;

T °C TK
27 300.15

Delta Rxn cal/mol A

- 30,000

CPA=CPC cal/g mol K

53

CPB=CPD cal/g mol K

15

Tabla
xeq keq TK paso
0.9999929934 142720.7698 300.15 10
0.9999645299 28191.7806 310.15
0.9998377557 6162.5435 320.15
0.9993234424 1477.0707 330.15
0.9974096681 385.0509 340.15
0.9908583189 108.3891 350.15
0.9703580496 32.7360 360.15
0.9134029933 10.5477 370.15
0.7829488567 3.6072 380.15
0.5658552117 1.3034 390.15
0.3313391629 0.4955 400.15
0.164919459 0.1975 410.15
0.0759832984 0.0822 420.15
0.0344354806 0.0357 430.15
 0.0158115894 0.0161 440.15
0.0074423937 0.0075 450.15
0.003604395 0.0036 460.15
0.0017969224 0.0018 470.15
0.0009213926 0.0009 480.15
0.000485312 0.0005 490.15
0.000262208 0.0003 500.15
0.0001451145 0.0001 510.15
8.2154855E-05 0.0001 520.15
4.7518808E-05 0.0000 530.15
2.8047592E-05 0.0000 540.15
1.6875095E-05 0.0000 550.15
1.0338874E-05 0.0000 560.15
6.4441108E-06 0.0000 570.15
4.0825355E-06 0.0000 580.15
2.6267251E-06 0.0000 590.15
1.7150679E-06 0.0000 600.15
Ke (25°C) 25 𝐾𝑒�(𝑇) = 𝐾𝑒�(𝑇1 ) 𝑒𝑥𝑝 [( ∆��)/𝑅 (1/(�1 )
200,000 298.15

R cal / mol K
1.987
"X - Xo = (To - T )" "(CPA + CPB )" /"∆HR"
FA0 mol A / min
10

xo
grafica 0
x(t) y
300.15 0.99999
310.15 0.99996
320.15 0.99984
330.15 0.99932
340.15 0.99741
350.15 0.99086
360.15 0.97036
370.15 0.91340
380.15 0.78295
390.15 0.56586
400.15 0.33134
410.15 0.16492
420.15 0.07598
430.15 0.03444
 440.15 0.01581
450.15 0.00744
460.15 0.00360
470.15 0.00180
480.15 0.00092
490.15 0.00049
500.15 0.00026
510.15 0.00015
520.15 0.00008
530.15 0.00005
540.15 0.00003
550.15 0.00002
560.15 0.00001
570.15 0.00001
580.15 0.00000
590.15 0.00000
600.15 0.00000

PENDIENTE 0.0022666667
INTERSECCIÓN -0.68034
X
300.15
600.15
𝑒𝑥𝑝 [( ∆��)/𝑅 (1/(�1 )− 1/𝑇)]

" "(CPA + CPB )" /"∆HR"

condiciones
xnuevo(y nueva) x y
0.0000 300.15 0
0.0227 300.15 0.000
0.0453 310.15 0.0000
0.0680 310.15 0.022666667
0.0907 320.15 0.0227
0.1133 320.15
0.1360
0.1587
0.1813
0.2040
0.2267
0.2493
0.2720
0.2947
 0.3173
0.3400
0.3627
0.3853
0.4080
0.4307
0.4533
0.4760
0.4987
0.5213
0.5440
0.5667
0.5893
0.6120
0.6347
0.6573
0.6800

Y
0.0000
0.6800
condición
x(TEMP)

300.15

Op
Eq

Op
Eq
 1.2

f(x) = 1.54725238642069E-13x^6 - 4.07049846384712E-10

1

R² = 0.9813854472

0.8

0.6

0.4

0.2

0
300 350 400 450
y(XNUEVO_NUEVO)

0.0000

T K X
404.8727997 0.241905
404.8727997 0.3191 0.241904752
0 2.60676E-07

0 0
0 0
0 0
4.07049846384712E-10x^5 + 4.38454511582327E-07x^4 - 0.0002471351x^3 + 0.07677

450 500 550 600

y1 3125.092473
y2 0.3432

func obj
9105.747299
02471351x^3 + 0.0767764185x^2 - 12.4574484414x + 825.8148434001
x
445
 INTER
0.7000

434001 f(x) = 0.0022666667x - 0.680

0.6000
R² = 1
0.5000

0.4000

0.3000

0.2000

0.1000

0.0000
300 350 400 450
 INTER

67x - 0.68034

450 500 550 600

600