MATERIAL SAFETY DATA SHEET

PRODUCT NAME: ABRO SUPER GLUE HMIS CODES

HFRP
PRODUCT CODE: AB-747
DATE : 9/ 1/2018 2 2 2
===================== SECTION I - MANUFACTURER IDENTIFICATION =====================

MANUFACTURER'S NAME : ABRO INDUSTRIES, INC.

ADDRESS : 3580 Blackthorn Court
South Bend, IN 46628

COMPANY PHONE: 574-232-8289 NAME OF PREPARER : HOA

CHEMTREC TOLL-FREE 24 HOURS EMERGENCY PHONE: 800-424-9300

IN THE EVENT OF A CHEMICAL EMERGENCY INVOLVING A SPILL, LEAK, FIRE, EXPOSURE OR

ACCIDENT CONTACT: CHEMTREC INTERNATIONAL - 703-527-3887

============================ SECTION II - COMPOSITION =============================

Ethyl cyanoacrylate CAS No. 7085-85-0 93-100%

Poly Methyl Methacrylate CAS No. 9011-14-7 3-75
Hydroquinone CAS No. 123-31-9 0.1-0.5%

================== SECTION III - CHEMICAL AND PHYSICAL PROPERTIES ==================

Appearance: Clear liquid

Odor: Sharp, irritating
Boiling Point: More than 300 F
Solubility in Water: Polymerized
Specific gravity: 1.05 at 75F
VOC: 94.0%; 987g/l (EPA Method 24)
Vapor Pressure: Less than 0.2 mm at 75 F
Vapor Density: 3

INGREDIENTS WHICH HAVE EXPOSURE LIMITS:

Exposure Limits ACGIH OSHA OTHER

Ingredients (TLV) (PEL)
Ethyl cyanoacrylate None None 2ppm TWA
9.1 mg/m3
Hydroquinone 2 mg/m3 TWA 2mg/m3 TWA 2 mg/m3 TWA
4mg/m3 STEL

Exposure Limits (STEL)

Ethyl cyanoacrylate (4 ppm) (4 ppm)
(18 mg/m3) (16 mg/m3)
============= SECTION IV - FLAMMABILITY AND EXPLOSIVE PROPERTIES ====================

Flash point: 160-200F (TCC)

Extinguishing agents: Carbon dioxide, foam, dry chemical
Hazardous products formed by fire and thermal decomposition: irritating organic vapors.

===================== SECTION V - STABILITY AND REACTIVITY ===========================

Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Polymerized by contact with water, alcohols, amines, alkalies.

====================== SECTION VI - HEALTH HAZARD DATA ===========================

Toxicity: Skin contact may cause burns.

Bonds skin rapidly and strongly.
Skin and eye irritant.
Estimated oral LD50 more than 5000 mg/kg.
Estimated dermal LD50 more than 2000 mg/kg.

Primary routes of entry: None known.

Symptoms of exposure: Vapor is irritating to mucous membranes when above the TLV. Prolonged and repeated
overexposure to vapors may produce allergic reactions with asthma like symptoms in sensitive individuals.

======================= SECTION VII - PERSONAL PROTECTION =========================

Eyes: Safety glasses or goggles mandatory.

Skin: Polyethylene gloves and/or aprons. Do not use cotton.
Ventilation: Positive down draft exhaust ventilation should be provided to maintain vapor concentration below
TLV.

================ SECTION VIII - EMERGENCY TREATMENT PROCEDURES ==================

Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention.

Skin contact: Soak in warm water.
Eye contact: Flush with water.

=================== SECTION IX - ACCIDENTAL RELEASE MEASURES=========================

If a spill or leak occurs, flood area with water to polymerize.

Soak up with an inert absorbent.

======================= SECTION X - DISPOSAL CONSIDERATIONS =======================

Dispose of following EPA, Federal, State, and Local regulations.

================ SECTION XI - HANDLING AND STORAGE INFORMATION ==================

Safe Storage: Store below 72 ΕF.

Handling: Avoid contact with skin and eyes. Avoid breathing vapors.

=========================== SECTION XII - SUPPLEMENT ==============================

SKIN ADHESION: First immerse the bonded surface in warm soapy water. Peel or roll the surface apart with the
aid of a blunt edge such as a pencil, spoon, handle, etc. Do this gradually, in a gentle fashion, with care not to be too
forceful. Then remove the adhesive from the skin with soap and water. DO NOT try to pull surface apart with a
direct opposing action.

EYELID TO EYE LID OR EYEBALL ADHESION: In the event that eyelids are stuck together or bonded to the
eyeball wash thoroughly with warm water and apply a gauze patch. The eye will open without further action,
typically in one to four days. There will be no residual damage. Do not try to open eyes by manipulation. Let eh
natural cleansing action of the eye take place.

ADHESIVE ON THE EYEBALL: Cyanoacrylate introduced into the eye will attach itself to the eye protein and will
disassociate from it over intermittent periods, generally covering several hours. This will cause periods of tearing
until clearance is achieved. The adhesive residue will flush out of the eye normally in a matter of hours.

MOUTH: If lips are accidentally stuck together, apply lots of warm water to the lips and encourage maximum
wetting and pressure from saliva inside the mouth. Peel or roll the lips apart. Do not try to pull the lips apart with a
direct opposing action. It is almost impossible to swallow cyanoacrylate. The adhesive solidifies and adheres in the
mouth. Saliva will lift the adhesive in 12 ro 48 hours.

BURNS: Cyanoacrylates give off heat in solidification. In rare cases a large amount will increase in temperature
enough to cause a burn. Should this occur treat using normal medical procedures.