Anis Suhaila Shuib (PhD), AMIChemE,CIEM

Email: anissuhaila.shuib@taylors.edu.my
Office: Block C 9-16
YOUR JOURNEY

2
YOUR JOURNEY

3
Why chemical engineers need to learn
‘Thermodynamics’?

‘Thermodynamics’ ~ The Move of The

Energy?
 CETS TIME TABLE

 Lecture : Friday, 10 to 12 pm (E7.17)

 Tutorial : Tuesday, 4 to 6 pm (D8.15)
 Laboratory experiment: Monday, 2 – 6pm (EG.02)

 Simulation Lab: Week 11 to W14(UNISIM at computer lab C7.04 )

Chemical Eng. Thermodynamics & Simulation - CHE60303

8am 9am 10am 11am 12pm 1pm 2pm 3pm 4pm 5pm 6pm
CETS LAB-13
Mon
EG.02 (Pro & Reactions Lab)
CETS TUTORIAL - 13
Tue
D8.15 /wk 12 C7.04

Wed

Thu

CETS LECTURE - 19
Fri
E7.17 / WK 11 C7.04
LEARNING OUTCOMES (LO)

On completion of this module, students will be able to:

LO1 Solve ideal and real fluid systems using property

relations of thermodynamics.

LO2 Evaluate the effects of reaction conditions on

equilibrium constant of chemical process.

LO3 Solve complex chemical engineering challenges

using simulation tools.
6
 COURSE OUTLINE

Week Topic Topic Outcomes (TO) Remark

Chemical Engineering The basic laws of thermodynamics, Application of
Thermodynamics: Thermodynamic properties and equations.
1
Introduction

Volumetric Properties PVT behaviour of Pure Substances, Equation of State Ideal

2 of Pure Fluids gas equation, Viral Equation and Generic Cubic Equation.

Thermodynamic Property relations for homogeneous phases, Generalized LABORATORY

3
Properties of Fluids Correlation and Thermodynamic Diagrams EXPERIMENTS –
Vapour Liquid The Nature of Equilibrium, The Phase Rule, VLE 10%
4 Equilibria (VLE) I calculation by Ideal gas and Ideal solution (simple model),
Modified Raoult’s Law.
Vapour Liquid Determination of azeotrope, Calculation of P, V, T and
5 Equilibria (VLE) II composition of Flash column.

Solution Fundamental Property Relation (FPR), The Chemical

6 Thermodynamics: Potential and Phase Equilibria, Partial Properties, Ideal Gas
Theory mixture, Ideal solution, Fugacity and Fugacity coefficient.
7 TEST – 15% 7
 COURSE OUTLINE

Liquid Phase Properties from VLE data, Models

Solution for the Excess Gibbs Energy. Property Changes of LABORATORY
8 Thermodynamics: Mixing, Heat Effects of Mixing Processes. EXPERIMENTS
Application (continue)

The Reaction Coordinate, Application of

Chemical Reaction
Equilibrium Criteria to Chemical Reactions, The
9 Equilibria
Standard Gibbs Energy Change and the
Equilibrium Constant
Effect of Temperature on the Equilibrium
Chemical Reaction Constant, Evaluation of Equilibrium Constants,
10
Equilibria II Relation of Equilibrium Constants to
Composition and Equilibrium Conversions.
Gamma/ Phi Formulation of VLE, Relationship of
Gamma/Phi Formulation with Raoult’s Law,
11 Phase equilibrium Determination of Phi through Viral Coefficients, (e-learning)
Dew point and bubble point calculations, Flash
calculations.
FINAL EXAM- 60%
8
COURSE OUTLINE

Computer Simulation
12 The Onion Model
Layer 1: Reactor –The Heart of a Process
Computer Simulation
The Onion Model
13
Layer 2: Separation and Recycle Systems The Onion Model ASSIGNMENT15%

Computer Simulation
The Onion Model
14
Layer 3: Heat Exchanger Network
New Component Add-in

9
 MID-TERM TEST (week 7) 15%
ASSIGNMENT (week 13) 15%
LAB REPORTS 10%
FINAL EXAM 60%

*Formula Booklet- In lecture, tutorial, test and exam

 MAIN REFERENCES

1. Smith, J. M., Van Ness, H.C. and Abbott, M.M.,

"Introduction to Chemical Engineering
Thermodynamics", McGraw Hill, New York, 7th
Edition, 2005.
2. Felder, R. and Rousseau, R. W., “Elementary
Principles of Chemical Processes”, JohnWiley, New
York, 3th Edition, 2005.
3. Koretsky, M.D., “Engineering and Chemical
Thermodynamics”, John Wiley, 2nd Edition, 2012.
4. Elliott, J.R., Lira, C.T., “Introductory Chemical
Engineering Thermodynamics”, Pearson, 2nd
Edition, 2012.
30/08/2018 11
 1) Ideal gas law 2) Vapor liquid equilibrium
1. Lab report due date is 2 weeks after the completion of lab practical.

2. Late submission (lab report or assignment) after the deadline (which may have been
extended) shall have the percentage grade assigned to the work on face value
reduced by 10% for the first day and 5% for each subsequent day late. A weekend
counts as 1 day.
=> Late 1 day, deduct 10%, 2nd day 5%, … 5th day 5%, and 6th day onwards = zero mark.
(maximum period of 5 days ,at which time it will be assigned zero mark)
REVISION
 Conditions in
which occur no
∆Q = 0 changes

Glossary
Chapter 0
Introduction to Chemical
Engineering
Thermodynamics

15
Closed system
x
Mass flow

boundary

Mass flow

Open system
 Energy is conserved
- cannot be created
or destroyed

Energy has quality as well as

quantity - actual processes
occur in the direction of
decreasing quality of energy
 Energy is conserved
- cannot be created
or destroyed

dU = dQ + dW
W = -PdV
Definition of enthalpy

H = U + PV
 Energy has quality as well as
quantity - actual processes
occur in the direction of
decreasing quality of energy

Q = TdS

Definition of
Helmholtz energy A = U - TS
Definition of G = H - TS
Gibbs energy
 Energy is conserved
- cannot be created
Closed system
x
Mass flow
or destroyed
boundary

Energy has quality as well as

quantity - actual processes Mass flow
occur in the direction of
decreasing quality of energy Open system

dU = dQ + dW
Q = TdS
W = -PdV
Definition of enthalpy
H = U + PV
Definition of
Helmholtz energy A = U - TS
Definition of Gibbs energyG = H - TS
 E.g., mass, volume,
entropy, Gibbs
energy

E.g., hardness,
pressure, temperature,
density
SUMMARY 1
 Energy is conserved
- cannot be created
Closed system
x
Mass flow
or destroyed
boundary

Energy has quality as well as

quantity - actual processes Mass flow
occur in the direction of
decreasing quality of energy Open system

dU = dQ + dW
Q = TdS
W = -PdV E.g., mass, volume,
entropy, Gibbs
Definition of enthalpy energy
H = U + PV
Definition of
Helmholtz energy A = U - TS
Definition of Gibbs energyG = H - TS
E.g., hardness,
pressure, temperature,
density
 REPLACEMENT CLASSES

1. Public Holiday on Friday 31st August

Date: 3nd September 2018 (Monday)
Time: 2.30pm
Venue: To be announced

2. Public Holiday on Tuesday 11th Sept

Date: 13th September 2018 (Thursday)
Time: 12.00pm
Venue: To be announced
SIGN-IN ATTENDANCE
HAVE A GOOD MERDEKA DAY