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MEMBRANE TECHNOLOGY

The new generation of


MBR stands tall

O
ne of the more recent applications of membrane
Peter Miller and Ronald vanʼt Oever of Norit X- technology is in membrane bioreactors (MBR). The
Flow, and Stephan van Hoof of Norit enlighten us MBR design target is an ideal combination of bacteria
on the development and successful application of to reduce the organic content of waste and membrane
technology to remove particulate matter to produce high quality
a new generation of MBR — the side stream air lift
water for reuse.
MBR The first generation of MBRs were developed some
20 years ago for industrial applications and used tubular

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MEMBRANE TECHNOLOGY

second generation of MBRs. Development objectives


In the second generation MBR the The key development objective for
membranes are submerged in the BR. the AirLift MBR was to produce high
This is not an ideal arrangement as quality product water using biological
the BR requires good mass transfer of degradation and membrane filtration
oxygen from the air i.e. a fine bubble at the lowest whole of life cost while
size, while the membrane requires simplifying system control and
large bubbles to give adequate flow management when compared with
across the membrane surface to control submerged MBR.
fouling. This problem was addressed by The objectives to achieve the key
separating the BR tank and submerged objective were: 1) Use UF filtration (high
membrane tank so each can be operated water quality); 2) Operate at a high flux
at near optimum conditions. Although (low CAPEX/OPEX); 3) Low energy
submerged membrane systems in consumption (low OPEX); 4) Long
the second generation are claimed to membrane life (low OPEX); 5) Position
have low energy consumption, small membrane system outside of tanks
footprint and can be adapted to existing (simple maintenance); and 6) Small foot
BRs, they are not ideal because of poor print (low CAPEX).
control of operating variables, difficult
maintenance, relatively low flux and the AirLift concept design
risk of bio-contamination. As the BR is established technology
The AirLift system.
To address the deficiencies in the in MBR solutions, design efforts were
membranes in cross-flow mode to treat second generation MBR, Norit X-Flow focused on the membrane system
liquors with relatively high solids content. have developed, over seven years, leading to the development of the AirLift®
The bioreactor (BR) and membrane the third generation MBR for municipal UF membrane system to separate the
plant were separate process units. reuse using their expertise in the first liquid phase (effluent) from the MLSS
The advantage of better control of the generation MBRs. The third generation in the BR.
cake layer build-up giving a consistent uses vertical tubular membrane modules The UF system receives MLSS
flux is offset by complexity and high placed outside of the BR with air sparging from the BR by means of a controlled
energy costs and consequently was to control the buildup of biologically circulation/booster pump. The circulation
not commercially viable for treating active cake on the membrane surface. pump is used ensure a relatively constant
municipal wastewater. The AirLift™ MBR is energy efficient, flow of sludge from the bottom to the top
MBR became attractive for larger has a small footprint, simple to automate of the membranes.
flows when pneumatics (air scouring) and maintain, uses robust long-life The AirLift system, where the
is used to refresh the flow across membranes and produces high quality membrane module is mounted vertically,
the membrane rather than hydraulics UF product water. is a modification of proven conventional
giving a significant reduction in energy This paper reviews the development cross-flow system design where the
consumption compared to cross-flow of the product through pilot plant proof membranes are used in a horizontal
MBR. Consequently, MBR became of concept, demonstration plant trials for configuration.
viable for municipal reuse technical and commercial optimisation A vertical orientation allows the
leading to the and presents case studies of commercial cross flow to be maintained by both a
installations. circulation pump and injecting air at
the bottom of the membrane module to
circulate the MLSS via a “air-lift” pump
effect.
The injected air provides high
turbulence at the membrane surface to
maintain system flux. The net benefit of the
AirLift design is the use of proven tubular
membrane technology with significantly
reduced energy consumption.
Filtrate production in the AirLift
design is regulated by a dedicated filtrate
pump. A periodic short pulse from a
back-pulse pump also helps to maintain
Tubular membrane module. a high flux rate.
The concept uses membrane

Water & Wastewater Asia • January/February 2008 39


MEMBRANE TECHNOLOGY

Austrian pilot results Ootmarsum pilot results Peak Average

Flux (L/m2h) 45 – 60 45 – 60 Time 2 hours (2x per day) except during peak

Circulation flow (m3/h) 25 20 Flux rate 45 gfd 76.5 Lmh 30 gfd 51 Lmh

Airlift flow (Nm3/h) 15 10 Circulation flow 95 gpm 21.6 m3/h 70 gpm 15.9 m3/h

Back-pulse flow (L/m2h) 350 350 Airlift flow 6 SCFM 10 m3/h 6 SCFM 10 m3/h

Interval (Filtration/Backpulse) 7 min / 4 s 7 min / 7 s Backwash flow 240 gfd 408 Lmh 240 gfd 408 Lmh

MLSS (g/L) 9 – 13 10 – 14 Backwash time 6s

Table 1: Pilot results from Austria and Holland. Backwash interval 10 min

Drain/Flush Every 24 backwashes


modules assembled from Norit X-Flow 5.2 mm ID tubular
MLSS 10 – 11 g/L
membranes. The membranes are fabricated using PDVF on
the inside of a non-woven polyester tube and have an absolute DO 1.7 mg/L
pore size of 35 nanometres (0.035 µm). Table 2: Data from San Diego report; MWH, Oct. 2006.
These membranes have been used in industrial and
municipal applications for some 20 years and have a proven The plant was further expanded to multiple modules and
life of over 10 years. the plant optimised. The results, tabulated in Table 1, for
steady state operating conditions established the capability
Proof of concept of the concept.
A number of pilot and demonstration plant studies were A second pilot was installed in Holland where initially a
conducted over a 5-year period to prove the concept and single module pilot was compared to submerged systems
establish the capability of the concept. operating at the same site. A Dutch engineering and consulting
The first pilot was operated in Austria in the late nineties in company (DHV, Amersfoort) conducted the tests in cooperation
association with local universities and an engineering company. with the Dutch Sewage Water Works Association (Stowa).
The BR used municipal effluent and initially 75-mm tubular pilot A spin off pilot from this second plant, where initial settings
membrane modules later progressing to 200-mm commercial were established, now runs at a site in the city of Ootmarsum
modules as operating conditions were established. in the east of Holland where a municipal WwTP plant is under

Graph of trans-membrane pressure (tmp), flux and permeability of the pilot in Holland.

40 Water & Wastewater Asia • January/February 2008


MEMBRANE TECHNOLOGY

Graph of trans-membrane pressure (tmp), flux and permeability — San Diego pilot.

construction incorporating a 3.5-MLD X-Flow AirLift MBR. tabulated in Table 2 on page 40.
The plant should be on-line in the second half of 2007. The The flux level (and power consumption) found in the pilot
operating parameters for the pilot are tabulated in Table 1. An plant at a steady state flux rate of about 50 Lmh and a peak
overview of the typical performance of the Ootmarsum pilot is flux of 75 Lmh twice for 2 hours each day are significantly
shown in the graph on page 40. higher than a submerged MBR. The peak flux is designed to
The third pilot to be described is in San Diego, California, handle diurnal variations in the feedwater flow.
and it has achieved Title 22 approval for Norit X-Flow partner An overview of the typical performance of the San Diego
Parkson Corporation. Typical operating data for the pilot is pilot is shown above.

Some highlights of the results to date


Over the past two years, plant optimisation has reduced the
consumed power from 0.55 kWh/m3 to 0.25 kWh/m3 of UF
product water; among the lowest in the industry to date.
By optimising the hydraulic cross flow and the flow rate of
air into the distributing section of the aerating device at the
base of the membrane, significant gains were made in flux
and consumed power.

Proven concept to market reality


Over the last seven years, the Norit AirLift MBR has proven
itself in both pilot and full scale plants, showing the capability
of using membranes in a clean set up of easily serviced
membranes skids installed external to the BR.
Operators look forward to running MBR plants from the

Water & Wastewater Asia • January/February 2008 41


MEMBRANE TECHNOLOGY

Glen Meadows – 0.38 MLD. Saddle Ridge – 0.19 MLD.

Figure 1: Membrane skids positioned around the BR tank in the Palm Jumeirah.

Figure 2: The Palm Jumeirah.

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MEMBRANE TECHNOLOGY

HMI. This is now a reality as even the membrane cleaning can application at a whole of life cost at least equal to or better
be executed automatically or by the push of a button without than submerged MBR has been achieved while offering a small
having to handle effluent covered modules. footprint, ease of automation and simple maintenance. The
Currently, several smaller plants are operating in the USA third generation of MBR is now a commercial reality. WWA
and a number of larger plants are under construction in Europe Enquiry No: 003
and the Middle East.
The plants operating in the USA are treating municipal
wastewater in small communities and pictures of
two of these plants, operational since 2004, are
shown on the left.

Larger municipal plants


A number of larger plants are now under construction.
The clean setup of the plant can be seen in a
few examples in this article. Page 38 shows the
Ootmarsum BR with the penetrations for return lines
from the membrane skids. The 3.5-MLD Ootmarsum
municipal WwTP in the Netherlands is designed with
six identical skids to treat a variable feed volume
and quality.
Figure 2 below shows the Palm Jumeirah, Dubai,
which is a prestige real estate development supplied
with potable water from SWRO and reuse water from
a 17-MLD Norit X-Flow UF AirLift MBR currently
under construction. (Figure 1 shows the membrane
skids positioned around the BR tank).
Figure 3 on the right shows a 0.76-MLD
installation at the Port of the Islands in USA. Figure
4 (bottom right) shows the membrane train at the
4.2-MLD municipal WwTP in Millsborough, USA.

Conclusion
The original challenge of finding a way to apply
tubular side stream membranes into a MBR Figure 3: Port of the Islands.

Water & Wastewater Asia • January/February 2008 43

Figure 4: Millsborough municipal WwTP.

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