Escolar Documentos
Profissional Documentos
Cultura Documentos
2016
Report title
Date
December 5, 2016
Author
Dr. M. Betz
Results / Summary
Contents
1 Introduction .......................................................................................................... 4
2 Results ................................................................................................................. 4
2.1 Elongation at break and tensile yield strength of
Borealis Borcoat ME0420 ............................................................................ 10
2.2 Vicat softening temperature of Borealis Borcoat ME0420 ............................ 10
2.3 Water content of Borealis Borcoat ME0420 ................................................. 11
2.4 MFR of Borealis Borcoat Borcoat ME0420 ................................................... 11
2.5 Density of Borealis Borcoat ME0420 ............................................................ 12
2.6 Density of Borealis Borcoat HE3450 ............................................................ 12
2.7 Elongation at break, tensile yield strength and tensile strength at break
of Borealis Borcoat HE3450 .......................................................................... 13
2.8 Elongation at break of the extruded top layer of
Borealis Borcoat HE3450............................................................................. 14
2.9 Vicat softening temperature of Borealis Borcoat HE3450 ............................ 14
2.10 Water content of Borealis Borcoat HE3450............................................... 15
2.11 Shore D hardness of Borealis Borcoat HE3450 ........................................ 16
2.12 Environmental stress cracking resistance of Borealis Borcoat HE3450 .... 16
2.13 OIT of Borealis Borcoat HE3450 ............................................................... 17
2.14 Continuity according to ISO 21809-1 ........................................................ 19
2.15 Degree of cure of the epoxy ...................................................................... 19
2.16 Product stability during application of the PE top layer ............................. 19
2.17 Impact strength & low temperature impact strength .................................. 20
2.18 Indentation resistance of Borealis Borcoat HE3450 .................................. 20
2.19 Peel strength ............................................................................................. 21
2.20 Cathodic disbondment test........................................................................ 22
2.21 Flexibility test ............................................................................................ 23
2.22 Hot water immersion test .......................................................................... 24
2.23 UV resistance on the basis of NF A49-710 ............................................... 25
2.24 UV resistance according to ISO 21809-1 and DIN 30670 ......................... 27
2.25 Thermal ageing according to NF A49-710 ................................................ 28
2.26 Thermal ageing according to ISO 21809-1 and DIN 30670 ...................... 29
2.27 Specific insulation resistance .................................................................... 30
2.28 Resistance to microorganisms .................................................................. 31
page 3 of 32
SZMF-ED-PB-2016-0419
1 Introduction
2 Results
The following Table 2, Table 3 and Table 4 give an overview of the results. The indi-
vidual test results and the exact test conditions can be found in the corresponding
subsections.
page 4 of 32
SZMF-ED-PB-2016-0419
Table 2: Test results for the adhesive material Borealis Borcoat ME0420
Test
Test Name Standard Requirement Results
Conditions
Specimen type
1A,
ISO 21809-1 compression
Elongation at break ≥600 % 745 %
ISO 527-2 moulded,
23±2 °C,
50 mm/min
Specimen type
1A,
Tensile yield ISO 21809-1 compression
≥8 MPa 11.8 MPa
strength ISO 527-2 moulded,
23±2 °C,
50 mm/min
ISO 21809-1
Vicat softening
DIN 30670 A/50 (9.8 N) ≥85 °C 100.2 °C
temperature
ISO 306
ISO 21809-1 ISO 15512
Water content ≤0.1 % 0.020 %
ISO 15512 Procedure B2
DIN 30670 1.0
MFR 190 °C, 2.16 kg -
ISO 1133-1 g/10 min
DIN 30670
ISO 1183-1 0.9305
Density NF A49-710 -
procedure A g/cm³
ISO 1183-1
page 5 of 32
SZMF-ED-PB-2016-0419
Table 3: Test results for the HDPE top layer Borealis Borcoat HE3450
Test Require-
Test Name Standard Results
Conditions ment
ISO 21809-1
DIN 30670 ISO 1183-1 0.9458
Density ≥ 0.93 g/cm³
NF A49-710 procedure A g/cm³
ISO 1183-1
Specimen type
ISO 21809-1 1A, ISO 21809-1:
DIN 30670 compression ≥600 %
Elongation at break 719 %
NF A49-710 moulded, NF A49-710:
ISO 527-2 23±2 °C, ≥300 %
50 mm/min
Specimen type
1A,
ISO 21809-1
Tensile yield compression
DIN 30670 ≥ 15 MPa 19.9 MPa
strength moulded,
ISO 527-2
23±2 °C,
50 mm/min
Specimen type
1A,
Tensile strength at DIN 30670 compression
- 29.2 MPa
break ISO 527-2 moulded,
23±2 °C,
50 mm/min
Specimen type
ISO 21809-1
Elongation at break 5A,
DIN 30670
(extruded extruded, ≥400 % 597 %
NF A49-710
top layer) 23±2 °C,
ISO 527-2
25 mm/min
ISO 21809-1
Vicat softening
DIN 30670 A/50 (9.8 N) ≥110 °C 113.2 °C
temperature
ISO 306
ISO 21809-1
ISO 15512
Water content NF A49-710 ≤0.05 % 0.026 %
Procedure B2
ISO 15512
ISO 21809-1
Hardness Shore D DIN 30670 ≥ 55 57.5
ISO 868
page 6 of 32
SZMF-ED-PB-2016-0419
Table 3 (continued): Test results for the HDPE top layer Borealis Borcoat HE3450
Require-
Test Name Standard Test Conditions Results
ment
ISO 21809-1 50 °C, 1000 h, ≤ 50 % 0%
ESCR
ASTM D1693 Condition A failure failure
NF A49-710 50 °C, 100 h, ≤ 20 % 0%
ESCR
ASTM D1693 Condition A failure failure
ISO 21809-1
OIT DIN 30670 210 °C ≥30 min 54 min
ISO 11357-6
DIN 30670 0.5
MFR 190 °C, 2.16 kg -
ISO 1133-1 g/10 min
Test
Test Name Standard Requirement Results
Conditions
Free of defects, Free of defects,
discontinuities, discontinuities,
Continuity ISO 21809-1 delaminations, delaminations,
separations and separations and
holidays holidays
ISO 21809-1:
ISO 21809-1
Degree of cure ≤ 5 °C
DIN 30670 2.38 °C
of the epoxy Manufacturer:
NF A49-710
-2 °C≤∆Tg≤3 °C
Product stabil-
ity during ISO 21809-1
application of DIN 30670 190 °C, 2.16 kg ∆MFR≤20 % ∆MFR=0.6 %
the PE ISO 1133-1
top layer
ISO 21809-1
Impact strength DIN 30670 23±2 °C ≥ 7 J/mm > 7 J/mm
NF A49-710
Low tempera-
ture impact DIN 30670 -40±2 °C ≥ 7 J/mm > 7 J/mm
strength
Indentation NF A49-710 20±2 °C, 1 h ≤0.3 mm 0.052 mm
ISO 21809-1
Indentation 23±3 °C, 24 h ≤0.2 mm 0.070 mm
DIN 30670
page 7 of 32
SZMF-ED-PB-2016-0419
Test
Test Name Standard Requirement Results
Conditions
Indentation NF A49-710 70±2 °C, 1 h ≤1.0 mm 0.173 mm
70±2 °C,
Indentation DIN 30670 ≤0.4 mm 0.222 mm
24 h
ISO 21809-1 80±2 °C,
Indentation ≤0.4 mm 0.238 mm
DIN 30670 24 h
Average
Peel strength ISO 21809-1 23±2 °C ≥442 N/cm
≥150 N/cm
Minimum
Peel strength DIN 30670 23±2 °C ≥ 400 N/cm
≥150 N/cm
Minimum
Peel strength NF A49-710 23±2 °C ≥ 400 N/cm
≥80 N/cm
Minimum
Peel strength DIN 30670 70±2 °C ≥ 149 N/cm
≥30 N/cm
DIN 30670 Minimum
Peel strength 70±2 °C ≥ 149 N/cm
NF A49-710 ≥20 N/cm
Average
Peel strength ISO 21809-1 80±2 °C ≥ 151 N/cm
≥30 N/cm
28 d,
Cathodic disbond- ISO 21809-1
20±2 °C, ≤7 mm 2.5 mm
ment DIN 30670
USCE=-1.5 V
24 h,
Cathodic disbond-
ISO 21809-1 65±3 °C, ≤7 mm 0.5 mm
ment
USCE=-3.5 V
28 d,
Cathodic disbond-
ISO 21809-1 80±3 °C, ≤15 mm 9.5 mm
ment
USCE=-1.5 V
7 d,
Cathodic disbond-
NF A49-710 40±2 °C, ≤10 mm 2.1 mm
ment
USCE=-1.5 V
2 d,
Cathodic disbond-
DIN 30670 60±2 °C, ≤7 mm 2.2 mm
ment
USCE=-1.5 V
No cracking/
Flexibility ISO 21809-1 0 °C, α=2.0° No cracking
holidays
20±2 °C, No cracking/ No cracking/
Flexibility NF A49-710
=2.5% holidays holidays
page 8 of 32
SZMF-ED-PB-2016-0419
Test
Test Name Standard Requirement Results
Conditions
Delamination:
Hot water immersion 80±3 °C, Average ≤2 No loss of
ISO 21809-1
test 48 h mm adhesion
Max. ≤3 mm
NF A49-710
UV resistance 800 h ∆MFR≤25 % ∆MFR=3.7 %
ISO 4892-2
NF A49-710
UV resistance 800 h ∆B < 50 % ∆B < 1 %
ISO 4892-2
ISO 21809-1
UV resistance DIN 30670 7 GJ/m² ∆MFR≤35 % ∆MFR=6.1 %
ISO 4892-2
ISO 21809-1 4800 h,
Thermal ageing ∆MFR≤35 % ∆MFR=9.1 %
DIN 30670 100±2 °C
1000 h,
Thermal ageing NF A49-710 ∆MFR≤25 % ∆MFR=3.6 %
100±2 °C
Specific insulation DIN 30670 100 d, 8 ≥ 1.69*1013
≥ 10 m²
resistance NF A49-710 23±2 °C m²
Peel strength
Resistance against 6 months ≥ 84 %
NF A49-710 ≥ 80 % of ini-
microorganisms burying (≥ 376 N/cm)
tial value
page 9 of 32
SZMF-ED-PB-2016-0419
page 10 of 32
SZMF-ED-PB-2016-0419
Water content was determined to DIN EN ISO 15512 procedure B2 and the results
are listed in Table 7.
MFR was determined to ISO 1133-1 procedure A at 190 °C with a load of 2.16 kg
and a cut-off interval of 180 s. The results are listed in Table 8.
page 11 of 32
SZMF-ED-PB-2016-0419
Density was determined to DIN EN ISO 1183-1 procedure A with deionised water at
23.0 °C on 3 specimens. The results are listed in Table 9.
Density was determined to DIN EN ISO 1183-1 procedure A with deionised water at
23.0 °C on 4 specimens. The results are listed in Table 10.
page 12 of 32
SZMF-ED-PB-2016-0419
page 13 of 32
SZMF-ED-PB-2016-0419
Vicat softening temperature was determined to ISO 306 procedure A. The start tem-
perature was 29 °C, holding time 5 min, temperature gradient 50 K/h and the applied
load was 1019 g. The results are summarized in Table 13.
page 14 of 32
SZMF-ED-PB-2016-0419
Water content was determined to DIN EN ISO 15512 procedure B2 and the results
are listed in Table 14.
page 15 of 32
SZMF-ED-PB-2016-0419
Shore D hardness was measured to DIN EN ISO 868 at 23 °C with a meter reading
time of 15 s. The results are listed in Table 15.
A test sheet of Borealis Borcoat HE3450 was moulded in accordance with procedure
C of Annex A1 of practice ASTM D 4703 and conditioned in accordance with the pro-
cedure A of ASTM D 618.
Ten specimens were cut from the sheet to the dimensions given in ASTM D 1693
Fig. 2 and Table 1, condition A. Each one got a controlled notch on one surface. The
specimens were bent into a holder and the holder was inserted in the test tube with
the reagent.
page 16 of 32
SZMF-ED-PB-2016-0419
For Borealis Borcoat HE3450 0 % of the specimens failed while testing for 1000 h.
Borealis Borcoat HE3450 clearly passed the test for 1000 h.
The oxygen induction time (OIT) of Borealis Borcoat HE3450 was performed accord-
ing to ISO 11357-6. The flow of nitrogen respectively oxygen was 20 ml/min and the
temperature was kept constant at 210 °C during the measurement. For evaluation
the tangent method according to ISO 11357-6 was used. The results are listed in
Table 16 and can be seen in Figure 1.
page 17 of 32
SZMF-ED-PB-2016-0419
page 18 of 32
SZMF-ED-PB-2016-0419
A visual inspection of the coating came to the result that the coating is free of de-
fects, discontinuities, delaminations and separations. A holiday test was performed to
ISO 21809-1 Annex B (average total layer thickness: 4.9 mm) at 25 kV. No holidays
were detected.
The degree of cure of the epoxy was determined according to ISO 21809-1
Annex D / DIN 30670 Annex B and the results are presented in Table 17.
The melt flow index MFR190/2.16 was measured before and after extrusion of Borealis
Borcoat HE3450 (Table 18) according to ISO 1133-1 procedure A.
Table 18: MFR190/2.16 before and after extrusion of Borealis Borcoat HE3450,
cut-off interval: 180 s
MFR190/2.16 /g/10min
Measurement MFR/%
before extrusion after extrusion
1 0.502 0.502
2 0.499 0.496
3 0.502 0.495
Average 0.501 0.498 0.6
Standard
0.001 0.003
deviation
page 19 of 32
SZMF-ED-PB-2016-0419
Testing was carried out on cut plates, which were supported with a wooden base as
described in CSA Z245.20. The impacts were performed with a hard steel punch with
a hemispherical head (diameter 25 mm) and a distance of about 50 mm between the
impacts. In Table 19 the results of the impact tests are summarized.
Coating
Tem- Drop Drop Impact Holi-
Speci- Im- thick-
perature height weight strength days
men pacts ness
/ °C /m / kg / J/mm (25 kV)
/ mm
Pl. 1 23±2 °C 3 1.0 4.029 8.1 4.9 0
Pl. 2 23±2 °C 3 1.0 4.029 8.1 4.9 0
Pl. 3 23±2 °C 3 1.0 4.029 8.2 4.8 0
Pl. 4 23±2 °C 3 1.0 4.029 8.1 4.9 0
Pl. 5 -40±2 °C 2 1.0 4.029 7.8 5.1 0
Pl. 6 -40±2 °C 2 1.0 4.029 7.9 5.0 0
Pl. 7 -40±2 °C 3 1.0 4.029 7.9 5.0 0
Pl. 8 -40±2 °C 3 1.0 4.029 8.1 4.9 0
For the test temperatures 23±3 °C, 70±2 °C and 80±2 °C tempering of the specimens
was performed with water. The thickness of the specimens was about 2 mm and the
diameter of the used indenter was 1.8±0.05 mm with a cross-sectional area of
2.5 mm². The applied force was 25±0.5 N. Indentation was determined with a dial
gauge with an accuracy of ±0.003 mm. The individual results are given in Table 20
and the average indentations of 3 specimens are listed in Table 21.
page 20 of 32
SZMF-ED-PB-2016-0419
Peel strength was measured with a tensile testing machine at a constant rate of pull
of 10 mm/min. The width of the coating strips, which were peeled off, was about
20 mm. For determination of the peel strength the exact width was considered. The
results are summarized in Table 22. As required in ISO 21809-1, no single recorded
peeling value is 30 % below the requirement.
page 21 of 32
SZMF-ED-PB-2016-0419
The test conditions are listed in Table 23 and the results can be found in
Table 24 to Table 28.
Electrolyte: 3 % NaCl
Drill: 6 mm
Reference electrode: Ag/AgCl, saturated KCl electrolyte
Heating for tests above room temp.: Oven
Table 24: Test results for 28 d CD test at 23±3 °C, USCE = -1.50 V
page 22 of 32
SZMF-ED-PB-2016-0419
Table 25: Test results for 24 h CD test at 65±3 °C, USCE = -3.50 V
Table 26: Test results for 7 d CD test at 40±2 °C, USCE = -1.50 V
Table 27: Test results for 2 d CD test at 60±2 °C, USCE = -1.50 V
Table 28: Test results for 28 d CD test at 80±3 °C, USCE = -1.50 V
Based on the sample dimensions the mandrel radius was calculated to give the re-
quired bend. Additionally the bend of the specimens was measured and bending was
page 23 of 32
SZMF-ED-PB-2016-0419
stopped when the required bend was reached. Details of the flexibility test to
ISO 21809-1 can be found in Table 29 and of the flexibility test to NF A49-710 in Ta-
ble 30.
Table 29: Flexibility test to ISO 21809-1, 0 °C, mandrel radius 214 mm, = 2.0 °
Table 30: Flexibility test to NF A49-710, 23±3 °C, mandrel radius 153 mm, = 2.5 %
3 specimens were completely immersed in 80±3 °C hot deionised water for 48 h. Af-
ter hot water immersion the specimens were cooled down to room temperature and
were inspected for loss of adhesion at borders and edges. No loss of adhesion was
detected (Figure 2 and Figure 3) hence the test is passed.
page 24 of 32
SZMF-ED-PB-2016-0419
page 25 of 32
SZMF-ED-PB-2016-0419
test specimens of type 5A to ISO 527-2 were cut and the results of the tensile tests
are listed in Table 33.
Table 31: Detailed test conditions for UV ageing (corresponding to ISO 4892-2)
Table 33: Tensile testing at 23±2 °C and 50 % relative humidity after UV ageing and
comparison to initial elongation at break (B = 597 %)
page 26 of 32
SZMF-ED-PB-2016-0419
Table 35: Tensile testing at 23±2 °C and 50 % relative humidity after UV ageing and
comparison to initial elongation at break (B = 597 %)
page 27 of 32
SZMF-ED-PB-2016-0419
Table 36: MFR190/2.16 after 1000 h thermal ageing at 100±2 °C and comparison to
initial value (MFR190/2.16=0.498 g/10 min), cut-off interval: 180 s
Table 37: Tensile testing at 23±2 °C and 50 % relative humidity after thermal ageing
and comparison to initial elongation at break (B = 597 %)
page 28 of 32
SZMF-ED-PB-2016-0419
Table 38: MFR190/2.16 after 800 h thermal ageing at 100±2 °C and comparison to
initial value (MFR190/2.16=0.498 g/10 min), cut-off interval: 180 s
Table 39: MFR190/2.16 after 1600 h thermal ageing at 100±2 °C and comparison to
initial value (MFR190/2.16=0.498 g/10 min), cut-off interval: 180 s
Table 40: MFR190/2.16 after 2400 h thermal ageing at 100±2 °C and comparison to
initial value (MFR190/2.16=0.498 g/10 min), cut-off interval: 180 s
Table 41: MFR190/2.16 after 3200 h thermal ageing at 100±2 °C and comparison to
initial value (MFR190/2.16=0.498 g/10 min), cut-off interval: 180 s
page 29 of 32
SZMF-ED-PB-2016-0419
Table 42: MFR190/2.16 after 4000 h thermal ageing at 100±2 °C and comparison to
initial value (MFR190/2.16=0.498 g/10 min), cut-off interval: 180 s
Table 43: MFR190/2.16 after 4800 h thermal ageing at 100±2 °C and comparison to
initial value (MFR190/2.16=0.498 g/10 min), cut-off interval: 180 s
Table 44: Tensile testing at 23±2 °C and 50 % relative humidity after thermal ageing
and comparison to initial elongation at break (B = 597 %)
Specific electrical insulation resistance was determined according to DIN 30670 and
NF A49-710 on 3 pipe segments (P.1 to P.3) after a holiday test. An area of 0.049 m²
page 30 of 32
SZMF-ED-PB-2016-0419
of the coating was exposed for each specimen to 0.1 N NaCl solution for a duration
of 100 d at 23±2 °C. The electrical resistance was measured with a teraohmmeter at
500 V after the current was applied for 10 min as average over a duration of 1 min.
In the following Table 45 the values of the specific electrical insulation resistance af-
ter a test period of 40 d, 70 d and 100 d are presented.
After the time of 100 days the specific electrical insulation resistance of the speci-
mens shows values between 1.69*1013 and 2.33*1013 Ω m2 at 23±2 °C. All values are
much above the specified minimum value of DIN 30670 and NF A49-710.
page 31 of 32
SZMF-ED-PB-2016-0419
and were exposed for 6 months at 29±1 °C and 97±2 % relative humidity (ISO 846
method D). After exposure no damage on the specimens was detected visually. The
peel strength was determined to NF A 49-710 at room temperature with a peeling
rate of 10 mm/min (Table 47). The requirement of at least 80 % of the initial peel
strength was clearly met.
Table 47: Peel strength at room temperature after exposure for 6 month at 29±1 °C
and 97±2 % rel. humidity in soil (initial peel strength: 446 N/cm)
page 32 of 32