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Propriedades físicas do Carbamato de Amônio

Dados de Cp do Carbamato de amônio vapor Cp=A+B*T+C*T^2+D*T^3+E*T^4+F*T^5+G*T^6

Temperatura(K) Cp(J/mol*K) Knovel DataBase Cp(J/kmol*K) CHEMCAD

150 76.9181 76918.123714 250


200 80.2315 80231.505672
250 86.5421 86542.086405 200= 3.6894799999
f(x)
300 94.6399 94639.928292 R² = 1
350 103.6212 103621.24193
150
400 112.8379 112837.92741
450 121.8513 121851.26627
100
500 130.3898 130389.7641
550 138.3111 138311.14384
600 145.5685 145568.48969 50
650 152.1805 152180.54174
700 158.2061 158206.14125 0
750 163.7228 163722.82656 0 200 4
800 168.8096 168809.57971
850 173.5337 173533.72371 250000
900 177.9420 177941.97047
950 182.0556 182055.61938
200000
f(x) = 8.1792
1000 185.8699 185869.9066
R² = 0.99928
1050 189.3575 189357.50498
1100 192.4762 192476.17463 150000
1150 195.1806 195180.56421
1200 197.4382 197438.16283
100000
1250 199.2494 199249.40265
1300 200.6719 200671.91213
1350 201.8489 201848.91993 50000
1400 203.0418 203041.80953
1450 204.6668 204666.82443
0
1500 207.3359 207335.9241 0

Dados de Cp do Carbamato de amônio sólido

Temperatura(K) Cp(J/mol*K) Knovel DataBase


290 120.57
291 120.57
292 120.57
293 120.57
294 120.57
295 120.57
296 120.57
297 120.57
298 120.57
299 120.57
300 120.57
301 120.57
302 120.57
303 120.57
304 120.57

A B C D E F G
120.57 0 0 0 0 0 0
+F*T^5+G*T^6

Parâmetros (coeficientes requeridos pelo CHEMCAD)

250

200= 3.68947999999973E-16x^6 - 1.95432999999988E-12x^5 + 4.1333999999998E-09x^4 - 4.41887999999983E-06x^3 + 0.00240024x^2 - 0.446336715x + 102.8286216


f(x)
R² = 1
150
Column B
Column C
100 Polynomial (Column C)

50

0
0 200 400 600 800 1000 1200 1400 1600

250000

200000
f(x) = 8.17923249999844E-08x^4 - 0.0002759187x^3 + 0.2428849511x^2 + 80.5408906878x + 57394.0383464267
R² = 0.9992812963

150000
76918.1237139375
Column G
100000 Polynomial (Column G)

50000

0
0 200 400 600 800 1000 1200 1400 1600

Cp(J/kmol*K) CHEMCAD
120570
120570
120570
120570
120570
120570
120570
120570
120570
120570
120570
120570
120570
120570
120570
A 1
B 0.99999759
C 0.99991161
D -9.031E-05
E 5.3272E-08
FC
Microsoft Excel 12.0 Relatório de resposta
Planilha: [Pasta1.xlsx Levantamento de parâmetros para o TCC.xlsx]Plan2
Relatório criado: 29/09/2018 13:47:00

Célula de destino (Mín)


Célula Nome Valor original Valor final
$E$44 2109.3983134 0.0742731832

Células ajustáveis
Célula Nome Valor original Valor final
$P$9 a 1.00E+00 3.54E+01
$P$10 b 1 -560.9285299
$P$11 c 0.9999999999 -6.032417626

Restrições
NENHUMA
Microsoft Excel 12.0 Relatório de resposta
Planilha: [Pasta1.xlsx Levantamento de parâmetros para o TCC.xlsx]Plan2
Relatório criado: 29/09/2018 13:48:26

Célula de destino (Mín)


Célula Nome Valor original Valor final
$E$44 0.0742731832 0.0742731832

Células ajustáveis
Célula Nome Valor original Valor final
$P$9 a 3.54E+01 3.54E+01
$P$10 b -560.92852993 -560.9285299
$P$11 c -6.0324176257 -6.032417626

Restrições
NENHUMA
Propriedades físicas do Carbamato de Amônio

Dados de Cp do Carbamato de amônio sólido

Temperatura(K) Cp(J/mol*K) Knovel DataBase

120.57

Ponto de fussão T(K) Calor de formação (kJ/mol)


333 -154.17

Temperatura de Ebulição T(K)


333

Temperatura (K) Viscosidade de líquido (cP)

281 0.468246 -0.7587624122 -0.6529 0.011196871


291 0.433716 -0.8353645674 -0.7953 0.001605583
301 0.395246 -0.9282459452 -0.9351 4.660328E-05
311 0.355475 -1.0343013037 -1.0723 0.001444415
321 0.316380 -1.1508123472 -1.2070 0.003160894
331 0.279322 -1.2753892749 -1.3393 0.004084504
341 0.245141 -1.4059226145 -1.4692 0.003998014
351 0.214265 -1.5405432894 -1.5966 0.00314765
361 0.186824 -1.6775893229 -1.7218 0.001958118
371 0.162744 -1.8155779273 -1.8448 0.000853255
381 0.141822 -1.9531819879 -1.9656 0.000152997
391 0.123785 -2.0892101564 -2.0842 2.523585E-05
401 0.108328 -2.2225899223 -2.2008 0.000476854
411 0.095145 -2.3523531554 -2.3153 0.001372379
421 0.083942 -2.4776237096 -2.4279 0.002471778
431 0.074452 -2.5976067515 -2.5386 0.003481114
441 0.066432 -2.7115795417 -2.6475 0.004111504
451 0.059673 -2.8188834416 -2.7545 0.004142989
461 0.053992 -2.9189169614 -2.8598 0.003490881
471 0.049236 -3.0111296932 -2.9635 0.002272816
481 0.045274 -3.095017001 -3.0654 0.000875256
491 0.041999 -3.1701153598 -3.1658 1.854023E-05
501 0.039321 -3.2359982525 -3.2646 0.000819901
511 0.037169 -3.292272549 -3.3619 0.004854034
521 0.035487 -3.3385753017 -3.4578 0.014210996
0.074273183
Temperatura (K) Líquid Thermal Condutivity(W/m*K)

309 0.1802340102
319 0.1763359472
0.2
329 0.1723111042
0.18
339 0.1681594812 f(x) = - 6.33900000000009E-07x^2 + 8.2829
349 0.1638810782 0.16 R² = 1
359 0.1594758952 0.14
369 0.1549439322 0.12
379 0.1502851892
0.1
389 0.1454996662
399 0.1405873632 0.08
409 0.1355482802 0.06
419 0.1303824172 0.04
429 0.1250897742
0.02
439 0.1196703512
449 0.1141241482 0
250 300 350 400 450 500
459 0.1084511652
469 0.1026514022
479 0.0967248592
489 0.0906715362
499 0.0844914332

Temperatura (K) surface tension (dyne/cm)

270 24.547838813
275 23.9930189129
280 23.4405218967
285 22.8903824636
290 22.3426365206
295 21.7973212498
300 21.2544751807
305 20.7141382677
310 20.1763519746
315 19.6411593653
320 19.1086052028
325 18.5787360559
330 18.0516004161
335 17.5272488242
340 17.0057340093
345 16.4871110404
350 15.9714374927
355 15.4587736306
360 14.9491826095
365 14.4427306982
370 13.9394875257
375 13.4395263555
380 12.9429243905
385 12.4497631153
390 11.960128678
395 11.4741123225
400 10.9918108746
405 10.5133272957
410 10.0387713122
415 9.5682601371
420 9.1019193004
425 8.6398836098
430 8.1822982684
435 7.7293201854
440 7.2811195208
445 6.8378815219
450 6.3998087247
455 5.9671236157
460 5.540071885
465 5.1189264459
470 4.7039924656
475 4.295613751
480 3.8941809888
485 3.5001425765
490 3.1140191719
495 2.7364237386
500 2.368090013
505 2.0099144398
510 1.6630208266
515 1.3288659809
520 1.0094261069
525 0.7075630186
530 0.427871256
535 0.179297627
539.82 0
Cp=A+B*T+C*T^2+D*T^3+E*T^4+F*T^5+G*T^6

Cp(J/mol*K) Knovel DataBase Cp(J/kmol*K) CHEMCAD

120570

Calor de formação (BTU/lbmol)


-66280.884432999

Modelo 1 CHEMCAD trucado Mode 1 CHEMCAD completo


0.5205094973 0.4760071992 6.02E-05 0.4760071992
0.4514481098 0.4204894523 0.000175 0.4204894523
0.3925573631 0.3730098378 0.000494 0.3730098378
0.3422181899 0.3321924065 0.000542 0.3321924065
0.2990829922 0.2969308599 0.000378 0.2969308599
0.2620291822 0.2663294112 0.000169 0.2663294112
0.2301204375 0.2396579181 3.01E-05 0.2396579181
0.2025745701 0.2163175473 4.21E-06 0.2163175473
0.1787369777 0.1958142825 8.08E-05 0.1958142825
0.1580587537 0.1777383275 0.000225 0.1777383275
0.1400786576 0.1617479761 0.000397 0.1617479761
0.1244082694 0.1475568938 0.000565 0.1475568938
0.1107197612 0.1349240252 0.000707 0.1349240252
0.0987358163 0.1236455342 0.000812 0.1236455342
0.08822131 0.1135483333 0.000877 0.1135483333
0.0789764331 0.1044848563 0.000902 0.1044848563
0.0708309995 0.0963288166 0.000894 0.0963288166
0.0636397258 0.0889717456 0.000858 0.0889717456
0.0572783086 0.0823201565 0.000802 0.0823201565
0.0516401592 0.0762932074 0.000732 0.0762932074
0.0466336791 0.0708207703 0.000653 0.0708207703
0.0421799823 0.0658418263 0.000568 0.0658418263
0.0382109881 0.0613031281 0.000483 0.0613031281
0.0346678183 0.0571580812 0.0004 0.0571580812
0.0314994503 0.0533658031 0.00032 0.0533658031
0.012129
Modelo CHEMCAD

0.2
Column B
0.18
Column+ B0.2382 Polynomial
f(x) = - 1.83665846978485E-24x^4 + 3.06116726881638E-21x^3 - 6.33900000001904E-07
f(x) = - 6.33900000000009E-07x^2 + 8.28290000000706E-06x (Column B)
R² = 1 Polynomial (Column 0.16
R² =1
B)
0.14
0.12
0.1
0.08
0.06
0.04
0.02
0
350 400 450 500 550 250 300 350 400 450 500 550

Modelo CHEMCAD Modelo CHEMCAD


A
0.0245478388 Tc
0.0239930189 B=N
0.0234405219
0.0228903825 A
0.0223426365 B
0.0217973212 N
0.0212544752
0.0207141383
0.020176352 0.03
0.0196411594
0.0191086052
0.025
0.0185787361
0.0180516004
0.02
0.0175272488
0.017005734
0.016487111 0.015

0.01

0.005
0.02

0.015
0.0159714375
0.0154587736 0.01
0.0149491826
0.0144427307
0.005
0.0139394875
0.0134395264
0.0129429244 0
250 300 350 400 450 500 550
0.0124497631
0.0119601287
0.0114741123
0.0109918109
0.0105133273
0.0100387713
0.0095682601
0.0091019193
0.0086398836
0.0081822983
0.0077293202
0.0072811195
0.0068378815
0.0063998087
0.0059671236
0.0055400719
0.0051189264
0.0047039925
0.0042956138
0.003894181
0.0035001426
0.0031140192
0.0027364237
0.00236809
0.0020099144
0.0016630208
0.001328866
0.0010094261
0.000707563
0.0004278713
0.0001792976
0
E*T^4+F*T^5+G*T^6

(J/kmol*K) CHEMCAD Parâmetros (coeficientes requeridos pelo CHEMCAD)

120570

A 3.54E+01 A
de formação (BTU/lbmol) B -560.929 B
-66280.884432999 C -6.03242 C
D
E

Viscosidade de líquido (Pa*S)

0k 0.000468246
0.000433716
0.000395246
0.000355475
0.00031638
0.000279322
0.000245141
0.000214265
0.000186824
0.000162744
0.000141822
0.000123785
0.000108328
0.000095145
8.394246E-05
7.445155E-05
6.643179E-05
5.967253E-05
5.399213E-05
0.000049236
4.527424E-05
4.199875E-05
3.932093E-05
3.716928E-05
3.548748E-05
lo CHEMCAD

Column B
Polynomial
+ 3.06116726881638E-21x^3 - 6.33900000001904E-07x^2 + 8.2829000005238E-06x + 0.2382
(Column B)

450 500 550

lo CHEMCAD
57.294
539.82
1.2222

57.294
539.82
1.2222

0.0245478388
Column F
0.0245478388
Column F

400 450 500 550 600


CHEMCAD)

9.678169
0.290997
-3.31638 ok
9.675655
-0.02768
Propriedades físicas do Carbamato de Amônio

Dados de Entalpia do Carbamato de amônio líquido DeltaH=A+B*T+C*T^2+D*T^3+E*T^4+F*T^5+G*T

Temperatura(K) DeltaH(kJ/mol) Knovel DataBase DeltaH(J/kmol) CHEMCAD DataBase

150 -12.42232182 -12422321.82


200 -8.680037229 -8680037.229
250 -4.474512655 -4474512.655
300 0.1800496758 180049.67576
350 5.2690493428 5269049.3428
400 10.777487734 10777487.734
450 16.689968044 16689968.044
500 22.990695274 22990695.274
550 29.663476233 29663476.233
600 36.691719536 36691719.536
650 44.058435607 44058435.607
700 51.746236674 51746236.674
750 59.737336775 59737336.775
800 68.013551752 68013551.752
850 76.556299257 76556299.257
900 85.346598747 85346598.747
950 94.365071487 94365071.487
1000 103.59194055 103591940.55
1050 113.00703081 113007030.81
1100 122.58976896 122589768.96
1150 132.31918348 132319183.48
1200 142.17390468 142173904.68
1250 152.13216467 152132164.67
1300 162.17179736 162171797.36
1350 172.27023846 172270238.46
1400 182.40452551 182404525.51
1450 192.55129784 192551297.84
1500 202.68679659 202686796.59
*T^3+E*T^4+F*T^5+G*T^6

mol) CHEMCAD DataBase


Propriedades físicas do Carbamato de Amônio

Dados de Entalpia de vaporização do Carbamato de amônio

Chemical properties handbook


CHEMCAD 25000000
Temperatura (K) Tc Delta Hvap A n
400 539.82 22.7722 38.049 0.38 22772199 20000000
410 22.13902 22139023
420 21.47483 21474832 15000000
430 20.77531 20775313
440 20.03509 20035091 10000000
450 19.24733 19247326
460 18.4031 18403105 5000000
470 17.49045 17490450
480 16.49264 16492644 0
490 15.38516 15385161 380 400 420
500 14.12951 14129510
510 12.65906 12659062
520 10.83897 10838970
530 8.300247 8300246.8
539.82 0 0
25000000

20000000

15000000
22772199.0560852
10000000 Column I

5000000

0
380 400 420 440 460 480 500 520 540 560
Microsoft Excel 12.0 Relatório de resposta
Planilha: [Pasta1.xlsx Levantamento de parâmetros para o TCC.xlsx]Plan5
Relatório criado: 30/09/2018 23:42:38

Célula de destino (Mín)


Célula Nome Valor original Valor final
$L$5 soma 1.57731E+294 1.5773E+294

Células ajustáveis
Célula Nome Valor original Valor final
$O$4 A 1 1
$O$5 B 1 1
$O$6 C 1 1
$O$7 D 1 1
$O$8 E 1 1

Restrições
NENHUMA
Propriedades físicas do Carbamato de Amônio

Dados de pressão de vapor do Carbamato de amônio


Pressão de vapor(mmHg) Temperatura (K) LogP(Pa) Modelo CHEMCAD
LogP 7.859453E-03 247.05 1.047822E+00 1.3222E+110
3.261871E-01 254.05 4.348726E+01 1.4909E+113
6.254642E-01 261.05 8.338688E+01 1.6798E+116
9.073451E-01 268.05 1.209673E+02 1.8913E+119
1.173301E+00 275.05 1.564245E+02 2.1281E+122
1.424645E+00 282.05 1.899336E+02 2.3929E+125
1.662548E+00 289.05 2.216509E+02 2.689E+128
1.888062E+00 296.05 2.517165E+02 3.02E+131
2.102132E+00 303.05 2.802562E+02 3.3899E+134
2.305607E+00 310.05 3.073835E+02 3.803E+137
2.499254E+00 317.05 3.332005E+02 4.2644E+140
2.683765E+00 324.05 3.577996E+02 4.7794E+143
2.859770E+00 331.05 3.812645E+02 5.3541E+146
3.027836E+00 338.05 4.036711E+02 5.9953E+149
3.188481E+00 345.05 4.250883E+02 6.7104E+152
3.342177E+00 352.05 4.455790E+02 7.5077E+155
3.489351E+00 359.05 4.652003E+02 8.3964E+158
3.630398E+00 366.05 4.840046E+02 9.3868E+161
Chemical CHEMCAD
Modelo CHEMCAD Log CHEMCAD Diferença A 9.396380E+01 A 1
110.121289016 11897.02115 B -4.816000E+03 B 1
113.173436293 4856.163169 C -3.450200E+01 C 1
116.225256325 1078.358913 D 3.685800E-02 D 1
119.276766367 2.857742501 E -1.657800E-05 E 1
122.327982344 1162.574248
125.378918985 4167.308144
128.429589939 8690.208163
131.480007878 14456.80379
134.53018459 21236.08005
137.580131056 28833.18562
140.629857525 37083.45289
143.679373577 45847.47627
146.728688178 55007.04771
149.777809734 64461.78949
152.826746137 74126.35601
155.875504801 83928.10186
158.924092706 93805.1332
161.972516429 103704.6752
654344.5936
Propriedades físicas do Carbamato de Amônio

Dados de tensão superficial do Carbamato de amônio

Tensão superficial (dyne/cm) Temperatura (K)

270 24.54784
280
290
300
310
320
330
340
350
360
370
380
390
400
410
420
430
440
450
460
470
480
490
500
510
520
530
540
550