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Geology is the science that deals with the history and structure of the
earth and its life forms, especially as recorded in the rock record. A basic
understanding of its concepts and processes is essential in the petroleum
industry, for it used to predict where oil accumulations might occur. It is
the job of the petroleum geologist to use knowledge to reconstruct the
geologic history of an area to determine whether the formations are likely
to contain petroleum reservoirs. It is also the job of the geologist to
determine whether the recovery and production of these hydrocarbons
will be commercially profitable.
A Geologist is a scientist who studies the solid and liquid matter that
constitutes the Earth as well as the processes and history that have
shaped it. Geologists usually engage in studying geology. Geologists,
studying more of an applied science than a theoretical one, must
approach Geology using physics, chemistry and biology as well as other
sciences.
The earth is composed of three basic layers: the core, the mantle, and the
crust. The crust is the layer that is of most importance in petroleum
geology. Geologists distinguish between oceanic crust and continental
crust. Oceanic crust lies under the oceans, is thin about 5-7 miles (8-11
km), and is made up primarily of heavy rock that is formed when molten
rock (magma) cools. Continental crust is thick about 10-30 miles (16-48
km) and is composed of rock that is relatively light as compared to
oceanic crust.
Figure 2.1 illustrates the structure of the Earth. There is a central solid iron core,
surrounded by a liquid iron core, the lower mantle and the upper mantle. The
upper mantle consists of a weak, molten asthenosphere and finally there is a
strong lithosphere with a surficial crust of light rock. About 90% of the earth’s
crust is made up of the four elements: iron, oxygen, silicon and magnesium,
which are the fundamental building blocks of most minerals. Iron, being heavy,
sinks to the core, and lighter elements such as silicon, aluminum, calcium,
potassium and sodium have risen to the crust.
Rocks
The earth’s crust is composed of three basic rock types: igneous,
sedimentary and metamorphic.
Petroleum-Bearing Rocks
Sedimentary rocks are the source of petroleum, provide the reservoir rock,
and trap to hold the petroleum in the earth’s crust. There are the least
abundant rocks on the earth’s crust, making up about 7.9% of the earth’s
crust. Because most reservoir rocks are sedimentary rocks, they are of
particular interest to us in the study of petrophysics. Therefore,
Sedimentary rocks are the most important and interesting type of rock to
the petroleum industry because most oil and gas accumulations occur in
them; igneous and metamorphic rocks rarely contain oil and gas.
The start and end of all rocks is the magma in the mantle. This is cooled to
create igneous rocks. These can be broken down into sediments. The
sediments are turned into sedimentary rocks. This can be buried deeper
with heat and pressure, turning into metamorphic rocks. If these are then
heated, we return to the magma. Inside this major cycle are subsycles.
Igneous rocks can be heated to give metamorphic rocks. Any rocks can be
broken into sediments to give sedimentary rocks.
Sandstones
Sandstones are Clastics sedimentary rocks composed of mainly sand size
particles or grains set in a matrix of silt or clay and more or less firmly
united by a cementing material (commonly silica, iron oxide, or calcium
carbonate). The sand particles usually consist of quartz, and the term
“sandstone”, when used without qualification, indicates a rock
containing about 85-90% quartz.
Shale's
Shale is a type of detrital sedimentary rock formed by the consolidation of
fine-grained material including clay, mud, and silt and have a layered or
stratified structure parallel to bedding. Shale's are typically porous and
contain hydrocarbons but generally exhibit no permeability. Therefore,
they typically do not form reservoirs but do make excellent cap rocks. If a
shale is fractured, it would have the potential to be a reservoir.
Evaporites
Evaporites do not form reservoirs like limestone and sandstone, but are
very important to petroleum exploration because they make excellent cap
rocks and generate traps. The term “evaporite” is used for all deposits,
such as salt deposits, that are composed of minerals that precipitated
from saline solutions concentrated by evaporation. On evaporation, the
general sequence of precipitation is calcite, gypsum or anhydrite, halite,
and finally bittern salts.
Evaporites make excellent cap rocks because they are impermeable and,
unlike lithified shale's, they deform plastically, not by fracturing.
Source Rock
Possible source rock: Any unit of rock, which by its general lithology
and depositional environment may generate hydrocarbons.
The Reservoir
A reservoir is a formation of one or more rock formations that contains
liquid and/or gaseous hydrocarbons. It is mostly of sedimentary rock
origin, with few exceptions. Reservoir rocks are porous and
permeable; and bounded by impermeable barriers, which trap
hydrocarbons. Vertical arrangement of fluids in a reservoir is
governed by gravitational forces i.e. Gas-Oil-Water
Depth
Shallow reservoir
Deep reservoir
greater the area and thickness of the reservoir, the greater the potential
for large accumulations of oil and gas. However, there are reservoirs that
produce substantial amounts of hydrocarbons that are not of considerable
size.
Porosity
Porosity is the ratio of the pore volume to the bulk volume of the
reservoir rock on percentage basis. That is
If the organic materials within the source rock are mostly wood
fragments, then the primary hydrocarbons generated upon maturation
are natural gas. If the organic materials are mostly algae or the soft parts
of land plants, then both oil and natural gas are formed. Gas can be
generated in two ways in the natural systems; it can be generated directly
from woody organic matter in the source rocks or it can be derived by
thermal breakdown of previously generated oils at high temperatures.
Hydrocarbons are less dense than water. Once released from the source
rock, they thus tend to migrate upwards in the direction of the minimum
pressure, until either they escape at the ground surface, or an impervious
barrier, called a trap.
In a trap, the oil and gas accumulate by displacing pore water from the
porous rock. The top may be imperfectly sealed, which means that gas
and possibly some oil may "leak" to yet higher lying traps or up to the
ground surface. The part of the trap that contains hydrocarbons is called a
petroleum reservoir.
Both oil and gas are generated together, in varying proportions, from a
source rock, which results in a primary gas cap above the oil in the
reservoir. Likewise, a secondary gas cap may develop when the reservoir
pressure has decreased and the lightest hydrocarbon begin to bubble out
from the oil. Some "leaky" or limited-capacity traps may segregate oil and
gas that have been generated together, such that these accumulate in
separate reservoirs.
Migration is the process of the oil and gas moving away from the source
rock. This is a slow process. Migration is caused by burial, compaction,
and increase in volume and separation of the source rock constituents.
There must be space ‘porosity’ within the rocks to allow for movement. In
addition, there is should be Permeability’ within the rocks.
Once the water, oil and gas migrate into the trap, it separates according to
density. Gas being the lightest, goes to the top of the trap to form the free
gas cap. Oil goes to the middle and water that is always present, on the
bottom
Migration from the source rock into the carrier bed called primary
migration.
Primary migration driven by pressure build-up caused by
hydrocarbon generation.
Migration from the source kitchen area to the reservoir trap called
secondary migration.
Secondary migration is a gravity-driven processes controlled by
pore-entry networks.
As oil and gas migrate through the reservoir rock and carrier beds,
they may encounter a high point, barrier, or seal where the fluids stop
and accumulate.
Seals can be any rock with a low permeability to hydrocarbons.
Seals can also be the result of a barrier to flow such as a fault. Some
rocks commonly found acting, as seals are shale's and salts.
If there, no seal, or cap rock present, hydrocarbons will continue
migrate to the surface and never become trapped.
Figure 2.4 Diagram to illustrate the main geological conditions and geochemical
processes required for the formation of petroleum accumulations in sedimentary
basins: 1) petroleum generation in source rocks; 2) primary migration of
petroleum; 3) secondary migration of petroleum; 4) accumulation of petroleum in
a reservoir trap; 5) seepage of petroleum at the Earth’s surface because of a
fractured cap rock.
Table 1 Illustrates the distribution of discovered Oil and gas fields based on
geologic age
Geologic Age % of Fields
Neogene 18
Palaeogene 21
Cretaceous 27
Jurassic 21
Permo-Triassic 6
Carboniferous 5
Devonian 1
Cambrian-Silurian 1
Total 100
Hydrocarbon Traps
Hydrocarbon traps are any combination of physical factors that promote
the accumulation and retention of petroleum in one location. Traps can be
structural, stratigraphic, or a combination of the two.
Salt Domes
Fault Structures
Structures Unconformity
Lenticular Traps
Oil and gas may accumulate in traps formed by the bodies of porous
lithofacies (rock types) embedded in impermeable lithofacies, or by the
pinch-outs of porous lithofacies within impermeable ones, as seen in Fig.
2.10.
Figure 2.14 Structural traps associated with salt diapirs. Salt is mobile in the
subsurface and tends to rise to the surface, aided by its low density. Rising salt
takes on a distinctive "diapiric" shape. Salt domes are very common is some
areas of the world (e.g., Gulf Coast)
These data lead to the following estimate: only 0.003 vol. % of the world’s
source rocks actually turn into petroleum that can be trapped and thus
generate our petroleum resources.
Finally, beneath the oil-water transition zone is that part of the formation
completely saturated with water. It is important to note that not all
reservoirs may contain natural gas, oil, and water. Some formations may
only contain water. However, any formation that contains hydrocarbons
will also contain some amount of water.
Types of Hydrocarbons
Kerogen/Bitumen
Shale rock volume is composed of 99% clay minerals and 1% organic
material. We have seen that petroleum derived mainly from lipid-rich
organic material buried in sediments. Most of this organic matter is in a
form known as kerogen.
The organic content of a rock that is extractable with organic solvents that
known as bitumen. It normally forms a small proportion of the total
Crude oil
Crude oil is a mixture of many hydrocarbons that are liquid at surface
temperatures and pressures, and are soluble in normal petroleum
solvents. It can vary in type and amount of hydrocarbons as well as
which impurities it may contain. Crude oil may be classified chemically
(e.g. paraffinic, naphthenic) or by its density. This expressed as specific
gravity or as API (American Petroleum Institute) gravity according to the
formula:
Asphalt
Asphalt is a dark colored solid to semi-solid form of petroleum (at surface
temperatures and pressures) that consists of heavy hydrocarbons and
bitumen. It can occur naturally or as a residue in the refining of some
petroleum. It generally contains appreciable amounts of sulphur, oxygen,
and nitrogen and unlike kerogen; asphalt is soluble in normal petroleum
solvents. It is produced by the partial maturation of kerogen or by the
degradation of mature crude oil. Asphalt is particularly suitable for
making high-quality gasoline, roofing, and paving materials.
Natural Gas
There are two basic types of natural gas, biogenic gas and Thermogenic
gas. The difference between the two is contingent upon conditions of
origin. Biogenic gas is a natural gas formed solely as the result of bacterial
activity in the early stages of diagenesis, meaning it forms at low
temperatures, at overburden depths of less than 3000 feet, and under
anaerobic conditions often associated with high rates of marine sediment
accumulation.
The major hydrocarbon gases are methane (CH4), ethane (C2H6), propane
(C3H8), and butane (C4H10). The terms sweet and sour gas used in the
field to designate gases that are low or high, respectively, in hydrogen
sulfide.
Natural gas, as it comes from the well, also classified as dry gas or wet
gas, according to the amount of natural gas liquid vapors it contains. A
dry gas contains less than 0.1-gallon natural gas liquid vapors per 1,000
cubic feet, and a wet gas 0.3 or more liquid vapors per 1,000 cubic feet.
Natural gas usually consists mostly of methane (CH4) but may contain
variable amounts of higher-order paraffins (ethane, propane and butane).
“Dry gas” is predominantly methane and ethane, while “wet gas”
contains more than 50% propane and butane. Gas may originate as a
byproduct during the generation of oil, from coal, or as bacterial gas
(swamp gas).
Additional components in gas are CO2, which may be used to make dry
ice, and H2S, which has to be removed because of its toxicity (0.1% is fatal
to humans within 30 minutes). At the refinery, H2S is converted into
sulfur as follows:
Ethylene, propylene, and butylene are gaseous olefins that are originally
not present in petroleum but are formed in the refining process through
cracking of petroleum.
Condensates
Condensates are hydrocarbons transitional between gas and crude oil
(gaseous in the subsurface but condensing to liquid at surface
temperatures and pressures). Chemically, condensates consist largely of
paraffin's, such as pentane, octane, and hexane.
Temperature Gradient
Temperature is generally a function of depth because of the earth’s
natural geothermal gradient. Normal heat flow within the earth’s crust
produces a gradient of approximately 1.5°F for each 100 feet of depth
below the surface. The temperatures required to produce crude oil occur
between 5,000 and 20,000 feet of depth. Temperatures below 20,000 feet
are generally too high and only generate gas. Temperatures above 5,000
feet are not usually sufficient to transform the material into crude oil.
There are, of course, exceptions to the rules. Geologic conditions such as
volcanism and tectonics (folding and faulting) can change or effect the
temperature gradient.
Pressure Gradient
Most pressure that effects rocks is due to the weight of overlying rocks
and called overburden pressure. Overburden pressure is a function of
depth and increases one pound per square inch for each foot of depth. At
3000 feet, for example, the overburden pressure would be 3,000 pounds
per square inch. Hydrocarbons evolve from an immature stage to oil
generation, oil cracking (wet gas stage), and finally to dry gas generation
because of overburden pressure and the associated increase in
temperature.
Exploration Survey
Exploration for oil and gas has long been considered an art as well as a
science. It encompasses a number of older methods in addition to new
techniques. The explorationist must combine scientific analysis and an
imagination to solve the problem of finding and recovering
hydrocarbons.
such maps used to illustrate the size, shape and location of geologic
structures.
Subsurface Mapping
Geophysical Methods
Figure 2.20
Magnetic Surveys
Magnetic surveys are methods that provide the quickest and least
expensive way to study gross subsurface geology over a broad area. A
magnetometer used to measure local variations in the strength of the
The degree to which igneous rocks concentrate this field is not only
dependent upon the amount of iron or titanium present but also upon the
depth of the rock. An igneous rock formation 1,000 feet below the surface
will affect a magnetometer more strongly than a similar mass 10,000 feet
down. Thus, a relatively low magnetic field strength would indicate an
area with the thickest sequence of nonmagnetic sedimentary rock.
Once the magnetic readings have plotted on a map, points of equal field
strength connected by contour lines, thus creating a map that is the rough
equivalent to a topographic map of the basement rock.
In the case of a fault, a sharp change in magnetic values will occur since
basement rocks will be higher on one side than the other will.
Gravity Surveys
The gravity survey method makes use of the earth’s gravitational field to
determine the presence of gravity anomalies (abnormally high or low
gravity values) which can related to the presence of dense igneous or
metamorphic rock or light sedimentary rock in the subsurface. Dense
igneous or metamorphic basement rocks close to the surface will read
much higher on a gravimeter because the gravitational force they exert is
more powerful than the lighter sedimentary rocks. The difference in mass
for equal volumes of rock is due to variations in specific gravity.
Seismic Survey
One of the most common ways to generate acoustic waves today is an air
gun. Air guns contain chambers of compressed gas. When the gas
released under water, it makes a loud “pop” and the seismic waves travel
through the rock layers until they reflected back to the surface where they
are picked up by hydrophones, the marine version of geophones, which
trail behind the boat.
Seismic waves travel at known but varying velocities depending upon the
kinds of rocks through which they pass and their depth below Earth’s
surface. The speed of sound waves through the earth’s crust varies
directly with density and inversely with porosity.
Through soil, the pulses travel as slowly as 1,000 feet per second, which is
comparable to the speed of sound through air at sea level. On the other
hand, some metamorphic rocks transmit seismic waves at 20,000 feet
(approximately 6 km) per second, or slightly less than 4 miles per second.
Some typical average velocities are shale = 3.6 km/s; sandstone = 4.2
km/s; limestone = 5.0 km/s.
Isopach Maps
Figure 2.24 Structural map and longitudinal profile section showing top of
salt, which is datum for structure Contours
Surface Geology
There are several areas to look for oil. The first is the obvious, on the
surface of the ground. Oil and gas seeps are where the petroleum has
migrated from its’ source through either porous beds, faults or springs
and appears at the surface. Locating seeps at the surface was the primary
method of exploration in the late 1800’s and before.
Seeps are abundant and well documented worldwide. Oil or gas on the
surface, however, does not give an indication of what lies in the
subsurface. Geologic mapping, geophysics, geochemistry and aerial
photography are all crucial aspects in the exploration for oil and gas.
Figure 2.27 Seeps are located either up dip (A) or along fractures (B)
Exploratory drilling
The data collected from the geologic and geophysical surveys used to
formulate probable definitions and realizations of the geologic structure
that may contain oil and/or gas. However we still have to determine
whether petroleum exists in these geologic traps and if it does exist,
would it be available in such a quantity that makes the development of
the oil/gas field economical? The only way to provide a definite answers
is to drill and test exploratory well(s).
After the well drilled, and sometimes at various intervals during drilling,
various logs are taken. Several logging tools or techniques, (electric logs,
radioactivity logs, and acoustic logs) are used to gather information about
the drilled formations. These tools are lowered into the well on a wireline
(electric cable) and, as they are lowered, the measured signals are
transmitted to the surface and recorded on computers. The signals
collected are interpreted and produced in the form of rock and fluid
properties versus depth.
The exploratory well will provide important data on rock and fluid
properties, type and saturation of fluids, initial reservoir pressure,
reservoir productivity, and so forth. These are essential and important
data and information, which are needed for the development of the field.
In most situations, however, the data provided by the exploratory well
will not be sufficient.
Appraisal
The very large volume of information and data collected from the various
geologic and geophysical surveys and the exploratory wells used to
construct various types of map. Contour maps are lines drawn at regular
intervals of depth to show the geologic structure relative to reference
points called the correlation markers.
Reservoir engineers set the strategy for producing the petroleum reserves
and managing the reservoir for the life of the field. Production and
completion engineers design the well completions and production
facilities to handle the varying production methods and conditions, and
drilling engineers design the well-drilling programs based on well-
completion design.
In the past, each group used to work separately and deliver its product to
the next group. That is, when geologists and geophysicists finish their
work, they deliver the product to the reservoir-engineering group. Then,
reservoir engineering would deliver the results of their work to
production engineering, and so on. In almost all cases, it was necessary
for each group to go back to the previous group for discussion,
clarification, or requesting additional work.