MATERIAL SAFETY DATA SHEET issued: 21.08.

2008
ENGINE CLEANER updated: 26.08.2015

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. PRODUCT IDENTIFIER

TRADE NAME: ENGINE WASH PREPARATION

Identity of the individual substances which influence the classification of a mixture thereof.
Diethanolamine – registration no. 01-2119488930-28-XXXX
Sodium salt of sulfated ethoxylated lauryl alkohol C12-14 – registration no. 01-2119488639-16-XXXX

1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST:
The preparation is intended for engine cleaning and removal of lubricant and oil stains.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:

DISTRIBUTOR NAME AND ADDRESS: INTER CARS S.A.

Ul. Gdańska 15, Cząstków Mazowiecki
05-152 Czosnów
Telefon 022 7141000, adres mailowy do opiekuna produktu
Indeks produktu: 1305-01-0019E, 1305-01-0018E, 1305-01-0031E
1.4. EMERGENCY TELEPHONE NUMBER:
Emergency telephone: 112, FIRE BRIGADE 998 or the nearest local unit of the National Fire Service
National Centre for Toxicological Information: (42) 631 47 24
SECTION 2. HAZARDS IDENTIFICATION
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE
Classification in compliance with the regulation 1272/2008/EC
Skin Irrit.2 H315, Eye Dam. 1 H318
Causes skin irritation. Causes serious eye damage.

2.2. LABEL ELEMENTS

Hazard symbol and signal word

DANGER
Hazard statements

H315 Causes skin irritation.

H318 Causes serious eye damage.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352 IF ON SKIN: wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P501 - Dispose of contents/container to properly marked containers designed for selective waste collection and
emptied by an authorized company.
2.3 Other hazards
There is no information on fulfilment of PBT or vPvB criteria according to Annex XIII of the REACH Regulation .

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

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3.1. COMPONENTS OF THE MIXTURE
The mixture contains: phosphonates, aliphatic hydrocarbons, anionic and non-ionic surface-active agents
Classification
Composition EC No. CAS No. Registration No. Content
CLP
01-2119457892-27-
Skin Corr. 1A
XXX
Sodium hydroxide 215-185-5 1310-73-2 1.2 % H314
011-002-00-6
H290
Flam. Liq. 2
Eye Irrit. 2
01-2119457558-25- STOT SE 3
Isopropyl alcohol 200-661-7 67-63-0 5% H225
XXXX
H319
H336
Flam. Liq. 3
1-Methoxypropan-2-ol 01-2119457435-35- STOT SE 3
203-539-1 107-98-2 5%
XXX H226
H336
Acute Tox. 4
STOT RE 2
Skin Irrit. 2
01-2119488930- Eye Dam. 1
Diethanolamine 203-868-0 111-42-2 3%
XXXX H302
H373
H315
H318
Skin Irrit,2, H315
Sodium salt of sulfated Eye Dam. 1
01-211948863-16-
ethoxylated lauryl alkohol 500-234-8 68891-38-3 5% H318
XXXX
C12-14 Aquatic Chronic3,
H412

SECTION 4. FIRST AID MEASURES

4.1. DESCRIPTION OF FIRST AID MEASURES
4.1.1 In case of contact with skin: Wash skin thoroughly with plenty of water. Seek medical attention when
needed.
4.1.2 In case of contact with eyes: Rinse with plenty of water for approx. 15 minutes. Seek medical advice,
preferably an ophthalmologist.
Note: persons that might be exposed to eye contamination should be
instructed on the necessity and manner of immediate eye washing.
4.1.3 When swallowed: Do not induce vomiting. Do not use neutralizing substances. Seek
medical attention immediately.
4.1.4 When inhaled: Remove the affected person from the exposed area, keeping your own
safety. Provide fresh air. Protect from heat loss. If the affected person is
unconscious, he/she should be laid in a safe position and his/her breath
should be controlled. Perform artificial respiration when the person is not
breathing. Seek medical attention immediately.
-
4.2. Main acute and delayed
symptoms and effects of
exposure:
4.3. Indication of any immediate
medical attention and special
treatment needed:
SECTION 5. FIRE-FIGHTING MEASURES
5.1. EXTINGUISHING MEDIA
No limitations for extinguishing media

5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE - no particular hazards
5.3. ADVICE FOR FIREFIGHTERS
Insulating breathing apparatus for protection of respiratory tract, protective overalls. Protective goggles.
SECTION 6. ACCIDENTAL RELEASE MEASURES
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES

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Personal protection should include protective clothing, rubber gloves and helmet with a face cover or facial part
of a gas mask or goggles fitting tight to face. Do not inhale vapours. Provide ventilation.
6.2. ENVIRONMENTAL PRECAUTIONS
Locate leakage and remove it immediately avoiding excessive risk. Protect the area where there has been a leak
against possible spreading by sealing. Avoid formation and inhalation of vapours.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP
Cover with sand or soil. Place in tight, marked containers and hand over for disposal. Rinse the surface with
plenty of water.
6.4 REFERENCES TO OTHER SECTIONS
Disposal considerations – Section 13.
Individual protection equipment – Section 8.
SECTION 7. HANDLING AND STORAGE
7.1. PRECAUTIONS FOR SAFE HANDLING
Avoid spilling, contact with eyes and skin and splashing on clothes. Avoid inhalation of vapours. Use efficient
ventilation in rooms. Handle in accordance with the occupational health and safety guidelines.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Store in original, tightly closed containers, in dry and ventilated storage rooms, at temperatures above 10°C.
Observe storage regulations. Take necessary measures to prevent the preparation from getting into sewage
system, water reservoirs, rivers, underground waters and soil due to leaks from containers and transmission
systems. Use as directed. Protect form moisture.
7.3 SPECIAL END USE
No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. CONTROL PARAMETERS

MAC - NaOH 0.5 mg/m3
TLV-STEL - NaOH 1.0 g/m3
MAC - Isopropyl alcohol 900 mg/m3
TLV-STEM - isopropyl alcohol 1200 mg/m3
MAC - 1-methoxypropan-2-ol 180 mg/m3
TLV-STEM - 1-methoxypropan-2-ol 360 mg/m3
MAC - diethanolamine 9 mg/m3

8.2. EXPOSURE CONTROLS

The individual protection equipment to be used should meet the requirements of the Regulation of the Minister of
Economy of 21 December 2005 on the elementary requirements for personal protective equipment (the Official
Journal of Laws of 2005, No. 259, item 2173). The personal protection equipment should be cleaned for re-use.
Occupational exposure controls: Local exhaust ventilation and general room ventilation. Avoid contact with
eyes.
Individual protection equipment: Rubber protective gloves, safety goggles, suitable protective clothing and
safety boots. Provide eye wash station for immediate eye rinsing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
9.1. Appearance: Liquid, colourless
9.2. Odour: Characteristic
9.3 Odour threshold: -
9.4. pH: Approx. 12-13
9.5. Melting/freezing point: -
9.6. Starting boiling point and boiling -
point range:
9.7. Flash point: -
9.8. Evaporation rate: -
9.9. Flammability: -
9.10. Upper/lower flammability limit or -
upper/lower explosive limit:
9.11. Vapour pressure: No data available
9.12. Vapour density -
Relative density: -

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9.13. Solubility: All-water-soluble
9.14 Partition coefficient: -
n-octanol/water
9.15 Auto-ignition temperature: -
9.16 Decomposition temperature: -
9.17 Viscosity: -
9.18 Explosive properties: -
9.19 Oxidising properties: -

SECTION 10. STABILITY AND REACTIVITY

10.1. REACTIVITY – the mixture is not reactive
10.2. CHEMICAL STABILITY
The product is stable under normal use conditions.

10.3. POSSIBILITY OF HAZARDOUS REACTIONS - none

10.4. CONDITIONS TO AVOID - none
10.5. INCOMPATIBLE MATERIALS - alkali metals
10.6. HAZARDOUS DECOMPOSITION PRODUCTS - none
SECTION 11. TOXICOLOGICAL INFORMATION
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS
Effects on skin: May cause irritation, redness and itching.
Effects on eyes: Causes irritation, burning sensation, lacrimation.
Effects after inhalation: May cause serious respiratory tract irritation. Low concentration may cause
throat irritation, burning sensation in lungs, coughing and dyspnoea. May
cause pain and vomiting.

Carcinogenicity: Not classified as carcinogenic.

Mutagenicity: Not classified as mutagenic.
Long-term effect: -

SECTION 12. ECOLOGICAL INFORMATION

12.1. TOXICITY
LC50>100mg/l/48h (isopropyl alcohol) - for fish
EC50>100mg/l/24h (isopropyl alcohol) - for daphnia
EC50>100mg/l/72h (isopropyl alcohol) - for algae
LC50 fish = 45.4 mg/l/ 96 h for sodium hydroxide
EC50 (daphnia)=76 mg/l/24h for sodium hydroxide
12.2. PERSISTENCE AND DEGRADABILITY
Freely soluble in water.
12.3. BIOACCUMULATIVE POTENTIAL
12.4. MOBILITY IN SOIL
Avoid soil contamination. There is no data available for mixture.
12.5. RESULTS OF PBT AND VPVB ASSESSMENT
There is no data available for identification of mixture.
12.6 Other harmful effects – no data
SECTION 13. DISPOSAL CONSIDERATIONS
13.1. WASTE TREATMENT METHODS
Observe the regulations:
The product residues should be utilized according to the Act of 22 December 2012 on waste and Directive of the
European Parliament and of the Council 2008/98/EC of 19 November 2008 on waste.

Mixture waste: Hazardous waste. Do not empty into drains. Do not store in municipal
dumps. Consider possibility of reuse. The recovery and waste treatment
should be carried out in accordance with the applicable regulations.
Package waste: single use packaging shall be utilized in an authorized disposal plant. The
recovery (recycling) and waste treatment should be carried out in
accordance with the applicable regulations.

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 The independent utilization shall be carried out in accordance with the Act
on environment protection and the Act on packages and package waste –
Act of 14 December 2012 on waste.

SECTION 14. TRANSPORT INFORMATION

The preparation BIOSOL SDS is not subject to ADR regulations.
14.1. UN no.:
14.2. Proper shipping name:
14.3. Transport hazard class:
14.4. Packing group:
14.5. Environmental hazard:
14.6. Label number:
14.7. Air transport IATA/ICAO:
SECTION 15. REGULATORY INFORMATION
15.1. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE
This MSDS has been drawn up based on the following legal regulations:

Regulation of the Minister of Environment of 27 September 2001 on waste catalogue (the Official Journal of Laws
No. 112, item 1206)
Regulation (EC) No. 648/2004 of the European Parliament and of the Council of 31 March 2004 on detergents, as
amended by Regulation (EC) No. 1336/2008 of 16 December 2008 (the Official Journal of the EU I 354/60 of
31.12.2008).
Regulation (EC) No. 1907/2006 of 18 December 2006 (REACH), as amended.
Regulation (EC) No. 1272/2008 of the European Parliament and of the Council of 16 December 2008 on the
classification, labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No. 1907/2006.
Commission Regulation (EC) No. 790/2009 of 10 August 2009 (the Official Journal of the EU I 235/1 of
05.09.2009).
Regulation (EC) No. 453/2010 of the European Parliament and of the Council of 20 May 2010 amending
Regulation (EC) No. 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH).
Act of 25 February 2011 on chemical substances and their mixtures (the Official Journal of Laws of 2011, No. 63,
item 322 and of 2012, item 908).
Regulation of the Minister of Health of 10 August 2012 on criteria and mode of classification of chemical
substances and their mixtures (the Official Journal of Laws of 2012, item 1018).
Regulation of the Minister of Health of 10 August 2012 on criteria and mode of classification of chemical
substances and their mixtures (the Official Journal of Laws of 2012, item 1018).
Regulation of the Minister of Health of 22 May 2012 on labelling places, pipelines and containers for storing or
containing dangerous substances or dangerous preparations (the Official Journal of Laws of 2012, item 601).
Regulation of the Minister of Health of 20 April 2012 on labelling dangerous substances and dangerous
preparations as well as certain mixtures.15.2. CHEMICAL SAFETY ASSESSMENT
The chemical safety assessment has not been carried out.

SECTION 16. OTHER INFORMATION

Source materials: manufacturer's material safety data sheet and Internet databases; Polish
and European legal regulations, professional literature.
Trainings: Workplace: required documents on completed OHS/fire trainings and on-the-
job trainings.
MSDS describes the product with regard to occupational health and safety. This information is not a guarantee of
product properties.
The mixture classification has been carried out based on information supplied by manufactures and
suppliers of components according to the Regulation of the European Parliament and of the Council (CE)
no. 1272/2008, art. 6, par. 1.
Before mixing with other substances, it is necessary to make sure that no additional hazards will occur.

List of H-statements:

Skin Corr. 1A - skin corrosion

Flam. Liq. 2 - flammable liquid
Eye Irrit. 2 - irritating to eyes

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STOT SE 3 - target organ toxicity - single exposure
Acute Tox. 4 - acute toxicity
Skin Irrit. 2 - irritating to skin
Eye Dam. 1 - serious eye damage
H225- highly flammable liquid and vapours
H319 - irritating to eyes
H226 - flammable liquid and vapours
H336 - may cause drowsiness or dizziness
H302 - harmful if swallowed
H335 - may cause respiratory system irritation
H314 - causes serious skin burns and eye damage
H290 - may cause metal corrosion
H373 - may cause organ damage by long-term or repeated exposure
H315 - causes skin irritation
H318 - causes serious eye damage

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