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Parameter, °C Value
Room Temperature
Atmospheric Pressure
Corrected Barometic
Pressure, mmHg
Table 4.2. Gas constants for the Van der Waals EOS for Acetone and Methanol.
a, L2* bar*mol-2 b, L* mol-1
Acetone 16.02 0.1124
Methanol 9.472 0.06584
Reference: Dean, John A. (1999). Lange’s Handbook of Chemistry. 15th ed. USA: McGraw- Hill,Inc. p. 2609.
Table 4.5 Determining the change in the mercury levels of the manometer for acetone.
Temperature, Trial 1 Trial 2
o
C h1,mm h2,mm ∆h,mm h1,mm h2,mm ∆h,mm
36.1
38.1
40.1
42.1
44.1
46.1
48.1
50.1
52.1
54.1
56.1
Table 4.6 Determining the change in the mercury levels of the manometer for methanol.
Temperature, Trial 1 Trial 2
o
C h1,mm h2,mm ∆h,mm h1,mm h2,mm ∆h,mm
44.7
46.7
48.7
50.7
52.7
54.7
56.7
58.7
60.7
62.7
64.7
Table 4.7 Determining the ΔHvap of acetone using the corrected mercury manometer reading and gas
pressure for increasing Temperature mode.
Temperature 1/T (1/K) Trial 1 Trial 2
(K) hcorrected Pgas lnP hcorrected Pgas lnP
309.25
311.25
313.25
315.25
317.25
319.25
321.25
323.25
325.25
327.25
329.25
ΔHvap
- 𝑅
ΔHvap
Table 4.8 Determining the ΔHvap of acetone using the corrected mercury manometer reading and gas
pressure for decreasing Temperature mode.
Temperature 1/T (1/K) Trial 1 Trial 2
(K) hcorrected Pgas lnP hcorrected Pgas lnP
329.25
327.25
325.25
323.25
321.25
319.25
317.25
315.25
313.25
311.25
309.25
ΔHvap
- 𝑅
ΔHvap
Table 4.9 Determining the ΔHvap of methanol using the corrected mercury manometer reading and gas
pressure for increasing Temperature mode.
Temperature 1/T (1/K) Trial 1 Trial 2
(K) hcorrected Pgas lnP hcorrected Pgas lnP
317.85
319.85
321.85
323.85
325.85
327.85
329.85
331.85
333.85
335.85
337.85
ΔHvap
- 𝑅
ΔHvap
Table 4.10 Determining the ΔHvap of methanol using the corrected mercury manometer reading and gas
pressure for decreasing Temperature mode.
Temperature 1/T (1/K) Trial 1 Trial 2
(K) hcorrected Pgas lnP hcorrected Pgas lnP
337.85
335.85
333.85
331.85
329.85
327.85
325.85
323.85
321.85
319.85
317.85
ΔHvap
- 𝑅
ΔHvap
Table 4.11 Percent Error between the Experimental and Theoretical Molar Heat of Vaporization for
Acetone and Methanol.
Table 4.13. Recalculation of the Molar Heat of Vaporization for Acetone and Methanol with the
Compressibility Factor, Z included.