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JEE ( Main ) Examination–2019/Morning Session/12-01-2019

TEST PAPER OF JEE(MAIN) EXAMINATION – 2019


(Held On Saturday 12th JANUARY, 2019) TIME : 09 : 30 AM To 12 : 30 PM
CHEMISTRY
1. Iodine reacts with concentrated HNO3 to yield Y
along with other products. The oxidation state of Sol. A + 2B ‡ˆˆ ˆˆ† 2C + D
iodine in Y, is :- t =0 a0 1.5a0 0 0
(1) 5 (2) 3 (3) 1 (4) 7 t = t eq a 0 – x 1.5a 0 – 2x 2x x
Ans. (1)
Sol. I2 + 10HNO3 ¾® 2HIO3 + 10NO2 + 4H2O At equilibrium [A] = [B]
In HIO3 oxidation state of iodine is +5. a0 – x = 1.5a0 – 2x Þ x = 0.5a0
2. The major product of the following reaction is: t = teq 0.5a0 0.5a0 a0 0.5a0

CN [C]2 [D] (a 0 ) 2 (0.5a 0 )


KC = = =4
(i) DIBAL-H [A] [B]2 (0.5a 0 ) (0.5a 0 )2
O +
(ii) H3O 4. Two solids dissociate as follows
O
ˆˆ† B(g) + C(g) ; K = x atm2
A(s) ‡ˆˆ

(1)
CHO

O
(2)
EN CHO

O
p

ˆˆ† C(g) + E(g) ; K = y atm2


D(s) ‡ˆˆ p2
1

The total pressure when both the solids dissociate


simultaneously is :-
(1) x2 + y2 atm (2) x2 + y2 atm
CHO CH=NH (3) 2 ( )
x + y atm (4) x + y atm
LL
(3) OH (4) OH Ans. (3)
OH Sol. A(s)ƒB(g) + C(g) KP1 = x = PB×P C
CHO
P1 P1 x=P1(P1 + P2) ...(1)
Ans. (3) D(s)ƒC(g) + E(g) KP2 = y = PC × P E
P2 P2 y = (P1+P2) (P2) ...(2)
CN CHO
Adding (1) and (2)
A

(1) DIBAL-H
+
OH x + y = (P1 + P2)2
O (2) H /H2O
Sol.
H Now total pressure
O O PT = P C + P B + P E
DIBAL-H will reduce cyanides & esters to = (P1 + P2) + P1 + P2 = 2(P1 + P2)
aldehydes. PT = 2 ( x + y )
3. In a chemical reaction, A + 2B ‡ˆˆˆˆˆ †
ˆ 2C + D,
K
5. Freezing point of a 4% aqueous solution of X is
the initial concentration of B was 1.5 times of the equal to freezing point of 12% aqueous solution of
concentration of A, but the equilibrium Y. If molecular weight of X is A, then molecular
concentrations of A and B were found to be equal. weight of Y is :-
The equilibrium constant(K) for the aforesaid (1) A
chemical reaction is : (2) 3A
1 (3) 4A
(1) 16 (2) 4 (3) 1 (4) (4) 2A
4
Ans.(2) Ans. (2)

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JEE ( Main ) Examination–2019/Morning Session/12-01-2019
Sol. For same freezing point, molality of both solution
OH
should be same.
8. CH3CH2 –C–CH3 cannot be prepared by :
mx = my
Ph
4 ´1000 12 ´ 1000
= (1) HCHO + PhCH(CH3)CH2MgX
96 ´ M x 88 ´ M y
(2) PhCOCH2CH3 + CH3MgX
96 ´ 12 (3) PhCOCH3 + CH3CH2MgX
or, My = M x = 3.27 A (4) CH3CH2COCH3 + PhMgX
4 ´ 88
Ans. (1)
Closest option is 3A.
6. Poly-b-hydroxybutyrate-co-b-
O
hydroxyvalerate(PHBV) is a copolymer of___.
Sol. (1) H–C–H + Ph–CH–CH2MgX
(1) 3-hydroxybutanoic acid and
CH3
4-hydroxypentanoic acid
(2) 2-hydroxybutanoic acid and
3-hydroxypentanoic acid
(3) 3-hydroxybutanoic acid and Ph–CH–CH2–CH2–OH

Ans. (4)
2-hydroxypentanoic acid
(4) 3-hydroxybutanoic acid and
3-hydroxypentanoic acid
EN 9.
CH3

The volume of gas A is twice than that of gas B.


The compressibility factor of gas A is thrice than
Sol. PHBV is a polymer of 3-hydroxybutanoic acid and that of gas B at same temperature. The pressures
3-Hydroxy pentanoic acid. of the gases for equal number of moles are :
7. Among the following four aromatic compounds, (1) 2PA = 3PB
LL
which one will have the lowest melting point ? (2) PA = 3PB
(3) PA = 2PB
(1) (4) 3PA = 2PB
Ans. (1)
Sol. VA = 2VB
O ZA = 3ZB
A

OH PA VA 3 × PB × VB
(2)
OH =
n A RTA n B .RTB
O
2PA = 3PB
10. The element with Z = 120 (not yet discovered) will
CH3
be an/a :
O (1) transition metal
(3) O (2) inner-transition metal
CH3 (3) alkaline earth metal
(4) alkali metal
OH Ans. (3)
(4) Sol. Z = 120
Its general electronic configuration may be
Ans. (1) represented as [Nobal gas] ns2 , like other alkaline
Sol. M.P. of Napthalene ~ 80°C earth metals.

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JEE ( Main ) Examination–2019/Morning Session/12-01-2019
11. Decomposition of X exhibits a rate constant of 0.05 14. For diatomic ideal gas in a closed system, which
mg/year. How many years are required for the of the following plots does not correctly describe
decomposition of 5 mg of X into 2.5 mg ? the relation between various thermodynamic
(1) 50 (2) 25 (3) 20 (4) 40 quantities ?
Ans.(1)
Sol. Rate constant (K) = 0.05 µg/year
means zero order reaction Cv Cp
(1) (2)
a0 5µg
t1/ 2 = =
2K 2 ´ 0.05 mg / year = 50 year T P

12. The major product of the following reaction is :


CH3O (1) Cl /CCl Cv U
2 4

(2) AlCl3(anhyd.) (3) (4)


Cl Cl V T
Ans. (2)
(1) CH3O (2) CH3O
Sol. At higher temperature, rotational degree of

(3)

Ans. (4)
CH3O

Cl
(4)
CH3O
EN Cl
freedom becomes active.

CP =
7
2

5
R (Independent of P)

Sol. CH3O Cl CV = R (Independent of V)


Cl 2
MeO 2
Variation of U vs T is similar as C V vs T.
LL
EAS 15. The standard electrode potential E ! and its
MeO
+ æ dE ! ö
Cl
+H temeprature coefficient ç ÷ for a cell are 2V
è dT ø
13. Given
Gas H2 CH3 CO2 SO2 and –5 × 10–4 VK–1 at 300 K respectively. The
Critical 33 190 304 630 cell reaction is
A

Temperature/K Zn(s) + Cu2+ (aq) ® Zn2+(aq) + Cu(s)


On the basis of data given above, predict which (
The standard reaction enthalpy D r H! at 300 )
of the following gases shows least adsorption
on a definite amount of charcoal ? K in kJ mol–1 is,
(1) H2 (2) CH4 (3) SO2 (4) CO2 [Use R = 8jK–1 mol–1 and F = 96,000 Cmol–1]
Ans. (1) (1) –412.8 (2) –384.0
Sol. Smaller the value of critical temperature of gas, (3) 206.4 (4) 192.0
lesser is the extent of adsorption. Ans. (1)
so least adsorbed gas is H2 Sol. Chiefly NO2 , O3 and hydrocarbon are responsible
for build up smog.

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JEE ( Main ) Examination–2019/Morning Session/12-01-2019
16. The molecule that has minimum/no role in the O O
OH CH3
formation of photochemical smog, is : C
(1) CH2 = O H3C H H
(2) A = ; B=
(2) N2
H3C CH3 H3 C CH3
(3) O3
(4) NO O O
CH3 CH3
Ans. (2)
Sol. Chiefly NO2 , O3 and hydrocarbon are responsible (3) A = CH3 ; B = CH3
for build up smog. HO
17. In the Hall-Heroult process, aluminium is formed O O
CH3 CH3
at the cathode. The cathode is made out of : (4) A = CH3 ; B = CH3
(1) Platinum HO
(2) Carbon Ans. (4)
(3) Pure aluminium 19.
(4) Copper Ans. 4 O O
Sol. O OH

O
Ans. (2) C– H C–H + H 2O
17. Ans.(2) Carbon
Sol. In the Hall-Heroult process the cathode is made
of carbon.
18. Water samples with BOD values of 4 ppm and 18
ppm, respectively, are :
EN HO
O
H2O
O–
H
O

(1) Highly polluted and Clean H


(A)
(2) Highly polluted and Highly polluted
(3) Clean and Highly polluted D –H2O
LL
(4) Clean and Clean O
Ans. (3)
Sol. Clean water would have BOD value of less than
5 ppm whereas highly polluted water could have
a BOD value of 17 ppm or more. (B)
20. What is the work function of the metal if the light
19. In the following reactions, products A and B
are : of wavelength 4000 Å generates photoelectrons of
A

velocity 6 × 105 ms–1 form it ?


O O
(Mass of electron = 9 × 10–31 kg
dil NaOH [A]
H3C H3C CH3 H Velocity of light = 3 × 108 ms–1
+ Planck's constant = 6.626 × 10–34 Js
H 3O
[A] [B] Charge of electron = 1.6 × 10–19 JeV–1)
D
O O (1) 0.9 eV
OH H2C (2) 4.0 eV
H3C H H
(1) A = ; B= (3) 2.1 eV
H3C H3 C (4) 3.1 eV
CH3 CH3
Ans. (3)

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JEE ( Main ) Examination–2019/Morning Session/12-01-2019
Sol. hn = f + hn° Sol. ppm of CaCO3
(10 –3 × 103) × 100 = 100 ppm
1 æ1 1 ö
mv 2 = hc ç – ÷ 24. The correct order for acid strength of compounds
2 è l l0 ø CHºCH, CH3–CºCH and CH2=CH2
is as follows :
1
hn =f + mv 2 (1) CH º CH > CH2 = CH2 > CH3–C º CH
2
(2) HC º CH > CH3 –C º CH > CH2 = CH2
6.626 ´ 10 –34 ´ 3 ´ 10 8 1 (3) CH3–C º CH > CH2 = CH2 > HC º CH
– ´ 9 ´ 10 ´ (6 ´10 )
–31 5 2
f=
4000 ´ 10 –10 2 (4) CH3–C º CH > CH º CH > CH2 = CH2
f = 3.35 × 10–19 J Þ f ~ 2.1 eV Ans. (2)
21. Among the following compounds most basic amino Sol. CHºCH > CH3–CºCH > CH2=CH2
acid is : (Acidic strength order)
(1) Lysine 25. Mn2(CO)10 is an organometallic compound due
(2) Asparagine to the presence of :
(3) Serine (1) Mn – Mn bond (2) Mn – C bond
(4) Histidine (3) Mn – O bond (4) C – O bond
Ans. (4) Ans. (2)
Sol. Histidine

ligands in K3[Co(CN)6] are :


(1) dxz, dyz and dz2
EN
22. The metal d-orbitals that are directly facing the
Sol. Compounds having at least one bond between
carbon and metal are known as organometallic
compounds.

(2) dxy, dxz and dyz


(3) dxy and dx2–y2
(4) dx2–y2 and dz2
LL
Ans. (4)
Sol. K3[Co(CN)6] 26. The increasing order of reactivity of the following
Co+3 ® [Ar]18 3d6
compounds towards reaction with alkyl halides
directly is :

O O
eg
A

dx2y2 dz2 NH
NH 2
t2g
dxy dyz dxz (A) O
(B)
2 3
d sp
CN
23. The hardness of a water sample (in terms of NH2 NH2
equivalents of CaCO3) containing 10–3 M CaSO4
is :
(C) (D)
(molar mass of CaSO4 = 136 g mol–1)
(1) 100 ppm (1) (B) < (A) < (D) < (C)
(2) 50 ppm (2) (B) < (A) < (C) < (D)
(3) 10 ppm (3) (A) < (C) < (D) < (B)
(4) 90 ppm (4) (A) < (B) < (C) < (D)
Ans. (1) Ans. (2)

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JEE ( Main ) Examination–2019/Morning Session/12-01-2019
Sol. Nucleophilicity order Me
O OH :O OH Me
H
CN Sol. H–C–H + H + O
O O C+ rds
C +H

:
NH2 NH2 H H H H
NH < NH2 < <
O
B A C D OH
H OMe
MeOH +
27. The pair of metal ions that can give a spinonly C +
CH2–OMe + H
magnetic moment of 3.9 BM for the complex H OMe H

[M(H2O)6]Cl2, is : acetal
(1) Cr 2+ and Mn2+ (2) V2+ and Co2+ 1
rate µ
(3) V2+ and Fe2+ (4) Co2+ and Fe2+ steric crowding of aldehyde
Ans. (2) t-butanol can show formation of carbocation in
27. Ans.(2) V2+ and Co2+ acidic medium.
29. 50 mL of 0.5 M oxalic acid is needed to
Sol. V2+ ® [V(H2O)6]Cl2 ; [Ar]18
3
neutralize 25 mL of sodium hydroxide solution.
3d The amount of NaOH in 50 mL of the given
3 unpaired e– , spin only sodium hydroxide solution is :
magnetic moment
= 3.89 B.M.

Co2+ ® [Co(H2O)6]Cl2 ; [Ar]18


EN 7
(1) 40 g
BONUS
(2) 20 g (3) 80 g

H2C2O4 + 2NaOH ¾®Na 2C2O4 + 2H2O


meq of H2C2O4 = meq NaOH
(4) 10 g

3d 50 × 0.5 × 2 = 25 × MNaOH × 1
3 unpaired e–, spin only
\ MNaOH = 2 M
magnetic moment
Now 1000 ml solution = 2 × 40 gram NaOH
= 3.89 B.M.
LL
\ 50 ml solution = 4 gram NaOH
28. In the following reaction

Aldehyde + Alcohol ¾¾¾ ® Acetal


HCl
30. A metal on combustion in excess air forms X,
Aldehyde Alcohol X upon hydrolysis with water yields H2O2 and
HCHO t BuOH O2 along with another product. The metal is :
CH3CHO MeOH (1) Rb (2) Na (3) Mg (4) Li
Ans. (1)
A

The best combinations is :


(1) HCHO and MeOH Sol. Rb + O2(excess) ¾® RbO2
(2) HCHO and tBuOH 2RbO2 + 2H2O ¾® 2RbOH + H2O2 + O2
(3) CH3CHO and MeOH
(4) CH3CHO and tBuOH
Ans. (1)

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