Escolar Documentos
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Cultura Documentos
11, 2016
DOI: 10.1007/s11837-016-2111-y
Ó 2016 The Minerals, Metals & Materials Society
Fig. 3. Quantitative flow sheet of the alkali roasting-smelting-leaching (AR-S-L) and alkali roasting-smelting-quenching-leaching (AR-S-Q-L)
processes.
COST ASPECTS
Indicative cost aspects of the AR-S-Q-L process
are shown in Table I, including the estimated costs
of consumed reagents, energy and values of the
generated products. Similar cost analyses for the Fig. 4. Quantitative flow sheet of the sulfation-roasting-leaching (Su-
other processes (L, S-L, AR-S-L and Su-R-L) were R-L) process.
also performed. The consumption of bauxite residue
is represented as a benefit, and therefore as a
positive value, as the material is a liability to the taken from Alibaba.19 The price of acids and other
company.1 REE prices (as on 23 February 2016) chemicals (as on 23 February 2016) used in the
were taken from the mineral prices website.18 calculation was taken from Alibaba.19 Titanium
Prices that are not available on this website are dioxide and alumina prices were taken from USGS
Comparative Analysis of Processes for Recovery of Rare Earths from Bauxite Residue 2961
Minerals.20,21 The total REEs value except scan- Information Administration.22,23 As mentioned ear-
dium is the sum of the amounts recovered multi- lier, the residue generated in the process can be
plied by their respective price. For the Sc2O3 considered for application in building materials.
price,two values were considered: (1) the market However, it should be noted that the costs of
price (as on 23 February 2016), and (2) half of the smelting, alkali roasting, sulfation, roasting, fur-
market price. This was done to evaluate the ther recovery processes (e.g., solvent extraction, ion
decrease in margin if there is a price drop for exchange), labor and equipment were not consid-
Sc2O3 due to the increase in production from the ered in these preliminary calculations.
proposed plants. Hence, two margins were calcu- Different scenarios were also considered for cost
lated. Electrical energy was considered for smelting analysis: (1) recovery of only base metals (BM), (2)
and natural gas was considered for roasting pro- recovery of only scandium, (3) recovery of scandium
cesses. Natural gas and electricity prices (as on 10 and other rare earths (REEs), and (4) recovery of
May 2016) were taken from the US Energy scandium, other rare earths and base metals
(REEs + BM). These scenarios are shown in Fig. 6.
Scenario 4 is not simply the sum of scenarios 1 and 3
as the titanium can also be recovered from the leach
solutions together with REEs. It is evident from this
figure that the recovery of scandium is very impor-
tant. It can also be seen that only the recovery of
base metals from bauxite residue is not a good
option. However, the combined recovery of base
metals and scandium increases the margin. Recov-
ery of REEs other than scandium does not have
much impact on the margins.
Cost analysis of direct leaching shows a very low
margin. Furthermore, large volumes of effluents are
generated in this process. The margin can be
improved by iron recovery via smelting followed by
slag leaching. However, large volumes of effluents
would be still generated in such an improved
process. Therefore, alumina recovery prior to smelt-
ing can further increase the margin. Finally, the
process can be further improved by quenching
before slag leaching as it helps in dissolving tita-
Fig. 5. Energy consumption of different processes. nium and REEs.
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