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Article history: This study evaluates the energy use, exergy demand and the main hot spots of two municipal solid waste
Received 23 March 2018 (MSW) management scenarios including landfilling (100% landfilling) and composting-landfilling (48%
Received in revised form composting, 50.5% landfilling, 1.5% recycling), available in Rasht, Iran. The functional unit was defined as
9 July 2018
100 t MSW. The system boundaries encompassed activities ranging from MSW collection in the city up to
Accepted 29 August 2018
Available online 29 August 2018
MSW burial in the landfill and delivery of compost and recyclable materials to the market. For quanti-
fying the environmental impacts, 11 impact categories were analyzed using life cycle assessment
methodology, and the outcomes of characterization and normalization of impact categories were
Keywords:
Energy
interpreted. The results showed that total energy consumption for composting-landfilling was greater
Life cycle assessment than that of landfilling (22.5 vs. 17.5 GJ/100tMSW). Composting-landfilling scenario showed avoided
Composting environmental emissions in the forms of abiotic depletion, terrestrial ecotoxicity and freshwater aquatic
Landfilling ecotoxicity associated with the production of compost; moreover, global warming potential, human
MSW toxicity, marine aquatic ecotoxicity, photochemical oxidation and acidification of landfilling scenario
were found to be higher than those of composting-landfilling scenario by 495%, 239%, 49%, 679% and
669%, respectively. On the other hand, composting-landfilling scenario had higher fossil fuels abiotic
depletion, ozone layer depletion and eutrophication potential. Transportation accounted for the highest
contribution to overall environmental emissions in both of the investigated scenarios, demonstrating the
importance of decreasing environmental burdens during this step. Overall, compared to landfilling
scenario, the lower environmental burdens associated with composting-landfilling scenario make it
more environmentally attractive.
© 2018 Elsevier Ltd. All rights reserved.
https://doi.org/10.1016/j.jclepro.2018.08.307
0959-6526/© 2018 Elsevier Ltd. All rights reserved.
L. Behrooznia et al. / Journal of Cleaner Production 203 (2018) 1028e1038 1029
management of MSW (Jara-Samaniego et al., 2017). Composting the management scenarios to the input parameters. The outcomes of
organic part of MSW has several advantages including economic this research are useful for decision makers to develop more sus-
benefits, improving soil properties through compost application, tainable MSW management systems in the region and other places
and avoiding some environmental burdens that would otherwise in the world with similar climatic and lifestyle conditions.
emitted from waste (Bernstad et al., 2016).
System analysis tools are useful techniques to assess the 2. Materials and methods
promising waste management strategies (Seadon, 2010). Life cycle
thinking is considered as a key concept for the development of This section describes the methodology for energy, environ-
more sustainable systems. Life Cycle Assessment (LCA) can be used mental and exergy assessments of available MSW management
for the analysis of environmental emissions related to a processes, systems in Rasht, Iran. The overall framework for this methodo-
products, or services, by identifying the physical inputs, energy logical approach follows four steps including the goal and scope
consumption, and associated environmental hot spots. LCA has definition, data collection or inventory analysis, assessment of the
been used in the production and supply chains of products (Tassielli indicators, and interpretation of the results. The inputs, outputs and
et al., 2018). interactions between these four steps are illustrated in Fig. 1.
Comparison of alternative MSW management technologies
from the environmental life cycle perspective has been the subject
2.1. Case study region
of several studies; Ayodele et al. (2017) used LCA methodology for
environmental assessment of MSW based power generation sys-
This study was conducted in Rasht city, Guilan, Iran. This city is a
tems in 12 cities of Nigeria. They provided comparative analyses of
touristic place located in the geographical coordinates of 49 3501900
four MSW management scenarios including landfill without energy
E longitude and 37160 3300 N latitude in the north of Iran and in the
recovery, landfill with energy recovery system, combination of
south of Caspian Sea. Rasht city, with around 640,000 inhabitants,
incineration and anaerobic digestion, and combination of inciner-
is the most populated city of the north of Iran, and it has a moderate
ation and landfill with energy recovery system. Then the potential
climate with an average moisture content of 81.2%. With the
energy generation and associated environmental emissions,
highest rainfall level in Iran, this city is known as the wettest city in
including global warming and acidification for these scenarios,
the country. The location of the study area is given in Fig. 2.
were highlighted. In another study Milutinovic et al. (2017) applied
The MSW management systems of Rasht city include the com-
LCA and multi-criteria analysis tools to compare different scenarios
posting and landfilling sites located in southwest of the city on
for the MSW management. Also, Rajaeifar et al. (2015) conducted a
Tehran-Rasht road. The average distances of the composting and
study to compare five different MSW management scenarios in
landfilling sites from the city are 10 km and 30 km, respectively. The
Tehran, Iran. They concluded that combination of anaerobic
Rasht composting site was established in 2005 with the MSW ca-
digestion and incineration is the most environment-friendly sce-
pacity of 250 t/day. In 2014 the daily capacity of this site increased
nario. Alavi Moghadam et al. (2009) investigated the present situ-
to 400 t/day (RWMO, 2017). MSW from Rasht city and surrounded
ation of MSW management in the north of Iran and they reported
villages is delivered to these composting and landfilling sites.
that the main challenges of MSW management in this region
According to the data provided by the Rasht Waste Management
include lack of resources, infrastructure, suitable planning, leader-
Organization (RWMO, 2017), the daily per capita of waste produc-
ship, and public awareness. However, they did not provide in-depth
tion in this region is about 931 g. The physical composition of MSW
analysis on energy consumption or quantitative environmental
consequences of MSW management in this region.
Overall, attempts have been made to investigate the environ-
mental emissions of MSW management and most of them have
highlighted the need for analyzing MSW management scenarios by
taking into account the effects of local conditions, because the
lifestyle, climatic conditions and MSW physical composition vary
from place to place. Reviewing the literature reveals that there is no
study to analyze the available MSW management systems in the
north of Iran and hence this is the focus of our research for the first
time; moreover, comprehensive study of alternative MSW man-
agement scenarios, from the integrated energy, exergy and envi-
ronmental perspectives, is useful for appropriate decision making
on designing the sustainable agroecosystem. So, the main objective
of the present study is to evaluate the sustainability of available
MSW management systems in the north of Iran. To accomplish this
main objective, the following four specific objectives are identified:
1) investigate energy profiles of available MSW management sce-
narios in the case study region; 2) analyze exergy demand and the
main hot spots of MSW management processes via the LCA
methodology; 3) analyze the sensitivity of environmental impact
categories to the individual independent parameters; and 4)
identify potential options for improving the sustainability of MSW
management systems in the north of Iran based on the results of
energy analysis, LCA and sensitivity analysis. The novelty of this
research is not application of LCA, but performing comprehensive
analyses of MSW management scenarios from energy, exergy and
environmental perspectives. Moreover, this study for the first time Fig. 1. General framework for energy, exergy and environmental assessments of MSW
analyzes the sensitivity of environmental emissions of MSW management systems.
1030 L. Behrooznia et al. / Journal of Cleaner Production 203 (2018) 1028e1038
in Rasht is presented in Fig. 3. As it is seen, organic materials part (Fig. 4). Defining these system boundaries allows better under-
has the main contribution (64.1%) to total MSW in this region standing of the MSW management scenarios with more
(RWMO, 2017). This composition of MSW makes composting the environment-friendly strategies by considering the treatment of
appropriate strategy for the treatment of MSW in this region. the same amount of waste.
In goal and scope definition, the system boundaries are identi- Currently, the total production of MSW in Rasht and surrounded
fied and accordingly the functional unit is defined. The goals are villages is around 750 tons per day (RWMO, 2017). Two available
highlighting the energy consumption, identifying the main hot scenarios of MSW management in Rasht include: 1) composting-
spots, and quantifying exergy demand of available MSW manage- landfilling (CL), and 2) landfilling (L). In L scenario the MSW is
ment in the north of Iran. Accordingly, the functional unit was totally buried in the landfill without any separation. The physical
defined as 100 t MSW, indicating that the energy consumption, composition of MSW in this scenario is the same as that of Fig. 3,
environmental emissions and exergy demand are calculated based and it contains organic, inert and recyclable components. There is
on treatment of 100 t MSW. The system boundaries included the no energy recovery nor leachate treatment in the available land-
production of inputs and MSW generation in the background pro- filling system of Rasht. Currently, 350 t/day MSW follows this sce-
cesses, followed by the foreground processes of MSW trans- nario and it is directly transported from the city to the landfilling
portation, separation, composting until delivery of coarse and fine site by the distance of 30 km. Landfilling process includes geolog-
composts to the market, as well as landfilling of inert materials and ical modifications, waste handling and placement, compaction,
delivery of recyclable materials to the market (Fig. 4). In addition, shredding, providing coverage materials, and tracking and control
the direct emissions resulting from transportation, composting and operations. On the other hand, CL scenario begins with trans-
landfilling processes, as well as the indirect emissions from the portation and consequently centralized separation at the com-
production process of diesel fuel, lubricant (oil), electricity, ma- posting site. Currently, 400 t/day MSW follows this scenario and
chinery, and pesticide were included in the system boundaries MSW is transported from the city to the composting site by the
distance of 10 km. The physical composition of MSW entering the
separation process is the same as that of Fig. 3. During the
centralized separation 1.5% (6 t/day) is separated as recyclable
materials, i.e. metals, glass, plastic, PET (PolyEthylene Ter-
ephatalate), and it is delivered to the market after transportation by
10 km; 50.5% (202 t/day) is separated as inert materials and it is
delivered to the landfill after transportation using trucks by 20 km;
and the remaining of 48% (192 t/day) is separated as organic ma-
terials and transferred to the decomposition hall for composting
(Fig. 4). The composting process includes handling, sizing, mixing,
aeration, biological decomposition and control operations (Fig. 4).
Fig. 4. System boundaries of MSW composting and landfilling systems in Rasht, Iran.
machinery and equipment, as well as amounts of electricity, natural Specific energy (GJ t1) ¼ Input energy (GJ) / Organic fertilizer (t)(2)
gas, diesel fuel and lubricant, labor, pesticide, and other materials
needed for the processing of MSW during the transportation and
handling, separation, landfilling and composting operations. The 2.6. Environmental assessment
data of products included compost production yield and amounts
of recyclable materials. After collecting the primary data, the LCA is a powerful and popular tool in the world to assess the
amounts of indirect and direct emissions were estimated. Indirect environmental impacts of a product or system over its lifetime
emissions associated with the production of inputs during the (Liamsanguan and Gheewala, 2007). This methodology has already
background processes were estimated using LCA databases. Direct been applied in analyses of the waste landfilling, sorting plant and
emissions associated with combustion of diesel by machinery and incineration systems in Italy (Cherubini et al., 2009) and also for the
equipment were also estimated using LCA databases (Nemecek and comparison of waste management scenarios in India (Sharma and
Kagi, 2007). Direct emissions during the landfilling and composting Chandel, 2017).
processes were estimated by application of the existing tools and In quantifying the life cycle inventory of two scenarios, the
using the factors available in the literature. Further explanations are physical amounts of inputs as well as energy consumption and
provided in section 2.6. direct emissions were calculated based the functional unit. For
calculating the amount of machinery use, the depreciated weight of
machinery was estimated based on the weight of machine, eco-
nomic life time and operational time. Transportation is one of the
2.5. Energy analysis main contributors to total energy consumption and environmental
emissions in MSW management. In this study MSW transportation
Energy consumption in MSW management systems is an was estimated by multiplying the amount of transported MSW, in
important factor to assess the sustainability. Energy analysis for tons, by transportation distance, in km, and it was reported as t.km.
each of the scenarios was conducted by multiplying the amounts of The transportation distance in CL scenario was considered based on
physical inputs by their associated energy coefficients. Energy co- the distances of 10 km from the city to the composting site for
efficients are presented in Table 1. Diesel fuel, lubricant, natural gas, transporting total amount of MSW, 20 km from composting site to
electricity, pesticide, human labor and machinery were considered landfill for transporting inert materials, and 10 km from compost-
as inputs. The output in CL scenario was organic fertilizer, while in L ing site to the market for transporting the recyclable materials
scenario there was no output as there was no biogas collection (Fig. 4). Data of electricity consumption were taken by considering
system in current situation. that the combination of energy sources for electricity production in
For better analyzing the energy flow in CL scenario of MSW Iranian condition is 92% fossil fuels and 8% renewable energy
management, energy indicators for the functional unit of 1 t MSW sources. In CL scenario, diesel fuel was mainly used by on-site
were estimated using the following equations: machinery, i.e. loaders, trucks, windrower, bulldozer and shovel.
Direct emissions associated with diesel fuel combustion, from all of
Energy productivity (t GJ1) ¼ Organic fertilizer (t) / Input energy the steps of composting and waste disposal, were estimated based
(GJ) (1) on the Ecoinvent 2.2 database (Nemecek and Kagi, 2007) and the
1032 L. Behrooznia et al. / Journal of Cleaner Production 203 (2018) 1028e1038
Table 1
Energy equivalent of inputs and output in waste management systems.
A. Inputs
1) Human labor hr 1.96 103 Fathollahi et al., 2018
2) Diesel fuel L 47.8 103 Fathollahi et al., 2018
3) Transportation t.km 4.5 103 Tabatabaeefar et al., 2009
4) Electricity kWh 11.93 103 Mousavi-Avval et al., 2011
5) Lubricant L 42 103 Kitani, 1999
6) Pesticide kg 101.2 103 Mousavi-Avval et al., 2017
7) Machinery kg 62.7 103 Fathollahi et al., 2018
8) Natural gas m3 49.5 103 Kitani, 1999
B. Output
1) Organic fertilizer t 0.3 Mousavi-Avval et al., 2017
energy equivalent of diesel fuel as presented in Table 1. During the environmental emissions impact categories by percentile changes
landfilling process, the direct emissions to air were estimated using of the individual inputs. Sensitivity analyses were performed for
LandGem version 3.02 model (Alexander et al., 2005); the direct both of the investigated scenarios based on ±10% change on
emissions to water were calculated using the coefficients presented average levels of individual parameters. For analyzing the sensi-
by Erses Yay (2015); and the direct emissions to soil associated with tivity of each of the impact categories to parameter X, average value
use of chemicals (deltamethrin) were estimated using the LCA of individual parameter X was changed by ±10%, assuming that all
databases (Nemecek and Kagi, 2007). Similarly, during the com- of other factors remain constant at their average values, and then
posting process the direct emissions were estimated using the the variation of impact category was presented.
emission factors provided from the study conducted by the EPA
(2010). 3. Results and discussion
The next step in LCA, after quantifying the life cycle inventory, is
the life cycle impact assessment in which the data of physical inputs 3.1. Inventory analysis of MSW management scenarios
and direct emissions are converted to their equivalent emissions.
This step was conducted using CML-IA baseline V3.04/World 2000 The amounts of physical inputs, products and direct emissions
model available in SimaPro 8.3.0 software (Pre-Consultants, 2017). to air, water and soil in landfilling and composting-landfilling
Since this part of study is central in quantifying the different scenarios are presented in Table 2. As it is seen, labor use in CL
environmental impacts while comparing two MSW management scenario was considerably higher than that of L scenario. It was due
systems, the attributional modeling principle was chosen for this to higher use of human labor for separation of MSW in centralized
comparative LCA. This modeling principle has already been applied separation unit. Similarly, diesel fuel consumption in CL scenario
in LCA of MSW management systems (Ripa et al., 2017). The impact was higher than that of L scenario (141.53 vs. 33.66 L/100t MSW).
categories of this model include abiotic depletion potential (AD), Transportation in CL scenario was found to be 2078.85 t km/
abiotic depletion of fossil fuels (ADF), acidification potential (AC), 100tMSW, while it was calculated as 3140.24 t .km/100tMSW in L
eutrophication potential (EP), global warming potential (GWP), scenario; the difference was mainly due to higher distance of
terrestrial ecotoxicity potential (TE), ozone layer depletion poten- landfilling site compared to that of composting site from the city.
tial (OLD), human toxicity potential (HT), freshwater aquatic eco- The direct emissions of both of L and CL scenarios are presented in
toxicity potential (FE), marine aquatic ecotoxicity potential (ME) Table 2. For example, CH4 emissions during the landfilling
and photochemical oxidation potential (PO) (Guinee et al., 2001). (7185.87 kg/100tMSW) was considerably higher than CH4 emis-
sions during the composting-landfilling (913.74 kg/100 t MSW).
2.7. Exergy analysis
3.2. Energy analysis of MSW management scenarios
Exergy is known as maximum useful energy that should be
validated within the life cycle framework and should be achieved Energy conversion coefficients, shown in Table 1, were used to
when the system is compatible with the reference circumference. convert physical inputs to energy and the results are presented in
Cumulative exergy demand (CExD) is a quantitative index which Table 3. As it is seen, total energy consumption for CL scenario was
evaluates the quality of energy consumption and it contains also 22.54 GJ/100t MSW, while it was found to be 17.49 GJ/100t MSW for
the non-energetic materials. The CExD represents the sum of L scenario. Also, the results showed that energy consumptions from
exergy of all the natural sources required to produce a product and human labor, diesel fuel, electricity, lubricant, machinery, natural
it can be determined by the natural resources exergy quantity. gas, and water in CL scenario were higher than those of L scenario;
Exergy unit is known as Joule (Erses Yay, 2015). The concept of while transportation energy in L scenario was higher than that of CL
exergy was used for the resources existent in the equivalent data- scenario. On the other hand, energy amount of 0.9 GJ/100t MSW
base. Exergy analysis methods are based on life-cycle viewpoint associated with compost was produced in CL scenario, while there
and cradle-to-grave concept. Analysis of exergy demand is part of was no energy generation in L scenario.
LCA and it is based on the described methodology for the life cycle Contributions of energy sources to total energy consumption are
inventory analysis for quantifying the resources consumption presented in Fig. 5. The results revealed that transportation (80.8%),
(Dewulf et al., 2007). diesel fuel (9.2%) and machinery (8.7%) were the main contributors
to total energy consumption in L scenario. Similarly, in CL scenario
2.8. Sensitivity analysis the most of energy was consumed by transportation (41.5%), fol-
lowed by diesel fuel (30%), electricity (17.6%) and machinery (7.5%).
Finally, the sensitivities of each impact category to the individ- The contributions of pesticide, human labor, lubricant and water
ual inputs were analyzed to quantify the possible variations of were almost negligible in both of the scenarios. Considering these
L. Behrooznia et al. / Journal of Cleaner Production 203 (2018) 1028e1038 1033
Table 2 Table 3
Inventories of inputs, product and direct emissions of MSW management scenarios Energy inputs and output in MSW management scenarios (FU: 100 t MSW).
(FU: 100 t MSW).
Items MSW management scenarios
Items Unit MSW management
CL (GJ) L (GJ)
scenarios
A. Inputs
CL L
Human labor 0.26 0.03
MSW t 100 100 Diesel fuel 6.77 1.61
A. Inputs Transportation 9.35 14.13
Human labor hr 132.70 15.69 Electricity 3.98 e
Diesel fuel L 141.53 33.66 Oil 0.24 0.08
Transportation t.km 2078.85 3140.24 Pesticide 0.01 0.02
Electricity kWh 333.33 0.00 Machinery 1.69 1.52
Lubricant L 5.64 1.81 Gas 0.12 e
Pesticide kg 0.11 0.23 Water 0.12 0.10
Machinery kg 26.92 24.27 Total energy input 22.54 17.49
Natural gas m3 2.50 0.00 B. Output
Water L 122.50 96.75 Compost (Organic fertilizer) 0.9 e
Compost 3.00 e
B. Emissions to air
B.1. Emissions from fuel combustion
Carbon dioxide (CO2) a kg 503.99 119.87 electricity consumption in CL scenario is of high importance for
Sulfur dioxide (SO2) a kg 0.16 3.88 102 energy management.
Methane (CH4) a
kg 2.08 102 4.96 103 With considering the compost as the product of CL scenario, we
Benzenea kg 1.18 103 2.80 104
estimated some energy indicators and the results are presented in
Cadmium (Cd) a kg 1.62 106 3.85 107
Chromium (Cr) a kg 8.05 106 1.91 106 Table 4. It is evident that energy productivity was 3.33 t GJ1,
Copper (Cu) a kg 2.75 104 6.53 105 indicating that for consuming 1 GJ energy, 3.33 t compost materials
1.93 102 4.60 103 are produced. Specific energy of 0.3 GJ t1 indicates that for the
a
Dinitrogen monoxide (N2O) kg
Nickel (Ni) a
kg 1.13 105 2.69 106
production of 1 ton compost materials, 0.3 GJ energy is needed.
Zinc (Zn) a
kg 1.62 104 3.85 105
Benzo (a) pyrene a kg 4.84 106 1.15 106
Ammonia (NH3) a kg 3.23 103 7.68 104
3.3. Environmental analysis of MSW management scenarios
Selenium (Se) a kg 1.62 106 3.85 107
PAH (polycyclic hydrocarbons) a kg 5.31 104 1.26 104
Hydro carbons (HC, as NMVOC) a
kg 0.46 0.11 3.3.1. Characterization of LCA results
a
Nitrogen oxides (NOx) kg 7.17 1.71 The life cycle impact assessment was performed based on 11
a
Carbon monoxide (CO) kg 1.01 0.24 damage categories as summarized in Table 5. In analysis of envi-
Particulates (b2.5 mm) a kg 0.72 0.17
ronmental impacts of MSW management scenarios, two types of
B.2. CO2eq from labor b kg 92.89 10.98
B.3. Emissions from landfilling and composting impacts including gross impacts and net impacts were considered.
CH4 c,d kg 913.74 7185.87 The gross impacts refer to those emitted during the whole life cycle
CO2 d kg 10782.77 21737.24 in MSW management scenarios without considering positive
d
CO kg 0.50 3.90 environmental impacts of products; however, the net impacts refer
d
NMVOC kg 43.53 343.19
N2 d kg 0.52 4.10
to negative environmental emissions by subtracting the positive
N2O d kg 5.76 0.00 impacts associated with the products (Cherubini et al., 2009). In
HCL d kg 322.71 2544.18 LCA of L scenario there was no output, and therefore the positive
SO2 d kg 259.63 2046.88 environmental impacts were zero; however, in quantifying the
C. Emissions to water
environmental profile of CL scenario the compost product was
COD e
kg 2.17 102 1.71 101
BOD e kg 1.24 102 9.74 102 assumed to has positive environmental impacts as it was the
TKN e kg 1.65 105 1.30 104 outcome of this MSW management scenario; so, the impacts
AKM e kg 1.31 102 1.03 101 associated with compost product were subtracted from environ-
Top P e kg 2.14 105 1.69 104 mental emissions associated with the whole process; hence, the net
Top Cr e kg 6.52 106 5.14 105
Cr 6þ e
kg 2.89 106 2.28 105
environmental impacts of some of the impact categories were
Pb e
kg 2.65 106 2.09 105 found to be less than zero, which are in line with those of other
Fe 2þ e
kg 2.56 105 2.02 104 researches (Rajaeifar et al., 2015). As it is seen from Table 5, for the
Fe3þ e kg 1.53 108 1.21 107 functional unit of 100t MSW, the impacts of AD, FE and TE in L
Cu e 1.05 105 8.26 105
kg
scenario were 4.37 103 kg Sbeq, 1.56 102 kg 1,4-DBeq and
Zn e kg 7.91 106 6.24 105
D. Emissions to soil 2.17 kg 1,4-DBeq, respectively. CL scenario had avoided environ-
Deltamethrin f
kg 2.83 103 5.76 103 mental emission in the forms of AD, FE and TE. Avoided emissions
a
Emissions from fuel combustion by on-site machinery and equipment from
account for the substitution of compost synthetic fertilizer with
Ecoinvent 2.2 database (Nemecek and Kagi, 2007). nutrients (nitrogen N, phosphorus P and potassium K) recovered
b
Obtained from Ghaderpour et al. (2018). during the production of compost (organic fertilizer) as a useful
c
Methane from landfilling calculated based on LandGEM model (Alexander et al., output in this scenario (Parkes et al., 2015). Similar observations
2005).
d were reported by Abduli et al. (2011). The results also revealed that
Obtained from EPA (2010).
e
Obtained from Erses Yay (2015). GWP, HT, ME, PO, AC of L scenario were higher than those of CL
f
Obtained from Ecoinvent 2.2 database (Nemecek and Kagi, 2007). scenario by 495%, 239%, 49%, 679% and 669%, respectively (Table 5).
ADF, OLD and EP of CL scenario were higher than those of L sce-
nario. GWP is mainly caused by GHGs emitted during the processes.
results, more attention to transportation management, diesel fuel Higher GWP of landfilling can be interpreted by lack of energy re-
use, as well as machinery and equipment operations are needed for covery or emission control system in the landfill site, which causes
reducing energy consumption in both of the scenarios. Also, direct CH4 emission to the atmosphere. In particular, CH4 is the
1034 L. Behrooznia et al. / Journal of Cleaner Production 203 (2018) 1028e1038
Table 5
Characterization results of environmental impacts for MSW management scenarios in Rasht, Iran (FU: 100 t MSW).
AD kg Sbeq. 0 1.48 102 1.48 102 0 4.37 103 4.37 103 129
ADF MJ 6.89 103 1.76 104 2.45 104 1.61 103 1.29 104 1.45 104 41
GWP kg CO2eq 3.70 104 6.71 102 3.76 104 2.23 105 7.59 102 2.24 105 495
OLD kg CFC11eq 0 1.86 104 1.86 104 0 1.52 104 1.52 104 18
HT kg 1,4- 2.02 102 3.57 102 0.56 103 1.47 103 4.28 102 1.90 103 239
DBeq
FE kg 1,4- 0.36 30.40 0.30 102 0.68 1.55 102 1.56 102 618
DBeq
2 5 5 2 5 5
ME kg 1,4- 3.37 10 2.90 10 2.91 10 1.01 10 4.34 10 4.34 10 49
DBeq
TE kg 1,4- 2.96 102 20.38 20.35 5.05 102 2.12 2.17 111
DBeq
PO kg C2H4eq 18.10 0.10 18.20 1.41 102 1.58 101 142.00 679
AC kg SO2eq 3.16 102 3.28 0.32 103 2.46 103 2.85 2.46 103 669
EP kg PO3
4 eq 1.24 0.21 1.45 0.23 0.78 1.01 31
L. Behrooznia et al. / Journal of Cleaner Production 203 (2018) 1028e1038 1035
CL scenario it was 1.45 kg PO34eq. The difference was mainly due to 3.3.2. Normalization of LCA results
higher nitrate emissions during the composting process. The characterization results of LCA presents each of the impact
The percent contributions of resources for the characterization categories in their specific unit, making it difficult to compare the
results of L scenario are depicted in Fig. 7. It is evident that, direct impact categories. To overcome this problem, normalization of the
emissions during the CL process, transportation and machinery results was performed using the normalization factors available in
were the main contributors to most of the impact categories. It CML-IA baseline V3.04/World 2000 model and the results are
should be noted that emissions associated with diesel combustion presented in Table 6. As it is seen, the main impact categories
were also included in direct emissions. contributing to the total environmental loads of L scenario were AC,
Pollutants due to diesel fuel combustion, such as PM, SO2, NOx, GWP and PO. Similarly, ME, AC and GWP were the main impact
arsenic, cadmium, chromium, copper, nickel, and zinc are main categories in CL scenario. Moreover, most of the impact categories
contributors to toxicity impacts. Leachate is a potential source of in CL scenario were smaller than those of L scenario, which is also
emissions to groundwater and surface water (Kjeldsen et al., 2002). evident in Fig. 8. Abeliotis et al. (2012) investigated the LCA of MSW
FE potential is mainly due to toxic substances which affect the management scenarios in Greece. They hold a similar view that
quality of surface water. TE potential is affected by toxic substances MSW landfilling had the highest environmental emissions
on the soil. The results revealed that transportation and machinery compared to other MSW management scenarios. In another study,
were the main contributors to FE, ME and TE in both of the sce- landfilling of MSW in Czech Republic without energy recovery
narios; furthermore, in CL scenario the positive contribution of system showed the highest environmental impacts (Koci and
compost product on these impact categories was significant. Trecakova, 2011). Similarly, Banar et al. (2009) maintained that
AC is mainly caused by SO2, NOx and NH3. It can cause acid rain MSW composting in Turkey was more environmentally preferable
which is related to the release of SO2 and NOx into the atmosphere. than landfilling; in the same vein, MSW landfilling in China had the
Acid rain can reduce forest, acidify the soil and damage to buildings highest environmental impacts, mainly on human health, and it
(Guinee et al., 2001). As it is seen in Table 5, AC of L scenario was was due to lack of gas recovery system (Song et al., 2013).
considerably higher than that of CL scenario (2460 vs. 320 kg SO2eq/
FU).
Table 6 Table 7
Normalized environmental impacts of MSW management scenarios (FU: 100 t CExD results of MSW management scenarios based on LCA.
MSW).
Impact category Unit CL L
Impact categories CL scenario ( 109) L scenario ( 109)
Nonrenewable, fossil MJ 17602.31 13071.33
AD 0.07 0.02 Nonrenewable, nuclear MJ 1676.26 227.52
AD (fossil fuels) 0.06 0.04 Renewable, kinetic MJ 5.91 11.12
AC 1.34 10.30 Renewable, solar MJ 0.12 0.29
EP 0.01 0.01 Renewable, potential MJ 121.91 109.11
GWP 0.90 5.35 Nonrenewable, primary MJ 124.06 1.14
OLD 0.01 0.01 Renewable, biomass MJ 1253.62 84.86
HT 0.22 0.74 Renewable, water MJ 956.71 34.43
FE 0.01 0.07 Nonrenewable, metals MJ 194.10 255.00
ME 1.50 2.24 Nonrenewable, minerals MJ 19.79 40.45
TE 0.02 0.01
PO 0.50 3.85
Fig. 9. Sensitivity analysis (tornado diagram) of some of impact categories to individual input parameters on L scenario (L1-L8) and CL scenario (CL1-CL8) (FU: 100 t MSW). Blue
(brown) bars show changes of impact category by 10% decreasing (increasing) of individual parameters from the average. (For interpretation of the references to colour in this figure
legend, the reader is referred to the Web version of this article.)
1038 L. Behrooznia et al. / Journal of Cleaner Production 203 (2018) 1028e1038
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