, W12 = p0(V2-V) = 100 (13.92V – V) = 1292V
Substituting the above evaluated terms into equation (4.42), one may obtain, -6510.1V+0.05 = 0-1292V and solving
for V yields,
V = 9.58 10-6m3
The change in air volume is, V = V2 – V = 12.92V = 123.7 10-6 m3 which corresponds to the volume of the barrel,
AL = 123.7 10-6m3. Thus, for a cross sectional area of 0.785 10-4m2, the barrel length has to be
L = 1.575 m.
Where, W12 represents the work transfer at constant pressure. Thus, substituting equation (4.16)
into (4.43) and rearranging yields,
Notice that the pressure p represents the fluid pressure at any state of the process, and then p = p1 = p2.
As given by equation (2.1), using the definition of enthalpy, the above result may be expressed as,
In closed systems, the enthalpy difference represents the amount of heat transferred by a quasistatic
process at a constant pressure. In equation (4.39), on the other hand, the enthalpy term has entirely
a different meaning. There, due to a flow process, the enthalpy, signifies the sum of internal energy
and flow work of the mass which inlets or outlets the system.
Example 4.19: A long and vertical pipe encapsulated by a frictionless 2 kg piston has a cross-sectional area of 2 cm2 and
initially contains 1L of liquid water and vapor mixture of which the volumetric ratios respectively are 20% and 80%. Due to heat
leak through the walls of the device, as shown in Figure 4.28, the vapor condenses and the piston moves downward at a rate of
0.003 m/s. Assume that the atmospheric pressure is 100kPa, and determine, a. the rate of condensation, b. the rate of heat loss,
c. the distance of the piston from the base when the mixture comes into thermal equilibrium with the surroundings at 30°C.v
Solution:
a. The volume rate swept by the piston, V AV p 2 104 3 103 6 107 m3/s. The mixture pressure may be
calculated as,
mg 2 9.8
p po 100 198
A 2 104 103
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 119
From saturated steam tables, the specific volume of saturated steam at this
pressure, vg = 0.885 m3/kg, then the rate of condensation becomes,
V 6 107
g
m or g 6. 78 107 kg / s
m
vg 0.885
b. Since the condensation takes place at a constant pressure, the rate of heat
transfer, by equation (4.45), is:
Q g h fg 6. 78 107 2201. 9
m or 1. 492 Watts
Q
V2 0.00019
L2 or L2 0 95 m
A 2 104
Eventually these gases cool down in the atmosphere to the same temperature as the ambient tem-
perature. Such a sequence of processes can be considered as a cycle only if air at the original state is
supplied to the system. To illustrate the concept of thermodynamic cycle, as shown in Figure 4.30a,
consider a fluid contained in a piston-cylinder apparatus that undergoes heat interaction with two heat
120 THERMODYNAMICS
reservoirs at different temperatures. Suppose that the fluid exercises the following four processes and
regains its original state.
(1-2): Adiabatic compression to the temperature of high temperature reservoir, (2-3): The fluid at
the temperature of high temperature reservoir, isothermally heated, (3-4): Adiabatic expansion to the
temperature of low temperature reservoir, (4-1): Isothermal cooling of the gas to the initial pressure
and temperature. The cycle produced by these four processes is called the Carnot Cycle and will be
further studied in Chpt.5.
Equation (4.41) being valid for a particular state of the system in Figure 4.30b, it may be integrated
along the cycle as follows,
The initial and the final states of a cycle being identical, U E K E P dt 0 , and the energy
balance for a cycle results as,
Q W , or Q net
= Wnet (4.47)
This equation states that since the energy of a system remains unchanged as a result of cyclic pro-
cesses, an amount of energy equal to the net work output must have flowed into the system during the
cycle as the net heat input. As indicated by the shaded region in Figure 4.30b, the net work transfer,
Wnet, of a cycle equals to the area enclosed by the cycle on p-V representation and this is proved to be
true for any cycle in Example 4.20.
The performance of power cycles is measured by a parameter called thermal efficiency. The
thermal efficiency of a power cycle is the ratio of the net work output to the heat energy input and
represented by as follows,
Wnet
100% (4.48)
QH
For a power cycle, as in Figure 4.31b, interacting with two heat reservoirs, the net work output,
by equation (4.47), may be expressed as, Wnet = QH – QL. Accordingly, rearranging equation (4.48)
yields,
QL
h 1 (4.49)
QH
122 THERMODYNAMICS
The condition of QH QL always exists for power cycles. Thus, with respect to above relation, the
thermal efficiency of power cycles is always less than unity. As explained in Chapter 5, the efficiency
of a power cycle strongly depends on the temperature of the heat source. As the temperature of the heat
source is higher, the thermal efficiency is the better. Since ORC cycles are used for low temperature
heat utilization, the thermal efficiency of these cycles is rather low and is around 20-percent.
QL
br (4.50)
WC
Where QL represents the useful heat energy extracted from refrigerated space, and WC is the work
energy consumed by the compressor of the cycle. This reverse cycle is also used as a basic heat pump
cycle that extracts heat from the outside air in winter and transfers heat to the indoor air. For a heat
pump then the useful output is the heat supplied to the indoor air and represented by QH. Thus COP
of a heat pump is expressed as,
QH
hp (4.51)
WC
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 123
Example 4.20: A 1 kg of air contained in a piston-cylinder apparatus occupies an initial specific volume of 0.47 m3/kg at
250°C and executes a cycle between two heat reservoirs which are respectively at 250°C and 150°C in temperatures. As shown
in Figure 4.33, the cycle proceeds as follows, (1-2): Expanding isothermally to specific volume of 1.19 m3/kg. (2-3): Cooling
to 150°C at a constant volume. (3-4): Isothermal compression to specific volume of 0.47 m3/kg. (4-1): Heating to 250°C at
a constant volume. Show that equation (4.47) holds for this cycle and determine the thermal efficiency of the cycle.
Solution:
The net heat transfer to the system may be evaluated as, Qnet = Q41 + Q12 + Q23 + Q34
From Figure 4.33b, one may deduce that T1 = T2, T3 = T4, V1 = V4, V2 = V3, then the heat transfer for each process of
air is as follows,
V2 1.19
Q41 = U1 – U4 = mcv(T1 – T4) = 1 × 0.718(523 – 423) = 71.8 kJ, Q12 = W12 = mRT1 ln 1x0. 287 523 ln =
V1 0. 47
139.44kJ
V4 0. 47
Q23 = U3 – U2 = mcv(T3 – T2) = 1 × 0.718(423 – 523) = –71.8 kJ, Q34 = mRT3 ln 1x0. 287 423 ln =
V3 1.19
-112.78 kJ
Thus, the net amount of heat transferred through the cycle is Qnet = 71.8 + 139.44 + (-71.8) + (-112.78) = 26.66 kJ.
Similarly the net amount of work transferred by the cycle may be expressed as, Wnet = W14 + W12 + W23 + W34
Because of constant volume processes at (4-1) and (2-3), the corresponding work terms W41 and W23 are zero, in ad-
dition,
V2 1.19 V4 0. 47
W12 mRT1 ln 1x0. 287 523 ln = 139.44 kJ, W34 mRT3 ln 1x0. 287 423 ln = -112.78 kJ.
V1 0. 47 V3 1.19
Then, Wnet = 0 + 139.44 + 0 + (-112.78) = 26.66 kJ, and the equality of Qnet and Wnet is obvious from the numerical
results.
In equation (4.48), QH represents the total amount of heat transferred by the high temperature reservoir. Therefore,
QH = Q41 + Q12 = 71.8 + 139.44 = 211.24 kJ. For Wnet = 26.66 kJ/kg, the thermal efficiency of the cycle becomes,
26. 66
100 % or 12. 62 %
211. 44
Example 4.21: A heat pump supplies heat to the indoor air at 29°C by extracting 10kW of heat from the outside air at
-7°C. For a power input of 3.5kW, determine the heat supplied in one hour and COP of the heat pump.
Solution:
With respect to equation (4.47), Q H Q L WC 10 3.5 13.5 kW or 48600 kiloJoules per hour. Thus, the coefficient of
performance of the heat pump becomes,
124 THERMODYNAMICS
Q H 13.5 , or b = 3.85
b hp hp
W C 3.5
1 1
m h 2 V
e
2
gz
e
m h 2 V
i
2
gz Q W
i
(4.52)
Notice that the expression above involves mass flow rates of incoming and outgoing fluids. Therefore,
in solving equation (4.52) for a particular system, the application of the principle of mass conservation
is a necessity. The mass conservation in the form of equation (3.2) is valid for systems operating at
steady-state conditions, m i m e . In words, the sum of flow rates entering the system equals to
the sum of flow rates leaving the system.
In this section, energy analysis of certain equipment which are extremely important in engineer-
ing applications will be discussed. Considering their specific functions and the way the flowing fluid
behaves in such devices, the various forms of equation (4.52) will be considered. For instance, many
engineering systems operating under steady-state conditions have two ports, one inlet and one outlet,
and for such systems the conservation of mass and energy simplifies to
m i m e (4.53)
1 1
(h V 2 gz )e (h V 2 gz )i q w (4.54)
2 2
where q and w are respectively the heat and work transfer of the system per unit mass of fluid flowing
through the system.
Under subsonic or supersonic flow conditions, the general shapes of a nozzle or a diffuser are shown
in Figure 4.34. A nozzle for subsonic flow or a diffuser for supersonic flow must have a decreasing
cross sectional area in the flow direction as in Figure 4.34a. For supersonic flows, however, the op-
posite occurs. In Figure 4.34b, the spray atomizing nozzle, as used for humidification processes, is a
supersonic nozzle with increasing cross-sectional area in the flow direction. Besides, if a fluid has to
be accelerated from subsonic to supersonic velocity, a converging-diverging nozzle as in Figure 4.34c
must be used. In such applications, the fluid assumes the sonic flow conditions at the throat.
Since both of these devices are essentially ducts, no shaft work is involved, and for most conditions,
due to high velocity of the fluid, the heat transfer through the walls is negligible. The potential energy
change may also be neglected. Owing to single inlet and outlet, equations (4.53) and (4.54) are applicable
to such devices. With respect to these assumptions, equation (4.54) may be simplified and reduced to
Vi 2 V2
hi he e (4.55)
2 2
By rearranging this relation, the velocity of a fluid at any cross-section of a nozzle or a diffuser
may be calculated as,
Example 4.22. Steam enters a nozzle with a mass flow rate of 9kg/min at a
stagnation enthalpy of 2780 kJ/kg. At the nozzle exit, the steam
has a velocity 1070 m/s and a specific volume 18.75 m3/kg. De-
termine, at the nozzle exit, a. the enthalpy of the steam, b. the
cross-sectional area of the nozzle.
126 THERMODYNAMICS
Solution:
a. A stagnation enthalpy of a fluid is defined as the sum of the enthalpy and the kinetic energy and represented by
h .Thus,
V12
h1 h1 = 2780 kJ/kg
2
V22 10702
and according to equation (4.55), h2 h1 2780 , or h2 = 2207.5 kJ/kg.
2 2000
b. For one dimensional flow, considering the continuity relation as in the form of equation (3.10), the cross-sectional
2 0.15 18.75
mv
area at the exit becomes, A2 or A 2 0. 00262 m2 .
V2 1070
h i = he (4.57)
by which it is stated that a throttling process can be considered as a constant enthalpy process.
Example 4.23: As shown in Figure 4.37, compressed water at 20 bars in pressure and 200°C in temperature is adiabatically
throttled to 15 bars by flowing through a valve. Determine, at the exit of the valve, a. the temperature and the quality of
water, b. the velocity for A2 = 2A1, and V1 = 10 m/s.
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 127
Solution:
a. The enthalpy of the compressed liquid may be assumed to be the
same as the enthalpy of saturated water at 200°C. Then h1 = 852.45
kJ/kg, and by equation (4.57), h2 = h1 = 852.45 kJ/kg. By saturated
steam data at p2 = 15 bars, h2f < h2 < h2g, which states that water
at the valve exit is a mixture of liquid and vapor. Thus the exit
temperature becomes, T2 = 198.3°C, and the quality is,
h2 h2 f 852. 45 844.84
x2 , or x2 = 0.0039
h2 fg 1947. 3
b. The specific volume at the valve exit is, v2 = v2f + x2v2fg = 0.00115 + 0.0039 0.1306 = 0.00166 m3/kg. Consider-
ing the continuity equation of one-dimensional flow, the exit velocity becomes,
A v 1 0.00166
V2 1 2 V1 10 , or V2 = 8.3 m/s
A v
2 1 2 0.001
As can be deduced by this result, neglecting the change in kinetic energy is an appropriate assumption for throttling
processes.
m i m e (4.58)
m i hi m e he (4.59)
Solution:
With respect to the boundary around the chamber, equations (4.58), and
(4.59) become,
T3 = 87.3°C.
Turbines. In a turbine, the energy content of the working fluid that can be liquid or gas is converted
into mechanical shaft work. As the fluid does work on the rotating blades of this machine, the pressure
and the temperature of the fluid decrease in the flow direction. A single stage and axial flow steam
turbine is presented in Figure 4.39. As shown in the figure, the steam is first accelerated by nozzles,
then the blades that are attached to the turbine wheel transmit the work of steam to a rotating shaft
which in turn operates the generator. The change in potential energy between the inlet and the outlet
of a turbine is usually neglected. Unless stated, the heat losses through the turbine casing are small in
comparison to the enthalpy changes. Then, for a turbine, equation (4.54) reduces to
V2 2
w h h V (4.60)
2 2
i e
Compressors and Pumps. Compressors and pumps are utilized in compressing or raising the pres-
sure of a fluid. A compressor that uses a gas or a vapor as the working fluid can be either rotating or
reciprocating type. In a rotary compressor, the fluid is accelerated and the kinetic energy is increased
by the shaft work done on the impeller. Then, in the diffuser section, deceleration of fluid causes an
increase in fluid pressure. Figure 4.40a displays a rotary compressor which might be used for raising
the pressure of the inlet air stream of a jet engine. In a house hold refrigerator, however, a reciprocat-
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 129
ing compressor is used to raise the pressure of the refrigerant vapor. A cutaway view of a pump is
shown in Figure 4.40b. Pumps are used to raise the pressure of liquids.
Both machines consume work energy. Again the change in potential energy between the inlet
and outlet of a compressor is negligible. For compressors with a large power capacity either fins are
attached to the compressor body or water is circulated through the jackets of the compressor cylinders
for cooling. Hence, in general, the energy equation for a compressor might be written as,
V2 2
w q h h V (4.61)
2 2
i e
Fans and Blowers. Fans are almost universally used for the circulation of air or other gases through
low pressure systems. As shown in Figure 4.41, a centrifugal fan is widely used for moving large or
small quantities of air over an extended range of pressures at the expense of work consumption. The
heat transfer through the housing of a fan and the change in potential energy of the fluid are usually
neglected. Then. equation (4.54) simplifies to
V2 2
w h h V (4.62)
2 2
i e
130 THERMODYNAMICS
Example 4.25: A small steam turbine working at a partial load produces 100kW of power at a flow rate of 0.3kg/s. The
steam as in Figure 4.42 is throttled before entering the turbine from 1.5MPa, 300°C to a state of 1 MPa in pressure. For
an exhaust pressure of 10kPa, determine a. the state of steam at the turbine outlet, b. the diameter of the exhaust duct for a
stream velocity of 20m /s.
Solution:
a. In equation (4.60), neglecting the
change in kinetic energy, the out-
let enthalpy becomes, h 3 = h 1-w where
h1 = 3037.6kJ/kg, and the turbine specific
W 100
power is: w 333. 3 kJ/kg.
m 0. 3
Thus, the enthalpy relation yields, h3= 2704.3
Solution:
Assuming the compression process to be adiabatic, equation (4.61) reduces to
V2 V2
w h h
2 1 2 2
Since the atmospheric air is stagnant, V1 = 0, and h1 – h2 = cp(T1 – T2) = 1.005 (300 – 500) = –201 kJ/kg. Then,
1002
w 201 206 kJ/kg
2000
W
W 50
Considering the definition of specific shaft work w as, w
, Then the mass flow rate becomes, m , or
m w 206
m 0.242 kg/s by which the amount of air flowing through the compressor in one hour is: 871.2 kg.
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 131
Solution:
The mass flow rate of supplied air, m a i Vi
pi 100
where r i 1.169 kg/
RTi 0.287 298
m3, and m a 1.169 0.05 = 0.058kg/s. Neglecting the change
in kinetic energy of air, equation (4.61) simplifies to w q hi he , and the amount of heat removed by water is,
Q a 25.08
ferred per unit mass of air is: q = –432.41 kJ/kg,
and the heat trans m a 0.058
hi – he = cpa(Ti – Te) = 1.005 (25 – 80) = –55.275 kJ/kg. Substituting these values into the energy equation yields,
w = –432.41 + (–55.275) = –487.685 kJ/kg.
Then the shaft power of the compressor is:
W mw = –28.285 kW.
0.058 (487.685) or W
Example 4.28: Figure 4.46a presents a layout of a room air conditioner in which refrigerant R22 is used as the working
fluid. The warm room air at 100kPa, 27°C enters the evaporator of such a device at a flow rate 6m3/min. As shown in Figure
4.46b, the refrigerant at 245 kPa in pressure and 0.3 in quality flows into the tubes of the evaporator at a rate of 1kg/min.
and exits as a saturated vapor at the same pressure. Determine the air temperature at the evaporator exit.
Solution:
In this example, the hot and the cold fluids are respectively the room air, and the refrigerant. The mass flow rate of air is:
, pi
a i V
m
100
1.161 kg / m3 , and a 1.161
m
6
= 0.116kg/s
i i
RTi 0. 287 300 60
The enthalpy change of the refrigerant is: (he – hi)c = (1 – x1)hfg = 0.7 220.33 = 154.231 kJ/kg
Then, by equation (4.63), 0.0166 154.231 = 0.116 1.005 (27 – Te), and solving for Te, the temperature of air at
the evaporator exit becomes, Te = 5.03°C.
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 133
1
2
w v p2 p1 V22 V12 g z2 z1
(4.65)
Solution:
a. With respect to the system defined in Figure 4.45, the mass flow rate, m r 2 A2V2 , where,
p2 100
r2 1.078 kg / m3 , and m 0.00215V2
RT2 0.287 323
134 THERMODYNAMICS
The enthalpy change of air is: h2 – h1 = cp(T2 – T1) = 1.005 (50 – 20) = 30.15 kJ/kg
W
The total work transferred to the duct is: W W
–0.1 + (–0.05) = –0.15 kW
e f
There is no change in the potential energy of this flow, and the surface of the duct is assumed to be insulated. Then, equa-
tion (4.54) becomes,
V22 0.15
30.15 , where the velocity of ambient air is taken to be zero, V1 = 0. Rearranging this expression
2 0. 00215V2
b. The mass flow rate, m 0.00215V2 0.00215 2.147 0.0046 kg/s. Respect to inlet conditions, m 1V1
p1 100 m 0.0046
1 = 1.189 kg/m 3, and the volumetric flow rate at the inlet is: V1 , or
RT1 0. 287 293 1 1.189
V1 0.00386 m3/s.
Example 4.30: A house with an internal volume of 500m3 is to be heated by the circulation of hot air as in Figure 4.48. Air
flows through an insulated duct in which a 20kW electrical heater is installed. The circulation of air is provided by a 200W
fan. The inside temperature and pressure initially are 10°C and 95 kPa. The total heat loss through the walls and the ceilings
of the house is 450 kJ/min. For a change of 5°C in the temperature of air stream between the duct inlet and outlet, determine,
a. the time duration required for a final temperature of 25°C in the building, b. the average flow rate of air in the duct.
Solution:
a. Considering the house as a system, it should be treated as a closed system for which there is no change in kinetic
and potential energies, and equation (4.42) is reduced to
U = Q12-W12
p1V 95 500
m 584.82 kg. Neglecting the change
RT1 0.287 283
in the internal energy of the walls, the change in the internal
energy of air becomes identical to the internal energy change of
the system. Thus,
U = mcv(T2 – T1) = 584.82 0.718 (25 – 10) = 6298.51
kJ. Due to constant rate of heat loss and power supply,
Q Qt
12 12 e f
7.5t , W W W t = –20.2t, and the energy
balance results as, 6298.51 = –7.5t – (–20.2t)
Solving for t yields, t = 495.95s.
he – hi = –w
and w
W 20.2 . Substitution into the above relation yields,
m a m a
20.2
5.025 = . The mass flow rate of air becomes, m a = 4.019 kg/s.
m a
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 135
U m i hi Q W (4.66)
t
m(t ) m(0) m i dt (4.68)
0
Substitution of equation (4.68) into (4.67) results with the energy equation of the charging pro-
cesses. The process takes place in a time interval of (0-t).
136 THERMODYNAMICS
where m(t) and u(t) respectively are the mass and the specific internal energy of the system at
time t, and m(0), u(0) are the same parameters evaluated at the initiation of the process. On the other
hand, the terms Q12 and W12 represent the heat and work transfer of the process.
Example 4.31: As shown in Figure 4.50, a piston-cylinder apparatus containing 0.1 kg of saturated steam at 10 bars is
connected through a valve to a supply line which carries steam at 20 bars in pressure and 500°C in temperature. The valve
is opened and the steam is allowed slowly to flow into the apparatus until temperature reach 300°C. During the charging
process, 90 kJ of heat is transferred to the surroundings. Determine the amount of steam charged to the apparatus.
Solution:
With respect to the system boundary, the energy balance requires,
where the subscripts 1 and 2 respectively refer to the initial and the final states in the
apparatus. From steam tables, at state 1 (p1 = 10 bars, x1 = 1.0), u1 =2583.6 kJ/kg, v1 =
0.1944 m3/kg, and at state 2 (p2 = 10 bars, T2 = 300°C), u2 = 2793.2 kJ/kg, v2 = 0.2579
m3/kg. The enthalpy of the charged steam is: hi = 3467.6 kJ/kg. Let m represent the
amount of steam charged into the cylinder. Then, m2 = m1 + m. Since the work transfer
takes place at a constant pressure,
W12 p1 V2 V1
where, V1 = m1v1 = 0.1 0.194 = 0.0194 m3, and V2 = m2v2 = (0.1+m) 0.2579 =
0.02579 + 0.2579m. Then the work transfer becomes, W12 = 1000 (0.02579 +
0.2579m-0.0194) = 6.39 + 257.9m. In addition, Q12 = –90 kJ, substituting these
evaluated terms into the energy equation yields,
(0.1+m) 2793.2 – 0.1 2583.6 = 3467.6m + (–90) – 6.39 – 0.2579m, and solving for m results as m = 0.174 kg.
Example 4.32: A thermodynamicist is attempting to model the process of balloon inflation by assuming an evacuated and
elastic casing to behave as a spring opposing the expansion. As air at 10 bars, and 20°C is admitted through the valve, the
spring is compressed and the pressure in the gas space becomes p = p1+K(L-L1), where the spring constant K is 500kPa/m.
The initial condition in the gas space is: p1 = 1 bar, T1 = 20°C, L1= 0.2 m. For a piston area of 0.02 m2, determine the tem-
perature of air in the gas space when L2 = 0.8 m.
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 137
Solution:
For the system boundary shown in Figure 4.51, Q12 = 0, and equation (4.68) simplifies to
The enthalpy of charged air, hi = cpTi = 1.005293 = 294.46 kJ. Substituting these terms into the energy equation results
as, 16.01-1 = 294.46m-3, and solving for m yields, m = 0.061 kg.
The final mass of air in the casing, m2 = m1+m = 0.00475+0.061 = 0.0657 kg, and through the equation of state,
p2 V2 400 0. 016
T2 , or T2 = 339.4 K.
m2 R 0. 0657 0. 287
U m e he Q W (4.70)
138 THERMODYNAMICS
The change in the internal energy of the system which discharges fluid for a time interval of
(0 - t ) is: t
U (t ) U (0) m e he dt Q12 W12 (4.71)
0
t
m(t ) m(0) m e dt (4.72)
0
As a specific Example for such a process, consider a pressurized tank equipped with a gas releasing
valve contains an ideal gas. As shown in Figure 4.52, at a certain pressure p, the valve opens and the
gas is adiabatically released. It is desired to determine a relationship between the mass remained in the
tank and the gas temperature. Considering the differential form of equations (4.71) and (4.72) as,
dU me he Q W (4.73)
dm me (4.74)
Since the process is adiabatic, Q = 0, and the absence of a moving boundary, or a shaft crossing
the system boundary, etc., the transfer of work is also zero, W = 0. Due to change of system mass,
the differential form of the internal energy of the system is: dU mdu udm . At an instant of time,
the enthalpy of discharging fluid is the same as the system enthalpy, he = h. As a result, equation
(4.73) may be rearranged to yield,
dm cv dT
(4.76)
m R T
Integration between the initial and the final states yields,
k 1
m2 T2
(4.77)
m1 T1
1 k
Recall that for a reversible and adiabatic process of an ideal gas, Tp k Constant . Then the
mass ratio in equation (4.76) may be expressed in terms of the pressure ratio as,
k
m2 p
2 (4.78)
m1 p1
This result is unique in the sense that it provides a direct relationship between the mass and the
pressure of the gas remaining in the tank for a process of no work and no heat transfer interactions.
Example 4.33: The insulated tank in Figure 4.52 has a volume of 1.5 m3 and contains air at 10 bars, 227 C. The valve
automatically opens at this pressure, and air is released quasi-statically. The process stops when the tank pressure is reduced
to 1 bar. Determine a. the final temperature, b. the ratio of the discharged mass to the initial mass of the tank.
Solution:
p1V 1000x1.5
a. The initial mass of air in the tank, m1 10. 452 kg, and equation (4.78) gives the final mass as,
RT1 . 287 x500
1 1
m2 p2 k 1 1.4
0.193, m2 0.193 x10.452 2.017 kg. Thus the air temperature at the final state becomes,
m1 p1 10
m 8.435
b. The amount of discharged air is: m m1 m2 10.452 2.017 8.435 kg 80.7%
m1 10.452
Example 4.34: A 2m3 tank contains air at 2Mpa, and 500C. The tank is connected to a turbine which exhausts into the
atmosphere as in Figure 4.53. The tank, the connection pipes, and the turbine are insulated, and their volumes are negligible.
After opening the valve, the air expands quasi-statically. Determine, a. the total mass flowing through the turbine until the
flow stops, b. the work delivered to the turbine shaft.
Note: Air is always assumed to exhaust to atmospheric conditions at 1 bar, and 27C.
140 THERMODYNAMICS
Solution:
a. The flow of air through the turbine will stop when the final pressure in the tank is 1bar. Due to quasistatic and
adiabatic expansion of air, by equation (4.78), the mass remained in the tank at p2 = 1 bar is,
1 1
m2 p2 k 1 1.4 p1V 2000 x 2
0.117, where m1 18.03 kg, and m2 = 0.117 × 18.03 = 2.1 kg
m1 p1 20 RT1 0.287 x 773
Thus the amount of mass flowing through the turbine becomes, m m1 m2 18.03 2.1 or m = 15.93 kg
b. In applying equation (4.71) to the system in Figure 4.49, the enthalpy of air being constant at the exit,
t2 t2
t1
m e he dt he m e dt he (m1 m2 )
t1
and Q12 = 0 . Thus rearranging equation (4.70) for work transfer yields, W12 (m1u1 m2u2 ) he (m1 m2 )
p V 100x2
The final temperature of air, T2 2 331.8 K , considering that u = cvT, and h = cpT, the work transfer
may be evaluated as, m2 R 2.1x0. 287
There are many other types of transient flow problems of theoretical as well as practical interest. The
solution of each type depends on the restrictions and idealizations placed on the process. In every case,
it is better to begin with the basic or fundamental equations and to proceed logically from that point.
A discussion of some other type of transient flow systems is presented in the following examples.
Example 4.35: The pressure cooker in Figure 4.54 has an internal volume of 0.5 m3, and operates in the following manner:
A small amount of water placed in the cooker experiences a positive heat transfer increasing the water pressure to 2 bars.
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 141
At this pressure the vent valve opens automatically and vents the contents of the cooker to the atmosphere in a manner such
that the pressure in the cooker is held constant at 2 bars. After the cooking time is elapsed, the vent valve is closed and the
heat transfer becomes negative. When the pressure returns to 1 bar, the door is opened and the food is removed. In the event
that the vent valve fails to operate when the heat transfer is positive, the pressure will rise until the cooker explodes. To
prevent such a catastrophe, the cooker is equipped with a burst disk that ruptures at a pressure of 3.5 bars which is less than
the explosion pressure. Consider the case in which the cooker contains nothing but 3 kg of water at a pressure of 1 bar when
the cooker is sealed. The cooker now experiences a positive heat transfer until the pressure reaches 3.5 bars whereupon the
burst disk ruptures. The content of the cooker vents rapidly to the atmosphere. a. Determine the temperature and the quality
of water in the cooker just before the burst disk ruptures. b. If the venting process is modeled as adiabatic, estimate the mass
of water that escapes from the cooker. c. Calculate the work done against the atmosphere.
Solution:
a. The heating process until the burst disk ruptures is a constant volume process. Therefore, v2 = v1 = 0.166 m3/kg,
and from steam tables, at p2 = 3.5 bars, v2g = 0.524 m3/kg. Since, v2 < v2g , the state of water before bursting is a
saturated state. Thus the temperature at state 2 is, T2 = 138.9 C
v2 v2 f 0.166 0.001078
The quality of water just before the disk ruptures, x2 , or x2 = 0.315
v2 g v2 f 0.524 0.001078
b. This is a non-quasi-stastic discharging process, it occurs suddenly. To get a result, the system has to be treated
as closed. Letting the final state after the disk ruptures represented by 3, for the closed system in Figure 4.54, the
energy equation is:
m(u3 u2 ) W23
where, W23 = mp0(v3 - v2) and substitution yields, u3 p0v3 u2 p0v2 h3 . Recall that after bursting a mechanical
equilibrium establishes and p3 = p0 = 100 kPa. Evaluating the internal energy at state 2 as,
u2 u2 f x2 (u2 g u2 f ) 583.95 0.315 x(2546.9 583.95) 1203.8 kJ/kg . Thus the enthalpy at state 3 is:
h3 h3 f 1220.4 417.46
h3 1203.8 100 x0.166 1220.4 kJ/kg .Then the final quality of water, x3 0.355 , and the
h3 g h3 f 2258
specific volume becomes, v3 v3 f x3 (v3 g v3 f ) 0.602 m3 /kg . Thus the change in volume due to rupture is:
V m(v3 v2 ) 3 x(0.602 0.166) 1.306 m3 . Accordingly, the amount of discharged mass is:
Example 4.36: The device shown in Figure 4.55 is designed to provide hot air for defrosting the windshield of an auto-
mobile. Atmospheric air flows into a rigid, insulated chamber where it is heated by an electrical heating element. Assume
that steady-state conditions exist initially with the outlet temperature of air being T0. Shutting off the power to the heating
element at t = 0, T2 will decrease with time. Drive an expression for T2 as a function of time.
142 THERMODYNAMICS
Figure 4.55
Solution:
For t > 0, there is no heat and work transfer to the system in Figure 4.55. There is also no change in the system kinetic and
potential energies. Because of single inlet and outlet, equation (4.39) simplifies to
Substituting m e into the energy equation and rearranging results as, m (u he ) mu m i (hi he )
Since the outgoing fluid has the same properties as the system, u he RT . The mass of air in the system at an instant
pV 1 dT
of time t is, m pV , and the time rate of change may be expressed as m
R T 2 dt
, where the system pressure
RT
dT
and the volume are assumed to be constant. Additionally, u cv and hi - he c p (T1 - T ). After substitution of these
dt
pV dT dT m
relations into the energy equation and letting m0 , the following differential equation results, 1 dt and
RT1 T T1 T m0
T(0) = T0 and T(0) = T0
Together with the initial condition, the integration yields an expression for the outlet temperature as follows,
T1 T T0 m 1
t
T T T exp m
0 0
Figure 4.57
a. the final temperature and pressure,
b. the work required to restore the system to its Figure 4.59
initial state.
144 THERMODYNAMICS
4.10 As shown in Figure 4.60, a vertical and insulated tank reached a temperature of 650C and a pressure of 30MPa
has a volume of 40L and separated by a piston into and exploded. The steam then expanded into the boiler
two equal parts. The air is initially at 1 bar, 250C, room having a volume of 250 m3. The engineer feels
and water is at 250C with a quality of 0.6. the 100 that the final pressure of steam may have been high
kg piston has a cross-sectional area of 80 cm2, and is enough to cause the walls of the boiler room to burst.
held in place by a stop. Releasing the stop, the piston Thus he wants to calculate this pressure by assuming
moves upward and an equilibrium state is reached. that the boiler room is sealed and the initial contents
For a diathermal piston, of the room are negligible. Determine,
a. determine the final temperature, the pressure a. the final pressure in the room after the explo-
and the volume of air. sion,
b. Suppose now that the steam is replaced by oxy- b. the final quality of steam.
gen gas at 35 bars, 250C, determine the same
quantities stated in (a) for this case. Closed systems
4.13 An insulated copper container with a mass of 3 kg
contains 20 kg of water. The water is stirred by a very
light paddle-wheel connected to an electric motor as
shown in Figure 4.62. Due to stirring action, the tem-
perature of the system consisting of water and copper
rises at a rate of 1C per minute. Make a table showing
the rates of heat transfer and work transfer and the rate
of internal energy change of the system consisting of
Figure 4.60
4.11 A well insulated container 0.16 m3 in volume is
divided internally into two equal parts by a rigid,
adiabatic partition. As shown in Figure 4.61, a small
connecting tube through this partition equipped with
a valve accessible to the outside. Side A contains
oxygen gas at 37C and 1.5 bars, and side B also Figure 4.62
contains oxygen but at 97C, 7 bars. Both gases are
ideal with a specific heat of cp = 0.918kJ/kgK. a. the water,
b. the container,
a The valve is quickly opened and the pressures c. the water and the container,
on both sides are rapidly equalized. Assume no
d. the water, the container, and the motor.
conduction of heat takes place, and then determine
the temperatures and pressures on both sides. 4.14 A 0.5 kg of air is enclosed in a stepped cylinder. As
in Figure 4.63, the cross-sectional area of the large
b. The valve is left open and eventually the tem-
section is related to the small by A1 = 2A2 , and the
peratures become equal on both sides. Determine initial state of air is 3 Mpa and 327C. As air cools
the final pressure and the temperature. down, the piston descends and reaches the step. The
cooling process continues until the final temperature
is 7C. Determine,
Figure 4.61
4.12 A marine engineer is investigating the possible cause of
a recent submarine disaster, and comes upon the idea that
it may have been due to the explosion of a faulty steam
boiler. He hypothesizes that the 4 m3 boiler accidentally Figure 4.63
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 145
a. the temperature when the piston reaches the 4.22 A 1 kW of electric heater is placed at the base of a
step, laterally insulated cylinder which contains 2 kg of
b. the final pressure of air, water at 15C. As shown in Figure 4.64, a 25 kg of
c. the amount of heat and work transfers for the frictionless piston covers water at the top, and has a
complete process. cross-sectional area of 0.05 m2. For an atmospheric
d. Show the process on p-V diagram. pressure of 100 kPa, determine the time required to
boil off 0.8 kg of water.
4.15 Ammonia at a state of 200kPa and 20C is contained
in a piston-cylinder apparatus and occupies a volume
of 1.5 m3. A 750 kJ of work is transferred to ammonia
by compression and its temperature increases to
40C. During the compression process, 1500 kJ of
heat is transferred to surroundings at 20C. Through
an energy analysis, determine whether the given
process is feasible or not.
4.16 A piston-cylinder machine contains nitrogen initially
at 2 bars, 117C, and 0.25 m3. The piston moves
with negligible friction until the pressure rises to 5
bars. The process is described by, V = 0.4 - 0.05p,
where V and p are in m3 and in bars respectively.
Determine, Figure 4.64
a. the final temperature,
b. the work done, and the amount of heat transfer. 4.23 Consider two separate systems. One is a piston-cylinder
arrangement and the other a rigid tank both of which
4.17 Oxygen is contained within a piston-cylinder as- contain 10 kg of the same ideal gas initially at the same
sembly initially at 500 kPa, 200C, and occupies a pressure, temperature, and the volume. As a result of
volume of 0.04 m3. The gas expands according to heating, the temperature of the gas in both systems
the process described by pV1.15 = Constant , until the increases by 10C. Determine the amount more heat
temperature reaches 97C. Determine the value of to be supplied to the piston-cylinder assembly.
the work done and the heat transferred. Note: The molar mass of the gas is 25 kg/kmol.
4.18 A heat exchanger containing steam at 1.5 bars, 160C, 4.24 A balloon made of thin elastic material contains air at
has a volume of 0.15 m3 on the steam side. Because 200 kPa, 20C, and occupies a volume of 5 m3. The
of exchanger maintenance, the inlet and the outlet inside pressure of the balloon is proportional to its
valves are closed and the exchanger is allowed to volume and is represented by p = bV - 100 , where p
cool to a final temperature of 25C. Determine the is in kPa, and V in m3. The air is heated by a burner
heat transfer and sketch the process on a p-V diagram to a final temperature of 150C. The surroundings
relative to saturation line. outside of the balloon is at 1 bar in pressure and
4.19 A rigid tank contains 5 kg of refrigerant 22 at 5 bars, 20C in temperature. Determine,
75C. A paddlewheel within the tank adds energy at a. the final pressure in the balloon,
a constant torque of 150 Nm for 1000 revolutions. b. the work and the heat interactions during the
At the same time, the system is cooled to a final process.
temperature of 15C. Determine the heat transfer
and also sketch the process on p-V diagram relative
to saturation line.
4.20 A 2kg of water contained in a piston-cylinder device
is initially at 300C. The substance undergoes a
constant-temperature process with a volume changing
from 0.02 m3 to 0.15 m3. The measured work output
is 890 kJ. Determine,
a. the final pressure,
b. the heat transfer. Sketch the process on p-V
diagram, relative to saturation line.
4.21 A 2.5kW resistance heater is placed in a 0 08 m3
container filled with water at 27C and 1 bar. The
heater is allowed to operate for 30 minutes. The Figure 4.65
mass of heater is 2 kg, and its specific heat is 0.6kJ/
kgK. For an insulated container, determine the final Note: Assume that the heat transfer through the
temperature of water and the heating element. balloon material is negligible.
146 THERMODYNAMICS
4.25 As shown in Figure 4.65, a laterally insulated vertical a. Evaluate the spring constant for an atmospheric
cylinder contains saturated steam. Due to atmospheric pressure of 100kPa.
pressure and the piston weight, steam is initially at b. At what position of the piston, the refrigerant
10 bars in pressure and occupies a volume of 0.15 becomes saturated vapor?
m3. The steam is heated until the piston reaches the c. Calculate the heat transfer for the complete
stops with a resulting volume of 0.2 m3. Then an ad- process.
ditional of 30 kJ of heat is supplied. Determine the d. Sketch the overall process on a p-V diagram,
final temperature of steam. relative to saturation line.
4.26 A 200L of steam at 10 bars, 200C is contained in a
piston-cylinder arrangement. As the steam is cooled, 4.28 As shown in Figure 4.68, a vertical column of mercury
the piston in Figure 4.66 descends and reaches the 2 m in height rests on a frictionless, massless, and
locking mechanism. At this instant, the position of non-conducting piston which has 0.1 m2 of cross-
the piston is fixed by the locking mechanism. Then sectional area. A pocket of air trapped behind the
the content of the cylinder is heated so that the final piston has a height of 20 cm and provides sufficient
state of water is at the critical state. pressure to support the mass of mercury at an initial
temperature of 27C. It is desired to raise the piston
by heating the trapped air. As the piston rises, the
displaced mercury spills over the tube wall. To
displace all the mercury, determine,
Figure 4.66
a. Determine the heat lost and gained respectively
by the cooling and the heating processes.
b. Sketch the overall process on a p-V diagram, Figure 4.68
relative to saturation line. a. the amount of work and the heat transferred by
air.
4.27 The laterally insulated piston-cylinder arrangement in
b. Illustrate the process on p-V and T-V dia-
Figure 4.67 contains 4 kg of R22 at a temperature of
grams.
-5C, and a quality of 1%. Saturated vapor has to be
obtained by heating the refrigerant. When the piston Note: Assume that the density of mercury is 13600
impacts the mechanical stop, the cylinder volume kg/m3.
becomes 10L. The piston has a cross-sectional area
of 0.1 m2 and considered to be massless. The spring 4.29 A room with dimensions of 3 m x 6 m x 8 m is to
is linear and assumes its free length when the piston be heated by a heater which supplies 30,000 kJ of
is at the base. heat per hour. As shown in Figure 4.69, a fan of 200
W in power provides circulation currents for air.
Heat leaks through the walls of the room at a rate
of 10,000kJ per hour. For an initial temperature of
0C, determine the time required for bringing the
room temperature to 20C.
4.30 The piston-cylinder apparatus shown in Figure 4.70 is volumes of 0.4 m3. The refrigerant 22 having 4 kg
divided into two compartments by a frictionless piston. of mass is initially at 50C. A heater is installed on
Initially both of the compartments are filled with air the Freon side of the cylinder. Due to heat transfer,
at 1 bar, 27C. The piston is 5 cm in diameter, and the final pressure in the cylinder becomes 500kPa.
the cross-sectional area of the piston rod is negligible. Determine, Assuming ideal gas behavior for R22, with
An actuator capable of exerting a maximum of 1 kN c p 0.74 kJ/kgK , cv 0.57 kJ/kgK determine,
of force on the piston rod is activated. Determine,
a. the final temperatures in both sections,
b. the amount of heat transferred by the heater.
Figure 4.70
a. the distance traveled by the piston if the process
is quasi-static and adiabatic, Figure 4.72
b. the distance traveled if the process is carried out
quasi-statically and isothermally. 4.33 A well insulated piston-cylinder assembly contains
c. In each case, calculate the transfer of work and ideal gas at 10 bars, 27C. As shown in Figure 4.73,
heat for all the gas. a mechanical stop prevents the piston from mov-
ing against the surroundings at 1 bar. The cylinder
d. Suppose that the rod is pulled rather than pushed.
Would the answers to questions a, b, and c have height containing the gas is 40 cm and the piston
any change? cross-sectional area is 0.02 m2. The 250 kg piston
is tightly fitted into the cylinder and is frictionless.
4.31 As shown in Figure 4.71, a cylinder with thermally When the stop is released, the piston moves until it
insulated walls is initially divided into two equal impacts to another mechanical stop where the gas
compartments of 0.02 m3 in volume by a moveable, volume has just double.
frictionless, and insulated piston. Each comparment
contains 1 kg of carbon monoxide modeled as ideal
gas with a constant volume specific heat of 0.744
kJ/kgK, and a gas constant of 0.296 kJ/kgK. The
gases at both compartments are initially at the same
temperature of 300 K, and at the same pressure. Due
to electrical work transfer, the final pressure becomes,
p2 = 2p1. Determine,
a. the final temperatures of gases in each compart-
ment,
b. the electrical work transfer.
Figure 4.73
a. As an engineer, you are asked to estimate the tem-
perature and the pressure after the expansion.
b. Repeat the problem for a case that the cylinder
is rotated by 90 before tripping the mechanical
stop.
c. Solve the same problem for a case that the cylinder
is rotated 180 before the tripping action.
Figure 4.71
Note: Assume the constant volume specific heat and
4.32 As shown in Figure 4.72, R22 and saturated steam the gas constant to be 0.8kJ/kgK, and 0.4kJ/kgK
are contained in an insulated cylinder separated by respectively.
a non-conducting, frictionless piston into two equal
148 THERMODYNAMICS
4.34 A cylinder containing 0.5 kg of steam at 3Mpa is 500C while cylinder B is empty. Opening the valve
maintained at 400C by a constant temperature bath. on the connecting line, the steam is allowed to flow
As shown in Figure 4.74, a 200 kg of insulated piston from A to B through the turbine until piston in A
whose area is 200 cm2 is held in place by means of
comes to the base.
a stop. The stop is released, and the piston moves
upward, oscillates for a while and assumes a new
equilibrium state. For an atmospheric pressure of 1
bar, determine the work done by the steam.
Figure 4.76
Figure 4.74 For a final temperature of 200C in cylinder B,
4.35 As shown in Figure 4.75, a piston (A) and a piston rod determine the work delivered by the turbine.
(B) are fitted inside a cylinder of length 500 mm, and
area of 60 cm2. The piston weighs 100 N, the piston 4.37 The device shown in Figure 4.77 is equipped with
rod is 12 cm2 and weighs 50 N. On the top of the rod, an insulated horizontal cylinder, two frictionless
but outside of the cylinder, a 200 N of weight (C) is pistons and an orifice plate. The plate divides the
placed. Initially air in (D) is at atmospheric pressure volume of the cylinder into two compartments. The
while the piston is positioned in the middle of the pistons are clamped together in such a fashion that
cylinder. The initial temperature is 40C everywhere. when they move, the distance between their faces
Assume that the cylinder is insulated and the piston
remains constant. The cylinder initially contains 1 kg
rod is non-conductive. Determine the final pressure
and the temperature in (E), of air at a pressure of 10 bars, and a temperature of
100C. An actuator which is external to the system
moves the pistons so that 30 kJ of work is done to
the system. Determine the final temperature and the
pressure of air.
Figure 4.77
4.38 As shown in Figure 4.78, a vertical and insulated cylinder
Figure 4.75
is fitted with a 30 kg of frictionless and adiabatic piston
a. for a diathermal piston,
whose area is 15 cm2. The volume trapped between the
b. for an adiabatic piston.
piston face and the bottom of the cylinder is partitioned
4.36 Two vertical and insulated piston-cylinder assemblies off into two sections by a rigid and adiabatic membrane.
are connected through an adiabatic turbine as shown
The upper section contains 10 kg of saturated liquid
in Figure 4.76. The piston weights and the cylinder
water while the lower section has 1 kg of water at a
cross-sections are such that pressures of 1.5Mpa
and 0.15Mpa are necessary for moving the pistons pressure of 7 bars and a temperature of 200C. At the
respectively in cylinders A and B. The cylinder A moment when the membrane is ruptured, the system
initially contains 3 kg of steam at a temperature of comes into a new equilibrium state.
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 149
Figure 4.81
d. Is the cycle a power or a refrigeration cycle? rejects 700 kJ of heat to another. The heat engine
Explain. performs 1000 kJ of mechanical work. Determine,
4.43 A 2 kg of ideal gas with a molar mass of 44 kg is a. the amount of heat exchange with the third
contained in a piston-cylinder device. The gas, initially reservoir,
occupying a specific volume of 0.48 m3/kg at 20C,
undergoes a cycle as following: (1-2) isothermal com- b. the efficiency of the cycle.
pression to a volume of V1/2, (2-3) isobaric expansion
to a volume of 3V1/2, (3-1) returning to its initial state 4.48 A ton of refrigeration is defined as the heat absorption
by a process along a straight line on pV coordinates. rate by which 1 ton of water at 1 bar, and 0C freezes
a. Sketch the cycle on a pV diagram. in 24 hours and becomes ice at the same pressure and
b. Determine the net work output and the efficiency temperature. A refrigeration cycle produces 5 tons
of the cycle. of refrigeration by rejecting heat to surroundings at
Note: Assume that k = 1.5 for the gas. a rate of 25 kW. Determine,
4.44 Figure 4.83 presents a cycle undergone by an ideal a. the power input,
gas with constant specific heat cv and k = 1.6. The b. the coefficient of performance,
temperature and the pressure at state 1 respectively are
300C, and 14 bars. In addition, the volumes at state c. the cost of operation for one day, if the electric-
1 and 3 are given as 0.1 m3, and 0.4 m3 respectively. ity costs 10 cents per kilowatt-hour, and the
One of the processes of (1-2) or (3-1) should be refrigeration system is on one-third the time.
isothermal and the other is adiabatic. Determine,
4.49 The piston-cylinder arrangement shown in Figure
a. which one is isothermal, and which one is adia-
4.84 contains 1.5 kg of water at 50C and is used for
batic?
raising toys to a certain distance by cyclic processes
b. the pressures and the temperatures at state of 2
in a toy manufacturing facility. The piston weight
and 3,
causes a pressure of 200 kPa, and initially rests on the
c. the volume at state 2,
lower stop. The toy, together with the piston weight,
d. the net work output and the efficiency of this
causes a pressure of 500kPa when it is mounted on
cycle.
the piston. The content of the cylinder is heated until
its temperature reaches 200C. At this instant, the
piston reaches the upper stop, and the mounted toy
is removed. Then the water is cooled down to its
initial temperature of 50C.
a. Draw the cycle on a p-v diagram relative to
saturation line.
b. Determine the heat and work interactions of the
cycle.
c. Compute the efficiency of the cycle
4.45 Argon, k = 1.67, M = 40, and initially at 30 bars
undergoes a cycle in a piston-cylinder apparatus
consisting of the following three quasistatic processes:
(1-2) isobaric expansion to a volume of nine times
the initial volume, (2-3) isochoric cooling, (3-1)
adiabatic compression to the initial state. The piston
has a cross-sectional area of 200 cm2 and a stroke
of 18 cm. The crank-shaft that moves the piston by
a connecting rod rotates at a speed of 1500 rpm.
a. Sketch the cycle on a p-V diagram.
b. Calculate the power produced and the efficiency
of the engine.
at 1 bar pressure when the cylinder volume expands a. the mass flow rate of the refrigerant,
from V1 to V2. (2-3) the air in the cylinder is com- b. the exit enthalpy,
pressed quasistatically and adiabatically until the c. the exit temperature, and the exit area.
cylinder volume is V3. (3-4) some of air is delivered
at a constant pressure of 4 bars by decreasing the 4.56 Saturated liquid water at 150C flows steadily through
volume to V4. (4-1) after the delivery stroke, the air a throttle valve to a pressure of 2 bars.
remaining in the cylinder expands adiabatically until a. Determine the temperature of water at a cross-
the cylinder volume is V1. section downstream of the throttle valve where
the kinetic energy is negligible.
b. Suppose that the mass flow rate of water is 0.5
kg/s, and the valve cross-sectional areas at the
inlet and outlet are each 20 cm2. Then, justify the
negligible kinetic energy change for throttling
processes.
4.60 In a certain facility, 1000 kg per hour of saturated 1 bar, the steam enters a food dryer and exhausts as
steam at 1.5MPa pressure is needed. The existing a saturated liquid at the same pressure. The heating
boiler supplies steam at 2MPa in pressure and capacity of the dryer is 7 MW. If the heat transfer
300C in temperature. In order to obtain steam at from the surface of the turbine is 104kJ/h, determine
desired conditions, the steam of the boiler is mixed the power supplied by the turbine.
with water at 2MPa and 40C in a mixing chamber.
The steam, thus obtained by the mixing process, is
throttled down to 1.5MPa pressure at the chamber
exit.
a. Sketch the process.
b. Determine the mass flow rates of the cold water
and the steam from the boiler.
4.61 In an air-conditioning unit, two streams of air are
mixed in a mixing chamber to form a third stream.
The conditions of three streams and the volumetric
flow rates are given in the table below. Determine Figure 4.88
the temperature of the third stream exiting from the
chamber. 4.66 The centrifugal air compressor of a gas turbine re-
ceives air from the ambient where the pressure is 1
Stream no. 1 2 3 bar and the temperature is 27C. At the compressor
discharge, the pressure is 4 bars and the temperature
Pressure (bar) 1.5 1.5 1.5
is 200C. For a mass flow rate of 100 kg/min, the
Volumetric flow rate(m3/min) 2.5 5 - exit velocity is determined to be 100 m/s. Compute
the power required to drive the compressor.
Temperature(C) 25 60 -
4.67 A compressor steadily intakes 30 kg/min of refrigerant
22 at 80kPa and 0C through a pipe with an inside
4.62 The small high-speed turbine in a dentist’s drill is diameter of 10 cm. The compressor discharges the
driven by compressed air. Air inlets the turbine with refrigerant at 600kPa and 150C through a pipe with
a velocity of 2 m/s at a condition of 500kPa, 27C, 4 cm inside diameter. During the process, 45000 kJ/h
and exits at 100kPa and 0C. For an exit velocity of heat is lost to the surroundings. Determine,
of 30 m/s, the turbine produces a power of 50 W. a. the inlet and the outlet velocities,
Determine the mass flow rate of air through the b. the power input to the compressor.
adiabatic turbine.
4.68 A water pump mounted on the ground floor of a
4.63 A small steam turbine produces 75 kW output with skyscraper is used to deliver water to the observation
a steam flow rate of 0.2 kg/s. Steam at 1.4 MPa, platform that is 300 meters above the ground level.
250C is throttled to 1.15MPa before entering the Determine the power input to the pump for deliver-
turbine and expands to an exit pressure of 10kPa ing 3 kg/min of water at a discharge pressure of 2.5
in the turbine. Heat transfer from the turbine to the bars. Assume that the temperature of water does not
surroundings amounts to 40kJ per kg of flowing change during the process.
water. Determine the quality (if two phase) or the
temperature (if superheated) of water at the turbine 4.69 Crude oil is in a cavern at 35C and 5 bars, and is
exit. located 500 meters below the ground level. The oil
is pumped to the surface through a pipe with 10
4.64 In a power plant, steam at the outlet of the boiler cm inside diameter. The volume flow rate of oil is
is at 15 bars, 350C and is supplied at a rate of 1.5 20m3/h, and the local gravity is 9.75 m/s2. For oil
kg/s to an adiabatic turbine that is located 20 meters density of 850 kg/m3, determine,
below the boiler exit. The steam velocities at the a. the exit velocity,
inlet and outlet of the turrbine are 5 m/s and 40 m/s b. the required pump power.
respectively. Determine,
4.70 A fan described in a manufacturer’s table is rated
a. the power output of the turbine for an exit condi- to deliver 500 m3 of air per minute with a pressure
tion of 0.05 bars and a quality of 0.95, increase of 30 mm of water column when running at
300 rpm and requiring 4 kW of power. It is known
b. the error in power due to neglecting the effect
that the delivered volumetric flow rate, the increase
of elevation and the change in velocity.
in pressure, and the power required are directly pro-
4.65 In a food processing unit, steam at 20 bars, and portional to the first, second, and the third power of
500C enters a turbine at a rate of 3 kg/s as shown the fan speed respectively. For a fan speed of 400
in Figure 4.88. Leaving the turbine at a pressure of rpm, determine,
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 153
a. the volumetric flow rate, d. the inlet water velocity if the pipe diameter at
the inlet is 10 cm.
b. the increase in pressure, and the power re-
quired. 4.76 Steam is discharged from the turbine of a power plant
at a rate of 2500 kg/h and at conditions 0.1 bars and
4.71 A steady-flow steam generator operating at atmospheric
a quality of 0.9. The discharge of the turbine enters a
pressure uses 15 kg of water per minute at 25C and condenser where the steam is converted into saturated
transforms it into steam at 100C. Determine the heat liquid at the same pressure by the flow of cooling water
capacity rate of the steam generator. through the tubes of the condenser. Determine,
4.72 Water at 65 bars and 30C enters a steam generator a. the heat removal rate in the condenser,
at a rate of 200 000 kg/h. The super heated steam at b. the mass flow rate of cooling water for a tem-
60 bars and 550C leaves the generator. perature rise of 10C.
a. Determine the heating capacity rate of the steam
4.77 The ducts of an air heating system have the cross-
generator.
sectional dimensions of 30 cmX40 cm. The heated air,
b. Compute the fraction of this capacity that is used flowing with a velocity of 5 m/s at 85C and 1 bar, is
for the phase change in the generator. transported through an uninsulated section. As a result
4.73 Refrigerant 22 at 10 bars, 50C, flows at 8 kg/s of heat losses, the temperature of air drops by 5C.
through a heat exchanger, leaving at 9 bars and Determine the heat loss from air to the surroundings.
100C. Refrigerant exchanges heat with a stream
of steam entering at 2 bars, 200C. 4.78 Steam enters a long and inclined pipe with an inlet
diameter of 5 cm at 5 bars, 300C, and at a velocity
a. If the steam leaves the exchanger as saturated
vapor at 2 bars, determine the mass flow rate of of 10 m/s. At the pipe exit that is elevated by 30
steam. meters, the conditions are 3 bars, and 250C, and the
b. For the same inlet and outlet conditions, the diameter of the pipe is 10 cm. Determine,
refrigerant flow rate is reduced to 4 kg/s, and the a. the exit velocity of steam,
flow rate of steam remains the same. Determine b. the rate of heat loss of the pipe.
the outlet temperature of the steam.
4.79 A 3kW pump is used to pump well water that is 5
4.74 As shown in Figure 4.89, carbon dioxide at a state meters below the ground level to a storage tank 15
of 7 bars, 525C inlets to a shell-and-tube heat ex-
meters above the ground. The transporting pipe is
changer with a velocity of 150 m/s. The gas has to
be cooled by refrigerant 22 flowing through tubes. insulated. Due to frictional effects, however, the
At the outlet of the exchanger, conditions of carbon water temperature rises by 0.03C during the process.
dioxide are 3.5 bars, 125C. The inlet and the outlet Determine the mass flow rate of water.
states of the refrigerant and other related parameters
are given in the figure. Assume ideal gas behavior Unsteady flow systems
for R22, with c p 0.74 kJ/kgK , and Determine,
4.80 The weightless piston of
the insulated cylinder in
Figure 4.90 is initially
at the base, and the un-
compressed spring is
just touching the piston
surface. Steam flowing
through a pipe at 15 bars,
300C slowly enters the
cylinder as the valve is
Figure 4.89 opened. The charging
a. the exit velocity of carbon dioxide, process terminates when
b. the mass flow rate of refrigerant 22. the pressure inside the
cylinder reaches 10 bars
4.75 Water enters a heat exchanger at 0.5MPa and 140C Determine the final tem- Figure 4.90
at a rate of 24 kg /min and it leaves the exchanger at perature and the amount of steam in the cylinder if
0.5MPa and 60C. The water is cooled by passing air
the final volume is 0.1 m3.
through the heat exchanger at an inlet volume flow
rate of 100 m3/min. The air at the inlet is 110kPa, 4.81 A storage tank initially contains 2 kg of air at 1
25C and the exit pressure is 110kPa. Calculate, bar, 27C. Atmospheric air at 1 bar, 27C is to be
a. the exit temperature of air, compressed and supplied into a tank. Assuming
b. the heat transfer rate, that both the tank and the compressor are adiabatic,
c. the inlet cross sectional area for air flow if the determine the shaft work of the compressor if the
inlet velocity of air is 25 m/s, final pressure in the tank is 14 bars.
154 THERMODYNAMICS
4.82 A 1.5 m3 of refrigerant storage vessel contains 700 temperature bath at 300C. While the walls of tank
kg of liquid R22 in equilibrium with its vapor that B are insulated, both tanks are identical and each
fills the rest of the vessel. The temperature in the one has an internal volume of 0.2 m3. The valves of
vessel is 0C. An additional amount of 200 kg of the tanks are left open until the pressure equilibrium
saturated liquid refrigerant at -5C is pumped into with the main is obtained.
the vessel. Neglecting the pump work, determine the
heat transfer necessary for the content of the vessel
to remain at its original temperature and pressure.
4.83 Steam is used to move a frictionless lift cabin up-
wards in a certain application. As shown in Figure
4.91, the steam below the cabin is initially saturated
vapor at 500kPa with a volume of 0.002 m3 and the
steam source is at 1MPa and 300C. After opening
the valve, 0.15 kg of steam from the source slowly
flows in until the volume below the cabin becomes
0.04m3. Determine,
Figure 4.92
a. Determine the heat transfer of tank A.
b. Compute the mass of steam supplied to each
tank and the mass ratio of tank A to B at the
final state.
4.87 As shown in Figure 4.93, an evacuated tank of 100
L in volume is charged by two mains. First, 1.5 kg
of water at 15MPa, 300C is charged by main A,
and then steam at 5MPa, 600C is admitted into the
tank through main B. The desired final state in the
tank is saturated vapor at 5MPa. Determine,
a. the amount of steam supplied by main B,
b. the heat transfer to the tank.
Figure 4.91
a. the final state of steam,
b. the heat transferred from the cylinder.
4.84 A space capsule with an internal volume of 1.5 m3
is initially evacuated, and is on the surface of Mars.
Owing to small cracks on the capsule, the atmosphere
of Mars slowly penetrates into the capsule. In a few
hours of time duration, temperature and pressure
equilibrium are established between the inside of the
capsule and the Mar’s atmosphere whose pressure is
70kPa. Assuming that the Mar’s atmosphere behaves
as ideal gas, compute the amount and the direction Figure 4.93
of heat transfer during the process. 4.88 A pipeline contains steam flowing at 40 bars with an
4.85 A rigid and insulated tank is initially evacuated. unknown temperature T. In determining the value of
Atmospheric air at 1bar, 20C is allowed to leak T, the following experiment is proceeded. A tank of 1
into the tank until the pressure reaches 1 bar. a. m3 in volume, initially containing saturated vapor at 1
Determine the final temperature of air in the tank, b. bar, is attached to the pipe. Opening the valve located
Suppose that the tank initially contains air at 0.1bar, between the tank and the pipe, the steam is allowed to
and 20C. Determine the final temperature of air for flow until the tank pressure reaches 20 bars. At this
this case. instant, a thermometer, measuring the inside temperature
of the tank, registers 350C. The heat loss during the
4.86 Steam at 15 bars, 300C flows with a velocity of filling process is determined to be 198 kJ. Estimate the
100 m/s through a main as shown in Figure 4.92. temperature of steam, T, in the line.
Two tanks are connected to this main by pipes. Both
tanks contain steam at 5 bars and 300C. Tank A has 4.89 It is desired to pump well water at 10C from 5 meters
diathermal walls and is surrounded by a constant below the ground level to a storage tank that is 65
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 155
meters above the ground and occupies a volume of dangerously brittle at low temperatures, and the drop
50 m3. The tank is leak proof, and initially contains of gas temperature to such a low level might result
air at 1 bar, 10C. It is desired to fill half of the tank with a hazardous operation. Therefore, it is desired
with water. For a final temperature of 10C in the to determine the time variation of temperature in the
tank, determine the shaft power of the pump. bottle. A 1 m3 of bottle initially contains nitrogen gas
4.90 A vessel of 0.2 m3 in volume contains nitrogen gas at 140 bars and 0C. During the blow down period,
at 1 bar, 17C. The vessel has a safety valve that it is known tthat the gas pressure in the bottle varies
prevents the pressure rising above 1.5 bars. When
as, p 2 100 p0 , where t is in seconds. For a negli-
the pressure reaches 1.5 bars, the valve opens, and
the excess nitrogen is released. The vessel is heated gible heat transfer, estimate the gas temperature after
until the final temperature of nitrogen becomes 300C. 2 minutes of operation.
Determine,
a. the temperature at which the valve opens, 4.96 An insulated piston-cylinder
b. the amount of nitrogen released, apparatus equipped with a
c. the heat transfer of the process. linear spring as shown in
Figure 4.95 initially con-
4.91 A 5L pressure cooker has an operating pressure of tains 0.2 m3 of steam at 10
180kPa and initially 1/4 of volume is filled with vapor, bars, 400C. As the valve at
and the rest is liquid water. Heat is supplied at a rate the bottom of the cylinder
of 500 W to the cooker. If the pressure cooker is not
is opened, the steam flows
allowed to run out of liquid, estimate the maximum
time duration of the heating process. out, the piston moves down,
and the spring unwinds. At
4.92 A 40L bottle of refrigerant 22 at 20 bars, 35C is in an the final state, the cylinder Figure 4.95
environment at 1 bar, 35C. A small crack develops contains 0.1 m3 of saturated
on the bottle, and the refrigerant escapes slowly to vapor at 6 bars. Determine,
the atmosphere so that the temperature in the bottle is
always at 35C. For a final state of 1 bar, 35C in the a. the amount of steam discharged during the
bottle, determine the heat transfer of the process. process,
4.93 A tank with a volume of 2 m3 is half filled with liq- b. the average enthalpy of the steam at the outlet.
uid R22 and the remainder is filled with vapor at a
pressure of 909kPa. The content of the tank is heated 4.97 A tank of 0.8 m3 in volume contains 5% liquid water
until one-third of the liquid by mass evaporates. An by volume and the rest is water vapor at 2bars. The
automatic valve allows saturated vapor to escape at container is heated until the pressure reaches 100
such a rate that the pressure remains constant within bars. Then, as shown in Figure 4.96, the vapor is
the tank. Determine the heat transfer required. allowed to flow through an adiabatic turbine. During
4.94 As shown in Figure 4.94, a 1 m3 insulated rigid the process, the heating continues, and the pressure
vessel has a connection valve and a paddle wheel. is maintained at 100 bars. The vapor at the outlet
The vessel initially contains air at 27C and 400kPa.
of the turbine is always at 1 bar and a quality of 80
When the valve is opened to allow air to escape, the
paddle wheel begins to turn in such a way that air percent. During the process, it is also known that the
temperature remains constant during the process. enthalpy of steam at the outlet of the tank linearly
As the air pressure drops to 250 kPa, the valve is varies with its temperature. Determine,
closed and the paddle wheel stops. Determine the
work done on air during the process
Figure 4.96
a. the temperature of water when pressure reaches
100 bars in the tank,
Figure 4.94
b. the mass of discharged steam for a final tem-
4.95 In many industrial installations, occasions arise when perature of 700C in the tank,
compressed gas bottles are rapidly blown down. These c. the total work output of the turbine,
bottles are constructed of carbon steel that becomes d. the amount of heat transfer.
156 THERMODYNAMICS
Figure 4.98
4.100 Consider the following process which simulates the
operation of the Newcomen steam engine which
was used during the 18th century for pumping
water from mines in England. As shown in Figure
4.99, the cylinder 50 cm in diameter is fitted with a
frictionless piston and the volume of the cylinder is
0.3 m3 when the piston is against the stop.
Figure 4.97
Initially the piston rests against the stop and the
Miscellaneous systems cylinder contains saturated water vapor at 1 bar in
pressure. Liquid water at 1.4 bars, 20C is sprayed
4.99 The working fluid of the refrigeration system shown into the cylinder. The resulting condensation creates a
in Figure 4.98 is R22. The mass flow rate of the pressure drop. When the pressure inside the cylinder
refrigerant through the cycle is 0.015 kg/s, and the decreases to 0.7 bars, the atmospheric pressure is
power consumed by the compressor is 1 kW. The sufficient to overcome the load on the piston, and
conditions of the refrigerant at several points of the the piston begins a downward travel. Assume that
cycle are given in the table below. Determine, the process is adiabatic, determine the mass of water
a. the heat transferred through the compressor, that must be sprayed into the cylinder to cause the
piston to travel 1 meter.
b. the cooling capacity of the evaporator,
c. the mass flow rate of the cooling water,
d. the heat transfer rates of pipes at sections (8-1)
and (2-3),
e. the pipe diameters for sections (1-8) and (2-3)
for a maximum of 5 m/s refrigerant velocity.
State 1 2 3 4
Temperature(C) 0 100 80 30
State
5 6 7 8
Figure 4.99
Pressure (MPa) 1.3 0.2 0.2 0.2
4.101 Water 10MPa and 150C enters the boiler of a steam
Temperature (C) 32 -25 -25 -1 power plant with low velocity. The volumetric flow
rate entering the boiler is 0.02 m3/s. Exiting the
State 9 10 boiler at 10MPa with low velocity, water enters an
adiabatic turbine and leaves the turbine at 10kPa and
90 % quality with an average velocity of 200 m/s.
Pressure (MPa) - -
The power output of the steam turbine is 20.8MW.
Assuming steady flow process, calculate,
Temperature (C) 10 20
a. the mass flow rate of steam,
CHAPTER 4 ENERGY ANALYSIS OF SYSTEMS 157
Figure 4.101
x. A turbine is an energy conversion ma- 5. Refrigerant R134a with a mass of 0.5kg is at 4bar,
chine which first converts the flow energy into 500C is contained in a piston-cylinder arrangement.
kinetic energy by stationary blades and then to The refrigerant is cooled under constant volume until
its temperature is -40C, and then is compressed to
shaft work by the rotary blades.
be saturated liquid at -40C. The total amount of heat
y. A diffuser is an adiabatic device which removed in kJ might be,
decreases kinetic energy but increases the flow a. 114 b. 119,
enthalpy.
c. 124, d. 129.
z. On a hot summer day, a student turns his
fan on when he leaves his room in the morning. 6. Air enters a compressor operating at steady state at
1.05bar, 300K with a volumetric flow rate 20m3/min,
When he returns in the evening, the room must
and exits at 12bar, 400K. Heat transfer occurs at a rate of
be warmer than the neighboring room.
3kW to surroundings. Neglecting kinetic and potential
energy effects, and assuming ideal gas behavior, the
Check Test 4 shaft power of the compressor in kW is,
a. 43.8 b. 40.8,
Choose the correct answer:
c. 35.8, d. 45.8.
1. Liquid-vapor mixture of H2O is initially at 10bar
with a quality of 90% is contained in a rigid and 7. Air enters a household electric furnace at 250C, 1bar
well insulated tank. The mass of water is 2kg. The with a volumetric flow rate of 20m3/min. The furnace
electric resistance heater in the tank transfers energy delivers air at 500C, 1bar to a duct system with three
to water at a constant rate of 70W for 1.8h. The final branches consisting of two 15cm diameter ducts and
temperature of water in the tank in 0C is, 30cm duct. The air velocity in smaller ducts is 3m/s,
and hot air in large duct is used for laundry drying
a. 215 b. 235, and leaves the duct at 270C. Hence the amount of
c. 255, d. 275. heat absorbed by the laundry in kW is,
a. 6.4 b. 7.4,
2. A 2kg block of ice with an initial temperature of
-250C is dropped into an insulated tank containing c. 8.4, d. 9.4.
10kg of water initially at 200C. Assuming that the
specific heats of solid ice and water respectively are 8. The exhaust gas from a gas turbine is used to gener-
2.0kJ7kgK, and 4.18kJ/kgK, and the heat of melting ate steam to drive a steam turbine. The exhaust gas
of ice is 335kJ/kg, the final temperature of tank water is approximated as air, and the air stream as shown
in 0C is, in Figure 4.106 exchanges heat with water in the
heat exchanger. The air stream with 5.2kg/s of mass
a. -30C b. 30C, flow rate enters at a temperature 727°C, and 1bar
c. 00C, d. -50C. pressure, and leaves at 227°C, 1bar. Water at 30bar
of operating pressure enters the exchanger at 20°C
3. On a cold winter day, outside temperature is -100C, and and exits at 440°C. The steam produced expands in
yet, the outside surface temperature of the mechanical an adiabatic turbine to a pressure of 0.5bar, and at
engineering building is -90C. The thickness of the turbine exit water is saturated vapor. The turbine
building wall is 25cm and the thermal conductivity is power output in kW is,
0.6W/mK. The convective heat transfer coefficients a. 490 b. 590,
on the outer and the inner wall surfaces are 28W/m2K,
and 5W/m2K respectively. The interior temperature c. 540, d. 440.
of the building is,
a. 11.2 b. 15.2,
c. 20.2, d. 25.2.
9. A scuba divers’ tank of 0.6m3 is to be filled with 10. As shown in Figure 94.108, 6kg of two-phase propane
atmospheric air at 1bar, 27°C by an adiabatic com- is contained in a rigid tank initially at 10 bar, and the
pressor as shown in Figure 4.107. Assume air to be quality is 0.5. Heat transfer from a higher temperature
an ideal gas with c p 1.005 kJ/kgK, and k 1.4 , external source (possibly a fire nearby the tank) to
and the tank is initially empty. For an adiabatic tank, the propane in the tank occurs until temperature has
if the final pressure in the tank is 10bar, the amount increased to 120°C. During the process a pressure-
of work done by the compressor in kJ is, relief valve allows propane to escape maintaining
a. 310 b. 360, constant pressure in the tank. The total amount of
c. 410, d. 460. energy transferred by heat in kJ is,
a. 1446 b. 949,
c. 496, d. 1246.
161
162 THERMODYNAMICS
version is unachievable and impossible. For this reason, work is classified as the energy of higher
quality respect to heat and such a classification cannot be made solely by the use of first law of ther-
modynamics.
The maximum portion of heat energy that can be converted into useful work is called exergy. As
explained in the following sections, the higher the temperature of the reservoir that supplies the heat
energy, the higher the possibility of converting more heat energy into work. Hence the thermal energy
stored at high temperatures has higher quality of heat energy than the thermal energy supplied by
reservoirs at low temperatures. For instance, the amount of thermal energy stored in sea water is im-
mense. However, because of its low temperature, its quality is very low and it is frequently useless.
Another important observation about heat energy is that as heat is transferred from a system
to another or transformed into other form, its quality always lessens and changes in descending
order. Some of the factors that might exist in a process that reduce the quality of heat energy are:
1.Mechanical friction, 2.Electrical resistance, 3.Turbulence in a fluid flow, and 4.Transfer of heat
through a temperature difference.
1. Cooling of a coffee mug. As illustrated in Figure 5.2, two coffee mugs at different temperatures
brought into thermal contact. After a long period of time, both mugs assume an equilibrium tempera-
ture (T1<Te<T2). The reverse event, however, cannot be done. It is impossible to bring the two mugs
to their initial temperatures without consuming any work.
2. Two tanks at different pressures. As shown in Figure 5.3, two tanks having the same gas at differ-
ent pressures are brought to mechanical equilibrium by turning on the connecting valve. Both tanks
assume an equilibrium pressure p1 pe p2 . The reverse event cannot be accomplished. It is
impossible to bring the two tanks at their initial pressure without consuming any work.
Each and every process in nature occurs in a particular direction, and second law of thermodynam-
ics secures that there is no any arbitrary path for a process to take place.
Second law of thermodynamics particularly assists engineers in the following subjects:
1. Makes possible to measure the quality of energy.
2. Provides means for defining a criteria for ideal performance of energy conversion systems.
3. Predicts the natural direction of processes.
4. Determines the final equilibrium state of instant processes
Considering its role on the above indicated subjects, second law is not a law of conservation. In
mathematical terms, therefore, it can not be expressed as equality, and there is no single statement
in expressing the law. Differing from conservation principles, several statements that are identical in
essence can be used in describing the law. Presenting these statements without getting certain maturity
164 THERMODYNAMICS
on the subject is like describing an elephant by a person who has never seen and has no idea at all
about an elephant. If that person touches the leg of the elephant, he may think that it is the trunk of a
tree, if he grabs its tail, he might think that it is a sneak, or contacting its body, he may assume that he
is against a wall. Each one of these imaginations is part of the reality and helps identifying the beast.
However, none of them is capable of expressing her totally. This is exactly analogous to providing
different statements for describing the second law as whole. Each statement views the law from a
different point of view but none of them is sufficient to describe the law completely.
Principle 12: If two systems are not in mutual equilibrium with each other,
these two systems can be brought into equilibrium by extracting work en-
ergy out of the composite system. If the two systems are in mutual equilib-
rium, then the work that can be taken out of the composite system is zero.
This principle is basically a result of experimental observations and is considered a part of the
second law of thermodynamics. In bringing two systems into mutual equilibrium, there is certainly
more than one method in each of which the resulting work energy output will not be the same.
Example 5.1: Discuss two methods in bringing the pressurized air of a piston-cylinder device as shown in Figure 5.4 to
mutual equilibrium with surroundings.
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 165
Solution:
Method 1: Remove the locking mechanism on the piston. As the enclosed air suddenly expands the piston eventually as-
sumes a new position which will be the equilibrium state of air with the surroundings.
In this method, as described in Figure 5.4, the useful work output of the composite system is zero, W12=0.
Method 2: Instead of sudden pull of the pin, small weights located on the piston are slide to the corresponding shelves
one by one as the piston moves upward. This process continues until the equilibrium with surroundings is established. As
shown in Figure 5.4, since the weights are lifted up to certain distances, certain amount of work has been drawn out of the
composite system, W12>0. Finally, the two subsystems are brought into thermodynamic equilibrium. The amount of useful
work taken out of the composite system is as following:
As can be concluded by this example, there are several possible processes in bringing two systems
into mutual equilibrium. As far as the maximum amount of the work energy produced, however, there
is only one particular process that is more advantageous with respect to others in bringing the system
into mutual equilibrium with its environment.
Solution:
Due to “pushing” action of the surroundings at a pressure of
p0 by a volume change of V, a portion of the actual work
of the system is unrecoverably lost. Thus,
Wuseful Wactual p0 V
the exergy of the composite system “the system and the surroundings” is zero, then the system must
be in equilibrium with its surroundings. The properties of exergy can be stated as following,
1. Exergy defines the maximum amount of useful work that can be transferred by the composite
system at an instant time, t . At a particular state of a system, there is only a single value for the
maximum work. In evaluating this maximum work, it is not essential to know how the system has
assumed its present state at time t . Exergy is a property of the system and is not path depended. It is
exactly like p, T , v, h, u of the system. Exergy depends on the state of the system and on the state
of its environment.
2. Exergy of a system assumes the value of zero when the system is in mutual equilibrium with the
surroundings. Other than this, the exergy of a system is always positive. Negative exergy is mean-
ingless.
3. As shown in Figure 5.6, as the system changes its state from an initial to an intermediate state, its
exergy also changes. However, only some portion of this change can be converted into work. Regard-
less of how carefully the process proceeds and how professional methods are applied in transforming
energy into work, the useful work will always be less than the change of exergy of the system.
4. The exergy of a system increases the more it deviates from its environment. Whenever energy loses
its quality, exergy is destroyed.
5. The surroundings is assumed to be unaffected by the changes of the system. The surroundings is at
a constant state of pressure po and temperature To . Hence, in estimating the exergy of a system, the
state of the surroundings is taken to be the reference state.
These are the properties of system exergy and care must be exercised as the change for a particular
system is evaluated. The following Example is helpful on this basis.
Example 5.3: As shown in Figure 5.7, air with a velocity of 10m/s flows through a wind generator having a propeller with
a diameter of 12 meters.
a. Discuss under what conditions the work provided by the wind generator becomes the maximum.
b. Determine the maximum work.
c. Evaluate the change in exergy of air.
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 167
Solution:
a. Assuming that the air stream has the same pressure and tem-
perature as the surroundings, decelerating it to zero velocity
without any loss of energy will yield the maximum work. In
doing this, turbine must be frictionless and free of wake behind
the propeller blades.
b. To get the maximum work, the air stream is stationary at the
turbine exit, V2 = 0, and the kinetic energy change becomes,
Definition: If one or some of the above indicated factors does not exist in a process occurring between
a system and its environment, then the process is called a reversible process. The exergy loss of a
system undergoing a reversible process is zero.
168 THERMODYNAMICS
Since there is no exergy loss for a system undergoing a reversible process, the exergy of a system at
an instant of time “ t ” also signifies the maximum possible work that can be obtained until the system
comes into mutual equilibrium with its environment. The reverse is also true. For a reversible process,
without the need of any additional energy, the amount of work just extracted from the system can be
supplied back, and hence the conditions at the initial state of both the system and the environment can
be restored. Consequently, there will be no traceable change in the system nor in its environment.
Example 5.4: Analyze the following systems in Figure 5.8 and the related reversible processes.
Solution:
In Figure 5.8a, assume that the piston-cylinder device is adiabatic and the gas in the cylinder expands quasi-steadily by the
motion of a frictionless piston. Hence, the amount of work done by the gas is pdV . This energy is stored as rotational
kinetic energy on the fly wheel. In the reverse process, due to rotation of the fly wheel, the piston is moved slowly forward.
The gas is brought to its initial state. Eventually, the fly wheel stops. Without any need of additional energy or the need
of any external interference, both the gas and its environment (the fly-wheel) are brought to their original states. Thus, the
process is reversible.
In Figure 5.8b, the flow in a nozzle is adiabatic and frictionless. As the enthalpy of the flowing fluid decreases, the fluid
particles are accelerated, and the kinetic energy of the fluid increases. At the diffuser section, however, the frictionless fluid
is slowly decelerated, due to increase in pressure, the fluid enthalpy increases. At the exit of the diffuser, the state of the
fluid is identical with the state at the nozzle inlet. Since the nozzle-diffuser system is perfectly insulated, the flowing fluid
does not undergo any energy interaction with its environment, and the environment is always at its initial state. Hence, the
process of frictionless flow of fluid through a converging-diverging nozzle is an Example for reversible process.
As shown in Figure 5.8c, the motion of a free pendulum in a frictionless medium is an Example for reversible process.
Since there is no frictional loss, the energy of the pendulum transforms between kinetic and potential without any reduction
in the amount.
As presented in Figure 5.8d, the slow extension or contraction of an ideal elastic spring is again a reversible processes.
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 169
Example 5.5: One of the factors that leads to the exergy loss of a system is heat transfer at a finite temperature difference.
As shown in Figure 5.9, which is initially at a state of (p1, T1) where p1>p0 and T1>T0. Explain two different methods to
bring the system into mutual equilibrium with its environment at (p0, T0) and show that heat transfer at a finite temperature
difference causes exergy loss.
Solution:
Method 1: First expand the gas by reversible and adiabatic process until the final temperature is at surroundings, T2=T0.
Then, compress the gas by reversible and isothermal process so that the final pressure becomes the pressure of surround-
ings. In compression, heat is transferred to surroundings to keep the temperature constant. Thus the system is brought from
state (p1, T1) to state (p0, T0) completely by a reversible manner. The shaded region in Figure 5.9 represents the maximum
amount of work that can be extracted from the system by changing from the initial state (p1, T1) to the state of the surround-
ings, and hence it is the exergy of the system at state 1. As explained by method 2, by a simple heat transfer, this amount
of work is totally lost.
Method 2: The gas in the piston-cylinder device can be brought into the state of surroundings by cooling it down to the sur-
roundings temperature at constant volume. The amount of work output of the system by this process, however, will be zero.
The exergy level of the system by constant-volume cooling process is decreased, but no transfer of work is accomplished.
The total exergy of both the system and its environment is lessened.
Considering the results of the above explained methods of Example 5.5, one may conclude that
the transfer of heat at a finite temperature difference causes a decrease in the system exergy.
Example 5.6: Another factor that causes a loss in exergy of a system is “sudden expansion”. As illustrated in Figure 5.10,
the gas contained in a piston-cylinder device has to be brought into equilibrium with its environment. The gas is assumed
to expand in a frictionless medium. Explain two methods in bringing the gas from its initial state (p1, T0), where p1 > p0, to
the state of the surroundings at (p0, T0) and prove that sudden expansion causes a loss of exergy.
170 THERMODYNAMICS
Solution:
Method 1: As shown in Figure 5.10a, after releasing the locking mechanism of the piston, the gas expands without any
frictional loss, the piston oscillates around the state (0) and eventually comes to a stop at (p0, T0). Thus the amount of work
that can be extracted from this system is, p0 (V0 V1 )
Method 2: Instead of using a locking mechanism, suppose that small weights are located on the top of the piston, and the
frictionless piston moves slowly as the weights are laterally slide one by one. Since the piston-cylinder device is not insu-
lated, the gas expands reversibly and isothermally. The amount of work extracted from the system is, p1V1ln( p1 / p0 ) , and is
exactly identical to the exergy change of the system. The difference in the amount of work of these two methods is indicated
by the shaded region in Figure 5.10b (the area (1-0-a-1)) and corresponds to exergy loss of sudden expansion.
Comparing the two processes of Figure 5.10, a sudden expansion process causes a loss of exergy
of the system, and the amount of exergy loss is indicated by the shaded region in p-v plot of Figure
5.10b.
Principle 15: All processes involving a sudden pressure drop or a sudden expan-
sion result in an exergy loss. Decrease in exergy loss is directly proportional
with the decrease of pressure difference between the two states.
Example 5.7: As shown in Figure 5.11, mass A, on an inclined plane, has to be brought from state (1) to state (2). Show
that as an outcome of the frictional motion the system losses exergy.
Solution:
As shown in Figure 5.11a, on a frictionless surface, mass A can be brought to state (2) by the required minimum mass of
mB1+mB2. For a surface with friction, however, an extra mass of mB3 is required. Since the frictional effects are opposite to
motion, in restoring the mass A to its initial state, it is not enough to release mass B3. Both masses B2, and B3 have to be left
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 171
on the reference plane. As shown in Figure 5.11b, when the mass A comes back to its initial state, the work potential of the
system composed of masses A and B is reduced.
As a consequence of the above experiment, due to friction, the work potential of systems are al-
ways reduced. Initially the work potential of the system in Figure 5.11 is mB mB mB gL , however,
1 2 3
after a frictional process restoring the system into its initial state, the work potential of the composite
system becomes . Thus, due to friction, the system has undergone an exergy loss process.
Definition: The amount of exergy loss by an irreversible process measures the irreversibility of that
process. The irreversibility of a reversible process is zero. No exergy loss takes place by a reversible
process.
The irreversibility that may take place at a particular process may be gathered in the following
two groups,
Solution:
a. The surface of the heater is hotter than
the surroundings, Ts To , and consider-
ing principle 14, the process is externally
irreversible.
b. Due to resistivity of the wires, the flow
of current through the heating element
is done by a voltage difference. In fact,
the rubbing action between the moving
electrons causes heating. Hence the pro-
cess is also internally irreversible.
c. A process which is both internally, and
externally irreversible is called totally
irreversible, or simply irreversible.
Since the system exergy is single valued at a particular state of a system and is the property of the
system, like the other properties, the rate of exergy change of a system may be stated as following,
As explained in section (4.3), transfer of energy from one system to another can be done in three
different modes. Similarly, the transfer of exergy through a system can be carried out in three differ-
ent modes.
Consequently, the net rate of exergy transported into the system becomes,
Let us represent the rate of irreversibility produced by a real process at an instant of time as İ. As
all we know the value of İ is zero for reversible processes and is always positive for irreversible ones,
I 0 . Substituting Eq. (5.5) into (5.1) and rearranging yields,
m m
i
i i
e
e e Q W I (5.6)
where, , represents the rate of exergy accumulation in the system at an instant of time t. As you
may also note that the rate of exergy destroyed at a particular process, destroyed , is identical to the rate
of irreversibility produced by that process,
destroyed I (5.7)
In order to make use of equation (5.6) in analyzing engineering systems, one has to explore how
the terms like, W , Q and i depend on the system properties. Figure (5.13) illustrates schemati-
cally exergy balance of a system interacting with other systems at all modes of energy transfer.
dV
W W p0 (5.8)
dt
Example 5.9: A rigid and insulated tank as in Figure 5.14 contains 1kg
of air at a pressure of 1bar and temperature of 27C. Work is done against
the air by running the fan and the final temperature becomes 527C.
The increase in exergy of air is determined to be 100kJ. Calculate the
exergy loss by this process, and give reasons for such losses.
Solution:
Since the tank is adiabatic, the energy equation yields, U 2 U 1 W12 ,
for ideal gas behavior, U 2 U 1 mcv ( T2 T1 ) , and, W12 358 kJ .
Since the tank is rigid, no transfer of work takes place by volume
change. Respect to Eq. (5.8), for a reversible process, the increase of
the exergy of the system would be 358kJ.
For this particular problem, however, the exergy change of the
system is given as 100 kJ , and the exergy transfer by work is W 358 kJ. Substituting into Eq. (5.6) yields,
100 358 I12
As can be deduced from this example, contrary to energy conservation, exergy is not conserved. Due
to friction, certain amount of exergy is lost during the transfer of work from one system to another.
Definition: A heat engine is a cyclic device which operates between two thermal reservoirs, and
produces positive work after completion of a cycle.
Let Q be the amount of heat energy received from high temperature reservoir. The maximum
portion of this heat energy that can be converted into work identifies the exergy of Q. Since we use a
cyclic machine in this conversion, there would not be any exergy loss at all processes of the cycle, if
and only if the heat engine undergoes a reversible cycle. Thus, each and every process of a reversible
cycle must be reversible. As explained in section (4.13), Carnot cycle is an Example for a reversible
cycle.
Definition: A cycle is called a reversible cycle if each and every process of the cycle is reversible. If one of
the processes is irreversible that cycle is called irreversible cycle. Carnot cycle is a reversible cycle.
Carnot cycle. Named after a French engineer and army officer, Nicolas Sadi Carnot, he described
his cycle in 1820 as explained in the following example.
Example 5.10: Assuming an ideal gas behavior for the working fluid, determine the cyclic efficiency of a heat engine
undergoing a reversible Carnot cycle.
Solution:
As explained previously, Carnot cycle contains the following processes:
(1-2) Isothermal process at temperature T1, heat is transferred reversibly from a heat reservoir at temperature T1 to working
fluid at the same temperature. The amount of heat transferred is:
V2
Q1 mRTln (5.9)
V1
V3
Q0 mRT0ln (5.10)
V4
The two other processes of Carnot cycle are reversible and adiabatic
processes, and the 1st law states that
dT dV
dU pdV , or cv R (5.11)
T V
T0 V
For the process of (2-3) cv ln Rln 3 (5.12)
T1 V2
176 THERMODYNAMICS
T1 V
For the process of (4-1) cv ln Rln 1 (5.13)
T0 V4
V3 V2
Combining Eqs. (5.12) and (5.13) yields, (5.14)
V4 V1
Dividing Eq. (5.9) by (5.10) side by side and considering the result of Eq. (5.14), one may get the following relation
between the amount of heat transfer and the temperatures of the reservoirs as,
Q0 T0 Q1 Q0
or (5.15)
Q1 T1 T1 T0
Thus, for Carnot cycle, the ratio of the heat transfers is equal to the ratio of absolute temperatures of the respective res-
ervoirs. Considering the definition of the cyclic efficiency (Eq. (4.49)), then the efficiency of the Carnot cycle becomes,
Q0 T
1 1 0 (5.16)
Q1 T1
In accord with this result, one may state that the efficiency of any reversible cycle is independent
from the properties of the working fluid. All the reversible engines working between the same two
heat reservoirs yield the same efficiency. The efficiency of a reversible heat engine is unique. The
thermal efficiency of an actual heat engine, however, is much less than the value to be determined by
Eq. (5.16) and varies in the range between 10 percent and 40 percent.
Principle 18: (i) The thermal efficiency of an irreversible heat engine is always less than the ef-
ficiency of a reversible engine operating between the same heat reservoirs. (ii) All reversible heat
engines, irrespective of their cyclic differences, provide the same efficiency, and its value is the
maximum under giving conditions. (iii) The efficiency of a reversible heat engine is unique.
Respect to Eq. (5.16), the net work output of the Carnot cycle becomes,
T0
Wrev Q(1 ) (5.17)
T
A refrigeration system. This cycle is the reverse of heat engine cycle. The overall effect of the cycle
is to transfer heat from a low temperature medium to a high temperature by consuming work and finds
a wide application in our daily activities.
Definition: A cycle that transfers heat from low temperature medium to high temperature one by
consuming work is called refrigeration cycle.
Principle 19: (i) A refrigeration cycle is the reverse cycle of a heat engine. (ii) When
operated on the reverse order, a reversible heat engine becomes a refrigeration
cycle.(iii) The coefficient of performance (βr) of a refrigeration system is always less
than the reversible one operating between the same heat reservoirs. Hence a revers-
ible refrigeration cycle consumes the minimum amount of work for the same heat
transfer rate.
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 177
In terms of heat interactions, this principle states that no difference exists between a reversible heat
engine and a reversible refrigeration cycle. Thus, Eq. (5.15) is still valid for the reversible refrigera-
tion. Substituting Eq. (5.15) into (4.50) and (4.51) yields the performance coefficients for a reversible
refrigeration and a reversible heat pump respectively as,
T
1 T
r hp 0 hp r 1 (5.18)
T T
1 1
T0
T0
Similar to reversible heat engine, the coefficient of performance COP of a reversible refrig-
eration cycle is independent from the properties of the working fluid. Equation (5.18) provides the
maximum value of the coefficient of performance of a refrigeration system operating between specified
low and high temperature reservoirs. In Figure 5.16, again Carnot cycle is exemplified as a reversible
refrigeration cycle and the cycle components are illustrated.
Example 5.11: As shown in Figure 5.17, a reversible heat engine running between the thermal reservoirs at 227C and
27C supplies work to a reversible refrigeration system that cools down a space at -50C and rejects heat to an environment
/ Q .
at 27C. Evaluate Q1 2
Solution:
T
In regard to Eq. (5.16), the work output of the reversible heat engine is, Whe Q1 1 0 , and the amount of work consumed
T1
T0
1
T Q T
by the reversible refrigeration is, Whe Q1 1 0 . Since, W he W r , The heat ratio becomes, 1 2
T1 Q 2 T
1 0
T1
Q 1
Substituting the temperature values as, T1 = 500K, T0 = 300K, T2 = 223K, into above relation yields, 0.862 .
Q 2
178 THERMODYNAMICS
Example 5.12: As shown in Figure 5.18, a reversible heat pump is to be used for heating a farm house. To keep the inside
temperature at 22C, the required heat supply for an outside temperature of 2C is determined to be 12x104 kJ/h. The com-
pressor of the heat pump is rated as 10 kW.
a. Calculate the number of hours that the heat pump works on one day period.
b. Instead, the heating of the farm house could be done by electric heaters. Determine, on daily basis, the useful energy
conserved by using the heat pump
Solution:
a. For this particular case, the high and the low temperature
reservoirs are the farm house (T = 295K), and the sur-
roundings (T0 = 275K) respectively. The amount of heat
supplied by the reversible heat pump is,
W hp
Q , Q 10 147.5 kW . The heat loss of the
T0 275
1 1
T 295
120000
house is, Q h 33.3 kW
3600
The electrical energy daily consumed by the heater is, Eh 33.3 24 799.2 kWh
Instead of heating by electrical heaters, the use of heat pump saves up to (799.2 - 54.18) = 745.02 kWh of electrical energy.
Example 5.13: Heating of a convention center in winter has to be done by warm air heated by a heat pump. The total heat
loss of the center to outside air is 200kW. As shown in Figure 5.19, the indoors air is circulated through a heat exchanger.
The atmospheric air is at 100kPa and -15C of temperature.
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 179
Determine,
a. The amount of heat supplied by the heat pump,
b. The mass flow of air flowing through the heat ex-
changer,
c. The power consumption of the heat pump,
d. The coefficient of performance of the heat pump.
Solution:
a. The amount of heat supplied by the heat pump to warm
air equals to the amount lost by the center, Q = 200kW.
b. In terms of the inlet and the outlet enthalpies, the heat
supplied to warm air is, Q m p ( Ti Te ) ,
a ( hi he ) mc
200
a
m 19.9 kg / s
1.005( 30 20)
c. The amount of heat extracted from the environment is,
Q 0 Q dT
or Q 0 m a c pT0 Q0 m a c pT0lnT
T0 T T
Q 0 17316
. kW . Then the power consumption of the heat pump is, W hp Q Q 0 , W hp 200 17316
. 26.84 kW
This result also represents the minimum work required to accomplish the heating task.
d. The coefficient of performance of the pump is,
Q 200
hp hp 7.45 . This value of the coefficient of performance is the highest attainable under given condi-
Whp 26.84
tions.
Example 5.14: A heat pump is used for heating a greenhouse in winter and cooling in summer. Inside temperature of the
greenhouse has to be kept constant at 20C throughout the year. Heat leaks through the outside walls and ceiling of the
house. The heat leaking rate is 2000 kilo Joules per hour per 1C temperature difference (2000kJ/hC).
For a period of one day, in winter, the temperature of the environment varies as, T ( K ) 273 10 Sin t , calculate daily
0
energy consumption of the heat pump. 12
a. Calculate the average coefficient of performance on daily basis.
b. By switching to cooling mode, the same device with the same amount of work input at the compressor is used for cool-
ing purposes in summer. Determine the maximum value of the outside temperature.
c. Calculate the average coefficient of performance of refrigeration on daily basis.
Solution:
The temperature difference between inside and outside is T Ti T0 , or T 20 10Sint / 12 and the rate of heat
leaking from the green house is Q 2000 x 20 10Sin t / 12 . Then, for a reversible heat pump, the rate of heat taken from
T 2000
the surroundings ( Q 0 ) is Q 0 0 Q , Q 0 x 20 10 Sin( t / 12)x 20 10 Sin( t / 12) . For a period of 24 hours,
Ti 293
the total amount of heat supplied to the greenhouse and taken from the surroundings respectively are,
24 24
Q
0
960000 kJ
Qdt Q0
Q dt 886279 kJ
0
0
Daily energy consumption of the heat pump becomes Whp Q Q0 , Whp 960000 886279 73721 kJ
Q 960000
b. Daily average value of the performance coefficient is, hp , hp 13
Whp 73721
180 THERMODYNAMICS
c. For the case of running the same system in refrigeration mode, the amount of heat leaking per day is,
Q 48000(T0 293) kJ/day and energy consumption of the compressor is still the same Wr = 73721 kJ/day. Then the
amount of heat rejected to surroundings becomes, Q0 = 48000(T0 – 293) + 73721 kJ/day. Since the system performs revers-
48000( T0 293 48000( T0 293) 73721
ible cycles, , the solution of this equation yields, T0 = 314K.
293 T0
d. For surroundings at T0 = 314K, and the greenhouse at T = 293K, the amount of heat to be extracted from the house per
day is Q 48000(314 293) 1008000 kj/day kj/day, and Wr =73721 kJ/day. Then, in refrigeration mode, the daily
average coefficient of performance is, Q r
1008000
r 13.6
Wr 73721
The Example problems given above are illustrative in the sense that explains how much of heat en-
ergy at the upper most limit can be converted into useful work or how a certain amount of work can
be utilized in the most advantageous way so that the maximum heat energy can be transferred from
a low temperature medium to a higher one.
An actual heat engine is less efficient than a reversible one operating between the same two thermal
energy reservoirs. Similarly an actual refrigerator or a heat pump has a lower coefficient of performance
than a reversible one operated at the same conditions. As stated by Eq. (5.15), for a reversible heat
engine, Qo , is the minimum amount of heat that is rejected to the low temperature reservoir. Since
T1 and To are the same for an actual cycle, and (Q0 ) actual (Q0 ) rev , then Eq. (5.15) becomes,
Q1 Q0
(5.19)
T1 T0 actual
T
Q Q 1 0 (5.20)
T
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 181
As indicated by the diagram in Figure 5.20, in order to convert the maximum possible portion of
heat energy into work, it must be processed through a reversible system.
For the case of simultaneous transfer of heat from isothermal surfaces at different temperatures,
the total exergy transferred to the system becomes,
n
T
Q 1 0 Q j (5.21)
j 1 Tj
Solution:
a. Taking the rod as a system, the transfer of heat occurs at surface of 1 and 2 respectively. With respect to Eq. (5.19)
then,
T T 300 300 ,
Q Q1 1 0 Q 2 1 0 . Where Q 2 Q 1 500kj / h . Substitution yields, Q 500 1 500 1
T1 T2 500 350
Q 128.58kj / h
b. Since the concrete rod is at steady state, there will be no accumulation of exergy in the system. There is no exergy transfer
to or from the system other than the transfer of exergy by heat. The exergy equation (Eq. (5.6)) for this particular case
becomes. Then the irreversibility rate of the process is,
I 128.58 kj/h
Q
Even though the rate of exergy supplied to the concrete rod is 200 kJ/h, the exergy available at the
exit of the rod is 71.42 kJ/h. Due to the temperature difference between the two ends of the rod, an
exergy loss takes place. If there was no thermal friction, both ends would be at the same temperature
for transferring the same amount of heat. Hence, there wouldn’t be any loss of exergy.
Example 5.16: A blender is on when the blades are in a fluid at 97C and transfers work to the fluid at a rate of 360kj/h.
As shown in Figure 5.22, the bowl containing the fluid is laterally insulated and transfers heat to surroundings at 27C from
the bottom surface at a rate of 360 kJ/h. Calculate,
a. the rate of net energy supplied to the system,
b. the rate of exergy accumulation of the system,
c. the rate of irreversibility of this process.
182 THERMODYNAMICS
Solution:
a. The rate of work and heat transfers respectively are
5.8 Entropy
In previous sections, we have studied the exergy balance of a system for a particular process, and
discussed the factors that might cause an exergy loss. In this section, a system property, which is an
important parameter in evaluating the exergy of a system at an instant of time t , is introduced.
As shown in Fig. (5.23), a piston-cylinder device placed in an environment at po , To contains
gas at an initial state of p1 , T1 and reaches to a final state of p2 , T2 by a reversible process. In
accord with Eq. (5.6), the rate of exergy change of the system becomes,
or 1 T0 Q W p V
Q W T
0 (5.22)
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 183
d E p0V dE dV
T p (5.23)
dt T0 dt dt
Since the right hand side of Eq. (5.23) is completely related to the system properties (energy,
pressure, and volume), the left hand side must also be a property of the system. After all, E, V, and
are all properties of the system and (p0, T0) are constants of the environment. Hence the combina-
( E p0V )
tion of these properties in the form of must also be a property of the system. Such a
T0
definition of property is called the entropy of the system. Thus the entropy of a system at an instant
of time t is expressed as,
E p0V
S (5.24)
T0
For a stationary system, the energy of the system, E, equals to the internal energy . Modifying
Eq. (5.24) accordingly and substituting into Eq. (5.23) yields,
dS dU dV
T p (5.25a)
dt dt dt
or
TdS dU pdV (5.25b)
This is called fundamental equation of thermodynamics or the first TdS equation, and evalu-
ates the rate of change of the system entropy with respect to other properties like u, p, v, and T of
the system. Since the enthalpy of the system is defined as H = U + pV, then the derivative of internal
dU dH dV dp
energy with respect to time becomes, p V . Thus, Eq. (5.25a) can be modified
dt dt dt dt
accordingly to yield,
dS dH dp
T V (5.26a)
dt dt dt
or
TdS dH Vdp (5.26b)
This is the second TdS equation and relates the entropy to H , V , p, and T of the system. Even,
though both equations (5.25) and (5.26) are derived for reversible processes, they are equally ap-
plicable to irreversible processes with the same end states. A close examination of both expressions
reveals that they both contain terms which are properties, and computing the change of a property
is not related to the type of the process, depends only on the end states. Thus, both equations can be
used in evaluating the entropy change at a particular process.
184 THERMODYNAMICS
dU 2 2 p
S 2 S1
1 T
1 T
dV
2 dH 2V
(5.27)
S 2 S1
1 T
1 T
dp
Entropy change of solids and liquids. The following assumptions are usually made in evaluating
the entropy change of solids and liquids:
a. The internal energy and the enthalpy of solids and liquids are usually strong function of tem-
perature. The effect of the pressure or the volume change can be neglected.
b. For liquids and especially for solids, specific volume at a particular state assumes such a
small value that the “pv” term in enthalpy formulation can be neglected; h~u. In addition, the
change in volume due to change in temperature is so small that such a change can be neglected;
dv~0.
In accord with the above stated assumptions, Eq. (5.27) can be simplified as,
2 dT
s2 s1
1
c
T
(5.28)
Instead of temperature variation of the specific heat , defining an average value for a particular
liquid or solid transforms Eq. (5.28) into,
T2
s2 s1 c0 ln (5.29)
T1
Entropy change of ideal gases. Recalling that the internal energy and the enthalpy change of an
ideal gas respectively are du = cvdT, dh = cpdT. Together with the equation of state, substituting these
relations into Eq. (5.27) and rearranging yields,
T2 v
s2 s1 cv 0ln Rln 2
T1 v1
(5.30)
T p
s2 s1 c p 0ln 2 Rln 2
T1 p1
The above set of equations reveals that s = f1(T, v) or s = f2(p, v). Entropy can also be described
in the following form of s = f3(p, v) by substituting (p2/p1)(v2/v1) for T2/T1 in Eq. (5.30).
v2 p
s2 s1 c p 0ln cv 0ln 2 (5.31)
v1 p1
Entropy change of a system with two-phase in equilibrium. For saturated states, the system pres-
sure and the temperature are not independent properties. If the temperature stays constant then the
pressure is constant and Eq. (5.27) reduces to
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 185
hg h f h hf
sg s f or s sf (5.32)
T T
In addition, substituting the enthalpy of a saturated state as h = hf + xhfg into Eq. (5.32) results as,
s s f x( s g s f ) (5.33)
This relation can be used in evaluating the entropy of liquid-vapor or solid-liquid mixtures.
E p V T S
(5.34)
0 0
This result can also be used in evaluating the exergy transfer by pure convection.
i i , however, the
In evaluating the rate of exergy transferred into the system by a fluid stream, m
exergy transfer by work has to be taken into account. Pressing the matter at the inlet by a pressure
difference of pi p0 requires the following amount of work to be done on the system,
The total rate of convective exergy transfer into the system is the sum of the exergy transferred by
pure convection, Eq. (5.35), and the work of compression, Eq. (5.36). Hence, the convective exergy
transfer of a fluid stream can be formulated as,
m m h h T s s ke pe
i i i i 0 0 i 0 i i (5.37)
Similarly, the rate of exergy transferred by the system in convective mode to a fluid stream is,
m m h
e e e e h0 T0 se s0 kee pee (5.38)
Together with the exergy transfer by heat and by work Eq. (5.6) can be expressed in the follow-
ing general form,
E p0V T0 S
cv m h h T s s ke pe m h
i i 0 0 i 0 i i e e h0 T0 se s0 kee pee
n T0
+ 1 T Q j W p0V I (5.39)
j 1 j
186 THERMODYNAMICS
In addition to the measures described in section (4.10), the following steps have to be considered
in exergy analysis of systems:
1. For closed systems, mass analysis is not a factor. However, since the exergy equation contains
terms like, Q j , and W , then the exergy and the energy equations have to be solved simultaneously.
Besides, depending upon the number of unknowns of the problem, additional relations may be devised
by utilizing the property relations of the system.
2. For control volume applications, together with property relations and specifics of that particular
process, three equations, mass, energy and exergy have to be solved simultaneously. Particularly, for
steady flow systems, due to irreversibilities of the system, I , the relations are not system free.
Example 5.17: Consider universe as an isolated system, and analyze the variation of energy and of the exergy content with
respect to processes occurring in it.
Solution:
Wdt
change is, E2 E1 Qdt
t
. For an isolated
t
n T0
2 1 1 T
j 1
Q12 j W p0V 12 I12
j
(5.40)
Consider a stationary system, i.e. ep=ek=0, with respect to Eq. (5.34), the exergy change be-
comes,
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 187
2 1 (U 2 U1 ) p0 (V2 V1 ) T0 ( S2 S1 ) (5.41)
Example 5.18: Air is contained in a tank of 0.4m3 at a pressure and temperature of 400kpa, 300K respectively. Deter-
mine,
a. the maximum useful work that can be obtained.
b. the exergy change of air upon doubling its volume by a reversible and adiabatic process.
c. the exergy change of air upon doubling its volume by a reversible and isothermal process.
Assume p0=101kpa, T0=300K.
Solution:
pV 400 x0.4
a. The mass of air in the container, m , m = 1.858 kg
RT 0.287 x300
v1 = 0.4/1.858 = 0.215m3/kg, v0 = 0.287 × 300/101=0.852 m3/kg, s1-s0 = -0.287ln(400/101) = -0.395 kJ/kgK. Since the initial
and the final temperatures are the same and for an ideal gas, u1-u0=0. Hence by Eq. (5.42),
1 1.858 x 0 101x 0.215 0.852 300 x 0.395 1 100.634 kJ. This is the maximum amount of energy that
can be extracted until the system attains mutual equilibrium with its environment.
k
V
b. Since the process is reversible and adiabatic, I12 = 0, Q12 = 0, V2 = 0.8m , and p2 p1 1 151.57
3
V2
400 x0.4 151.57 x0.8
kPa, and the work done due to expansion, W12 , W12=96.86kj. The exergy change of the system by
0.4
Eq. (5.40) is:
2 1 98.86 101x0.4 =-56.46 kJ. This is the amount of exergy decrease in air due to adiabatic expansion.
c. For a reversible and isothermal process, Q12 0, but Tj=T0, hence there is no exergy change due to heat transfer.
For a reversible process, I12=0, and W12=p1V1ln(V2/V1), W12=110.885 kJ. Substituting these results into Eq. (5.40) yields,
0 110.885 101x0.4 0 , 70.485 kJ. Decrease in exergy for isothermal process is bigger. However, for
none of the processes, exergy decrease can be greater than the exergy value of the system at the initial state.
Example 5.19: Referring to the Example problem (4.14) and Figure 4.23, for the same change of state of the gas, deter-
mine:
a. The exergy change of the gas
b. The total exergy transfer by work
c. The irreversibility of the process
The surroundings is at p0 = 100kPa, T0 = 25C.
Solution:
a. Considering the results obtained by the solution of Example (4.14), m 0.8 kg, U 216 kJ, V=0.75 m3 ,
Example 5.20: An insulated room of a dormitory is at 2.5mx3mx4m of dimensions and contains air at p1=100kPa, T1=25C.
The student, being in hurry for his thermo exam, leaves the 50W-fan on and the fan runs for 8 hours. Determine the loss of
exergy for such a case.
Solution:
p1V1 100 x30
The mass of air in the room, m 35.07 kg
RT1 0.287 x 298
The room final temperature, 1 st law of thermodynamics applied to the room, U W12 , W 12 =-50-
x8x3600=-1440kJ. Thus, 35.07 x 0.781x (T2 25) ( 1440), T2 77.5 C The final pressure, p 2/T 2=p 1/T 1,
100
p2 x 350.5 , p2=117.6kPa and the entropy change of the room
298
Example 5.21: An elastic and spherical tank contains 2 kg of refrigerant R134a at 0C with 30% vapor quality. It has been
stated that the inside pressure varies linearly with the diameter of the tank. The refrigerant reaches a thermal equilibrium
with the surroundings at 25C, determine,
a. The exergy loss of the system
b. The reveresible work that could be obtained by the heating process
Solution:
a. Since the diameter of the sphere is proportional to 1/3-power of its volume, pV relationship of the heating process becomes,
pV 1/3 C . Using the R134a tables for T1 = 0C, and x1 = 0.3, p1 = 0.294 MPa, v1 = 0.0213 m3/kg, and the constant C
of the proposed relation is 1.06. In addition to this relationship taking into consideration the super heated vapor data, the
pressure and the volume at the final state becomes p2=0.4MPa, v2=0.0543 m3/kg. The work done by the elastic tank is
p V p1V1
W12 2 2 23.186 kJ and the internal energies at both states are u1=253.24 kJ7kg, u2=392.25 kJ/kg. The total
1 n
changes in the internal energy, the entropy and the volume are, U 278.02 kJ , S=1.082 kJ/K, V 0.066 m3 .
Thus the overall exergy change of the system becomes, 278.02 6.6 293 x1.082 32.406 kJ . Since at the
boundary of the system, Tj=To, then Q 0, and W W12 po V 16.586 kJ .
Substitution of the above evaluated parameters into exergy relation provides the wasted energy of the process.
32.406 0 (16.586) I12 , or I12=15.82 kJ.
b. To determine the amount of reversible work that could be obtained by this process, let I12=0 and substitute
Q 0, W Wrev 6.6, and -32.406 into exergy relation (Eq. 5.40) yields, 32.406 0 (Wrev 6.6) or
Wrev=39.006kJ.
In fact, the amount of reversible work just figured out is identical with the sum of the actual work W12 and irrevers-
ibility I12 of the process.
X Q X W m m
e
e e
i
i i I (5.44)
1
(h h0 ) T0 ( s s0 ) V 2 gz (5.45)
2
If the steady flow system under study is a single inlet and outlet system with negligible kinetic
and potential exergy changes, then Eq. (5.44) reduces to
Since the system has a single inlet and outlet, the mass flow rate at the inlet and the exit are the same.
In Eq. (5.46) xQ X Q / m and xW X W / m represent respectively the exergy transfer by heat and
work per kg of flowing fluid.
The following sample problems illustrate the use of these results for various engineering applica-
tions.
Example 5.22: Determine the maximum power that can be obtained from a hydroelectric power station located at the foot
of a 450m dam as shown in Figure 5.28. Water with a mass flow rate of 1500 kg/s enters the discharge pipe at 100 kPa, and
20C and flows downward. Assume that the pipe diameter is constant throughout and the water pressure and temperature
at the outlet is the same as at the inlet. The surroundings is again at 100 kPa, and 20C.
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 191
Solution:
a. The flow exergy of water at state1 has to be calculated by Eq. (5.45). Since flowing water is at the temperature and pres-
sure of surroundings, h1 h0 0, s1 s0 0 , and being stationary, V=0. Then, 1 gz1 9.81x 450 / 1000
=4.414 kJ/kg. To get the maximum work, the process must be reversible, in Eq. (5.44), I 0 . Since there is no
1
heat transfer, Q 0, X Q 0 . Finally, Eq. (5.44) reduces to X W m 1 , or X W 1500 x 4.414 6621 kW,
Example 5.23: As shown in Fig. 5.29, for a regenerative thermal power plant, steam is extracted and enters the feed water
heater at (1MPa, 200C) with a flow rate of 0.5 kg/s, and leaves the heater as saturated liquid at the same pressure. Likewise,
the feed water enters the heater at (2.5MPa, 50C), and is heated to a temperature 10C below the exit temperature of the
steam. Neglect the heat loss at the outer surface of the exchanger and determine,
a. The flow rate of feed water
b. The exergy loss of the process.
Solution:
a. The energy balance on the heater yields, m s (h1 h2 ) m w (h4 h3 ) For T 2=180C, T 3=50C, T 4=170C, and
h1-h2=2065.09 kJ/kg, h4-h3=504 kJ/kg, the above stated energy equation yields the mass flow rate of steam,
ms=2.048 kg/s.
b. Together with the energy balance, assuming that the change in kinetic and potential energies of both fluids are
negligible and substituting X Q 0, X 0 in Eq. (5.44) results as, I T m ( s s ) m ( s s ) ,
W 0 s 2 1 w 4 3
s2-s1=-4.556 kJ/kgK, s4-s3=cln(T4/T3)=1.326kJ/kgK, and the irreversibility rate for surroundings at 25C becomes,
I 298 x 0.5(4.556) 2.048(1.326) 130.4kW , the exergy loss is then, destroyed 130.4 kW.
Example 5.24: Liquid water (200 kPa, 20C) at a flow rate of 2.5 kg/s is mixed with steam (200 kPa, 300C) in a mixing
chamber as shown in Fig. 5.30, and the chamber loses heat at a rate of 600 kJ per minute to surroundings at 25C. Water
leaves the chamber at (200 kPa, 60C). Determine,
a. The mass flow rate of steam,
192 THERMODYNAMICS
Solution:
a. Together with the continuity relation, the energy balance for the chamber yields, Q m 1 (h3 h1 ) m 2 (h3 h2 ) . For
h3-h1=168 kJ/kg, h3-h2=-2819.8 kJ/kg, Q =-10 kW, and m 1 =2.5 kg/s, then m 2 =0.152 kg/s.
b. Considering that X Q 0, X W 0 and T j T0 , the exergy equation (Eq. 5.44) for this particular application
turn out to be, I m 1 (h1 h3 ) m 2 (h2 h3 ) T0 m 1 ( s1 s3 ) m 2 ( s2 s3 ) , where s2-s3=7.0615 kJ/kgK, s1-s3=cLn
(T /T )=-0.537 kJ/kgK. Then I 90.207 kW.
1 3
Due to mixing of two fluids at different temperature (highly irreversible process), a useful energy at maximum value
of 90.207 kW becomes unavailable. In other words, this amount of exergy is lost.
c. For two streams entering the mixer, the exergy supply rate is X supplied 1 2 , and
For stream 1, 1 m 1 h1 h0 T0 s1 s0 2.5 x 83.96 104.89 298 x 0.2966 0.3674 , 1 0.345kW.
For stream 2, 2 m 2 h2 h0 T0 s2 s0 0.152 x 3071.8 104.89 298 x 7.892 0.3674 , 2 110.136
kW.
I
The exergy supplied, X supplied 110.481 kW. Finally, percent of exergy destruction becomes, X dest % x100%
X supplied
or X dest 81.69 %.
The process is highly irreversible. Essentially two factors contribute to the irreversibility of the process.
1. Heat transfer through the mixing chamber. The chamber should be insulated and heat leaks should be reduced as much
as possible.
2. Work can be extracted from two streams separately for best performance and then the fluids can be mixed for the lowest
exergy destruction.
Example 5.25: The combustion gas products flow at a speed of 80 m/s through the nozzle of a turbo-jet engine at (260 kPa,
747C), and exits at (70 kPa, 500C). For a surroundings temperature of 17C, determine,
a. The gas speed at the nozzle exit
b. The rate of exergy decrease of the gas for a flow rate of 0.1 kg/s.
Assume cp=1.15 kJ/kgK, and k=1.3 for the expanding gas.
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 193
Solution:
a. With no heat and work transfer at the boundaries of the nozzle, the steady state energy equation for this particular case
V2 V2
becomes, h1 1 h2 2 , and for the given data the gas velocity at the nozzle exit is, V2=757.9m/s.
2 2
b. The exergy equation (Eq. 5.44) takes the following form for this particular application,
1
I m (h1 h2 ) (V12 V22 ) T0 m ( s1 s2 ) and I m T0 ( s1 s2 ) . Assuming ideal gas behavior, the entropy change
2
k 1
can be calculated by Eq. 5.28, and the gas constant, R c p , can be used. The rate of exergy decrease due to friction
k
and mixing of fluid particles becomes, I 0.841 kW.
Example 5.26: Steam enters to an adiabatic turbine at (6 MPa, 600C) with a velocity of 80m/s and exits at (50 kPa, 100C)
and the speed at the exit is 140 m/s. For ambient conditions of 100 kPa, 25C, the turbine shaft power is measured to be 5
MW. Determine the rate of exergy loss in the turbine.
Solution:
The following simplifications can be done on exergy equation (Eq. 5.41) for this particular case, Q 0, W 5MW
1
and also recall that for steady flow systems the shaft work is expressed as, W m (h1 h2 ) (V12 V22 ) W . Thus the
2
exergy relation, Eq.5.44, is reduced to I m T ( s s ) , where the mass flow rate is calculated by the above expression as,
0 1 2
m 5.15 kg/s. Then for s = 0.527 kJ/kgK, T0 = 298K, the exergy loss is destroyed 810.04 kW.
194 THERMODYNAMICS
Similarly, for energy conversion machines, the energy based efficiency would be,
energy output
e (5.47)
energy supplied
Unfortunately, the energy based efficiency is not a useful parameter in energy management. Due
to absence of comparison with the ideal process, this definition of efficiency makes no reference to
the performance of the system. An engineer would have no idea how well or how poor the device
performs for that particular process.
Example 5.27: Feed water with 3kg/s mass flow rate enters to a power plant boiler, as shown in Figure 5.33, at 10 bar,
50°C, and exits as saturated vapor at the same pressure. The boiler consumes 0.22 kg/s natural gas with lower heating value,
Hu=42000 kJ/kg. Determine the energy based efficiency of the boiler.
Solution:
Referring to Eq. (4.63), the energy out may be calculated as, Q out m s (h2 h1 ) 3 x(2778.1 209.33) , Q out = 7706.31kW.
The energy supplied by combustion of fuel, Q m H 0.22 x 42000 , Q = 9240kW. Hence by Eq. (5.47), the energy
in f u in
This Example illustrates only that the present design of the boiler allows 83.4% of the energy supplied
by the burner is transferred to water. Is this a good performance? What if heat leaks through the boiler
walls were reduced by better insulation and if the exit temperature of stack gases were reduced to the
temperature of surroundings, then the boiler efficiency will approach to unity, i.e. e 1 . This simply
indicates the proper supply of heat energy to the product. On this basis, however, do you think that
the performance of the boiler becomes the best?
The use of energy based efficiency in assessing and improving the energy conversion systems is mislead-
ing and mostly confusing. The reduction of energy losses of a process can clearly be identified by exergy
analysis. Exergy plays an important role in increasing the efficiencies of energy systems. Because the
location, the type, and the magnitude of wastes and loses can be quantified by exergy analysis. Accord-
ingly, more meaningful efficiencies are evaluated with exergy rather than energy analysis.
Definition: The exergetic efficiency or “second law efficiency“ of a system is the ratio of exergy
recovered through a process or a cycle to the exergy supplied.
In Eq. (5.48), the exergy supplied indicates the amount of maximum useful energy supplied to the
system, and the exergy recovered is the amount of maximum useful energy left after the process
through the device. Since exergetic efficiencies are always a measure of the approach to the ideal
process or the ideal cycle, the exergy analysis also identifies the margin available to design more
efficient energy systems by reducing inefficiencies.
Example 5.28: Determine the exergetic efficiency, x , of the power plant boiler in Figure 5.34, operating at the same
conditions as given in Example 5.27.
Solution:
Referring to Figure 5.34, the energy balance for the boiler requires that Q in Q e Q out 0 . Then the heat energy removed
by stack gases is Q e 9240 (7706.31) or Q = -1533.69 kW.
e T T
Since the boiler operates at steady state, the exergy balance, Eq. (5.44), requires that I 1 0 Qin 1 0 Q e
Ti T0
0
m s h1 h2 T0 s1 s2 or I 4464.528 kW .
196 THERMODYNAMICS
T0 4464.528
The exergy supplied = 1 Qin 6876.828 kW . Hence by Eq. (5.48), x 1 0.35 x = 35 %
Ti 6876.828
As provided by the above example, if one compares the energy based, and the exergy based effi-
ciencies of the same boiler the lower exegetic efficiency for steam production reflects the fact that
fuel is consumed by combustion and only 35-percent of the useful energy is transferred into water.
In addition to the irreversibilities involved in combustion phenomena, the required temperature
difference to transfer the heat against thermal friction caused a reduction in exergy efficiency of
the boiler.
Similar approach can be used to determine the exergy efficiency of industrial furnaces and heat-
ers. The methodology implemented here can be extended for the development of exergy efficiencies
for other components of energy conversion devices. In the following sections, the exergy efficiency
of most common devices is formulated.
I m ( 1 2 ) (5.49)
Since the flow exergy always decreases, this result of efficiency is applicable to both nozzles and
diffusers.
Example 5.29: Determine the exergetic efficiency of the nozzle of Example (5.25). Surroundings at T0=17C, p0=100
kPa.
Solution:
Referring to Figure 5.31, the flow exergy of the gas stream at the inlet, Eq. (5.45), 1 839.5 290 1.15 ln(1020 / 290)
0.2653 ln(260 / 100) 802 / 2000 , 1 497.02 k/kg. Similarly, at the exit,
2 555.45 290 x 1.15 xLn(773 / 290) .2653 xLn(70 / 100) 757.92 / 2000 , 2 488.27 kJ/kg. By Eq.
(5.50), the exergy efficiency of the nozzle is nx 98.2%. The same result could be obtained by using the numerical
value of the irreversibility term, I , of Example (5.25).
(5.51)
Wt m 1 2 I
Exergy destruction
Decrease in the exergy of the
Shaft power
Since the exergy supplied to the turbine is m 1 2 , then the exergy efficiency becomes,
Wt / m w
tx
1 2 wrev (5.52)
Considering the definition of exergy, 1 2 represents the maximum useful work, Wrev, that
could be extracted from the fluid stream at the same inlet and outlet conditions. Hence, as in Eq. (5.52),
two different expressions for the exergetic efficiency of a turbine may be provided.
For a compressor, a pump, or a fan operating at steady state with no heat transfer to surroundings,
and stating, X w Wc in Eq. (5.44), the exergy equation reduces to the following form,
m 2 1 Wc I (5.53)
Since the exergy efficiency is the ratio of the increase in flow exergy to the exergy supplied, then for
adiabatic compressor or a fan the efficiency becomes,
2 1 wrev
cx (5.54)
Wc / m wc
Example 5.30: Determine the exergy efficiency of the adiabatic compressor explained in Example (4.26). Surround-
ings at T0=27C, p0=100kpa.
Solution:
Referring to Figure 4.43, the compressor intakes the air at atmospheric conditions, and compresses it to (500 kPa, 227C).
The air exit velocity is 100 m/s and the mass flow rate is 0.242 kg/s. The shaft power input is given as, Wc 50 kW .
In accord with Eq. (5.45), the exergy change of air stream is,
2 1 1.005 500 300 300 x 1.005 xln 500 / 300 0.287 xln 500 / 100 1002 02 / 2000 , or
2 1 190.559 kJ/kg. The exergy supplied to the compressor is, wc 206.6 kJ/kg, and by Eq. (5.54),
190.559
cx cx 92.2%
206.6
m h 1 2 h m c 4 3 c I (5.53)
Exergy destruction
Decrease in the exergy of the hot Increase in the exergy of the cold
198 THERMODYNAMICS
Considering the fundamental definition, Eq. (5.48), the exergy efficiency of a heat exchanger
becomes,
m ( 3 )c
hx c 4
m h 1 2 h (5.54)
Example 5.31: Water enters the tubes (d=10cm) of an air heater at 0.5 MPa and 140C at a rate of 24 kg /min and leaves
the exchanger at 0.5 MPa and 60C. The cold fluid is air and enters the heat exchanger with a volume flow rate of 100 m3/
min. The velocity of air at the inlet is 25m/s, and inlet conditions are 110 kPa, 25C. The air pressure at the exit is 110 kPa.
If surroundings is at T0=25C, p0=100 kPa, calculate,
a. The exit temperature of air,
b. The efficiency of the exchanger.
Solution:
a. Referring to Figure 5.35, the energy equation for steady state conditions becomes, m w h1 h2 m a c pa T4 T3 .
Assuming ideal gas behavior for air 3 p3 / RT3 110 / 0.287 x 298 1.286 kg/m3 and m a 33 2.147 kg/s.
use Table A3 for water thermodynamic properties, then
0.4 589.13 251.13
T4 T3 62.65 K, T4 = 87.65C
2.147 x1.005
b. Assuming that the change in water velocity is negligible, then the exergy change of water stream becomes,
T4
Assuming that the cross section area of air at the exit is the same as the inlet, 3V3 4V4 or V4 V3 1.21x 25 30.25
m/s T3
The exergy change of air stream is,
m a 4 3 2.147 x 1.005 x 87.65 25 298 x1.005 x ln(360.65 / 298)
1
2000
30.252 252 12.843 kW.
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 199
12.843
To get the efficiency of the exchanger, apply Eq. (5.54), hx 0.476 , hx 47.6%
26.978
This result means that the 52.4% of the useful energy at the inlet of the exchanger is lost, whereas referring to the
energy efficiency, there is no loss, and the energy efficiency of the device is 100-percent which is “NOT TRUE!!”. The
useful energy of hot fluid is not completely transferred to the cold.
m 1 1 3 m 2 3 2 I
(5.55)
Exergy
destruction
Increase in the
Decrease in the exergy of low
exergy of high pressure stream
pressure stream
Together with the relation in Eq. (5.55), the exergy efficiency of a mixing chamber is,
200 THERMODYNAMICS
m 2 3 2
mx (5.56)
m 1 1 3
Example 5.32: An industrial facility vents 5000 kg/h of saturated steam at atmospheric pressure. The wasted steam
can be converted into useful low pressure process steam by boosting its pressure to 2 bar, saturated steam. The avail-
able saturated motive steam is at 15 bar. Assume surroundings is at 27C, and determine,
a. The required mass flow rate of motive steam (kg/s)
b. The efficiency of the thermocompressor under given operating conditions.
Solution:
a. Referring to Figure 5.37, the energy equation at steady state conditions yields the mass flow rate of high pressure
steam as,
b. Together with the tabulated values of steam, the exergy increase of low pressure steam is,
1.389 x101.1
mx 0.963 or mx 96.3%
0.50 x 291.6
The thermo-compressor requires 0.5 kg/s saturated steam at a pressure of 15 bar, to produce a discharge of 1.889
kg/s of 2bar pressure steam, and doing this the efficiency of the thermocompressor is 96.3-percent.
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 201
As shown in Figure 5.38a, after a combustion process, a reservoir of high temperature, T1, is pro-
duced. The exergy of the heat energy, Q1, released by the combustion process is Q1 1 T0 / T1 , and is
identical to the maximum useful work “reversible work” obtainable at these given conditions. Hence
the exergetic efficiency of the heat engine is,
Wnet W
Hx net (5.57)
T Wrev rev
Q1 1 0
T1
Similarly the exergy supplied to the refrigeration system in Figure 5.38b is Wc , and the exergy
recovered may be expressed as,
Reversible
which represents the reversible work obtainable by the heat extracted from the low temperature
environment. Hence the exergy efficiency of the refrigeration system is,
T 1
Q 2 0 1
T
Wrev COPrev COP
Rx 2 (5.59)
Wc Wc 1 COPrev
COP
This result is also applicable to the heat pump applications of refrigeration systems.
The exergy based efficiency is especially useful for devices carrying out a single process. For
instance, a device performing a heat transfer process, there is no way of having any idea about its
performance by simply looking into its energy based efficiency. Because, for all operating conditions,
202 THERMODYNAMICS
the energy based efficiency would be 100-percent. Whereas, the exergy based efficiency signifies
the performance of the device, and depending upon the operating conditions, the device performance
and the exergetic efficiency will alter. In case of cyclic devices, however, why do we need exergy
based efficiency? Is energy based efficiency not sufficient for measuring the performance of the
cycle? The performance of a cyclic device can only be measured by comparing the actual useful work
recovered with the ideal one at the given conditions of the cycle. Two cycles at the same operating
conditions might have the same energy based efficiency but perform differently. An improvement in
performance might not be implemented if an increase in total cost would result. In industry, decisions
are usually made on the basis of total cost.
Example 5.33: Consider two heat engines both of which having the same energy based efficiency of 45-percent. Engine1 oper-
ates between heat reservoirs of 1000K and 300K, and Engine2 between 700K and 300K. Which engine performs better?
Solution:
At a first glance, one might state that since both engines convert the same fraction of heat energy into work, both perform
equally well. However, the performance is measured by comparing the actual useful work output with the ideal one.
Engine 1: The reversible engine efficiency at the given conditions is, rev1 1 300 / 1000 0.7 , 0.45 . Hence
1 0.45
the exergy efficiency becomes, Hx1 0.642
rev1 0.70
Engine 2: Similarly the reversible and the energy based efficiencies are, rev 2 1 300 / 700 0.571, and 0.45 .
2 0.45
The engine exergy efficiency is Hx 2 0.788
rev 2 0.571
Comparison shows that Engine 2 performs better than Engine 1 which means that Engine 2 converts more of available
energy into work than Engine 1.
m w 2 1
Wx (5.61)
We
It is possible to relate the exergy and the energy based efficiencies of liquid heaters by considering
the energy based efficiency definition. Due to heat losses through the outer surface of the heater, the
energy based efficiency may be expressed as,
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 203
Q in
e (5.62)
W e
where, Qin represents the rate of heat transferred to liquid and is,
T2 T1 mc
Q in mc T (5.63)
T
By Eq. (5.45), the exergy increase of liquid is, m 2 1 mc
T T0 ln 1 and together
T1
with eqs. (5.63) and (5.62), substituting this relation into Eq. (5.61) and rearranging results as,
T0 T 1
x / e 1 ln 1 or x / e 1 ln 1 ay (5.64)
T T1 y
where, T1 and T0 are the temperatures of liquid at the inlet and surroundings respectively, and a T0 / T1
and y T / T0 .
The performance behavior of an electric heater for a liquid having surroundings tempera-
ture at the inlet (a=1) is represented in Figure 5.39. In this graph, the energy based efficiency
is taken to be constant and is assumed to be unaffected by the temperature rise range ( T ) of
204 THERMODYNAMICS
liquid which is taken to be between 5°C and 60°C. The typical behavior of these heaters is that
even though the energy based efficiency is close to unity, the exergy based efficiency is only a
small fraction of ηe.
Space heaters deliver heat by radiation or by convection. As shown in Figure 5.41a, radiant heaters
emit heat from a glowing red bar, and directly transfer the heat to people and the objects. They are
appropriate for rooms with high ceilings where it is difficult to retain warm air.
Convective heaters are effective in closed insulated rooms with average ceiling heights. As shown
in Figure 5.41b, the radiant convective heaters combine both radiant and convection effects in space
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 205
heating. For both the electrical resistance and the natural gas fired space heaters, the energy efficiency
is nearly 100-percent and there are almost no energy losses. Yet the exergy efficiency of such devices
is typically less than 10-percent. Indicating that by system improvements it is possible to heat the
same space by consuming only one-tenth of the electricity used at the present.
Example 5.34: A water heater supplies water at 62C. At steady state conditions, the rate of heat input to the heater is
1 kW. Due to heat leaks through the insulation on the outer surface, 2-percent of the energy input is lost to surroundings.
Assuming surroundings temperature at 300K, determine the energy and the exergy based efficiencies of the heater if the
energy is supplied by,
a. an electrical resistance heater
b. an air heat pump with overall COP=4.0
Solution:
a. Electrical resistance heater:
Energy analysis, Qin Wel Ql 0.98 kW, and energy efficiency of the heater,
T 300 0.102
d = Qin 1 0 0.98 x 1 0.1023 kW, Wx 1 x100% Wx 10.2%
T1 335
Exergy analysis, exergy supplied, 1kW, exergy recovered, 3.92 x 1 300 0.4095 kW. The exergy efficiency,
335
0.4095
Wx x100% 40.95% Wx 40.95%
1
or
335
300 COP 3.92
By Eq. (5.18), COP rev 9.568 and by Eq. (5.59),
335 Wx 40.95%
300
1 COP rev 9.568 .
The same result is obtained. The air heat pump is much better than the resistance heater. If daily consumption of hot water
is high, then the use of heat pump for water heating will be a better choice.
206 THERMODYNAMICS
The exergy efficiencies and loses due to exergy destruction describe the system better and provide
more meaningful information. It is actually a measure of how the operation of the system approaches
the ideal or theoretical upper limit. Together with information in system performance, a better under-
standing of factors affecting the efficiency is attained, and efforts to improve the performance can be
better directed. However, efficiency improvements require creativity and engineering, and involve
trade off with other factors such as economics and environmental impact.
References
1. B. R. Bakshi, T. G. Gutowski, and D. P. Sekulic, Thermodynamics and the Destruction of Resources, Cambridge
University Press, ISBN 978-0-521-88455-6, 2011.
2. “Modeling and Computation in Engineering” Editor, Jinrong Zhu, CRC Press, ISBN 978-0-415-61516-7, 2011.
3. I. Dincer, and M. A. Rosen, Exergy, Energy, Environment and Sustaniable Development, Elsevier Publications,
2007.
4. C. P. Kothandaraman, and R. Rudramoorthy, Fluid Mechanics and Machinery, 2nd edition, New age international
publisher, ISBN 978-81-224-2558-1, 2007.
5. Y. A. Cengel, and R. H. Turner, Fundamentals of Thermo-fluid Sciences, McGrawHill Inc., ISBN 978-0-072-97675-6,
2004.
Problems
Exergy balance and closed systems b. the change in exergy of air upon doubling its
volume in reversible adiabatic process,
5.1 A 0.8 m of tank contains air. a. Plot how the total
3
stored energy and total stored exergy of air in the c. the change in the exergy of air upon doubling
tank change as the pressure is increased from 10 kPa its volume in reversible isothermal process
to 10 MPa with temperature held constant at 27°C. d. the change in exergy of air upon doubling its
b. Repeat the plot for the specific stored energy and volume in an adiabatic process with no work.
specific stored exergy. c. Plot how the stored energy
and stored exergy of air in the tank change as the
temperature is increased from -100°C to +100°C
with pressure held constant at 100 kPa. d. Repeat
the plot for the specific stored energy and specific
stored exergy. Assume atmospheric conditions to
be 100 kPa, 27°C
Figure 5.48
Figure 5.49
5.16 Consider the following descriptions of a number of
processes that take place in a closed system which 5.19 15 kg of water is heated in an insulated tank by a
contains 1 kg of water at 180C and 0.7 MPa. The churning process from 300K to 340K. If the surround-
surroundings is at 300K and 1.02bar and there are ing temperature is 300K, find the loss in exergy for
no other reservoirs unless otherwise stated. this process.
1. The volume of the system is doubled at a constant
pressure by heating with the help of a reservoir 5.20 Calculate the unuseable energy in 55 kg of water at
at the lowest temperature allowable to complete 55°C with respect to the surroundings at 5°C. Take
the process. the pressure of water as 1 atmosphere.
2. The volume of the system is doubled at a constant 5.21 2.1 kg of air at 6 bar, 90°C expands adiabatically is
pressure by rapid stirring of the system. a closed system until its volume is doubled and its
3. The volume of the system is doubled in an temperature becomes equal to that of the surround-
adiabatic process. ings which is at 1 bar, 5°C. Determine,
CHAPTER 5 SECOND LAW EXERGY ANALYSIS OF SYSTEMS 209
a. the maximum work obtainable, 5.25 1.2kg of ice at 0°C is mixed with 12 kg of water at
b. the change in exergy of air, 27°C. Find the loss in available energy when the
c. the exergy loss or the irreversibility of the process. system reaches an equilibrium temperature. Assume
Assume for air, cv = 0.718 kJ/kg K, R= 0.287 the temperature of the surroundings as 15°C.
kJ/kg K. Data: The specific heat of water, cp=4.18kJ/kgK, the
5.22 A bicyclist in Figure 5.50 rides the bicycle at a speed specific heat of ice, cp=2.1kJ/kg K and the enthalpy
of 5 m/s. To keep the speed constant, a trust force of of fusion of ice (latent heat), hfs=333.5kJ/kg.
20N has to be created on the pedals. Determine the 5.26 A power cycle operating between two reservoirs
loss in useful energy and discuss where that energy receives energy QHby heat transfer from a hot res-
is gone. ervoir at TH=1100K and rejects energy QC by heat
transfer to a cold reservoir at TC =300K. For
C
each
of the following cases determine whether the cycle
operates reversibly, irreversibly, or is impossible:
a. QH = 800 kJ, Wcycle = 480 kJ,
b. QH = 800 kJ, QC=200 kJ,
c. Wcycle = 800 kJ, QC =200 kJ,
d. η = 50%.
at TH =300K. If QC=1400kJ and Wcycle=140 kJ, the 5.35 Calculate the decrease in exergy when 20 kg of water
cycle operates, at 90°C mixes with 30 kg of water at 30°C, the pres-
a. Reversibly, b.Irreversibly, c.It is impossible sure being taken as constant and the temperature of
the surroundings is 10°C. Take cp of water as 4.18
kJ/kg K.
5.36 As shown in Figure 5.53, a flywheel whose moment
of inertia is 0.75 kg m2 rotates at a speed 3200 r.p.m.
in a large heat insulated system, the temperature of
which is 20°C. If the kinetic energy of the flywheel
is dissipated as frictional heat at the shaft bearings
which have heat capacity of (mc)b =10 kJ/K. Cal-
culate,
a. the rise in the temperature of the bearings when
the flywheel has come to rest,
b. the greatest possible amount of the above heat
which may be returned to the flywheel as high-
Figure 5.52 Cross section of a steam actuator
grade energy,
c. the amount of kinetic energy lost,
5.31 A cylinder maintained at 260C by a bath is divided d. the final r.p.m. of the flywheel, if it is set in
by a stopped piston into two parts. Part A contains motion with this available energy
0.01 m3 water at 30 MPa, and part B contains 2.49 m3
of steam at 0.2 kPa (see Figure 5.52). The surround-
ings is at 102 kPa, and 20C. The stopped is removed
and the two parts reach equilibrium. Determine,
a. the final state in the cylinder,
b. the work and heat interaction,
c. the maximum work associated with the pro-
cess.
5.32 A cylindrical rod of length L insulated on its lateral
surface is initially in contact at one end with a wall
at temperature TH and at the other end with a wall
at a lower temperature Tc. The temperature within
the rod initially varies linearly with position x ac-
of 4.2K by means of a container of liquid helium. 5.42 An inventor claims to have developed a device
Since liquid helium is very expensive, $30.0 per liter, requiring no work input or heat transfer, yet able
the most economical scheme for cooling should be to produce at steady state hot and cold air streams
used. You are to make an engineering evaluation of as shown in Figure 5.54. Employing the ideal gas
two proposed schemes: model for air ignoring kinetic and potential energy
1. Assume that the copper block is dropped very effects, evaluate this claim by exergy analysis.
quickly into the liquid helium.
2. Assume that the copper block is lowered slowly
into the container so that helium gas leaving
the container is always in thermal equilibrium
with the copper block. You have to answer the
following questions:
a. How much liquid helium is required by scheme
1?
b. How much liquid helium is required by scheme
2?
c. Is one of the processes reversible? Give some
justification.
d. Determine the exergy loss, if any, in both
schemes.
To aid the solution of the problem the following
data is given. Figure 5.54
Helium; p=1bar, T=4.2K, uf=9.2kJ/kg, ug=24.8kJ/
kg, hf=10kJ/kg, hg=30.9kJ/kg, sf=3.47kJ/kgK,
5.43 Liquid water enters an adiabatic piping system at
sg=8.43kJ/kg, vf=8.01L/kg, vg=59.83 L/kg. Ad-
17°C at a rate of 7.5 kg/s. It is observed that the
ditionally assume that at 1bar pressure, gaseous
water temperature rises by 0.6°C in the pipe due to
helium is ideal at all temperatures above the
friction. If the environment temperature is also 17°C,
normal boiling point.
evaluate the rate of exergy destruction due to flow
Copper; (mc)=0.01 kJ/K
in the pipe.
Steady flow systems 5.44 Air enters a nozzle steadily at 350 kPa, 87°C with a
velocity of 25 m/s and exits at 95 kPa, and 375 m/s.
5.38 Steam at 0.5 MPa, 360oC flows through a 10-cm-
The heat loss from the nozzle to the surroundings
diameter pipe with a velocity of 25 m/s. Determine
at 22°C is estimated to be 3.2 kJ/kg. Determine,
the rate of exergy transported by the flow, what would
a. the temperature of air stream at the nozzle exit
the rate of exergy transported if air instead of steam
were flowing through the pipe? Take atmospheric b. the amount of exergy destroyed per kg of air
conditions as 100 kPa and 25°C.
5.39 At an industrial facility, 3 cm thick and 60 cmx60
cm in dimensions bronze plates (=7000 kg/m3,
cp=0.45 kJ/kgK) are heated from 24°C to 500°C by
passing the plates at a rate of 250 plates/min through
an oven at 700°C. Determine the rate of exergy loss
of this heating process.
5.40 A geothermal source provides 4.5 kg/s of hot water
at 800 kPa, 150°C flowing into an adiabatic flash
evaporator that separates vapor and liquid at 200 kPa. Figure 5.55 Convergent-divergent nozzle
Sketch the problem schematically and determine,
a. the exergy of three fluxes (one inlet and two 5.45 As shown in Figure 5.55, carbon dioxide (CO2) enters
outlets) a nozzle at 2.5bar, 760°C, 75m/s and exits at 0.8bar,
b. the rate of exergy loss for this process 640°C. Assuming the nozzle to be adiabatic and the
5.41 A 2.6 kg/s flow of steam at 15 bar and 640°C should surroundings to be at 1bar and 17°C. Determine,
be brought to 400°C by spraying liquid water at 15 a. the velocity at the nozzle exit,
bar and 27°C. Sketch the problem and determine, b. the drop in useful energy between the inlet and
a. the cold water flow rate the exit.
b. the exergy destruction of the process if the sur- c. What would the exit velocity be if carbon diox-
roundings is at 27°C. ide entered the nozzle at 150m/s and the same
pressure and temperature?
212 THERMODYNAMICS
5.46 Steam expands in an adiabatic turbine from 8 MPa 5.49 Air (ideal gas) enters a compressor operating at steady
and 440°C to a pressure of 50 kPa as saturated vapor. state at 17°C, 1bar and exits at a pressure of 5 bar.
For a steam flow rate of 1.8 kg/s, determine the KE and PE changes can be ignored. If there are no
maximum possible power output of the turbine. internal irreversibilities, evaluate the work and heat
transfer in kJ/kg for an isothermal compression.
5.47 In a turbine as shown in Figure 5.56, the air expands
from 7 bar, 600°C to 1 bar, 250°C. During expansion
9 kJ/kg of heat is lost to the surroundings which is at
1bar, 15°C. Neglecting kinetic energy and potential
energy changes, and assume air behaves like an ideal
gas with cp=1.005 kJ/kg K, determine per kg of air,
a. the decrease in exergy,
b. the maximum work obtainable,
c. the irreversibility of the process.
Figure 5.58
5.56 Water (cp=4.18 kJ/kgK) at a flow rate of 0.35 kg/s Figure 5.62
is heated from 20C to 60C by flowing through a
heat exchanger. The hot fluid of the exchanger being
geothermal water (cp=4.31 kJ/kgK) is at 165C and
the flow rate is 0.28 kg/s at the inlet. The heated water
Efficiency of systems
passes through the tubes of 10 mm diameter with a 5.58 As shown in Figure 5.63, 0.08 kg of steam initially at
velocity of 0.5 m/s. Neglect the tube thickness, and 1MPa, 240C in a piston-cylinder device expands to
determine, 300 kPa, 160C by doing work and releases 3 kJ of
a. the number of tubes, heat to surroundings at 100 kPa, 27C. Determine,
b. the exergy loss rate due to heat exchange process a. the exergy values at the initial and the final
in the exchanger. states
214 THERMODYNAMICS
b. the reversible work obtainable from steam c. the average overall heat transfer coefficient in
between the end states W/m2K.
c. the irreversibility or the exergy loss of the pro-
cess
d. the exergy efficiency of the process
Figure 5.63
5.59 The gear train of car gear transmission system as Figure 5.65
shown in Figure 5.64 operates at steady state. The
gear system runs in lubrication oil and the power 5.61 In a steady flow machine, air having a mass flow
input, and output of the box respectively are 85 kW, rate of 0.5 kg/s enters the system at a pressure of 10
and 81.1 kW. The surface temperature of the box bar and 200°C with a velocity of 100 m/s and leaves
is 37°C. Assume surroundings at a temperature of at 1.5 bar and 27°C with a velocity of 50 m/s. The
27°C and determine, temperature of the surroundings is 27°C and pressure
is 1 bar. Determine,
a. the type of the flow machine
b. the reversible work and the actual work for an
adiabatic process,
c. the irreversibility of the system,
d. the exergy based efficiency of the system.
Take for air : cp =1.005 kJ/kg K, R =0.287 kJ/kg K.
the can is 1.5Mpa. A small hole is made in the can cooled down to +20°C by passing through plate type
allowing air to escape slowly to the atmosphere, of heat exchangers and cold water at +15°C is used
and the pressure reduced to atmospheric pressure. for this purpose. Finally, the milk is refrigerated
The process is carried out slowly enough so that the back +5°C in a cold storage room. To save energy,
temperature of the air in the can is always the same the plant installs a regenerator and preheats the hot
as its environment. Determine, water entering the boiler. The combustion gases
a. the amount of mass escaping the can, are at 820°C, and 1bar pressure (cp = 1.10 kJ/kgK)
b. the heat interaction of the can during the pro- and the temperature drops to T10 = 300°C before
cess, entering the regenerator. The stack gases leave the
c. the exergy destruction of the process. system at T11 = 140 °C. Assume the temperature of
surroundings be at 15°C and evaluate,
5.71 A granite rock of Ephesus (density 2700 kg/m3, a. the fuel consumption rate, take the heating value
specific heat 1.017 kJ/kg.K) with a mass of 3200 of natural gas as Hu = 37800 kJ/kg,
kg heats up to T = 53°C during daytime due to solar b. the combustion gas mass flow rate,
heating. Assuming the surroundings to be at 27°C,
c. the mass flow rate of hot water through the
determine,
circulation pump,
a. the maximum amount of useful work that could
d. the temperature, T4, at the exit of regenerator,
be extracted from the rock,
e. the exergy efficiency of the regenerator
b. what would the answer be in “a” if the rock
temperature was less by 5°C, f. overall exergy loss due to pastuerization pro-
cess
c. what would the answer be in “a” if the ambient
temperature decreased by 5°C?
5.72 The 0.2 m3 tank of Figure 5.70 initially contains
saturated vapor R134a at 28°C. The tank is charged
to 1 MPa pressure, and the refrigerant is in thermal
equilibrium with surroundings at the final state of
28°C. The supply line carries R134a at 1.5 MPa and
30°C. Determine,
a. the heat transfer of the process
b. the wasted work potential.
f. Energy is degraded each time as it flows u. There are processes for which the exergy
through a finite temperature difference. destruction becomes negative.
h. Direct mixing of warm stream with w. An evacuated space has a negative
a cold one would result with higher mixing exergy
temperature than mixing after extracting some
work from warm stream.
Check Test 5
i. The exergy change of a flowing stream Choose the correct answer:
is determined by dh T0 ds .
1. 0.1kg of water at 100 kPa, 2000C can be isothermally
j. Exergetic efficiency of a heat engine compressed in a piston-cylinder arrangement to a
cannot be greater than its thermal efficiency. final volume of 6.1% of the initial volume. Which
one of the following might represent the work done
k. In domestic hot water systems, the on the system in kJ?
exergy destruction may be reduced by using a. 132 b. 145
the discarded water for heating the fresh cold
c. 150 d. 158
water.
l. The maximum work obtainable from a 2. All four engines, operating between temperatures
957°C and 27°C, reject heat at a rate of 400 kW to
non-flow system is h1 h0 T0 s1 s0 low temperature reservoir. The heat rate received
and the work produced by each engine is indicated
m. Exergy based efficiency is for comparing below. Which engine is reversible?
two systems. However, energy based efficiency
measures the performance of a system.
Engine Q H (kW ) Wnet (kW )
n. The actual work which a system does A 1500 1100
is always less than the system exergy change, B 1400 1058
and the difference represents the irreversibility
C 1800 1400
of the process.
D 1600 1200
o. A nozzle with small pressure gradient a. A b. B
is better than a nozzle having large pressure
gradient. Both operate at the same inlet and c. C d. D.
outlet conditions.
3. A 10 g of bullet travelling horizontally with a speed
p. A water heater with two gradual heating of 800 m/s at a height of 30m above the ground is at
tanks consumes less energy than a heater with 200°C and has a specific heat of 0.16 kJ/kgK. For
single tank. p0 100 kPa, T0 270 C , the exergy of the bullet
in kJ is,
q. In comparing two heat exchangers
operating with the same fluids at the same inlet a. 3.261 b. 2.261
conditions, the heat exchanger with larger heat c. 4.261 d. 3.521
transfer surface area performs better.
4. 100 g of ice at 00C is mixed with 1kg of lemonade at
r. When you heat a glass of water you 400C. Assume lemonade has the same properties as
increase its exergy.
water, c p 4.18 kJ/kgK, and the latent heat of ice
s. The exergy of a system is totally inde- is 333.5 kJ/kg. For T0 270 C , the final temperature
pendent of the energy and the entropy of that and the destructed exergy respectively are,
system.
a. 29.10 C 3.9kJ b. 27.10 C 3.9kJ
t. The exergy of a block of ice decreases
as it melts. c. 29.10 C 4.9kJ d. 27.10 C 4.9kJ
218 THERMODYNAMICS
8. The energy based efficiency of an automobile engine a. 302, 70.6 b. 303, 72.6
is 23% and the efficiency of a reversible engine op- c. 304, 71.6 d. 304, 72.6
erating at identical conditions is 62 %. The exergetic
efficiency of this engine is, 11. The temperatures of cold and hot water streams at
a. 34% b. 35% the inlet of a heat exchanger are 1000 C and 200 C
c. 36% d. 37%. respectively. Both fluids having the same mass flow
rate and the same temperature change ( T 400 C ),
9. Same fluids having the same mass flow rate and the exergy based efficiency of the exchanger is,
temperature drop flow through an heat exchanger. a. 33.1% b. 37.1%
The exit temperatures of both hot and cold fluids and
the temperature of the environment respectively are c. 35.1% d. 39.1%
The , Tce , T0 . If the temperature change is T , the
exergy efficiency of the exchanger becomes 12. A water heater, having 10% energy loss through
the insulation, raises the water temperature from
T0 T 0
T1 270 C to T2 47 C . The exergetic efficiency
1 ln 1
T Tce of water heater is,
a.
T T
1 0 ln 1 a. 3.0% b. 2.9%
T The
c. 2.8% d. 2.7%.
C H
6A P T E R
6.1 Introduction
It is clear from the previous chapter that entropy is a useful property and serves as a
valuable tool in exergy analysis of engineering devices. However, we do not exactly know
what the entropy means. Our understanding of entropy will deepen as we continue making
use of it.
When viewed microscopically, entropy is a measure of molecular disorder, and the
entropy of a system increases whenever the molecular randomness or uncertainty of the
system increases. As shown in Figure 6.1a, we know from experiments that a paddle-wheel
inserted into a tank containing a gas at high pressure and temperature will not be rotated.
This is because the gas molecules are disorganized and we cannot extract useful energy
from disorganized molecules. Similarly, in Figure 6.1b, the magnetic field around the un-
magnetized iron is randomly oriented. This randomness is what causes the magnetic field of
each domain to be cancelled out by the magnetic field of another domain. As a result there
is no single northpole or southpole. A bunch of north and south poles cancels each other
strength and no work can be produced.
As shown in Figure 6.2, however, consider the case of organizing the gas particles to
a certain extent by letting it flow through a pipe as in Figure 6.2a, this time, since the mol-
ecules are partially organized to flow in the same direction, it will be possible to extract
some useful energy. After the flow process, however, the energy of the gas is degraded,
and the ability to do work is reduced. Due to increase in molecular disorder an increase in
entropy will be noted. Similarly, as in Figure 6.2b, when the molecules of an iron bar are
realigned, that piece becomes a powerful magnet with a single north and south poles and
creates a magnetic field.
219
220 THERMODYNAMICS
From statistical point of view, entropy indicates the uncertainty about the positions of molecules
at any instant. At high temperatures, even for solids, the molecules oscillate with high frequency and
create relatively large uncertainty about their position. As the temperature decreases, however, these
oscillations fade away, and molecules become motionless at absolute zero. Thus, at absolute zero,
the entropy of a pure substance is zero. This is because there is no uncertainty about the position of
molecules.
A system can only generate, not destroy entropy. This means that the natural direction of a change
in state of a system is from order to disorder. However, energy conversions may proceed in such a
way that the entropy of a system may decrease. Charging a battery, freezing ice cubes, or formation
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 221
of sand dunes in desert are examples entropy reduction processes. In each of these examples, order
has been won from disorder and entropy has decreased. If the system together with its environment
is considered, the total effect is an increase in disorder. In Figure 6.3, you may clearly see that the
sand has ordered itself into ripples which are caused by the wind blowing over the desert. Hence, the
increase in the order of the sand was accompanied by a larger increase in the disorder of the wind and
the overall effect is an increase in the disorder.
As a result, the quantity of energy is always preserved during an actual process but the quality
is bound to decrease. After a process, the system energy becomes disorganized to a certain extend.
Therefore, the concept of entropy, as a measure of disorganized energy, indicates that the energy, the
exergy, and the entropy balances of a system are not independent from each other.
In fact, as shown in Figure 6.4, these three are interrelated. There are cases for which each of these
three properties is free of others. For instance, electrical energy is an entropy free energy. Similarly,
air at atmospheric conditions contains energy but no exergy (dead state). The most systems appear
222 THERMODYNAMICS
at the shaded region in Figure 6.4. Steam used in industrial applications possesses energy, exergy,
and entropy.
Referring to Figure 6.4, the following relation makes possible to evaluate the third one by know-
ing the other two.
Depending upon the system properties, this general statement can be cast into rigorous equations
as described in the following sections.
Q j
E
T
o poV I .
j Tj
Together with the definition of entropy (Eq. 5.24), one may state that the rate of entropy change
for close systems is,
Q j I
S (6.2)
j Tj T0
or expressing in words,
Since there is no work term in Eq. (6.2), the increase in entropy of a system, the increase in the
system disorder, is solely caused by heat transfer. However, if the process is an irreversible one then
the degree of irreversibility is another cause for the entropy production of the system. Thus, for an
adiabatic system, the entropy production of the system results from the irreversibility of the process
and identified as the entropy generation of the system. The entropy generation mathematically ex-
pressed as,
I I
S gen or ( S 2 S1 ) gen 12 (6.4)
T0 T0
For an adiabatic system, the entropy generation of the system is proportional to the irreversibilty
of the process and the constant of proportionality is 1/T0. If a system is adiabatic and the process is
reversible, then Eq. (6.4) reduces to S gen 0 . In other words, a reversible and adiabatic process is
also called constant entropy process or simply “isentropic process”.
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 223
Recall that an isolated system is defined as constant energy system. As a result of Eq. (6.4), one
may also define the isolated system in terms of the system entropy.
Definition: As an isolated system undergoes a process, the system entropy always increases. If the
process is a reversible one then the system entropy is kept constant. Hence, in general, for an isolated
system, one may state that S iso 0 .
The results of Eq. (6.2) should not be misunderstood. For instance, a constant entropy process does
Q j I
not always mean a reversible and adiabatic process. For a process, if then respect to Eq.
j Tj T0
(6.2) the system entropy change becomes zero. However, the system is not adiabatic and the process
Q j I
is not a reversible one. Moreover, for a process, if then the system entropy change
j Tj T0
could be negative. It means the system losing so much heat energy that the uncertainty in molecular
disorder is reduced.
Example 6.1: An ideal gas in a piston-cylinder device changes states through an isentropic process (constant entropy).
Determine the p-V relationship for that gas.
Solution:
Referring to the entropy equation for ideal gases (Eq. 5.28), for an isentropic process, s 2 s1 0 , and the equation trans-
forms into p2 / p1 v v1 / v2 p or p2 / p1 v1 / v2 p
c c c / cv
and considering the definition of the ratio of specific heats as,
k = cp/cv, the equation for the process results as, pv k Constant .
Example 6.2: Drive the isentropic shaft work relation for an incompressible substance flowing through a pipe.
Solution:
The transport of liquids in pipes is of primary importance in numerous engineering designs. A pump may or may not be part
of the control volume, and the pipe may have different diameters at different sections of the flow, or the fluid may undergo
a considerable change in elevation. Considering all these possibilities, and referring to Eq. (4.54), the energy equation is
in the following form,
1 1
(h V 2 gz )e (h V 2 gz )i q w
2 2
For incompressible flow, h u vp and the above equation for shaft work can be modified as,
For a case of fluid having the same temperature as surroundings, or for flow through an insulated pipe, the heat transfer will
be zero ( q 0 ). In addition, due to internally reversible flow process, s 0 , and Eq. (5.27) states that T2 T1 and that
u 0 . Thus the energy equation for isentropic and incompressible process reduces to
Hence the shaft work for an incompressible, frictionless fluid flowing through a pipe is due to change of pressure, velocity
and elevation in general. In case of excluding the pump work from the control volume, the steady flow energy equation
becomes,
V22 V12
vp ke pe 0 or v(p2 p1 ) g( z2 z1 ) 0 Bernoulli’s equation
2
224 THERMODYNAMICS
This is known as the Bernoulli’s equation in fluid mechanics, and is used for energy analysis of isentropic flow of incom-
pressible fluids through pipes and ducts.
Example 6.3: Refrigerant R12 is compressed isentropically from (1bar, x=0.957) to a pressure of 6 bars in a piston-cylinder
device. Determine,
a. the final temperature of the refrigerant
b. the specific work done to the refrigerant
Solution:
Together with Eq. (5.31), the table values of entropy at saturated state yield the initial entropy as s1 = 0.6877 kJ/kgK, and
for isentropic processes s1=s2, p2=6 bar. Hence the temperature at the final state becomes T2 = 22C, saturated vapor state.
Simplifying the energy equation for a closed system with no heat transfer, W12 u2 u1 where u1 u1 f x1u1 fg 151.77
kJ/kgK, and at the final state (p2=6 bar, x2=1.0) u2=179.09kJ/kg. Thus the energy equation yields W112 27.32 kJ/kg.
Solution:
For a system that consists of gears and water in the tank,
energy balance yields, mg u2 u1 g mw u2 u1 w 0 ,
and substitution of numerical values gives the final temperature as, T2=24.713C.
297.713
S g 15 0.465 ln 5.1504 kJ/K, similarly for water,
The entropy change of the gears is 623
297.713
S w 200 4.18 ln 7.616 kJ/K, and the entropy generation of the process is the same as the entropy change
295
of the overall system. Thus, S gen S w S g 2.4390 kJ/K. Then by Eq. 6.4, the irreversibility of the process is
I12 T0 S gen 719.514 kJ.
Q I
Sdt
T
T
0
(6.5)
Together with the definition of a thermodynamic cycle, since entropy is a system property, the
cyclic integral of entropy of the working fluid must be zero; Sdt
0 . For all cyclic processes, the
irreversibility is never negative; I 0 , then, respect to Eq. (6.5), one may conclude that for all
possible cycles the following statement must hold.
Q
T 0 (6.6)
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 225
As stated for a cycle, this relation leads to Clasius inequality which was first described by German
Physicist R.J.E.Clasius in 1870. It is an important criterion in testing the 2nd law appropriateness of
a cycle and as can be deduced from this statement that the cyclic integral of Q/T is always negative
for real cycles. Specifically, for reversible cycles, it assumes the value of zero at the limit.
Example 6.5: A heat engine withdraws 325 kJ of heat energy from high temperature reservoir at 1000K and rejects 125 kJ
of heat to a low temperature reservoir at 400K. The net work output of the engine is claimed to be 200 kJ. Is it possible to
run such an engine at these conditions?
Solution:
For a cycle first law states that Qnet Wnet or 325-125=200 kJ and the engine satisfy the energy balance requirement.
However, Applying Eq. (6.5) to the proposed heat engine yields,
Q Q1 Q001 325 125
T
T1
T0 1000 400
0.0125 kJ/K 0 which tells us that the engine is inappropriate in terms of the second
law and is not possible to run such an engine at engine by these conditions.
Example 6.6: The ice surface of an ice skating ring in İzmir experiences
heat transfer with air in the arena at a rate of Q r 2500T0 Tr kJ/h,
and is to be withdrawn by a heat pump that is used to warm up a close
by facility. The heat loss of the facility is Q 5000T T kJ/h.
h h 0
a. Determine the minimum driving power for the heat pump for
Tr=-12C, Th=21C, and T0=0C.
b. Determine the ambient temperature for which the heat exchange
of the heat pump with the surroundings changes sign.
Solution:
a. First law applied to the refrigeration system yields
Q Q Q W . Assuming a reversible cycle, Clasius
0 r h p
Q Q Q
inequality becomes 0 r h 0 and together with the
T0 Tr Th
energy equation, the compressor work can be expressed as,
T T
W p 1 0 Q h 1 0 Q r . For a reversible cycle, the
Th Tt
minimum amount of work is used at the compressor and equals
to 2.465kW.
226 THERMODYNAMICS
b. At the temperature where the heat exchange between the pump and the surroundings changes sign, the heat transfer
2500(T0 Tr ) 5000(Th T0 )
must be zero, Q 0 0 and together with Clasius inequality, . Substituting numeri-
Tr Th
cal values for Tr and Th, the surroundings temperature may be determined as T0=282K.
Q j
In evaluating the term, , in Eq. (6.2), a system has to have a finite number of isothermal surfaces.
j Tj
For a case of continuous variation of temperature along the system boundary, however, this term has
q
A
T
to be transformed into an integral and expressed as, dA . Hence, in a general format, the rate of
dS q
cv A
dt T dA m s m s
i
i i
e
e e S gen (6.8)
where q (kW/m2) presents the rate of heat transfer per unit surface area of the system. Unlike the exergy
equation (Eq. 5.37), in Eq. (6.8), there is no need for identifying the reference state of the process,
and entropy analysis can be performed without referring to any state of the system.
One may recall that the system energy and the exergy are invariant in time for Steady State Steady
Flow Systems (SSSFS). Since entropy is a system property, likewise the system entropy is invariant
dS
with time for SSSFS. Hence, substituting 0 into Eq. (6.8) and rearranging results as,
dt cv
q
m s T dA m s S
e
e e
i
i i gen
(6.9)
A
If a SSSF system is adiabatic having single inlet and outlet, then Eq. (6.9) may be reduced to the
following form
se si sgen (6.10)
Due to irreversibilities in the flow; friction between surface and particles, and within particles, sgen
is always a positive quantity and hence for SSSF and adiabatic systems with single inlet and outlet,
Eq. (6.10) reveals that se si is true.
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 227
As a consequence, one may state that exergy loss through a process results with entropy gain
through that process. For processes through which the exergy is conserved (reversible processes), the
entropy is also conserved, and does not increase. This is called the principle of entropy increase.
Principle 21: Entropy is a system property. Through all real processes, some
entropy is generated and this generation of entropy is due entirely to the non-con-
servation of exergy.
This principle assists us in identifying the real processes that might exist and the direction through
which these processes may possibly take place.
Example 6.7: As shown in Figure 6.8, the ducting of a ventilation system operating at steady state is well insulated, and
the pressure is very nearly 1atm throughout. Assuming ideal gas model for air with cp=1.005 kj/kgK, and ignoring kinetic
and potential energy effects, determine
a. the temperature of air at the duct exit,
b. the pipe diameter at the exit,
c. the rate of entropy production within the duct in kW/K
Solution:
a. Neglecting the changes in kinetic and potential energies, the energy equation for a control volume around Figure 6.8,
results as, m 1h1 m 2h2 m 3h3 and the conservation of mass yields, m 3 m 1 m 2 . The mass flow rates at the corre-
100 1 1.603 kg/s . Similarly, 2 1.149 kg/m3
sponding sections, m 1 1 ( AV )1 1 = =1.283 kg/m3 and m
0.287 x 283
D2
and m 2 2 V2 . After substituting the numerical values, m 2 4.464 kg/s and m 3 6.067 kg/s . For ideal
4
gases, h=cpT, the energy equation may be expressed in terms of temperatures, and the temperature of air at the
1.603 282 4.464 303
exit becomes, T3 297.7 K
6.067
100
b. Since m 3 3 A3V3 and 3 1.17 kg/m3 , then the diameter of the circular cross section becomes
0.287 297.7
D3 1.73 m .
c. Since the system is at steady state and insulated Eq. (6.9) reduces to S gen m 1 ( s3 s1 ) m 2 ( s3 s2 ) , and using the
entropy relation for ideal gases, Eq. (5.30), the entropy generated through the mixing action is, S gen 2.412 x10 3 kW/K .
228 THERMODYNAMICS
As mentioned previously, the principle of entropy increase, Eq. (6.8), allows us to identify processes
that could never occur, irrespective of the details of the system. A process that violates equation (6.8)
also violates the second law and is obviously impossible. The following Example numerically illus-
trates how to use this principle.
Example 6.8: As shown in Figure 6.9, two entering streams of air mix to form a single exiting stream. A hard to read photo-
copy of the data sheet indicates that the pressure of the exiting stream is either 1.8MPa or 1.3MPa. Stray heat transfer and
kinetic and potential energy are negligible. Assuming the ideal gas behavior for air with cp=1.02 kJ/kgK, determine if either
or both these pressure values can be correct
Solution:
The energy equation, m 1h1 m 2 h2 m 3h3 , yields the exit temperature as, T3 (1.2 900 2.2 500) / 3.4 641.1K . For
steady state conditions, the entropy equation, Eq. (6.8), becomes S gen m 1 ( s3 s1 ) m 2 ( s3 s2 ) . Since the entropy genera-
tion term is always positive, m 1 ( s3 s1 ) m 2 ( s3 s2 ) 0 . Substituting the entropy difference for ideal gases, Eq.(5.30), the
relation for the exit pressure is ln( p30.975 / 1.269) 0.14261, or p3 1.476 Mpa. The correct exit pressure is then 1.3MPa.
p presents the pressure at the moving boundary. For an ideal process, however, the system properties,
like pressure, temperature etc., must be uniform throughout the system. Gradients of any property
should not be allowed. Otherwise, due to internal irreversibility, an exergy loss will take place. As a
2
consequence, the work done due to change of system volume may be represented by pdV , where
1
p must be the system pressure not the pressure at the boundary at any instant of time t. For an ideal
process then the area under the curve in p-V diagram represents pdV type of work of the system. Due
to non-uniformities in thermodynamic properties for an irreversible process, however, the system
work is always be less than the shaded area in Fig. 6.10.
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 229
Figure 6.10 The Ideal mechanical work of the moving boundary is represented by the shaded area.
Similarly, for a reversible change of state, the system should not experience any temperature gradi-
ents, and at an instant of time t, the system temperature must be fixed at a value of T. Hence, for a
Q
reversible process of a closed system, Eq. (6.8) reduces to S . Integrating this relation between
T
the initial and the final states yields,
2
Q12 TdS
1
(6.11)
This relation provides us to calculate the amount of reversible heat transferred through a closed
system and is represented by the shaded area in Fig. 6.11a. Recall that for a non-ideal process, the work
2
transfer of the system is always less than; pdV . Likewise, for an irreversible heat transfer process,
1
2
one may state that the relation between the heat transfer and the entropy variation is Q12 TdS .
1
Up to this section, the pressure, p and the volume, V are used for representing the processes of
the system. Likewise, since T and s are two independent properties of the system, they can also be
utilized in identifying various reversible processes. On this respect, Fig. 6.11b shows isentropic, iso-
choric, isobaric, and isothermal processes. Referring to Eq. (5.28), isochoric and isobaric processes
are logarithmic, and since cp>cv, the slope of isochoric process is greater than isobaric one.
230 THERMODYNAMICS
Figure 6.11 The Ideal heat transfer to a system and T-s presentation of various ideal processes
Example 6.9: As shown in Fig. 6.12, steam enters to an adiabatic turbine at (16 bar, 350C) and outlets at 1bar pressure as
saturated vapor. Determine,
a. if the turbine can run under given conditions,
b. the mass flow rate for a shaft power of 150kW,
c. the mass flow rate if the turbine operates isentropic for the same shaft power.
d. Show both processes on T-s diagram.
Solution:
a. Referring to the steam tables, the entropy at state 1 is s1=7.069kJ/kgK and at state 2, s2=7.359kJ/kgK, and the
results are consistent with Eq. (6.10); s2> s1. Hence, the turbine can run under these conditions.
b. Considering the energy equation (Eq. (4.60)), and h1=3145.4kJ/kg, h2=2675.5kJ/kg, the mass flow rate can be
computed as 0.319kg/s.
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 231
Solution:
a. Assuming that the air behaves like an ideal gas with constant specific heats, then the entropy change of air due to
483 5
compression may be evaluated by Eq. (5.30) as, s2 s1 1.005 ln 0.287 ln , or s 2 s1 0.0243kJ/kgK 0
298 1 .
Thus it is possible that the compressor might work under these conditions.
p T1 T2 s 8.713kW
T2s=471.4K, and the shaft power is, Wrev mc
d. The graphical illustration is given in Fig. 6.15. As shown in the figure, fluid temperature at the outlet of an adiabatic
compressor is larger than the one obtained by isentropic compression to the same pressure.
232 THERMODYNAMICS
Recall that at a saturated state on T-s diagram, the constant pressure curve is horizontal. Unlike
the T-s diagram, the constant pressure lines continue declining even for saturated states. In this graph,
the saturation temperature at a particular pressure can be determined by the intersection of constant
pressure and constant temperature lines at the saturated vapor line.
The measured vertical distance between the predefined states on this diagram presents the enthalpy
change, h, and that means the shaft work of an adiabatic turbine or work consumed by an adiabatic
compressor. In addition, the enthalpy change, h, might mean a kinetic energy change for a flow
through a nozzle, or through a diffuser. The horizontal distance between two specified states on this
graph indicates the entropy generated, ∆s, through an adiabatic flow process.
where, dh q vdp , and the entropy balance relation (Eq. 6.8) for a reversible process becomes
q
ds . Substituting these relations into Eq. (6.12) yield the reversible shaft work of a steady flow
T
machine as,
e
wrev vdp
2
1 2
Vi Ve2 g( zi ze ) (6.13)
i
For a negligible change in kinetic and potential energies, the above relation reduces to
e
wrev vdp (6.14)
i
These relations provide quantitative results if a functional relationship between v and p is known,
and lead to the maximum work output or minimum work input for unit mass flowing steadily and
reversibly through turbines, compressors, and pumps. For a polytropic and reversible compression or
expansion process, pv n Constant , and the integral of Eq. (6.14) yields
n 1
n n p2 n
wrev p2v2 p1v1 p1v1 1 (6.15)
n 1 n 1 p1
Example 6.11: Ammonia at 2.0 bar, -15C enters a compressor with a volumetric flow rate of 0.02 m3/s. The refrigerant is
compressed to a pressure of 10 bar by a reversible process expressed as, pv1.15 Constant . Determine,
Solution:
Since the pressure-volume relation for the compression process is given as, pv n p1v1n , you may use Eq. (6.15)
n
as w ( p2v2 p1v1 ) , and V2 0.02 x(2 / 10)1/1.15 0.00493 m3 /s . Substituting into work expression yields,
1 n
1.15
W (1000 0.00493 200 0.02) 7.13 kW
0.15
Apply 1st law to control volume around the compressor, Q W m (h2 h1 ) , m V1 / v1 0.02/0.605=0.033 kg/s , then
v2 0.605 x(0.0049 / 0.012) 0.148 m3/kg, and from Ammonia table h2=1549.4kj/kg. Substituting the results into energy
equation yields, Q 7.13
7.13 0.033 (1549.4 1428.51) 3.14 kW
Figure 6.17 Mechanical refrigeration cycle and (h-p) representation for various
evaporator temperatures
Figure 6.17 indicates that decrease in evaporator temperature reduces the amount of heat removed
by the evaporator; (h1 h4 ) (h1a h4 a ) (h1b h4b ) . However, the amount of work consumed by
the compressor increases; (h2 h1 ) (h2 a h1a ) (h2b h1b ) . In short, as the evaporator temperature
drops, the single stage compression becomes inefficient and impractical and two-stage compression
becomes a necessity.
In Equation (6.15), v1, is the specific volume of the gas at the inlet, and the specific work input
to the compressor is directly proportional to this value. Hence, at a specified pressure, reducing the
inlet volume by cooling also reduces the work input as indicated by the shaded area in Figure 6.18a.
It can be demonstrated that, in Figure 6.18b, (h2 h1 ) (h4 h3 ) (h2b h1 ) .
Intercooling of a gas may be achieved by using a flash tank as in the case of refrigeration systems,
or water cooled heat exchanger which is commonly used in air compressors. In addition to reducing
the compressor work input, intercooling also reduces the exit temperature of the compressed gas which
results with a better lubrication and a longer compressor life.
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 235
Determining the intermediate pressure for two-stage compression process so that the total work
consumed attains a minimum value is essential in engineering applications. Assuming that the com-
pressors work reversibly, the total work input may be stated as,
n 1
n 1
n pi n n p2 n
wrev p1v1 1 p1v1 1 (6.16)
n 1 p1 n 1 pi
In this expression, we assume that the gas is cooled down to the inlet temperature before entering
the second stage. Hence the only variable in Eq. (6.16) is the intermediate pressure, pi, and by letting
the derivative of work equal to zero, one may obtain the following,
pi p1 p2 (6.17)
On the basis of reversible conditions and for two-stage compression, the intermediate pressure
has to be the geometric average of the end pressures for minimum work consumption.
Example 6.12: The R22 refrigeration system shown in Figure 6.19 uses two-stage compression with inters cooling by a
flash chamber. The evaporator capacity is 200 kW and operates at -30C, and the refrigerant at state 1 is saturated vapor.
For the flash chamber and the condenser pressures of 600 kPa, and 1500 kPa respectively, determine the total power
required by the two isentropic compressors.
Solution:
The mass flow rate through compressor1 is determined by the energy balance on the evaporator, qe m 1 h1 h8 , h8=h7=51.8kJ/
kg, and h1=237.7 kj/kg, then m 1 1.075kg/s . Since the compressors are isentropic, s2=s1=0.9787 kJ/kgK, p2=600kPa,
h2=268.2 kJ/kg, and the power consumed by the first compressor is Wc1 m 1 h2 h1 1.075 268.2 237.78 32.7 kW .
The rate of refrigerant flowing through the second compressor may be calculated by the energy balance around
the flash chamber as, m 1 h2 h7 m 3 h3 h5 or, m 3 1.075 268.2 51.8 / 252 93.5 1.466 kg/s .Hence,
Wc 2 m 3 h4 h3 1.466 273.9 252 32.095 kW . The total power consumed is Wt Wc1 Wc 2 64.795 kW .
236 THERMODYNAMICS
Discussion: The geometric average of the evaporator and the condenser pressures (pi=495.6 kPa) does not match with the
flash chamber pressure. Simply, the gas is not an ideal gas, and it is not cooled down to the inlet temperature of the first
compressor at the intermediate state.
Referring to Eq. (6.8), for an adiabatic process, s s e s i 0 , and together with Eq. (5.27),
one may conclude that the fluid temperature at the exit of the device is greater than the inlet (Te > Ti).
However, in case of isentropic flow, Te = Ti. Thus the isentropic process of an inviscid fluid is also an
isothermal process and the change in fluid internal energy is zero. Depending upon the reversibility
of the flow, the shaft work of a flow machine involving a unit amount of incompressible fluid may
be stated in two-fold:
Equations 6.13, 14, and 6.19 form the basis for efficiency analysis of various flow devices.
Definition: An isentropic flow is an adiabatic and frictionless flow (reversible) for which the entropy
of the fluid is constant throughout the flow field.
Although no real flow is entirely isentropic, the major portion of many flows of engineering
practice can adequately be modeled as steady, one-dimensional and isentropic. As shown in Figure
6.20a, in internal duct flows, the effects of viscosity and heat transfer are usually restricted to thin
layers adjacent to the wall and the rest of the flow field can be assumed to be isentropic. Similarly, in
external flows, the effect of viscosity and heat transfer can be assumed to be restricted to the bound-
ary layers, wakes, and shock waves and the rest of the flow field, as indicated in Figure 6.20b, can be
treated with adequate accuracy as isentropic flow.
As Explained in Example 6.1, for an isentropic change of state of an ideal gas with constant spe-
cific heats, the following relations hold,
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 237
k 1
k 1
p T2 2 p k
constant and 2 (6.21)
k T1 1 p1
In addition, recalling that the speed of sound in an ideal gas is a kRT , then for an isentropic
flow,
k 1 k 1
a2 T 2 p 2k
2 2 2 (6.22)
a1 T1 1 p1
For steady and adiabatic flow of an ideal gas through a stream tube in Figure 6.18, the energy
equation yields,
238 THERMODYNAMICS
k 1 2
1 1 1 M1
T2 2
c pT1 V12 c pT2 V22 or (6.23)
2 2 T1 1 k 1 M 2
2
2
where, M 1 ( M 1 V1 / a1 ) and M 2 are the Mach numbers at specified states. Substituting Eq. 6.23
into Eq.6.21, one may obtain the following for isentropic flow conditions,
k 1
k 1 2 k 1 k 1 2 k 1
1 M1 1 M1
p2 2 2 2
p1 1 k 1 2 and
1 1 k 1 2 (6.24)
M2 M2
2 2
Example 6.13: Consider compressible and frictionless flow through a stream tube. For such a flow, the pressure-velocity
1
relation, and the temperature-velocity relations are respectively given as, dp VdV , and dT VdV . Applying the
cp
ideal gas equation,
d dV
a. Show that the density-velocity relation is M 2 .
V
b. Calculate percent variations in density and temperature for Mach numbers; M=0.1, 0.3, 0.4.
Solution:
d dp dT
After differentiating the gas equation one may obtain, . In addition to gas equation considering the above
p T
dp dV V2
pressure-velocity relation the pressure ratio becomes, kM 2 , where, M 2 . Similarly, the temperature ratio in
p V kRT
dT dV d dV dV
differential form is k 1M 2 . Substituting these two ratios into the gas equation, kM 2 k 1M 2
T V V V
d dV
and simplifying results as, M 2 . Therefore, at M=0.1, the fractional change in density will be 1% of fractional
V
change of velocity. At M=0.3, the fractional change in density will be 9% of fractional change of velocity, and at M=0.4,
the fractional change in density will be 16% of fractional change of velocity.
Let us calculate the temperature variation of air (k=1.4) with Mach numbers at M=0.1, 0.3, 0.4. The fractional change
in temperature will respectively be 0.4%, 3.6%, and 6.4% of the fractional change in velocity.
Comments. The temperature variation becomes increasingly important as Mach number increases. Especially, for flows
at M>0.3, the compressibility effect and the temperature variation have to be considered and become significant.
Example 6.14: Consider compressible and frictionless flow through a stream tube and determine how the flow cross sectional
area changes with respect to Mach number.
Solution:
d dA dV
After differentiating the continuity equation one may obtain, 0 . Since we know the density-velocity
A V
Stagnation conditions. If the flow at any point in the fluid stream is brought to rest isentropically
then the stagnation conditions are obtained. As shown in Figure 6.23, if the velocity is zero at some
point in the flow then the measured values of pressure, temperature and density are stagnation values.
Hence, substituting M2=0 in Eqs. 6.23, and 24, the stagnation parameters become,
k 1
k 1 2 k 1 2 k 1 k 1 2 k 1
To T1 1 M1 po p1 1 M1 o 1 1 M1 (6.25)
2 2 2
The critical conditions are those conditions that will exist if the flow is isentropically accelerated or
decelerated until the Mach number is unity. Hence, for a supersonic nozzle, the critical conditions
take place at the minimum area called the throat. The critical conditions are denoted by the symbols
p* , T * , * , A* , V * and are formulated by letting M1 = 1 in Eq. (6.25).
240 THERMODYNAMICS
k 1
k 1
* k 1 k 1
* k 1 k 1
*
To T po p o (6.26)
2 2 2
Under steady conditions, the mass flow rate of isentropic gas flow can be described in terms the
stagnation properties, the flow cross sectional area, and the flow Mach number as following,
p k M
m AV A kRT M p0 A k 1 (6.27)
RT RT0
k 1 2 2( k 1)
1 2 M
For specified stagnation values and the flow area, the maximum flow rate is obtained at the condi-
dm
tion for which 0 . This yields M=1 and the flow Mach number assumes unity at the minimum
dM
cross-sectional area, A*. Thus the maximum flow rate is:
k 1
* k 2 2( k 1)
m max p0 A
RT0 k 1
(6.28)
It is important to note that for constant stagnation properties, the maximum flow rate is a linear
function of the throat area. This fact is widely used in the design of flow meters, medical devices,
and mass flux control systems. Hence there are four distinct possibilities for the maximum flow rate
as following,
a. p0, 0, and A* are fixed : m max is also fixed.
b. p0 increases only : m max linearly increases.
c. A increases only
*
: m max linearly increases.
d. T * increases only : m max decreases.
Example 6.15: Consider hot combustion gases (k=1.33) flow in an adiabatic and no work system. At one section p1=14
bar, T1=500K, V1=125m/s, and A1=500mm2. At a downstream section M2=0.8. Assume isentropic flow conditions, R=0.28
kj/kgK and calculate,
a. p2, T2, V2 and A2,
b. the stagnation pressure and temperature,
c. the critical values at the throat and the throat cross sectional area.
Solution:
a. The speed of sound at section 1 is, a1 1.33 280 500 431.5 m / s and M1=0.289. In regard to Eqs. (6.23)
1.33
T2 p
and (6.24), 0.916 , T2 458 K , 2 0.916 0.33 , p2 9.83bar , V2 a2 M 2 , a2 412.98 m/s and
T1 p1
V2 330.39 m/s . Since m 1V1 A1 2V2 A2 and 2 7.66 kg/m3, 1 10 kg/m3, the mass flow rate becomes
0.33
b. By Eq. (6.25), the stagnation pressure and temperature are T0 500 1 0.2892 ,
2
1.33
0.33 0.33 , T 506.8 K , p 1479.39 kPa
p0 1400 1 0.2892 0 0
2
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 241
1479.39 506.8
c. The critical values are determined by Eq. (6.26), p* 799.4kpa , T * 435.02K , and
1.33 2.33
2.33 0.33 2
2
* 6.56kg/m3 . Since M*=1 at the throat, V * 1.33 280 435.02 402.49 m/s , and the continuity at the
0.625
throat yields, A* 236.7 mm 2
6.56 x 402.49
Comments. To accelerate the combustion gases, the channel must converge in the flow direction and if the cross sectional
area assumes the critical values, then the gas flow becomes sonic.
Converging and diverging nozzles. As shown in Figure 6.24, let us consider a pressurized tank with
a converging nozzle attached is situated in a controllable environment. Initially, the stagnation pres-
sure and the pressure of the surroundings are identical. Then the surroundings pressure is lowered
gradually and the flow accelerates. The gas pressure at the nozzle exit is identical with the back
pressure until the flow Mach number assumes unity, M=1, or pb= pe= p*. However, when the back
pressure is lowered further, pb<p*, the gas pressure at the nozzle exit does not respond to this change
and stays at the critical value. As shown in Figure 6.24c, the flow is called chocked at this condition
and is not possible to accelerate the fluid further. The mass flow rate at this condition is determined
by Eq. (6.28). Hence the converging nozzles are useful only for flows for which pb p * and flow
Mach number is M 1 . The objective of making a convergent-divergent nozzle (sometimes called a
Delaval nozzle) is to obtain supersonic flow.
Figure 6.25 A typical converging-diverging nozzle and the pressure variation for various
flow conditions
242 THERMODYNAMICS
Lowering the back pressure at the nozzle exit relative to the pressure at the nozzle inlet, one may note
several different operational modes as are presented in Figure 6.25b.
Case a: “Venturi mode” For pressures above the first critical; pb p fc , the nozzle operates like a
venture. The velocity at the throat is less than the sonic value. The nozzle is not chocked and the flow
rate is less than the maximum.
Case b: “the first critical mode” For back pressures at the first critical value pb p fc the fluid veloc-
ity reaches the sonic speed at the throat, and the diverging section operates like a diffuser. The fluid
decelerates, and the flow is subsonic between 2 and 3.
Case c: “the third critical mode” For back pressures at the third critical value pb ptc the fluid veloc-
ity reaches the sonic speed at the throat, and at the diverging section the fluid continues acceleration.
The flow is subsonic from 1 to 2, sonic at 2, and supersonic between 2 and 3. For cases b and c, the
flow variations are identical from the inlet to the throat.
Case d: As shown in Figure 6.25b, in a region, p fc pb ptc , a normal shock develops at a section
between the throat and the exit plane which causes a sudden increase in pressure and the flow is non-
isentropic.
One may notice by Figure 6.25 that the first and the third critical points represent the only operat-
ing conditions that satisfy the following:
a. The Mach number is unity (M=1) at the throat,
b. Isentropic flow throughout the nozzle,
c. The pressure at the nozzle exit is the same as the surroundings.
Example 6.16: As shown in Figure 6.26, a converging-diverging nozzle discharges air into surroundings at 100 kPa of
pressure. A duct having 0.1m2 cross sectional area feeds the nozzle with air at 6.80 bar, 175C, and a velocity such that
the Mach number M1=0.25. The area at the nozzle exit is such that the flow exit pressure exactly matches the surroundings
pressure. Assume perfect gas, and steady, one-dimensional and isentropic flow, calculate,
a. the mass flow rate,
b. the throat area,
c. the nozzle exit area.
Solution:
a. The density and the velocity at state 1; 1 p1 / RT1 680 / (0.287 x 448) 5.28 kg/m3, a1 1.4 x 287 x 448 424.27 m / s
and V1 106.06m / s m 1V1 A1 5.28 x0.1x106.06 56.095 kg/s.
3.5
0.4 0.4
b. Flow stagnation values are, T0 448 1 0.252 453.6 K, p0 680 1 0.252 710.2 kpa. At
2 2
the throat, M*=1, by Eq. (6.26), p* 375.19 kpa, T * 378 K, and * 375.19 / (0.287 378) 3.458 kg/m3. The
mass flow rate will be the same at the throat, A* 56.095 / (3.458 x 424.27) 0.038 m2.
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 243
0.5
(710.21 / 100)0.285 1
c. Since p3 = 100 kPa, by Eq. (6.25), the Mach number at the nozzle exit is M 3 1.937
0.2
and T3 453.6 / (1 0.2 x1.937 2 ) 259.2 K, a3 322.7 m/s, V3 625.1 m/s, 3 1.344 kg/m3. Then the continu-
ity equation yields the exit area as, A3 56.095 / (1.344 x625.1) 0.066 m2.
If the surroundings pressure is below the
third critical value, the nozzle operates in-
ternally as though it were at the third critical
point but expansion waves or shock waves
occur outside the nozzle. The shock waves
that occur in a plane normal to the direction
of the flow are called normal shock waves.
As shown in Figure 6.27, the flow process
through the shock wave is highly irrevers-
ible, but relations for the flow properties
before and after the shock may be developed
by applying and combining the conservation
of mass and energy equations that yields so
called Fanno line in literature. Similarly,
combining the conservation of mass and
momentum equations yields the Rayleigh
line. On h-s diagram, these lines intersect at two points at which all three conservation relations are
satisfied. One of these points represents the state before the shock and the other after the shock. The
details of the flow behavior after the occurrence of a shock is explained in gas dynamics texts.
Referring to Eq. (4.60), for a negligible kinetic energy change across a turbine, the isentropic ef-
ficiency may then be determined in terms of the enthalpy change as,
h1 h2
t (6.30)
h1 h2 s
The h-s presentation in processing of a fluid flowing through an adiabatic turbine or a nozzle
is shown in Fig. 6.28. The isentropic change in enthalpy is always greater than the adiabatic one,
(h1 h2 s ) (h1 h2 ) and hence t 1 . For pre-specified relationship between p and v, the isentropic
enthalpy variation in Eq. (6.30) may be calculated by Eq. (6.14), or may be evaluated from tables
by using the constant entropy constrain. In general, the isentropic efficiencies of turbines vary in the
range between 80% and 90%.
Va2 / 2
n (6.31)
V s2 / 2
Va2 V2
Where, h1 h2 , and s h1 h2 s . Hence the nozzle efficiency may be expressed in terms
2 2
of the enthalpy change of the fluid as,
h1 h2
n (6.32)
h1 h2 s
This expression is analogous to turbine efficiency and the same process line on h-s diagram as
used for a turbine also applies to the expansion through an adiabatic nozzle. Nozzles for subsonic
flow have greater efficiency than the supersonic ones. In general, nozzle efficiencies are rated above
90-percent.
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 245
w s
c (6.33)
w a
Neglecting the changes in kinetic energy of the fluid across the adiabatic compressor and refer-
ring to Eq. (4.60), the isentropic efficiency of a compressor may be evaluated in terms of the enthalpy
difference of the fluid as,
h2 s h1 (6.34)
c
h2 h1
Figure 6.29 presents the adiabatic compression process of a gas through a compressor in h-s dia-
gram. As can be seen by this figure, the entropy of the flowing gas increases as it approaches to the
exit. The adiabatic efficiencies of gas compressors range roughly between 75% and 85%.
If an effort is made to cool the gas during the compression by using a water jacket or fins, the
ideal process for such a case is considered to be a reversible isothermal process. Then the isothermal
efficiency of a cooled compressor is then the ratio of the isothermal work, w T , to the actual work, w a ,
required for the same inlet conditions and the same outlet pressure and is defined as,
w T
isother .comp (6.35)
w a
deceleration of flow than it is to obtain an efficient acceleration. There is a natural tendency in a dif-
fusing process for a fluid to break away from the walls of the diverging passage. Experiments have
shown that the maximum permissible angle of divergence of a rectangular channel with one pair of
sides diverging is about 11-degrees. If the divergence is too rapid, this may result in the formation
of eddies with a consequence of lost kinetic energy. Hence the isentropic efficiency of a diffuser is
defined as the ratio of the isentropic enthalpy increase to the actual increase in enthalpy for the same
inlet conditions and the same outlet pressure.
h2 s h1
d (6.36)
h2 h1
w s vp
p (6.37)
w a cT vp
The pump efficiencies may range from 50% to 85%.
Example 6.17: Air from the environment where the conditions are 101 kPa, 25C is compressed at a rate of 0.3kg/s to 600
kPa by an adiabatic compressor with an isentropic efficiency of 75% (see Figure 6.30). The compressed air is then cooled
at a constant pressure to 45C in a heat exchanger by water that enters at 101 kPa, 25C and exits at 100 kPa, 40C. The air
is treated as ideal gas with M=29, k=1.4. Determine,
a. the power consumed by the compressor,
b. the minimum power associated with compressing the air to the same exit pressure
c. the irreversibility of the process.
Solution:
a. b. For reversible and adiabatic compression of an ideal gas, the
compressor exit temperature becomes,
(1.4 1)
T2 s 298 (600 / 101) 495.1K . H e n c e t h e m i n i m u m
1.4
power to be consumed, Wcs 0.3 1.005 (495.1 298) or. By
Eq. (6.33), the actual power consumed by the compressor is
Wc Wcs / c 59.425 / 0.75 79.234 kW
.
c. The actual exit temperature of air;
T2 298 79.234 / (0.3 1.005) 560.8K ,
and the energy balance around the heat exchanger yields water
0.3 1.005 (560.8 318)
m a s s f l o w r a t e a s , m w 4.18 (40 25)
1.167
kg/s. After applying Eq. (6.9) with q 0 to the control volume in Figure 6.30, the generated entropy is
where, s3 s1 1.005 ln(318 / 298) 0.287 ln(600 / 101) 0.446 kJ/kgK and
S gen m a ( s3 s1 ) m w ( s5 s4 )
s s 4.18 ln(313 / 298) 0.205kj/kgK . Then the entropy generation rate becomes, S 0.1054 kW/K and
5 4 gen
q
(6.38)
qmax
In equation (6.38), qmax , is the reversible heat transfer and can only be realized if the tempera-
ture difference between the two fluids is infinitesimally small. This, in turn, requires an infinitely
large heat transfer surface area, and the fluid with minimum heat capacity experiences the maximum
temperature difference as, Tmax Th , in Tc , in . Thus, qmax is calculated as, qmax mc
p Tmax ,
c
if mc
p mc
p , and qmax mc
p Tmax , if mc
p mc
p . Referring to Figure 6.31, having
c h h h c
identical flow rates of the same fluid in both flow circuits of the exchanger, the heat exchanger ef-
fectiveness may be expressed as,
h2 h1
(6.39)
h3 h1
enthalpy, and later in chapter 5, the entropy of an ideal gas. Besides the use of tables, however, nothing
is mentioned about formulating and determining these properties of a fluid in terms of the measured
ones. Such questions can only be answered by studying the thermodynamic relations among fluid
properties. In studying the thermodynamic relations, the following topics have to be cooperated:
1. Definitions. A property definition plays an important role in expressing the differential form with
respect to other properties and frequently used property definitions are represented in Table 6.1.
Isothermal bulk p
Enthalpy h u pv B v
modulus v T
Joule-Thomson T
Gibbs free energy g h Ts J
coefficient p h
Volume expansivity 1 v T
j
v T p
Joule coefficient
factor v u
Isothermal 1 v p
Speed of sound a v 2
compressibility v p T v s
2. State principle. As studied in chapter 2, this principle can be used in forming an exact differ-
ential of a property respect to other two independent properties.
Example 6.18: The internal energy of an ideal gas with constant specific heat is u u0 cv T T0 and the entropy ex-
T v
pressed as, s s0 cv ln R ln . Determine a rigorous relationship in the form of u u s, v for the internal energy
T0 v0
of an ideal gas.
Solution:
R / cv 1 k
s s0 T v T v s s0
Referring to entropy relation, ln or exp , and rearranging the internal energy
cv T0 v0 T0 v0 cv
1 k s s0
v
equation yields, u u0 cvT0 exp 1
v0 cv
3. Fundamental equation of thermodynamics. As stated by equation (5.25), using the fundamental
equation of thermodynamics, the exact differentials of enthalpy, Helmholtz free energy, and Gibbs
free energy can be expressed as following,
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 249
4. Mathematical properties of exact differentials. If z z x, y and if the exact differential ex-
pressed as, dz Mdx Ndy then the following relations hold,
z z
M N
x y y x
M N
(6.41)
y x x y
z y x 1
x y z x y z
The last relation in equation (6.41) is called cyclic relation among the variables. With the exact
differential relations as stated in Eq. (6.41), utilizing Eq. (6.40) in order, one may obtain relations
between p, v, T, and s of a fluid as indicated in Table 6.2.
Table 6.2 Maxwell relations
z z M N
Differential equation M N
x y y x y x x y
u u T p
du Tds pdv T p v s
s v v s s v
h h T v
dh Tds vdp T v
s p p s p s s p
250 THERMODYNAMICS
f f p s
df pdv sdT p s T v
v T T v v T
dg vdp sdT g g v s
v s T p
p T T p p T
In Table 6.2, one may note that one property derivable by two different derivatives, and using
these relations, a change in an immeasurable quantity of a system can be evaluated by measuring the
change in p, T, and v.
Example 6.19: As shown in Figure 6.33, a fluid completes a differential reversible cycle which consists of two constant
T p
volume and two constant entropy processes. Show that for the cycle.
v s s v
Solution:
p
In p-V diagram, the net work done by the cycle is the shaded area and is expressed as,
W s dsdv . Similarly, in
v
T
T-s diagram of Figure 6.33, the net heat transferred to the cycle is
Q v dvds , where dv has a negative value.
s
Referring to the first law of thermodynamics for cycles, the two shaded regions in Figure 6.30 have to be identical. Therefore,
p T p T
s dsdv v dvds or s v .
v s
v s
Comments: Considering the above example, the physical importance of Maxwell relations can be demonstrated.
Example 6.20: Show that Joule-Thompson coefficient of an ideal gas is zero.
Solution:
h h
Since functional form of enthalpy of a fluid is h h p, T and in differential form, dh dT dp . Refer-
T p p T
h T h p T
ring to Table6.1, c p and . Employing the cyclic relation in Eq. (6.41), 1 then
T p p h p T T h h p
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 251
h
c p . Hence the differential form of enthalpy becomes dh c p dT c p dp . As studied in chapter 2, enthalpy of
p T
an ideal gas is only a function of temperature and c p 0 then only choice in dh expression is 0 .
T2
p2
v
h2 h1
T1
c p dT
p p1 p1
v T
T
dp
p
(6.42)
T2
The information needed to integrate the first term in equation (6.42) is the variation of cp along
an isobar line, and totally gives the enthalpy change of an ideal gas. For the integration of the second
term, however, an equation of state which relates p, v, and T of the substance or the compressibility
v
chart is needed. Then the derivative, can be evaluated and the integral can be carried out along
T p
isotherm at T2. This term also presents the amount of deviation of enthalpy change from the enthalpy
change of ideal gas behavior.
Example 6.21: Considering the compressibility factor of a real gas, derive an equation for enthalpy deviation so that the
amount of deviation from ideal gas enthalpy change can be evaluated in terms of the reduced values.
Solution:
Since the state equation for real gas is pv ZRT and in differential form, vdp pdv ZRdT RTdZ . For constant pressure,
v ZRT RT 2 Z v RT 2 Z
T . Hence the second term of Eq. (6.42) can be rearranged as v p .
T p p p T p T p p T p
Then the enthalpy deviation in terms of reduced values can be expressed as,
In accord with this relation, generalized enthalpy correction chart has been prepared in literature
and enthalpy deviation can be estimated graphically.
Similar methodology may be applied to evaluate the change of entropy of a pure substance by
measurable quantities. Since the entropy of a pure substance can be expressed in functional form as,
s s
s s p, T or as, s s v, T , the change in entropy will be, ds dp dT or by Eq.
p
T T p
252 THERMODYNAMICS
dh ds dp h s s cp
(6.40), T v and for constant pressure, T T T . Hence T T . More-
dT dT dT p p p
s v
over, utilizing Maxwell’s relations, and substitution into ds expression yields,
p T T p
T2 dT p2
v
s2 s1
T1
cp
T p p1 p1
T dp
p T T
(6.44)
2
Example 6.22: Considering the compressibility factor of a real gas, derive an equation for entropy deviation from the ideal
gas entropy change and express the entropy deviation in terms of reduced values.
Solution:
Consider the differential form of equation of state of a real gas as, vdp pdv ZRdT RTdZ , for constant pressure,
v Z v v RT Z
p ZR RT T or T T p T . Together with the ideal gas entropy change expression, the
T p p p p
p2
s* s T Z 1
v
entropy deviation may be expressed as, dp .
R p1 RT p T p p
Considering the result of Example 6.22 and rearranging, the entropy deviation of a real gas may
be expressed as,
s* s pr 2 Z dpr
R
Tr 2 pr 1
Tr pr pr
(6.45)
Example 6.23: A piston-cylinder device in Figure 6.34 contains 1.8kg of water vapor at 280C, and 0.44m3 of volume.
After a reversible and isothermal expansion process, vapor assumes a final volume of 0.6m3. Assuming that water vapor
obeys Van der Waal’s equation of state, determine
a. percent deviation in initial pressure,
b. the amount of heat transferred.
Solution:
a. Referring to Table (2.3), a 552.6 m6 kPa/kmol and b 0.03042 m3/kmol. The mole number is n 1.8 / 18 0.1 kmol
8.314 553 552.6
and the initial molar volume is v1 0.44 / 0.1 4.4 m3/kmol. Eq. (2.24) yields, p1 1023
4.4 0.03042 4.42
kPa. Tabulated value for p1 is p1 1000 kPa, and the percent deviation becomes, err%=2.3-percent.
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 253
s s
b. Consider s s v, T and differential change in s becomes, ds dv dT , since the process is isothermal,
v T T v
s p R v2 v2 dv
dT = 0, and utilizing Maxwell relations,
v
T T v b . For a reversible process, q12
v
v1
Tds RT
v1 vb
,
v b
or Q12 nRT ln 2 , v2 0.6 / 0.1 6.0 m3/kmol, and Q12 143.39 kJ.
v
1 b
2
p v p v
c p cv T T or c p cv TvB 2 (6.46)
T v T p v T T p
Referring to Table 6.1, B in Eq. (6.46) is the isothermal bulk modulus, and is the volume ex-
pansivity of the substance. Since for any fluid the quantities, T, v, B, are always positive, cp will
always be greater than the value of cv.
Example 6.24: Evaluate the difference in specific heats of water at 20C. Take the bulk modulus and volumetric expansion
coefficient for water at 20C respectively as, B=2.15x109Pa, and =0.207x10-31/K.
Solution:
Assuming, v 0.001002 m3/kg and respect to Eq. (6.46), c p cv 293 1.002 103 2.15 x109 0.207 2 x106 27.05 J/
kgK, or c p cv 0.027 kJ/kgK. As can be seen this difference is considerably small with respect to bulk value of cp (0.6-
percent). For liquids the difference is usually neglected and is not considered in the calculations.
We already know that both specific heats are functions of temperature, and in fact, empirical equa-
tions in polynomial form are cast for many fluids but we certainly do not know much about how the
254 THERMODYNAMICS
pressure or volume variations affect the specific heats as the temperature is kept constant. Consider
dT v
the exact differential of entropy of a fluid at single phase as, ds c p dp and making use
T T p
cp / T
of Maxwell’s relations in Table 6.2, one may state that,
v / T
p or rear-
p T
T p
ranging yields the effect of pressure on constant pressure specific heat at isothermal conditions as,
c p 2v
T 2 (6.47)
p T T p
Here, we need the state equation for determining the pressure effect on cp. Similar analysis can be
carried out for determining the effect of volume variation on cv by considering the second equation
dT p
of entropy in differential form as, ds cv dv . Applying Maxwell’s relations to this rela-
T T v
cv / T
p / T
and after rearrangement the effect of volume on constant
v
tion yields,
v
T T
v
volume specific heat at isothermal conditions may be expressed as,
cv 2 p
v T 2 (6.48)
T T v
Here again we need the information between p, T, and v for evaluating the effect of volume
change on cv.
Example 6.25: Neon gas obeys Clausius equation of state as, p v b RT at a state of 100 MPa, and 300K. Evaluate,
a. the effect of pressure and volume respectively on cp and on cv of Neon gas,
b. the amount of heat transfer to 1.5 kg of Neon gas if gas expands from 100 MPa to 50 MPa reversibly and isother-
mally,
Solution:
a.
Referring to the equation of state, v / T p R / p and 2v / T 2 0 . Hence constant pressure specific heat does
p
not vary respect to pressure, by Eq. (6.47), c p / p T 0 . Similarly by the state equation, p / T v v b R
or 2 p / T 2 v b 0 . Hence, in equation (6.48), cv / v T 0 . For Neon gas, the specific heats are in-
v
dependent of pressure and volume variations.
b. Since, v / T p R / p , and the process is reversible and isothermal,
0
dT R dp Q nRT ln p2 , the molar mass of Neon, M=20.17kg, and
Q Tds T c p dp c p dT RT 12
T p p p1
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 255
50
n 1.5 / 20.17 0.074 , Q12 0.074 x8.314 x300ln 127.93 kJ.
100
h v RT
T
v v
T p
T T p p b 0.0022
c. J or J substituting the values yields, J
p h h cp cp cp 6.4
T
p
J =-3.4x10-4 K/kPa. Negative sign indicates that the gas becomes hot as it expands to lower pressure.
g f ( p, T ) g g p, T or dg f dg g (6.49)
Due to change in pressure and temperature, the change in Gibbs values of both phases can be
evaluated by Eq. (6.40) as,
dg f v f dp s f dT and dg g vg dp sg dT (6.50)
Combining these two relations at the equilibrium of these two phases and rearranging yields,
dp sg s f
dT v v (6.51)
sat g f
This expression gives the rate of change of pressure with temperature on the line representing the
liquid-vapor equilibrium. As shown in Figure 6.35a, since for many substances sg s f , and vg v f ,
the equilibrium line has a positive slope. Furthermore the phase change takes place at constant pressure;
the entropy change may be expressed as, sg s f h fg / T and substituting into Eq. (6.51) yields,
dp h fg
dT Tv (6.52)
sat fg
256 THERMODYNAMICS
Special solution of the above relation (Eq. 6.52) may be obtained at pressures very low respect to
the critical pressure of a fluid ( p pc ). For such a case, the specific volume of saturated liquid may
be neglected ( vg v f ) and the gas phase may be assumed to behave like an ideal gas, vg RT / p .
dp h fg dT
Thus Eq. (6.52) may be rearranged as, . For moderate changes of pressure and temperature,
p R T2
the enthalpy of evaporation does not change appreciably, and may be assumed to be constant. Thus,
p h fg 1 1
ln 2 (6.53)
p1 R T1 T2
The above equation represents the relation between pressure and temperature along the liquid-
vapor phase equilibrium line, and the slope of the line is expressed as,
d ln p h fg
(6.54)
d 1 / T R
As illustrated in Figure 6.35b, for higher values of slope, an appreciable change in saturation pres-
sure will not affect the saturation temperature, and the saturation temperature will almost be constant.
This is a desired property for some fluids to accommodate at working conditions; especially refriger-
ants are desired to have such a property.
dg f dg s v f dp s f dT vs dp ss dT (6.55)
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 257
Furthermore, for the phase change process, s f ss hsf / T and vsf v f vs , the slope of (p, T)
line representing the solid-liquid equilibrium in the phase diagram becomes,
dp hsf
dT Tv (6.56)
sat sf
In short, (C-C) equation provides the slope of phase equilibrium line at a particular pressure and
temperature.
Example 6.26: Estimate the sublimation pressure of water at -40C by using the following data of water at the triple point:
ptp 0.61 kPa , Ttp 0.01 C and hsg 2834.8 kJ/kg and compare the result with the tabulated value.
Solution:
a. Considering that vg vs Equation (6.53) may be applied to the present problem by some modifications as,
p 2834.8 1 1
R 8.314 / 18 0.461 kJ/kgK, and ln 2 or p2 0.0249 0.61 0.0151 kPa. The
p
1 0.461 273 233
tabulated value of sublimation pressure at -40C is 0.013 kPa, and C-C equation estimated the pressure by 16%
error.
Example 6.27: The enthalpy of melting of benzene (C6H6) at p 100 kPa and T 5.5 C is 7.165 kJ/kg and its density in
liquid and solid phases respectively are 894 kg/m3, and 1014 kg/m3. Determine the dp / dT slope of the phase equilibrium
line at this pressure temperature.
Solution:
1 1 dp 7.165
a. Respect to Eq. (6.56), vsf 1.323 x104 m 3/kg, then 4
278.5 1.323 10 194.46
kPa/K 894 1014 dT sat
The entropy-based design is an emerging design methodology that incorporates the second law with
computational fluid dynamics (CFD), and experimental techniques. The methodology may shed some
light on various flow processes, ranging from optimized flow configurations in an aircraft engine to
highly ordered crystal structures (low entropy) in a turbine blade. Hence, the entropy based design ex-
tends the methods like exergy analysis and entropy minimization to more complex configurations.
In the development of a workable or an acceptable design that satisfies the prescribed require-
ments and the constraints, first as indicated in Figure 6.36, the entropy generation in a fluid that has
temperature and velocity gradients along the flow direction will be discussed.
Together with the definition of compressible and incompressible Newtonian fluids, as schemati-
cally described in Figure 6.37, rewriting the entropy transport equation (Eq. (6.8)) for an infinitesimal
control volume, δV, one may determine a way of calculating the local entropy generation for such
fluids as,
2
k T ij ui
sgen (W/m3K) (6.57)
T 2 xi T xi
In Equation (6.57), k is the thermal conductivity of the fluid, and τij is the viscous shear arising
from the velocity gradients in the flow and is expressed as,
u u j 2 uk
ij i (Pa) (6.58)
x j xi 3 xk ij
where, μ, is the dynamic viscosity and δij is the kronecker delta. One may note that the last term
u
in Eq. (6.58) will vanish for an incompressible flow k 0 .
xk
Eq. (6.57) is a positive definite expression for the entropy generation rate. The first term on the
right represents entropy generation due to heat transfer across the fluid stream for a finite temperature
difference. If the fluid is isothermal then there will be no temperature gradient across the fluid body
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 259
and this term will be zero. The second term is the local entropy generation due to viscous dissipation
(conversion of kinetic energy into internal energy through fluid friction). This term will be zero if the
fluid is ideal or the flow is inviscid (μ=0). Thus, for the flow of isothermal, ideal, and incompressible
fluids, sgen 0 .
In general, the vector form of Eq. (6.57) for entropy production of laminar flow is expressed as
following:
k T T
sgen 2
(6.59)
T T
where is viscous dissipation function and is due to velocity gradients in the flow. For two-
dimensional flow (2D flow), this function is expressed as,
u v 2 u 2 v 2
2 (6.60)
y x
x y
and the first term in Eq. (6.59) represents the entropy generation due to heat transfer across tem-
perature gradients in the fluid body.
The head loss, hl , due to entropy generation in the fluid may be formulated by integrating the
irreversibilities over the entire channel as following,
1
hl
Ts dV
V gen
mg
(6.61)
260 THERMODYNAMICS
The objective is to show that the relationship of Eq. (6.61) also holds for calculating the frictional
u
losses of isothermal fluid flowing through a 2D channel. Since the flow is fully developed, 0,
x
2
u
and v=0. Then the viscous dissipation function reduces to and by the velocity distribution
y
u 2u y
equation, c2 . In addition, for an isothermal fluid, T 0 . Hence, the entropy rate gener-
y h
ated in the fluid becomes,
2
u 4 uc2 y 2 9u 2 y 2
sgen or sgen (6.62)
T y Th 4 Th 4
Substituting this result into Eq. (6.61) and integrating over the fluid volume ( dV 1 dy 1 ) with
m 2h u yields,
2
24 u l p
hl (6.63)
Re 2 g 2h g
where, Re represents the flow Reynolds number and is defined as, Re u (2h) / .
Example 6.28: Water at 290K flowing isothermally with an average velocity of 0.05m/s through a duct with a height of
0.02m. Determine variation of entropy production rate with the channel height and the energy loss for a channel length of
2 meters.
Solution:
The viscosity of water at T=290K is μ=1.14x10-3 kg/ms, h=0.01 m, and referring to Eq. (6.59), for isothermal flow, T 0 ,
and sgen 8.844 y 2 . Since the range of y is 0.01 y 0.01 , the variation of entropy generation rate is as shown in
Figure 6.39.
Due to viscous effects, the entropy production rate is at maximum near the walls and is zero at the center. Water density,
998 0.05 0.02 2
=998kg/m3, and the flow Reynolds number is Re 875.4 , and by Eq. (6.61) the head loss for the entire
1.14 103
channel is hl 0.697 m . Since the rate of energy loss is calculated by El mgh
l or El 0.998 9.81 0.697 6.823 W
Since the energy loss, El , is totally equivalent to useful work, it also represents the exergy loss for the channel flow.
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 261
The entropy production rate in turbulent flows may be determined by subdividing the fluid entropy
into mean and fluctuating components and by applying the entropy transport equation (Eq. (6.8)) to
an infinitesimal control volume, δV. However, the resulting equations are too complex for the content
of this text and are not studied here.
n j n
1
w vdp Vn2 V12 g ( zn z1 )
2
T s j gen , j (6.64)
1 j 1
In equation (6.64), beginning from the inlet, j=1, to the exit, j=n, the entropy generation term is
summed up over the n sections throughout the entire turbine. In accord with this result, the power
output is maximized when the total entropy production over the control volume of the turbine is
minimized. Hence, the turbine stages have to be designed in such a way that the energy loss due to
viscous mixing, flow separation and the losses due to inlet and exit to a stage are minimized. One way
to achieve this goal is to apply design modifications to blade shape, gap spacing, and the thickness by
using CFD for studying the flow field in a stage or by experimental techniques. In such experiments,
the Particle Image Velocimetry (PIV) system is usually used for recording the necessary data of local
entropy production rates.
Wind turbines. The wind turbines are the special type of flow machines that are used to extract
the exergy of the wind. Locations having annually averaged wind velocities of 5m/s or greater are
considered to be suitable for wind turbine installation. The wind turbines are separated into two basic
types by which the way the turbine spins. As shown in Figure 6.41, 1.(HAWT) The horizontal axis
wind turbine that has blades that spins around a horizontal axis, 2.(VAWT) The vertical axis wind
turbine such as Darrieus, and Savonius.
262 THERMODYNAMICS
The main components of a typical HAWT are indicated in Figure 6.41a. If the wind data for a
particular wind field is available then the average wind velocity over the given time period is calcu-
lated as,
V i 1
i
V (6.65)
n
VE i 1 (6.66)
n
With respect to V and VE values, the type of the wind turbine may be decided.
Example 6.29: As shown in Figure 6.42, wind pressures well away from an axial wind generator are identical (pi=pe) and
the wind velocity distribution around the turbine is shown in Figure 6.42c. Formulate,
a. the power extracted from the turbine with respect to inlet and exit wind velocities,
b. the condition for which the maximum power is obtained,
c. the value of the maximum power,
d. the exergy based ideal efficiency of the rotor.
Assumptions: constant density, no temperature gradient through the fluid, negligible potential energy change. In figures,
a and b respectively represent front and rear surfaces of the propeller.
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 263
Solution:
1 2 1
a. The energy equation between (i) and (a), and for isothermal fluid becomes, pi vi Vi pa va Va2 . Simi-
2 2
1 2 1 2 1
larly the energy equation for (b) to (e) is, pb vb Vb pe ve Ve , where, Va Vb Vturbine Vi Ve .
2 2 2
1
Then the pressure difference between the front and the rear of the turbine is pa pb Vi 2 Ve2 . The
2
1
force and the power generated on the rotor respectively then are, F A pa pb A Vi Ve and
2
2 2
1
W FVturbine A Vi Ve Vi 2 Ve2
4
dW
b. The condition by which the maximum power results is: 0 . In other words, the optimum value of Ve has to
dVe
1
be determined. After differentiating the power expression with respect to Ve and setting to zero yields Ve Vi .
3
8
c. Substituting this result into the power expression yields the maximum power as, Wmax AVi3
27
the max. exergy recovered
d. The exergy based ideal efficiency of the rotor is then max or
the exergy of the wind
8
AVi3
max 27 0.59
1
AVi3
2
As discussed in this example, the actual efficiency of the rotors is usually below this limiting
value and is around 30%-40%. The actual efficiency basically depends on the following factors: 1.
The blade tip to wind speed ratio (tsr), tsr Vtip / V , 2. The spillage and other losses. In Figure 6.43,
264 THERMODYNAMICS
the efficiencies of various rotors are indicated. For high speed propellers, the efficiency attains a
maximum value at a tip-speed-ratio between 6 and 7.
References
1. Y. Jaluria, Design and Optimization of Thermal Systems, 2nd edition, CRC press, ISBN 978-0-8493-3753-6, 2008.
2. A. Ben-Naim, A Farewell to Entropy: Statistical Thermodynamics Based on Information, World Scientific Publishing,
ISBN 978-981-270-706-2, 2008.
3. I. Dincer, and Y. A. Çengel, Energy, Entropy, and Exergy Concepts and Their Roles in Thermal Engineering, MDPI,
Entropy, Vol. 3, pp.116-149, 2001.
4. P. O’Keefe, G. O’Brien, and N. Pearsall, The Future of Energy Use, Earthscan Publishing, ISBN 978-1-84407-504-1,
2010.
5. R. Petela, Engineering Thermodynamics of Thermal Radiation-for solar power utilization, McGraw-Hill Inc., ISBN
978-0-07-163963-7, 2010.
6. G.F. Naterer, and J.A. Gamberos, Entropy-Based Design and Analysis of fluids Engineering Systems, CRC Press, ISBN
13-978-0-8493-7262-9, 2008.
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 265
heat of fusion respectively as c p 2.093kj/kgK , T0 There are no other heat transfer process during
the cycle,
h fs 333.3kj/kgK , and determine,
a. Show that the net work developed per cycle
a. the entropy generated by this process,
b. the amount of minimum work required to bring T0
is given by Wcycle Q1 1 T0 S gen ,
water at 27C back into ice at -10C T1
6.15 A perfectly insulated piston-cylinder device contains
where S gen entropy generation rate due to ir-
ammonia at 1400 kPa, 70C. The piston moves in
a reversible manner and the temperature drops to reversibilities within the cyclic system.
-25C. Since the amount of work done by ammonia
is 350kJ, determine the initial volume occupied by b. If the heat transfers Q1 and Q 0 are with hot
ammonia.
and cold reservoirs that are respectively at Th
6.16 Argon in a light bulb as in Figure 6.45 is at 95kPa and Tc , what is the relationship of T1 to the
and heated from 22C to 65C by electric input. At
temperature of the hot reservoir and Th and the
steady state conditions, the bulb emits 60W of power.
If the bulb volume is 50cm3, calculate, relationship of T0 to the temperature of the cold
reservoir Tc ?
6.26 A salesperson claims to have a 100kW steam turbine. h-s diagram of the process and apply trial and error
The steam enters the turbine at 10 bar, 300C and method.
leaves the turbine at 3bar, 200C. The temperature
6.31 An adiabatic air compressor is to be powered by a
of the surroundings is 25C.
direct-coupled adiabatic turbine that is also driving a
a. Explain if the processes in the turbine is adiabatic generator. Steam enters the turbine at 12.5MPa and
or not? 500°C at a rate of 25kg/s and exits at 10kPa and a
b. As a further explanation, the salesperson states quality of 0.92. Air enters the compressor at 98kPa
that to get 100kW of power at turbine shaft, and 295K at a rate of 10kg/s and exit at 1MPa and
the turbine consumes 0.2kg/s of steam. Is this 620K. List your assumptions and determine,
possible? a. the net power delivered to the generator by the
6.27 As shown in Figure 6.51, a steam turbine having an turbine,
isentropic turbine efficiency of 85-percent drives b. the isentropic efficiencies of both turbine and
an air compressor with an isentropic compressor the compressor,
efficiency of 78-percent. The steady state operating c. the total rate of entropy generation within the tur-
data are provided on the figure. Assume the ideal bine and the compressor during this processes.
gas model for air, and ignore stray heat transfer and
kinetic and potential energy effects. Determine the 6.32 Exhaust gases at 1.9bar, 750C exits from a jet engine
mass flow rate of the steam entering the turbine, in powering an airplane and enter an adiabatic nozzle
kg of steam per kg of air exiting the compressor, i.e. at a rate of 180kg/s, and at a velocity of 85m/s. The
pressure of the surroundings at the airplane level is
m steam / m air .
0.6bar. Assume exhaust gas behaving like air,
a. Determine the maximum possible speed at the
nozzle outlet.
b. For an isentropic nozzle efficiency of 92%
evaluate the gas speed at the nozzle outlet.
c. Determine the rate of entropy change of exhaust
gases as they pass through the nozzle for case a
and case b.
6.33 A turboprop engine consists of a diffuser, compressor,
combustor, turbine, and nozzle. The turbine drives
a propeller as well as the compressor. Air enters
3
the
diffuser with a volumetric flow rate of 83.7m /s at 40
kPa, 240K, and a velocity of 180m/s, and decelerates
essentially to zero velocity. The compressor pressure
ratio is 10 and the compressor has an isentropic ef-
ficiency of 85%. The turbine inlet temperature is 1140
K, and its isentropic efficiency is 82%. The turbine
exit pressure is 50kPa. Flow through the diffuser and
nozzle is isentropic. Considering variable specific
heat for air and neglecting kinetic energy except at
6.28 For a steam compressor, a salesperson states that the the diffuser inlet and the nozzle exit, determine
steam enters the compressor at a pressure of 1 bar, a. the power delivered to the propeller, in MW.
100C, and leaves 15 bar, 400C. The temperature b. the velocity at the nozzle exit, in m/s.
of the surroundings is 25C.
6.34 Air is compressed at steady state from 1 bar, 300 K,
a. Is this an adabatic compressor? Explain.
to 6 bar with a mass flow rate of 4 kg/s. Each unit of
b. The salesperson further states that for a steam mass passing from inlet to exit undergoes an ideal
flow rate of 0.35kg/s, the power consumed by the
process described by pv1.27 Constant . The exer-
copressor is 62kW. Is this possible? Explain.
getic efficiency of the compressor is 0.92. If kinetic
6.29 A compressor is used to bring saturated water vapor and potential energy changes are negligible,
at 1bar to 10 bar where the actual exit temperature a. Calculate the compressor power, in kW
is 420°C. Find the isentropic compressor efficiency b. If heat transfer occurs at a rate of 4.695 kJ per kg
and the specific entropy generation. of air flowing to cooling water circulating in a
6.30 Steam enters a turbine at 320°C and exhausts at 50 water jacket enclosing the compressor, determine
kPa. It is estimated that the isentropic efficiency of the exit temperature of the compressed air.
the turbine is 75-percent. If the steam is not to be 6.35 After graduating you get an interview with TEK for
in the two-phase region at the exhaust, what will be an engineering job at one of their power plants. As
the maximum turbine inlet pressure? Hint: Consider is the custom, the prospective employees are given a
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 269
tour of the control room. Having passed MECH3033, mass flow rate of steam entering the first turbine
you recognize a lot of the system diagrams showing stage is 2.63x105kg/h.
how the water flows through the various components. a. Assuming that the turbines are isentropic, de-
You are feeling confident. As your potential future termine the power output of each turbine stage
boss is talking to you about all the great benefits they and the total power of the system.
offer, you accidentally lean on a lever. Everyone b. Sketch T-s diagram for overall process of steam
in the room starts to scramble and you turn around between states 1 and 4.
to look at what you did. The lever is marked THE c. Suppose each turbine stage operates with an
MAIN TURBINE VALVE and you have moved isentropic efficiency of 88%, then repeat (a)
it from the open position to somewhere between and (b).
the open and closed position. This valve is located
after the boiler and just before the turbine inlet. The
pressure and temperature of the water just before
the valve are 20bar and 400C, respectively. The
pressure between the valve and the turbine inlet is
15bar and the turbine outlet pressure is 0.7bar. For
a turbine isentropic efficiency of 85%,
a. show the processes through the valve and turbine
on a T-s diagram,
b. determine the turbine work output per unit
mass,
c. what is the effect of your action on the turbine
work output?
6.36 Air enters an insulated diffuser operating at steady Figure 6.52 Two stage turbine with reheating
state at 1 bar, -3C, and 260m/s and exits with a
velocity of 130m/s. Employing the ideal gas model 6.40 An adiabatic air compressor is to be powered by a
and ignoring potential energy change, determine direct-coupled adiabatic turbine that is also driving a
a. the temperature of the air at the exit and the generator. Steam enters the turbine at 12.5MPa and
diffuser isentropic efficiency, 500°C at a rate of 25kg/s and exits at 10kPa and a
b. the maximum attainable exit pressure. quality of 0.92. Air enters the compressor at 98kPa
and 295K at a rate of 10 kg/s and exit at 1MPa and
6.37 Steam flowing at a rate 0.65kg/s enters at 10 bar, 620K. List your assumptions and determine :
400°C and 50m/s the nozzles of a Curtis Wheel. A a. the net power delivered to the generator by the
total of 10 identical nozzles are located on a row of turbine,
the wheel and the pressure at the exit of nozzles is b. the rate of entropy generation within the turbine
2 bar. and the compressor during these processes.
a. Calculate the steam velocity at the nozzle exit
for isentropic nozzles, and for nozzles having 6.41 Liquid water enters a 10kW pump at 100kPa pressure
isentropic efficiency of 83-percent. at a rate of 1.5kg/s. Determine the highest pressure
b. Determine the inlet and the outlet cross sectional the liquid water can have at the exit of the pump.
areas of each nozzle for both cases of part (a). Neglect the kinetic and potential energy changes of
water, and take the specific volume of water to be
6.38 Liquid water at a temperature of 25°C, and 1.5 bar 0.001m3/kg.
with a mass flow rate of 1.1kg/s is used as part of
non-adiabatic mixing chamber to cool steam with 6.42 Fire fighters working in a shipyard desire to have a
a mass flow rate of 1.2 kg/s from a pressure of 1.5 pump with the following minimum requirements; 1.the
bar and a temperature of 200°C to a pressure of 1.5 minimum height of the sea water jet at the exit of the
bars and a quality of 40%. The surface temperature pump must be 25 meters, 2.the minimum flow rate of
of the mixing chamber is 127°C. Determine, sea water through each pump must be 0.052m3/s. The
pump suggested by a company consumes 6.5kW of
a. the heat transfer from the mixing chamber,
power, and has an efficiency of ηp=0.72. Determine
b. the entropy generation in the mixing chamber if this pump is suitable for the fire fighters.
c. the maximum surface temperature that heat
transfer can take place. 6.43 The room air at 100 kPa, 30°C with a flow rate of
5m3/min enters the evaporator section of an air
6.39 Water is the working fluid of a two-stage turbine conditioner unit. The refrigerant (R134a) of the
system as shown in Figure 6.52. Superheated vapor system at the inlet of the evaporator is saturated
enters the first turbine stage at 8MPa, 480C and liquid at -20°C, and leaves as saturated vapor at the
expands to 0.7MPa. Then, it is reheated to 480C same pressure with a mass flow rate of 1.2kg/min.
before entering the second turbine stage, where it If the heat transfer from the room of 30°C to the
expands to the condenser pressure of 0.6 bar. The evaporator is 0.3kW, determine,
270 THERMODYNAMICS
Take the heating value of natural gas as Hu=37800kJ 6.50 As shown in Figure 6.58, air with a mass flow rate
per normal m3, and determine, 1.2kg/s at 95kPa, 10°C is compressed to 2.0MPa by
a. the amount of water to be circulated, isentropic two-stage compressor. At the intermedi-
b. how much natural gas in percent the regenerator ate pressure, the air is cooled down to 10C by an
will save per year? intercooler. Determine,
c. the percentage of annual reduction in entropy a. the intermediate pressure for the minimum power
generation. input to the compressor,
b. the total power required,
c. the mass flow rate of water through the intercooler
for 10C temperature change of the cooling
water.
d. Show the overall compression process of air on
T-s diagram
e. Repeat (b), (c) and (d) for isentropic efficiency
of 0.8 of each stage of the compressor.
6.71 As in Figure 6.65, a tank of 5m3 of volume contains 6.75 Using mathematical and thermodynamic relation-
pressurized air at 20 bar, 400C. The tank is con- ships, write algebraic expressions for the following
nected to an air turbine which exhausts the air into
partial derivatives: a. S / U , b. V / U T ,
the atmosphere at (po=1bar, To=7C) by a reversible v
c. F / V s
and adiabatic process. Neglect the volume occupied
by the connecting pipes and determine,
a. the amount of air discharged through the turbine 6.76 Using, du Tds pdv and appropriate Maxwell’s
until the flow stops. relations find out a relation for u / p T that only
b. the amount of work received at the turbine
shaft. parameters p, v, T, and are involved. Determine
c. Calculate the exergy change of air and compare the value of this partial derivative, u / p T , for
this change with the shaft work.
an ideal gas.
CHAPTER 6 ENTROPY: A SYSTEM DISORDER 275
6.77 Starting with the fundamental equation, Water vapor initially at 280bar and 440C is heated
dh Tds vdp and using Maxwell’s relations, isothermally to a pressure of 320bar. Estimate the
ideal gas deviation in specific enthalpy and entropy
express h / v T and h / T v in terms of p,
by considering the critical point data as, pc 22.12
T, and v. MPa, Tc 374.15 C for water. Take a 0.147 and
Hint: Use relations like cv u / T v T s / T v b 0.087 .
wherever applicable. 6.83 The triple point data of water is given as following:
6.78 Show that the dependence of entropy on Gibbs free ptp 0.61kpa, Ttp 0.01C .
energy and enthalpy may be described as following:
a. b. c. d.
6.81 Copper 22kg of mass at 27C and 100kPa is first Figure 6.66 Ice skating blade
heated reversibly to 227C and then compressed
isothermally to 100Mpa of pressure. Determine,
6.84 The saturation pressure and the enthalpy of vapor-
a. the volume at its final state, ization of R22 at 20C are respectively tabulated as
b. the entropy change, 9.1 bar, and 187.28kJ/kg. Estimate the saturation
c. the work done, pressure at 0C and determine the percent error by
d. the heat transfer, comparing with the tabulated value of 4.9811 bar.
e. the internal energy change of copper.
Hint: Consider that the final state is reached by two
processes as; isobaric heating and then reversible iso-
thermal compression. Express V, S and U accordingly.
space is filled with CO2 gas at ambient pressure. b. Entropy of a closed system performing
The liquid oxygen flows through the line at 100K, a reversible process can never decrease.
and most of the carbon-dioxide gas in the annulus
will freeze, and accumulate on the inner wall. The c. The entropy of R134a increases as it
pressure in this space will be the sublimation pres- flows through an expansion valve.
sure of CO2 at 100K. Since no available data at this
d. If an ideal gas compressed isentropi-
low temperature, carbon-dioxide pressure will be
approximated by the data at the triple point. Evalu- cally, its temperature always goes up.
ate the pressure of CO2 by considering that at triple e. The outlet of an actual turbine is at
point, Ttp 56.6C , ptp 510 kPa , and hsg 574.5 higher energy state than that of the same turbine
kJ/kg. operating ideally with the same inlet state and
the outlet pressure.
6.86 In throttling of gases, the change in temperature with f. The internal energy of a system and
respect to change in pressure at constant enthalpy
its surroundings is not conserved during an ir-
conditions is called Joule-Thomson coefficient J .
reversible process.
Depending upon the volume expansivity, the specific
volume, the constant pressure specific heat and the g. When a closed system with internal
temperature of the gas, show that J can be determined irreversibilities undergoes a process from state
v 1 to state 2, the entropy change is negative and
T v the entropy production is positive.
T p
as, J . Referring to the generalized
cp h. It is possible to compress air adiabati-
equation of state for real gases, pv ZRT , show cally from (1bar, 150C) to (2bar, 300C) inside a
closed device.
RT 2 Z
also that J .
pc p T p i. The relation pv k Constant corresponds
to an incompressible process.
6.87 An elastic rod has a length X and temperature T
when a tensile force of F is applied on its ends. The j. Mollier diagram is especially useful for
internal energy u and the entropy s of the system analyzing flow systems in energy interactions.
are determined by the following relations; u cT , k. In reducing the work consumption of
2 high pressure ratio compressors, multi-stage
s c ln T KX where c and K are constants.
a. Show that an equation of state for this system compression with intercooling is applied.
is F 2 KX 0 . l. The effectiveness of a heat exchanger
b. The elastic rod performs a Carnot cycle between compares the actual heat transferred with the heat
heat reservoirs at 87C and 27C. The minimum that would be transferred by an infinitely large
length at higher temperature is 2 meters, and exchanger operating at the same conditions.
the work extracted per cycle is 100 Joules. For
m. The stagnation conditions are those that
c 3.0 J/K, and K 5.5 Joules/m2K, evaluate
the maximum length of the rod at higher tem- would be obtained when the flow at any point
perature for engine efficiency of 10-percent. in the fluid stream was isentropically brought
to rest.
dp
6.88 Use the C-C equation, h fg Tv fg , to n. The critical conditions for a flow in a
dT sat
nozzle are those that would exist if the flow is
estimate the enthalpy of vaporization of R134a at accelerated until the Mach number is unity.
24C. Assume that for pressure difference of p 1
bar, the saturation temperature change is given as, o. When M 1 , velocity and area change
are in the same direction, and for M 1 , velocity
T 5.14 K.
and area change are in the opposite direction.
u The relation
p / v T v / T p T / p v 1 is valid
for all p-V-T state relations in solids, gases,
and liquids.
7. Using the methodology of your choice, you may 9. Rapid freezing of fresh fruit requires air at -34°C.
compute V / U T of a substance in terms of the A refrigeration system with R134a produces air at
measurable properties as the isothermal compress- this temperature by operating at -40°C of evaporat-
ing and +46°C of condensing temperatures. The
ibility, , the volume expansivity, , pressure, p ,
refrigeration system rejects heat to surroundings at
and temperature, T as following, 300C, and the isentropic efficiency of the system
compressor is 90-percent. The refrigerant leaves the
1 1 evaporator by +40C of superheat. The evaporator
T T
a. p , b. p , cooling load at steady conditions is 20kW. On these
operating conditions, the device that generates the
most amounts of entropy and its entropy generation
T T rate in kW/k are as follows,
c. p , d. p.
a. Evaporator, 0.1051,
b. Condenser, 0.0138,
c. Condenser, 0.1051,
d. Compressor, 0.1051.
The mixture properties depend not only on the properties of the individual gases (called
components) but also on the amount of each component. Hence, rules have to be developed
for estimating the mixture properties like the pressure, energy, enthalpy, entropy, etc., by
the similar properties of each component and the mixture composition.
279
280 THERMODYNAMICS
As shown in Figure 7.2, let us study the properties of a binary mixture (a mixture of two compo-
nents). Any extensive property of a mixture, H, may be formulated as, H f p, T , n A , nB . Then,
the change in H at the temperature and pressure of the mixture is,
H H
dH p,T dn A dnB (7.1)
n A nB , p ,T nB nA , p ,T
H H
In this formulation, H A and H B respectively define the partial proper-
n A nB , p ,T nB nA , p ,T
ties if both components A and B are at the same temperature and pressure of the mixture. Similarly, if
H is considered to be formulated as, H f V , T , n A , nB , then the partial properties may be defined
as each component is at the same temperature and volume of the mixture as,
H H
dH V ,T dn A dnB (7.2)
n A nB ,V ,T nB nA ,V ,T
Definition: The partial properties of a component ‘i’ in a mixture of n components may be defined in
two different methods: a. HA, represents the partial rate of change in that property caused by the only
*
change in the amount of A at the same temperature and pressure of the mixture. b. H A represents
the partial rate of change in that property caused by the only change in the amount of A at the same
temperature and volume of the mixture.
The above definitions are applicable to all extensive properties of a mixture as, V, U, H, S, F, and
G. Hence for a binary mixture, both definitions yield,
H p ,T H A n A H B nB
(7.3)
H V ,T H A n A H B nB
* *
Two types of fractions are defined and used in mixture analysis. For molar or volume analysis,
the mole fraction ( yi ) is used. For gravimetric analysis, the mass fraction ( xi ) is determined and both
of these fractions are expressed as following,
CHAPTER 7 GAS MIXTURES & PSYCHROMETRY 281
yi ni / n , n n
i
i and xi mi / m , m m
i
i (7.4)
In calculating the mean molecular mass of the mixture, however, the total mass of the system has
to be known as, nM m n1M 1 n2 M 2 .. nn M n , then the mixture molecular mass becomes,
Mm yM
i
i i (7.5)
After determining the mean molecular mass, conversion between mole and mass fractions can
be done as following,
Mi
xi yi (7.6)
Mm
The most common gas mixture of nature is the atmospheric air, and for all practical purposes, the
composition of atmospheric dry air is considered to be constant as provided in Table 7.1.
Table 7.1 Properties of Atmospheric dry air
yM i i 28.96
Since the existence of Argon and Carbon dioxide is negligibly small, for approximate calculations,
the atmospheric dry air may be assumed to be as indicated in Table 7.2.
Table 7.2 Approximate composition of atmospheric dry air
Example 7.1 A tank of 0.5m3 of volume contains 0.35kg of carbon monoxide (CO), 0.65kg of carbon dioxide (CO2), 1kg
of sulfur trioxide (SO3). Calculate,
a. the mass fraction, the mole fraction of each constituents and the molar mass of the mixture.
b. the amount of carbon monoxide to be pumped into the tank to increase the mass ratio to 20-percent.
282 THERMODYNAMICS
Solution:
a. The following table may be prepared for mass and the mole fractions of the constituents.
Constituents mi Mi ni mi / M i xi yi yi M i
As indicated on the table above, the molar mass of the mixture is 50.3kg.
b. To increase the carbon monoxide mass fraction to 20-percent, the following relation should hold, 0.35 x 0.2 2 x
and the mass of CO to be pumped x 0.0625 kg.
In chapter 2, first, p-v-T behavior of ideal gas model of a pure substance is studied. Then p-v-T
behavior of real gasses followed. The same sequence may be considered for studying the properties
and p-v-T behavior of non-reacting ideal gas mixtures and real gas mixtures. However, similar to the
state principle introduced for a single substance, one has to know the number of independent properties
(degrees of freedom) required to identify the state of a mixture of n components. In determining the
degrees of freedom of a gas mixture with n components, Gibbs phase rule may be applied.
Hence, for a binary gas mixture, n = 2, since both substances are in gas phase, p=1, then the
number of variables required to fix the state of a system is, f = 2 – 1 + 2 = 3. Thus, three properties,
usually p, T, and x1 are specified to identify a particular state of the mixture.
Example 7.2 Determine the number of independent prop-
erties to be specified for water under phase equilibrium as in
Figure 7.3.
a. Two phases are in equilibrium,
b. Three phases are in equilibrium.
Solution:
a. For two phases in equilibrium, the number of compo-
nents of the system, n 1 , and the number of phases,
p 2 , then f 1 2 2 1 . Only the temperature
or the pressure can vary.
Principle 24: When the effect of dissimilar molecules on each other in a mixture
is negligible, then each gas component in the mixture behaves like it exists alone
at the mixture temperature and volume.
If a gas mixture obeys the above principle then it is called ideal gas mixture. For an ideal gas
mixture, then the partial property of component ‘i’ becomes the property of the pure substance at the
same volume and temperature of the mixture. For instance, the internal energy of a mixture is ex-
U U 0 V ,T
n u u
i 0 . For an ideal gas mixture, the internal energy of each
pressed as, is i i V ,T
component
independent of volume and expressed as, u u0 i cvi T T0 . Thus, substitution
yields the internal
energy of the mixture as following,
u u0
y c T T
i
i vi 0 (7.7)
The same procedure may be followed for determining the enthalpy and the entropy of an ideal
mixture as,
h h0
y c T T
i
i pi 0 (7.8)
s s0 y s s
i
i 0 i (7.9)
If the ideal gas mixture is treated as a single gas, then the corresponding specific heats may be
expressed as,
c pm (kJ/kmolK) yc
i
i pi cvm (kJ/kmolK) yc
i
i vi (7.10)
or
c pm (kJ/kgK) x c
i
i pi cvm (kJ/kgK) x c
i
i vi (7.11)
The same principle, however, does not work for relating the intensive properties; properties like
pressure and specific volume of the components.
Example 7.3 Express the mole volume of a binary mixture in terms of partial mole volumes of constituents at the same
temperature and volume as the mixture. Show that intensive mole properties of a mixture cannot be represented by partial
properties.
284 THERMODYNAMICS
Solution:
Each component occupying the same volume V, the specific mole volumes expressed as, v A V / n A , vB V / nB . In ac-
cord with Eq. (7.2), the following relation should hold, v v A vB . However, n n A nB and if we divide both sides by
n n A nB 1 1 1
the mixture volume V, or and this result is quite different from Eq. (9.2).
V V V v v A vB
Hence for determining the intensive properties of a mixture Dalton’s rule of additive pressures
or Amagat’s rule of additive volumes have to be utilized instead.
Principle 25: (a) The pressure of a gas mixture is the sum of contributing pressures
of each component gas. The partial pressure of component ‘ i ’ is evaluated when
all other components are removed but the volume and the temperature remained the
same. This is known as Dalton’s rule of additive pressures. (b) The volume of a gas
mixture is the sum of the volumes of each component evaluated at the mixture pressure
and temperature. This is also known as the Amagat’s rule of additive volumes.
As shown in Figure 7.4, if one applies the Dalton’s rule to a binary mixture, the pressure of the
mixture at V and T becomes, p V , T p A V , T pB V , T . Here, the partial pressure of each com-
ponent is quite different from the definition given by Eq. (7.3). In regard to Amagat’s rule, however,
the volume occupied by the mixture at (p, T) is expressed as, V p, T VA p, T VB p, T . These
results can be generalized for a mixture with n component as,
n
p V , T
p V ,T
i 1
i
n
(7.12)
V p, T Vi p, T
i 1
Since both expressions in the set of Eq. (7.12) yield identical results for ideal gases, there is no differ-
ence between these two rules for ideal gas behavior. In fact, for an ideal gas component being at the
temperature and volume of the mixture, the partial pressure is piV ni T , or being at the temperature
and pressure of the mixture, the partial volume is pVi ni T and the ratio of these two expressions
to pV nT yields,
ni pi Vi
yi (7.13)
n p V
CHAPTER 7 GAS MIXTURES & PSYCHROMETRY 285
The mole fraction of component i indicates the volume ratio as well as the partial pressure ratio
of that component. If one considers the equation of state for component i on mass basis, piV mi RiT ,
T
since p
pi
V
mi Ri then the gas constant of the mixture becomes,
R x R (kJ/kgK)
i i (7.14)
Since cp, cv, and R values of an ideal gas mixture can be evaluated by the corresponding values of
its constituents, as illustrated in the following examples, processes related to ideal gas mixtures can
be reduced to a process of a single gas.
Example 7.4 As shown in Figure 7.5, 0.1kg of combustion gases in an engine cylinder initially at p1 150 bar, V1 0.0022 m3
has the following volumetric analysis: 5%CO, %12CO2, 8.5%O2 and 74.5%N2. In accord with the relation pv1.3 Constant ,
the gas expands reversibly through a volume ratio of 7:1 in the cylinder. Determine,
a. the work done by the gas,
b. the heat transfer through the engine cylinder wall,
c. the entropy change of the gas mixture
Solution:
The following table calculates the molar mass, the mass fractions of each component, the mixture gas constant and the
constant pressure specific heat by considering the mixture composition.
Component yi Mi yi M i xi Ri xi Ri c pi xi c pi
p1V1 p2V2 .
a. With respect to the results on the table above, R 0.274 kJ/kgK, c p 1.1 kJ/kgK, and the work done W12
n 1
n 1.3
p2 v1 1
Due to polytropic expansion, 0.0796 , p2 11.95 bar, V2 0.0154 m3 and the work is
p1 v2 7
W12 48.65 kJ.
286 THERMODYNAMICS
b. Apply 1st law to the piston-cylinder device as, Q12 U 2 U1 W12 where, U 2 U1 mcv T2 T1 and
p1V1 15000 0.0022
cv c p R 0.826 kJ/kgK, T1 1204 K, and T2 671.6 K. Hence the internal energy
mR 0.1 0.274
change becomes, U 2 U1 43.97 kJ, and the heat to be supplied is, Q12 4.68 kJ.
c. The entropy change of the mixture is S m s2 s1 , since the mixture properties are known,
Example 7.5 Combustion gases of a fuel have the following volumetric analysis: 9.87%CO2, 4.00%CO, 14.2%H2O,
0.9%H2, 71.03%N2. As illustrated in Figure 7.6, the combustion products at 400C enter to the economizer of a boiler with
a mass flow rate of 2.1kg/s. If the gas temperature drops to 150C at the economizer exit, determine the mass flow rate of
water so that its temperature will be increased by 70C.
Solution:
With respect to mixture composition, the following table determines the molar mass, the mass fractions of each component,
and the constant pressure specific heat of the mixture at the average bulk temperature.
Component yi Mi yi M i xi c pi xi c pi
CO2 0.0987 44 4.342 0.155 1.02 0.1581
CO 0.040 28 1.12 0.04 1.065 0.0426
H2O 0.142 18 2.556 0.0915 1.985 0.1816
H2 0.009 2 0.018 0.00064 14.52 0.0093
N2 0.7103 28 19.88 0.712 1.056 0.752
∑ 27.924 1.143
For steady state conditions, with negligible kinetic and potential energy changes, if we apply the 1st law to the econo-
2.1 1.143 250
mizer, the following result is obtained: m mc pm Tin Tex m wc pwT , or m w 2.05 kg/s. Hence,
4.18 70
m w 7.38 tons of water can be heated from 20C to 90C per hour.
CHAPTER 7 GAS MIXTURES & PSYCHROMETRY 287
Example 7.6 “Entropy increase in mixing of ideal gases.” As in Figure 7.2, let us consider two different gases, nA
moles of gas A at pressure p, and temperature T, be mixed with nB moles of gas B at the same pressure and temperature in
an adiabatic chamber of constant volume. Formulate the entropy increase for this process.
Solution:
0 0
If we apply the 1st law to the entire chamber of Figure 7.2, dU Q W 0 and dU ncv dT , hence the temperature
is kept constant for adiabatic mixing. Similarly, the final pressure is p, but the components assume partial pressures after
the mixing, p A y A p and pB yB p . The entropy change of the system is Sm S A S B . For isothermal process,
p p
the entropy change of each component becomes, S A n A ln A and S B nB ln B . Finally, the entropy
p p
Due to mixing of different gases, the entropy of the system increases and the system exergy decreases.
The irreversibility of the mixing process or the amount of exergy destroyed can be calculated by,
Example 7.7 An ideal mixture of 2kmol Helium (He) and 1kmol of Hydrogen (H2) contained in a piston-cylinder device
initially at a state of 2bar, 40C is compressed isentropically to a pressure of 10bar. Determine,
a. the final temperature of the mixture and the amount of work done,
b. the entropy change of each component.
Solution:
/ y c
n c ln TT n ln pp T2 p2
i pi
2 2 0 . Hence, the temperature ratio becomes and with the
T1 p1
i pi
1 1
W12 n y c T T or W
i vi 2 1 12 3 15.158 707.2 313 17925.85 kJ.
b. The entropy change of Helium is, S He nHe c p ln T2 ln p2 . Since the content of each component
T1 p1 He
does not change, the ratio of partial pressures is the same as the ratio of total pressures. Thus,
707.2 10
S He 3 20.77 ln 8.314 ln 4.427 kJ/K and the entropy change of Hydrogen gas will be
313 1
+4.427kJ/K so that the sum is assured to be zero.
288 THERMODYNAMICS
pcm y p i ci Tcm y T
i ci (7.18)
Together with the critical values evaluated by Eq. (7.18), the generalized compressibility chart
can be used for studying p-V-T behavior of the gas mixture. Similar mixing rules can be generated
for studying p-V-T behavior of gases by analytical methods. For instance, Van der Waals equation
of state, Eq. (2.25), might be appropriate if the constants “a” and “b” of the equation are evaluated
by the following rule: am
yi ai , bm
yi bi . However, Van der Waals originally proposed the
following rule in evaluating the equation constants as,
y
2
am i ai bm yb
i i (7.19)
Example 7.8 An insulated rigid tank having 200L of volume contains a mixture of 85 % methane and 15 % ethane gases
on mole basis at 3.5MPa, and 40C. Accidentally, the valve on the tank opens and the pressure inside quickly drops to 2MPa
before the valve is closed. For atmospheric pressure of 1bar, calculate the mass that escapes from the tank by assuming that
Kay’s rule is applicable.
Solution:
Apply the 1st law to a control volume including the tank and the escaped gas mixture: u2 u1 p0 v2 v1 and the enthalpy
change is, h2 h1 p0v2 p0v1 p2v2 p1v1 . The enthalpy change can be expressed with respect to deviations as,
h1* h1 h* h p0
Tcm
Tcm
Tcm 2 2
Tcm yc i pi T2 T1
p
2
1 Z m 2T2 p1 p0 v1 . Assuming the final temperature
as T2 300 K , this relation may be solved by trial and error method. In addition to the compressibility chart, the enthalpy
correction chart has to be used.
Component yi pci (bar) Tci (K) yi pci (bar) yiTci (K) c pi (kJ/kmolK) yi c pi
h1* h1
pcm 46.76 bar, Tcm 208.1 K; pr1 0.748 , Tr1 1.5 , Z m1 0.945 , and 0.25 .Similarly, at pr 2 0.42 ,
Tcm
h2* h2 0.945 8.314 313
Tr 2 1.44 , Z m 2 0.965 , and 0.2 , v1 0.702 m3/kmol. Substituting these values into the
Tcm 3500
above relation and solving for T2 results as, T2 312.4 K. There is no need to repeat the calculations.
Use Eq. (7.5) for the molar mass of the mixture, M m 0.85 16 0.15 30 18.1 kg/kmol, the number of initial
3500 0.2 2000 0.2
and final moles; n1 0.284 , n2 0.159 . The amount of mass escaped,
0.945 8.314 313 0.965 8.314 312.4
m M m n1 n2 2.26 kg.
Example 7.9 A piston cylinder apparatus contains 0.362kg of the same mixture as in Example 7.8 and initially occupies a
volume of 2L at 40C. The mixture is compressed isothermally until the volume is reduced by 50-percent. Assume that the
mixture obeys Van der Waals equation of state, and calculate,
a. the initial pressure in the cylinder,
b the work done.
Solution:
a. To reduce the mixture to a single gas behavior Eq. (7.19) has to be used. Hence,
2
am 0.85 232.4 0.15 557.1 272.19 and bm 0.85 0.0427 0.15 0.065 0.046 .
Since the molar mass is M m 18.1 kg, the mole number, and the initial molar volume respectively are,
0.362 0.002
n 0.02, v1 0.1 m3/kmol. Then the pressure is calculated by Van der Waals equation as,
18.1 0.02
8.314 313 272.19
p1 20971 kPa.
0.1 0.046 0.12
2
v2 bm 1 1
b. the work is w12
pdv T ln v b
1
1 m
am or
v2 v1
0.05 0.046 1 1
w12 8.314 313 ln 272.19 4051 and the total work is
0.1 0.046 0.05 0.1
W112 4051
4051 0.02 81.02 kJ.
290 THERMODYNAMICS
The gas sample is usually at atmospheric pressure. The temperature and thus the density of gas are
held constant by water jacket around the burette. The pipettes are interconnected and contain different
chemicals to absorb CO2, CO, and O2. For instance, pipette 1 contains KOH for absorption of CO2.
Each pipette also contains a number of small tubes for increasing the absorption surface area. The
constituents are chemically absorbed one by one and the remainder volume of the sample is measured
after each absorption process. The difference in volume gives the partial volume occupied by the
constituent in that mixture. Since the temperature of the sample gas is reduced below the saturation
temperature of water vapor present, Orsat’s apparatus gives analysis of dry products of combustion.
The dry product analysis, on the other hand, may be used to calculate the air-fuel ratio of combustion
processes.
Example 7.10 A sample of flue gases from a coal fired boiler is analyzed by an Orsat’s apparatus and the following volu-
metric analysis is provided: 11.4% CO2, 0.5% CO, 6.5% O2 and 81.6% N2. The gravimetric composition of coal is given
as; carbon 80%, hydrogen 5%, oxygen 4% and non-combustibles are 11%. Determine,
a. the mass of dry flue gases per kg of coal,
b. the total mass of flue gases per kg of coal,
c. the mass of excess air per kg of coal.
Solution:
a. The first step in determining the mass of flue gases is to convert the volumetric analysis into gravimetric ratios as
presented in the table below.
CHAPTER 7 GAS MIXTURES & PSYCHROMETRY 291
Gas Mole fraction, Molecular mass Mass in the mixture Mass fraction
(y%) M(kg) x yM (kg) (x%)
CO2 0.114 44 5.016 16.67
CO 0.005 28 0.14 0.465
N2 0.816 28 22.84 75.94
O2 0.065 32 2.08 6.91
Sum 30.076
3 3
Amount of carbon per kg of flue gas= carbon in (CO2) + carbon in (CO) = 11 0.1667 7 0.00465 0.0474
kg carbon/kg gas.
The stoichiometric coefficients are calculated as following:
Coal gravimetric analysis indicates that 1 kg of coal contains 0.8kg of carbon. Thus the mass of dry flue gas per kg of
0.8
coal is, mg dry 16.877 kg/kg-coal.
0.0474
b. Together with the stoichiometric equation between hydrogen (H2) and oxygen (O2), the amount of vapor created by
0.05kg of hydrogen is: 9 0.05 0.45 kg-water/kg-coal. Hence the total mass of flue gas per kg of coal becomes
mg 16.877 0.45 17.32 kg/kg-coal.
c. Considering the above table and allowing oxygen for unburned carbon monoxide, the mass of excess oxygen per
kg of flue gas is,
4
mo2 0.0691 0.00465 0.0664 kg/kg-gas, or per kg of coal, mo2 0.0664 16.877 1.12 kg/kg-coal. The amount
7
100
of excess air containing the required amount of oxygen is mair 1.12 4.87 kg-air/kg-coal.
23
7.3 Moist Air and its Psychrometric Properties
As indicated in Figure 7.9, atmospheric air is a mixture of dry air, water vapor, and pollutants.
Even though the composition of dry air is fairly constant, the content of water vapor and pollutants in
atmospheric air may vary with respect to the location in the atmosphere. However, the pollutants can
be filtered out by a process and then what is left is a mixture of dry air and certain amount of water
vapor. The combination of dry air and water vapor is called moist air.
As illustrated in Table 7.2, the composition of dry air is fairly constant. Hence, in air conditioning
processes, the amount of water vapor may be changed from zero value to a maximum depending on
the temperature and the pressure of the mixture. On the basis of real gas behavior, it is quite difficult
292 THERMODYNAMICS
to estimate the exact thermodynamic property values of moist air. Up to 300 kPa of pressure, however,
moist air can be treated as an ideal gas mixture with accuracy sufficient for engineering calculations.
For such cases then, Dalton’s rule of additive pressures yield the total barometric pressure of moist
air as,
p pa pv (7.20)
where pa ma RaT / V and pv mv RvT / V are the partial pressures of dry air and water vapor
respectively.
In analyzing the moist air properties, the following terms are frequently used and need to be
defined.
Definitions: Saturated air is a mixture which contains the maximum amount of water vapor at a given
temperature and pressure. Dry bulb temperature (DBT) is the temperature of the moist air measured
by any temperature measuring instrument. Saturated vapor pressure ( pvs ) is the partial pressure of
water vapor that corresponds to the saturation pressure at the given temperature of the mixture.
For moist air temperatures in the range of 0°C and 100°C, ASHRAE (American Society of Heat-
ing Refrigerating and Air conditioning Engineers) suggests the following regression equation for
saturated vapor pressures,
a1
ln pvs a0 a1T a2T 2 a3T 3 a4 ln T (7.21)
T
where T is in K, and the regression coefficients respectively are, a1 5800.2 , a0 5.516 ,
a1 0.04864 , a2 0.0000417 , a3 0.0000000144 , and a4 6.545 .
Definition: Relative humidity () is the ratio of mole fraction of water vapor in moist air to the mole
fraction of water vapor in saturated air both at the same temperature and pressure.
Since, nv pvV / T and nvs pvsV / T then, the relative humidity may be expressed as,
nv p
v (7.22)
nvs pvs
Definition: Humidity ratio ( ) is the amount of water vapor per kilogram of dry air and is also
called specific humidity ( mv / ma ).
The mass of dry air and water vapor respectively are, ma paV / RaT , mv pvV / RvT where
Ra 0.287 kJ/kgK, and Rv 0.4618 kJ/kgK. Then, the humidity ratio becomes,
pvV / RvT pv pv
or 0.622 0.622 (7.23)
paV / RaT pa p pv
As indicated by this relation, specific humidity is a function of both the total pressure and the dry
bulb temperature (DBT) of the mixture.
CHAPTER 7 GAS MIXTURES & PSYCHROMETRY 293
Definition: If the unsaturated moist air is cooled at constant pressure then Dew point temperature
(DPT) is the temperature at which the moisture starts to condense.
As illustrated in Figure 7.10, when unsaturated moist air at state (1) is cooled down, the partial
pressure of vapor remains constant until state (2) is reached. The temperature at state (2) is called the
dew point temperature ( T2 DPT ) of state (1) and is the saturation temperature corresponding to the
partial pressure of vapor. Hence the dew point temperature can also be obtained from steam tables.
Since the mixture at state (2) is saturated, some of water vapor condenses as the cooling process con-
tinues. As indicated by state (3), the mixture is always at saturated state, but due to condensation, the
partial pressure of vapor decreases. With respect to relative humidity () and DBT of the mixture,
the dew point temperature may be approximated by the following equation.
Solution:
a. Equation (7.22) yields pv pvs , pvs 7.82 kPa at 410C, and pv 7.12 kPa is the partial pressure of water
vapor.
7.12
b. Use Eq. (7.23) as W 0.622 0.048 kg-water/kg-air.
99.34 7.12
294 THERMODYNAMICS
c. By steam tables, the saturation temperature at pv 7.12 kPa is 38.90C. The use of Eq. (7.24) results as following,
4030 41 235
DPT 235 39.2 0C which deviates by 0.7-percent from the table reading.
4030 41 235 ln 0.91
As shown in Figure 7.11, processing of moist air at steady state conditions, the mass, energy and
the entropy balances may be expressed as,
Continuity: m a1 m a 2 m a
m v1 m v 2 m f 2 (7.25)
Q12 ma cva T2 T1 mv 2uv 2 mv1uv1 m2 f u2 f (7.28)
Even though, the above relations are written on an unmixed component basis, it can also be de-
fined on premixed mixture basis.
Definition: The enthalpy ( h ) of most air is the sum of enthalpy of dry air and water vapor ( h ha hv ).
This definition of enthalpy is especially useful for psychrometric chart applications. Since the energy
values are always based on the same reference state, the enthalpy of dry air and water vapor are both
zero at 00C. Then, together with approximate values of cpa and cpv, the mixture enthalpy becomes,
h c paT h fg c pvT or h 1.005T 2501 1.88T (7.29)
CHAPTER 7 GAS MIXTURES & PSYCHROMETRY 295
Example 7.12 A piston-cylinder apparatus contains two kilograms of air and water vapor mixture at 200C, 100 kPa, and
80 % relative humidity. The mixture is compressed at constant temperature to 200 kPa. Determine,
a. the final relative humidity and humidity ratio
b. the mass of liquid water condensed
c. the amount of work done.
d. the amount of heat transfer
Solution:
a. The humidity ratio at state (1), pv1 1 pvs 0.8 2.34 1.872 kPa, and use of Eq. (7.23) yields,
1.872
1 0.622 0.0118 . Let us consider an intermediate state (2) at which the condensation just starts
100 1.872
and find out the total pressure of the mixture at that state. For 1 2 , and pv 2 pvs 2.34 kPa, Eq. (7.23) yields,
2.34
0.0118 0.622 , p2 125.68 kPa. Since p3 p2 , some of water vapor will condensate as the pressure
p2 2.34
reaches 200 kPa at 200C.
pa1V1 pv1V1
The volume occupied by the mixture at state (1), 2 or V1 1.693 m3. The values of ma and mv1
RaT1 RvT1
98.128 1.693
respectively are ma 1.975 kg, mv1 2 1.975 0.025 kg. At state (3),
0.287 293
2.34
3 0
0.622
622 0.00736
200 2.34
b. The amount of condensation is m f 3 mv1 mv3 and mv3 0.00736 1.975 0.0145 kg, then
m f 3 0.025 0.0145 0.0105 kg.
pa 2
c. pa 2 123.34 kPa, pa 3 197.66 kPa, V2 1.351 m3, and V3 V2 0.843 m3. The work done by dry air is
pa 3
pa1
W13 a ma RaT ln 1.975 0.287 293 ln(98.128 / 197.66) or W13 a 116.301 kJ. The work of water
pa 3
vapor is calculated at two steps, W12 v 0.025 0.462 293 ln(1.872 / 2.34) 0.755 kJ , W23 v pvs V3 V2
W23 v 2.34 0.843 1.351 1.188 kJ. The total work then is
d. Apply the 1st law between states (1) and (3), Q13 W13 m f 3h fg or
Example 7.13 One means of condensing steam during an emergency blow down of a nuclear reactor is to use of containment
vessel. The vessel is insulated and has a total volume of 30m3 with liquid water initially occupying 1m3. The initial state inside
the vessel is 350C, and 100kPa. For a short period of time, 55 kg of water from reactor enters the vessel at an average state
of pi 700 kPa, xi 0.5 . Find the temperature and pressure inside the vessel at the end of this water entrance period.
Solution:
At initial state, pv1 pvs 5.62 kPa, pa1 94.38 kPa, and the volume occupied by saturated air, V1 29 m3. Hence,
94.38 29 5.62
ma 30.96 kg, 1 0.622 0.037 , mv1 0.037 30.96 1.145 kg, mw1 1000 1.14 1001.14 kg,
0.287 308 94.38
1.14
x1 0.001 , u1 146.67 0.001 2276.73 148.94 kJ/kg, and the enthalpy of inlet water is hi 1730.37 kJ/kg.
1001.14
After the water inlet, the final total mass of water in containment becomes, mw2 mw1 mi 1056.14 kg, and air is still
T2 psv 2 T1
saturated at state (2) for which Pa 2 pa1 . The mass of vapor is mv 2 0.622ma (a)
T1 pa1 T2
1st law for the containment hi mi mv 2uv 2 mw2 mv 2 u f 2 ma cva T2 T1 mw1u1 (b)
Apply trial and error method to solve equations (a) and (b) simultaneously. Assume T2=530C, and by Eq. (a) mv 2 2.65 kg
,and u f 2 209 kJ/kg, uv 2 2449 kJ/kg and substitute these values into Eq. (b) to find a new temperature, T2=52.50C.
m a ha1 ha 3 m v1 hg1 h f 2 m v 3 h f 2 hg 3 0 (7.30)
where, T3 T2 and h fg 2 hg 3 h f 2 . The wet bulb temperature of moist air at state 1 is indicated
by temperature T2. Hence, knowing the temperatures DBT(T1) and WBT(T2), Eq. (7.31) calculates the
humidity ratio of state 1. The WBT temperature like DBT is a property of moist air and is independent
of path. The thermodynamic wet-bulb temperature (T2) is always less than the DBT (T1) but greater
than the dew point temperature (DPT).
7.3.3 Psychrometer
In accord with Gibbs phase rule, three independent properties are required for measuring the
psychrometric state of moist air. Two of these parameters are usually the barometric pressure and
the dry bulb temperature (DBT). Due to inaccuracies involved in measurement of humidity ratio, the
third parameter is again depicted to be a temperature and is the wet bulb temperature (WBT) of moist
air. The sling psychrometer, as shown in Figure 7.15a, is widely used for measurements involving
room air applications.
The sling psychrometer consists of two thermometers and is fitted in a frame with a handle for
swinging in air as shown in Figure 7.15b. Readings are taken when both thermometers indicate the
steady state values.
298 THERMODYNAMICS
Figure 7.16 illustrates graphically the thermodynamic properties of moist air and is readily avail-
able for standard barometric pressure of 101.32 kPa at sea level and for temperatures between 0°C and
50°C. ASHRAE has also developed psychrometric charts for other temperatures and pressures such
as a chart for low temperature (-40°C to 10°C) and a chart for high temperatures (100°C to 120°C).
In solving moist air problems by a chart, first the barometric pressure that the system works has to
be known. Then, as shown in Figure 7.17a, the state of moist air is located by two independent proper-
ties like DBT1 and 1 , and the unknown properties like WBT1, 1 , h1 etc. can be read on chart. Figure
7.17b shows the directions of simple processes like sensible heating, cooling, and humidifying.
Example 7.14 The DBT and WBT temperatures of moist air at sea level respectively are 350C and 280C. Determine the
followings by using both a chart and related equations,
a. the humidity ratio,
b. the partial pressure of water vapor,
c. the relative humidity,
d. the moist air density,
e. the enthalpy
Solution:
a. After locating the given state on a psychrometric chart, 1 is 20.8 g/kg-air. Consider Eq. (7.31), to calculate the
3.78
humidity ratio at state (1), first the humidity ratio at WBT has to be determined, 3 0.622 0.024
101.3 3.78
and h fg 2 2552.6 117.4 2435.2 kJ/kg, hg1 h f 2 2565.3 117.4 2447.9 kJ/kg. Substitution of these values
c. The value of relative humidity by chart is 1 0.57 and the use Eq. (7.22) for numerical calculations results as,
1 pv1 / vs1 0.58 .
d. From chart, the moist air specific volume is v1 0.903 m3/kg-air, and the density becomes 1 1.107 kg/m3. To calcu-
late the density, consider ma / V1 p1 / Ra 1Rv1 T1 and after substitution of numerical values 1 1.108 kg/m3.
e. The enthalpy value by chart reading is h1 89.2 kJ/kg-air, and by Eq. (7.29) it can be calculated as h1 89.08 kJ/
kg.
7.4 Air Conditioning Processes
Air conditioning processes involve altering the temperature and the humidity of moist air so that
comfort conditions (DBT temperature in the range between 18°C and 22°C, with 40 to 50 % relative
humidity) are provided in dwellings. Since most of the air conditioning processes can be modeled as
steady flow processes, together with mass and energy balance equations (Eqs. (7.25) and (7.26)), the
psychrometric chart is an important tool in determining the final state and/or the heat load through
an air conditioning system. As shown in Figure 7.18a, whenever there is no moisture addition or
removal from air, the process is simply represented as a horizontal line on the chart. The following
fundamental processes are carried out in air conditioning applications.
Figure 7.18 Air conditioning processes: (a) sensible heating or cooling, and (b) humidification
300 THERMODYNAMICS
m s m a 2 1 (7.24)
Spraying water particles. The injected water particles are in liquid phase and the required heat
of vaporization for evaporation comes from moist air. As a result, the temperature of air stream de-
creases, but the wet bulb temperature is kept constant. Such process (line 1-3 in Fig. 7.18b) is also
called constant WBT process. A similar constant WBT process is called evaporative cooling process.
You probably notice that on a hot and dry summer day, the environment feels a lot cooler when water
is sprayed into the atmosphere in a café. This is because water absorbs heat from air as it evaporates.
The enthalpy of the mixture is constant ( WBT1 WBT3 ) but the DBT drops as on line 1-3 in Figure
7.18b for evaporative cooling.
Example 7.15 Saturated air at 5°C with a volumetric flow rate 150m3/min is required to be supplied to a conference room
where the temperature must be at 20°C with relative humidity 50%. As shown in Figure 7.19, air is first heated and then
water at 10°C is sprayed to provide the required humidity. Determine,
a. the temperature at which air must be heated,
b. the mass rate of hot water flowing through the heater for 7°C of temperature increase,
c. the mass required to be sprayed per hour.
CHAPTER 7 GAS MIXTURES & PSYCHROMETRY 301
Solution:
a. As shown on the schematic diagram, Figure 7.20, to determine the air temperature at the heater exit, the lines A
and B have to be crossed. The intersection is the exit state of air, and T2=26°C.
b. The required heat input by the exchanger is Q m a h2 h1 m wcT where air mass flow rate is m a V1 / v1 and
by psychrometric chart, v1 0.795 m3/kg and m a 150 / (60 0.795) , m a 3.145 kg/s. Hence the heater capacity
is, Q 3.145 41 20 66.045 kW, and the hot water flow rate becomes, m w 66.045 / (4.18 7) 2.26 kg/s.
c. The mass flow rate of sprayed water is calculated by m sw m a 3 1 3.145 8.3 6 103 kg/s or
m sw 26.04 kg/h.
7.4.3 Dehumidification
Dehumidification by cooling is a process by which the humidity ratio of moist air is reduced by
flowing through a cooling coil. As shown in Figure 7.21, the moist air is dehumidified after reaching
saturated conditions. Once the air becomes saturated, it remains saturated even if the temperature is
further decreased ( 2 1 ). After dehumidification, to reduce the relative humidity to a desired level,
the moist air has to be reheated ( 3 2 ) as by line (2-3) in Figure 7.21. The collected condensate
leaves the channel at the same temperature as air at the cooler exit. The heat capacity rates of the
cooling coil and the heater are,
Example 7.16 An air conditioning system for an industrial process has to be designed so that 250 m3/min of outside air at
350C and 60% relative humidity has to be processed to 250C with 55% relative humidity. The dew temperature on the coil
surface (T6) is known to be 120C. Show the process on psychrometric chart and calculate,
a. the mass of water removed per hour,
b. the cooling capacity,
c. the temperature at the cooler exit,
d. the heating capacity,
e. the percent error in cooling capacity if air at the cooler exit is assumed to be saturated.
Solution:
a. As shown in Figure 7.22, since the dew temperature on the surface
is 120C, the exit state of air has to be on line (1-6). The interaction
of lines (1-6) and (5-3) yields the coil exit (2) which indicates
that air may not be fully saturated at the exit. Hence by chart, the
thermodynamic values are v1 0.91 m3/kg, 1 0.023 , h1 95
kJ/kg, 2 0.0115 , h2 45 kJ/kg, T2 15 0C, h3 55 kJ/kg,
h6 39 kJ/kg, h f 2 62.9 kJ/kg. Then the mass flow rate of air
is, m a 250 / (60 0.91) 4.578 kg/s, and Eq. (7.24) yields,
m f 2 4.578 (0.023 0.0115) 3600 189.36 kg/h
b. Referring to Eq. (7.25), the cooling capacity is
Q c 4.578 45 95 0.023 0.0115 62.9 225.588 kW.
c. In accord with the chart in Figure 7.22, the air temperature at the
cooler exit is T2 15°C.
e. If air is assumed to be fully saturated at the cooler exit, then h f 5 50.41 kJ/kg, and the cooling capacity becomes
Q c 4.578 44 95 0.023 0.0115 50.41 230.824 kW. The percent error in estimating the capacity
Mixing without condensation. As shown in Figure 7.23, if two air streams are not at saturated
state then during the mixing process, no condensation will take place.
For an adiabatic mixer as shown in Figure 7.23, consider a control volume surrounding the mixer
and apply mass and energy balance equations to yield the mixture conditions as following,
m 1 2 3 h2 h3
(7.27)
m 2 3 1 h3 h1
The above equations reveal that the final humidity ratio and the enthalpy are weighted average of
inlet humidity ratios and enthalpies. Therefore, the final temperature of the mixture is the weighted
average of inlet temperatures and the state of the mixture will be on a straight line connecting the two
inlet states. If the ratio m 1 / m 2 has changed by keeping the inlet states fixed (the points 1&2 in Figure
7.23), the mixing state will still be on the same line connecting the two points but the final state be
moved to points like 3 or 3 depending on the magnitude of the mass ratio.
Mixing with condensation. When very cold air stream is mixed with very warm and humid air,
the state of the resulting mixture might be in two-phase region. As shown in Figure 7.24, since the
mixture cannot hold the liquid droplets, a certain amount of water vapor will condensate and the
resulting air stream will be saturated air at state 4. Such a process hardly occurs in air conditioning
systems, but when occurs, due to release of latent heat of condensation in this adiabatic system, an
increase in temperature of the mixture will take place (T4>T3).
304 THERMODYNAMICS
Solution:
kg/s. Similarly, psychrometric properties of cold air are: V2 4.167 m /s, 2 0.007 kg/kg-air,
3
T2 10 0C, v2 0.813 m3/kg, and m 2 4.167 / 0.813 5.125 kg/s. Since none of mixing streams is on saturated
2.285 0.007 3
state, no condensation will take place, and Eq. (7.27) is applicable as, 0.4458 . Solving
5.125 3 0.0176
0.0102
for 3 results as; 3 kg-v/kg-air. Together with a psychrometric chart in Figure 7.25, knowing that the
mixture state is on the line connecting the two inlet states, the mixture temperature and relative humidity respec-
tively are T3 20 °C, 3 68% .
b. As shown on chart in Figure 7.25, if air at state 3 is heated, the horizontal line crosses the constant relative humidity
curve ( 4 50% ) at temperature T4 25°C.
and evaporating some of water. As shown in Figure 7.26, the classification of cooling towers may be
done with respect to the draft type, the flow geometry, and the mode of heat transfer.
Understanding the advantages and limitations of cooling towers as classified in Figure 7.26 is
of vital importance to the project engineer. Figures 7.27a and b show a typical natural draft tower
which operates on the basis of air density variation (chimney effect) and is more effective in regions
of high relative humidity. In mechanical draft towers, Figure 7.27c, the air flow is caused by single
or multiple fans. Fans can also compensate changes in atmospheric and load conditions. Hence, the
thermal performance of mechanical draft towers is less affected by psychrometric changes in air.
Depending upon the air flow direction relative to the fan, the mechanical draft towers can be either
forced or induced draft type.
In counter flow towers, Figure 7.27c, air moves vertically upward through the fill and is in op-
posite direction to the downward motion of water. Due to high pressure losses of air at inlet and
outlet plenums, the counter flow configuration is generally appropriate for large capacity cooling
towers. The enclosed nature of counter flow tower, however, restricts the exposure of water to sun
and retards the growth of algae. The particular tower in Figure 7.27c may also be categorized as an
induced draft type tower.
In cross flow towers, Figure 7.27d, air flows horizontally through fill and crosses the downward
fall of water. This type of tower is especially useful in regions where prevailing wind directions occur.
The tower can be sited so that the air inlet section facing the prevailing wind direction, the power
needed for air circulation can be reduced.
All the towers types indicated above are evaporative type towers in which the cooling effect
is generated by evaporation of water droplets when air and water are brought into direct contact.
However, in sensible (dry) type towers no direct contact between water and air takes place. Water
is cooled by sensible heat transfer. Due to need of large heat transfer surface area, the use of such
towers is seldom.
306 THERMODYNAMICS
Figure 7.27 Cooling tower illustrations: (a) and (b) natural draft type (c) counter flow type
(d) cross flow type
The amount of water lost to air is, m w1 m w 2 m a a 2 a1 , and the water mass flow rate at
the tower exit becomes,
The energy balance along the control volume on the tower yields, m w1hw1 m w 2 hw 2 m a ha 2 ha1
,
and substitution of m w 2 in Eq. 7.28 into energy balance equation and rearranging results with the air
mass flow rate as following,
m a m w1
hw1 hw2
(7.29)
ha 2 ha1 a 2 a1 hw 2
The conditions within the cooling tower are typically such that the emerging air is very close to
100% relative humidity and is assumed to be saturated air at the tower exit. On the other hand, the
minimum temperature that can be attained by water at the tower exit is thermodynamically limited
to the WBT of the incoming air. However, such a temperature is only obtainable for infinitely tall
cooling tower and a reasonable achievable limit for exit water temperature is within 5K to 10K above
the WBT of the entering air.
Example 7.18 Warm water at 40°C from a power plant condenser enters the cooling tower at a flow rate of 400tons per
hour. The atmospheric air at 95kPa, 25°C, and 70% relative humidity is circulated through the tower and leaves the tower
at 35°C as saturated air. For a wet bulb temperature WBTa1=21°C of entering air estimate,
308 THERMODYNAMICS
Solution:
a. For WBTa1=21°C at the air entrance, the cold water temperature at the outlet may be taken to be Tw2 WBTa1 5 ,
Tw2 26 °C. The humidity ratio of air at the inlet and outlet respectively are,
0.7 3.16 5.62
a1 0.622 0.0238 kg-a/kg-water, a 2 0.622 0.039 kg-a/kg-water. The enthalpy
95 0.7 3.16 95 5.62
difference for water, hw1 hw2 167.5 109.07 58.43 kJ/kg, and for air is
ha 2 ha1 c pa T2 T1 a 2 hg 2 a1hg1 1.005 35 25 0.039 2565.3 0.0238 2547.2 49.47 kJ/kg.
58.43
By Eq. (7.29), the needed mass flow rate of air is m a 111.11 135.74 kg/s.
49.47 0.039 0.024 109.07
b. By Eq. (7.28), the amount of make-up water needed, m mu 135 0.039 0.0238 2.06 kg/s, or
m mu 7.43 tons per hour.
Assuming that water is at WBT of incoming air, then Tw Ta hi ha / c pm , and Eq. (7.30)
reduces to
A exit
hdA Te dT hA 1
c pm
4.18m w
Ti hi ha
or
c pm
4.18m w Te Ti
inlet hi ha
(7.31)
0
where Ti and Te are temperatures of water entering and leaving the tower, h is the convective heat
transfer coefficient, and hi is the enthalpy saturated air at water temperature. The value of hA / c pm
can be numerically determined by using a stepwise integration method. If air and water flow rates are
kept constant, the magnitude of hA / c pm essentially remains constant for a particular tower and is used
for predicting the tower performance at various water inlet temperatures. Cooling tower manufacturers
often treat the term hA / c pm as NTU (Number of Transfer Units) of the tower. Hence, the higher the
value of NTU, the better the performance of the tower is.
The tower characteristics can also be represented graphically as shown in Figure 7.29. In this figure,
water enters the tower at Tin, and exits at Tex. The corresponding saturated air enthalpies respectively
are hi ,in and hi ,ex . Similarly the air enthalpies at the inlet and exit are ha ,in and ha ,ex .
CHAPTER 7 GAS MIXTURES & PSYCHROMETRY 309
As shown in Figure 7.29, two terms are regularly used in performance analysis of cooling towers
and are defined as following: 1.Range is the temperature change of water through the tower, and 2.
Approach indicates the difference between the WBT of entering air and exit temperature of water.
A tower with a smaller approach and a larger range is always preferable and provides a higher value
of NTU.
Example 7.19 Warm water at 38°C from a condenser enters a counter flow cooling tower at a flow rate of 108 tons per
hour. The atmospheric air at 100kPa, DBT1=25°C, and WBT1=22°C ( 1 =70%) is circulated through the tower and leaves
the tower at 35°C as saturated air. Calculate NTU hA / c pm parameter of the tower.
Solution:
As indicated in Figure 7.29, the approach for the condenser is assumed to be 8K, then the water temperature at the condenser
exit is Twe 22 8 30o C . By the given data and by the psychrometric chart, the numerical values of the parameters in
Eq. 7.29 are a1 0.0148 , a 2 0.042 , ha1 63 kJ/kg, ha 2 146 kJ/kg and water enthalpy values are, hw1 159.2 kJ/kg,
33.41
hw2 125.79 kJ/kg. Hence, the required air mass flow rate becomes m a 30 12.59 kg/s.
83 0.042 0.0148 125.79
As shown in Figure 7.30, let us divide the tower into five sections (n=5) with identical water temperature drop at each
section as, T 38 30 / 5 1.6o C . The air enthalpy change of air at each section is ha (i ) ha (i 1) 4.18 30 1.6 / 12.59
or ha (i ) ha (i 1) 15.93 kJ/kg, ha 0 63 kJ/kg.
78.93 63
Section 1: ha (1) ha (0) 15.93 or ha (1) 78.93 , ham(1) 70.96 kJ/kg, Tw(1) 31.60 C
2
30 31.6
Twm(1) 30.80 C , and the corresponding saturated air enthalpy is, hsam(1) 115 kJ/kg, and the mean differ-
2
ence at section 1 becomes, hsa (1) ha (1) m 44.23 kJ/kg.
Section 2: Similar calculations can be carried out for this section. The values of related parameters are ha (2) 94.86
kJ/kg, ham(2) 86.31 kJ/kg, Tw(2) 33.20 C , Twm(2) 32.40 C , and hsam(2) 122 kJ/kg. The corresponding enthalpy dif-
ference is hsa (2) ha (2) m 35.69 kJ/kg.
Similar algorithm may be applied to the rest of the sections, and the enthalpy of air at the tower exit is determined to be
ha (5) 142.65 kJ/kg which is 2.39% off the real value. Better estimates, however, can be obtained by increasing the number
of sections (n) of the tower. The summary of related calculations is presented in Table 7.3.
h sa (i ) ha (i ) m =0.1562
0
Since the temperature drop of water at each section is T 1.6 C , Eq. (7.31) yields,
hA
4.18 30 1.6 0.1562 31.33 kW/(kJ/kg) or NTU 31.33 .
c pm
mA mB
xA , xB and xB 1 x A (7.32)
mA mB mA mB
CHAPTER 7 GAS MIXTURES & PSYCHROMETRY 311
In the above plot, solution temperature is the abscissa of the diagram, the saturation temperature
of water corresponding to vapor pressures is shown as the ordinate. The chart applies to saturated
conditions where the solution is in equilibrium with water vapor. In determining the vapor phase partial
pressure of the solute, the solution concentration and the temperature have to be specified. In accord
with the chart, (LiBr) solution with 54-percent of (LiBr) concentration at 800C develops water vapor
pressure of 10.92 kPa. The same pressure can be recorded at 45-percent of LiBr solution at 650C of
solution temperature. For an isothermal process of solution (vertical line on the chart), increasing the
concentration (states 1 to 2) results with a decrease in vapor pressure. For a constant concentration
process, however, increasing the solution temperature (states 1 to 3) increases the vapor pressure.
Example 7.20 Dilute LiBr-water solution at 300C with water vapor pressure at 1.23 kPa enters a heat exchanger in Figure
7.32 with a mass flow rate of 0.5kg/s. The solution is heated to 1000C by steam flow through the exchanger tubes. Some of
water evaporates, and water vapor pressure increases to 7.38kPa. The concentrated solution leaves the exchanger at state
2. Determine,
a. the solution concentration at the exchanger inlet and outlet,
b. the mass flow rate of concentrated solution at the exchanger outlet.
c. the mass flow rate of water vapor at state 3.
312 THERMODYNAMICS
Solution:
a. From chart in Figure 7.31, at p1 1.23 kPa, T1 30o C , the concentration at the exchanger inlet is, x1 0.49 .
Similarly, at the exchanger outlet, p2 7.38 kPa, and T2 100o C , then the concentration at the equilibrium is
x2 0.66 .
b. Since LiBr is highly non-volatile substance, the mass balance requires that x1m 1 x2 m 2 , or 0.49 0.5 0.66 m 2 ,
m 2 0.371 kg/s.
c. Considering the overall mass balance on the solution side, we may state that m 1 m 2 m 3 , and the mass flow rate
of water vapor becomes, m 3 0.5 0.371 0.129 kg/s.
v x Av A xB vB x Av A (1 x A )vB (7.33)
2. Upon mixing of two components, there should be no heat generation, or absorption ( hmix 0 ).
Then the specific enthalpy of solution at a particular state is,
h x A hA xB hB x A hA (1 x A )hB (7.34)
Principle 27: Raoult’s law: The vapor pressure of component A can be expressed in
terms of the saturation pressure of pure component A ( p As ) at the same temperature
as that of binary system is as following: lim y 1 p A y A p As , where y A is the vapor
A
phase mole fraction of component A in the solution.
Ideal solutions should obey the Raoult’s law over the entire range of 0 y A 1 . However, most
solutions obey the law in the limit y A 1 . Hence the partial vapor pressures of components A and B
at the temperature of the solution are given as,
As illustrated in Figure 7.33a, for positive deviation from Raoult’s law, the actual equilibrium
pressure will be higher than that predicted by Raoult’s law, or the equilibrium temperature at a given
concentration and pressure will be lower. For refrigerant-absorbent type binary solutions, because
of exothermic process of absorption, the enthalpy of mixing ( hmix 0 ) is negative as in Figure
7.33b.
4. The vapor phase of the solution should obey Dalton’s law of additive pressures. Hence, the
partial vapor pressures of components A and B at temperature T can be calculated as,
ptotal p A pB (7.37)
For refrigerant-absorbent type of binary solutions, one component is non-volatile with respect to
other. For instance, consider Lithium Bromide-water solution, Lithium Bromide salt is non-volatile
314 THERMODYNAMICS
component, and in vapor phase, yB 0 . Thus, together with Eq. (7.36), Eq. (7.37) is reduced to the
following,
ptotal y A p As (7.38)
Example 7.21 Let us consider water-lithium bromide solution with 50% mole fraction of (LiBr) at 49°C. Estimate the
total pressure on the (LiBr) solution, and compare with the actual measurement of 0.9kPa.
Solution:
As explained above, (LiBr) being a highly non-volatile
salt, its existence in vapor phase is almost untraceable. In
accord with Raoult’s law, Eq. (7.38), the total pressure
becomes, p 1 yB pw or p 1 0.5 3.1.69 1.58
kPa.
With respect to actual pressure measurement, the
pressure of mixture is pmix 0.9 1.58 0.68 kPa,
and the actual equilibrium temperature should be less
than the predicted value.
Solution:
a. From Figure 7.34, the enthalpy of (LiBr) solution at the given state is h1 186 kJ/kg.
b. For a (LiBr) solution at 100°C, with enthalpy value of h2 300 kJ/kg, Figure 7.34 helps us to determine the
concentration as, x2 0.22 .
Example 7.23 Consider the heat exchanger in Example 7.20, where the (LiBr) solution with a mass flow rate of 0.5 kg/s
inlets the exchanger at ( T1 30o C , x1 0.49 ) and exits at ( T2 100o C , x2 0.66 ). Steam at 1bar, enters the exchanger
at T4 150o C and leaves at as saturated vapor. Evaluate the mass flow rate of steam.
Solution:
Referring to Figure 7.35, the temperatures, concentrations, mass flow rates, and the enthalpies of both solution and the steam
at various states are represented in the table below. All fluids are at 1 bar pressure.
State no. Temp. (0C) Concentration (%) Mass flow rate (kg/s) Enthalpy (kJ/kg)
1 30 0.49 0.5 60
2 100 0.66 0.371 260
3 100 - 0.129 2676.1
4 150 - - 2776.4
5 100 - - 2675.5
With respect to control volume around the heat exchanger, the energy balance yields, m s h4 h5 m 2 h2 m 1h1 m 3h3 .
0.371 260 0.5 60 0.129 2676.1
Substituting the tabulated values into energy equation, the steam flow rate is m s 4.08 kg/s
2776.4 2675.5
References
1. Y. V. C. Rao, Engineering Thermodynamics Through Examples, Universities Press, ISBN-81-7371-4231, 2003.
2. J. P. Holman, Heat Transfer, 6th Edition, McGraw-Hill Book Company, ISBN-0-07-029620-0, 1986.
3. B. E. Poling, J. M. Pravnitz, J. P. O’connell, Gases and Liquids, 5th Edition, McGraw-Hill Publishing, ISBN 0-07-
149999-7, 2001.
4. H. D. B. Jenkins, Chemical Thermodynamics at a Glance, Blackwell Publishing, ISBN 978-1-4051-3997-7, 2008.
5. “Virial Coefficients of Pure Gases and Mixtures”, Edited by M. Frenkel, and K. N. Marsh, Springer-Verlag, ISBN
3-540-44340-1, 2002.
6. W. P. Jones, Air Conditioning Engineering, 5th Edition, Butterworth-Heinemann, ISBN 0-7506-5074-5, 2001.
7. R. W. Serth, Process Heat Transfer, Principles and Applications, Elsevier Science, ISBN 0-1237-3588-2, 2007.
8. “Power Plant Engineering”, Edited by Black and Veatch, Springer Science, ISBN 0-412-06401-4, 1996.
316 THERMODYNAMICS
7.13 Air having a mass of 3.5kg at 100 kPa, 10°C is mixed a. The valve is opened and the pressure rapidly
with 6kg of nitrogen (N2) at 100 kPa, 110°C. The equalizes on both sides and then the valve is
mixing takes place at constant pressure. Assuming closed. No conduction of heat occurs. Determine
that air consists of 21%O2 and 79%N2 by volume, the pressure and temperature on both sides of
determine, the tank, and evaluate the entropy generation.
a. the final temperature of the mixture, b. The valve is left open and eventually the tem-
b. the entropy change of the system. peratures become equal on both sides. Determine
the final pressure and temperature for this case,
7.14 An insulated rigid tank is divided into two compart- and evaluate the entropy generation.
ments by a membrane. Compartment A contains 70
c. Repeat parts (a) and (b) if O2 is substituted for
kg of O2 and compartment B contains 140 kg of CO2.
nitrogen in compartment B.
Both gases are initially at 27°C and 120 kPa. The
membrane breaks up and the gases mix. Assuming
that both gases behave like ideal gas, determine,
a. the entropy generation,
b. the exergy destruction.
c. What would be the exergy destruction if there
were 140 kg of O2 in compartment B instead.
7.15 As shown in Figure 7.38, a rigid and insulated tank
is divided into three compartments each of which
is 0.1m3 in volume. The end compartments contain
argon (Ar) at 6bar, 35°C, and helium (He) at 2.5bar,
110°C, and the compartment at the center is evacu-
ated. After removing the partitions, gases mix and
attain an equilibrium state. Determine,
a. the final pressure and the temperature, Figure 7.39 A schematic of Problem 7.17
b. the partial pressure of each gas at the equilibrium
state, 7.18 An insulated vertical cylinder with a frictionless
c. the entropy change of the system. piston having a cross-sectional area of 0.2 m2 is
initially 1.2 m in height and contains methane at 120
kPa, 300K. As shown in Figure 7.40, the cylinder
also contains 10 L of capsule containing air at 600
kPa, 300K. The capsule accidently breaks and two
gases mix in a constant pressure process. Take air
as an ideal gas and Assume that the surroundings is
at 300K and 100 kPa, determine,
a. the final temperature,
b. the final height of the cylinder,
Figure 7.38 Schematic of three-zone c. the work done,
insulated tank d. the entropy generation of the process,
7.16 Rigid tank A contains 1.2 kg of argon (Ar) at 37°C, e. the exergy destruction.
100 kPa and is connected by valve to rigid tank B
containing 0.6kg of O2 at 117°C, 500 kPa. The valve
is opened and the gases mix achieving an equilibrium
temperature of 77°C. Assuming surroundings is at
37°C, determine,
a. the volume of each tank in m3,
b. the final pressure in kPa,
c. the heat transfer from or to gases in kJ,
d. the entropy change of each gas, and the entropy
generation of the process.
7.17 A well insulated container with a volume of 0.2 m3 is
divided internally into two equal parts by a rigid and
adiabatic partition. As can be seen on Figure 7.39,
the compartments are connected by a pipe and valve
system. Compartment A contains nitrogen at 27°C,
2bar, and B also contains nitrogen but at 57°C, 10bar.
Both gases are ideal with constant specific heats. Figure 7.40 Schematic of methane storage tank
318 THERMODYNAMICS
7.19 One kmol mixture of CO2 and ethane (C2H6) occu- Steady flow systems
pies a volume of 0.5 m3 at a temperature of 125°C.
7.23 As shown in Figure 7.42, CO2 gas at 87°C is mixed
The mole fraction of CO2 is 0.25. Using Kay’s rule,
with N2 at 27°C in an insulated mixing chamber.
determine,
Both flows are at 100 kPa and the mass ratio of CO2
a. the mixture pressure,
to N2 is 5:2. Determine,
b. the volume occupied by the mixture if the pres-
a. the exit temperature of the mixture,
sure increased by 10-percent.
b. the entropy generation rate for 2kg/s mass flow
rate of the mixture.
7.27 A mixture of O2 and N2 with the same mole numbers 7.30 A steady stream of equimolar mixture of O2 and N2
enters a compressor at 15 bar, 220K with a mass flow is heated from -25°C to 0°C at a constant pressure
rate of 2kg/s. The mixture exits the compressor at 55 of 10 MPa. Assuming that the gas mixture obeys
bar, 400K. Neglecting the changes in ke and pe and Kay’s rule, determine the heat capacity rate of the
assuming an adiabatic compressor, determine the exchanger to be used for heating the mixture with a
mass flow rate 1.5 kg/s.
required power and the rate of entropy generation,
a. if ideal gas model is used,
7.31 A gas mixture consisting of 25% helium, 75%
b. if Kay’s rule is applied. hydrogen by volume is compressed isentropically
from 37°C, 350 kPa, to 1100 kPa. Determine the
final temperature and the specific work required if
7.28 Air (79% N2 and 21% O2 by volume) is compressed the compression process is carried out by
isothermally at 210°C from 3.5 MPa to 7 MPa in a
a. a piston cylinder apparatus,
steady-flow compressor at a rate of 5.1 kg/s. Assume
b. a compressor.
no irreversibilities occur during the compression,
and determine the power input to the compressor
by treating air as a mixture of 7.32 One of the natural resources for helium is natural
gas which is composed of 0.1% He and 99.9% CH4
a. ideal gases, on mole basis. To store pure helium, natural gas is
b. real gases obeying Kay’s rule. processed through a separation unit. The gas enters
the separation unit at 130 kPa, 17°C with a volumetric
flow rate of 80 m3/s. Pure helium leaves the unit at
100 kPa, 27°C, and pure methane exits at 130kPa,
37°C. Take the surroundings temperature at 27°C,
and determine
a. the required minimum power to drive the separa-
tion unit
b. the rate of entropy generation due to separation
process.
Hint: The separation unit is not insulated and
Figure 7.43 Flow of gas mixture through a might be heat transfer between the unit and the
compressor environment.
Figure 7.44 Heating of gas mixture through a Figure 7.45 Oxyacetylene torch and it is use in
heat exchanger metal cutting
320 THERMODYNAMICS
7.34 Combustion gases at the exhaust stroke of an engine 7.36 Air-water vapor mixture at 100 kPa, 20°C, 30%
have a volumetric analysis of 12%CO2, 11.5%O2, relative humidity is contained in a rigid tank of 0.5
and 76.5%N2 at 530°C, 1.8 bar. As shown in Figure m3. The tank is cooled until water droplets just start
7.46, the gas mixture expands through a turbo charger to occur on the surface. Determine the temperature
to atmospheric pressure of 1 bar and compresses at which the condensation starts.
isentropically atmospheric air at 27°C, 1 bar. As- 7.37 A conference room in dimensions of 25mx10mx3.5m
sume mass flow rates through the compressor and initially contains air at 0.92 bar, 25°C, and relative
the turbine are the same, and calculate the maximum humidity of 25%. After a humidification process,
air temperature at the compressor outlet. the room temperature drops to 20°C and the relative
humidity becomes 55%. Determine the amount of
water to be added to the room air.
7.42 Fill the blanks of the following table by using ASHRAE psychrometric chart for sea level.
DBT WBT Dew point Humidity ratio Enthalpy Relative humidity Specific volume
(°C) (°C) (°C) (kg-v/kg-air) (kJ/kg-air) (%) (m3/kg-air)
29 16
24 40
30 60
21 0.0114
45 50
7.43 Air stream of 225 m3/min at sea level is cooled from 7.44 The products of combustion are flowing through a
the condition, DBT 27o C , WBT 20o C , until it heat exchanger with 13%CO2, 12%H2O, and 75%N2
becomes saturated at a temperature of 10o C . By on volume basis at a rate of 0.5kg/s and 100 kPa,
using ASHRAE psychrometric chart, determine, 85°C.
a. the moisture removed in kg per hour, a. Determine the dew point temperature.
b. the sensible heat and the total heat removed in kW, b. The mixture is cooled 5°C below the dew point
c. the sensible heat factor (SHF) of the system as the temperature. Calculate the time required to col-
ratio of sensible heat to total heat removed. lect 15kg of liquid water.
CHAPTER 7 GAS MIXTURES & PSYCHROMETRY 321
7.45 An air conditioning unit takes the outside air at 27°C, 7.47 Moist air stream enters a refrigeration coil at
85% relative humidity cools down to 17°C before DBT 32o C , WBT 24o C at a flow rate of 50
transporting it into the room. As shown in Figure m3/min. The dew point temperature of the coil is
7.47, the cooling process is accomplished by running 12o C . If the refrigeration capacity of the coil is 3.2
cold water through the tubes of a fin-and-tube heat
tons, determine the exit temperature of air stream.
exchanger. Determine,
Hint: 1ton=3.516 kW.
a. the humidity ratio and the enthalpy at the ex-
changer inlet,
7.48 Damp egg cartons designed for carrying whole eggs
b. the mass of water removed per kg of kg of dry initially at 35°C and the moisture content is 50% of
air, the dry box mass. The boxes, as shown in Figure 7.49,
c. the relative humidity, and enthalpy of air entring enter a drier and the moisture content is reduced to
the house, 5%. Air at atmospheric pressure enters and leaves
d. the amount of heat removed per kg of dry air. the drier at specified conditions in the figure.
a. Determine the mass flow rate of air on mass
basis,
b. In providing drier inlet conditions to air, the
atmospheric air at 20°C, 60% relative humid-
ity is heated prior to entering into the furnace.
Find the heat capacity of the heat exchanger to
be used.
second stream mixes adiabatically with the return air a. the volume flow rate of air at the tower inlet,
stream. Finally, the combined stream is distributed to b. the mass flow rate of makeup water in kg/s.
various rooms of the building. Assume all processes
take place at constant pressure of 101.3kPa, sketch 7.54 A cross flow type cooling tower is used to cool water
the system schematically and show the processes on from 37°C to 24°C at a water flow rate of 100 tons
a psychrometric chart. Determine, per hour. The air enters the tower at 16°C with rela-
tive humidity of 50% and leaves at the top at 32°C
a. the temperature of return air after the dehumidi-
as saturated air. Determine,
fication process,
a. the mass flow rate of air in kg/s,
b. the amount of heat rejected during the dehu-
b. the mass of makeup water required per hour.
midification process,
c. the amount of heat input to the outside stream 7.55 A counter flow type and pilot-scale cooling tower at
to bring its temperature to 17°C, a volumetric flow rate of 20m3/min and relative hu-
d. the temperature of outside stream after humidi- midity of 40% at 20°C. Air leaves with DBT 34o C ,
fication, WBT 33o C at atmospheric pressure of 101.3kPa.
e. the temperature and the relative humidity after final As shown in Figure 7.50, the height of cooling
mixing of return air and outside air streams. tower is 2 m.
Figure 7.54 An isothermal discharging process m. For an unsaturated air, water vapor in
the mixture is at superheated state.
c. The apparent molar mass of a mixture r. For a binary solution, a negative devia-
of two gases is determined by simply taking the tion from Raoult’s law means that the actual
arithmetic average of the molar masses of the equilibrium temperature is more than the one
individual gases. predicted by Raoult’s law.
1 1
ideal gas mixture is given by where a. 18.6, 322, b. 19.6, 322,
v vi
vi V / ni .
c. 18.6, 332, d. 19.6, 342.
CHAPTER 7 GAS MIXTURES & PSYCHROMETRY 325
2. An ideal gas mixture of hydrogen (H2) and argon 6. A conference room in dimensions of 12mx15mx4m
(Ar) with identical mass fractions enter an adiabatic contains air at 100kPa, 25°C and 60% relative hu-
turbine at 1000K, 10bar at a rate of 0.5kg/s. The midity. Estimate the amount of water in that room
in kg.
mixture isentropically expands through the turbine
and develops power in kW as, a. 5.91, b. 7.91,
c. 9.91, d. 11.91.
a. 1509.2, b. 1609.2,
c. 1709.2, d. 1809.2.
7. Outside air at 10°C, 40% relative humidity is mixed
with inside air of a factory building at 35°C, 70%
3. An automobile exhaust gas analysis shows that the gas relative humidity taken from the ceiling. The volume
composition on mole fraction basis is as following, flow rates of inside and outside air streams respectively
are 30m3/min and 50m3/min. The mixing takes place
N2 CO2 O2 CO H2 at 100kPa pressure. Estimate the relative humidity
0.808 0.100 0.002 0.065 0.025 of the mixed stream in percent (%).
a. 75, b. 80,
The specific volume of the exhaust gas in m3/kg is
c. 85, d. 90.
a. 0.72, b. 0.82,
c. 0.92, d. 1.02. 8. If water is sprayed into air at relative humidity of
35% in an adiabatic and constant pressure environ-
ment, the following happens,
4. In a test of a new furnace, first 1.5m3/s methane is a. the temperature decreases,
adiabatically mixed with 2.5m3/s of propane gas.
b. the enthalpy decreases,
Then, the mixture is preheated to 170°C by passing
c. humidity ratio decreases,
through an adiabatic heat exchanger which uses
steam at 200°C for heating the gas mixture. Steam d. relative humidity decreases.
inlets the exchanger as saturated steam and exits
as saturated liquid. As shown in Figure 7.55, both 9. A stream of moist air is subjected to two processes in
gases are at 1bar, 25°C before entering the mixing sequence. First the stream is cooled then humidified
chamber. The mass of steam in kg/s, and the rate of by steam injection into the stream.
total entropy generated in kW/K respectively are,
a. the enthalpy of air decreases,
a. 0.72, 2.755, b. 0.72, 3.775, b. the enthalpy of air remains constant,
c. 0.72, 1.755, d. 0.92, 1.75. c. the enthalpy of air first decreases then in-
creases,
d. the enthalpy of air increases.
12. Dilute (Li-Br)-water solution inlets a heat exchanger 14. An important property of binary solutions used
at 70°C, 59% concentration with a mass flow rate for vapor absorption refrigeration systems is to
of 0.45kg/s. The solution is heated by hot water exhibit
at 115°C, and exits the exchanger at 95°C, 64%
concentration. The mass flow rate of water vapor a. a negative deviation from Raoult’s law upon
produced in kg/h is, mixing,
a. 121.56, b. 122.56, b. producing a large heat of mixing,
c. a positive deviation from Raoult’s law upon
c. 125.56, d. 126.56. mixing,
d. a large temperature difference between the boil-
ing points of components.
C H
8
A P T E R
Figure 8.1 The power cycles commonly in use for industrial applications
If the combustion is not a part of the cycle, then the system is named as external combus-
tion system. Since the combustion is external to the cycle, the composition of the working
fluid does not change throughout the cycle. The classification of power producing systems
which are in common use is presented in Figure 8.1. In rating the internal combustion engines
on a power scale from the least power producing one to the most, three types of engines
327
328 THERMODYNAMICS
have found general acceptance in industry. These are respectively SI engine, CI engine with positive
displacement and the rotary type CI engines.
The cycles related to the engines presented above are very complex to analyze. In internal combus-
tion engines, for instance, the air-fuel mixture is usually mixed with the residual exhaust gas remaining
from the previous cycle, and this resulting mixture is actually compressed. Due to friction, pressure
drop takes place in the intake and the exhaust systems. Heat at a certain rate is usually lost through
the pipes connecting the main components of the engine, and non-equilibrium conditions may exist
within the processes of the system. To make the analysis more manageable, however, the following
model has found a general acceptance in literature.
Principle 27: An ideal cycle is an internally reversible cycle. For an ideal cycle, a. the work-
ing fluid does not cause any pressure drop due to flow through pipes and heat exchangers, b.
pipes connecting the components of the cycle are well insulated, and the transfer of heat is
neglected, c. the expansion and the compression processes are considered to be reversible. If
there is no heat transfer, then those processes become isentropic, d. Changes in kinetic and
potential energies due to flow through the devices are neglected.
A comparison of an actual cycle with the ideal correspondence is presented in Figure 8.2. Con-
sistent with the ideal cycle definition, no pressure difference is required for the intake and exhaust
periods, and no time is needed for completion of combustion process. The heat addition and extrac-
tion processes take place instantly in the ideal cycle. However, an ideal cycle is not a reversible
cycle. Heat transfer between the working fluid and the low or high temperature medium takes place
at a finite temperature difference and this causes irreversibility. Therefore, the efficiency of an ideal
cycle is always less than the efficiency of a reversible cycle operating between the same high and
low temperature reservoirs.
CHAPTER 8 POWER PRODUCING SYSTEMS 329
Definitions: Spark ignition (SI): The combustion process of the cycle is started by a spark plug.
Compression ignition (CI): The combustion process starts when air-fuel mixture self ignites due to
high temperature in the chamber.
Four-stroke cycle: The cycle is completed by four piston movements over two engine revolutions.
Two-stroke cycle: The cycle is completed by two piston movements over one engine revolutions.
Top Dead Center (TDC): The position of the piston when it is at the furthest point away from the
crankshaft.
Bottom Dead Center (BDC): The position of the piston when it is at the closest point to the crank-
shaft.
Bore (D): The diameter of the cylinder, and due to small clearance, the diameter of the piston face.
Stroke (H): The distance between the (TDC) and the (BDC) of the cylinder.
Stroke volume (Vst): The volume that is swept by the piston as travels through one stroke.
For one cylinder, Vst H D 2 / 4 , for N cylinders, Vst H D 2 / 4 N (8.1)
Clearance volume (Vc): The volume left in the combustion chamber when the piston is at (TDC).
Fuel-Air ratio (FA): The ratio of mass of fuel input to the mass of air, FA m f / m a . The ideal or
stoichiometric FA for many hydrocarbon fuels is around 1:15. Gasoline fueled SI engines usually
have FA input in the range of 1:10 to 1:18. However, FA input of CI engines ranges between 1:18
and 1:50.
Vmax Vc Vst V
r 1 st (8.2)
Vmin Vc Vc
Typical values of compression ratio are r 8 to 12 for SI engines, and r 12 to 25 for CI en-
gines.
Typical values of pm for SI engines are 1000 kPa to 1400 kPa, and for CI engines are 800 kPa
to 1000 kPa.
Torque ( T ): Torque indicates the engine’s ability to do work, and for a four-stroke engine, is related
to the net work per cycle as,
T pmVst / 4 (8.4)
Power (W ): For an engine of N cylinders running at a speed of n revolutions per second, the power
developed is,
Engines producing power in the range of 2 kW to 5 kW are commercially used for lawn mowers,
chain saws, and for snow blowers. Automobile engines mostly produce power in the range between
50 kW and 200 kW. With respect to Eq. (8.5), more power may be generated by increasing the stroke
volume. Increased volume, however, results with a bulky engine size which is an unfavorable approach
in design. Hence, modern engines are smaller in size but run at high speed.
Example 8.1 An eight cylinder four-stroke cycle SI engine operates at 2200 rpm. Determine,
a. the number of cycles per minute,
b. the number of cycles per revolution,
c. the degrees of engine rotation for each ignition to take place.
Solution:
2200
a. The number of cycles per minute is ncycle 8 4400 cycles/min.
2
b. If we divide the number of cycles per minute by the revolutions per minute, the result would be the number of
2200
cycles per revolution. Hence, ncycle 8 / 2200 4 cycles/rev.
2
c. Since one ignition takes place per cycle and four cycles are completed in one revolution, then the angle of rotation
for each ignition is ignition 360 / 4 900.
Example 8.2 An automobile has 2.4 liter SI four-cylinder engine operating on a four-stroke cycle at 3800rpm. At this
speed, the torque output of the engine is 220 Nm, and air enters the cylinder at 90 kPa, 50°C. The engine is square (D=H),
and the compression ratio is 8. Determine,
a. the cylinder bore and the stroke length,
b. the clearance volume of one cylinder,
c. the power produced,
d. the mean effective pressure,
e. the specific work output of the engine.
Solution:
D2
a. Since the engine is square, V 4Vst 4 D 0.0024 or D = H = 0.091m.
4
Vst
b. By Eq. (8.2) r 1 8 or Vc Vst / 7 0.0006 / 7 0.000085m3.
Vc
c. Equation (8.5) yields the power developed as, W 2 3.14 (3800 / 60) 220 87.5 kW.
d. Eqs. (8.3) and (8.4) provide the mean effective pressure of the cycle as, pm 4 T / Vst 4 3.14 220 / 0.0006 4605.33
kPa.
e. The amount of work done per cycle is Wcycle 4 T 4 3.14 220 / 1000 2.76 kJ/cycle. Besides, the amount
of air that inlets the cylinder per cycle is mcycle p1V1 / RT1 90 0.006 0.000085 / (0.287 323) 0.00066
kg/cycle. Thus, the engine specific work is w Wcycle / mcycle 2.76 / 0.00066 4181.81kJ/kg.
332 THERMODYNAMICS
As illustrated in Figure 8.5, this basic cycle is fairly standard for all SI engines and consists
of the following processes,
Stroke 1. The piston travels downward with the intake valve at open position and the exhaust
valve closed. Because of pressure differential, air passing through the intake system mixes with
fuel vapor at a desired level and fills the cylinder.
Stroke 2. The intake valve closes when the piston reaches BDC, and the air-fuel mixture is com-
pressed when the piston travels upward. Close to TDC, the spark plug is ignited, and the combustion
starts. This, in turn, raises the pressure and temperature in the cylinder to a very high level.
Stroke 3. Combustion gases at high pressure causes the piston to move away from TDC, and the
pressure and temperature in the cylinder drops. The exhaust valve opens before the piston reaches
the BDC for exhaust blow down.
Stroke 4. The piston moves upward and pushes the remaining exhaust gases in the cylinder after
the exhaust blow down. However, the gas trapped in the clearance volume will be left for the
next cycle.
These engines provide peak pressure values between 1030 kPa and 2060 kPa. They employ
carburetor, gas mixing system, or fuel injection system. A wide variation in speed and power is ob-
tainable for SI engines. They are commonly used in automobiles. The indicator diagram for a typical
four-stroke SI engine is illustrated in Figure 8.6a. As shown in the figure, at point A, the intake valve
opens and the exhaust valve closes. The intake valve closes at B, and combustion starts and ends at
points C and D respectively. The exhaust blow down takes place at E.
CHAPTER 8 POWER PRODUCING SYSTEMS 333
To reduce the complexity of the actual cycle of SI or CI engines, the real cycle is further approxi-
mated with an air-standard cycle.
Principle 28: In addition to being an ideal cycle, an air-standard cycle differs from the actual cycle
by the following: 1. The working fluid is air for the entire cycle and the property values of air are
used in the analysis. 2. The combustion process is replaced by heat addition process, and the combus-
tion chamber works as a heat exchanger. 3. The open exhaust process is replaced by a heat rejection
process that restores the air to its initial state. 4. The real open cycle is changed into closed cycle by
assuming that the air after the exhaust process is fed back into the intake of the engine.
The air-standard cycle for four-stroke SI engines is Otto cycle. As shown in Figure 8.6b, Otto cycle
starts with the piston at TDC (point 5). As the piston moves downward, the pressure in the cylinder
is kept constant (5-1). Then, the air trapped in the cylinder is compressed isentropically (1-2). The
334 THERMODYNAMICS
compression stroke is followed by a constant volume heat input process at TDC (2-3). The air at peak
pressure and temperature isentropically pushes the piston downward (3-4). The exhaust blow down is
accomplished by constant volume heat rejection process at BDC (4-1). Finally, as the piston travels
from BDC to TDC, the exhaust gases are expelled from the cylinder at constant pressure (1-5). Figure
8.6c also illustrates Otto cycle on T-s coordinates. It is quite common to find Otto cycle shown with
processes 5-1 and 1-5 left off the figure. The reasoning for that is simply these two processes cancel
each other thermodynamically and not needed for the cycle analysis.
Thermal efficiency of Otto cycle. The thermal efficiency of Otto cycle, as determined by Eq. (4.48),
may be expressed as following,
wnet q
o 1 out (8.6)
qin qin
In both heat addition and extraction processes of the cycle, the temperature of air changes drastically
and causes appreciable change in specific heat values. If such a change in specific heats is taken into
consideration, then the air tables have to be utilized in the analysis. Otherwise, for constant specific
heats, qin cv T3 T2 , qout cv T4 T1 and the thermal efficiency in terms of cycle temperatures
becomes,
T4 T1 T T / T 1
o 1 1 1 4 1 (8.8)
T3 T2 T2 T3 / T2 1
For an isentropic process of an ideal gas with constant specific heats, the following relations hold,
T1 / T2 v2 / v1 v3 / v4
k 1 k 1
T4 / T3 and Eq. (8.8) reduces to
T1 1 1
o 1 1 1 k 1 (8.9)
T2 v1 / v2 k 1
r
This oversimplified model of the working fluid with constant specific heats concludes that the
efficiency goes up as the compression ratio (r) increases. This result is also true for real SI engines.
Then, the next logical question is that to what values the compression ratio can be increased for the
purpose of enhancing the efficiency. In real engines, the phenomenon called knocking occurs when
the compression ratio exceeds a certain limit, and the temperature in the cylinder self ignites the fuel
without spark. Even though, the knocking might be avoided by increasing the octane number of the
fuel, the compression ratios of SI engines generally are not greater than 12.
Example 8.3 A six-cylinder, 3.0-liter SI automobile engine operating on a four stroke air standard Otto cycle at 3200
rpm. The engine has a compression ratio 8.5:1, and a stroke-to-bore ratio H/D=1.02. Air at the start of compression process
is at 98 kPa, 60°C, and 1075 kJ/kg of heat is generated during the combustion process. Assuming variable specific heats,
determine,
a. the peak temperature and the pressure,
b. the net specific work output of the engine,
c. the mean effective pressure,
d. the thermal efficiency,
e. the power produced by the engine.
CHAPTER 8 POWER PRODUCING SYSTEMS 335
Solution:
a. Air Tables (A24) and Figure (8.6b) will be used in solving the problem. For T1 333K , the reduced volume and the
V1 Vr1
internal energy of air is Vr1 479, u1 237.6 kJ/kg. Since the compression process is isentropic, 8.5 ,
V2 Vr 2
and Vr 2 56.35 , by air Table, T2 755 K , u2 555 kJ/kg. Since, qin u3 u2 , u3 555 1075 1630 kJ/kg. By
v T2 755 T
The state equation yields the peak pressure as following, p2 p1 1
98 8.5 1888.6 kPa, p3 3 p2
v T
2 1 333 T2
1950
or p3 1888.6 4877.8 kPa.
755
V V 1
b. Since the expansion process is isentropic, 3 r 3 or Vr 4 8.5 3.022 25.68 and the air table yields
V4 Vr 4 8.5
u4 754.3 kJ/kg, qout 754.3 237.6 516.7 kJ/kg. The net specific work is wnet 1075 516.7 558.3 kJ/kg.
0.287 333
c. To calculate the effective mean pressure, first the volume at state 1 has to be found by v1 0.975
98
wnet 558.3
m3/kg. Then, the mean pressure is pm 648.96 kPa.
1 1
v1 1 0.975 1
r 8.5
558.3
d. By Eq. (8.6), the thermal efficiency of the cycle is o 51.9%
1075
e. As indicated by Eq. (8.5), the power produced is W m kg/cycle wnet kJ/kg n cycles/s . On the other hand, Vst 0.003
0.003
m3 and V1 0.003402 m3, the amount of mass per cycle is m kg/cycle 0.003402 / 0.975 0.003489
1 1 / 8.5
kg/cycle. The number of cycles per second is n 3200 / (2 60) 26.67 cycles/s. Hence the power developed is,
Example 8.4 The automobile engine in Example 9.2 consumes fuel with a heating value of 41,100 kJ/kg. The FA ratio for
the engine is 1:18, and the combustion is assumed to be ideal. Assuming constant specific heats (k=1.4), determine,
a. the thermal efficiency,
b. the specific heat input,
c. the specific net work,
d. the power produced by the engine.
Solution:
1
a. The thermal efficiency by Eq. (7.9) becomes o 1 56.4%
81.4 1
b. To calculate the specific heat input, first the mass of fuel per cycle has to be determined. Since, Vst 0.0024 m3,
p1V1 90 0.00274
Vc 0.00034 m3 and V1 0.00274 m3, then the mass of air-fuel mixture per cycle is m 0.00266
RT1 0.287 323
1
kg/cycle. The mass of fuel becomes, m f 0.00266 1.4 104 kg fuel/cycle. The heat input per cycle is
19
qf 5.754
q f m f H u 1.4 x104 4.11 104 5.754 kJ/cycle. The specific heat input then is qin 2163.15
m 0.00266
kJ/kg
336 THERMODYNAMICS
c. Since the thermal efficiency is known, wnet o qin 0.564 2163.15 1221.58 kJ/kg
d. By Eq. (8.5), the power output becomes, W 0.00266 1221.58 31.67 102.89 kW
Stroke 1. Same as the intake stroke of SI engine, except that no fuel is added to the incoming air.
Stroke 2. Only air is compressed. Because of high compression ratio, the air temperature assumes
high enough values to self-ignite the fuel at the end of compression stroke.
Stroke 3. As combustion continues, the piston moves towards BDC. The pressure in the cylinder is
almost kept constant until the fuel injection is completed.
Stroke 4. As the piston travels towards TDC, the exhaust gases in the cylinder are discharged.
These engines produce high thermal efficiency followed with low specific fuel consumption, and
provide peak pressures between 2760 kPa and 4830 kPa. Over the years CI engines have become the
premier transportation system for intermediate power needs.
The indicator diagram for four-stroke CI engine is shown in Figure 8.8a. Due to time requirement
for the completion of combustion, the combustion process still continues when the expansion starts.
This, in turn, keeps the cylinder pressure at peak levels well past TDC. Hence, the combustion is well
approximated as constant pressure heat input in air standard CI cycle which is called Diesel cycle. As
shown in Figure 8.8b, except the constant pressure heat input, Diesel cycle resembles Otto cycle and
the occurrence of exhaust blow down is exactly the same for Diesel cycle. The temperature-entropy
diagram of Diesel cycle is illustrated in Figure 8.8c. The increase in volume during fuel injection
period is an important parameter for cycle analysis and is called Cutoff ratio.
CHAPTER 8 POWER PRODUCING SYSTEMS 337
Definition: Cutoff ratio rc : is the volume change during combustion (see Figure 8.8b) and ex-
pressed as,
v3
rc (8.10)
v2
Thermal efficiency of Diesel cycle. Referring to Figure 8.8b, the amount of heat transferred to the
working fluid (air) at constant pressure is qin h3 h2 . Because of exhaust blow down, the amount of
338 THERMODYNAMICS
heat rejected is qout u4 u1 . Rewriting Eq. (8.6) for constant specific heats, the thermal efficiency
may be expressed by cycle temperatures as,
cv T4 T1 T1 T4 / T1 1
d 1 1 (8.11)
c p T3 T2 kT2 T3 / T2 1
where, T3 / T4 v4 / v3
k 1
v1 / v2 v2 / v3
k 1
T2 / T1 1 / rck 1 . Further manipulation of
this result with ideal gas equation yields,
T4 T3 k 1 T3 v3
rc and rc (8.12)
T1 T2 T2 v2
Substitution of Eq. (8.12) into Eq. (8.11) provides the Diesel cycle efficiency as a function of
compression ratio (r) and cutoff ratio (rc) as following,
1 rck 1 1
d 1 (8.13)
k rc 1 r k 1
This equation is valid for constant specific heat of air and states that Diesel efficiency can be in-
creased by greater compression ratio, r, and by smaller cutoff ratio, rc. In fact, for rc 1 , Diesel and
Otto efficiencies become identical. However, for rc 1 , the term, rck 1 / k rc 1, is always greater
than unity, and Diesel efficiency is always lower than that of Otto cycle having the same compression
ratio. For instance, if r 10 , and rc 2 , Otto and Diesel efficiencies respectively are o 60.2% ,
d 53.4% . In practice, however, Diesel cycle always runs at higher compression ratios. Hence, for
r 20 and rc 2 , Diesel efficiency would be d 64.7% 60.2% . Thus, because of higher com-
pression ratios, Diesel cycle operates at higher efficiencies than Otto cycle.
Example 8.5 A CI engine operating on air-standard Diesel cycle has cylinder conditions at the start of compression process
as 60°C and 120 kPa. Light diesel fuel with a heating value, Hu=31,000 kJ/kg-fuel, is used at a fuel-air ratio of FA=1:20.
Compression ratio is 19, and combustion is ideal. For variable specific heats, calculate,
a. the peak cycle temperature,
b. the cut-off ratio,
c. the heat lost to the environment,
d. the thermal efficiency.
Solution:
a. The mass of fuel used per kilogram of mixture is m f 1 / 20 1 0.0476 kg-fuel/kg. Then the amount of heat
input per kilogram of the mixture becomes qin m f H u 0.0476 31000 1476.19 kJ/kg. For isentropic compres-
sion, v1 / v2 19 vr1 / vr 2 and by air tables, vr 2 478.5 / 19 25.18, the temperature and the enthalpy at the end
of compression are T2 1000 K , h2 1046.04 kJ/kg respectively. Referring to Figure 8.8b, since qin h3 h2 ,
the enthalpy at the end of combustion is h3 1476.19 1046.04 2522.23 kJ/kg. The air tables yield the peak
temperature as T3 2224 K.
v3 T3 2224
b. Due to ideal gas behavior, the cut-off ratio may be expressed as, rc 2.224 .
v2 T2 1000
CHAPTER 8 POWER PRODUCING SYSTEMS 339
c. The amount of heat lost to the environment is qout u4 u1 . Due to isentropic expansion,
v3 / v4 vr 3 / vr 4 v3 / v2 v2 / v4 or vr 4 1.94 19 / 2.22 16.6 , and by air tables, u4 881 kJ/kg, T4 1142 K.
Thus the heat lost is qout 881 237.7 643.3 kJ/kg.
643.3
d. The thermal efficiency of the cycle by Eq. (8.6) is d 1 56.4%
1476.19
Thermal efficiency of Dual cycle. Referring to Figure 8.9a, the amount of heat transferred to the
working fluid (air) in both processes (2-3) and (3-4) is qin q23 q34 u3 u2 h4 h3 . Due to
exhaust blow down, the heat rejected at constant volume is qout u5 u1 . For constant specific heats,
Eq. (8.6) yields the thermal efficiency in terms of cycle temperatures as,
340 THERMODYNAMICS
cv T5 T1 T1 T5 / T1 1
du 1 1 (8.14)
cv T3 T2 c p T4 T3 T2 T3 / T2 1 kT3 T4 / T3 1
1 rp rck 1
du 1 (8.15)
r k 1 krp rc 1 rp 1
It can be deduced from this relation that Dual cycle represents the Diesel for rp 1 , and the Otto
for rc 1 . However, for rp 1 , the term rp rck 1 / krp rc 1 rp 1 assumes smaller values
and the efficiency increases. In fact, Dual cycle efficiency lies between that of the Otto cycle and the
Diesel having the same compression ratio.
Example 8.6 The CI engine of a small truck operating on air-standard Dual cycle with a compression ratio of r 20 has
cylinder conditions at the start of compression process as 50°C and 98 kPa. An ideal combustion of light diesel fuel with a
heating value of Hu=31,000 kJ/kg-fuel, is completed at a fuel-air ratio of FA=1:18. Due to structural limitations, however,
the maximum allowable pressure in the cylinder is 10 MPa. Assume constant specific heats at cv 0.788 kJ/kgK, and
c p 1.075 kJ/kgK, and determine the efficiency of the cycle.
Solution:
With respect to the given data of the problem, the pressure ratio, rp , and the cut-off ratio, rc , of the cycle have to be calcu-
lated. Since, p2 p1r k , then the pressure ratio is rp p3 / p1 r k (10000 / 98) 201.364 1.715 . Referring to Figure
1.364 1
8.9a, the temperatures at state 2 and 3 respectively are T2 323 20 961.12 K, T3 1.715 961.12 1648.32
K. The portion of heat input for constant volume process becomes, qi1 cv T3 T2 0.788 1648.32 961.12 541.51
kJ/kg. Moreover, the fuel mass per kilogram of mixture is m f 1 / 19 0.0526 kg f / kg and the total heat input by the
combustion process would be qin 0.0526 31000 1631.57 kJ/kg. Then the portion of heat input at constant pres-
sure process is qi 2 1631.57 541.51 1090.06 kJ/kg. Since the heat input at constant pressure may be calculated by
1090.06
qi 2 c p T4 T3 c pT3 rc 1 , then the cut-off ratio becomes rc 1 1.615 .Substituting r , rp , rc
1.075 1648.32
1 1.715 1.6151.364 1
values into Eq. (8.15) results as, du 1 50.3%.
200.364 1.364 1.615 1 1.715 1
Case 1: Same compression ratio and heat rejection. As shown in Figure 8.10a, the area defined
as A(a14b) represents qout and is the same for each type of cycle. However, due to same com-
pression ratio, qin differs from cycle to cycle. In fact, on (T-s) diagram qin Diesel A(a123''4b) ,
qin Dual A(a1253'4b) , and qin Otto A(a1234b) , and comparison of these area values shows that
qin Diesel qin Dual qin Otto . Under these conditions, together with Eq. (9.6), we may be state that
d du o .
Case 2: Same compression ratio and heat addition. Since the heat inputs for all cycles have the same value,
from Figure 8.10b, it can be seen that area values are identical, A(a1234b) A(a1253'4' c) A(a123''4'' d ) .
In addition, the initial state and the compression ratio of all cycles are identical. Under these conditions,
the heat rejection of Otto cycle which corresponds to the area value of A(a14b) is the smallest in Figure
8.6b. In fact, the area comparison shows that qout Otto qout Dual qout Diesel . Consequently, the Otto
cycle has the highest work output, and with respect to Eq. (8.6), we may state that d du o .
Case 3: Same peak pressure, peak temperature and heat rejection. In applications, these three cycles
do not operate on the same compression ratio. CI engines operating on the Dual or Diesel cycle have
much higher compression ratio than SI engines operating on the Otto cycle. Hence, another case would
be to fix the peak pressure and the amount of heat rejection and then compare the cycles.
Referring to Figure 8.11, the heat input for each cycle is represented as qin Diesel A(a12''34b)
,
qin Dual A(a12'534b) and qin Otto A(a1234b) and comparison of these area values shows that
qin Diesel qin Dual qin Otto . With respect to Eq. (8.6), Diesel cycle becomes the most efficient
cycle and the efficiency distribution among cycles is as follows, d du o . With respect to the
(T-s) behavior of these cycles as in Figure 8.11, we may state the most efficient engine as follows:
the most efficient engine would be a high compression ratio CI engine that completes the combustion
as close to constant volume process as possible.
Figure 8.12 Basic principles of a gas turbine cycle and p-V representation
As shown in Figure 8.12a, the main difference of gas turbines from the reciprocating engines is
that the four steps of the cycle occur at the same time but in different sections. Hence the power is
produced in a continuous manner. Air is sucked into the compressor at atmospheric conditions and
is compressed to state 2 in Figure 8.12b. Heat is added to air by burning the injected fuel in the com-
bustor ( qin ). The combustion is essentially a constant pressure process, but due to flow enlargement,
contraction and frictional effects in the combustor, pressure drop occurs. The combustion gases at high
pressure and temperature enters the gas turbine at state 3, and expands through the turbine. Because
of hot gases leaving the turbine at state 4, certain amount of heat is rejected to the surroundings ( qout
). To provide the above indicated cycle, a gas turbine engine consists of the following sections:
Inlet section. Clean and undisturbed inlet airflow extends the engine life by preventing erosion,
corrosion, and foreign object damage. The air inlet duct assembly is designed for this purpose and
provides clean and unrestricted airflow for the system. As shown in Figure 8.13a, the inlet duct sec-
tion is produced as a separate item.
Compressor. With respect to the air flow path, the compression of air is accomplished by one
of two basic types of compressors which are named as axial flow and radial flow compressors. As
shown in Figure 8.13a, the axial flow compressor attains higher pressure ratios than the centrifugal
344 THERMODYNAMICS
one and provides more air flow rate for the same frontal area. Because of its simplicity, the centrifugal
compressors, shown in Figure 8.13b, are usually favored for smaller engines.
As illustrated in Figure 8.14, the compressor rotor blades convert mechanical energy into kinetic
energy of air. The stator vanes slow down the airflow by means of their divergent duct shape. Hence,
the kinetic energy is converted into enthalpy of air by increasing the air pressure at the exit of stator
vanes. The vanes are positioned at an angle such that the exiting air is directed into the rotor blades
of the next stage, and the process of increasing the pressure is repeated.
Figure 8.15 Cross-sectional view and air flow distribution in a combustion chamber
CHAPTER 8 POWER PRODUCING SYSTEMS 345
Turbine. As shown in Figure 8.16, the turbine converts the gaseous energy into mechanical energy
by expanding the hot, high pressure gases to a lower temperature and pressure.
The number of stages employed in a turbine depends upon the power required, the rotational
speed, and the turbine diameter. As the air stream enters the turbine section from the combustor, it
is accelerated by the stationary vanes of the first stage. As illustrated in Figure 8.17, the stator vanes
also called nozzles form convergent ducts that converts the gaseous enthalpy into kinetic energy and
the flow is accelerated.
346 THERMODYNAMICS
In addition to acceleration, the stator vanes change the direction of the flow and direct it into the
rotor blades at an optimum angle. Then, the rotor blades extract the fluid kinetic energy. The veloc-
ity, the temperature and the pressure of the gas decrease as it leaves the stage. All the gas must flow
across the blades to achieve the maximum efficiency in the turbine. To ensure this, as illustrated in
Figure 8.16, the first three stages of the turbine blades have tip shrouds to minimize the gas leakage
around the blade tips. Besides, a smooth flow of gas through the blades and vanes affects the turbine
efficiency.
An ideal gas turbine engine would perform the processes that make up the Brayton cycle. As it is
represented on p-V and T-s diagrams in Figure 8.18, air standard Brayton cycle consists of the follow-
ing processes: (1-2): Isentropic compression of air from lower pressure p1 to higher pressure p2. The
temperature of air increases but there is no heat flow. (2-3): Due to heat addition at constant pressure,
both the volume and temperature of air increase from values (V2, T2) respectively to (V3, T3). Since air
behaves like an ideal gas with constant specific heats, the amount of heat added is,
p T3 T2
qin mc (8.16)
(3-4): The air at high pressure and temperature expands isentropically from p2 to p1, and the
temperature falls from T3 to T4. (4-1): Heat is rejected from the working fluid by exhaust into the
atmosphere. Then, the volume and the temperature decrease from values of (V4, T4) respectively to
(V1, T1), but the pressure remains constant at p1. The amount of heat rejected is,
p T4 T1
qout mc (8.17)
Thermal efficiency of Brayton cycle. Starting with the basic definition of cyclic efficiency, the
thermal efficiency of air standard Brayton cycle may be expressed as following,
qout T T T T / T 1
1 1 4 1 1 1 4 1 (8.18)
qin T3 T2 T2 T3 / T2 1
Because of isentropic compression and expansion of air with constant specific heats, the following
k 1/ k k 1/ k
relations hold for temperature ratios; T1 / T2 p1 / p2 p4 / p3 T4 / T3 . Furthermore,
let us represent the cycle pressure ratio as, rp p2 / p1 , then the ideal Brayton cycle efficiency
becomes,
T1 1
1 1 ( k 1)/ k (8.19)
T2 rp
It is evident from Figure 8.19 that increasing the compressor pressure ratio increases the thermal
efficiency. The pressure ratios used in gas turbine engines vary in the range between 5 and 20.
As illustrated in Figure 8.20, the actual Brayton cycle differs from the ideal counterpart by the
following two facts: 1. Compression and the expansion processes are not isentropic. With respect to
isentropic efficiencies defined by Eqs. (6.29) and (6.33), the actual work input to compressor is more,
and the actual work output of the turbine is less than the ideal counterparts. 2. A pressure drop in the
range of 2% to 5% of the compression ratio takes place during the combustion and also in the heat
rejection processes. This fact even causes more reduction in the turbine work output.
Figure 8.19 Efficiency of an ideal Brayton cycle Figure 8.20 Comparison of ideal and actual
Brayton cycles
Definition: In a gas turbine engine the ratio of the work consumed by the compressor, wc , to the
turbine work, wt , is called back work ratio ( rbw ) and expressed as,
wc
rbw (8.20)
wt
348 THERMODYNAMICS
In simple gas turbine engines, consumption of more than 50-percent of turbine work by the
compressor is common, and the situation becomes even worse if the isentropic efficiencies of the
compressor and the turbine are low.
Example 8.7 The gas turbine engine in Figure 8.21 produces 15MW of power and has a compressor pressure ratio of 6.0.
The air temperature at the turbine inlet is 1000K, and the ambient conditions are 310K and 1bar. Determine the back work
ratio, the mass flow rate of air, and the thermal efficiency for
a. air standard Brayton cycle,
b. actual Brayton cycle having compressor and turbine efficiencies of 86% and 89% respectively. Due to fractional
pressure drop, a total of 5-percent of the pressure increase in the compressor is lost in the combustor and in the
exhaust sections.
Solution:
a. Together with air tables, the reduced pressure at state 2 is pr 2 rp pr1 6 1.55 9.3 , and T2 515 K, h2 518.3
kJ/kg. Similarly, at state 3, the temperature, enthalpy and reduced pressure are T3 1000 K, h3 1046.04 kJ/
114
kg, pr 3 114 . Then, pr 4 19 and the corresponding temperature and enthalpy values are T4 625 K ,
6
h4 633.1 kJ/kg.
wc 518.3 310.24 208.06 kJ/kg, wt 1046.04 633.1 412.94 kJ/kg and rbw 208.06 / 412.94 0.503.The
net work is
Wnet
wnet wt wc 204.88 kJ/kg, and the mass flow rate becomes m 73.21 kg/s. The heat input rate at the
wnet
204.88
combustor is qin h3 h2 1046.04 518.3 527.74 kJ/kg, and the thermal efficiency is 38.8%.
527.74
b. The pressure drops in the combustor and in the exhaust system are assumed to be identical; pc pex 0.025 600 15
518.3 310.24
kPa. Besides, the enthalpy and the temperature at state 2 respectively are h2 310.24 552.17 kJ/kg,
0.86
and T2 547.4 K . At state 3, the reduced pressure is the same, pr 3 114 , but the pressure ratio of the tur-
bine is not identical with the compressor, p3 585 kPa, p4 115 kPa. The reduced pressure ratio of the
pr 3 585
turbine is 5.087 , and pr 4 22.41 , h4 s 665.34 kJ/kg. Hence, the enthalpy at state 4 is
pr 4 115
CHAPTER 8 POWER PRODUCING SYSTEMS 349
h4 1046.04 0.89 (1046.04 665.34) 707.22 kJ/kg. From air tables, the temperature of gases at the exit becomes
T4 695 K . Therefore, the compressor work input, turbine work output, and the back work ratio respectively are
wc 552.17 310.24 241.93 kJ/kg, wt 1046.04 707.22 338.82 kJ/kg, rbw 241.93 / 338.82 0.714.Since
15000
the net work output is wnet 96.89 kJ/kg, the mass flow rate of the actual engine becomes m 154.81 kg/s.
96.89
96.89
Similarly, for qin 1046.04 552.17 493.87 kJ/kg, the thermal efficiency of the engine is 19.61%
493.87 .
Figure 8.22 Effect of pressure ratio (rpB>rpA) on thermal efficiency for fixed T3, and T1
Due to limited ability of the material for the turbine blades to withstand the high thermal and rota-
tional stresses, there is an upper bound for the turbine inlet temperature. Figure 8.22 demonstrates that as
the pressure ratio increases (rpB>rpA) the amount of heat supplied and rejected both decrease for a fixed
turbine inlet temperature. However, the decrease in heat supply is less than the heat rejected, and this
causes an increase in the engine thermal efficiency. In fact, there is an optimum pressure ratio, rpo, for
which the thermal efficiency attains a maximum value at a specified turbine inlet temperature, T3.
Let us express the net work output of the engine with respect to pressure ratio as,
350 THERMODYNAMICS
c pT1 rp 1
k 1 / k
For the maximum value of wnet the derivative of Eq. (8.21) has to be zero, dwnet / drp 0 . Hence
for constant values of T1 and T3, taking the derivative of Eq. (8.21) with respect to rp and equating
to zero yields,
k /2k 1
T
rpo ct 3 (8.22)
T1
This relation indicates that the higher inlet temperature allows for increased pressure ratio and
improves the thermal efficiency. If we exceed the temperature limit for blade durability, then the
blades become brittle and take the shape shown in Figure 8.23a even for a short operational period
of the engine.
Increasing the gas stream temperature beyond the safe limit and keeping the blade surface tem-
perature as low as possible can be accomplished by a blade cooling scheme. Figures 8.23b and 8.23c
illustrate the application of this scheme to the first stage blades of a gas turbine engine.
Example 8.8 Due to application of blade cooling scheme to the first stage of the gas turbine engine in Example 8.7, the
inlet temperature of gas stream, T3, is raised to 1904K. At ambient conditions of 1bar, 310K, determine the thermal efficiency
and the back work ratio for optimum pressure ratio. Assume constant specific heats of air, and take k=1.4.
Solution: 1.4/(20.4)
1904
As given by Eq. (8.22), the optimum pressure ratio for maximum efficiency is rpo 0.86 0.89 15.0 .
310
0.285
Then, by Eq. (8.19), the thermal efficiency becomes b 1 15 0.5378 . Since the specific heats of air are assumed
to be constant, the back work ratio may be expressed as,
CHAPTER 8 POWER PRODUCING SYSTEMS 351
k 1/ k
wc T1 rppo 33100 150.285
rbbw 0.46
wt T3 ct 1904 0.86 0.89
With respect to these results, the engine efficiency and the back work ratio values are incomparably convenient than the
values at rp=6.0. However, the designer has to realize that the compressors and the turbines become more expensive with
increasing the pressure ratio.
q h3 h2
(8.23)
qmax h5 h2
where, q m a h3 h2 . If we assume that the mass flow rates of compressed air and the exhaust
gas are approximately the same m a m g , then the maximum temperature of air attainable at the
exchanger exit will be identical with the inlet temperature of the hot exhaust gas T3 T5 . Thus the
352 THERMODYNAMICS
maximum heat flow rate becomes qmax m a h5 h2 . A greater amount of fuel will be saved by an
exchanger having a higher effectiveness. Higher effectiveness, however, requires a larger heat transfer
surface area that causes a larger pressure drop. The pressure drop especially on the high pressure side
of the regenerator is an important parameter and is usually kept below 2-percent of the compressor
discharge pressure. The effectiveness of the most regenerators in use is generally below 0.85.
Let us formulate the thermal efficiency of air standard Brayton cycle with regeneration for which
the effectiveness is taken to be unity ( 1 ). For constant specific heats of air, the thermal efficiency
may be expressed as,
T6
1
qo T6 T1 T1 T1
1 1 1 (8.24)
qi T4 T3 T4 T3
1
T4
Since 1 , we realize that T6 T2 , and T5 T3 . In addition, the temperature ratios in Eq. (8.24)
k 1 1 k
may be expressed as, T6 / T1 T2 / T1 r p
k
and as, T3 / T4 T5 / T4 rp
k
. Substituting these tem-
perature ratios into Eq. (8.24) and rearranging yields,
T1 kk1
1 rp (8.25)
T4
As shown in Figure 8.24b, the term T1 / T4 indicates the temperature ratio of the cyclic minimum
to the maximum temperature. This parameter has to be as low as possible for high thermal efficiency.
Similarly, as verified by Figure 8.25, regeneration becomes more effective at lower pressure ratios.
Example 8.9 Consider the regenerative gas turbine engine in Figure 8.24a that has a compressor pressure ratio of 5.0,
and the isentropic efficiencies of compressor and the turbine respectively are 0.85, and 0.9. The regenerator effectiveness
is 0.72. For ambient temperature at 300K, the turbine inlet temperature is 1300K. Determine,
a. the back work ratio and the net work output,
b. the gas temperatures at the turbine outlet, and at the regenerator exit,
CHAPTER 8 POWER PRODUCING SYSTEMS 353
Solution:
a. Using the air tables (A24), h1 300.19 kJ/kg, pr1 1.386 , and for pr 2 / pr1 5.0 , pr 2 6.93 , the isen-
tropic enthalpy at state 2 is h2 s 477.24 kJ/kg. Through the compressor efficiency, the enthalpy at state 2 is
477.24 300.19
h2 300.19 508.48 kJ/kg. Similarly, at state 4, the enthalpy is h4 1395.97 , pr 4 330.9 and for
0.85
pr 4 / pr 5 5 , pr 5 66.18 , the isentropic enthalpy at state 5 is h5 s 888.27 kJ/kg. By using the turbine efficiency, the
enthalpy at state 5 may be calculated as h5 1395.97 0.9 1395.97 888.27 939.04 kJ/kg. Considering the definition
of regenerator effectiveness (Eq. (8.23)), the enthalpy at state 3 is h3 508.48 0.72 939.04 508.48 818.48 kJ/
kg. Hence, the turbine work output and the compressor work input respectively are wt 1395.97 939.04 456.93
kJ/kg, wc 508.48 300.19 208.29 kJ/kg. The back work ratio becomes, rbw 208.29 / 456.93 0.455 , and the
net work is wnet wt wc 248.64 kJ/kg.
b. By air tables, the gas temperature at the turbine outlet is T5 906.2 °C. For the same mass flow rate at both sides of
the regenerator, the energy balance requires that h3 h2 h5 h6 , or 818.48 508.48 939.04 h6 and h6 626.04
kj/kg, T6 618 K.
c. qin 1395.97 818.48 577.49 kj/kg, and 248
248.64
64 / 577
577.49
49 43.05% .
d. For the similar engine with no regenerator, qin h4 h2 1395.97 508.48 887.49 kj/kg, and qout h5 h1 638.85
638.85
kj/kg. Then the engine efficiency is 1 28.01% .
887.49
This result shows that the effect of regenerator on the engine efficiency is predominantly strong for gas turbine engines
operating at low compression ratios.
Working fluid is usually cooled down to its inlet temperature through the inter cooler of the com-
pressor. Besides, due to avoiding excessive temperatures, the amount of air drawn into the combustor
is four times larger than the amount needed for a stoichiometric combustion. As shown in Figure 8.26a,
this excess oxygen may be used for burning of additional fuel sprayed into the reheat combustor.
Due to application of inter-cooling and reheating, the working fluid leaves the compressor at a
lower temperature and the turbine at a higher temperature. This makes regeneration more attractive
in these systems.
354 THERMODYNAMICS
Figure 8.26 Gas turbine engine with intercooling, reheating and regeneration
Therefore, in addition to inter-cooling and reheating, these systems also have regenerator, and
as in Figure 8.26a, air leaving the compressor may be heated to a higher temperature before entering
the combustion chamber.
Figure 8.26b is the T-s diagram of an ideal Brayton cycle with inter-cooling and reheating. The
regenerator is also assumed to be an ideal heat exchanger with 1 . The air enters the first stage of
the compressor (state 1), and is compressed isentropically to an intermediate pressure (state 2), and
is then cooled to inlet temperature by an inter-cooler (state 3). In the second stage, it is compressed
to the final pressure (state 4). Air enters the regenerator where it is heated to the turbine exhaust
temperature for 1 and at constant pressure (state 5). After the combustor (state 6), the gas enters
and expands isentropic ally through the first stage of the turbine (state 7). The gas is then reheated at
constant pressure where it enters the second stage of the turbine (state 8). At the turbine exit (state
9), the gas enters the regenerator and is cooled at constant pressure (state 10). The cycle is completed
by purging the exhaust gases into the atmosphere (state1).
As shown in Figure 8.27b, for two-stage compression and expansion systems, air is usually cooled
to the inlet temperature of the first compressor (T3=T1) and the gas is reheated to the inlet temperature
of the first stage (T6=T8). In addition, let us assume that the efficiency of the compressors respectively
are c1 , and c 2 . Then the total work consumed by the compressors is,
k 1
k 1
1 p2 k 1 p k
wc c pT1 1 4
1 (8.26)
c 2 p2
c1 p1
Since the overall compression ratio is defined as, rp p4 / p1 rp1rp 2 , then the above relation may
be expressed in terms of rp1 as following,
k 1
1
k 1
1 r k
wc c pT1 rp1 k 1
p
1 (8.27)
c 2 rp1
c1
CHAPTER 8 POWER PRODUCING SYSTEMS 355
For minimum work consumption, the derivative of Eq. (8.27) with respect to pressure ratio rp1
has to be zero. After mathematical manipulations, the optimal pressure ratios may be formulated as,
k k
2 k 1 2 k 1
rpo1 c1 rp and rpo 2 c2 rp (8.28)
c 2 c1
In accord with this result, the compressor with higher efficiency should have the higher pressure
ratio. For a special case of identical efficiencies, both compressor stages share the same pressure ratio,
rpo1 rpo 2 and the intermediate pressure p2 becomes the geometric average of the initial and the final
pressures as following,
Referring to the basic definition of cyclic efficiency, the thermal efficiency of this system may
be determined as following,
w net
1
q out
1
qout1 qout 2
(8.30)
q in q in qin1 qin 2
Example 8.10 A two-shaft gas turbine engine in Figure 8.27 produces 6 MW of power and operates with two compressor
stages having an overall pressure ratio of 16:1. Air inlets each compressor at 300 K, and the high pressure turbine derives the
compressors with an isentropic efficiency of 80-percent for each one. With an isentropic efficiency of 86-percent for each
turbine, the high pressure turbine derives the compressors and the low pressure turbine generates the power. The exhaust
gases at the exit of low pressure turbine flow through a regenerator having an effectiveness of 0.75.
Neglect the mass of fuel, and all pressure losses, and assume that c pa 1.005 kJ/kgK, ka 1.4 for air, and that c pg 1.15
kJ/kgK, k g 1.33 for combustion gases. Determine,
a. the temperature of the gas at the turbine inlet,
b. the back work ratio,
c. the mass flow rate of air,
d. the thermal efficiency of the cycle.
Figure 8.27 A two-shaft gas turbine engine with intercooling, reheating and regeneration
356 THERMODYNAMICS
Solution:
a. The pressure ratio for each compressor is 4 ( rp1 rp 2 4 ) and the temperature ratio for isentropic compression is
T2 s T T / T 1
(4)0.285 1.4845 . Then the temperature at the compressor exit is T2 T1 1 2 s 1 481.68 K T4 .
T1 c
The total work consumed by the compressors is wc 2 1.005 481.68 300 365.18 kJ/kg. This work has to
0.248
T T7 s 1
be supplied by the high pressure turbine and calculated as, wt1 t c pg T6 1 7 s where 0.709 ,
T6 T6 4
and substitution yields the gas temperature at the turbine inlet as, 365.18 1.15 0.86 T6 1 0.709 or
T6 1268.9 K. The gas temperature at the turbine exit may be calculated by the turbine isentropic efficiency as,
T7 T6 t T6 T7 s 951.34 T9 .
b. Since the turbines are identical, each one produces the same work, wt1 wt 2 365.18 kJ/kg. Hence the back work
365.18
ratio becomes rbw 0.5
2 x365.18
Wnet 6000
c. The mass flow rate for the required power production is m 16.43 kg/s.
wnet 365.18
d. To find out the heat input at the first combustion chamber (CC1), the temperature at state 5 has to be calcu-
lated by the effectiveness of the exchanger, T5 T4 T9 T4 833.92 K. Hence, the heat input at CC1 is
qin1 h6 h5 1.15 1268.9 1.005 833.92 621.15 kJ/kg. Similarly, for the reheat combustor (CC2),
qin 2 h8 h7 1.15 1268.9 951.34 365.19 kJ/kg. Thus the thermal efficiency is
365.18
37%
621.15 365.19
In the above example, a case for two-stage compression and two-stage expansion has been studied. If more and more
stages are added to the system, the thermal efficiency will increase and approach to Carnot efficiency. However, the contri-
bution of each additional stage to thermal efficiency is not identical, and in fact, becomes less and less. Therefore, the use
of more than two or three stages may not be economically justified.
Let us assume that the temperature at the turbine inlet is fixed at T3 1000 K, referring to Figure
8.28, increasing the atmospheric temperature from 250K to 310K causes a drop of 21.8-percent in the
thermal efficiency of a simple gas turbine engine working at pressure ratio of rp 8.0 .
Several methods like inlet fogging, or injection of water droplets are employed to make the gas
turbine engines insensitive to the variation of the ambient temperature.
Since the high power, light weight, and small volume are the most inevitable design parameters of
these engines, the configuration and the design of jet engines differ significantly from those stationary
gas turbines. To start with, we have not considered the effect of kinetic energy change in stationary
gas turbine analysis. In jet engines, however, due to considerable change in gas speeds, the kinetic
energy term cannot be neglected. Therefore, the analysis can be done in terms of stagnation (total)
temperature or stagnation (total) pressure where kinetic energy is taking into consideration.
The stagnation conditions, as given by Eq. (6.25), are obtained by decelerating the flow isen-
tropically to zero velocity. Hence, at the engine inlet, the stagnation (total) values of temperature and
pressure are,
358 THERMODYNAMICS
k / k 1
T00 T0 V02 / 2c p and p00 p0 T00 / T0 (8.31)
For an adiabatic inlet duct, the stagnation enthalpy will be constant, h00 h01 . However, due to
effect of friction, and turbulence, a drop of 5 to 10-percent in total pressure may take place between
states (0) and (1). For an isentropic flow of air through the inlet section, we may simply state that
T00 T01 , p00 p01 .
For jet engines, the compressor pressure ratio is expressed as the ratio of total pressures as fol-
lowing,
rc p02 / p01 (8.32)
Then, the isentropic and actual stagnation temperatures at the compressor exit are,
k 1
T02 s T01
T02 s T01rc k and T02 T01 (8.33)
c
The pressure losses in the combustion chamber may be neglected and the combustion is assumed
to take place at constant total pressure, p03 p02 . Neglecting the mass of fuel injected into the com-
bustor, and considering the fact that the power produced by the turbine is absorbed by the compressor,
the following relation holds,
Similar to stationary gas turbine engines, the durability limit of blade material determines the
stagnation temperature at the turbine inlet, T03 . Hence, for a predetermined value of T03 , the isentropic
discharge temperature, T04s , and the stagnation pressure, p04 , at the turbine exit may be calculated as,
k / k 1
p5 / p04 T5 / T04 (8.37)
Example 8.11 An aircraft flies at a speed of 200m/s at an altitude for which the atmospheric temperature and pressure
respectively are 260K, and 60 kPa and uses a gas turbine engine schematically shown in Figure 8.29b for producing trust.
Assume that no losses occur at the engine intake, and the mass flow rate of air through the engine is 80kg/s. The engine
operates at a compressor pressure ratio of 8, with the turbine inlet temperature at 1200K. The compressor and turbine ef-
ficiencies are 0.9 and 0.88 respectively. At the turbine exit, combustion gases flow through an isentropic and convergent
nozzle. Take k 1.4 , and c p 1.005 kJ/kgK throughout the engine, and determine,
CHAPTER 8 POWER PRODUCING SYSTEMS 359
Solution:
40000
a. The stagnation temperature and pressure at the intake duct are T00 260 1 279.9 K,
2 1005 260
T
kept constant, p00 p01 , and T00 T01 . The work consumed by the compressor is wc c pT01 02 1 where
T
01
T02 T / T 1 , and T02s 8 0.285 1.808 . Substituting backwards yields, T02 1.897 , T 530.97
1 02 s 01 02
T01 c T01 T01
K, wc 252.32 kJ/kg, p02 8 x77.67 621.36 kPa, and T03 1200 K.
and the gas velocity at the exit becomes, V5 2 1005 948 790 563.5 m/s.
c. Since p03 p02 621.36 kPa, and rt p03 / p04 then p04 621.36 / 3.9 159.32 kPa. By Eq. (8.37), the
0.287 790
v5 2.693 m3/kg. Considering the mass flow rate of air and the continuity equation, the nozzle exit
84.165
mv 80 2.693
area becomes A5 5 0.382 m2.
V5 563.5
p04 159.32
d. The applied pressure ratio for the present nozzle is 2.655 . However, as calculated previously, the
p0 60
p04 p p
nozzle critical pressure ratio, 1.892 , is smaller than the applied pressure ratio, 04 04 and the nozzle
p5 p5 p0
flow has to be at chocked conditions.
If the combustion process of a cycle is not part of that cycle, the composition of the working fluid
will not be altered throughout the cycle, and the engine working with this principle is called the ex-
ternal combustion engine. The Stirling engine is a typical Example for external combustion engines.
Due to complexity of its construction for performing the cycle processes and high manufacturing cost,
however, Stirling engines are generally used for small scale power needs varying in the range 0.5 kW
to 5 kW. Figure 8.30 illustrates some of the applications of Stirling engine.
As shown in Figure 8.31a, Stirling engine generally uses air as the working fluid, but helium is
also used at some particular applications. The cycle is composed of two isothermal and two isochoric
processes. There are two pistons in two different cylinders A and B. As in Figure 8.31a, one of the
pistons is called power piston (P), and the other is displaced piston (D). At state 1 in Figure 8.31b, the
displacer D is at BDC and piston P is at TDC, and the air in cylinder A is at temperature T1.
Isothermal compression process. (1-2) As the crankshaft rotates clockwise direction between 1
and 2, D moves from BDC to TDC compressing the air isothermally at temperature T1, and heat is
rejected ( qout ).
Isochoric heating process. (2-3) As piston P continues moving downward, the cold fluid in cylinder
A is pushed through the regenerator and is heated to temperature T3. Since the sum of volumes above
the piston P and D in both cylinders is constant, the heating process takes place at constant volume.
Isothermal expansion process. (3-4) Air in cylinder B is at temperature T3, and both pistons move
downward as the crankshaft rotates from 3 to 4. Heat is added by high temperature reservoir at T3 to
keep the temperature constant ( qin ) at T3=T4.
Isochoric cooling process. (4-1) Displacer D continues moving downward, and the piston P moves
upward. Hence, air flows from hot cylinder B to cylinder A by passing through the regenerator, and is
cooled down to temperature T1. Again this cooling process takes place at constant volume.
For an ideal regenerator, it can be shown that the heat absorbed by air from the regenerator during
process (2-3) is identical to the heat given by air to the regenerator at process (4-1). Thus, the exchange
of heat with external sources takes place during isothermal processes.
The thermal efficiency of the Stirling engine is determined by considering the fundamental effi-
ciency relation as, 1 qout / qin . For an ideal cycle with an ideal regenerator, qin T3 s4 s3 and
qout T1 s1 s2 . To calculate the entropy change, we may use Eq. (5.30) as, s4 s3 R ln v4 / v3
and s1 s2 R ln v1 / v2 . As indicated in Figure 8.31b, v1 v4 and v2 v3 , then the volume ratios
become identical as, v1 / v2 v4 / v3 . Hence, the entropy change of both isothermal processes is identi-
cal, s1 s2 s4 s3 , and the preceding relations yield,
T1
1 (8.38)
T3
The ideal Stirling cycle has the same efficiency as the Carnot cycle. However, to accomplish iso-
thermal compression and expansion process in a machine running at a certain speed is considerably
hard and is almost impossible.
Example 8.12 Ideal Stirling engine, as shown in Figure 8.31, operates with 0.1kg of air as a working fluid between tem-
peratures of 10000C and 300C. The highest power piston pressure is p3 3000 kPa, and the lowest pressure of the displacer
piston is p1 500 kPa. Determine,
Solution:
p4V4 p1V1
a. Since the process (4-1) is a constant volume process, applying the ideal gas equation results as, ,
T4 T1
1273
or p4 500 2100.66 kPa.
303
p3V3 p2V2
b. Similarly, for displacer piston, we consider the process (2-3), and apply the gas equation as, , then
T3 T2
303
p2 3000 714.1 kPa
1273
c. To raise the temperature of working fluid from T2 to T3 during process (2-3), the amount of heat supplied by the
regenerator is
Q23 U 3 U 2 mcvm T3 T2 0.1 0.8 970 77.6 kJ/cycle. Similarly, the amount of heat rejected during
the process (4-1) through the regenerator is Q41 U1 U 4 mcvm T1 T4 0.1 0.8 970 77.6 kJ/cycle.
The specific heat of air is determined at the arithmetic mean temperature, and the results show that the amount of
heat rejected by hot air is totally absorbed by cold air at the regenerator.
362 THERMODYNAMICS
d. Since the process (3-4) is isothermal, the work done and the heat supplied are identical for an ideal gas,
W34 Q34 Qin p3V3 ln p3 / p4 0.1 0.287 1273 ln 3000 / 2100.66 13.02 kJ/cycle. Similarly, the heat
rejected at low temperature reservoir is, W12 Q12 Qout p1V1 ln p1 / p2 0.1 0.287 303 ln 500 / 714.1 3.1
kJ/cycle.
e. The net work obtained at each cycle is calculated as, Wnet W12 W34 3.1 13.02 9.92 kJ/cycle. Since
Wnet
the thermal efficiency of the engine is defined as, , substitution of numerical values of Wnet and Qin
Qin
9.92
into efficiency relation yields, 76.2% . The same result could also be obtained by Eq. (8.38).
13.02
qin h1 h4 (8.39)
The rate of fuel consumed and the heat transferred to steam may be related through the boiler
efficiency as,
where, H u kJ/kg-fuel, is the fuel heating value, and ηboiler, describes the portion of the fuel energy
transferred to water and is defined as,
m s h1 h4
boiler (8.41)
m f H u
CHAPTER 8 POWER PRODUCING SYSTEMS 363
364 THERMODYNAMICS
2. Turbine. High pressure and temperature steam at the boiler exit flows to steam turbine where part of
its energy is converted to shaft work and transmitted to an electrical generator. Unless stated, turbine
is essentially an adiabatic device and the work is represented by process (1-2) or (1´-2´) in Figures
8.32b, c, and d and calculated as,
wt h1 h2 t h1 h2 s (8.42)
3. Condenser. The low energy steam flowing out of turbine condenses and becomes saturated liquid
at the condenser exit. The heat rejection process in the condenser is isobaric, and is represented by
process (2-3) or (2´-3) in Figures 8.32b, c, and d. The specific energy rejected at the condenser is,
qout h2 h3 (8.43)
As shown in Figure 8.32a, the heat rejected in the condenser is transferred to a separate cooling
water loop which in turn delivers this energy to atmosphere by cooling towers. The mass flow rate of
the cooling water is calculated by the following energy balance equation,
m w c pw T m s h2 h3 (8.44)
4. Feed water pump. The low pressure of condensate is raised to boiler pressure by a feed water
pump. The process is indicated by line (3-4) in Figures 8.32b, c, and d. Since the working fluid is
at liquid state at the pump inlet, the required work is incomparably smaller than the work needed to
transport vapor at the same pressure differential. Referring to Eq. (6.20), the adiabatic pump work
may be calculated as,
CHAPTER 8 POWER PRODUCING SYSTEMS 365
h4 s h3 v p4 p3
w p h4 h3 (8.45)
p p
The ideal Rankine cycle is the one with the isentropic efficiencies of unity for both the turbine and
the pump. As shown in Figure 8.35a, the ideal Rankine cycle is depicted with area (123461) and is not
Carnot cycle. In fact, Carnot cycle is not a realistic model for Rankine cycle. As defined by area (12561)
in Figure 9.35a, to complete Carnot cycle, the liquid –vapor mixture at state (5) has be compressed
isentropically to saturated liquid state. First, it is almost impossible to device a system which provides
an appropriate quality so that after the compression process water is at saturated liquid state. Secondly,
there is no such a pump that compresses two-phase flow. As an alternative system, if we run the Carnot
cycle as shown in Figure 8.35b, the problem of pumping two-phase flow is eliminated. However, an-
other problem of transferring heat isothermally at decreasing pressure between states (6) and (1) arises.
Moreover, the process (6-1) takes place above the critical point and is unpredictable at what phase the
water will be during this process. Hence, Carnot is not an ideal cycle for Rankine cycle.
Figure 8.35 Unrealistic features of Carnot and comparison with ideal Rankine cycle
Similar to the other cycles as explained in this Chapter, Eq. (8.6) may be used for calculating
the energy based thermal efficiency of Rankine cycle. In determining the overall efficiency of the
plant, however, fuel heat energy released by combustion has to be compared with the electrical
power at the generator outlet as following,
W g W g Wnet Q in
o g Rb (8.46)
Q fuel Wnet Q in Q fuel
Example 8.13 As shown in Figure 8.36, a coal fired steam power plant running with a simple Rankine cycle produces
250MW of power at the generator outlet and provides the following data at the specified states.
4 Pump exit 60 - - - -
Solution:
V2 2502
a. The turbine specific work is, wt h1 h2 2 3195.7 2383.6 780.85 kJ/kg. Referring to the isen-
2 2000
v p4 p3 0.001 6000 20
tropic efficiency of the pump, the pump specific work is w p h4 h3 8.54
p 0.7
kJ/kg, and the enthalpy at state 4 becomes, h4 251.4 8.54 259.94 kJ/kg. Hence, wnet wt w p 772.31 kJ/
W g 250000
kg, the net power at the turbine outlet is Wnet 263157.89 kW. The corresponding steam mass
g 0.95
Wnet 263157.89
flow rate is m s 340.74 kg/s
wnet 772.31
wp 8.54
b. The back work ratio is rbw 1.09% and is much lower than the values for gas turbine engines.
wt 772.31
c. The heat loss through the pipe line connecting the boiler and the turbine is
Q lossm h h 340.74 3309 3195.7 38605.8 kW.
s 5 1
d. The boiler capacity is Q in 340.74 3309 259.94 1038936.7 kW. Then the thermal efficiency of the cycle is
Wnnet 263157.89
R 25.3% . Without any heat loss through the connection pipes, the heat input in the boiler
Q iin 1038136.7
263157.89
is Q in 340.74 3195.7 259.94 1000330.86 kW and the cyclic efficiency becomes R 26.3% .
1000330.86
W g Q 1038936.7
e. Referring to Eq. (9.45), the overall efficiency of the system is o , where Q fuel in 1331970.13
Q fuel b 0.78
250000
kW. Hence, o 18.77% .
1331970.13
Q fuel 1331970.13
f. The coal consumption rate is calculated by m f 44.69 kg/s or 160.9 tons of coal per
Hu 29800
hour.
CHAPTER 8 POWER PRODUCING SYSTEMS 367
g. The condenser heat capacity is Q con m s h2 h3 340.74 2383.6 251.4 726525.8 kW. The energy balance
Q con 726525.8
at the condenser yields the mass flow rate of cooling water as, m w 17381 kg/s or 62571.6
c p T 4.18 x10
tons of water per hour.
As shown in Figure 8.37b, if we increase the boiler pressure by keeping the condenser pressure
constant, the net work increases by blue area (A55´1´A+34´5´3) but decreases by the amount of red
area (122´A1). As a result, there might be some increase in the net work, but the amount of heat re-
jected definitely decreases by green area (266´2´2).
368 THERMODYNAMICS
As illustrated in Figure 8.38, for an ideal Rankine cycle with fixed condenser pressure at 0.2
bars and saturated vapor at the turbine inlet, the overall effect is to increase the plant efficiency
as the boiler pressure increases. If pressure in the boiler is increased, the temperature at which
heat is added during evaporation also increases. Due to increase of average temperature of the
working fluid, the cycle efficiency will increase. Although it is an advantage to increase the
boiler pressure as much as possible, there are practical limitations as boiler components have to
be sufficiently robust to withstand the high pressures. Besides, increase in thermal efficiency is
not linearly proportional with the increase in boiler pressure. In Figure 8.38, increase in thermal
efficiency is 8.7-percent for raising the pressure from 50bar to 100bar. However, the efficiency
increase drops to 2.9-percent by increasing the pressure from 100 bars to 150 bars. Thus, the
generally accepted maximum economical pressure and temperature for circulating boilers is at
about 160bar and 560°C.
As discussed below, several modifications can be done on Rankine cycle for further improvement
in thermal efficiency and for better specific net work output.
There is an optimum pressure of reheat for which the cyclic efficiency is kept at maximum level.
The optimum values of reheat pressure lie in the range 20% to 30% of the initial pressure of steam.
Since the steam is reheated in the boiler, the thermal efficiency has to be defined as following,
wnet qout
1 (8.47)
qin1 qin 2 qin1 qin 2
Example 8.14 As in Figure 8.39, steam at a pressure of 20bar, 320°C is expanded through a first stage of the turbine to a
pressure of 5bar. It is then reheated at constant pressure to the initial temperature of 320°C and expanded through the second
stage to 10 kPa of condenser pressure. Assume ideal cycle,
Solution:
a.
370 THERMODYNAMICS
6 20 - 193.82 0.649 -
b. The total specific work of turbines is, wt h1 h2 h3 h4 3069.5 2757 3105.6 2386.8 1031.3
kJ/kg. Since the pump work is w p v p6 p5 0.001 2000 10 1.99 kJ/kg, then the net work out-
put of reheating becomes, wnet 1031.3 1.99 1029.31 kJ/kg.. Without reheating unit, the net work is
wnet 3069.5 2168.3 1.99 899.21 kJ/kg. Hence by reheating the specific net work of the same plant has
been increased by 14.46-percent.
For the cycle without reheating, the heat input is, qin h1 h6 3069.5 193.82 2875.68 kJ/kg, and thermal ef-
ficiency becomes 31.27% . The change in efficiency is reheat 31.9 31.27 0.63% .
c. Increase in specific net work is wnet 1029.31 899.21 130.1 kJ/kg. Due to reheating, the extra power de-
veloped by the plant is, Wnet m s wnet 100 x130.1 13.01 MW.
Comments. Even though the efficiency of the system is slightly improved, the major en-
hancement is done on the net power developed. As numerically determined, 13.01 MW of extra
power is gained by the implication of reheating. This is why reheating is a preferred method in
large power plants.
Definition: Preheating the water before entering the boiler by steam extracted from the main stream
expanding in the turbine is called regeneration.
CHAPTER 8 POWER PRODUCING SYSTEMS 371
Even though regeneration reduces the amount of steam flowing into the condenser, the power
generated by the same steam flow rate also lessens. Hence no actual alleviation in efficiency takes
place due to energy monitoring. Increase in efficiency is solely due to increase of feed water tem-
perature at the boiler inlet.
Figure 8.41 illustrates a simple regenerative Rankine cycle with a single feed water heater (FWH)
which transfers heat to feed water incoming from the condenser. The particular heater in Figure 8.41a
is an open type heater and the extracted steam at state 2 in Figure 8.41b is directly mixed with the feed
water at sub-cooled conditions at state 5. Since the mixing takes place at steam extraction pressure,
the pressure of condensed water at state 4 is increased to mixing pressure by pump A. The amount of
extracted steam is such that the mixture becomes saturated liquid at the outlet of the heater (state 6 in
Figure 8.41b). Finally, the pressure of feed water is raised to boiler pressure by pump B.
A feed water heater is basically a heat exchanger and the types shown in Figure 8.42 are used in
regenerative systems.
372 THERMODYNAMICS
Open feed water heaters are simple, inexpensive, and provide saturated liquid at the outlet. For
regenerative systems furnished with open feed water heaters, the number of pumps needed is one
more than the number of heaters ( n p nheater 1 ). The amount of steam extracted may be determined
by the energy balance around the feed water heater in Figure 8.41a as following,
m 2 h2 m m 2 h5 mh
6
Representing the extracted amount as the fraction of steam flowing into turbine and rearranging
yields m h h
y 2 6 5 (8.48)
m h2 h5
Hence, feed water at the heater outlet is at the saturation temperature of extracted steam pressure.
Closed feed water heaters are generally shell and tube type and feed water passes through the
tubes while steam flows on the shell side. The steam condensates and either passes through a trap
to a lower pressure heater (drains cascaded backward), or is pumped by a condensate pump into the
main feed water line (drains pumped forward). The steam traps are designed in such a way that only
allows condensed liquid to flow through by reducing the pressure but they are leak free to superheated
or saturated steam.
As necessitated by open type heaters, there is no need for a pump at the inlet of each heater.
However, closed type feed water heaters are more expensive, and as shown in Figure 8.43, are more
complex due to internal tubing network. For all types of heaters, the optimum pressure at which the
steam should be extracted is determined as following: 1. Single heater, the feed water temperature at
the heater outlet should the arithmetic average of boiler saturation temperature and condenser tem-
perature. 2. Several heaters, the temperature difference between the boiler and the condenser should
be divided as equally as possible among heaters.
Figure 8.43 Closed type feed water heater and installation types
CHAPTER 8 POWER PRODUCING SYSTEMS 373
Example 8.15 As shown in Figure 8.41, consider an ideal regenerative cycle with a single open type feed water heater.
Steam enters the turbine at 40bar and 400°C, and some of steam is extracted at an appropriate pressure for regeneration.
The rest of steam expands to condenser pressure of 10 kPa. Determine,
a. the appropriate pressure for steam extraction,
b. percent of steam extracted,
c. efficiency of the system
Solution:
a. The saturation temperatures at 40bar and at 0.1bar respectively are 250.40C, and 45.80C. Then the mean temperature
becomes Tm 250.4 45.8 / 2 148.1o C , and the steam extraction pressure should have a value between 4bar
and 4.5bar. Let the pressure at state 2 be p2 4 bar.
b. For p2 4 bar and s2 s1 6.769 kJ/kgK, x2 0.97 , the enthalpy at state 2 is h2 604.7 0.97 2133.8 2674.48
kJ/kg. For isentropic pump, the outlet and inlet enthalpy difference is h5 191.83 0.001 400 10 or h5 192.22
kJ/kg. By Eq. (8.47), the fraction of extracted steam becomes y 604 604.74
74 192 22 / 2674
192.22 2674.48
48 192 22 0.166
192.22
c. The steam quality and the enthalpy at the condenser inlet respectively are x3 6.769 0.649 / 7.5 0.816 , and
h3 2144.3 kJ/kg. The heat rejected at the condenser is qout 1 y h3 h4 0.834 2144.3 191.8 1628.38
kJ/kg. Similarly, the enthalpy of feed water at the boiler inlet is calculated as, h7 604.74 0.001 4000 400
or h7 608.34 kJ/kg, and the heat input at the boiler is qin h1 h7 3213.6 608.3 2605.26 kJ/kg. Hence the
1628.38
thermal efficiency of the cycle becomes, 1 37.5%
2605.26
Essentially we may convert an ideal Rankine cycle to Carnot cycle by using very large number of
heaters. Due to economical considerations, however, this is not only impractical but also impossible.
You may add a heater only if it saves more fuel than its cost and maintenance. Modern power plants
generally use up to 8 feed water heaters. The power plant shown in Figure 8.44 includes reheating
and also regeneration. Two heaters one open and the other closed type are used for regeneration. In
Figure 8.44, the condensed steam (state 12) and the feed water at the outlet of close feed water heater
(state 10) are usually taken to be at the saturation temperature of steam extraction pressure at that
particular heater.
374 THERMODYNAMICS
Example 8.16 As presented in Figure 8.44, a steam power plant operates on ideal Rankine cycle with reheating and uses
two feed water heaters for regeneration. One of the heaters is open type and the other is closed type with drains pumped
forward. Steam enters the turbine at 160 bar, and 560°C, and expands to condenser pressure of 0.1bar. At the exit of high
pressure turbine, some steam is extracted for closed feed water heater at 30bar, and the remaining is reheated to 560°C.
Steam for open type feed water heater is bled from low pressure turbine at 4 bar. A cross drum type boiler with a steam
capacity rate of 50kg/s is used in the plant.
a. Draw T-s diagram of the cycle.
b. Determine the fraction of steam extracted at each bled point.
c. Calculate the thermal efficiency and the net power developed by the plant.
Solution:
a. State no. Pressure (bar) Temp.(0C) Enthalpy(kJ/kg) Entropy(kJ/kgK) Quality(%)
1 160 560 3465.4 6.513 -
2 30 300 2993 6.513 -
3 30 560 3591.6 7.398 -
4 4.0 - 2964 7.398 -
5 0.1 45.8 2345 7.398 0.899
6 0.1 45.8 191.8 0.649 0.0
8 4.0 143.6 604.7 1.77 0.0
12 30 233.9 1008.4 2.79 0.0
Figure 8.45 Tabulation of state properties and T-s representation of the cycle
b. Energy balance around the closed feed water heater yields, y1h2 1 y1 h9 h12 1 y1 h10 , where
h9 604.7 0.001 16000 400 620.3 kJ/kg, and h10 h12 . Substituting the enthalpy values results with the
steam extraction ratio at state 2 as, y1 0.413 and 1 y1 0.587 .
Similarly, for the open type heater, the energy balance yields, h4 y2 h7 0.587 y2 0.587 h8 , wherev
h7 191.8 0.001 400 10 192.19 , and the steam extraction fraction at state 4 is, y2 0.087 .
c. To determine the thermal efficiency, first we have to evaluate the enthalpy of feed water at the boiler entrance
(state 11), the enthalpy at state 13 is h13 1008.4 0.001 16000 3000 1021.4 kJ/kg. The energy bal-
ance at the mixing box yields, h11 y1h13 h10 1 y1 . Substitution of enthalpy values yields h11 1013.7
kJ/kg. Hence, heat input at the boiler is qin1 h1 h11 3465.4 1013.7 2451.7 kJ/kg. In addition, heat
input due to reheating is, qin 2 1 y1 h3 h2 351.37 kJ/kg. The heat rejected at the condenser is cal-
culated as, qout 1 y1 y2 h5 h6 1076.6 kJ/kg. Hence, the thermal efficiency of the plant becomes,
q 1076.6
1 out 1 61.59% .
qin 2451.7 351.37
The specific net work output of the plant is wnet 0.6159 2451.7 351.37 1726.41 kJ/kg and the power
output is Wnnet 50 1726.41 86.32 MW.
CHAPTER 8 POWER PRODUCING SYSTEMS 375
8.10 Cogeneration
Cogeneration means the combined production
of electricity and heat in an energy conversion
facility. Because of this feature, cogeneration
plants are also called Combined Heat and Power
(CHP) systems. As described by Example 8.17,
cogeneration makes sense only when there is a
continuous demand for large amount of heat at
power plant location. Hence, the energy transferred
to water in the boiler is utilized as process heat Figure 8.46 A cogeneration plant
as well as electric power.
All continuous processes used in industrial plants such as petrochemicals, hydrocarbon refineries,
food processing units, dairy plants, pharmaceuticals require uninterrupted energy input in the form of
power and heat. Hence, it is appropriate to define a utilization factor εu for a cogeneration plants as,
u
W net Q
process
1
Q out
(8.49)
Q in Qin
where Q out represents the heat rejected in the condenser. Notice that the utilization factor of co-
generation plant with an ideal cycle is 100-percent. Actual cogeneration plants have utilization factors
as high as 80-percent.
Example 8.17 Let us consider the plant in Figure 9.46 that requires 2.5 MW of electrical energy and 3.0 MW of heat energy
for its processes. Analyze the methods available to solve the energy needs of the system and determine which method is
more economical.
Solution:
a. If we solve the electrical energy and heat requirement of the system by separate plants, then a centralized power
plant meets the electrical energy requirement by consuming 6MW of fuel energy. Similarly, as shown in Figure
8.47a, the need for steam can be met by a coal fired steam boiler. Considering the losses of these two systems
(4.5MW), the need for total fuel energy becomes 10MW of conventional generation. However, if we use a cogen-
eration plant, as shown in Figure 8.47b, to supply the same amount of power and heat, the total fuel energy needed
may be reduced to 7MW.
The cogeneration system configuration used in various plants is classified in the following
sections.
376 THERMODYNAMICS
For ξ values in the range 4.0 15.0 , usually back pressure type steam turbines are used.
However, for ξ values,1.0 8.0 , extraction-condensing steam turbines are preferred. As shown
in Figure 8.48a, at times of high demand for process heat, some steam leaving the boiler is throttled
and then routed to the process heater. The extraction fractions are adjusted so that steam leaves the
process heater as saturated liquid.
Example 8.18 As shown in Figure 8.49, an extraction-condensing cogeneration plant is modified with regeneration. Steam
at 4MPa, and 500°C enters the high pressure turbine and expands to 0.5MPa. At this pressure, 50-percent of steam is ex-
tracted and the remainder expands to 20kPa. Part of the extracted steam is used for 20MW capacity process heater and the
rest feeds the open type feed water heater at 0.5MPa. After leaving the process heater and the FWH, the saturated liquid is
pumped to the boiler.
a. Draw the T-s diagram of the cogeneration plant.
b. Determine the mass flow rate of steam through the boiler.
c. Calculate the net power developed, and the utilization factor of the plant.
Solution:
a. T-s diagram of the plant is indicated above.
640.2 251.88
b.
With respect to energy balance on FWH, 0.5 y f h6 y f h2 0.5h5 , or y f 0.5
2855.4 640.2
0.088 ,
20000
y p 0.5 0.088 0.412 . The mass flow rate for process heater is m p 9.02 kg/s, and the
2855.4 640.2
9.02
mass flow rate through the boiler becomes, m 21.89kg/s.
0.412
378 THERMODYNAMICS
c. Wt 21.89 3445.3 2855.41 0.5 2855.4 2336.1 18596 kW, W p 21.89 0.5 0.48 3.5 81.86
kW. Wnet 18514.14 kW. The boiler capacity is Q in 21.89 3445.3 643.7 61327 kW. Hence the utiliza-
20 18.514
tion factor of the plant is u 0.628 .
61.327
As illustrated in Figure 8.50, a gas turbine based cogeneration system provides recovery of heat
in exhaust flue gases by a boiler for steam production or by a heat exchanger to generate hot water for
district heating purposes. If the heat output of the system is less than that required by the consumer,
it is possible to have supplementary firing by mixing additional fuel to oxygen rich exhaust gas to
boost the thermal capacity.
Gas turbine based cogeneration plants is ideal for chemical industries where the demand of steam
is high and fairly constant in comparison to that of steam turbine based cogeneration.
8.51, the exhaust gases from the gas turbine produce high pressure steam in a waste heat boiler.
Depending upon the plant needs, the high pressure steam expands through a back-pressure or
extraction-condensing steam turbine to generate additional power, and some portion of steam might
be used as process steam.
When the ratio of electrical power to thermal load is high, the cogeneration plant based on combined
cycle principle provides better results than the gas turbine cogeneration plant. In combined cycles,
about 66-percent of power is generated in gas turbine and the rest 34-percent in steam turbine, and
the plant utilization factor achieves values above 90-percent.
Example 8.18 The combined gas-steam power plant in Figure 8.51 works with a pressure ratio of rp 9 in gas turbine
part and air enters the compressor at 290 K, and the turbine at 1500 K. The combustion gases leaving the gas turbine
are utilized in a waste heat recovery boiler and steam at 10 MPa and 500°C is produced. The combustion gases leave
the boiler at 250°C. After expanding in a high pressure turbine to 1 MPa, 60-percent of steam is utilized for 1.5 MW of
process heat and the rest is reheated to 500°C at the combustor before expanding in low pressure turbine to 10 kPa. As-
sume ideal combustion, and all compression and expansion processes are isentropic. Determine,
a. the mass flow rate of air,
b. for fuel heating value of 40,000 kJ/kg, the rate of fuel consumed,
c. the thermal efficiency of the overall plant,
d. the plant utilization factor.
380 THERMODYNAMICS
9 1000 658.94
10 10000 667.94
11 1000 500 3478.5 7.762
12 10 2460.17 0.948
13 10 191.8
Solution:
1500
a. The mass flow rate for process heater is m p 0.739 kg/s, and the mass flow rate of steam through
2790 762.8
9.02
the boiler becomes, m s 1.233 kg/s. Flue gases leave the boiler at 2500C with the enthalpy of 526.63kJ/kg.
0.6
Energy balance around the boiler yields the mass flow rate of air as, m a
1.233 3373.7 667.94
8.859 kg/s
903.2 526.63
b. Energy balance around the combustor gives us the heat input of the system as,
qin 8.859 1635.9 544.3 0.494 3478.5 2790 10010.6 kW. Hence the fuel consumption rate be-
10010.6
comes, m f 0.25 kg/s
40000
c. The net power of the gas turbine is Wnet gas m a h3 h4 h2 h1 42359.56 k W . The
power consumed by pumps 1 and 2 respectively are W p1 0.494 0.0011000 10 0.489 kW and
W 1.233 0.001 10000 1000 11.097 kW. Then, the net power developed by steam turbine is,
p2
Wnet steam 1.233 3373.7 2790 0.494 3478.5 2460.17 0.489 11.097 o r Wnet steam 1211.214
kW. The total power of the plant is W net 5450.77 kW, and with respect to Eq. (8.30), the plant efficiency is
5450
5450.77
77 / 10010
10010.66 54.45%
d. The amount of heat rejected at the condenser is qout m 12 h12 h13 0.494 2460.17 191.8 1120.57 kW,
1120.57
and by Eq. (8.49), the plant utilization factor becomes u 1 88.8% .
10010.6
Besides industrial waste heat, heat sources such as solar and geothermal energy as well as biomass
can be utilized by ORC systems. Because of small temperature range, only a simple Rankine cycle can
be used. As shown in Figure 8.52, due to low temperature of the heat source, the cycle efficiency is
rather low and varies in the range of 8-percent and 16-percent. Because of free fuel source, however,
efficiency is not a critical parameter.
When appropriate working fluid and operating conditions are selected, the power produced by an
ORC system varies in the range of 0.1MW to 1MW. Organic fluids such as Pentane and Freon family
fluids are preferred in ORC systems. As can be seen by Figure 8.53, working fluids are classified with
respect to the slope of the saturation curve in a T-s diagram as following: (1) wet (negative slope), (2)
isentropic (vertical), and (3) dry (positive slope).
Referring to Figure 8.53, to avoid occurrence of liquid droplets that impinge and cause erosion on
the turbine blades during the expansion, isentropic or dry fluids are selected for ORC systems. Besides,
the specific volume of such fluids (refrigerants) at low temperature is incomparably less than that of
steam, and the desired turbine size can be much smaller and less expensive. High density and latent heat
are desirable properties for working fluids by that high turbine specific work output can be provided.
382 THERMODYNAMICS
An ORC cycle with regeneration used as geothermal power plant is shown in Figure 8.54a. The
working fluid of the cycle is isopentane. The geothermal fluid (usually liquid water) enters the vapor-
izer at state (w1). If the fluid pressure is sufficiently high, there is no need for a gas extraction system,
and the non-condensable gases will not separate from the fluid. Geothermal fluid cools down in the
vaporizer at constant pressure, and then is re-injected into the well at state (w2). ORC fluid enters the
vaporizer at state (2), and becomes saturated or superheated at the vaporizer exit (state 3) and enters
the turbine. At the turbine exit (state 4), ORC vapor enters the regenerator where the condensed ORC
fluid is preheated prior to the vaporizer entry. Moreover, the cooled vapor enters the condenser at
state 5 and becomes saturated liquid at the condenser exit (state 6).
Figure 8.54 Schematic of ORC power plant with regeneration and T-s diagram representation
Air cooled condensers are generally used for ORC plants with the cooling air entering the con-
denser at state (a1) and leaving at state (a2). Figure 9.54b represents the T-s diagram of ORC power
cycle with regeneration. Because of regeneration, the heat extracted between states 4 and 5 must be
the same with the heat given between states 1 and 2.
References
1. Heywood, J. B., Internal Combustion Engine Fundamentals, McGrawHill Publications, ISBN-0-07-028637-X, 1988.
2. Giampaolo, T., Gas Turbine Handbook-Principles and Practice, 4th edition, CRC Press,ISBN-10: 0-88173-613-9, 2009.
3. Kiameh, P., Power Generation Handbook-Selection, Applications, Operation, and Maintenance, McGrawHill Publica-
tions, ISBN: 00 71396047, 2002.
4. Leyzerowich, A. S., Steam Turbines for Modern Fossil-Fuel Power Plants, The Fairmont Press Inc., ISBN: 0-88171-
548-5, 2008.
5. Barclay, F. J., Combined Power and Process-An Exergy Approach, Professional Engineering Publishing Ltd., ISBN:
1-86058-129-3, 1998.
6. Turns, S. R., An Introduction to Combustion Concepts and Applications, 2nd Edition, McGrawHill, ISBN: 0-07-230096-5,
2000.
7. Mollenhauer, K., and Tschoeke, H., Handbook of Diesel Engines, Springer-Verlag, ISBN: 978-3-540-89082-9, 2010.
8. Oates, G. C., Aerothermodynamics of Gas Turbine and Rocket Propulsion, 3rd edition, American Institute of Aeronautics
and Astronautics, Inc., ISBN: 1-56347-241-4, 1997
CHAPTER 8 POWER PRODUCING SYSTEMS 383
Problems
SI and CI engine cycles, dual cycle Hint: Assume variable specific heats.
8.5 A four-cylinder gasoline engine has a displacement
volume of 2.2 L and operates with a compression ratio
8.1 A four-cylinder 3.2-liter SI engine operates on a four of 12:1. Air at the inlet is at 17°C, 100 kPa, and 1600
stroke cycle at 3000 rpm. At this condition, 1kJ of kJ/kg of heat is added by the combustion process.
indicated work is produced in each cylinder at each Assuming variable specific heats, determine,
cycle. Determine,
a. the net work output,
a. the mean effective pressure, b. the thermal efficiency,
b. the torque produced by the engine at the given c. the mean effective pressure of the cycle.
speed.
8.8 A 5L SI engine as shown in Figure 8.57 is mounted 8.11 A construction vehicle as shown in Figure 8.58 has
on a hydraulic dynamometer provides an output of a Diesel engine with eight cylinders of bore 12 cm
60 HP at 4000 rpm. Water absorbs the energy output bore, and 20 cm stroke and operates on a four-stroke
of the engine as it flows through the dynamometer cycle. The engine with a compression ratio of 18:1
delivers 250 HP at 1000 rpm. Determine,
at a rate of 1.5 L/s. Water inlets the dynamometer at
10°C. For a dynamometer efficiency of 95-percent, a. the engine total displacement volume,
evaluate b. the mean effective pressure,
a. the temperature of water at the dynamometer c. the torque at 1000rpm.
exit,
b. the torque output of the engine,
c. the mean effective pressure at this condition.
a. the mass of air in the cylinder, a. the net specific work output,
b. the pressure and temperature at the end state of b. the mean effective pressure,
each process, c. the thermal efficiency of the cycle,
c. the specific compression and expansion work, d. the thermal efficiency of Carnot cycle operating
d. the thermal efficiency of the engine. between the same temperature levels.
CHAPTER 8 POWER PRODUCING SYSTEMS 385
8.21 A proposed air standard piston-cylinder arrangement of 15, and a maximum temperature of 777°C. The
cycle consists of the following processes: (1-2) Isen- volumetric flow rate of helium at the compressor
tropic compression process, (2-3) Constant volume inlet is 350 m3/min. Assume constant specific heats
heat addition, (3-4) Isentropic expansion, (4-1) evaluated at 300K, and calculate,
Constant pressure heat rejection. The compression a. the power output of the cycle,
ratio of the cycle is 9:1, and the heat added at constant b. the rate of heat input,
volume process is 1250 kJ/kg. For air at 95 kPa, 17°C c. the thermal efficiency of the cycle.
at the beginning of the compression process, draw
the cycle on T-s diagram and evaluate,
a. the net work of the cycle,
8.26 A large stationary power plant uses simple Brayton
b. the thermal efficiency of the cycle,
cycle and produces a power of 102 MW. The mini-
c. the mean effective pressure.
mum and the maximum temperatures in the cycle
respectively are 300K, and 1700K. The compressor
8.22 An air standard cycle with constant specific heats compression ratio is 14:1, and air inlets the compressor
is enclosed in a piston-cylinder arrangement and at a pressure of 95 kPa. The isentropic efficiencies
is composed of the following processes: (1-2) of both turbine and the compressor are identical at
Isentropic compression with a compression ratio 88-percent. Evaluate,
of 6, (2-3) Constant pressure heat addition, (3-1) a. the power output of the turbine,
Constant volume heat rejection. Air at the begin-
b. the back work ratio,
ning of compression process is at 100 kPa, 27°C,
c. the thermal efficiency of the cycle.
and 951 kJ/kg of heat is added during the constant
pressure process. Sketch the p-V and T-s diagrams
of the cycle and evaluate,
a. the net work of the cycle, 8.27 A gas turbine engine at San Francisco Power Station
b. the back work ratio of the cycle. takes in 110,000kg/h of filtered outside air at 27°C
and compresses it to 6.516bar. Due to combustion,
30MW of heat is added to the air, and the turbine
exhausts to atmospheric pressure of 1bar. Assuming
Gas turbine engines, regeneration, intercool-
both the compressor and the turbine are 75-percent
ing, reheating, and stirling cycle
efficient,
8.23 A simple ideal Brayton cycle with air as the working a. draw the T-s diagram of the cycle,
fluid has a pressure ratio of 10. The air enters the b. evaluate the net power output and the efficiency
compressor at 17°C and the turbine at 850°C. Ac- of the cycle.
counting for the variation of the specific heats with
temperature, evaluate,
a. the air temperature at the compressor and at the
turbine exits,
b. the net work output,
c. the thermal efficiency of the cycle.
8.28 An air standard cycle is executed in a closed system c. the temperature of air at the inlet of the combus-
and is composed of the following processes: (1-2) tion chamber, T3,
Isentropic compression from (95 kPa, 17°C) to 10 d. the thermal efficiency of the cycle.
bar, (2-3) Constant pressure heat addition in amount
of 2500 kJ/kg, (3-4) Constant volume heat rejection
to 95 kPa, (4-1) Constant pressure heat rejection
to initial state. Assume constant specific heats at
17°C, draw the cycle on p-V and T-s diagrams, and
determine,
a. the maximum temperature of the cycle,
b. the thermal efficiency of the cycle.
c. Compare the efficiency of this cycle with the ef-
ficiency of air standard Brayton cycle operating
between the same pressure limits and supplied
with the same amount of heat.
8.33 Regeneration in Brayton cycle is useful only when a. the maximum air temperature,
the turbine exhaust temperature is greater than the b. the power required by the first and the second
compressor exhaust temperature. As the compres- compressors,
sion ratio increases, however, the difference in these c. the back work ratio, and the net power devel-
temperatures decreases and the effectiveness of oped,
regeneration vanishes. Determine an expression for d. the thermal efficiency of the cycle.
the pressure ratio of an ideal regenerative Brayton
cycle in terms of Tmin , Tmax , and k for which ef-
fectiveness of regeneration becomes zero. Assume 8.36 A large gas turbine plant producing 10 MW of power
constant specific heats, and evaluate the pressure comprises low pressure (LP) and high pressure (HP)
ratio for Tmin 17 oC , Tmax 1627 oC and k 1.4 compressors and turbines, and air inlets the plant at
. 7°C, 95 kPa. Air is compressed to 300 kPa in the
LP stage and then inter-cooled down to 27°C with
a pressure loss of 10 kPa. The air pressure is arisen
8.34 As shown in Figure 8.64, air enters the turbine of to 1200 kPa after the HP compressor. Air flowing
an ideal gas turbine engine at 1600 kPa, 1400K and through a regenerator with an effectiveness of 0.65
expands to 100 kPa in two stages. Air is reheated to is heated by hot gases from LP turbine and then exits
1400K at a constant pressure of 400 kPa between the the combustor at a temperature of 817°C. Air leaves
stages. Determine the following per kg of atmospheric the HP turbine at a pressure of 350 kPa, and then
air at 27°C flowing through the engine, reheated to 767°C with a pressure loss of 10 kPa.
Isentropic efficiencies of all turbines and compres-
a. the work developed by each turbine stage, sors are identical at 82%. Sketch the system, and
b. the work consumed by the compressor, calculate,
c. the heat added at both combustors, a. the back work ratio, and the net specific work
d. the percent increase in the net work as compared output,
to a single turbine with no reheat. b. the mass flow rate of air,
c. the thermal efficiency of the cycle.
8.44 Water is the working fluid in a Rankine cycle. Su- a. the net power developed,
perheated water vapor at 60 bar, 540°C enters the b. the thermal efficiency of the cycle,
turbine with a mass flow rate of 7.5 kg/s and exits at c. the mass flow rate of cooling water through the
20 kPa. Leaving the condenser as saturated liquid at condenser.
20 kPa enters the feed water pump. The isentropic
efficiencies of the turbine and the pump are t 0.87 8.47 Water is the working fluid of a Rankine power cycle
and p 0.80 . Cooling water enters the condenser shown in Figure 8.69. Turbine is non-adiabatic and
at 20°C and exits at 28°C. Neglecting any pressure loses heat at a rate of 2500kW. Assume no pressure
loss throughout the cycle, show the cycle on a T-s and heat losses on the connecting pipes, and sketch
diagram and determine, accurately T-s diagram of the cycle. Determine,
a. the net power developed by the cycle,
b. the thermal efficiency of the cycle,
c. the mass flow rate of cooling water through the
condenser.
8.45 Water is the working fluid of a Rankine power cycle
and leaves the boiler at 90 bar, 480°C. Due to pressure
loss and heat transfer effects in the pipe-line between
the boiler and the turbine, the state of steam at the
turbine inlet becomes 85bar, 440°C. At the exit of
adiabatic turbine with isentropic efficiency of 85%,
the pressure is reduced to 20 kPa, and water leaves
the condenser 16 kPa, 40°C. The feed water pump
with 80% isentropic efficiency increases the water
pressure to 95 bar before entering the boiler. For
water mass flow rate of 16.5 kg/s, calculate,
a. the net power developed,
b. the thermal efficiency of the cycle,
c. the rate of heat loss at the pipe line connecting
Figure 8.69
the boiler and the turbine.
a. the heat capacity of the boiler,
8.46 As shown in Figure 8.68, a conventional Rankine
b. the power output of the turbine,
power cycle with water as the working fluid has a
turbine and a pump operating with identical isentropic c. the thermal efficiency of the cycle,
efficiencies as t p 0.85 . Steam enters the turbine d. the thermal efficiency of Carnot cycle operating
at 80 bar, 520°C, and exits to condenser pressure of between the same temperature limits.
6 kPa. The heating capacity of the steam generator
is 500 MW. In the condenser, the cooling water is e. The temperature rise of cooling water through
the condenser is designed to be 12oC. Calculate
available at 17°C, and we wish to limit the temperature
the mass flow rate of cooling water.
increase of water by 10°C. Determine,
f. Evaluate the rate of entropy production for the
turbine, condenser, pump, and the connecting
pipes.
g. Using the results of part (f), place components in
rank order by beginning with the one contributing
the most inefficiencies.
a. For isentropic turbine and pump, evaluate the a. the vapor temperature at the inlet of each tur-
boiler pressure, the net specific work output, bine,
and the thermal efficiency of the cycle.
b. the thermal efficiency of the cycle.
b. Repeat the same problem for a turbine with an
isentropic efficiency of 88%. Assume the pump
to be isentropic.
a. the fraction of steam extracted for feed water b. Reanalyze the whole system for the same operating
heater, conditions and constraints but the air temperature
b. the net power output of the system, at the compressor inlet has increased from 290K
to 310K. Determine the drop in power output for
c. the thermal efficiency of the cycle.
the same mass flow rate of air as calculated in
a. Assume the same isentropic efficiencies and
regenerative effectiveness.
a. Determine the cost of heating in December that can be met by this form of cogeneration plant if the electricity
consumption of the campus is 2500 kWh for that month. Assume that gasoline yields 25 MJ of heat energy per
liter and the cost of gasoline at the pump is $0.87 per liter.
b. Compare also the cost of purchasing the electricity from the grid at $0.17 per kWh with the results of (a).
8.62 A proposal is made to use a geothermal supply of hot water at 15 bar, 170°C to operate a steam turbine. Water is first
throttled into a flash chamber in which liquid and vapor phases are separated at 5bar pressure. The liquid is discarded
while saturated vapor flows into the turbine and exits at 8 kPa of pressure. The turbine isentropic efficiency is 85%,
and water at the turbine exit is reinjected back to the source. Draw the system schematically, and determine the mass
flow rate of geothermal hot water required for producing 1 MW of power at the turbine shaft.
8.63 The geothermal supply of hot water in problem 8.62 is to be utilized by running a Rankine cycle with isopentane
as the working fluid. As shown in Figure 8.76, pentane enters the turbine as saturated vapor at 1000 kPa, and exits
at 100kPa. Pentane is then condensed at 100 kPa and leaves the condenser as saturated liquid at 28°C. Assume that
both the pump and the turbine share the same isentropic efficiency of 82%, and the data of pentane at the specified
states are given by the table below.
CHAPTER 8 POWER PRODUCING SYSTEMS 395
Determine,
a. the mass flow rate of geothermal hot water for producing 1 MW of power at the turbine shaft,
b. the thermal efficiency of the cycle,
c. the mass flow rate of air flowing through the condenser, if cooling air inlets the condenser at 15oC and experi-
ences 10°C of temperature rise,
d. the frontal area of the condenser if the air velocity at the inlet is 20m/s.
5. The primary reason for replacing the exhaust process 9. An ideal Stirling engine operates with 0.01kg of
of Otto and Diesel cycles with a constant volume carbon dioxide as the working fluid between tem-
process is: peratures of 1027°C and 27°C. The highest and the
lowest pressures during the cycle are 20bar and
a. no heat transfer of the actual exhaust process,
1.5bar respectively. If the engine runs at a speed of
b. no work transfer of the actual exhaust process,
200rpm, then the power developed in kW is:
c. restoring air to its initial conditions,
d. satisfying the second law of thermodynamics a. 3.5, b. 4.5,
for the cycle. c. 5.5, d. 6.5.
8. An simple Brayton cycle is modified to incorporate c. 332, 40%, 5, d. 322, 45%, 15.
multi-stage compression and expansion with intercool-
ing and reheating. As a result of this modification,
a. compressor work: increases
turbine work: increases
efficiency: increases
b. compressor work: increases
turbine work: increases
efficiency: increases
c. compressor work: decreases
turbine work: increases
efficiency: increases
d. compressor work: increases
Figure 8.77 Schematic of reheat
turbine work: increases
Rankine cycle
efficiency: increases
398 THERMODYNAMICS
12. The demand for energy from an industrial plant at 13. A steam plant uses a simple ideal Rankine cycle
steady state conditions is 50MW of process heat with one regenerative feed water heater. The boiler
at 120°C, and a maximum of 40MW of power to produces steam at 80bar 500°C. For a condenser
drive the electrical generators. Steam is available pressure of 0.1bar, the pressure (kPa) at which steam
from the boiler at 60bar, 550°C, and the condenser has to be extracted, and the efficiency of the plant
pressure is 0.05bar. The process heat is extracted respectively are,
from the turbine at an appropriate pressure, and
a. 600, 36%, b. 800, 42%,
the condensed steam returns to the feed water line
c. 800, 48%, d. 600, 54%.
at 120°C. Neglect the feed pump work, assume a
linear relationship between enthalpy and entropy,
and take the isentropic efficiency of the turbine as
95%. Then the steam flow rate in kg/s through the
boiler becomes:
a. 30.6, b. 38.6,
c. 46.6, d. 54.6.
14. Consider the ammonia Rankine cycle power plant as in Figure 8.78. The plant is designed to operate in a location where
geothermal hot water at 170°C is available. Ammonia at the turbine inlet is at 20bar, 120°C, and expands to 12bar of
condenser pressure. Both the turbine and the pump share the same isentropic efficiency of 90%, and the geothermal
water exits the vaporizer at 80°C. If you assume that the specific heat of geothermal water is c p 4.2 kJ/kgK , then
for 5MW of net power output, the mass flow rate from the geothermal well in tons per hour is:
a. 832, b. 932, c. 732, d. 1032.
Refrigeration Systems
9.1 General Considerations
Refrigeration is part of our life and without it modern life would be impossible. The
need for refrigeration arises from the fact that keeping a space at its low temperature re-
quires withdrawing the amount of heat leaking into the space through a higher temperature
environment. Because of this fact, refrigeration systems are used for food preservation and
processing, for commercial refrigeration (supermarkets, cold stores, and refrigerated trans-
port), industrial refrigeration (chemical processing, petrochemicals etc.) and for domestics
needs (air conditioning, domestic refrigerator etc.).
Refrigeration is a cyclic process by which the transfer of heat from a low temperature
level at the heat source to a high temperature level at the heat sink is accomplished by work
type of energy consumption. Hence for refrigeration cycles, we may state that W 0 .
399
400 THERMODYNAMICS
As shown in Figure 9.1, for a typical cold store in supermarkets, the thermal energy moves from
left to right through five loops of heat transfer as it is extracted from the cold space and expelled into
the outdoors. In the leftmost loop of Figure 9.1, (loop1) indoor air of a conditioned room is driven
by a supply air fan through a cooling coil, and (loop2) its heat is transferred to chilled water. Water
flows through the evaporator of the refrigeration system and transfers the heat to condenser water by
the refrigeration cycle (loop3). Water absorbs the heat from the condenser and the heated water is
pumped to the cooling tower (loop4). The fan of the cooling tower derives air across the hot condenser
water, and thus the heat is transferred to the outdoors (loop5).
Depending upon the refrigeration application, the required temperature level of the refrigerated
space might change. Table 9.1 provides typical refrigeration temperatures and the corresponding
areas of application.
Table 9.1 Temperature levels for typical refrigeration applications
To condition the air or a product to the above indicated temperatures, various refrigeration methods
are devised and are in use in practice. Figure 9.2 shows the classification of refrigeration methods that
are most widely used in domestic and industrial applications.
In selection of a proper refrigeration method, not only the required refrigeration capacity but also
the temperature level has to be considered. Besides, the application environment is also a factor. Even
though more than one refrigeration method may be suitable for a given application, the selection has
to be tested by factors like cost, reliability, size, and unit power.
CHAPTER 9 REFRIGERATION SYSTEMS 401
Among these cooling methods indicated in Figure 9.2, the vapor compression refrigeration cycle
is the most widely used refrigeration cycle in practice. Since the refrigeration capacities are in the
range of 50W and 1MW, and the evaporator temperatures may vary between +5C and -70C, these
systems are suitable for many applications in commercial, domestic, and air conditioning sectors.
Constant pressure heat rejection in a condenser, qcon h2 s h3 , refrigerant at the condenser out-
let is at saturated liquid state, (3-4) Throttling in an expansion device, h3 h4 , and (4-1) Constant
pressure heat absorption in an evaporator, qev h1 h4 . Then the coefficient of performance of ideal
VCRC is,
q h h
COPideal ev 1 4 (9.1)
wcs h2 s h1
In VCRC, there are two pressure zones, the low pressure zone starts at the exit of the expansion
valve and ends at the inlet of the compressor (p4=p1), and the high pressure zone lies between the
exit of compressor and the inlet of the expansion valve (p2=p3). The transfer of heat at the refrigerated
space and at the condenser may be maintained by respective conditions of Tev Ti , and T0 Tcon .
402 THERMODYNAMICS
An actual vapor compression refrigeration cycle is depicted in Figure 9.4. In this particular cycle,
the cold space and the surroundings are respectively maintained at Ti=+2C, and T0=+23C, and the
working fluid is R134a. Due to losses, the pressures at the evaporator exit and the compressor inlet
are not the same. In Figure 9.4, similar behavior can be traced between the compressor exit and the
expansion valve inlet. In addition, due to heat transfer, the refrigerant at the compressor inlet is su-
perheated, and is sub-cooled at the expansion valve inlet.
Figure 9.5 presents deviations between actual and ideal refrigeration cycles. In numbering the
actual states of the refrigerant, the actual vapor compression cycle in Figure 9.4 is considered. Then
the main deviations are as follows: 1. (a) type difference takes place due to heat transfer at the
connection pipes, 2. (b) type difference is the pressure drop in regions evaporator-compressor and
compressor-condenser, and 3. (c) type difference is the deviation of compression process from isen-
tropic compression. As a result, the actual work consumed and the actual COP of the refrigeration
plant may be calculated as,
h2 s h1a qev h1 h4 a
wc h2 a h1a COPactual (9.2)
c wc h2 a h1a
Example 9.1 For an ideal refrigeration cycle using R134a, the evaporating and the condensing temperatures respectively
are -10C, and +34C. If the refrigeration capacity is 80 kW, determine,
a. the volume flow rate of the refrigerant at the inlet of the compressor,
b. the power required by the compressor,
c. the COP of the cycle.
Suppose that the actual cycle is as depicted in Figure 9.4, repeat questions a, b, and c for the actual cycle and evaluate
the isentropic efficiency of the compressor.
Solution:
Ideal cycle:
80
a. Energy equation for the evaporator is Q ev m h1 h4 and m 0.555kg/s additionally V1 mv
1,
241.3 97.31
V1 0.555 0.099 or V1 3.296 m3 / min .
b. Wcs m h2 s h1 , s1 s2 s 0.925kJ/kgK and h2 s 271.52kJ/kg , Wccs 0.555 271.52 241.3 16.77 kW
80
c. the COP of the cycle by Eq. (9.1) is, COPiideal 4.77
16.77
Actual cycle:
80
a. Employing similar analysis, Q ev m h1 h3a , m 0.505kg/s and
241.3 82.9
V1 0.505 0.099 60 2.969m3 / min
b. Respect to Eq. (9.2), the compressor power is Wc 0.505 294 253 20.705 kW
80
c. The cycle COP on the other hand is COPaactual 3.86 .
20.705
W
d. The isentropic efficiency of the compressor is c cs . However, the conditions at the inlet of the actual case
Wc
differ from the ideal one. Thus Wcs m h2 sa h1a 0.505 288.1 253 17.725 kW and the compressor ef-
17.725
ficiency is c 0.85 .
20.705
Example 9.2 Some refrigeration systems use a liquid-to-suction heat exchanger to increase the COP of the system. As
shown in Figure 9.6, this may positively affect the refrigeration capacity but also increases the work consumed by the com-
pressor. Thus, as an overall result, the heat exchanger may provide a negligible advantage. Consider an ideal VCRC with
R22 as the working fluid. The heat exchanger warms up the saturated vapor at -10C coming from evaporator from -10C
to 0C with liquid coming from condenser at +32C. Determine,
a. the COP without the heat exchanger on the system,
b. the COP with the heat exchanger on the system.
404 THERMODYNAMICS
Solution:
Referring to (h-p) diagram, the evaporator specific cooling rate is qev h1 h4 246.15 84.14 162.01 kJ/kg . Since
the cycle is ideal, s1 s2 0.9424 kJ/kgK and wc h2 h1 277.5 246.15 31.35 kJ/kg . Then the performance of the
162.01
cycle is COP1 5.16
31.35
Q ev1 Q ev2
COPsys (9.3)
Wc
Example 9.3 A refrigeration system as depicted in Figure 9.7 uses R22 as the working fluid and the low temperature evapo-
rator with a capacity of 5ton operates at Tev2=-20C. The higher temperature evaporator having a capacity of 3tons operates
at -5C. The cycle is ideal and the condenser pressure is 16bars. Determine,
a. the mass flow rate of refrigerant through each evaporator, and the compressor,
b. the compressor power input,
c. the condenser capacity.
Solution:
a. Refrigerant leaves both evaporators as saturated vapor, and the condenser as saturated liquid. Since,
1 ton refrigeration=3.516kW , then the refrigeration capacities of both evaporators are Q ev1 10.548 kW
and Q ev 2 =17.58 kW . Considering the energy equation for both evaporators and Table A6 for R22,
10.548 17.58
m 1 = 0.069kg/s , m 2 = 0.121kg/s , m =m 1 +m 2 =0.069+0.121=0.19kg/s
248.16 96.83 242.09 96.83
b. First, the enthalpy of the refrigerant at the compressor inlet has to be evaluated. For an ideal mixing with no heat loss,
m 1h8 m 2 h7 mh
1 thus h1 245.21 kJ/kg . For s1 s2 0.97 kJ/kgK , and p2 16bar , the enthalpy at the compressor
exit is h2 295.0 kJ/kg . Then the compressor power becomes Wc =m h2 h1 0.19 295 245.21 9.46 kW .
c. One way of determining the condenser capacity is Q con =m h2 h3 0.19 295 96.83 37.65 kW . The other
alternative way is Q con Q ev1 Q ev2 Wc 10.548 17.58 9.46 37.588 kW . The difference between these two
results is due to table reading error.
406 THERMODYNAMICS
Q ev
COPsys (9.4)
Wc1 Wc 2
Example 9.4 a. Determine energy savings in kW-h per year by using the refrigeration system as depicted in Example
6.12 instead of a single stage system operating at the same conditions. Assume that both systems are ideal and operate 8400
hours a year. b. Evaluate percent increase in COP of the system
Solution:
a. Recalling the data of Example 6.12, the refrigerant is R22, evaporator capacity is 200 kW, and works at Tev=-30C,
and the condenser pressure is 1500 kPa. The total power required is W 64.795 kW . If the system had been a
t
single-stage one with the same evaporator and condenser pressures, then the cycle would be as (19510) cycle on
(h-p) diagram of Figure 9.8. Since s9=s2=s1=0.9787 kJ/kgK, and p9=1500 kPa, Table A6 yields h9=292.97 kJ/kg.
qe 200
Additionally, the refrigerant flow rate would be m 1 1.386kg/s . Then the power required
h1 h10 237.7 93.5
for single stage compression is Wc m h9 h1 or Wc 1.386 292.97 237.7 76.604 kW . Thus the annual
energy savings due to two-stage compression is, ES 76.604 64.795 8400 or ES 99,195.6kW-h/year
q 200
b. The COP of the system with two-stage compression is COPts ev 3.08 . Similarly for single stage
Wt 64.795
200 3.08 2.61
compression, COPs 2.61 . Thus the percent increase in COP becomes COP % 100 or
76.604 2.61
COP % 18% which is a considerable increase in COP.
CHAPTER 9 REFRIGERATION SYSTEMS 407
In decision making stage for the use of two-stage refrigeration with inter-cooling several factors has to be considered.
Respect to evaporator operating temperature, the boiling pressure of the refrigerant to be selected should not be below 1 bar
and the specific volume should not assume high values. These two are effective criteria in selection of suitable refrigerant.
In addition, due to sudden drop in compressor efficiency, reciprocating compressors are suitable for Tev 30 C if single
stage system, Tev 50 C if two-stage system and Tev 70 C if three stage systems are employed.
In applications such as liquefaction of petroleum vapors or manufacturing of dry ice for which
Tev 70 C , it becomes advantageous to separate the low pressure region from the high and built a
cascade system. This arrangement permits selecting a suitable refrigerant for the low pressure region.
As illustrated in Figure 9.9a, a cascade system is consists of two separate single stage refrigeration
system connected by a cascade condenser that operates like evaporator for the higher system and
condenser for the lower. In sizing the lower system compressor, the specific volume of the refrigerant
at the suction line plays an important role. For instance, at Tev 60 C , the specific volume of R22
is 0.537m3/kg, and of R23 is 0.073m3/kg, so R22 occupies 7.35 times the volume of R23 and is not
suitable for the low pressure region cycle.
Figure 9.9b illustrates (h-p) diagram of a cascade system which uses R22 for the higher pressure
system and R23 for the lower. The main disadvantage of a cascade system is the overlap of tempera-
tures at the cascade condenser. This overlap is necessary for the heat transfer between the two cycles
but results with higher energy consumption due to internal irreversibilities caused by the temperature
difference.
It may be demonstrated that for two-stage Carnot Cascade system, the cascade condenser tem-
perature at which COP of the system becomes maximum is determined as following.
where Tev and Tcon are the evaporator temperature of the low pressure and the condenser tem-
perature of the high pressure cycles respectively.
Figure 9.9 A typical two-stage cascade refrigeration system and (h-p) presentation
408 THERMODYNAMICS
Q ev1 Q ev2
COPsys (9.6)
Wc1 Wc 2
Example 9.5 In a food processing unit, tuna fish first shocked at -32C and then is stored at -18C by the ammonia refrig-
eration system shown in Figure 9.10 for which the condenser operates at +40C. The cooling loads of the low and the high
pressure evaporators are estimated to be 250 kW and 150 kW respectively. Assuming isentropic compression, determine,
Solution:
a. The numbers in Figure 9.10 only represent the thermodynamic states of the refrigerant, but the mass flow rate at
the float valve is m 5l and the gas discharge from flash tank is m 3 f . Considering the energy balance around the
flash chamber,
m 5l h5 m 7 h2 m 3 f h3 m 7 h7 , and the mass balance around the chamber yields, m 7 m 5l m 3 f . The enthalpy
m 3 f h2 h5 h7 1475.1 371.35 97.68
values at states 2, 3, 5, and 7 are known. Thus, 0.625
m 5l h2 h3 h7 1475.1 1420.45 97.68
CHAPTER 9 REFRIGERATION SYSTEMS 409
Q eevl 250
b. The mass flow rate through low pressure compressor is m 2 0.191kg/s , similarly,
h1 h7 1400 1400.81
81 97.68
Q eevh 150
for the high pressure compressor, m 4 0.1429kg/s .
h3 h5 1420 1420.45
45 371.35
Comments: Recall that the system is assumed to an ideal cycle. For an actual cycle the COP will assume lower values.
Medium and large capacity refrigeration systems usually use open type compressor which
is externally driven by an electric motor or an engine. The major drawback of this type of com-
pressors is that refrigerant may leak through the seal at which crank shaft extends outside. As
shown in Figure 9.12, in hermetic compressors, the motor and the compressor are enclosed in
410 THERMODYNAMICS
the same housing and the possibility of refrigerant leakage is highly reduced. Some portion of
the refrigeration load of systems with hermetic compressors is used for cooling the motor and
thus the COP of these systems is lower than open compressor based systems. However, hermetic
compressors are usually preferred for small capacity systems like domestic refrigerators, water
chillers, and split type air conditioning units. In some hermetic units, the cylinder head of the
compressor may be removed for replacing the valves and pistons, this type of compressor is
called semi-hermetic compressor.
Reciprocating compressors. It is the most widely used compressor type in refrigeration industry
for cooling capacities in the range of 102 W to 103 kW. As illustrated in Figure 9.13, a reciprocating
compressor is a two-stroke machine. The intake and the discharge processes are completed in one
revolution of the crank shaft, and may be constructed as a single cylinder or multiple of cylinders
up to 16 cylinders.
In determining the actual mass rate of refrigerant flowing into the compressor cylinder, ideal
compressor has to be defined. As explained in Figure 9.14a, an ideal compressor is one in which;
1.There is no clearance volume, 2.No pressure drop during suction and compression period, 3.All
processes (suction, compression, and discharge) are reversible and adiabatic.
CHAPTER 9 REFRIGERATION SYSTEMS 411
In ideal reciprocating compressor, no gas is left in the cylinder at the end of discharge stroke and
suction starts as soon as the piston moves towards BDC. Referring to Eq. (6.15), the power consumed
by the compressor is,
pcon k 1
k pcon k
Wcs vdp pb vb
k 1 pev
1 h2 s h1
(9.7)
pev
As in Figure 9.14b, in actual compressors, a clearance volume, Vc, is left between the cylinder
head and the piston to tolerate the valve motion, and the thermal expansion. Hence, the clearance
ratio is defined as,
Vc
(9.8)
Vst
Depending upon the arrangements of valves and the piston speed, assumes values between
4-percent and 10-percent. Due to clearance, however, some gas will be left in the cylinder at the end
of discharge stroke. This left gas expands as the piston moves towards BDC, and the suction starts
only when the pressure in the cylinder is less than the evaporator pressure. Hence, the volumetric
efficiency of the compressor becomes,
Vb Va
Actual mass intake vb V Vc Vex vb
v b (9.9)
Mass in stroke volume Vb Vc Vb Vc vb
vb
412 THERMODYNAMICS
Since, Vex Vc pcon / pev , Vst Vb Vc , Vb Vst Vc , and due to low pressure at the suction
1/ n
stroke, the ideal gas behavior yields, vb / vb ( pb / pev ) Tev / Tb . Accordingly, rearranging Eq. (9.9)
results as,
1
Tev
v 1 rp pp
n b
x
Tb
(9.10)
ev
If the data of refrigerant at the compressor inlet are not known, the term in the right parenthesis
of the above expression may be assumed to be unity. Eq. (9.10) indicates that an increase in pressure
ratio, rp, or in clearance volume ratio, ε, decreases the volumetric efficiency. In fact the limiting value
of pressure ratio for which the volumetric efficiency becomes zero is,
n
1
rp
max
1
(9.11)
The actual pressure ratio has to be much less than this limiting value. Besides, due to leaks through
cylinder wall, the amount of refrigerant leaving the compressor at the discharge is not the same as
sucked into the cylinder. Since Vleak Vsuction Vdischarge , the discharge volumetric efficiency at the
inlet conditions may be defined as,
Vdischarge Vs Vleak
vd v 1 w (9.12)
Vst Vst
Where (1 w ) represents percent leak through the wall. As a result, the mass flow rate of refrig-
erant at the compressor exit is,
Vst vd n D 2
m vd z H (9.13)
vb vb 60 4
where, n, is rotational speed (rpm), D and H are the bore and the stroke length of the cylinder, and
z is the number of cylinders. “ vb ” indicates the specific volume at the compressor inlet.
Example 9.6 A reciprocating R134a compressor having 4 cylinders with 100mm of bore, 100mm of stroke length, and
5-percent clearance volume ratio runs at a speed of 3600rpm, and has to be used for a refrigeration system operating between
-18C and +40C evaporator and condenser temperatures respectively. A pressure drop of 0.04bar occurs at the suction
line, and the refrigerant enters the compressor with +6C superheat. The wall leaks estimated to be 10-percent of the stroke
volume. For refrigerant polytrophic index n = 1.15,
a. Determine the mass flow rate supplied by the compressor.
b. Assuming saturated vapor at the evaporator exit, evaluate the evaporator capacity in tons of refrigeration.
Solution:
a. Together with tabulated values of R134a, Eq. (9.10) yields,
1
10.16 1.15 1.44 0.04 255 The discharge volumetric efficiency
v 1 0.05 0.05 1.44 0.738
1.448
261
.
CHAPTER 9 REFRIGERATION SYSTEMS 413
by Eq. (9.12) is vd v 1 w 0.738 0.1 0.638 , and the specific volume at
(-12C, 1.4bar) is vb 0.143m3 /kg . Substituting these values into Eq. (9.13) results as
0.638 3600 3.14 x0.12
m 4 0.1 0.84 kg/s
0.143 60 4
.
b. Since the refrigeration system is a single pressure system as in Figure 9.5, then the evaporator capacity is,
0.84 236.53 106.19
Q ev m h1 h4 31.14 ton
3.516
If one considers the flow losses that take place at the compressor valve region, there exists a strong
relation between the volumetric efficiency and the compressor isentropic efficiency. Depending upon
the compressor pressure ratio and the clearance volume, the variation of the ratio of these two ef-
ficiencies, c / vd , is illustrated in Figure 9.15. Since the volumetric efficiency at the discharge
is evaluated by Eq. (9.12), then the compressor isentropic efficiency becomes,
c vd (9.14)
Especially in selection of lubrication oil for the compressor or determining the power need, the
outlet temperature of the refrigerant is required. In calculating the actual outlet temperature of the
gas, however, compressor efficiency is needed. The dependence of compressor efficiency on pressure
ratio is not the same as the volumetric efficiency. As presented in Figure 9.15, the upward trend of
curves is indicative of this difference.
Example 9.7 Consider the reciprocating R134a compressor of Example 9.6, and referring to the states indicated in Figure
9.5 evaluate,
414 THERMODYNAMICS
Solution:
a. The state of refrigerant at the compressor inlet, p2 1.4bar, T2 12 C and pressure at the exit p3 10.16bar .
The pressure ratio and the clearance volume ratio respectively are rp 7.05, =0.05 . Thus, by Figure 8.15,
1.32 , and Eq. (9.14) yields, c 1.32 0.638 0.842
h3s h2
b. Since compressor isentropic efficiency, respect to Figure 8.5, is defined as, c and tabulated values of
h3 h2
283.3 241.2
R134a yields, s2 s3s 0.953 kJ/kgK and h3s 283.3 kJ/kg . Hence, h3 241.2 291.2 kJ/kg
0.842
and R134a table yields T3 60 C
Screw compressors. Figure 9.16 illustrates the basic geometry of a screw compressor. The male rotor
is labeled as lobe and the female rotor as flute. As the male rotor turns in an outward direction, a gas
pocket enters into the void created. The trapped gas compressed when the lobes of rotor begin to mesh.
The gas will be discharged at the opposite end where the exhaust port is uncovered. The gas volume
is always reduced to a preset proportion of the inlet volume by the time the outlet port is reached.
This is called built-in volume ratio (rv) which should always correspond to working pressure ratio
for optimum power consumption of the compressor.
As shown in Figure 9.17, for the maximum compressor efficiency, as the working pressure ratio
increases the built-in volume ratio also has to increase. Screw compressors are engineered with no
valves and no rolling elements. In respect to reciprocating compressors, drastic reduction in number
of parts dramatically improves reliability of the compressor and reduces the risk of refrigeration loss.
As is in reciprocating compressors, there is no re-expansion of trapped gas, and more refrigerant can
be compressed for the same size of a compressor. Therefore, screw compressors are commonly used
for water cooled chillers having a cooling capacity of 50 to 500tons of refrigeration.
CHAPTER 9 REFRIGERATION SYSTEMS 415
Figure 9.17 Twin screw compressor efficiency for various built-in volume ratios
Example 9.8 Consider the refrigeration system given in Example 9.6 for which the refrigerant is R134a, and the conditions
at the compressor inlet and outlet respectively are p2 1.4bar, T2 12 C , p3 10.16bar . The reciprocating compressor
has to be replaced by a twin screw compressor with a built-in ratio of 4.6. Determine,
a. compressor efficiency,
b. refrigerant exit temperature,
Solution:
a. For compressor pressure ratio, rp=7.05, and built in volume ratio, rv=4.6, Figure 9.17 yields ηc=0.75.
h3s h2 283.3 241.2
b. Referring to isentropic efficiency definition, h3 h2 241.2 297.3 kJ/kg and
c 0.75
T3 65.4 C .
Scroll and vane type compressors. As in Figure 9.17, scroll compressor compresses the refrigerant
with two inter fitting spiral shaped members. One scroll is fixed, and the other orbits the fixed one
with a circular motion.
At the first orbit, the ends of both scrolls are fully open and low pressure gas flows in. As the
lower scroll completes the second orbit, the gas pocket is sealed off. The third orbit begins with the
crescent-shaped pocket is pushed toward the center decreasing the gas volume increasing the gas
pressure. At the fourth orbit, the discharge port is uncovered and the refrigerant is discharged.
416 THERMODYNAMICS
Due to flat volumetric efficiency curve, a scroll compressor provides more cooling capacity
at extreme conditions. In addition, exhibiting lower noise levels, scroll compressors are gradually
replacing reciprocating compressors in room air conditioning, heat pumps, and in package units for
residential and commercial buildings.
As shown in Figure 9.18, a vane compressor operates on the basis of varying the volume between
an eccentric rotor and a sliding vane as angular position changes. A vane compressor has a small clear-
ance volume and a greater volumetric efficiency than a reciprocating compressor. These compressors
are widely used in small refrigeration systems having cooling capacities less than 3.0 kW.
Dynamic compressors. The most common type is the centrifugal compressor. First, the impeller ac-
celerates the gas particles. Then the gas flows into a diffuser or volute where the flow is decelerated
and some of the kinetic energy is converted into pressure. As in Figure 9.19, the torque imparted
by the impeller is, T V2t r2 V1t r1 . Considering that the refrigerant enters the impeller at radial
direction, V1t 0 , and assuming that the impeller tip speed and the refrigerant tangential velocities
are identical, the power required by the impeller becomes,
In the design of centrifugal compressors, two crucial parameters are the wheel diameter and the
width between the impeller faces. In addition, considering the impeller strength, the tip speed should
not exceed the limiting value of 300 m/s. The following Example illustrates numerically the effect of
refrigerant choice on the impeller size and the tip speed.
CHAPTER 9 REFRIGERATION SYSTEMS 417
Example 9.9 An ideal refrigeration cycle operates between -10C evaporator and +36C condenser saturation tempera-
tures. The rotational speed of the impeller is 3600rpm. Evaluate the tip speed and the impeller diameter for the following
refrigerants.
a. R22
b. Ammonia (R717)
Solution:
a. Together with Eq. (9.15), referring to the tabulated values for R22, s1 s2 s 0.942 kJ/kgK, h2 s 281.5kJ/kg, T2 s 60 C ,
V2t h1 h2s or V2t 1000 281.5 246.15 188 m/s <300 m/s. Respect to tip speed the impeller di-
ameter becomes,
60V2t 60 188
D2 0.99 m
n 3.14 3600
V2t 1000 1651.2 1430.55 469.73 m/s , which is well above the limiting value of 300 m/s. The impeller
60 469.73
diameter is, D2 2.49 m . The size is also impractical for consideration.
3.14 3600
Neither the tip speed nor the impeller diameter is in manageable level for ammonia, and am-
monia is not a suitable refrigerant for the system in the example. Even for R22, the impeller size is
still large. To reduce the size to reasonable level, rotor speeds of 10,000rpm are common. For such
a speed, the impeller diameter becomes D2=36cm. A high speed two-stage centrifugal compressor
with magnetic bearings is shown in Figure 9.20. Because of the magnetic bearings, no lubrication
is needed.
The width of the impeller directly affects the mass flow rate of the refrigerant flowing through
the compressor. Systems with high refrigeration capacity require large width between the faces of the
impeller. Since the centrifugal compressors may handle relatively large flow rates, they are widely
used for systems having refrigeration capacities above 500 tons.
418 THERMODYNAMICS
Example 9.10 Consider a R134a thermostatic valve operating between -4C evaporator and +40C condenser saturation
temperatures. At nominal operating conditions, sub-cooling of 4C at the condenser outlet and superheating of 4C at the
evaporator exit take place.
a. Determine the pressure caused by the spring on the diaphragm.
b. If the evaporator cooling load increases by 10-percent, evaluate the pressure to be applied by the sensing bulb on
the diaphragm just at the beginning of this load change.
Solution:
a. At nominal operating conditions, the evaporator pressure is pev 2.52bar , and due to 4C of superheat, the sens-
ing bulb pressure is, pb 2.92bar , and the difference between these two pressures, psp pb pev 0.4bar , is
balanced by the spring.
b The nominal cooling load is qev h1 h4 248 100.25 147.75 kJ/kg . Just at the beginning of the load change,
h1' h4 1.1 147.75 162.5 kJ/kg and the enthalpy at the evaporator
the mass flow rate is the same, but qev
exit is h1' 262.7 kJ/kg . Then the temperature at the evaporator exit becomes T1' 12 C . The corresponding bulb
pressure is pb 4.42bar and the valve is pressed down for larger mass flow rate.
CHAPTER 9 REFRIGERATION SYSTEMS 419
If an evaporator coil is equipped with a refrigerant distributor, then a considerable pressure drop
will take place, and for such a case, as shown in Figure 9.22, expansion valves with external equal-
izer are used.
The advantage of an external equalizer is as following, let us consider the case in Example 9.10,
the pressure at the evaporator inlet is pev i 2.52bar . Due to refrigerant flow through distributor,
pressure drops by 0.67 bar, the pressure at the evaporator exit is pev e 1.85bar . Hence, the superheat
to be given by the evaporator becomes T 4 12 16 C and this, in turn, requires unnecessarily
large evaporator surface area. With the external equalizer, however, the evaporator pressure acting on
the diaphragm is the exit value. Since the pressure caused by the spring is 0.4 bar, then the balanced
pressure by the bulb becomes, pb 1.85 0.4 2.25 bar . This time, the amount of superheat require-
ment is much less than the case without external equalizer and becomes T 4 6.5 10.5 C .
When the sensing bulb is charged with the same refrigerant as used in the cycle, this type of charge
is called straight charge. Respect to refrigerant saturation curve, as in Figure 9.23a, for the same
value of p pb pev the amount of superheat caused would be different for different evaporator
temperatures. Since T2 T1 , compressor flooding at high evaporator temperatures is always pos-
sible. As shown in Figure 9.23b, this may be prevented by charging the bulb with refrigerant different
from the one used in the cycle. This is called cross charge.
420 THERMODYNAMICS
Capillary tubes. Because of their simplicity and low cost, capillary tubes are used as a throttling
device in small refrigeration systems with a capacity of 3 tons or less. The inside diameter is in
the range between 0.5mm and 2.0 mm and the length varies from 1.0 m to 6.0 meters. It is usually
made of copper. The pressure drop in a capillary tube takes place due to following two factors: 1.
The flow of refrigerant must overcome the frictional resistance, 2. As the refrigerant flows, the
pressure drops, and liquid refrigerant flushes into a mixture of liquid and vapor, and due to drop
in the average density, the refrigerant accelerates and causes additional pressure drop. Hence,
the compressor and the tube assume balanced conditions at the suction and at the discharge, so
that the compressor pumps the same amount as the capillary tube feeds the evaporator. Capillary
tubes are not capable responding to variations in suction pressure, discharge pressure or cooling
load. They are susceptible to clogging by impurities, and the refrigerant charge has to be held
within close limits due to possibility of compressor flooding. However, they are very simple,
contain no moving parts, and are inexpensive devices. During the off-cycle period, capillary
tube allows the high and low side pressures to equalize, and thereby the starting torque required
by the compressor is reduced. They are ideal for hermetic compressor based systems which are
critically charged and factory assembled.
If a capillary tube is to be used for a refrigeration system, the diameter and the length have to
be selected so that the compressor and the capillary tube achieve a balanced point at the desired
evaporator temperature. Both analytical and graphical methods are used in sizing the capillary
tubes. Usually a tube longer than the calculated value is installed, and by cut-and-try method, the
tube is shortened until the desired balanced point is achieved. In graphical procedure, the varia-
tion of the maximum mass flow rate through a capillary tube of 1.63 mm diameter and 2.03 m
length is given in Figure 9.24. The flow rate is at the maximum for the given conditions because
at the tube exit the chocked flow conditions occur.
CHAPTER 9 REFRIGERATION SYSTEMS 421
Figure 9.25 also provides the correction factor, φ, for different diameters and lengths. Hence the
mass flow rate at any diameter di and length L is determined by,
m m * (9.16)
In this equation, the mass flow rate m * of the standard tube size is first evaluated by Figure 9.24
for the same flow conditions.
Example 9.11 Consider a capillary tube operating between +36C condenser and -8C evaporator saturation temperatures
has to be selected to throttle 0.01kg/s of R22. At the tube inlet, the refrigerant is at 30C. If a copper tubing having 1.5mm
of diameter is selected, determine the tube length by graphical method.
Solution:
For R22, the condenser pressure is pcon 1389.7 kPa and the sub-cooling at the inlet of the tube is Tsc 36 30 6 C ,
then by Figure 9.24, the mass flow rate for standard tube becomes m * 0.01242 kg/s and the correction factor is
The most common type water cooled condenser is shell-and-tube type. As presented in Figure 9.26,
the hot gas from the compressor enters at the top inlet. To provide effective sub-cooling, water inlets
the copper tubes from the pipe near the bottom, and discharges near the top. In horizontal condens-
ers, to prevent gas bubbles to enter the liquid line, one-sixth of the shell volume is filled with liquid
refrigerant. Usually water cooled condensers are preferred over the air cooled condensers when there
is a long distance between the compressor and the heat rejection location. Conveying water rather
than refrigerant in long pipe lines is always less expensive and more secure.
Air is the external fluid for air cooled condensers. Figure 9.27 presents a typical forced convection
type air cooled condenser. If the working fluid is ammonia, the material of construction is aluminum
fins on stainless steel tubing, but aluminum fins on copper tubing is used for halocarbon refrigerants.
The diameters of copper tubes for air cooled condensers vary in the range from 6.5 mm to 19 mm.
Aluminum fins having fin spacing between 200 and 500 fins per meter enlarge the air side heat transfer
area 10 to 30 times of bare tube area. The number of tubes in the flow direction is called tube rows.
The air cooled condensers have 2 to 8 rows of tubes carrying the refrigerant.
Air cooled condensers are simple in construction. The fouling is small and the maintenance cost
is low. Table 9.2 compares the basic features of water and air cooled condensers.
CHAPTER 9 REFRIGERATION SYSTEMS 423
As shown in the table above, due to low density and specific heat of air, the volumetric flow rates
for the same cooling load is approximately thousand times larger for air cooled condensers. Therefore,
air cooled condensers cost 2 to 3 times more for the same heat rejection rate. However, water cooled
condenser usually require cooling tower for recycling the used water.
In thermodynamic analysis of condensers, Eq. (4.63) may be used in determining the heat load of
the condenser. Completion of a cycle requires that the condenser must reject both the energy absorbed
by the evaporator and the energy input of the compressor.
Because of the difficulty in determining the exact energy input of the compressor some manufac-
turers provide ratings in terms of evaporator load by defining a heat rejection factor as following,
Q con Q ev Wcomp 1
= 1 (9.18)
Qev
Qev COP
Figure 9.28 illustrates variation of the heat rejection factor with respect to condenser satura-
tion temperature at two different evaporator temperatures for refrigerants R134a, and R22. For
constant condenser temperature, reducing the evaporator temperature reduces the COP of the
system, and increases. Similarly, increasing the condenser temperature at constant evaporator
temperature will decrease COP and increase the heat rejection factor, . As illustrated in Figure
9.28, since the heat generated by the electric motor of a hermetic compressor is transferred to
the refrigerant, the heat rejection factor is always larger for a hermetic compressor than an open
type one.
The required surface area of a condenser is calculated by the fundamental equation of heat ex-
changers as,
=UAT
Q (9.19)
con m
where the overall heat transfer coefficient, U (W/m2K) based on outer surface area and for water
cooled condenser is calculated as following,
1 1 d 0 di ln d 0 / di d 0 1 d0
= R fi (9.20)
U 0 h0 di 2k w di hi di
For air cooled condensers, due to finned surface on the air side, the overall heat transfer coefficient
takes the following form,
1 1 A d ln d 0 / di A0 1 A0
= 0 i R fi (9.21)
U 0 0 h0 Ai 2k w Ai hi Ai
Af
o 1
A0
1
f (9.22)
CHAPTER 9 REFRIGERATION SYSTEMS 425
As shown in Figure 9.29, depending upon the geometry of the finned surface, the total external
area Ao is determined by,
d 02 4 s1 s2
Ao A f Ato n1n2
4 d0 d0
1 s f n1n2 d 0 1 ts f (9.23)
where sf represents the number of fins per meter. In addition, the total inside area of tubes per
unit length is
Ai n1n2 di (9.24)
The fin efficiency may be determined by transforming the plate fin to an annular fin by defining
an equivalent outer radius as r2 s1s2 / and r2c r2 t / 2 . Then Figure 9.30 yields the appropri-
ate value of ηf for the specific fin radius ratio of r2c/r1 of the exchanger.
In water cooled condensers, the coolant (water) flows through the tubes and depending upon the
flow structure, the one of following correlations has to be depicted for calculating the average heat
transfer coefficient of the tube side.
1. For Reynolds numbers, Re Vdi / , less than 2300, the flow is laminar, and the average heat
transfer coefficient for the combined entry length with constant wall temperature is proposed by
Seider and Tate as following,
426 THERMODYNAMICS
1/3 0.14
k d i b
hi 1.86 Pe (9.25)
di L w
where, Pe is the Peclet number and is defined as Pe Re Pr . Equation (9.25) is valid for
1/3 0.14
d
0.48<Pr<16700 , 0.004<b / w <9.75 , and recommended for Pe i b 2 . Below this
L w
limit, flow is fully developed and the heat transfer coefficient is calculated by hi 3.66(k / di ) .
2. If the flow is in transition region, 2300 < Re < 104, Gnielinski recommended the following correla-
tion for the average heat transfer coefficient.
Properties have to be evaluated at the average bulk temperature. The above relation predicts the
average heat transfer coefficient in the range 2300 < Re < 104, and 0.5 < Pr < 2000 with 10-percent
error.
3. For fully developed turbulent regime, Re > 104, Dittus-Boelter correlation is appropriate for deter-
mining the average heat transfer coefficient as,
k 0.8 0.4
hi 0.023 Re Pr (9.28)
di
0.25
k 3f f f g gh fg
h0 0.725 (9.29)
nd 0 f Ts Tw
where, n, indicates the average number of tubes per row, and to be determined by the tube
layout. The subscripts “f” and “g” are for saturated liquid and saturated vapor respectively. The
term Tm in equation (9.19) is logarithmic mean temperature difference (LMTD) and expressed
as,
Tm
Tcon Ti Tcon Te
(9.30)
T T
ln con i
Tcon Te
CHAPTER 9 REFRIGERATION SYSTEMS 427
As shown in Figure 9.31, referring to the temperature distribution of fluids in a typical condenser,
Eq. (9.30) should no longer be valid. Because of gaseous state, the heat transfer coefficient of the
de-superheating section is lower than the condensation coefficient, but the temperature difference is
higher. When multiplied, these two deviations compensate each other. As a conclusion, the use of Eq.
(9.30) provides satisfactory results.
It is good practice to consider the scale formation on the exchanger surface and its effect on the
overall heat transfer coefficient. Depending upon the operating conditions of the condenser, the fouling
values may be found in TEMA (Tabular Exchangers Manufacturer’s Association) standards.
Example 9.12 Consider R134a refrigeration plant having a capacity of 10tons and operates between -8C evaporator and
+40C condenser temperatures. A hermetic type compressor is used in the plant. The tube layout of the condenser is shown
in Figure 9.32, has two water passes and a total of 28 copper tubes with diameters of di/d0=14mm/16mm. Water enters the
condenser tubes at 25C and leaves 30C. Determine the tube length.
Solution:
Respect to the tube layout in Figure 9.32, the total number of rows is
28
11, and the number of tubes per row, n 2.54 . The tube wall
11
temperature at the exit approximately is 35C and at the inlet 33C. Then
the average wall temperature is 34C, and T Ts Tw 6 C . Together
with these values, substituting the properties of R134a at 40°C into Eq.
(9.29) results as,
0.25
(0.0747)3 1146.7 1096.7 9.81 163020
h0 0.725 1552.74
2.54 0.016 0.0001634 6
W/m2K Hermetic compressor working between temperatures of -8C
and +40C, Figure 9.28 yields the heat rejection factor as 1.35 and
the condenser capacity is Q con (10 3.516) 1.35 47.466 kW. Water
3
properties are taken at the average bulk temperature of 28C as c p 4.179 kJ/kgK, 996 kg/m , 0.00086 kg/ms ,
44.466
k 0.614 W/mK and Pr 5.85 . Then the mass flow rate of water becomes m w 2.271 kg/s and the water veloc-
4.179 5
m w 2.271 996 1.058 0.014
ity and the Reynolds number are V 1.058 m/s , Re 17150 104
wn p Ai 996 14 0.0001538 0.00086
428 THERMODYNAMICS
0.614
17150 5.85 4989.3 W/m2K. Thus, by Eq.
0.8 0.4
fully turbulent flow and Eq. (9.28) yields hi 0.023
0.014
1 1 16 0.014ln 16 / 14 16 1 16
(9.20), the overall heat transfer coefficient is, 0.000176
U 0 1552.74 14 2 390 14 4989.3 14
or U 0 928.62 W/m2K. Eq. (9.30) yields the logarithmic mean temperature difference as T 12.33K and Eq. (9.19)
m
47466
provides the heat transfer surface area as, A 4.146 m2. Since A nt d 0 L , then the tube length is
928.62 12.33
4.146
L 2.95 m .
3.14 0.016 28
In air cooled condensers, the coolant (air) flows over the finned tube bank and the correlation to
evaluate the average heat transfer coefficient of the finned surface is given by Kayansayan as fol-
lowing,
h0 0.15c p Gm Re 0.28 Pr 2/3 0.362 (9.31)
Properties have to be evaluated at the average bulk temperature of air. The above relation predicts
the average heat transfer coefficient in the range of 500 Re 3 104 , and 11.2 23.5 with 10-
percent deviation from the experimental data. In this expression, Gm is the maximum mass flux and
referring to Figure 9.29, the value of Gm, the Reynolds number, Re, and the exchanger fining factor,
ε, are calculated as following,
m air Gm d 0 Total finned surface area Ao
Gm , Re and (9.32)
Amin b outer tube surface area Ato
As described in Figure 9.33, initially the condensate forms an annular film around the tube pe-
riphery while vapor flows in the core region. This flow regime is called annular flow regime, zone
1 in Figure 9.33. As condensation proceeds the condensate begins to accumulate at the bottom of the
tube, and at low flow rates, the condensate flows along the bottom portion with vapor above, strati-
fied flow, zone 2 in Figure 9.33. At high flow rates, flow changes to slug flow, zone 3, finally vapor
pockets flow as bubbles in the flow direction which is called bubbly flow, zone 4. In refrigeration
CHAPTER 9 REFRIGERATION SYSTEMS 429
condensers, if the gas Reynolds number, Rev 4m / di g 35000 , then the flow regime zone 2 will
be dominant in the condensation process. Thus Chaddock and Chato’s correlation gives the average
heat transfer coefficient over length of the tube as following,
0.25
k 3f f f g gh*fg
hi 0.555 (9.33)
di f T
h*fg h fg 3 / 8 c p , f T (9.34)
In both relations, T Tcon Tw , represents the difference between the condensation temperature
and the surface temperature.
Example 9.13 Reconsider the R134a refrigeration plant in Example 9.12, air cooled condenser is to be designed for
the same load and the same operating conditions. The condenser is plate fin-and-tube type with the following geometric
parameters: s1 40 mm , s2 35 mm , t 0.2 mm , s f 312 m-1, 15.81 , di / d 0 14 / 16 . The number of tubes per
row is, n1 100 , and the number of rows is, n2 4 . Air flowing on the finned surface side inlets at 25C and exits at 30C.
Determine the length of the condenser.
Solution:
Respect to the tube layout in Figure 9.34, H n1s1 100 40 4000 mm.
Q ev 35.16
m r 0.255 kg/s and through
Refrigerant mass flow rate, h1 h3 393.87 256.41
0.255
a single tube, m r1 0.00255 kg/s. The vapor Reynolds number is,
100
4m 1 4 0.00255
Rev 18488 35000 , and Chato’s correlation
di v 3.14 0.014 12.55 106
0.25
0.07433 1146.7 1096.7 9.81 166390.5
yields, hi 0.555 1553.23 Figure 9.34 Finned tube
0.014 0.0001634 6
geometric parameters
Q con 47.466
W/m2K. In addition, the air side mass flow rate is, m a 9.436
c pa Te Ti 1.006 5
kg/s, the minimum flow area, Amin 100 40 16 1 0.2 0.312 103 2.248 m2/m, and the air side Reynolds
Gm d 0 4.196 0.016
number becomes Re 3668.6 . Apply Eq. (9.31) for h0 as,
18.3 106
0.28 0.67 0.362
h0 0.15 1006 4.196 3668.6 0.707 15.81 29.5 W/m2K.
47446 193.75
Tm 12.33K . Eq. (9.19) yields Ao 193.75 m2, then the exchanger length is L 0.65 m.
19.86 12.33 297.7
Calculations are to be repeated for the new tube length L=0.65 m. However the overall effect on heat transfer surface area
might be negligible.
These evaporators consist of coils placed in a number of rows with various fin arrangements to
increase the heat transfer area. Plate fins accommodating tube rows are used in halocarbon based
refrigerants. However, in ammonia applications, steel tubes with spiral fins are usually used.
Liquid cooling evaporators may be direct expansion type or flooded type. In Figure 9.35b,
shell-and tube type flooded evaporator contains liquid refrigerant on the shell side. As the refrigerant
evaporates from the top, the float allows liquid refrigerant inlet the evaporator.
CHAPTER 9 REFRIGERATION SYSTEMS 431
The type of evaporator as illustrated in Figure 9.36 is used in household refrigerators and is called
roll-bond type or bonded plate evaporators. In construction, two aluminum sheets are embossed in
such a manner that when they are welded the embossed section makes a channel for refrigerant flow
through the entire plate.
The thermal design of evaporators is much more difficult than the design of a condenser. The
complexity arises from the following facts: 1. Pressure drop in evaporators is much more critical and
significantly affects the overall heat transfer coefficient. To reduce the pressure drop effects, multiple
circuits have to be used in large systems. 2. Depending upon operating conditions, the air side surface
of an air cooling evaporator may partly become wet. Therefore the effect of mass transfer on evapora-
tor heat transfer has to be considered. In case of frost formation on the surface, the thermal resistance
of the evaporator will increase respect to time. 3. In case of refrigerant flowing through the tubes,
due to rapid change of flow regime from inlet to outlet, the heat transfer coefficient will be altered
accordingly. An accurate estimate of boiling side heat transfer coefficient becomes a very hard task.
Because of these difficulties, a brief explanation will be given for shell-and-tube type liquid cooling
evaporators with the refrigerant boiling on the shell side. In addition, for air cooling evaporators, flow
boiling inside the tube will be studied.
Since the heat transfer coefficients in nucleate pool boiling regime are stable and high in magnitude,
flooded evaporators usually operate in this regime. Rohsenow presented the following correlation for
the heat flux of liquid boiling in nucleate pool boiling regime.
0.5 3
g f g c pf T
q h fg f (9.35)
Csf h fg Pr n
where, the coefficient Csf and the exponent n depend on the surface-liquid combinations and is
Csf 0.013 , n 1.7 for halocarbon-copper combination. T is the temperature difference between
the surface and the fluid, and all fluid properties are evaluated at the saturation temperature. As can
2
be noticed by Eq. (9.35), q h fg , and knowing that h fg decreases with the increase in pressure,
the heat transfer coefficient will increase as the refrigerant pressurized.
In air cooling evaporators, forced convection boiling takes place inside the tubes, and the flow
regimes of such a boiling process is explained in Figure 9.37. Since the wall temperature exceeds the
saturation temperature of the liquid, the vaporization starts as in the sub-cooled flow boiling regime.
As the fluid further flows in the downstream direction, the vapor quality, x, increases, and due to
density difference, the average velocity in the pipe also increases, and sequentially bubbly, slug, an-
nular and mist flow regimes take place.
432 THERMODYNAMICS
For saturated flow boiling region in smooth tubes, the following correlation has been developed
by Kandlikar,
f
0.45
q
0.7
h
1.136
g
x 0.72
1 x 0.08
f Fr 667.2 ev
Gh fg
1 x 0.8 Gsf (9.36)
hl
m R Q
Where, G , is the mass flow rate of refrigerant per unit cross sectional area, and qev ev , is
Ac A0
the heat flux on the outer surface of the evaporator. In addition, Fr, is the liquid phase Froude number,
/ gd . The coefficient G
2
and is defined as Fr G / f i sf
is a function of surface-liquid combina-
tion, and is 1.63 for R134a, 1.1 for R22, and 1.0 for ammonia (R717) with stainless steel tubing. The
stratification parameter, f(Fr), is unity for vertical tubes and for horizontal tubes with Fr 0.04 . If
Fr 0.04 for horizontal tubes, then f becomes f Fr 2.63Fr 0.3 . Eq. (9.36) is applicable only if
the average vapor quality is in the following range, 0 x 0.8 , and all properties of the refrigerant
has to be evaluated at the saturation temperature. The liquid phase heat transfer coefficient, hl , in Eq.
(9.36) has to be evaluated for turbulent regime and the flow conditions should satisfy the turbulent
flow conditions in tubes.
Example 9.14 Reconsider the R134a refrigeration plant of Example 9.12, air cooling evaporator is to be designed for the
same load and the same operating conditions. The evaporator is plate fin-and-tube type with the following geometric pa-
rameters: s1 40mm , s2 35mm , t 0.2mm , s f 312 1/m, 15.81 , di / d 0 14 / 16 , the number of tubes per row,
n1 25 , and the number of rows, n2 4 . As shown in Figure 9.38, the refrigerant flowing through the expansion valve is
distributed into four circuits. Hence each row consisting of 25 tubes makes one circuit. Air flowing on the finned surface
side inlets at +5C and exits at 0C. Find the length of the evaporator.
Solution:
m R 0.255
The mass flux of the refrigerant, G 416.33 kg/m 2s, the Froude number of the refrigerant,
n2 Ai 4 0.000153
/ gdi 416.33 / 1146.7 2 / 9.81 0.014 0.959 and f ( Fr ) 1.0 . The exchanger length is assumed
2
Fr G / f
to be L=1m, then At 0 n1n 2 d 0 1 ts f 4.71 m /m and A 0 = At 0 74.47 m /m and the heat flux at the surface,
2 2
CHAPTER 9 REFRIGERATION SYSTEMS 433
same geometry and the same materials of Example 9.13, therefore, f 0.856 , 0 0.865 and assuming clean air side surface,
1 C
C1 2 (9.37)
U0 hi
Assuming fully turbulent flow through condenser tubes, Eq. (9.28) may be reduced to hi C3Vi 0.8 .
Substituting this result into (9.37) and rearranging yields,
1 C4
C1 0.8 (9.38)
U0 Vi
434 THERMODYNAMICS
1 d 0 di ln d 0 / di d 0
where, C1 R fi (9.39)
h0 di 2k w di
In Figure 9.39, as Vi assumes very large values, 1 / Vi 0.8 approaches zero, and the y-intercept
represents the experimental value of C1 which is also expressed by Eq. (9.39). For a new condenser,
however, Rfi=0, and the tube thermal resistance can be estimated, then for known C1 Eq. (9.39) yields
the condensation side heat transfer coefficient h0.
Example 9.15 A heat exchanger manufacturer measures the following data on a shell-and-tube ammonia condenser.
Water flows inside of steel tubes having 46 mm inside and 50 mm outside diameter and the tube thermal conductivity
is 55 W/mK. Determine,
a. the heat transfer coefficient of the condensing side,
b. the overall heat transfer coefficient for water velocity of 0.35 m/s.
Solution:
a. Since the overall heat transfer coefficient is expressed by Eq. (9.38), the constants of the equation may be evalu-
1 C4 1 C4
ated by the given data as, C1 0.8 and C1 . Solving for the constants, C1 1.423 104
2099 1 1381 0.50.8
and C4 3.34 104 . Considering that C1 is evaluated for a new condenser with R fi 0 in Eq. (9.39), and
1 50 0.046 ln 50 / 46
1.423 104 or h0 9578.6 W/m2K.
h0 46 2 55
1 3.34 104
b. Substituting C1 and C2 values into Eq. (9.38), 1.423 104 , then U o 1092 W/m2K
U0 0.350.8
9.4.6 Refrigerants
As explained by the classification chart in Figure 9.40, the refrigerants used for refrigeration
processes are classified into 1. Primary refrigerants, and 2. Secondary refrigerants.
CHAPTER 9 REFRIGERATION SYSTEMS 435
Secondary refrigerants are antifreezes or brines which are liquids used for absorbing heat from
the cold space and rejecting it to the refrigeration system at the evaporator. Secondary refrigerants do
not change phase but transports cold energy from low temperature medium. For carrying cold energy
in the temperature range of -10C to -30C, commonly used secondary refrigerants are brines and are
essentially water solutions of ethylene glycol, propylene glycol, or calcium chloride.
Primary refrigerants are used as working fluid in vapor compression cycle, and are in the form
of either compounds or mixtures. The refrigerants in the form of compounds can be either natural
compounds or synthetic compounds. Organic compounds like hydrocarbons (CH4, C2H6, C3H8, etc.)
and inorganic compounds like (Ammonia NH3, Carbon-dioxide CO2, Sulfur-dioxide SO2, and water
H2O) are called natural compounds. The natural compounds have been used since the early ages of
refrigeration. A revolution in refrigeration technology came about with the invention of synthetic com-
pounds in early 1930s. Synthetic compounds are chemical combination of carbon, hydrogen, chlorine,
and fluorine and in general format expressed by the following chemical formula, Cm H n Fp Clq and
commonly indicated as CFCs, HCFCs, or HFCs. Refrigerants in the form of mixtures can be either
Azeotropic or Zeotropic. Azeotropi mixture has two components, and cannot be separated into its
constituents by evaporation or condensation. An azeotropic mixture offers different properties from
its constituents. Similarly, zeotropic mixtures contain three different components.
As indicated in classification chart, a large number of refrigerants are developed over the years for
a wide variety of applications. To distinguish one refrigerant from the other, a numbering system is
adopted by ASHRAE, and all refrigerants are designated by letter R followed by a unique number.
In developing the numbering system for synthetic and for organic refrigerants, the chemical for-
mula is taken into consideration, and for general molecular formula of Cm H n Fp Clq the refrigeration
number is designated as following,
(9.40)
436 THERMODYNAMICS
Example 9.16 Determine the refrigeration numbers of the following compounds: a. CHClF2, b. C2H2F4, and c. Propane,
CH3CH2CH3.
Solution:
a. For CHClF2, X 1 1 0 , Y 1 1 2 , and Z 2 . If X is zero, it is indicated in the numbering system and the
refrigerant is R22.
b. For C2H2F4, X 2 1 1 , Y 2 1 3 , and Z 4 . The refrigerant is R134a where “a” stands for an isomer of
the same chemical composition.
c. For propane, CH3CH2CH3, X 3 1 2 , Y 8 1 9 , and Z 0 . Propane is indicated by R290 as a refrigerant.
The designation of inorganic refrigerants starts with number 7 and the numbers following 7 repre-
sent its molecular weight. For instance, Ammonia, molecular weight is 17, it is an inorganic refrigerant
and the refrigeration number is R717. Similarly, CO2, molecular weight is 44, and the refrigeration
number is R744. Azeotropic refrigerants are designated by 500 series like R502, which is a mixture
of 48.8% R22 and 51.2% R115. R502 offers better advantages than R22, especially behaves better
with oil. Zeotropic mixtures (non-azeotrops) are 400 series refrigerants and contain three synthetic
compounds. For instance, R404A, is a mixture of 44%R125, 52% R143a, and 4% R134a. Especially
at low temperature applications, R404A exhibits low temperature discharge and avoids the need for
inter-stage cooling.
Refrigerant selection. In addition to the temperature application ranges; low temperature (-40C to
-25C), medium temperature (-25C to -5C), and high temperature (-5C to +10C), due to several
environmental issues like “ozone layer depletion” and “Global Warming Potential” and their relation
to refrigerants in use, the selection of an appropriate refrigerant for a particular application has become
a difficult task. In fact, once a refrigerant is selected, to replace it for some unavoidable reason is an
expensive procedure and may require several changes in the system design. Therefore, the following
constraints have to be considered in selecting a refrigerant: 1. Thermodynamic constraints, 2. Physical
property constraints, 3. Environmental and safety constraints, 4. Economic constraints.
1. Thermodynamic constraints: A refrigerant should have high latent heat of vaporization, high
density at the compressor inlet, and low condenser pressure to allow for light weight and small size
compressor construction. These thermodynamic requirements are somewhat contradictory. The rela-
tion between saturation pressure and temperature as given by Clasius-Clapeyron equation explains
this contradiction as following,
dp h fg
(9.41)
dT Tv fg
RT
Where, v fg vg v f , vg v f and vg . Substituting this result into Eq. (9.41) and integrat-
p
ing between evaporator and condenser pressures yields,
p h fg 1 1
ln con (9.42)
pev R Tev Tcon
At a particular evaporator and condenser temperature, this relation indicates that high value in hfg
cannot be obtainable without an increase in pressure ratio. Hence, these two contradicting properties
have to be balanced. Similarly, the critical values of the refrigerant must be outside of the working
range. In fact, high critical temperature yields higher COP, but the vapor pressure will be low and will
cause low volumetric capacity. Again these two contradicting facts must be balanced for a particular
application.
CHAPTER 9 REFRIGERATION SYSTEMS 437
2. Constraints on physical properties: Appreciable sub-cooling requires the specific heat of the liquid
phase to be small but the vapor phase specific heat should be large for small degree of super heat-
ing. In both phases, the thermal conductivity should be high for high heat transfer rates. In addition,
refrigerants should have smaller viscosity values for less frictional pressure drops.
3. Constraints related to environment and safety: Refrigerants should be non-corrosive, non-toxic,
and non-flammable. Depending upon a particular application, toxicity of a refrigerant might change.
For instance, some CFC and HCFC compounds are non-toxic when mixed with air. However, in
contact with a flame or a heating wire, they become very toxic. Hence, decision should be made on
a particular application basis. Respect to non-flammability of the refrigerants, ASHRAE divides the
refrigerants into six groups as, A1, A2, A3, B1, B2, and B3. In this grouping, A1 is the least hazardous
group and contains refrigerants like R22, R134a, R744, while B3 is the most hazardous and contains
refrigerants like R1140.
Refrigerants should be chemically stable as long as they are in the system, and also should be
miscible for the return of oil into the compressor. For instance, ammonia is not a miscible refrigerant,
and systems using ammonia should have oil separators. High dielectric strength especially is a must
for refrigerants used in hermetic compressors.
Ozone Depletion Potential (ODP) of a refrigerant basically exists due to presence of chlorine or
bromine in the molecular structure. Since ODP should be zero, refrigerants like CFCs and HCFCs
cannot be used under new regulations. In addition, a refrigerant should have low value of Global
Warming Potential (GWP). For instance, ODP=0 for R134a but GWP value is high and has to be
reconstructed under new regulations.
4. Economic constraints: Refrigerants should be inexpensive and easily available products.
by manipulating between four points of the system which are the compressor discharge, the compressor
outlet, the evaporator outlet, and the condenser inlet. Therefore, the valve is usually called as four-way
reversing valve. The functions of the indoors and the outdoors coils can be reversed by the activation
of the valve, and the condenser is changed to evaporator and the evaporator turns to condenser.
T-s and p-h representation of heat pump cycle is given in Figure 9.42, and with respect to Figure
9.42b, the coefficient of performance of the heating effect in a heat pump system is,
Q23
COPhp (9.43)
Wc
In accord with the type of heat source from which heat is absorbed by the refrigerant, the heat
pump systems are classified as following: 1. Air sourced heat pumps, 2. Water sourced heat pumps.
For air sourced heat pumps, surroundings air acts as a heat source from which heat extracted dur-
ing the heating, and as a heat sink to which heat is rejected during cooling. One of the fundamental
problems of these pumps is the formation of frost on the outdoor coil during the heating mode of
operation in cold weather. To melt the accumulated frost, the reverse cycle switches heating mode of
operation to cooling mode by which the outdoor coil changes from evaporator to condenser and the
hot gas flows through. After the frost melts, the heat pump switches back to the normal heating mode
again. This process is known as defrosting.
Water source heat pumps may be either ground water type, or surface water type or a combination
of these two. Ground water heat pumps use well water as a heat source during heating and as a heat
sink during cooling, and are suitable for low-rise residents or commercial buildings.
Experiment 1: Let us consider two vessels A and B connected with a pipe and a valve as shown in
Figure 9.44a, and initially the entire system is in equilibrium with surroundings. Vessel A contains
pure water and the corresponding vapor pressure at 35°C is 5.63 kPa, and lithium bromide solution
(LiBr) with 45-percent concentration is in vessel B at the same temperature. Referring to Section 7.6,
since LiBr is highly non-volatile, the pressure on the solution is the vapor pressure of water, and with
respect to Figure 7.31, the solution pressure is 2.4 kPa.
If we open the valve on the connecting pipe, due to pressure difference, water vapor will flow from
vessel A to B and absorbed by the solution in vessel B. The absorption process is exothermic. To keep
the solution temperature constant, however, the released heat of absorption ( Qa ) has to be transferred
to surroundings. Suppose also that by some means the concentration of solution in vessel B is kept
constant. Then, because of evaporation of water in vessel A, the pressure will be reduced to 2.4 kPa.
Coexistence of both liquid and vapor phases at 2.4 kPa in vessel A requires that the water temperature
should drop to 20.5°C which in turn causes a refrigeration effect of ( Qe ) on the surroundings.
Experiment 2: Let us consider the reverse process of experiment 1 as shown schematically in Figure
9.44b. Suppose that solution in vessel B absorbs enough water vapor, so that the pressure increases
to 5.63 kPa and the solution is diluted. Let us apply heat ( Qg ) to dilute LiBr solution in B for regen-
eration. Due to heat addition, water evaporates and flows into vessel A where it is condensed by heat
440 THERMODYNAMICS
rejection ( Qc ) into the surroundings. Transferring the amount of water absorbed during refrigeration
process to vessel A, the solution in vessel B returns to its initial concentration and system also restores
itself back to its initial conditions.
These two experiments described above explain the basic principles of absorption refrigeration
system. To get continuous refrigeration effect, however, the system has to be modified as shown in
Figure 9.43. Essentially, together with a solution pump and an expansion valve, four basic components
of absorption refrigeration system are the generator and the condenser on the high pressure side, and
the absorber and the evaporator on the low pressure side.
Heat input to the generator is determined by the following energy balance on the generator,
Q g m 4 h4 m 6 h6 m 3 h3 (9.44)
CHAPTER 9 REFRIGERATION SYSTEMS 441
Besides, considering the concentrations at the inlet and exit of the generator, the mass flow rates
are related as following,
m 3 x3 m 4 x4 and m 6 m 3 m 4 (9.45)
Water vapor surrounding the condenser tubes condenses as heat is transferred to the cooling water
at the following rate,
Q c m 6 h6 h7 (9.46)
High pressure liquid water flows through an expansion device into the evaporator section of the
cycle. As an expansion device usually an orifice type restriction is used for maintaining the pressure
difference between the condenser and the evaporator.
Evaporator and absorber sections. Principally the evaporator and the absorber are contained inside
the same shell. Due to pressure drop at the expansion valve, water (refrigerant) evaporates and cools
down warm water returning from the chilled-water system. As shown in Figure 9.45b, evaporator
pump continuously circulates and sprays the refrigerant over the tubes for better heat transfer.
Referring to Figure 9.45b, at steady state working conditions, the mass balance on the evaporator
gives m 1 m 8 . In addition, the energy balance for the evaporator is,
Q e m 1h1 m 8 h8 (9.47)
The resulting refrigerant vapor (water vapor) in the evaporator is drawn into the low pressure
absorber where it is absorbed by LiBr-water solution. The released heat due to absorption is rejected
to the cooling water circulating through the absorber tubes. The absorber spray pump in Figure 9.45b
mixes the concentrated solution returning from the generator with dilute solution and delivers the
mixed solution to the absorber spray. In accord with equilibrium chart, the mixing process is a neces-
sity. If concentrated solution were sprayed directly on the absorber tubes, increase in temperature
would cause the solution to crystallize. To avoid this possibility, the concentration is reduced by
mixing with dilute solution.
With respect to Figure 9.45b, the mass balance around the absorber yields,
m 2 m 1 m 5 and m 2 x2 m 5 x5 (9.48)
Similarly the energy balance yields the heat rate to be withdrawn from the absorber as,
Q a m 1h1 m 5 h5 m 2 h2 (9.49)
Qe Qe
COP (9.50)
Qg W p Qg
The work input of the solution pump ( W p ) is usually negligible compared to the generator heat
input ( Q g ). Comparing the COP values of absorption refrigeration system and vapor compression
refrigeration system working at the same refrigeration and heat rejection conditions, the COP of
442 THERMODYNAMICS
absorption refrigeration system is lower than the COP of vapor compression refrigeration system.
However, comparing only the COP values of two systems is not justifiable. Because, high grade
mechanical energy is more expensive than low grade thermal energy and comparing exergetic effi-
ciencies instead would be more meaningful. Both systems provide exergetic efficiencies at the same
order of magnitude.
The complete system and the representation of the cycle on the equilibrium chart are shown in
Figure 9.46. The heat exchanger in the system transfers heat between the two streams of solutions. It
heats the dilute solution from the absorber and cools the strong solution returning from the generator
to the absorber. The heat exchanger helps the system to increase COP.
Example 9.17 As shown in Figure 9.46, consider a water-LiBr absorption refrigeration system with a cooling capacity of
100kW. Evaporator and condenser temperatures of the system respectively are 6°C and 45°C. Dilute LiBr solution leaves
the absorber at 35°C with 55% concentration. The mass flow rate delivered by the solution pump is 0.53kg/s. The solution
passes through the heat exchanger where it is heated to 65°C. In generator, the solution absorbs the heat from steam, the
refrigerant begins to boil and separate from the solution. At the generator exit, the solution is at 90°C with 60% concentra-
tion. The concentrated solution passes through the heat exchanger and is cooled to 55°C (state 7). Determine,
a. the ratio of mass flow rates of refrigerant (water) to solution, m 1 / m 2
e. the power consumed by the solution pump, and the COP of the system.
CHAPTER 9 REFRIGERATION SYSTEMS 443
Solution:
State no. Pressure (kPa) Temp.(°C) Enthalpy(kJ/kg) Mass flow rate( m kg/s) Concentration(x%)
2 0.934 35 83 0.53 55
3 9.66 35 83 0.53 55
5 9.66 90 212 - 60
7 9.66 - - - 60
a. The table above gives the properties of the solution at specified states. The energy balance for the evaporator yields,
100
Q e m 1 h1 h9 , and for 100 kW of evaporator capacity, m 1 0.043 kg/s. Hence, the ratio of
2512 188.45
mass flow rates is m 1 / m 2 0.043 / 0.53 0.081.
b. With respect to Figure 9.46a, mass conservation of LiBr requires that x3m3 x5m5 . Besides, the following rela-
tions for mass balance can be expressed as, m 3 m 5 m 8 and m 8 m 1 . Hence, the flow rate of strong solution at
the generator exit is m 5 0.53 0.043 0.487 kg/s.
c. The energy balance for the heat exchanger yields, m 3 h4 h3 m 5 h5 h7 and the enthalpy at state 7 is
quires that Q g m 5h5 m 8h8 m4 h4 , or Q g 0.487 x 212 0.043 x 2583.2 0.53 x145 137.47 kW. Similarly,
the energy balance for the condenser is Q c m 8 h8 h10 , or Q c 0.043 2853.2 188.45 114.58 kW.
e. The density of LiBr solution for concentration in the range ( 0.2 x 0.6 ) and for temperature range of
( 0o C T 200o C ) is expressed as, x 1145.36 470.84 x 1374.79 x 2 0.33 0.571x T 273 . At the solu-
tion pump inlet, x2 0.55 and T2 35o C , then the solution density is 1620 kg/m3. The pump is isentropic,
Example 9.18 a. Drive a relationship for maximum COP of a vapor absorption refrigeration system at which the genera-
tor, and the evaporator temperatures are Tg and Te respectively. The heat rejection at the absorber and the condenser takes
place at the same environmental temperature of To .
b. Determine COP max of the system in Example 9.17 by applying the findings in part (a) and compare with the
actual COP value.
444 THERMODYNAMICS
Solution:
In Figure 9.47, the vapor absorption system is represented as a combination of heat engine and a refrigerator. If we apply
first law of thermodynamics stated for cycles as,
Q W to this system, we end up with the following energy bal-
ance as,
Q e Q g Q a c W p
In accord with the second law, the total entropy change of the system and the environment has to be positive or zero at the
limit.
Since the system completes a cycle and works at steady state conditions, Ssys 0 , then the rate of entropy change of
environment becomes
Q Q g Q a c
So e 0
Te Tg To
Expressing Q a c with respect to Q g and Q e by using the energy equation and substituting into So expression yields,
Tg To T T
Q g Q e o e W p
Tg Te
Q e Te / To To
COP 1
Neglecting the pump work, COP of the system becomes, Q g 1 Te / To Tg
T T /T
For a reversible cycle then COP assumes the maximum value as COP max 1 o e o
Tg 1 Te / To
Heat Engine Refrigerator
A shown in Figure 9.47, a reversible absorption cycle can be considered to be a combined system of reversible heat
engine and a reversible refrigerator and the system COP becomes the product of engine efficiency and the refrigerator COP.
As can be deduced from COP max expression, the COP of the system increases as the generator ( Tg ) and evaporator ( Te )
temperatures increase and the surroundings temperature ( To ) decreases.
CHAPTER 9 REFRIGERATION SYSTEMS 445
b. In Example 9.17, the component temperatures are Tg 363K , Te 279 K , and To 300 K . At this condition,
300 279
79 / 300
the maximum value of COP is COP max 1 2.305 and is three times larger than the
363 1 279 / 300
actual COP .
9.6.3 Crystallization
The equilibrium chart (Figure 7.31) and the enthalpy chart (Figure 7.34) both contain crystalliza-
tion zone where LiBr salt solidifies and blocks the pipes and valves. When a hot and strong solution
is cooled to low temperatures in a heat exchanger, crystallization may take place. To avoid this to
happen, decrease in condenser pressure due to low cooling water temperature has to be prevented.
In industrial applications, the condenser pressure is maintained at certain level irrespective of the
cooling water temperature by the following methods: 1. Depending on the condenser pressure, the
cooling water flow rate is regulated. As the condenser pressure increases due to vapor accumulation,
the flow rate should be increased. To prevent the drop of condenser pressure below a certain value,
the flow rate should be lessened. 2. Additives are used for preventing the crystallization.
Keeping condenser pressure at certain level is against the performance of the system, but has to
be done for proper operation of the system.
446 THERMODYNAMICS
The two fluids mix at the mixing section, and enter the diffuser section where the pressure recov-
ery occurs. The mixed fluid flows to gas-liquid separator, and the liquid portion passes through the
expansion valve before entering the evaporator. The pressure of the remaining vapor is raised to the
condenser pressure by the compressor of the cycle. In comparison with conventional systems, the ejec-
tor provides the following advantages: 1. Ejector utilizes the energy of high pressure liquid otherwise
dissipated in the expansion valve, 2. Ejector works as a pump and reduces the compressor work.
Figure 9.49c shows the assembly of a simple thermoelectric refrigeration system. To reduce the
effect of thermal contact resistance, the module in the figure is installed through mechanical clamp-
ing, epoxy bonding, or solder bonding. Thermoelectric cooling is used in portable refrigerators, space
applications, micro-processors, cameras, laser devices. Thermoelectric devices are light in weight,
small, quite, and inexpensive, and may function in environments that are too severe, too sensitive,
and too small for other refrigeration methods.
As shown in Figure 9.51b, in producing continuous refrigeration effect, the element Gd, in pow-
dered form, is stuffed in pockets inside a ring shaped regenerator. The regenerator rotates and the
powdered (MCE) material is placed in and out of a gap where a powerful magnetic field exists. Hence,
a continuous refrigeration effect is created by consuming work for rotating the regenerator disc.
References
1. A.R. Trott, and T.C. Welch, Refrigeration and Air-Conditioning, 3rd edition, Butterworth-Heinemann, ISBN-0-7506-
4219-X, 2000.
2. S. Kakaç, A.E. Bergles, F. Mayinger, and H. Yüncü, Heat Transfer Enhancement of Heat Exchangers, Nato Scientific
Affairs Division, Kluwer Academic Publisher, ISBN 0-7923-5637-3, 1998.
3. S.K. Wang, Handbook of Air Conditioning and Refrigeration, 2nd edition, McGrawHill Publications, ISBN: 0-07-
068167-8, 2001
4. T. Kuppa, Heat Exchanger Design Handbook, Marcel Dekker Inc., ISBN: 0-8247-9787-6, 2000.
5. R. Miller, and M.R. Miller, Air Conditioning and Refrigeration, McGrawHill Publications, ISBN: 0-07-146788-2,
2006.
6. S.G. Kandlikar, and M.S.V.K. Dhir, Handbook of Phase Change: Boiling and Condensation, Taylor and Francis, ISBN:
1-56032-634-4, 1999.
7. P.K. Bansal, and A.S. Rupasinghe, An Empirical Model for Sizing Capillary Tubes, International Journal of Refrigera-
tion, Vol.19, no:8, pp. 497-505, 1996.
450 THERMODYNAMICS
Problems
9.8 A refrigeration unit, as in Example 9.2, includes a e. the rate of exergy destruction in the condenser
liquid-to-suction exchanger. The refrigerant vapor as a percentage of the power input.
from the evaporator is heated from -12°C to +4°C
with the liquid flowing from the condenser at 40°C.
Assume that the compressors have 82% of isentropic
efficiency for both cases indicated below. Evaluate,
a. the COP of the unit without the heat ex-
changer,
b. the COP of the unit with the heat exchanger,
c. the refrigeration capacity of the unit without the
heat exchanger for refrigerant flow rate of 20L/s
at the compressor inlet,
d. the power needed to run the compressor in (c).
e. With the same compressor power in (d), deter-
mine the refrigeration capacity of the unit with
the heat exchanger.
9.9 As shown in Figure 9.53, an ideal vapor-compression
refrigeration unit with ammonia as the working
fluid, the evaporator temperature is at -30°C, and
the condenser operates at 10bar pressure. The mass
flow rate of ammonia is 1.2 kg/min. Determine,
a. the refrigerating capacity in tons of refrigera-
tion,
b. the coefficient of performance of the unit.
c. Consider the case of keeping all conditions except
the condenser pressure of the cycle constant. The
condenser pressure is varied between 10bar and
20bar with 5bar increments. Calculate the varia-
tion of COP with respect to condenser pressure,
and graph the results in COP-p diagram.
9.12 Compare the refrigeration effect, the compressor work, and the exergetic efficiency for refrigerants R22 and R404A
for an ideal refrigeration unit having +5°C evaporator and 55°C condenser temperature. The thermodynamic proper-
ties of R404A are given in a table at the bottom of the page:
9.14 Consider the two-stage vapor-compression unit as illustrated in Figure 9.56, and assume that R134a is the working
fluid. The system produces 3200 tons of refrigeration with the evaporator, intercooler and the condenser operating at
pressures of 1bar, 6bar, and 20bar respectively. Additionally, the isentropic efficiencies of both compressors are 90%.
The thermodynamic properties of the refrigerant at various states of the cycle are provided by the table below,
State no. Location Pressure (bar) hf (kJ/kg) hg (kJ/kg) sf (kJ/kgK) s (kJ/kgK) Enthalpy
(kJ/kg)
1 Compressor inlet 1 - 231.35 - 0.939
2s Compressor exit 6 - - - 0.939
3,7 Flash chamber exit 6 79.48 259.19 0.29 0.909
4s Compressor exit 20 - 281 - 0.909
5 Condenser exit 20 150
Evaluate,
a. the mass flow rate of the refrigerant flowing through each compressor in kg/s,
b. the total power required to run the system in kW,
c. the COP of the system.
9.15 A two-stage and ideal vapor-compression refrigeration 9.17 Consider a two-stage refrigeration system that op-
unit as in Figure 9.56, operates with R134a, and the erates with -36oC evaporator and +60°C condenser
pressures of the evaporator, intercooler, and of the temperature. The cycle consists of two ideal vapor
condenser are 1.2bar, 7bar, and 24bar respectively. compression cycles connected by a heat exchanger
If the refrigeration load is estimated to be 10 tons, that serves as the condenser for the low pressure
calculate, cycle and the evaporator for the high pressure. The
a. the ratio of mass flow rates, r m 3 / m 1 , evaporating and the condensing temperatures of
b. the COP of the system, both fluids in the exchanger are 0°C. Assume that
c. the heat removal rate at the condenser. R22 is the working fluid for the two cycles, and the
heat capacity of low pressure evaporator is 55 tons
9.16 A frozen food manufacturer needs 25tons of refrigera- of refrigeration.
tion for storing frozen food at -18°C of evaporator a. Evaluate the power required and the COP for a
temperature. As shown in Figure 9.57, the same single stage system having the same evapora-
refrigeration system is also used for air conditioning tor and condenser conditions of the cascade
of the office buildings with another evaporator operat- system.
ing at +5oC with a capacity of 8tons. The condenser b. Calculate the mass ratio of the two refrigerant
operates at 60oC, and the isentropic efficiency of the flows.
compressor is 80%. The refrigerant of the cycle is
c. Determine and compare the total power input,
R22. Including the saturation curve, graph the h-p
and the COP values of the cascade system with
diagram of the system and determine,
the corresponding values for the single stage
a. the enthalpy of the refrigerant at state 1, system.
b. the power of the compressor,
c. the mass flow rate of condenser cooling water,
if the water temperature rise is 10°C, 9.18 A vapor compression refrigeration system with
d. the COP of the system. a cooling capacity of 100 kW uses three-stage
compression with intercooling, and R134a is the
working fluid. As shown in Figure 9.58, the system
is equipped with two intercoolers and two mixing
chambers, and all the compressors of the system
are isentropic. Assume that the refrigerant is satu-
rated liquid at the inlet of each expansion valve,
and is saturated vapor at the evaporator outlet. The
thermodynamic properties of refrigerant at various
states are given by the table above.
Determine,
a. the mass flow ratios y13 m 13 / m 10 , and
y14 m 14 / m 8 supplied to mixing chambers,
b. the mass flow rates for each compressor,
Figure 9.57 A two-evaporator c. enthalpy and entropy values of the refrigerant
at the mixing chamber outlet (states 3 and 5),
refrigeration system
d. power supplied to each compressor in kW,
454 THERMODYNAMICS
9.19 A new commercial refrigerator-freezer combina- effect, graph the h-p diagram of the system, and
tion unit is designed as a dual evaporator system. determine,
The freezer compartment is to be at -32°C and the a. the total power required by the cascade sys-
refrigerator compartment is at +4°C. The system tem,
uses R134a which is saturated liquid at 40°C at the b. the COP of the cascade system.
condenser outlet. The cooling capacity of both the
refrigerator and the freezer is the same and is 0.5kW c. Suppose that the cascade system is replaced with
for each. The compressor isentropic efficiency is a single stage ammonia system operating at the
87%. Draw the system schematically, and show the same evaporator and condenser temperatures as
cycle on h-p diagram. Determine, given above, determine the power required by
this new system,
a. the required mass flow rate through each evapo-
rator, and the compressor. d. evaluate the COP value of this single stage am-
b. the enthalpy of the refrigerant at the compressor monia system and compare with the COP of the
inlet, cascade system.
c. the power to be supplied to the compressor,
d. the coefficient of performance of this design.
9.24 Analyze the effect of condenser temperature on the condenser pressure at 12bar. The refrigeration load
COP of the refrigeration cycle if the following recip- of the chiller is 50 tons. Assume that the compressor
rocating compressor with R22 refrigerant is used for with an isentropic efficiency of 80% operates at a
the system (the polytropic exponent, n 1.13 ). The speed of 3000rpm. Determine the impeller wheel
compressor characteristics are: d 50mm , H 40mm diameter for the following refrigerants:
, 0.035 , Vleak / Vst 0.06 , n 1000rpm , and a. R134a
the number of cylinders is, z 4 . The evaporator b. Ammonia.
temperature is kept constant at -18°C and the condenser c. Comparing diameters, and the tip speeds, decide
temperature varies in the range between +32°C and which refrigerant is more appropriate for the
+56°C with 8°C of temperature increments. given system.
d. Calculate the impeller width at the compressor
9.25 A single cylinder reciprocating compressor is to exit for the selected refrigerant.
be designed for a domestic refrigerator with 100W
9.28 A method for reducing the impeller diameter to rea-
of cooling capacity. The refrigerator operates at
sonable limits in refrigeration systems is to increase
evaporator temperature of -18°C and the condens-
the number of stages. As shown in Figure 9.64, the
ing temperature is +56°C, and R134a is used as the
compression might be isentropic and executed in
refrigerant of the system (the polytropic exponent,
three stages with 3600rpm rotational speed. Am-
n 1.15 ). The compressor characteristics are as monia is compressed from saturated vapor at 2 bar
follows: 0.045 , Vleak / Vst 0.04 , and the to condenser pressure at 8 bar. The refrigeration load
rotational speed is n 2900rpm . Assume that the of the chiller is 50 tons. If the all impeller wheels
bore and the stroke are identical, and determine, are at the same diameter, determine,
a. the cylinder diameter,
a. the wheel diameter,
b. the compressor power input,
b. the impeller width for 1 m/s velocity at each
c. the refrigerant temperature at the compressor
impeller exit.
exit,
d. the COP of the system.
Figure 9.68 Tube layout for four-pass water 9.42 Provide the refrigerant R number of the following
cooled condenser fluids:
a. CClF3, b. CHF3, c. CO2,
d. H2O, e. CH2ClF.
9.39 A direct-expansion and fin-and-tube type evaporator
has the following properties: 1. Refrigerant side: sur-
9.43 Determine the chemical formula of the following
face area, Ai 20 m 2 , and heat transfer coefficient, refrigerants and specify whether the refrigerant is a
hi 1100 W/m 2 K , 2. Air side: the bare tube surface halogenates or inorganic compound. If it is a mix-
area, Ato 18.5 m 2 , and the total area of the finned ture, specify whether it is azeotropic or zeotropic
mixture:
surface, Ao 180 m 2 and the heat transfer coefficient,
a. R290, b. R11, c. R744,
ho 50 W/m 2 K . Air inlets the evaporator at 20°C
and exits at 12°C. The evaporator operates at a d. R502, e. R404A f. R600
CHAPTER 9 REFRIGERATION SYSTEMS 459
Heat pumps
9.47 Using the performance curves shown in Figure 9.71 c. If the house requires 2100 kW-h of seasonal
develop linear equations for a heat pump with 3.8 heating, determine the energy saving by using
tons of refrigeration capacity to predict the following domestic water instead of air as a heat source.
parameters:
a. the cooling capacity Q r (kJ/h) as a function of Vapor absorption refrigeration (VAR)
outdoor air temperature, To (°C), 9.49 The operating temperatures of a vapor absorption
b. the power input Wr (kW) as a function of outdoor refrigeration system are as follows: 1. Condenser:
air temperature To (°C), 85°C, 2. Absorber: 42°C, 3. Evaporator: 5°C. The
refrigeration capacity of the system is 33 tons, and
c. the cooling COP as a function of outdoor air the heat input to the system is 180 kW. The work
temperature To (°C). consumed by the solution pump is neglected.
d. It is known that placing the outdoor condensing a. Determine the system COP and the heat rejected
unit in the shade could improve the cooling COP at the condenser.
of the system. Assume that the average outdoor b. An engineer claims that by design improvement
temperature during air conditioning season is in components of the system, the heat input to
35°C in the sun and 30°C in the shade. If a house the system may be reduced to 150 kW for the
requires 15 106 kJ/year of cooling, and elec- same operating conditions and the refrigeration
tricity costs $0.10/kW-h, calculate the savings load. Is this true?
from locating the condenser in the shade.
9.50 Consider an ideal vapor absorption refrigeration
9.48 An engineer suggests the use of domestic water system that receives heat from a solar collector at a
instead of outside air as a heat source for heat pump temperature of 65°C, performs refrigeration at 10°C,
heating of a house. Domestic water enters the house and rejects heat to surroundings at 37°C. Determine
at a higher temperature than the outside air by which the COP of this system.
the performance of the heat pump may be increased.
As shown in Figure 9.72, the pump withdraws Q w 9.51 For the LiBr-H2O absorption system as in Figure 9.73,
from the inlet water at Tw 20o C and decreases its the solution temperature leaving the heat exchanger
and entering the generator is 45°C. The operating
temperature to surroundings temperature, To 4o C .
temperatures of absorber and the generator respectively
The house with UA 65 W/K is maintained at
are 30°C and 105°C. Moreover, the evaporator and
Ti 20o C , and the heat pump with R22 as the work- the condenser operate respectively at temperatures
ing fluid supplies the necessary heat, and operates 5°C and 35°C. The flow rate of the solution pump
o
between Tsource 8 C of evaporating and + 30o C of is 0.4 kg/s. Sketch the system schematically, and
condensing temperatures. If the isentropic efficiency clearly indicate the location of the regenerative heat
of the compressor is 82%, determine, exchanger, and determine,
9.52 A Diesel engine develops 400 kW of power with 9.53 Consider a single effect
a thermal efficiency of 36-percent. Almost all of LiBr-H2O absorption re-
the heat rejected by the engine is transferred to the frigeration system as in
generator of an absorption refrigeration system with Figure 9.46. The concen-
COP = 0.82. trated solution from the
a. Derive a relation for the evaporator capacity in o
generator at T5 100 C ,
terms of the engine efficiency, the engine power x5 0.65 enters the ex-
output, and the COP of the system. changer of Figure 9.74 and
b. Determine the evaporator capacity of the refrig- heats up the solution from
eration system in tons for the above indicated
the absorber at T3 30o C
diesel engine.
, x3 0.5 . The mass flow
rate of the dilute solution is m 3 0.5 kg/s . Determine
the maximum temperature of the solution at the
generator inlet so that crystallization starts in the
system.
9.54 As shown in Figure 9.75, a single effect vapor absorption refrigeration system with LiBr-H2O solution operates at
+4°C of evaporating and 40°C of condensing temperature. The thermodynamic properties of the solution along the
cycle and the mass flow rates are provided by the table below. The refrigerant is assumed to be at saturated vapor
state at the evaporator exit, and at saturated liquid state at the condenser outlet. Determine,
a. the refrigeration capacity in tons,
b. the heat capacity rates of the condenser, the generator, and the absorber,
c. the heat capacity rate and the effectiveness of the solution heat exchanger,
d. the power required by the solution pump,
e. the COP of the system.
State no. Pressure (kPa) Temp.(°C) Enthalpy (kJ/kg) Mass flow rate(kg/s) Concentration(x%)
1 0.81 33 85.8 0.05 57
2 7.35 33 85.8 0.05 57
3 7.35 63 147 0.05 57
4 7.35 90 0.045
5 7.35 0.045
6 0.81 - - 0.045
7 7.35 77 2645 0.005 0.0
8 7.35 40 167.5 0.005 0.0
9 0.81 167.5 0.005 0.0
10 0.81 4 2508.7 0.005 0.0
Check Test 9
Choose the correct answer:
1. A vapor-compression refrigeration unit uses R22 and works between temperature limits of -18°C, and 27°C. The
isentropic efficiency of the compressor is 79%, and states of R22 in the cycle are given by the following table:
For a refrigerant mass flow rate of 5.0kg/min, the cooling capacity of the unit in kW, the actual temperature of
refrigerant at the compressor exit in oC are respectively given as,
a. 13.42, 68, b. 13.42, 58, c. 10.42, 68, d. 11.42, 64.
2. If the surroundings temperature is at 300K, the 3. Ammonia enters the compressor of an actual refrigera-
actual coefficient of performance (COP), and the tor at 150kPa, -20°C at a rate of 0.06kg/s and leaves
exergetic efficiency of the above refrigeration unit at 10bar. The isentropic efficiency of the compressor
are accordingly determined to be, is 85%, and the refrigerant is cooled in the condenser
a. 3.4, 0.75, b. 3.0, 0.70, to 24°C. The power input in kW, and the cooling load
c. 3.4, 0.65, d. 3.4, 0.6. of the system in tons are respectively expressed as,
a. 29.9, 19.3, b. 9.9, 25,
c. 19.9, 19.3, d. 19.9, 9.9.
4. As shown in Figure 9.76, a cascade refrigeration system without a regenerative heat exchanger at the evaporator
outlet with R22 in both loops is used to produce 40 tons of refrigeration with -40°C of evaporating and +36°C of
condensing temperatures. The refrigerant, in loop B, evaporates at -12°C, and in loop A, condenses at -4°C. The
isentropic efficiencies of both compressors are identical and equal to 80%. Considering the data given by the table
above, the mass flow rates of refrigerants in loops A and B respectively are,
a. 0.73, 1.31, b. 0.63, 1.41, c. 0.63, 1.11, d. 0.73, 1.11.
State no. Location Pressure (bar) Temp.(°C) Quality(%) Entropy(kJ/kgK) Enthalpy(kJ/kg)
Loop A
1 Compressor inlet 1.052 -40 1.0 1.0005 233.27
2s Compressor exit 4.36 - - 1.0005
3 Condenser exit -4 0.0 0.16 40.46
4 Evaporator inlet 1.052 - - - 40.46
Loop B
5 Compressor inlet 3.3 -12 1.0 0.9457 245.36
6s Compressor exit 13.89 - - 0.9457
7 Condenser exit 36 0.0 0.326 89.29
8 Evaporator inlet 3.3 - - - 89.29
464 THERMODYNAMICS
5. Show that the pressure ratios of both compressors 9. When a refrigeration system with R134a operates
are approximately the same for the above cascade at 40oC of condensing and +4°C of evaporating
system, and the total power needed by the system temperature, the pressure difference across the
in kW is, thermostatic expansion valve is 600kPa, and the
system produces 15kW of refrigeration. For pressure
a. 90, b. 95, difference of 400kPa, the refrigeration capacity in
c. 72, d. 83. kW becomes,
a. 5.0, b. 10.0
c. 15.0, d. 20.0
6. A vapor-compression chiller operates with a recip-
rocating compressor between +36oC condensing,
and -12oC of evaporating temperatures and uses 10. A refrigeration system with R134a operating between
40°C of condensing and +4°C of evaporating tem-
R134a refrigerant. The compressor has a volumetric
peratures provides 22kW of refrigeration and uses a
efficiency of 70%, and operates at 1450 rpm with a compressor with isentropic efficiency of 85%. Heat
displacement volume of 1600cm3. The refrigerant is rejected to a water cooled condenser with overall
leakage during the compression is counted as 3% of heat transfer coefficient 200W/m2K. Water at a flow
the stroke volume. The refrigeration capacity of the rate of 0.6kg/s inlets the condenser at 27°C. The
system in kW is, required surface area for the condenser in m2 is,
a. 29, b. 34, a. 13, b. 18
c. 39, d. 32. c. 23, d. 28
8. A capillary tube is to be used for throttling 0.005kg/s 12. A single effect vapor absorption refrigeration system
of R22 from condensing pressure of 10bar to 2.5bar of with LiBr-H2O solution operates between 6oC of
evaporating pressure. The refrigerant enters the tube evaporating and 55°C of condensing temperatures.
as saturated liquid. For a tube diameter of 1.5mm, The temperature and the concentration of the solu-
the tube length in meters is, tion at the exit of both absorber and the generator
respectively are (45°C, 0.55), and (100°C, 0.65).
a. 3.0, b. 4.0 Neglecting the solution pump work, the COP of the
c. 5.0, d. 6.0 system is,
a. 0.88, b. 0.68
c. 0.78, d. 0.98
Appendices
Table Page
A1 Properties of saturated water, temperature
A2 Properties of saturated water, pressure
A3 Properties of superheated water vapor
A4 Properties of compressed liquid water
A5 Properties of Saturated (Solid–Vapor) Water, Temperature
A6 Properties of Saturated Refrigerant 22, Temperature
A7 Properties of Saturated Refrigerant 22, Pressure
A8 Properties of Superheated Refrigerant 22 Vapor
A9 Properties of Saturated (Liquid–Vapor) Carbon Dioxide, Temperature
A10 Properties of Saturated (Liquid–Vapor) Carbon Dioxide, Pressure
A11 Properties of Superheated Carbon Dioxide Vapor
A12 Properties of Saturated (Liquid–Vapor) Refrigerant 134a, Temperature
A13 Properties of Saturated (Liquid–Vapor) Refrigerant 134a, Pressure
A14 Properties of Superheated Refrigerant R134a Vapor
A15 Properties of Saturated (Liquid–Vapor) Ammonia, Temperature
A16 Properties of Saturated (Liquid–Vapor) Ammonia, Pressure
A17 Properties of Superheated Ammonia Vapor
A18 Properties of Saturated (Liquid–Vapor) Propane, Temperature
A19 Properties of Saturated (Liquid–Vapor) Propane, Pressure
A20 Properties of Superheated Propane Vapor
A21 Critical Properties of Selected Elements and Compounds
A22 Critical Properties of Selected Elements and Compounds
A23 Ideal Gas Specific Heats of Some Common Gases
A24 Ideal Gas Properties of Air
A25 Ideal Gas Properties of Carbon Dioxide
A26 Thermo-physical Properties of Air
A27 Thermophysical Properties of Water
Figure
A1 Generalized compressibility chart
A2 Generalized enthalpy correction chart
A3 Generalized entropy correction chart
A4 Psychrometric chart
A5 Equilibrium chart for (LiBr) solution
A6 Enthalpy-Concentration diagram for (LiBr) solution
Guidance
Answers to even numbered problems
True-False Tests
Check Tests
465
466 THERMODYNAMICS
75 0.3858 1.0259 4.131 313.9 2475.9 313.93 2321.4 2635.3 1.0155 7.6824 75
80 0.4739 1.0291 3.407 334.86 2482.2 334.91 2308.8 2643.7 1.0753 7.6122 80
85 0.5783 1.0325 2.828 355.84 2488.4 355.90 2296.0 2651.9 1.1343 7.5445 85
90 0.7014 1.0360 2.361 376.85 2494.5 376.92 2283.2 2660.1 1.1925 7.4791 90
95 0.8455 1.0397 1.982 397.88 2500.6 397.96 2270.2 2668.1 1.2500 7.4159 95
100 1.014 1.0435 1.673 418.94 2506.5 419.04 2257.0 2676.1 1.3069 7.3549 100
110 1.433 1.0516 1.210 461.14 2518.1 461.30 2230.2 2691.5 1.4185 7.2387 110
120 1.985 1.0603 0.8919 503.5 2529.3 503.71 2202.6 2706.3 1.5276 7.1296 120
130 2.701 1.0697 0.6685 546.02 2539.9 546.31 2174.2 2720.5 1.6344 7.0269 130
140 3.613 1.0797 0.5089 588.74 2550 589.13 2144.7 2733.9 1.7391 6.9299 140
150 4.758 1.0905 0.3928 631.68 2559.5 632.20 2114.3 2746.5 1.8418 6.8379 150
160 6.178 1.1020 0.3071 674.86 2568.4 675.55 2082.6 2758.1 1.9427 6.7502 160
170 7.917 1.1143 0.2428 718.33 2576.5 719.21 2049.5 2768.7 2.0419 6.6663 170
180 10.02 1.1274 0.1941 762.09 2583.7 763.22 2015.0 2778.2 2.1396 6.5857 180
190 12.54 1.1414 0.1565 806.19 2590 807.62 1978.8 2786.4 2.2359 6.5079 190
200 15.54 1.1565 0.1274 850.65 2595.3 852.45 1940.7 2793.2 2.3309 6.4323 200
210 19.06 1.1726 0.1044 895.53 2599.5 897.76 1900.7 2798.5 2.4248 6.3585 210
220 23.18 1.1900 0.08619 940.87 2602.4 943.62 1858.5 2802.1 2.5178 6.2861 220
230 27.95 1.2088 0.07158 986.74 2603.9 990.12 1813.8 2804.0 2.6099 6.2146 230
240 33.44 1.2291 0.05976 1033.2 2604 1037.3 1766.5 2803.8 2.7015 6.1437 240
250 39.73 1.2512 0.05013 1080.4 2602.4 1085.4 1716.2 2801.5 2.7927 6.0730 250
260 46.88 1.2755 0.04221 1128.4 2599 1134.4 1662.5 2796.6 2.8838 6.0019 260
270 54.99 1.3023 0.03564 1177.4 2593.7 1184.5 1605.2 2789.7 2.9751 5.9301 270
280 64.12 1.3321 0.03017 1227.5 2586.1 1236.0 1543.6 2779.6 3.0668 5.8571 280
290 74.36 1.3656 0.02557 1278.9 2576 1289.1 1477.1 2766.2 3.1594 5.7821 290
300 85.81 1.4036 0.02167 1332 2563 1344.0 1404.9 2749.0 3.2534 5.7045 300
320 112.7 1.4988 0.01549 1444.6 2525.5 1461.5 1238.6 2700.1 3.4480 5.5362 320
340 145.9 1.6379 0.01080 1570.3 2464.6 1594.2 1027.9 2622.0 3.6594 5.3357 340
360 186.5 1.8925 0.006945 1725.2 2351.5 1760.5 720.5 2481.0 3.9147 5.0526 360
374.1 220.9 3.155 0.003155 2029.6 2029.6 2099.3 0.0 2099.3 4.4298 4.4298 374.14
0.50 81.33 1.0300 3.240 340.44 2483.9 340.49 2305.4 2645.9 1.0910 7.5939 0.50
0.60 85.94 1.0331 2.732 359.79 2489.6 359.86 2293.6 2653.5 1.1453 7.5320 0.60
0.70 89.95 1.0360 2.365 376.63 2494.5 376.70 2283.3 2660 1.1919 7.4797 0.70
0.80 93.50 1.0380 2.087 391.58 2498.8 391.66 2274.1 2665.8 1.2329 7.4346 0.80
0.90 96.71 1.0410 1.869 405.06 2502.6 405.15 2265.7 2670.9 1.2695 7.3949 0.90
1.00 99.63 1.0432 1.694 417.36 2506.1 417.46 2258.0 2675.5 1.3026 7.3594 1.00
1.50 111.4 1.0528 1.159 466.94 2519.7 467.11 2226.5 2693.6 1.4336 7.2233 1.50
2.00 120.2 1.0605 0.8857 504.49 2529.5 504.70 2201.9 2706.7 1.5301 7.1271 2.00
2.50 127.4 1.0672 0.7187 535.10 2537.2 535.37 2181.5 2716.9 1.6072 7.0527 2.50
3.00 133.6 1.0732 0.6058 561.15 2543.6 561.47 2163.8 2725.3 1.6718 6.9919 3.00
3.50 138.9 1.0786 0.5243 583.95 2546.9 584.33 2148.1 2732.4 1.7275 6.9405 3.50
4.00 143.6 1.0836 0.4625 604.31 2553.6 604.74 2133.8 2738.6 1.7766 6.8959 4.00
4.50 147.9 1.0882 0.4140 622.25 2557.6 623.25 2120.7 2743.9 1.8207 6.8565 4.50
5.00 151.9 1.0926 0.3749 639.68 2561.2 640.23 2108.5 2748.7 1.8607 6.8212 5.00
6.00 158.9 1.1006 0.3157 669.90 2567.4 670.56 2086.3 2756.8 1.9312 6.7600 6.00
7.00 165.0 1.1080 0.2729 696.44 2572.5 697.22 2066.3 2763.5 1.9922 6.7080 7.00
8.00 170.4 1.1148 0.2404 720.22 2576.8 721.11 2048.0 2769.1 2.0462 6.6628 8.00
9.00 175.4 1.1212 0.2150 741.83 2580.5 742.83 2031.1 2773.9 2.0946 6.6226 9.00
10.0 179.9 1.1273 0.1944 761.68 2583.6 762.81 2015.3 2778.1 2.1387 6.5863 10.0
15.0 198.3 1.1539 0.1318 843.16 2594.5 844.84 1947.3 2792.2 2.3150 6.4448 15.0
20.0 212.4 1.1767 0.09963 906.44 2600.3 908.79 1890.7 2799.5 2.4474 6.3409 20.0
25.0 224.0 1.1973 0.07998 959.11 2603.1 962.11 1841.0 2803.1 2.5547 6.2575 25.0
30.0 233.9 1.2165 0.06668 1004.8 2604.1 1008.4 1795.7 2804.2 2.6457 6.1869 30.0
35.0 242.6 1.2347 0.05707 1045.4 2603.7 1049.8 1753.7 2803.4 2.7253 6.1253 35.0
40.0 250.4 1.2522 0.04978 1082.3 2602.3 1087.3 1714.1 2801.4 2.7964 6.0701 40.0
45.0 257.5 1.2692 0.04406 1116.2 2600.1 1121.9 1676.4 2798.3 2.8610 6.0199 45.0
50.0 264.0 1.2859 0.03944 1147.8 2597.1 1154.2 1640.1 2794.3 2.9202 5.9734 50.0
60.0 275.6 1.3187 0.03244 1205.4 2589.7 1213.4 1571.0 2784.3 3.0267 5.8892 60.0
70.0 285.9 1.3513 0.02737 1257.6 2580.5 1267.0 1505.1 2772.1 3.1211 5.8133 70.0
80.0 295.1 1.3842 0.02352 1305.6 2569.8 1316.6 1441.3 2758 3.2068 5.7432 80.0
90.0 303.4 1.4178 0.02048 1350.5 2557.8 1363.3 1378.9 2742.1 3.2858 5.6772 90.0
100. 311.1 1.4524 0.01803 1393.0 2544.4 1407.6 1317.1 2724.7 3.3596 5.6141 100.
110. 318.2 1.4886 0.01599 1433.7 2529.8 1450.1 1255.5 2705.6 3.4295 5.5527 110.
120. 324.8 1.5267 0.01426 1473.0 2513.7 1491.3 1193.6 2684.9 3.4962 5.4924 120.
130. 330.9 1.5671 0.01278 1511.1 2496.1 1531.5 1130.7 2662.2 3.5606 5.4323 130.
140. 336.8 1.6107 0.01149 1548.6 2476.8 1571.1 1066.5 2637.6 3.6232 5.3717 140.
150. 342.2 1.6581 0.01034 1585.6 2455.5 1610.5 1000.0 2610.5 3.6848 5.3098 150.
160. 347.4 1.7107 0.009306 1622.7 2431.7 1650.1 930.6 2580.6 3.7461 5.2455 160.
170. 352.4 1.7702 0.008364 1660.2 2405.0 1690.3 856.9 2547.2 3.8079 5.1777 170.
180. 357.1 1.8397 0.007489 1698.9 2374.3 1732.0 777.1 2509.1 3.8715 5.1044 180.
190. 361.5 1.9243 0.006657 1739.9 2338.1 1776.5 688.0 2464.5 3.9388 5.0228 190.
200. 365.8 2.036 0.005834 1785.6 2293.0 1826.3 583.4 2409.7 4.0139 4.9269 200.
220.9 374.1 3.155 0.003155 2029.6 2029.6 2099.3 0 2099.3 4.4298 4.4298 220.9
APPENDİCES 469
p = 10 bar p = 15 bar
(Tsat = 179.91oC) (Tsat = 198.32oC)
Sat. 0.1944 2583.6 2778.1 6.5865 0.1318 2594.5 2792.2 6.4448
200 0.2060 2621.9 2827.9 6.6940 0.1325 2598.1 2796.8 6.4546
240 0.2275 2692.9 2920.4 6.8817 0.1483 2676.9 2899.3 6.6628
280 0.2480 2760.2 3008.2 7.0465 0.1627 2748.6 2992.7 6.8381
320 0.2678 2826.1 3093.9 7.1962 0.1765 2817.1 3081.9 6.9938
360 0.2873 2891.6 3178.9 7.3349 0.1899 2884.4 3169.2 7.1363
400 0.3066 2957.3 3263.9 7.4651 0.2030 2951.3 3255.8 7.2690
440 0.3257 3023.6 3349.3 7.5883 0.2160 3018.5 3342.5 7.3940
500 0.3541 3124.4 3478.5 7.7622 0.2352 3120.3 3473.1 7.5698
540 0.3729 3192.6 3565.6 7.8720 0.2478 3189.1 3560.9 7.6805
600 0.4011 3296.8 3697.9 8.0290 0.2668 3293.9 3694.0 7.8385
640 0.4198 3367.4 3787.2 8.1290 0.2793 3364.8 3783.8 7.9391
p = 20 bar p = 30 bar
(Tsat = 212.42oC) (Tsat = 233.90oC)
Sat. 0.0996 2600.3 2799.5 6.3409 0.0667 2604.1 2804.2 6.1869
240 0.1085 2659.6 2876.5 6.4952 0.0682 2619.7 2824.3 6.2265
280 0.1200 2736.4 2976.4 6.6828 0.0771 2709.9 2941.3 6.4462
320 0.1308 2807.9 3069.5 6.8452 0.0850 2788.4 3043.4 6.6245
360 0.1411 2877.0 3159.3 6.9917 0.0923 2861.7 3138.7 6.7801
400 0.1512 2945.2 3247.6 7.1271 0.0994 2932.8 3230.9 6.9212
440 0.1611 3013.4 3335.5 7.254 0.1062 3002.9 3321.5 7.0520
500 0.1757 3116.2 3467.6 7.4317 0.1162 3108.0 3456.5 7.2338
540 0.1853 3185.6 3556.1 7.5434 0.1227 3178.4 3546.6 7.3474
600 0.1996 3290.9 3690.1 7.7024 0.1324 3285.0 3682.3 7.5085
640 0.2091 3362.2 3780.4 7.8035 0.1388 3357.0 3773.5 7.6106
700 0.2232 3470.9 3917.4 7.9487 0.1484 3466.5 3911.7 7.7571
APPENDİCES 471
p = 40 bar p = 60 bar
(Tsat = 250.4oC) (Tsat = 275.64oC)
T v u h s v u h s
°C m3/kg kJ/kg kJ/kg kJ/kgK m3/kg kJ/kg kJ/kg kJ/kgK
Sat. 0.04978 2602.3 2801.4 6.0701 0.03244 2589.7 2784.3 5.8892
280 0.05546 2680.0 2901.8 6.2568 0.03317 2605.2 2804.2 5.9252
320 0.06199 2767.4 3015.4 6.4553 0.03876 2720.0 2952.6 6.1846
360 0.06788 2845.7 3117.2 6.6215 0.04331 2811.2 3071.1 6.3782
400 0.07341 2919.9 3213.6 6.7690 0.04739 2892.9 3177.2 6.5408
440 0.07872 2992.2 3307.1 6.9041 0.05122 2970.0 3277.3 6.6853
500 0.08643 3099.5 3445.3 7.0901 0.05665 3082.2 3422.2 6.8803
540 0.09145 3171.1 3536.9 7.2056 0.06015 3156.1 3517.0 6.9999
600 0.09885 3279.1 3674.4 7.3688 0.06525 3266.9 3658.4 7.1677
640 0.1037 3351.8 3766.6 7.4720 0.06859 3341.0 3752.6 7.2731
700 0.1110 3462.1 3905.9 7.6198 0.07352 3453.1 3894.1 7.4234
740 0.1157 3536.6 3999.6 7.7141 0.07677 3528.3 3989.2 7.5190
p = 200 bar
p = 240 bar
(Tsat = 365.81oC)
Sat. 0.00583 2293.0 2409.7 4.9269
400 0.00994 2619.3 2818.1 5.5540 0.00673 2477.8 2639.4 5.2393
440 0.01222 2774.9 3019.4 5.8450 0.00929 2700.6 2923.4 5.6506
480 0.01399 2891.2 3170.8 6.0518 0.01100 2838.3 3102.3 5.8950
520 0.01551 2992.0 3302.2 6.2218 0.01241 2950.5 3248.5 6.0842
560 0.01689 3085.2 3423.0 6.3705 0.01366 3051.1 3379.0 6.2448
600 0.01818 3174.0 3537.6 6.5048 0.01481 3145.2 3500.7 6.3875
640 0.01940 3260.2 3648.1 6.6286 0.01588 3235.5 3616.7 6.5174
700 0.02113 3386.4 3809.0 6.7993 0.01739 3366.4 3783.8 6.6947
740 0.02224 3469.3 3914.1 6.9052 0.01835 3451.7 3892.1 6.8038
800 0.02385 3592.7 4069.7 7.0544 0.01974 3578.0 4051.6 6.9567
-2 0.5176 1.0904 241.7 -337.62 2372.6 -337.62 2835.3 2497.7 -1.237 2372.6 -2
-4 0.4375 1.0901 283.8 -341.78 2369.8 -341.78 2835.7 2494.0 -1.253 2369.8 -4
-6 0.3689 1.0898 334.2 -345.91 2367.0 -345.91 2836.2 2490.3 -1.268 2367.0 -6
-8 0.3102 1.0894 394.4 -350.02 2364.2 -350.02 2836.6 2486.6 -1.284 2364.2 -8
-10 0.2602 1.0891 466.7 -354.09 2361.4 -354.09 2837.0 2482.9 -1.299 2361.4 -10
-12 0.2176 1.0888 553.7 -358.14 2358.7 -358.14 2837.3 2479.2 -1.315 2358.7 -12
-14 0.1815 1.0884 658.8 -362.15 2355.9 -362.15 2837.6 2475.5 -1.331 2355.9 -14
-16 0.1510 1.0881 786.0 -366.14 2353.1 -366.14 2837.9 2471.8 -1.346 2353.1 -16
-18 0.1252 1.0878 940.5 -370.10 2350.3 -370.10 2838.2 2468.1 -1.362 2350.3 -18
-20 0.1035 1.0874 1128.6 -374.03 2347.5 -374.03 2838.4 2464.3 -1.377 2347.5 -20
-22 0.0853 1.0871 1358.4 -377.93 2344.7 -377.93 2838.6 2460.6 -1.393 2344.7 -22
-24 0.0701 1.0868 1640.1 -381.80 2342.0 -381.80 2838.7 2456.9 -1.408 2342.0 -24
-26 0.0574 1.0864 1986.4 -385.64 2339.2 -385.64 2838.9 2453.2 -1.424 2339.2 -26
-28 0.0469 1.0861 2413.7 -389.45 2336.4 -389.45 2839.0 2449.5 -1.439 2336.4 -28
-30 0.0381 1.0858 2943 -393.23 2333.6 -393.23 2839.0 2445.8 -1.455 2333.6 -30
-32 0.0309 1.0854 3600 -396.98 2330.8 -396.98 2839.1 2442.1 -1.471 2330.8 -32
-34 0.0250 1.0851 4419 -400.71 2328.0 -400.71 2839.1 2438.4 -1.486 2328.0 -34
-36 0.0201 1.0848 5444 -404.4 2325.2 -404.40 2839.1 2434.7 -1.501 2325.2 -36
-38 0.0161 1.0844 6731 -408.06 2322.4 -408.06 2839.0 2430.9 -1.517 2322.4 -38
-40 0.0129 1.0841 8354 -411.7 2319.6 -411.70 2838.9 2427.2 -1.532 2319.6 -40
-32 1.5049 0.7231 0.1468 8.68 214.80 8.79 228.10 236.89 0.0369 0.9828 -32
-30 1.6389 0.7262 0.1355 1088 215.58 11.00 226.77 237.78 0.0460 0.9787 -30
-28 1.7819 0.7294 0.1252 13.09 216.34 13.22 225.43 238.66 0.0551 0.9746 -28
-26 1.9345 0.7327 0.1159 15.31 217.11 15.45 224.08 239.53 0.0641 0.9707 -26
-22 2.2698 0.7393 0.0997 19.76 218.62 19.92 221.32 241.24 0.0819 0.9631 -22
-20 2.4534 0.7427 0.0926 21.99 219.37 22.17 219.91 242.09 0.0908 0.9595 -20
-18 2.6482 0.7462 0.0861 24.23 220.11 24.43 218.49 242.92 0.0996 0.9559 -18
-16 2.8547 0.7497 0.0802 26.48 220.85 26.69 217.05 243.74 0.1084 0.9525 -16
-14 3.0733 0.7533 0.0748 28.73 221.58 28.97 215.59 244.56 0.1171 0.9490 -14
-12 3.3044 0.7569 0.0698 31.00 222.30 31.25 214.11 245.36 0.1258 0.9457 -12
-10 3.5485 0.7606 0.0652 33.27 223.02 33.54 212.62 246.15 0.1345 0.9424 -10
-8 3.8062 0.7644 0.0610 35.54 223.73 35.83 211.10 246.93 0.1431 0.9392 -8
-6 4.0777 0.7683 0.0571 37.83 224.43 38.14 209.56 247.70 0.1517 0.9361 -6
-4 4.3638 0.7722 0.0535 40.12 225.13 40.46 208.00 248.45 0.1602 0.9330 -4
-2 4.6647 0.7762 0.0501 42.42 225.82 42.78 206.41 249.20 0.1688 0.9300 -2
0 4.9811 0.7803 0.0470 44.73 226.50 45.12 204.81 249.92 0.1773 0.9271 0
2 5.3133 0.7844 0.0442 47.04 227.17 47.46 203.18 250.64 0.1857 0.9241 2
4 5.6619 0.7887 0.0415 49.37 227.83 49.82 201.52 251.34 0.1941 0.9213 4
6 6.0275 0.7930 0.0391 51.71 228.48 52.18 199.84 252.03 0.2025 0.9184 6
8 6.4105 0.7974 0.0368 54.05 229.13 54.56 198.14 252.70 0.2109 0.9157 8
10 6.8113 0.8020 0.0346 56.40 229.76 56.95 196.40 253.35 0.2193 0.9129 10
12 7.2307 0.8066 0.0326 58.77 230.38 59.35 194.64 253.99 0.2276 0.9102 12
16 8.1268 0.8162 0.0291 63.53 231.59 64.19 191.02 255.21 0.2442 0.9048 16
20 9.1030 0.8263 0.0259 68.33 232.76 69.09 187.28 256.37 0.2607 0.8996 20
24 10.164 0.8369 0.0232 73.19 233.87 74.04 183.40 257.44 0.2772 0.8944 24
28 11.313 0.8480 0.0208 78.09 234.92 79.05 179.37 258.43 0.2936 0.8893 28
32 12.556 0.8599 0.0186 83.06 235.91 84.14 175.18 259.32 0.3101 0.8842 32
36 13.897 0.8724 0.0168 88.08 236.83 89.29 170.82 260.11 0.3265 0.8790 36
40 15.341 0.8858 0.0151 93.18 237.66 94.53 166.25 260.79 0.3429 0.8738 40
45 17.298 0.9039 0.0132 99.65 238.59 101.21 160.24 261.46 0.3635 0.8672 45
50 19.433 0.9238 0.0116 106.26 239.34 108.06 153.84 261.90 0.3842 0.8603 50
60 24.281 0.9705 0.0089 120.00 240.24 122.35 139.61 261.96 0.4264 0.8455 60
0.80 -45.73 0.7026 0.2650 -6.28 209.41 -6.23 236.84 230.61 -0.0270 0.0144 0.80
0.90 -43.30 0.7061 0.2374 -3.66 210.37 -3.60 235.34 231.74 -0.0155 1.0084 0.90
1.00 -41.09 0.7093 0.2152 -1.26 211.25 -1.19 233.95 232.77 -0.0051 1.0031 1.00
1.25 -36.23 0.7166 0.1746 4.04 213.16 4.13 230.86 234.99 0.0175 0.9919 1.25
1.50 -32.08 0.7230 0.1472 8.60 214.77 8.70 228.15 236.86 0.0366 0.9830 1.50
1.75 -28.44 0.7287 0.1274 12.61 216.18 12.74 225.73 238.47 0.0531 0.9755 1.75
2.00 -25.18 0.7340 0.1123 16.22 217.42 16.37 223.52 239.88 0.0678 0.9691 2.00
2.25 -22.22 0.7389 0.1005 19.51 218.53 19.67 221.47 241.15 0.0809 0.9636 2.25
2.50 -19.51 0.7436 0.0910 22.54 219.55 22.72 219.57 241.29 0.0930 0.9586 2.50
2.75 -17.00 0.7479 0.0831 25.36 220.48 25.56 217.77 243.33 0.1040 0.9542 2.75
3.00 -14.66 0.7521 0.0765 27.99 221.34 28.22 216.07 244.29 0.1143 0.9502 3.00
3.25 -12.46 0.7561 0.0709 30.47 222.13 30.72 214.46 245.18 0.1238 0.9465 3.25
3.50 -10.39 0.7599 0.0661 32.82 222.88 33.09 212.91 246.00 0.1328 0.9431 3.50
3.75 -8.43 0.7636 0.0618 35.06 223.58 35.34 211.42 246.77 0.1413 0.9399 3.75
4.00 -6.56 0.7672 0.0581 37.18 224.24 37.49 209.99 247.48 0.1493 0.9370 4.00
4.25 -4.78 0.7706 0.0548 39.22 224.86 39.55 208.61 248.16 0.1569 0.9342 4.25
4.50 -3.08 0.7740 0.0519 41.17 225.45 41.52 207.27 248.80 0.1642 0.9316 4.50
4.75 -1.45 0.7773 0.0492 43.05 226 43.42 205.98 249.40 0.1711 0.9292 4.75
5.00 0.12 0.7805 0.0469 44.86 226.54 45.25 204.71 249.97 0.1777 0.9269 5.00
5.25 1.63 0.7836 0.0447 46.61 227.04 47.02 203.48 250.51 0.1841 0.9247 5.25
5.50 3.08 0.7867 0.0427 48.3 227.53 48.74 202.28 251.02 0.1903 0.9226 5.50
5.75 4.49 0.7897 0.0409 49.94 227.99 50.40 201.11 251.51 0.1962 0.9206 5.75
6.00 5.85 0.7927 0.0392 51.53 228.44 52.01 199.97 251.98 0.2019 0.9186 6.00
7.00 10.91 0.8041 0.0337 57.48 230.04 58.04 195.60 253.64 0.2231 0.9117 7.00
8.00 15.45 0.8149 0.0295 62.88 231.43 63.53 191.52 255.05 0.2419 0.9056 8.00
9.00 19.59 0.8252 0.0262 67.84 232.64 68.59 187.67 256.25 0.2591 0.9001 9.00
10.00 23.40 0.8352 0.0236 72.46 233.71 73.30 183.99 257.28 0.2748 0.8952 10.00
12.00 30.25 0.8546 0.0195 80.87 235.48 81.90 177.04 258.94 0.3029 0.8864 12.00
14.00 36.29 0.8734 0.0166 88.45 236.89 89.68 170.49 260.16 0.3277 0.8786 14.00
16.00 41.73 0.8919 0.0144 95.41 238.00 96.83 164.21 261.04 0.3500 0.8715 16.00
18.00 46.69 0.9104 0.0127 101.87 238.86 103.51 158.13 261.64 0.3705 0.8649 18.00
20.00 51.26 0.9291 0.0112 107.95 239.51 109.81 152.17 261.98 0.3895 0.8586 20.00
24.00 59.46 0.9677 0.0091 119.24 240.22 121.56 140.43 261.99 0.4241 0.8463 24.00
-18 20.938 0.000978 0.018131 158.77 277.93 436.70 0.8494 1.9386 -18
-16 22.237 0.000987 0.017002 163.14 273.30 436.44 0.8659 1.9287 -16
-14 23.593 0.000997 0.015950 167.55 268.54 436.09 0.8825 1.9187 -14
-12 25.010 0.001007 0.014967 172.01 263.65 435.66 0.8991 1.9086 -12
-10 26.487 0.001017 0.014048 176.52 258.62 435.14 0.9157 1.8985 -10
30.978 73.773 0.002139 0.002139 332.25 0.00 332.25 1.4336 1.4336 30.978
482 THERMODYNAMICS
p = 40 bar p = 50 bar
(Tsat = 5.30oC) (Tsat = 14.30oC)
Sat. 0.008640 427.25 1.8145 0.006383 417.66 1.7544
10 0.009224 436.55 1.8477
20 0.010257 452.99 1.9047 0.007110 432.38 1.8051
30 0.011141 467.15 1.9523 0.008063 451.44 1.8691
40 0.011939 480.10 1.9943 0.008846 467.13 1.9200
50 0.012681 492.31 2.0327 0.009538 481.15 1.9641
60 0.013382 504.02 2.0684 0.010173 494.19 2.0039
70 0.014053 515.39 2.1020 0.010768 506.59 2.0405
80 0.014699 526.51 2.1339 0.011334 518.54 2.0749
90 0.015326 537.45 2.1645 0.011876 530.16 2.1073
100 0.015937 548.26 2.1939 0.012399 541.55 2.1383
110 0.016534 558.97 2.2222 0.012907 552.76 2.1679
120 0.017120 569.62 2.2496 0.013403 563.84 2.1965
130 0.017695 580.22 2.2763 0.013887 574.82 2.2240
140 0.018263 590.80 2.3022 0.014363 585.73 2.2508
150 0.018823 601.35 2.3274 0.014830 596.59 2.2767
160 0.019376 611.90 2.3521 0.015290 607.41 2.3020
170 0.019924 622.46 2.3762 0.015745 618.22 2.3267
p = 60 bar p = 70 bar
(Tsat = 22.00oC) (Tsat = +28.7oC)
T v h s v h s
°C m3/kg kJ/kg kJ/kgK m3/kg kJ/kg kJ/kgK
Sat. 0.004742 403.32 1.6862 0.003289 376.91 1.5844
30 0.005833 430.71 1.7779 0.003752 392.71 1.6367
40 0.006700 451.72 1.8462 0.005050 432.12 1.7649
50 0.007396 468.57 1.8992 0.005814 453.99 1.8337
60 0.008006 483.44 1.9445 0.006430 471.53 1.8872
70 0.008561 497.16 1.9851 0.006969 486.98 1.9329
80 0.009079 510.11 2.0223 0.007459 501.18 1.9737
90 0.009569 522.55 2.0570 0.007916 514.57 2.0111
484 THERMODYNAMICS
p = 80 bar p = 90 bar
10 0.001107 220.04 1.0543 0.001096 218.97 1.0467
20 0.001208 246.91 1.1475 0.001186 244.58 1.1355
30 0.001425 284.04 1.2719 0.001344 276.32 1.2419
40 0.003599 402.90 1.6578 0.00206 343.78 1.4600
50 0.004562 436.37 1.7632 0.003509 413.81 1.6810
60 0.005219 458.13 1.8296 0.004248 442.78 1.7693
70 0.005760 475.93 1.8822 0.004807 463.86 1.8317
80 0.006237 491.69 1.9275 0.005280 481.59 1.8827
90 0.006672 506.21 1.9681 0.005703 497.46 1.9270
100 0.007078 519.90 2.0053 0.006092 512.15 1.9669
110 0.007462 532.99 2.0399 0.006455 526.02 2.0036
120 0.007828 545.65 2.0725 0.006798 539.32 2.0378
130 0.008180 557.98 2.1035 0.007127 552.17 2.0701
140 0.008521 570.06 2.1331 0.007443 564.70 2.1008
150 0.008852 581.95 2.1615 0.007749 576.97 2.1302
160 0.009174 593.68 2.1889 0.008046 589.03 2.1584
170 0.009489 605.29 2.2154 0.008336 600.94 2.1855
180 0.009799 616.82 2.2411 0.008619 612.73 2.2118
T v h s v h s
°C m3/kg kJ/kg kJ/kgK m3/kg kJ/kg kJ/kgK
10 0.001086 218.06 1.0396 0.001078 217.26 1.0330
20 0.001168 242.70 1.1251 0.001152 241.14 1.1158
30 0.001296 271.62 1.2220 0.001263 268.21 1.2066
40 0.001591 313.04 1.3563 0.001463 302.38 1.3173
50 0.002602 384.07 1.5795 0.00199 354.37 1.4806
60 0.003449 425.02 1.7045 0.002795 404.93 1.6349
APPENDİCES 485
p = 200 bar
0.6 -37.07 0.7097 0.3100 3.41 206.12 3.46 221.27 224.72 0.0147 0.9520 0.6
0.8 -31.21 0.7184 0.2366 10.41 209.46 10.47 217.92 228.39 0.0440 0.9447 0.8
1.0 -26.43 0.7258 0.1917 16.22 212.18 16.29 215.06 231.35 0.0678 0.9395 1.0
1.2 -22.36 0.7323 0.1614 21.23 214.50 21.32 212.54 233.86 0.0879 0.9354 1.2
1.4 -18.80 0.7381 0.1395 25.66 216.52 25.77 210.27 236.04 0.1055 0.9322 1.4
1.6 -15.62 0.7435 0.1229 29.66 218.32 29.78 208.19 237.97 0.1211 0.9295 1.6
1.8 -12.73 0.7485 0.1098 33.31 219.94 33.45 206.26 239.71 0.1352 0.9273 1.8
2.0 -10.09 0.7532 0.0993 36.69 221.43 36.84 204.46 241.30 0.1481 0.9253 2.0
2.4 -5.37 0.7618 0.0834 42.77 224.07 42.95 201.14 244.09 0.1710 0.9222 2.4
2.8 -1.23 0.7697 0.0719 48.18 226.38 48.39 198.13 246.52 0.1911 0.9197 2.8
3.2 2.48 0.7770 0.0632 53.06 228.43 53.31 195.35 248.66 0.2089 0.9177 3.2
3.6 5.84 0.7839 0.0564 57.54 230.28 57.82 192.76 250.58 0.2251 0.9160 3.6
4.0 8.93 0.7904 0.0509 61.69 231.97 62.00 190.32 252.32 0.2399 0.9145 4.0
5.0 15.74 0.8056 0.0409 70.93 235.64 71.33 184.74 256.07 0.2723 0.9117 5.0
6.0 21.58 0.8196 0.0341 78.99 238.74 79.48 179.71 259.19 0.2999 0.9097 6.0
7.0 26.72 0.8328 0.0292 86.19 241.42 86.78 175.07 261.85 0.3242 0.9080 7.0
8.0 31.33 0.8454 0.0255 92.75 243.78 93.42 170.73 264.15 0.3459 0.9066 8.0
9.0 35.53 0.8576 0.0226 98.79 245.88 99.56 166.62 266.18 0.3656 0.9054 9.0
10.0 39.39 0.8695 0.0202 104.42 247.77 105.29 162.68 267.97 0.3838 0.9043 10.0
12.0 46.32 0.8928 0.0166 114.69 251.03 115.76 155.23 270.99 0.4164 0.9023 12.0
14.0 52.43 0.9159 0.0140 123.98 253.74 125.26 148.14 273.40 0.4453 0.9003 14.0
16.0 57.92 0.9392 0.0121 132.52 256.00 134.02 141.31 275.33 0.4714 0.8982 16.0
18.0 62.91 0.9631 0.0105 140.49 257.88 142.22 134.60 276.83 0.4954 0.8959 18.0
20.0 67.49 0.9878 0.0093 148.02 259.41 149.99 127.95 277.94 0.5178 0.8934 20.0
25.0 77.59 1.0562 0.0069 165.48 261.84 168.12 111.06 279.17 0.5687 0.8854 25.0
30.0 86.22 1.1416 0.0053 181.88 262.16 185.30 92.71 278.01 0.6156 0.8735 30.0
490 THERMODYNAMICS
-50 0.4086 1.4245 2.6265 -43.94 1264.99 -43.88 1416.2 1372.32 -0.1922 6.1543 -50
-45 0.5453 1.4367 2.0060 -22.03 1271.19 -21.95 1402.52 1380.57 -0.0951 6.0523 -45
-40 0.7174 1.4493 1.5524 -0.10 1277.20 0.00 1388.56 1388.56 0.0000 5.9557 -40
-36 0.8850 1.4597 1.2757 17.47 1281.87 17.60 1377.17 1394.77 0.0747 5.8819 -36
-32 1.0832 1.4703 1.0561 35.09 1286.41 35.25 1365.55 1400.81 0.1484 5.8111 -32
-30 1.1950 1.4757 0.9634 43.93 1288.63 44.10 1359.65 1403.75 0.1849 5.7767 -30
-28 1.3159 1.4812 0.8803 52.78 1290.82 52.97 1353.68 1406.66 0.2212 5.7430 -28
-26 1.4465 1.4867 0.8056 61.65 1292.97 61.86 1347.65 1409.51 0.2572 5.7100 -26
-22 1.7390 1.498 0.6780 79.46 1297.18 79.72 1335.36 1415.08 0.3287 5.6457 -22
-20 1.9019 1.5038 0.6233 88.40 1299.23 88.68 1329.1 1417.79 0.3642 5.6144 -20
-18 2.0769 1.5096 0.5739 97.36 1301.25 97.68 1322.77 1420.45 0.3994 5.5837 -18
-16 2.2644 1.5155 0.5291 106.36 1303.23 106.70 1316.35 1423.05 0.4346 5.5536 -16
-14 2.4652 1.5215 0.4885 115.37 1305.17 115.75 1309.86 1425.61 0.4695 5.5239 -14
-12 2.6798 1.5276 0.4516 124.42 1307.08 124.83 1303.28 1428.11 0.5043 5.4948 -12
-10 2.9089 1.5338 0.4180 133.50 1308.95 133.94 1296.61 1430.55 0.5389 5.4662 -10
-8 3.1532 1.5400 0.3874 142.60 1310.78 143.09 1289.86 1432.95 0.5734 5.4380 -8
-6 3.4134 1.5464 0.3595 151.74 1312.57 152.26 1283.02 1435.28 0.6077 5.4103 -6
-4 3.6901 1.5528 0.334 160.88 1314.32 161.46 1276.1 1437.56 0.6418 5.3831 -4
-2 3.9842 1.5594 0.3106 170.07 1316.04 170.69 1269.08 1439.78 0.6759 5.3562 -2
0 4.2962 1.5660 0.2892 179.29 1317.71 179.96 1261.97 1441.94 0.7097 5.3298 0
2 4.6270 1.5727 0.2695 188.53 1319.34 189.26 1254.77 1444.03 0.7435 5.3038 2
4 4.9773 1.5796 0.2514 197.80 1320.92 198.59 1247.48 1446.07 0.7770 5.2781 4
6 5.3479 1.5866 0.2348 207.10 1322.47 207.95 1240.09 1448.04 0.8105 5.2529 6
8 5.7395 1.5936 0.2195 216.42 1323.96 217.34 1232.61 1449.94 0.8438 5.2279 8
10 6.1529 1.6008 0.2054 225.77 1325.42 226.75 1225.03 1451.78 0.8769 5.2033 10
12 6.5890 1.6081 0.1923 235.14 1326.82 236.20 1217.35 1453.55 0.9099 5.1791 12
16 7.5324 1.6231 0.1691 253.95 1329.48 255.18 1201.7 1456.87 0.9755 5.1314 16
20 8.5762 1.6386 0.1492 272.86 1331.94 274.26 1185.64 1459.90 1.0404 5.0849 20
24 9.7274 1.6547 0.1320 291.84 1334.19 293.45 1169.16 1462.61 1.1048 5.0394 24
28 10.993 1.6714 0.1172 310.92 1336.20 312.75 1152.24 1465.00 1.1686 4.9948 28
32 12.380 1.6887 0.1043 330.07 1337.97 332.17 1134.87 1467.03 1.2319 4.9509 32
36 13.896 1.7068 0.0930 349.32 1339.47 351.69 1117.00 1468.70 1.2946 4.9078 36
40 15.549 1.7256 0.0831 368.67 1340.70 371.35 1098.62 1469.97 1.3569 4.8652 40
45 17.819 1.7503 0.0725 393.01 1341.81 396.13 1074.84 1470.96 1.4341 4.8125 45
50 20.331 1.7765 0.0634 417.56 1342.42 421.17 1050.09 1471.26 1.5109 4.7604 50
494 THERMODYNAMICS
p = 20.0 bar
(Tsat = 49.37oC)
Sat. 0.06445 1342.37 1471.26 4.7670
60 0.06875 1372.05 1509.54 4.8838
80 0.07596 1421.36 1573.27 5.0696
100 0.08248 1465.89 1630.86 5.2283
120 0.08861 1508.03 1685.24 5.3703
140 0.09447 1549.03 1737.98 5.5012
160 0.10016 1589.65 1789.97 5.6241
180 0.10571 1630.32 1841.74 5.7409
200 0.11116 1671.33 1893.64 5.8530
220 0.11652 1712.82 1945.87 5.9611
240 0.12182 1754.90 1998.54 6.0658
260 0.12706 1797.63 2051.74 6.1675
280 0.13224 1841.03 2105.50 6.2665
APPENDİCES 499
-100 0.02888 1.553 11.27 -128.4 319.5 -128.4 480.4 352.0 -0.634 2.140 -100
-90 0.06426 1.578 5.345 -107.8 329.3 -107.8 471.4 363.6 -0.519 2.055 -90
-80 0.1301 1.605 2.774 -87.0 339.3 -87.0 462.4 375.4 -0.408 1.986 -80
-70 0.2434 1.633 1.551 -65.8 349.5 -65.8 453.1 387.3 -0.301 1.929 -70
-60 0.4261 1.663 0.9234 -44.4 359.9 -44.3 443.5 399.2 -0.198 1.883 -60
-50 0.7046 1.694 0.5793 -22.5 370.4 -22.4 433.6 411.2 -0.098 1.845 -50
-40 1.110 1.728 0.3798 -0.2 381.0 0.0 423.2 423.2 0.000 1.815 -40
-30 1.677 1.763 0.2585 22.6 391.6 22.9 412.1 435.0 0.096 1.791 -30
-20 2.444 1.802 0.1815 45.9 402.4 46.3 400.5 446.8 0.190 1.772 -20
-10 3.451 1.844 0.1309 69.8 413.2 70.4 388.0 458.4 0.282 1.757 -10
0 4.743 1.890 0.09653 94.2 423.8 95.1 374.5 469.6 0.374 1.745 0
4 5.349 1.910 0.08591 104.2 428.1 105.3 368.8 474.1 0.410 1.741 4
8 6.011 1.931 0.07666 114.3 432.3 115.5 362.9 478.4 0.446 1.737 8
12 6.732 1.952 0.06858 124.6 436.5 125.9 356.8 482.7 0.482 1.734 12
16 7.515 1.975 0.06149 135.0 440.7 136.4 350.5 486.9 0.519 1.731 16
20 8.362 1.999 0.05525 145.4 444.8 147.1 343.9 491.0 0.555 1.728 20
24 9.278 2.024 0.04973 156.1 448.9 158.0 337.0 495.0 0.591 1.725 24
28 10.27 2.050 0.04483 166.9 452.9 169.0 329.9 498.9 0.627 1.722 28
32 11.33 2.078 0.04048 177.8 456.7 180.2 322.4 502.6 0.663 1.720 32
36 12.47 2.108 0.03659 188.9 460.6 191.6 314.6 506.2 0.699 1.717 36
40 13.69 2.140 0.03310 200.2 464.3 203.1 306.5 509.6 0.736 1.715 40
44 15.00 2.174 0.02997 211.7 467.9 214.9 298.0 512.9 0.772 1.712 44
48 16.40 2.211 0.02714 223.4 471.4 227.0 288.9 515.9 0.809 1.709 48
52 17.89 2.250 0.02459 235.3 474.6 239.3 279.3 518.6 0.846 1.705 52
56 19.47 2.293 0.02227 247.4 477.7 251.9 269.2 521.1 0.884 1.701 56
60 21.16 2.340 0.02015 259.8 480.6 264.8 258.4 523.2 0.921 1.697 60
65 23.42 2.406 0.01776 275.7 483.6 281.4 243.8 525.2 0.969 1.690 65
70 25.86 2.483 0.01560 292.3 486.1 298.7 227.7 526.4 1.018 1.682 70
75 28.49 2.573 0.01363 309.5 487.8 316.8 209.8 526.6 1.069 1.671 75
80 31.31 2.683 0.01182 327.6 488.2 336.0 189.2 525.2 1.122 1.657 80
85 34.36 2.827 0.01011 347.2 486.9 356.9 164.7 521.6 1.178 1.638 85
90 37.64 3.038 0.008415 369.4 482.2 380.8 133.1 513.9 1.242 1.608 90
95 41.19 3.488 0.006395 399.8 467.4 414.2 79.5 493.7 1.330 1.546 95
96.7 42.48 4.535 0.004535 434.9 434.9 454.2 0.0 457.2 1.437 1.437 96.7
500 THERMODYNAMICS
0.05 -93.28 1.570 6.752 -114.6 326.0 -114.6 474.4 359.8 -0.556 2.081 0.05
0.10 -83.87 1.594 3.542 -95.1 335.4 -95.1 465.9 370.8 -0.450 2.011 0.10
0.25 -69.55 1.634 1.513 -64.9 350.0 -64.9 452.7 387.8 -0.297 1.927 0.25
0.50 -56.93 1.672 0.6720 -37.7 363.1 -37.6 440.5 402.9 -0.167 1.871 0.50
0.75 -48.68 1.698 0.5467 -19.6 371.8 -19.5 432.3 412.8 -0.085 1.841 0.75
1.00 -42.38 1.719 0.4185 -5.6 378.5 -5.4 425.7 420.3 -0.023 1.822 1.00
2.00 -25.43 1.781 0.2192 33.1 396.6 33.5 406.9 440.4 0.139 1.782 2.00
3.00 -14.16 1.826 0.1496 59.8 408.7 60.3 393.3 453.6 0.244 1.762 3.00
4.00 -5.46 1.865 0.1137 80.8 418.0 81.5 382.0 463.5 0.324 1.751 4.00
5.00 1.74 1.899 0.09172 98.6 425.7 99.5 372.1 471.6 0.389 1.743 5.00
6.00 7.93 1.931 0.07680 114.2 432.2 115.3 363.0 478.3 0.446 1.737 6.00
7.00 13.41 1.960 0.06598 128.2 438.0 129.6 354.6 484.2 0.495 1.733 7.00
8.00. 18.33 1.989 0.05776 141.0 443.1 142.6 346.7 489.3 0.540 1.729 8.00.
9.00 22.82 2.016 0.05129 152.9 447.6 154.7 339.1 493.8 0.580 1.726 9.00
10.00 26.95 2.043 0.04606 164.0 451.8 166.1 331.8 497.9 0.618 1.723 10.00
11.00 30.80 2.070 0.04174 174.5 455.6 176.8 324.7 501.5 0.652 1.721 11.00
12.00 34.39 2.096 0.03810 184.4 459.1 187.0 317.8 504.8 0.685 1.718 12.00
13.00 37.77 2.122 0.03499 193.9 462.2 196.7 311.0 507.7 0.716 1.716 13.00
14.00 40.97 2.148 0.03231 203.0 465.2 206.0 304.4 510.4 0.745 1.714 14.00
15.00 44.01 2.174 0.02997 211.7 467.9 215.0 297.9 512.9 0.772 1.712 15.00
16.00 46.89 2.200 0.02790 220.1 470.4 223.6 291.4 515.0 0.799 1.710 16.00
17.00 49.65 2.227 0.02606 228.3 472.7 232 285.0 517.0 0.824 1.707 17.00
18.00 52.30 2.253 0.02441 236.2 474.9 240.2 278.6 518.8 0.849 1.705 18.00
19.00 54.83 2.280 0.02292 243.8 476.9 248.2 272.2 520.4 0.873 1.703 19.00
20.00 57.27 2.308 0.02157 251.3 478.7 255.9 265.9 521.8 0.896 1.700 20.00
22.00 61.90 2.364 0.01921 265.8 481.7 271.0 253.0 524.0 0.939 1.695 22.00
24.00 66.21 2.424 0.01721 279.7 484.3 285.5 240.1 525.6 0.981 1.688 24.00
26.00 70.27 2.487 0.01549 293.1 486.2 299.6 226.9 526.5 1.021 1.681 26.00
28.00 74.10 2.555 0.01398 306.2 487.5 313.4 213.2 526.6 1.060 1.673 28.00
30.00 77.72 2.630 0.01263 319.2 488.1 327.1 198.9 526.0 1.097 1.664 30.00
35.00 86.01 2.862 0.009771 351.4 486.3 361.4 159.1 520.5 1.190 1.633 35.00
40.00 93.38 3.279 0.007151 387.9 474.7 401.0 102.3 503.3 1.295 1.574 40.00
42.48 96.70 4.535 0.004535 434.9 434.9 454.2 0.0 454.2 1.437 1.437 42.48
APPENDİCES 501
Chemical M Tc pc pc c
Substance
Zc
Formula (kg/ kmol) (K) (bar)
RTc
Carbon C 12.01 — — —
Copper Cu 63.54 — — —
Table A.22 Variation of c p (kJ/kmolK) with Temperature for Selected Ideal Gases
cp
a0 a1T a2T 2 a3T 3 a4T 4
R
T is in K, the equation is valid from 300 to 1000 K
Gas a0 a1 a2 a3 a4
CO 3.710 -1.619 3.692 -2.032 0.240
CO2 2.401 8.735 -6.607 2.002 0
H2 3.057 2.677 -5.810 5.521 -1.812
H2O 4.070 -1.108 4.152 -2.964 0.807
O2 3.626 -1.878 7.055 -6.764 2.156
N2 3.675 -1.208 2.324 -0.632 -0.226
Air 3.653 -1.337 3.294 -1.913 0.2763
SO2 3.267 5.324 0.684 -5.281 2.559
CH4 3.826 -3.979 24.558 -22.733 6.963
C2H2 1.410 19.057 -24.501 16.391 -4.135
C2H4 1.426 11.383 7.989 -16.254 6.749
Monatomic gases
2.5 0 0 0 0
(Ar, He, Ne)
Table A.23 Ideal Gas Specific Heats of Some Common Gases (kJ/kgK)
250 1.003 0.716 1.401 1.039 0.742 1.400 0.913 0.653 1.398 250
300 1.005 0.718 1.400 1.039 0.743 1.400 0.918 0.658 1.395 300
350 1.008 0.721 1.398 1.041 0.744 1.399 0.928 0.668 1.389 350
400 1.013 0.726 1.395 1.044 0.747 1.397 0.941 0.681 1.382 400
450 1.020 0.733 1.391 1.049 0.752 1.395 0.956 0.696 1.373 450
500 1.029 0.742 1.387 1.056 0.759 1.391 0.972 0.712 1.365 500
550 1.040 0.753 1.381 1.065 0.768 1.387 0.988 0.728 1.358 550
600 1.051 0.764 1.376 1.075 0.778 1.382 1.003 0.743 1.350 600
650 1.063 0.776 1.370 1.086 0.789 1.376 1.017 0.758 1.343 650
700 1.075 0.788 1.364 1.098 0.801 1.371 1.031 0.771 1.337 700
750 1.087 0.800 1.359 1.110 0.813 1.365 1.043 0.783 1.332 750
800 1.099 0.812 1.354 1.121 0.825 1.360 1.054 0.794 1.327 800
900 1.121 0.834 1.344 1.145 0.849 1.349 1.074 0.814 1.319 900
1000 1.142 0.855 1.336 1.167 0.870 1.341 1.090 0.830 1.313 1000
APPENDİCES 507
Temp. Temp.
Carbon Dioxide, CO2 Carbon Monoxide, CO Hydrogen, H2
K K
250 0.791 0.602 1.314 1.039 0.743 1.400 14.051 9.927 1.416 250
300 0.846 0.657 1.288 1.040 0.744 1.399 14.307 10.183 1.405 300
350 0.895 0.706 1.268 1.043 0.746 1.398 14.427 10.302 1.400 350
400 0.939 0.750 1.252 1.047 0.751 1.395 14.476 10.352 1.398 400
450 0.978 0.790 1.239 1.054 0.757 1.392 14.501 10.377 1.398 450
500 1.014 0.825 1.229 1.063 0.767 1.387 14.513 10.389 1.397 500
550 1.046 0.857 1.220 1.075 0.778 1.382 14.530 10.405 1.396 550
600 1.075 0.886 1.213 1.087 0.790 1.376 14.546 10.422 1.396 600
650 1.102 0.913 1.207 1.100 0.803 1.370 14.571 10.447 1.395 650
700 1.126 0.937 1.202 1.113 0.816 1.364 14.604 10.480 1.394 700
750 1.148 0.959 1.197 1.126 0.829 1.358 14.645 10.521 1.392 750
800 1.169 0.980 1.193 1.139 0.842 1.353 14.695 10.570 1.390 800
900 1.204 1.015 1.186 1.163 0.866 1.343 14.822 10.698 1.385 900
1000 1.234 1.045 1.181 1.185 0.888 1.335 14.983 10.859 1.380 1000
when Δs = 0 when Δs = 0
T h u s0 T h u s0
pr vr pr vr
200 199.97 142.56 1.29559 0.3363 1707. 450 451.80 322.62 2.11161 5.775 223.6
210 209.97 149.69 1.34444 0.3987 1512. 460 462.02 329.97 2.13407 6.245 211.4
220 219.97 156.82 1.39105 0.4690 1346. 470 472.24 337.32 2.15604 6.742 200.1
230 230.02 164.00 1.43557 0.5477 1205. 480 482.49 344.70 2.17760 7.268 189.5
240 240.02 171.13 1.47824 0.6355 1084. 490 492.74 352.08 2.19876 7.824 179.7
250 250.05 178.28 1.51917 0.7329 979.0 500 503.02 359.49 2.21952 8.411 170.6
260 260.09 185.45 1.55848 0.8405 887.8 510 513.32 366.92 2.23993 9.031 162.1
270 270.11 192.60 1.59634 0.9590 808.0 520 523.63 374.36 2.25997 9.684 154.1
280 280.13 199.75 1.63279 1.0889 738.0 530 533.98 381.84 2.27967 10.37 146.7
285 285.14 203.33 1.65055 1.1584 706.1 540 544.35 389.34 2.29906 11.10 139.7
290 290.16 206.91 1.66802 1.2311 676.1 550 554.74 396.86 2.31809 11.86 133.1
295 295.17 210.49 1.68515 1.3068 647.9 560 565.17 404.42 2.33685 12.66 127.0
300 300.19 214.07 1.70203 1.3860 621.2 570 575.59 411.97 2.35531 13.50 121.2
305 305.22 217.67 1.71865 1.4686 596.0 580 586.04 419.55 2.37348 14.38 115.7
310 310.24 221.25 1.73498 1.5546 572.3 590 596.52 427.15 2.39140 15.31 110.6
315 315.27 224.85 1.75106 1.6442 549.8 600 607.02 434.78 2.40902 16.28 105.8
320 320.29 228.42 1.76690 1.7375 528.6 610 617.53 442.42 2.42644 17.30 101.2
325 325.31 232.02 1.78249 1.8345 508.4 620 628.07 450.09 2.44356 18.36 96.92
330 330.34 235.61 1.79783 1.9352 489.4 630 638.63 457.78 2.46048 19.84 92.84
340 340.42 242.82 1.82790 2.149 454.1 640 649.22 465.50 2.47716 20.64 88.99
508 THERMODYNAMICS
T h u s0 T h u s0
Chapter 1
1.12 Wt 14.18 N , 1.14 Lc 4.39m , 1.16 pi 1450kPa, pe 6.67 kPa , 1.18 Fwind 1.78kN ,
b. p2 255.3kPa , 1.24 Lleft 10.94cm , Lright 34.52cm , 1.28 a. 42.7o C , b. 28.6o C , c. 4.4o C , d. 85.5o C .
Chapter 2
2.10 Vliq / V 48%, Vgas / V 52% , 2.12 ms / m 99.91% , 2.14 b. T1 81.33o C , T2 120.2o C ,
o
c. T2 190.3 C , H 16.84kJ , d. 5.6% , e. 30.65% , 2.24 a. m 497.53kg , b. m 888.44kg , c. p2 18.33bar ,
o
c. u 0 , ideal gas, 2.30 a.two-phase region, x2 0.59 , b. T2 99.63 C , s2 4.876kJ / kgK .
Chapter 3
3
3.2 mR 22 80.27 kg , b. Vliquid 0.1754m , 3.4a. m cv 25, 0, 25kg / h , b. m 50kg , 3.6 m nitrogen 0.0008kg / s ,
di2
3.8 Vliq Vo , 3.10 V 2n 2
d o2 di2
Vc n 12n 1
, 0.71, 0.79, 0.84, 0.86, 3.12 d 0.408 , 3.14 a. V
D
inlet 1.28m / s ,
b. D2 14.57cm , T2 1742.5 K , 3.16 Vexit 143.8 m/s, 3.18 a. m a 0.12kg / s , b. m liq 0.6 g / s , c. V2 0.204m / s
APPENDİCES 519
dp m RT
3.20 V3 12m / s , 3.22 m cv 42.39Va 0 rising, 3.24 d / dt 11.25kg / m3s , 3.26 e 1 ,
dt V
Chapter 4
o
4.2 T f 20.95 C , 4.4 mcu 86.13 kg , 4.6 a. p2 1.27 bar , T2 300 K b. W 206.46 kJ/kg ,
o
c. p f 200 kPa T f 302 C , 4.8 a. V2 / V1 1.04 , b. x 0.85 , 4.12 a. p2 500 kPa , b. x 1.0 , 4.14 a. T2 300 K ,
b. p3 28 MPa , c. W12 43 kJ Q12 33.38 kJ W23 0 Q23 7.16 kJ , 4.16 a. T2 585 K
b. W12 40 kJ Q12 24.82 kJ , 4.18 Q12 275.77 kJ , 4.20 a. p f 32.71 bar , b. Qin 2666 kJ , 4.22 t 42.2 min ,
4.24 a. p2 248.6 kPa , b. W12 101 kJ Q12 1207 kJ , 4.26 a. Q12 1983.5 kJ Q23 1212.2 kJ , 4.28 Q12 83.3 kJ ,
4.30 a. L 13.7 cm , b. L 3.9 cm , c. for adiabatic compression, W12 0.06 kJ Q12 0 , for isothermal compression,
W12 Q12 0.045 kJ, 4.32 a.T2 A 400o C, T2 B 190o C b. Q12 997.81 kJ , 4.34 W12 142.7 kJ , 4.36 W12 885.3 kJ ,
3
4.38 a. x2 0.1 V2 0.685 m b. W12 109 kJ , 4.40 T2 266.6 K , 4.42 a. U 2 75 kJ U 3 93 kJ ,
b. Q12 10 kJ Q23 18 kJ Q31 20 kJ, c. H 0.0 , d. Refrigeration 4.44 b. T2 573K , T3 249.4 K , p2 p3 1.52 bar ,
3
c. V2 0.93 m , d. Wnet 98.3 kJ 31.6% , 4.46 QH 78353 kJ/h , 4.48 a. Wc 7.42 kW b. COP 2.37 ,
o o
c. cost $5.94 / day , 4.52 Q 2.67 kW , 4.54 Texit 93.1 C , 4.56 a. T2 120.2 C , b. Ek 42.5 W , 4.58 44.6% ,
4.60 b. cold water, m w 515 kg/h , steam, m s 485 kg/h, 4.62 m a 0.00187 kg/s 4.64 a. W 1044 kW b. err % 0.2% ,
4.66 Wc 298.7 kW , 4.68 W p 0.155 kW , 4.70 a. V2 666.67 m /min , b. p2 53.3 mmH 2O , Wc 2 9.48 kW ,
3
4.74 a. V4 75 m/s , b. m R 22 1240 kg/s , 4.76 a. Q con 1496.7 kW , b. m w 35.8 kg/s , 4.78 a. V2 3.8 m/s ,
b. Q 3.9 kW , 4.80 T f 350 C , m 0.354 kg , 4.82 Q12 535 kJ , 4.84 Q12 75 kJ , 4.86 a. Q12 A 213.8 kJ ,
o
o
b. m A 0.8 kg , mB 0.6 kg , m A / mB 1.2 kg , 4.88 T 286o C , 4.90 a. T2 162 C b. m 0.057 kg ,
c. Q13 54.66 kJ ,
520 THERMODYNAMICS
Chapter 5
5.2 1 1418.43 kJ, 2 0.33 kJ, 1418.1 kJ , 5.4 a. 1 151.5 kJ , b. 56.53 kJ , c. 10.55 kJ ,
d. 10.55 kJ 5.6 a. Q12 W12 436.1 kJ , b. W12 max 188.15 kJ , 5.8 a. 1630 kJ , b. dest 3370 kJ ,
5.10 a. p2 4954 kPa , b. W12 180.69 kJ, Q12 185.15 kJ , c. balloon 173.94 kJ , 5.14 S 1.91 kJ/K ,
o
5.16 a. p2 0.7 MPa, T2 600 C , b. W12 198.8 kJ/kg, Q12 897.5 kJ/kg , c. Wu 169.83 kJ/kg ,
1 T T 2
d. W12 max 313.3 kJ/kg , e. 304.6 kJ/kg , f. dest 114.5 kJ/kg , 5.18 dest mcTo ln 1 2 ,
2 4T1T2
5.20 the useable work, W12 77 J , 5.22 air and tire friction, dest 100 W , 5.24 dest 48.7 kJ , 5.26 a. irreversible,
3
b. impossible, c. impossible, d. irreversible, 5.28 a. TL 234 K , TH 585 K , b. p1 7.1 bar, v1 0.236 m /kg ,
c. W23 253.9 kJ/kg, Q 23 0, W34 Q34 15.78 kJ/kg, W41 251.43 kJ/kg, Q 41 0, 5.30 rev ,
5.34 dest 2382 kJ/min , 5.36 a. T 4.28 K , b. Wnet 0.608 kJ , c. Ek loss 41.48 kJ/kg , d. n 384 rpm ,
5.38 steam 308.69 kW, air 134.5 kW , 5.40 a. 1 398 kW, 2 226 kW , 3 152.73 kW
o
b. dest 19.27 kW , 5.42 dest 0.000875m 3To claim is possible, 5.44 a. T2 50 C , b. dest 81.45 kJ/kg ,
5.50 Wmin 24.17 kW , b. Wactual 33.57 kW , 5.52 Wnet 656.53 kJ/kg , 5.54 dest 104.1 kJ/kg , 5.56 a. n 9 ,
b. dest 98.65 kJ/kg , 5.58 a. 2 41.47 kJ , b. Wrev 11.08 kJ , c. dest 9 kJ , d. x 49.4% , 5.60 a. x 8% ,
5.64 a. m2 / m1 0.78 , b. x 50.4% , 5.66 a. R134 a 0.561 kW, Air 0.17 kW , b. x 30.5%
,
5.68 a. COP 4.43 , b. Wel 1.75 kW , c. dest 9.17 kWh
APPENDİCES 521
Chapter 6
6.2 a. Q12 10.98kJ , W12 6kJ b. TR 120.2 C c. W12 9.64kJ , 6.4 1.85kJ/K, 6.6 a.Heat loss, b.Reversible process,
o
c. Irreversible process, d.Differential change on reversible process, e.Reversible cycle, 6.8 a. s 0.053kJ / kgK ,
b.No, it isn’t, 6.10 Q12 W12 7.57 kJ , 6.12 S 0.212kJ / K , 6.14 a. S gen 0.0766kJ / K , b. Wmin 8.1kJ ,
6.16 a. S gen 0.004132 J / K , b. S gen 0.203W / K , 6.20 a. 60o C, 6.22 Q12 13.93kJ , W12 3.87 kJ ,
Q23 0 , W23 133.54kJ , 6.24 S gen 1.48kJ / K 0 This process is possible. 6.26 a. s2 s1 0 and is an adiabatic
process, b.not possible. 6.28 a.is not an adiabatic compressor, b. Q 43.52kW not possible, 6.30 p1 10 bar ,
6.32 a. Vmax 762.84m / s , b. Va 731.69m / s , c. S 0 isentropic flow , S 4.83kW / K , 6.34 a. Wc 21.75kW ,
b. T2 301K , 6.36 a. T2 295 K , d 0.96 , b. p2 1.366 bar , 6.38 a. Q 440.05kW , b. S gen 0.144kW / K ,
c. S gen 0 , Ts , max 460.4 K , 6.40 a. Wnet 20.4 MW , b. S gen 8.35kW / K , 6.42 not suitable,
o o
6.44 Q 264.55kW , b. T2 140.6 C , c. S gen 0.159kW / K , 6.46 a. S gen 0.159kW / K , b. T2 77.27 C ,
c. 0.82 , 1.0 , 6.48 a. m w 5.29 kg/s , b.36.5%, c.in water, 39%, in milk 36%, 6.50 a.intermediate pressure
p 436kPa , b. Wc 371.2kW , c. m w 4.44 kg/s , e.464kW, 5.55 kg/s, 6.54 0.057W, 4.56 p / po 0.718 ,
3 3
6.58 291.9K, 85.05kPa, 6.60 a. 1 4.73 kg/m , V1 89.15 m/s , m 42.17 kg/s , b. 2 1.17 kg/m ,
b. m 9.13 kg/s , 6.66 M 1.71 , b. 0.917 , c. s 0.0479kJ / kgK , 6.70 a.carbon dioxide T2 360.4 K ,
b.air T2 578.2 K , c. mco2 2.33 kg , d. S a 0 , S CO2 0.368 kJ/K , e.is not reversible, 6.72 a.1957.5kg,
Chapter 7
7.2 a. M m 37.6kg / kmol b. xN 2 29.7%, xCO2 70.3% c. Vt 2.57 m , 7.4 Vt 258m , 7.6 T 309 K , p 125.6kPa ,
3 3
b. S gen 23.051kJ / K , c. S gen 0 , 7.14 a. S gen 30.1kJ / K , b. dest 9030kJ , c. dest 12825kJ ,
S gen 0.349kJ / K , 7.18 a. T 300 K , b. H 2 1.39m , c. W12 4.56kJ , d. S gen 0.0521kJ / K , e. dest 15.64kJ ,
7.20 a. p 3398kPa , 7.22 W12 2.61kJ , Q12 0.946kJ , 7.24 a. Te 1251.8 K , b. S gen 1.159kW / K ,
7.26 a. T2 202 K , V2 50m / s , b. dest 945.47 kW , 7.28 a. W 487.7 kW , b. W 487.7 kW no appeciable change,
o o
7.30 Q 42.29kW , 7.32 a. W 71.25kW , b. S gen 0.013kW / K , 7.34 T2 146 C , 7.36 T f 2 C ,
7.38 3 g / kg air , h 42kJ / kg air , 7.40 p 120.3kPa , 7.44 a. DPT 49.5o C , b. t 156 min , 7.46 a.Q 63.39kW ,
o
b. m f 0.021kg / s , c. m r 0.7 kg / s , 7.48 a. m a 0.2743kg / s , b. Q 11.527 kW , 7.50 a. T2 25 C , b. Q 7.3kW ,
o o
c. Q 8.28kW , d. T5 17 C , e. T6 19.5 C , 6 70% , 7.54 a. m a 18.95kg / s , b. m w, make up 1739.6kg / h ,
o
7.58 a. Ts 71 C , b. For increased concentration, the saturation temperation increases at the same pressure,
c. ms 9kg , d. Qsupplied 4170.7 kJ , Q removed 3500.7 kJ , e. Qs >Q r , 7.60 p f 150kPa , 7.62 a. p2 107.7 kPa ,
b. mw 24.8kg
Chapter 8
8.2 a. 90o b. 4 power strokes/rev, 66 power strokes/s , 8.4 a. T3 1544 K , p3 4220kPa , b. T3 770 K , p3 256.65kPa ,
o
b. 55.2% , 8.8 a. T2 16.7 C , b. T2 105.5 Nm , c. pm 265kPa , 8.10 a. 19.8g ,
b. T2 745 K , p2 28.28bar , T3 1650 K , p3 62.6bar , T4 805 K , p4 3.39bar , 8.12 a. pm 8571kPa ,
b. 47.1% , 8.14 a. wnet 515.74kJ / kg , b. p m 644.7 kPa , c. 59.3% , d. 81.8% , 8.16 a. T3 2200 K ,
8.32 a. T2 566 K , T5 658 K , b. Q i 101.44kW , c. Wnet 37.64kW , d. 37% , 8.34 a. wt1 wt 2 571.4kJ / kg ,
b. wc 359.61kJ / kg , c. qi1 855.6kJ / kg , qi 2 471.4kJ / kg, d. w% 42.4% , 8.36 a. rbw 0.60, wnet 214.5kJ / kg ,
b. m 46.62kg / s , c. 33% , 8.38 a. p4 604kPa , b. V 1097 m / s , 8.40 V=655.7m/s before the afterburner,
8.42 a. w12 q12 -198.25kJ / kg , w23 0.0, q23 646.2kJ / kg , w34 q34 793.01kJ / kg
w41 0.0, q41 646.2kJ / kg , b. wnet 594.76kJ / kg , 41.3% , 8.44 a. Wnet 7846.7 kW , b. 32% ,
8.54 a. y 0.087, b. wnet 695kJ / kg , c. 25.8% , 8.56 a. qi 2936kJ / kg without FWH, qi 2266kJ / kg with FWH,
Chapter 9
9.2 7.74 ton 9.4 a. Wmin 4.65kW , b. Wc 2.58kW , c. power needed for refrigeration unit, Wmin 4.65kW ,
9.12 a. R22, qev 136.5kJ / kg , wc 29.8kJ / kg , 82.4% , b. R404, qev 80.82kJ / kg , wc 22.38kJ / kg ,
64.8% , 9.14 a. m 1 74.08kg / s , m 3 130.58kg / s , b. Wc 6172kW , c. COP 1.82 , 9.16 a. h1 245kJ / kg ,
b. Wc 63.8kW , c. m w 4.3kg / s , d. COP 1.82, 9.18 a. y13 0.153, y14 0.094, b. m 1 0.62kg / s , m 3 0.732kg / s ,
524 THERMODYNAMICS
Wc 2 12.94kW , Wc3 7.03kW , e. Q con 139.62kW , f. COP 2.48 , 9.20 a. Wc 22kW , b COP 1.918 ,
.
c. Wc 24.3kW , d. COP 1.73 , 9.22 a. v 80% , b. vd 75% , c. m 0.5kg / s , d. Q ev 13.67ton , e. c 90% ,
f. T2 100 C , 9.24 a. Tcon 32 C , COP 4.16 , b. Tcon 40 C , COP 3.46 , 9.26. Wc 46kW , 9.28 a. D 1.37 m ,
o o o
b. W 7.2mm , 9.30 a. Tsh 2 K , b. Tsh 3K , 9.32 a. m 0.039kg / s, psp 43kPa , b. psp 11.1bar ,
2
b. m r 0.512kg / s , c. m w 2.39kg / s , d. U o 1027W / m K , e. L 2.44m , 9.40 a. m r 0.947 kg / s ,
b. Va1 671.5m / min , c. L 1.084m , 9.42 a. R13 , b. R 23 , c. R 744 , d. R 718 , e. R31 , 9.44 a. Wc 11kW ,
3
o
b. COPhp 4.55, 26.2% , c. v 94.1% , d. n 461 rpm , 9.46 a. Qhp (kJ / h) 42750 1525To ( C ) ,
o 11.875 0.423To o
b. Whp (kW ) 4.65 0.075To ( C ) , c. COPhp , d. To 23 C ,
4.65 0.075To
9.48 a. COPw 8.81 , COPa 6.24 b. m w 49.63kg / h , c. Wc 98kWh , 9.50 COP 0.868 , 9.52 Q ev 165.85ton ,
9.54 a. Q ev 3.33ton , b. Q con 12.39kW , Qgen 16kW Q abs 15.32kW c. Q hx 3.06kW , 0.44
d. W p 0.2Watt , e. COP 0.731 .
APPENDİCES 525
a F F F F T F T F F
b F F T F F F F T T
c F T F F F T F F T
d F F F T T T T T T
e T T T T T T F F T
f F T T F T F F F T
g T F T T F T F F F
h F F F T T F T T T
i T F T F F F T T F
j F T F T F T T F F
k T T F F T T T T T
l T F F F F T F T F
m F F F T T T T T T
n T T T F T T T T T
o T T T F T F F T F
p F T T F T T T F T
q F F F T T F F T
r T T T T F F T T
s T F F F T T F T
t F F T F F F F
u T F F F T T T
v F F F T T T F
w T T T T F T
x T F T
y T
z T
526 THERMODYNAMICS
1 c c c c c d a a a
2 a c c b b c d d d
3 d b b a a a b b c
4 d a b d c b c c d
5 a b d b d a c b d
6 c d c a d a c d b
7 a a a a c b b c c
8 d a c b d c a c c
9 a b a c b c c d b
10 c d c a d a b d c
11 d d b b b c a
12 d c c c d b b
13 a c b b
14 b d d b
15 b