UNITED STATES DEPARTMENT OF COMMERCE + Sialsr Weels, Seruery [NATIONAL BUREAU OF STANDARDS « A.V. Aan Dir Viscosities of Sucrose Solutions at Various Temperatures: Tables of Recalculated Values I.E. Swindells, C. F. Snyder, R. C. Hardy, and P. E. Golden Supplement to National Bureau of Standards Circular 440 Issued July 31, 1958 Dear Gorm Pig Oe IPDe PinsonViscosities of Sucrose Solutions at Various Temperatures: Tables of Recalculated Values* 4. F. Swindell, C. F. Snyder, R. C. Hardy, and P. B. Golden “oe tn of vena of arne sitions appearing NBS The nploa ceeg tenes suns epee, scm cle mening hau ee tt Ta ae ee ee rage ice ae wales Hag meatal See Sa ta ie ate eae EBSD ere inca ree Mat, cae ae a Sig Seecain oP in als pe ae meth et fete cae corte Pryce tables have been recalculated, La At the Bleventh Session of the Intemational Commission for U form Methods of Sugar Analysis ut Paris 1094, tho report on Subject 19 presented by the Referee, A, Van Hook (1}- called attention to the dodermination ofthe viscosity of water at 20°C at the National Buress of Standards [3).. This value 0.01002 poise has been adopted bythe National Bureau of Standards, the American Society for Resting Mac terials, the National Physical Laboratory in England, and the Physikae lische’Technische Bundesanstalt in Germany.” ‘The Referee's Teport sho plated ou the derabiity of «sander st of vacosty values ‘of suerose solutions. ‘discussion of the subject of viscosity of suerose solutions is given in chapter XXT of referents {3}. In the chapter, reference is matte to the won of Bingham and Tackson 6] and to Lt’ comprehensire review [6] of all data published up to 1936 and his comparison of this ‘the experimental rales on solutions containing fo St perent ‘Tho lack of agreement disclosed by this review [5], together with indiectovitons Ghat sons of the interpola “Sdtue® given, by Bingham and Jackson (i] were in error by several percent, led to further investigation at NBS by JF. Swindells, R. F. Jackson, and 'S. Cragoe (3, p. 337). ‘The values obtained in this study’ ‘wore tsed a5 the major basis for the ealculation of tables 120, 131, and 133, pages O71 to 673 in Cizeular 440 [3]. Viscosity measurements were nude over tho range 0° to 35° C on solutions containing 30, 40, 50, G0, 65, 70, and 79 percent of sucrose by weight in vacuum, ‘Thess solutions were intially prepared with « procision of better than 0.001, presen inthe concentration, wang suerose ef he highest purty. nges inthe etal eoncentetion daring the fling ofthe vss ters were. minimized by ‘special precautions. descrbed. in chupter XT] ‘Three instruments similar to the one described by Bingham. and Jackson [] were employed with capillaries of different diameters, ‘The instrument with the smallest capillary was calibrated with water at 20°C, assuming the value 1.0050 eentipoises. ‘The calibrations of the ube fatruments were earned out wth several Huds of Higher ina step-by-step process, Drainage errors were elimi iy always flowing the liqutds into @ dry bulb. “A separate sample wus wel for each visoaiy determination At lest two meas ments, usually ageing to 0.1 percent o: betier, were made at each temperature, which was adjusted to the desired integral temperature Godicated by « platinum resistance thermometer) asd usually malo fsined constant fo les than 0.012 C. ‘The very precise measurements bytdone apd Star [ofthe vicoity of Sosporentsueone elu tions at 25°.C were ustd os the primary basis for the fixation of the viscosity values for 20-pereent solutions. The values above 35° C twore based langely on te results of Bingham and Jackson {i Landt [5], and Bennett, and Nees [6]. ‘Yin all of the above data, the value of tho viscosity of water at 20°C 10 (1042) was ased. The nocept- 3 (0.91008 poise) accepted a that coe vue wis domed fea rene at that ime the value ‘ro100s ‘was generally employed. However, during the period 1938 to Lodi, an investigation ofthe viscosity of water af 20° C and other temperatures wes in progress a0 NBS by Coe and Godfrey who re Ported the tentative fale 0:010020 poise at 20" C in a letier to the oft furl of Applied gs rt wns feng, ow itat with the completion of so small «part of the contemplated of measurements wate the stent of hn ena value Bt thet Line vas fustiied only bythe neceityof indefinitely suspend fg the works the work tas Fesumed in 1047 by J. B Swindell, Iho completed the experimental program and reduced ail the date’ The final result. of the completed determination was found to be Gotog19 0.000008 pore. The magnitude of the uncertalnty in his flue is bach thet the ciple rae of 0010020 poise at 20° C has teen adopted Burin i latter pevod, 1047 to 1082, ropress: which was related to the pres wines End Tncladed a detgiedanvestgatjog ofthe constants ofthe identical egmeters weil the yors of Swindell, Jackson, and. Crazoe, hewn the major bass pr as 10,1, 132 of NBS Ce. 40 "Phe realeulaton of tables 100, 131, and 132 has been made Dy che more precise Yalu for viscometer constants and the nem alos forthe stot of water at 20° C (he, 0010020 poise). Data of other investigators, which vere considered in arriving at the tabu- © lated walues in table i , were adjusted to the new basis by applica tion of the factor, 0.907015, which represents the ratio of the new to the old value for tho viscosity of water at 20° . ‘[c is recommended that the revised tables for the viscosities of sucrose solutions at yarious temperatures, presented in this Supple- ‘ment, be substituted for the original tables in Circular 440. {0 A. Van Hook, Pgs Iteraatiog| Gomminon for Uaorm Methods of Sagar Aap Reeh Se leet is . (2) J. E Swindell J. R. Coe, Jr, and T. B. Godfrey, J. Research NBS 48, 1 dasa 88 ete ety, andthe eure NDS Cig. 440, 9, 360 (02) 18) Porte at of Bostinents . & Covermest Print Oe, Wash: i 2 EE Behan sad WE. dackoon, Bul, BS 44, $9 (1917) $208. (e) atesipn ae cet dackrnd “ty $09 C89); 86,8 190); rattan Goat att to) 5 Noa aan 3S (oo Cesta eh Gace F Sota iad (0) 0.3058, REFTE. Stautr, J. Am. Chem. Soe. 88, 1690 (1087, Breit, Z Zacks, Hei, 618, 24 0959. ose nd Eng, Cha. 2 9 (1830 ppl Piva. 5, . dad Ri. Cotiington, J: Research NBS 62, 105"Tamu 180 (revised 1957). 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