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SOLUTIONS
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of g.
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Mock Test 1
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(Paper-2)
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Regd. Office: Aakash Tower, Plot No.4, Sector-11, Dwarka, New Delhi-110075. Ph.: (011) 47623456.Fax : (011) 47623472
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2 Mock Test 1 (Paper-2) - Answers & Hints

MOCK TEST - 1
(Paper - 2)

ANSWERS
CHEMISTRY MATHEMATICS PHYSICS
1. (B) 20. (C) 39. (A)

2. (C) 21. (C) 40. (B)

3. (A) 22. (B) 41. (D)

4. (B) 23. (D) 42. (C)

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5. (B, C, D) 24. (A, C) 43. (A, C)

6. (A, B) 25. (A, C) 44. (A, D)

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7. (A, B, C) 26. (A, B, C) 45. (A, B, C, D)

46. (B, C, D)
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8. (A, B, C) 27. (A, B. C, D)

9. (B, C) 28. (A, B, C, D) 47. (A, B, C, D)

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10. A→ (q) 29. A → (q) 48. A → (p, r, t)

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B → (p, r) B → (p, q, r, s) B → (p, q, s, t)

C → (r, s) C → (p) C → (p, r)

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D → (r, s, t)
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D → (s, t) D → (p, q, r, s, t)
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11. A → (p, r) 30. A → (r) 49. A → (p, q, r)

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B → (q, t) B → (q) B → (q, r, s, t)

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C → (s) C → (s) C → (p, r)

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D → (r) D → (p) D → (s)

12. (1) 31. (2) 50. (1)

13. (4) 32. (1) 51. (9)

14. (4) 33. (1) 52. (3)

15. (1) 34. (6) 53. (2)

16. (7) 35. (4) 54. (5)

17. (4) 36. (2) 55. (1)

18. (2) 37. (6) 56. (2)

19. (0) 38. (5) 57. (3)

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Mock Test 1 (Paper-2) - Answers & Hints 3

ANSWERS & HINTS

PART - I : CHEMISTRY

1. Answer (B) ( a – x ) × 1+ x ×( n5+3 )+ = N × 35

At t = t,
Let the transition occurs in between the levels n1 & n2 . (F o r X )
n+ (F o r X )
Thus, if n2 > n1 , then given
4x = 13N
n 1 + n2 = 5
13
n2 – n1 = 3 x= N
4
So, n1 = 1 and n2 = 4
2303
. 22 N
1  1 1  Now, K= log
Therefore, = R H .Z2  2 – 2  15  13 
λ  1
n n 2   22 – N
 4 

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1 1 1  2303
. 22 × 4
= 109678 × 2 2  2 – 2  log
λ 1 4  K=
15 75

c
g.
1 15 2303
.
= 109678 × 4 × K= × .0693 = 1064
. × 10 –2 min– 1
λ
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16 15
λ = 2.43 × 10–6 cm 5. Answer (B, C, D)
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2. Answer (C) In BF4– , partial overlapping is lost.

Imidazole will behave as a base. Conjugate acid III is
In I3– , two I atoms are present on axial position. So, I – I
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more stable than conjugate acid IV.

bond length increases. In ICl–2 , two Cl atoms are present on
H
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H axial position So, I –Cl bond length increases.

N N
6. Answer (A, B)
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Fact.
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N N 7. Answer (A, B, C)
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H For the liquefaction of gas, ‘a’ is responsible not ‘b’.

H Higher is the value of ‘a’ easier is the liquefaction. Other
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Resonance stabilized conjugate acid statement are fact.

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8. Answer (A, B, C)
3. Answer (A)
In [NiCl4 ]2– , Ni has sp 3 hybridisation. In other cases, dsp 2
Due to isotopic effect. hybridisation of central atom is present.
4. Answer (B) 9. Answer (B, C)
n+ (n + 3)+
X X (A) In 10–6 M CH3COOH, α is not negligible. So, pH is
Millimole, at t = 0 a 0 always more than 6.
t = t (a –x) x (B) The solubility of AgCl in NH4OH solution becomes
– n+ (n – 1)+
more because it forms complex.
e +X X
– (n+3)+ (n – 2)+
(C) In case strong acid & weak acid, [H+ ] produced from
5e + X X weak acid is negligible in comparision to [H+ ] from
strong acid
Let normality be N for reducing agent So, [H+ ] = 10–2
At t = 0, a × 1 = N × 22 pH = –log[H+ ] = –log10–2
a = 22N
pH ≈ 2

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4 Mock Test 1 (Paper-2) - Answers & Hints

(D) In this case, [H+ ] from H2O is considered 14. Answer (4)

[H+ ] = 10–7 + 10–7 (from H2O)

CHCOOH
3 + NaOH CHCOONa
3 + HO
2
= 2 × 10–7 M At t = 0 120 ml 0.1M 40ml 0.1M O O
pH = 7 – log2 = 7 – .3 At t = t 80 ml 0.1M O 40ml 0.1M 40ml 0.1M

pH = 6.7 It forms acidic buffer solution.

10. Answer A(q), B(p, r), C(r, s), D(s, t)
H +  = Ka ×
[ Acid]
Fact. [Salt ]
11. Answer A(p, r), B(q, t), C(s), D(r) 80 × 0 .1
H +  = 2 × 10 –5 ×
(A) 2Cu 2+ + K4[Fe(CN)6] 
→ Cu 2 [Fe(CN)6] + 4K + 40 × 0.1
(Chocolate brown ppt) [H+ ] = 4 × 10–5
It also gives black ppt. of CuS with H2S in dil . HCl
Hence, x = 4

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(B) 4 Fe3+ + 3K4[Fe(CN)6]  → Fe4[Fe(CN)6]3 + 12K+
Ferriferro cyanide 15. Answer (1)
(Prussian blue) +1

Fe + 3KCNS  → Fe(SCN)3 + 3K+ → 2 K3 [Cu ( CN) 4 ] + 2 K2S O4 + ( CN )2

2 CuSO4 + 10 KCN 

c
3+
(excess)
Ferrithiocyanate (Red ppt.)
(C) Ni2+ gives DMG test & forms rose red ppt. of nickel
g.
16. Answer (7)
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dimethyl glyoxime. Only primary amines give positive carbyl amine reaction.
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+ CH2– NH 2 H3C NH2

(D) Pb2 + + H2 S →
H
PbS + 2H
+
NH2
( Blackppt )
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, ,
12. Answer (1)
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When CO is converted into CO+ then one electron removes H2N CH3 H 3C NH 2 H 2N H H NH2
from σ*2s.
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H H H H H CH3 CH3 H
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13. Answer (4)

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As the formed carbocation is fairly stable, the Beckmann 17. Answer (4)
rearrangement now goes via a fragmentation mechanism. Orthorhombic crystal system contains all the 4 types of
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Me Me IV unit cell i.e. simple, body centered, face centered and end
Me
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Me :N ≡ C – Me centered.
Me C
C Me Me 18. Answer (2)
N In the above electrolysis, the weight of anode is decreased
OH2 due to dissolution of copper and same weight of cathode is
I III
increased due to deposition of copper.
Me Ph Ph II
+ :N ≡ C – Ph 19. Answer (0)
C Ph C
Me
→ [ PCl4 ] [ PCl6 ]–
+
C Me Me 2 PCl5 
( Gaseous ) ( Solid)
N
In gaseous PCl5, sp 3d hybridisation is present. So, total
OH2
number of hybridised atomic orbitals = 5 + 5 = 10
∴ Two carbocation and two cyanides lead to formation
of four amides. In solid PCl5, sp 3 & sp 3d 2 hybridisation is present. So, total
number of hybridised atomic orbitals = 4 + 6 = 10

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Mock Test 1 (Paper-2) - Answers & Hints 5

PART - II : MATHEMATICS
20. Answer (C) = 2 sin(2θ + φ) sinφ + 3cos2 φ
21. Answer (C) 2
 1  10 10
We find thet = − 3 t −  + ≤ , t = 1|sin φ|
 3 3 3
∞ ∞ ∞ ∞
Equality can be achieved when
∑ ∑  4 m  4m ∑ ∑  4n  4m
1 1
k= =
m =1 n =1 4  n
m =1 n =1 4 
n
  +    +  1
 m  m n   
n m n  sin (2θ + φ) = 1 and sinφ =
3

2
∞  ∞ m
∞   2 2
2k = ∑ ∑ m n =  ∑ m
1 16
⇒   = (a, b, c) =  2 , 2 , 4 
m =1 n =1 4
.
4  m =1 4  81  
m n
25. Answer (A, C)

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⇒ 8
k= ⇒ 81k = 8 A B C
81 Let x = tan , y = tan , z = tan
2 2 2

c
g.
22. Answer (B)
A B B C C A
ur ur then 1 = tan tan + tan tan + tan tan
Let a = x1 i$ + x 2j$ + x 3k$ , b = y1 i$ + y 2 j$ + y 3 k$ ,
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2 2 2 2 2 2
ur A+ B  
c = i$ + j$ + k$  C A B
 1− tan 2 tan 2  1 − tan 2 tan 2  = 0
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⇒
  
r r r r r r
Then, a . b = a . c = b . c = 0
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A B
r r r Note that tan tan = xy ≠ 1 ,
⇒ a, b, c are mutually perpendicular vectors. We know 2 2
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that the sum of squares of projection of a unit vector on Otherwise z(x + y) = 0 ⇒ z = 0

w

three mutually perpendicular vectors is 1, hence

C A+ B A+ B C
+ = 90°
w

∴ tan tan = 1 or
x12 y12 2 2 2 2 2
+ =
://

x12 + x22 + x32 y 12 + y 22 + y 32 3 ⇒ A, B, C are the angles of a ∆ABC

tp

23. Answer (D) x y z

Now = =
5( x + 1) 12( y + 1) 13( z 2 + 1)
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2 2
We can select the ball at position 5 in 10 ways then the
ball at the corner can be selected in 9 C3 ways and can sin A sin B sin C
⇒ = = ⇒ sinC = 1
be arrnged in 2 ways. 5 12 13
∴ Total number of arrangements possible 5 12
⇒ sin A = , sin B =
= 10 × (9 C 3 × 2) × 6! = 1209600 13 13
24. Answer (A, C) x 5 1
⇒ = ⇒ x = 5,
a+c x +1
2
26 5
The condition is equivalent to b =
1 − ac 3 2
y= , , z =1
2 3
Let θ = tan–1 a, φ = (tan–1 c), we have b = tan(θ + φ)
1 2   1 2 
k=
2
−
2
+
3 Hence  , ,1  and  − , − ,1  are the required
5 3   5 3 
1 + tan θ 1+ tan ( θ + φ) tan φ + 1
2 2 2
possible triplets.

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6 Mock Test 1 (Paper-2) - Answers & Hints

26. Answer (A, B, C) 29. Answer

We have A(q), B(p, q, r, s), C(p), D(p, q, r, s, t)
xn+2 xn+1 – xn+1 xn = 1 By using rectangle
⇒ {xn+1 xn } is an A.P. with first term 1 and common
∫
1 2
difference 1 Area OPQT < e x dx < area OTRS
0
Hence xn+1 xn = n, n = 1, 2, 3,...
n + 1 n +1 1
∫e x2
⇒ xn + 2 = = xn , n = 1, 2, 3,... ⇒ 1< dx < 1.e
xn +1 n 0

2003 2003 2001 y

x2004 = . x2002 = . x2000...
2002 2002 2000 S R(1, e)
2003.2001...3
= x2 Q(1, 1)
2002.2002...2 P(0, 1)
27. Answer (A, B, C, D) T
O x
y (1, 0)
P( h, k) ⇒ a=e

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(–a, a) ( a, a) By using triangle
A 1
∫e x2

c
x Area OPQT < dx < area OPQT + area of ∆PQR
C 0

(–a, –a) g.⇒ 1<

∫e
1
x2 1
ng
( a, –a) dx < 1 + (1)( e − 1)
0 2
e +1
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1
∫e
PC < PA x2
⇒ 1< dx <
(PC)2 < (PA) 2 0 2
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⇒ k 2 < –2ah + a 2 ⇒ y2 + 2ax – a 2 < 0 ⇒ 2b = e + 1

which represents the inner part of the parabola 2
Also x ∈ (0,1) ⇒ e < e
x x
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y2 + 2ax – a 2 = 0
Similarly we may get four other parabolas
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1 1
∫e ∫
x2
y2 – 2ax – a 2 = 0 ⇒ 1< dx < e x dx
0 0
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x2 – 2ay – a 2 = 0
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x2 + 2ay – a 2 = 0 x
28. Answer (A, B, C, D) y=e (1, e)
tp

3 9 (0, 1) x2
(A) f   = y=e
ht

2 4
 3  3
⇒ f  f   =
  2 2 1
∫e x2
⇒ 1< dx < e − 1
0
   3   3
f  f  f    = f   ⇒ c = e –1
   2   2
30. Answer
A(r), B(q), C(s), D(p)
   5  
(B) 1 + f  f  f     = 1+ f ( f ( 2)) (A) GOOGLE
   2  
Case (i)
5
= 1 + f (1) = 2 = f   GOOG ,L,E
2
Number of such words = 3! = 6
(C) f(f(f(2))) = f(f(1)) = f(1) = 1 Case (ii)
Similarly 'D' can be solved.

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Mock Test 1 (Paper-2) - Answers & Hints 7

GOO_ L ,_  A+ B + C B C 
= 2sin  + − 
Number of such words = 2 × 2 × 3 = 12  2 2 2
Case (iii)
B C
= 2cos  − 
GOO_ _G
2 2 
41
Number of such words = = 12
2!
A  B−C  A
Total number of such words = 30 ⇒ AA1 cos = 2cos   cos
2  2  2
3 1
– x3 1– 5
+  B−C   B+C 
x x6 = 2cos   sin  
(B) lim =1  2   2 
x → –∞ 3 2 
x 
 x2 
–1
= sin B + sin C
Hence,

om
(C) A B C
AA1 cos + BB1 cos + CC1 cos
2 2 2

c
Any selection of 4 vertices gives one point of = 2(sin A + sin B + sin C)
intersection inside hexagon.
∴ Required number = 6 C4 = 15 g. A B C
ng
AA1 cos + BB1 cos + CC1 cos
⇒ 2 2 2 =2
 5 3 3 sin A + sin B + sin C
(D) The co-ordinates of point P are  , 
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2 2 
32. Answer (1)
4
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e= Let P(α, β) be a point on the centre y = tan –1 x, whose

5
image in y = x is (β, α).
∴ S = (4, 0)
w

S′ = (–4, 0)
w

SP = 3
w

S′P = 7
SS′ = 8
://

5
7 × 4 +3 ×–4 +8 ×
tp

2
x-coordinate of incentre =
7 + 3 +8
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= 2
31. Answer (2) From given information

We have, π π
CQ = and PQ =
A 2 2 2 2

AA
C1 B1  π  π
22
⇒ CP =  2 =
 2 2  2
I
B C π2
CP2 = (α – β)2 + (β – α)2 =
A1 2

 A π π π
AA1 = 2sin  B +  ⇒ 2β−α=± ⇒ β−α= ⇒β=α±
 2 2 2 2

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8 Mock Test 1 (Paper-2) - Answers & Hints

⇒ (α, β ) lies on y = tan–1 x 35. Answer (4)

π π
⇒ β=α− Now α − = tan− 1 α
2 2

π π π
Since0 < α < π ⇒ − <α− <
2 2 2

 π
⇒ α = tan  α −  = − cot α
 2 Clearly

⇒ – α = cot α 1
P(E) = ,
4
When gives only one solution for α ∈ (0, π )
∴ k =4
33. Answer (1)
36. Answer (2)
Clearly

om
x2 + y2 – 1 = 0, x2 + y2 + x(λ – 3) + y(2λ + 2) + 2 = 0
 1+ x 
2
1+ x 2
sin −1  is defined for 2 x ≤ 1
Equation of common chord is


c
 2x 
(λ – 3)x + (2λ + 2)y + 3 = 0 …(i)
⇒ x = ±1
g.
Let (h, k) is point of intersection of tangent
ng
2009 Equation of chord of contact is
and minimum value of x
4018
+ 2 is attained at x = ±1
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x hx + ky – 1 = 0 …(ii)
But x = –1 does not satisfy the equation. (i) and (ii) are identical
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34. Answer (6) h k –1

∴ = =
We have, λ – 3 2λ + 2 3
w
w

1 On solving
sin30° = sin150° = − sin210° =
2
w

3k – 6h + 8 = 0
Locus is
://

3 1 3 1
⇒ sin3 10° = sin10 ° − , sin3 50° = sin50° − ,
4 8 4 8 3y = 6x – 8
tp

3 1
sin3 (−70°) = sin( −70°) − 8
ht

4 8 y = 2x –
3
⇒ a, b, − c are roots of Slope = 2
3 1 37. Answer (6)
f (t ) = t3 − t+ = 0
4 8 Let α1 , α2 , ....., αn be the roots of f(x) = 0
⇒
∑α = − p , ∑
a + b –c = 0
α iα j = p2
1 Then i 1
i≠ j
⇒ a + b = c, ab ( −c) = −
8

ab − bc − ca =
3 ∑α i
2
= p12 −2 p2 = 1 − 2 p 2
4
From A.M. – G.M. inequality
⇒ c −1
−a −1
−b −1
= −6

⇒ a −1
+b −1
−c −1
=6
∑α i
2
≥ (∑ α ) i
2(1/ n )
= ( pn2 )1/n = 1
n

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Mock Test 1 (Paper-2) - Answers & Hints 9

The set of polynomials is

Equality holds iff α i2 = 1∀ i
 x − 1, x + 1, x2 − x − 1, x 2 + x − 1, 
Thus 1 – 2p 2 ≥ n
 3 
 x + x − x − 1, x − x − x + 1 
2 3 2
⇒ n≤3
whenn = 3, αi = ±1, ∀ i 38. Answer (5)

when n = 2, 3, p 2 = –1 x10 (x + 5)20 (25 – 2x)30

Which goes the following polynomials x + x + 5 + 25 – 2x = 30

n = 1, f(x) = x + 1 or f(x) = x – 1 Applying concept of A.M., G.M.

n = 2, f(x) = x2 + x – 1 or x2 – x – 1 for x10 (x + 5)20 (25 – 2x)30 to be maximum

n = 3, f(x) = (x – 1)2 (x + 1) = x3 + x2 – x – 1 10
x= × 30
or f(x) = (x + 1)2 (x – 1) = x3 – x2 – x+1 60
= 5

om
PART - III : PHYSICS

c
39. Answer (A) 41. Answer (D)

Force applied by boy is given by,

g. λ 3λ 5λ
ng
Lengths at resonance are , , ..... .
4 4 4
mv 2 L2 λ
F= = 3
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r As difference between successive lengths = =

mr 2
constant, resonances are heard at regular interval.
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r r − L2 r/ 2 42. Answer (C)

∫ ∫
1
⇒ Work = F .dr = dr
w

m r3 A
z X→ A
z − 1Y + 0
+1 e +v
r
w

Nuclear mass of X = m – zm′

w

L2  2 1 L2
= − = =k Nuclear mass of Y = M – (z – 1)m′ = M – zm′ + m′
2m  r 2 r 2  2mr 2
://

Mass of positron = m′
tp

40. Answer (B) ⇒ Mass defect = ∆m = m – M – 2m′

and Q – value = ∆mc 2
ht

−1
 R ( k r )(2πrdr )  43. Answer (A, C)
R′ = Resistance of conductor =  ∫ 
0
0 l 
  f =
1
=
1
2π LCeq π 2 LC
1 c
⇒ R′ ∝ or R′ = di
R 3
R3 when i is max, =0
dt
In steady state, ⇒ Charge on two capacitors is same
2
V 2 V 2 R3  Q0 
σ(2πRl )T 4 = = [V = voltage applied, l =  2  2
= 2×   = Q0
R′ c 1 2
Li 0
length of conductor] 2 2C 4C
Q0
⇒ T∝ R ⇒ i0 =
2LC

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10 Mock Test 1 (Paper-2) - Answers & Hints

44. Answer (A, D) 46. Answer (B, C, D)

In reference frame of end

A, initial velocity of block =  Force 
v(left). Velocity at maximum elongation = 0. By work [Surface tension] = [Spring constant] = 
energy theorem, wspring = ∆k.E.  Length 

1 2 1  Force 
⇒ − kx = − mv 2 [Eg ] = [a] =  
2 2  Mass 

 Energy 
x=
m [Vg ] = [L f ] = 
⇒ v …(i)  Mass 
k
47. Answer (A, B, C, D)
⇒ Maximum elongation ∝ v

In ground’s frame, for system of block plus spring ε 3ε

I= =
2R 2R
1 2 3

om
wmotor + wspring = mv
2
3 1
= × Bω l 2
1 2 1 2 2R 2

c
wmotor – kx = mv

g.
2 2 Bωl
2

2
ng
1 2 1
wmotor = kx + mv2 = mv 2 (from (i))
2 2 R
ye

45. Answer (A, B, C, D)

.m

For TVx = constant 2R

3Bωl 2
w

(i) C = fR − R =
2 x 4R
w
w

dP 3 Bωl 2 3 B2 ωl 3
(ii) B = = x +1 Magnetic force F = ×l×B =
dV 4R 4R
://

−
V
tp

3B 2 ωl 3 l 3 B2 ωl 4
τ= × =
dV 1 4R 2 8R
ht

(iii) r = =−
VdT xT
3 B2 ωl 3
Thus, for ∴ Force to be applied at the end =
8R

2 48. Answer A(p, r, t), B(p, q, s, t), C(p, r), D(r, s, t)

(A) x = ⇒ C = 0 ⇒ Adiabatic process
f (A) Energy density is zero at a point if field is zero.
(B) Field at any point is vector sum of all the fields by
1 superposition principle.
(B) x = f ⇒ C < 0
(C) Equlibrium at a point is stable along if on slight
displacement along axis the net force acts towards
1 the equilibrium position.
(C) x = –1 ⇒ γ = (D) Equilibrium at a point is unstable if on slight
T
displacement along the axis no net restoring force
(D) x = –1 ⇒ B = 0 acts on the particle.

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Mock Test 1 (Paper-2) - Answers & Hints 11

49. Answer A(p, q, r), B(q, r, s, t), C(p, r), D(s) 54. Answer (5)

Use kinematical analysis. In one connection half the energy is lost

80
50. Answer (1) ⇒ =n
2n − 1
w = wOA + wAB + wBC + wCO ⇒ 80 = 2n – 1n

⇒ n=5
As electric field lines are concentric circles with centre
55. Answer (1)
at O, wOA = wCO = 0 r

⇒ w = wAB + wBC = ∫
G ρ 0r (4πr 2 dr )
Inside E1 = 0
= Gπρ 0 r 2 …(i)
r   r  r2
 2 × B0  × q × r +  × B0  × q × 2r = qB0r 2
  2 2  R

51. Answer (9)

∫
G ρ r(4πr 2 dr )
Gπρ 0 R4
Outside E2 = 0
= …(ii)

om
r2 r2
√3v/2
60° R
E1 at r =

c
60°
√3v/2 is same as E2 at r = yR
v/2 x
Before After
g.
⇒
1
=
1
ng
x2 y2
After collision, vertical component becomes zero.
x
ye

52. Answer (3) ⇒ =1

y
Energy of element ∝(slope)2
.m

56. Answer (2)

V XY = VAC = 2V = I AC (2Ω )
w

E A tan2 45°
⇒ = =3 ⇒ IAC = 1 A = IAB
E B tan2 30°
w

⇒ IAB .RAB = 10 – IAB r

w

53. Answer (2) ⇒ 1 × 8 = 10 – 1 × r

://

⇒ r=2Ω
R1R2
tp

Radius of intermediate film = R − R =∝

57. Answer (3)
1 2 N = N0 e–λt
ht

⇒ Film is flat and so force due to surface tension will ⇒ m = m0 e–λt

act at 120° to each other. dm
⇒ = − λ m 0e−λt
dt
⇒ h = r + r sin30 ° = 1.5 r
dm
By conservation of volume ⇒ Fthrust = vrel = vrel ( λ m0e−λt )
dt
2
 3r   3r  Fthrust dv
2π    3r −  ⇒ a= = vrel λ =
 2   2  4 3
= πR m dt
3 3
⇒ v = vrelλt

v2 3t0
3r ⇒ = =3
⇒ R= v1 t0
23 2
q q q

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