Paper 2 Code 1 Solutions

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JEE MAIN + ADVANCED
EXAMINATION - 2016
QUESTION WITH SOLUTION
PAPER - 2 _ CODE - 1
(Page # 2) JEE (MAIN + ADVANCED) Examination (2016) (Code - 1)
[PHYSICS]
1. The electrostatic energy of Z protons uniformly distributed throughout a spherical nucleus of
3 Z(Z – 1)e2
radius R is given by E 
5 40R
The measured masses of the neutron, 11H, , 15

7 N and 15
8 O are 1.008665 u, 1.007825 u, 15.000109
15 15
u and 15.003065 u, respectively. Given that the radii of both the 7 N and 8 o nuclei are same, 1
u = 931.5 MeV/c (c is the speed of light) and e /(40) = 1.44 MeV fm. Assuming that the
2 2
15 15
difference between the binding energies of 7 N and 8 O is purely due to the electrostatic energy,,
the radius of either of the nuclei is (1 fm = 10 m) –15
(A) 2.85 fm (B) 3.03 fm (C) 3.42 fm (D) 3.80 fm

f=kT; k R oky s, d xksy kdkj ukfHkd esaZ i zksVksu l eku: i l sfor fj r gS
A , sl sukfHkd dhfLFkj fo| q
r Åt kZuhpsl ehdj .k esa
3Z(Z – 1)e2
AE 
nhxbZgS 40R
U; q
VªkW
u 11H, , 15
7 N , oa15
8 O
ukfHkdksads eki s x; s nzO
; eku Øe' k%1.008665 u, 1.007825 u, 15.000109 u , oa
15.003065 u gS
A 15
7 N
, oa15
8 o
ukfHkdksadhf=kT; k, sal eku nhxbZgS
A 1 u = 931.5 MeV/c2 (t gkac çdk' k dhxfr gS
)
vkS
j e2/(40) = 1.44 MeV fmA ; fn 15
7 N vkS
j 15
8 O
dhca
/kd Åt kZ
v ksdk va
r j fl QZ fLFkj fon~
;q
r Åt kZdsdkj .k gS
]
r ksnksuksaesal sfdl hHkh ukfHkd dhf=kT; k D; k gksxh\ (1 fm = 10–15m)
(A) 2.85 fm (B) 3.03 fm (C) 3.42 fm (D) 3.80 fm
Sol. C
15
7 N  7(11H)  8(10 n)
BE(N) = 0.123986 × 931.5 = 115.492959 MeV
15
8 O  8(11H)  7(10 n)
BE(O) = 0.12019 × 931.5 = 111.956985 MeV
3 e2
BE(N) – BE(O) = 3.535974 = [8(7) – 7 (6)]
5 4 ε 0 R
 R = 3.42 fm
2. An accident in a nuclear laboratory resulted in depostion of a certain amount of radioactive

material of half - life 18 days inside the laboratory. Tests revealed that the radiation was 64 times
more than the permissible level required for safe operation of the laboratory. What is the mini-
mum number of days after which the laboratory can be considered safe for use?
(A) 64 (B) 90 (C) 108 (D) 120
, d ukfHkdh; i z;ksx' kky k esanq ?kZ
Vuk dhot g l sj sfM; k, fDVo i nkFkZdhdq N ek=kk t ek gk x; h] ft l dhv/kkZ ;q
a18 fnuksadh
gS A i j h{k.k l si r k py k fd i z;ksx' kky k esafofdj .k dk Lr j l q
j f{kr Lr j l s64 xq. kk T; knk FkkA U; w
ur e fdr usfnuksadsckn
i z;ksx' kky k dke dj usdsfy , l q j f{kr gksxh\
(A) 64 (B) 90 (C) 108 (D) 120
Sol. C
64 = 26
 the material should decay for 6 half lines for a safe laboratory.
Thus answer = 18 × 6 = 108 days
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JEE (MAIN + ADVANCED) Examination (2016) (Code - 1) (Page # 3)
3. A gas enclosed in a cylinder with movable frictionless piston. Its initial thermodynamic state at
pressure Pi = 105 m3 and volume vi = 10–3 m3 changes to a final state a Pf = (1/32) × 105 Pa and
Vf = 8 × 10–3 m3 in an adiabatic quasi - static process, such that P3V5 = constant. Consider
another thermodynamic process that brings the system from the same initial state to the same
final state in two steps : an isobaric expansion at Pi followed by an isochoric (isovolumetric)
process at volume Vf. The amount of heat supplied to the system in the two process in approxi-
mately
(A) 112 J (B) 294 J (C) 588 J (D) 813J
, d [ kks[ky scsy u] ft l esa, d ?k"kZ. k & j fgr py k; eku fi LVu y xk gS] esa, d xS l ca n gSA fudk; dhi zkj fEHkd Å"ekxfr dh
voLFkk ea sxSl dk ncko Pi = 10 m , oavk; r u Vi = 10 m gS
5 3 –3 3
a
A , d : ) ks"e LFkS fr ddYi dh çfØ; k] ft l esaP3V5 =
fLFkj ka
d gS] l sfudk; va fr e Å"ekxfr dhdhvoLFkk Pf = (1/32) × 105 Pa , oaVf = 8 × 10–3 m3 esai fj ofr Z r gkst kr k
gSA , d nw l j hÅ"ekxfr dhçfØ; k esaoghaçkj fEHkd , oava fr e voLFkk, ankspj .kksaesai w
. kZdht kr hgS ] i gy spj .k esaPi i j l eku
ncko of̀) dsckn , d nq l j spj .k esa, d l eku vk; r u çfØ; k Vf vk; r u i j gksrhgS A nkspj .kksaoky hi zfØ; k esafudk; dks
nhxbZÅ"ek dh ek=kk y xHkx gS A
(A) 112 J (B) 294 J (C) 588 J (D) 813J
Sol. C
P1
P1 = 105 P2 =
32
V1 = 10–3 V2 = 8V1
PV5/3 = K
 = 5/3
Q = nCPdT + n CVdT P
P1V1 8T1
5 3 T1
= n R (T2 – T1) + n R (T3 – T2)
2 2
5 3 1
= nR (8T1 – T1) + nR (T3 – 8T1)
2 2 P2V2
5 3
= nR (7T1) + nRTT3 – 12 nRTT1 V
2 2
35 3
= nRT
T1 – 12 nRT1 + nRT
T3
2 2
11 3
= nRT
T1 + nRT
T3
2 2
11 3
(100) + (25)
2 2
1100  75
=
2
1175
= = 588
2
4. The ends Q and R of two thin wires, PQ and RS, are soldered (Joined) together. Initially each of
the wires has a length of 1m at 10º. Now the end P is maintained at 10ºC, while the end S is
heated and maintained at 400 ºC. The system is thermally insulted from its surroundings. If the
thermal conductivity of wire PQ is twice that of the wire RS and the coefficient of linear thermal
expansion of PQ is 1.2 × 10–5 K–1. the change in length of the wire PQ is
(A) 0.78 mm (B) 0.90 mm (C) 1.56 mm (D) 2.34 mm
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, d i r y sr kj PQ dsNksj Q dksvU; i r y s r kj RS dsNksj R i j Vka d k y xkdj t ksM+

k x; k gSA 10ºC i j nksuksar kj ksadh
y EckbZ1m gS A vc bl fudk; dsNksj P r FkkNksj S dksØe' k%10 ºC r Fkk400 ºC i j fLFkj j [ kkt kr k gS A ; g fudk; pkj ks
vksj l sÅ"ekj ks/khgS
A ; fn r kj PQ dhÅ"ekpky dr k r kj RS dhÅ"ek pky dr k l snq xquhgS A r Fkk r kj PQ dkj s[kh; Åf"er
of̀) xq. kka
d 1.2 × 10–5 K–1 gS ] r c r kj PQ dhy EckbZesai fj or Z
u dk eku gS
A
(A) 0.78 mm (B) 0.90 mm (C) 1.56 mm (D) 2.34 mm
Sol. A
P Q R S
1m 1m
P 2k Q K
 400°C
10°C R S
400  0 0  10
=
R R /2
400  0 2(0  10)
= dx
R R
x
420 = 30
10° 140°
420
0 = = 140°C T = 130x + 10
3
dl =  dx
–5
 dl   1.2  10 (130x)dx
l = 1.2 × 10–5 × 65 = 0.78mm

5. A small object is placed 50 cm to the left of a thin convex lens of focal length 30 cm. A convax
spherical mirror of radius of curvature 100 cm is placed to the right of the lens at a distance of 40
cm. The mirror is tilted such that the axis of the mirror is at an angle  = 30º to the axis of the
lens, as shown in the figure.
f=30cm
//
//
/

//
x
//
(0,0)
// ///
(–50,0)
R=
10
0
50 cm
cm
50  50 3,  50
If the origin of the coordinate system is taken to be at the centre of the lens, the coordinates (in
cm) of the point (x, y) at which the image is formed are
(A) (0, 0) (B) (50 – 25 3, 25) (C) (25,25 3) (D) (125 / 3,25 3)
, d NksVhoLr qdks30 cm Qksd l nw j h(focal length) oky s, d i r y smÙky (convax) oky s, d i r y smÙky y sa l dhckbZ a
vksj 50 cm dhnw j hi j j [ kk x; k gSA 100 cm dhoØr k f=kT; k oky s, d mÙky xksy kdkj ni Z . k dksy sa
l dhnkbZavksj 50
cm dhnw j hj [ kk x; k gSA ni Z. k dksbl r j g l s>qd k; k x; k gSfd ni Z
. k dk v{k y sa
l l s = 30º dksdks.k cukr k gS
]t Slk
fp=k esan' kkZ
; k x; k gS
A
f=30cm
//
//
/

//
x
//
(0,0)
// ///
(–50,0)
R=
10
0
50 cm
cm
50  50 3,  50
; fn funsZ
' ka
kd i ) fr dk ew
y fcUnqy sa
l dse/; esagksr kst gk¡ i zfr fcEc cuk gSml fca
nqdk funsZ
' ka
kd (x, y) l sa
VhehVj esa
] D; k
gksxk\
(A) (0, 0) (B) (50 – 25 3, 25) (C) (25,25 3) (D) (125 / 3,25 3)
Sol. Bonus
6. There are two Vernier calipers both of which have 1 cm divided into 10 equal divisions on the
main scale. The Vernier scale of one of the calipers (C1) has 10 equal divisions the correspond to
9 main scale divisions. The Vernier scale of the other caliper (C2) has 10 equal divisions that
correspond to 11 main scale divisions. The readings of the two calipers at shown in the figure.
The measured values (in cm) by calipers C1 and C2, respectively, are
2 3 4
C1
0 5 10
2 3 4
C2
0 5 10
(A) 2.85 and 2.82 (B) 2.87 and 2.83 (C) 2.87 and 2.86 (D) 2.87 and 2.87
nksofuZ; j dSfy i l Zbl r j g l sgS

afd mudseq [; iSekusdk 1 cm, 10 l r HkkxksaesafoHkkft r gS A , d dS fy i j (C1) dsofuZ ;j
iSekusi j 10 cj kcj Hkkx gSt ksfd eq [; iS
ekusds9 Hkkxksadscj kcj gS A nw
l j sdSfy i j (C2) dsofuZ ;j iSekusi j Hkh10 cj kcj
Hkkx gS
at ksfd eq [; iS ekusds11 Hkkxksadscj kcj gS
a
A nksuksadS
fui l Zdsi Buksadksfp=k esan' kkZ
; k x; k gS
A C1 r FkkC2 nqckj keki s
x, l gheku (cm esa ) Øe' k%gSA
2 3 4
C1
0 5 10
2 3 4
C2
0 5 10
(A) 2.85 , oa2.82 (B) 2.87 , oa2.83 (C) 2.87 , oa2.86 (D) 2.87 , oa2.87
Sol. B
LC1 = 1 MSD – 1 VSD LC2 = 1 MSD – VSD
10 VSD  9 MSD 11 VSD  10 MSD
9 10
1 MSD 1 VSD  MSD
10 11
9  10 
LC1 = 1 MS – MS LC2 = 1  11  MS
10  
1 1 1
= MSD =  × cm
10 11 10
1 1
= cm =– cm
100 110
1 1
C1 = 2.8 + 7 × C2 = 2.9 – 7 ×
100 110
= 2.87 = 2.83

7. Two thin circular discs of mass m and 4m, having radii of a and 2a, respectively are rigidly fixed
by a massless, rigid rod of length l  24 a through their centers. This assembly is laid on a firm
and flat surface, and set rolling without slipping on the surface so that the angular speed about

the axis of the rod is . The angular momentum of the entire assembly about the point 'O' is L
(see the figure) Which of the following is statement(s) is (are) true?
4m
z
m
l

l 2a
a
O
(A) The center of mass of the assembly rotates about the z-axis with an angular speed of /5.
(B) The magnitude of angular momentum of center of mass of the assembly about the point O is
81 ma2
(C) The magnitude of angular momentum of the assembly about its center of mass is 17ma2/2

(D) The magnitude of the z-component of L is 55ma2
m r Fkk4m nzO ; eku oky hnksi r y hoR̀r kdkj pf=kdk, ¡ ft udhf=kT; k, saØe' k%a r Fkk 2a gS] dsdsUnzksadksl  24 a y EckbZ
dhnzO ; eku & j fgr nz<+Ba Mhl st ksM+
k x; k gS
A bl l ew g dks, d et cw r l er y l r g i j fy Vk; k x; k gSvksj fQl y k; sfcuk

bl r j g l s?kqek; k x; k gSfd bl dhdks.kh; xfr Ba Mhdsv{k dsfxnZ gS Ai w
j sl ew
g dk fcUnq'O' dsfxnZdks.kh; l a osx L
(fp=k esans[ksa
) fuEufy f[ kr es
al sdkS ul k@dkSul sdFku l R; gS @gSa
\
4m
z
m
l

l 2a
a
O

(A) L dsz--?kVd dk i fj ek.k 55ma2gS A
(B) i w
j sl ew
g dsl a
gfr & dsUnzdksfcUnqz-v{k dsfxnZdks.kh; osx /5 l s?kw e j gk gS
A
(C) i w
j sl ew
g dk l a
gfr dsUnzdk fcUnqO dsfxnZdks.kh; l a osx dk i fj ek.k 81 ma2 gS A
(D) i w
j sl ew
g dsl agfr & dsUnzdsfxnZdks.kh; l a
osx dksi fj ek.k 17ma2/2 gS A
Sol. A,C
8. Light of wavelength ph falls on a cathode plate inside a vacuum tube as shown in the figure. The
work function of the cathode surface is  and the anode is a wire mesh of conducting material
kept at a distance d from the cathode. A potential difference V is maintained between the elec-
trode. If the minimum de Broglie wavelength of the electrons passing through the anode is e,
which of the following statement(s) is (are) true?
Light
Electrons
V
– +
(A) e decreases with increase in  and ph

(B) e is approximately halved, if d is doubled
(C) For large potential difference (V >> /e), e approximately halved if V is made four times
(D) e increases at the same rate as ph for ph < hc/
ph r j a
xnS/; Zdk i zd k' k fuokZ
r uy hdk dsva nj , d dSFkksM i j fxj r k gS
]tS l k fp=k esan' kkZ; k x; k gS
A dS FkksM+dh l r g dk
dk; ZQy u  gS, oa, uksMt ksfd , d pky dh; i nkFkZdsr kj ksadht ky hgS ] dS
FkksM+l sd nw j hi j fLFkr gSA by sDVªksMksadschp dk
foHkokUr j V fLFkj gS A ; fn , uksM dksi kj dj usoky sby sDVªksuksadh U; w
ur e Þnh czksXy hß r j a
xnS/; Ze gS] fuEufy f[ kr esal s
dkS
ul k@dkS
ul sdFku l R; gS
@gS
a
\
Light
Electrons
V
– +
(A) vxj ph < hc/gSr ksph dsl kFke , d l eku nj l sc<+ sxkA
(B)  vkS
j ph dksc<+ kusi j e de gksxkA
(C) d dksnqxquk dj usi j e y xHkx vk/kk gkst k, xkA
(D) mPp foH kokUr j (V >> /e), i j vxj V dkspkj c<+ k; k t k, r kse y xHkx vk/kk gkst k, xkA
Sol. C
hc
eV  
ph
hc 
v 
phe e
h
e 
2mE
h
e 
2meV
9. In an experiment to determine the acceleration due to gravity g, the formula used for the time
7(R – r)
period of a periodic motion is T = 2 . The values of R and r are measured to be (60 ± 1)
5g
mm and (m ± 1) mm, respectively. In five successive measurements, the time period is found to
be 0.52 sw, 0.56 s, 0.57 s, 0.54 s and 0.59. The least count of the watch used for the measure-
ment of time period is 0.01 s. Which of the following statement(s) is (are) true?
(A) The error in the measurement of r is 10%
(B) The error in the measurement of T is 3.57%
(C) The error in the measurement of T is 2%
(D) The error in the determined value of g is 11%

7(R – r)
xq
: Roh; Roj .k g dsfu/kkZ
j .k ds, d i z;ksx esai z;q =k T = 2
Dr vkor hZ& xfr dk l e; dky dk l w 5g
gS
A R r Fkkr
dkeki kx; keku Øe' k%(60 ± 1) mm r Fkk(10 ± 1) mm gS Ay xkr kj i ka

p eki u esa
eki kx; kl e; dky 0.52 sw, 0.56
s, 0.57 s, 0.54 s r Fkk0.59 gSA l e; dky dseki u dsfy , i z;ksx esay k; hx; h?kM+
hdkvYi Reka d 0.01 s gSAfuEufy f[ kr
esal sdkS
ul k@dkS
ul sdFku l R; gS
a\
(A) r dseki u esa=kq
fV 10% gS A (B) T dseki u es a=kq
fV 3.57% gS A
(C) T dseki u esa=kqfV 2% gSA (D) g dsfudky sx; seku es a=kq
fV 11% gS A
Sol. A,B,D
r 1
(a)  100   100  10%
r 10
7 R  r 
(b) T  2
5g
R = 60 ± 1
r = 10 ± 1
0.52  0.56  0.57  0.54  0.59

Tm 
5
= 0.556
T1 = 0.556 – 0.52 = 0.036
T2 = 0.556 – 0.56 = 0.004
T3 = 0.556 – 0.57 = 0.014
T4 = 0.556 – 0.54 = 0.016
T5 = 0.556 – 0.59 = 0.036
0.036  0.016  0.014  0.004  0.036

Tn 
5
T 0.020
  100 = 3.57%
T 0.556
42 7R  r 
(d) g
5T 2
g  R  r  T
 2
g R r T
2 2  0.02
 
50 0.556
 2 42 
    100
 50 55 
= 4 + 7.5
= 11.7 %
10. Consider two identical galvanometers and two identical resistors with resistance R. If the internal
of the galvanometers RC < R/2, which of the following statement(s) about any one of the
galvanometer is (are) true?
(A) The maximum voltage range is obtained when all the components are contained in series
(B) The maximum voltage range is obtained when the two resistors and one galvanometer are
connected in series, and the second galvanometer is connected in parallel to the first galvanometer
(C) The maximum current range is obtained when all the components are connected in parallel
(D) The maximum current range is obtained when the two galvanometers are connected in series
and the combination is connected in parallel with both the resistors
nks, d l eku xsYosuksehVj r Fkk , dl eku i zfr j ks/k R oky snksi zfr j ks/k fn; sx; sgSA ; fn xsYosuksehVj dk vka r fj d i zfr j ks/k RC <
R/2 gS ] r ksfdl hHkh, d xsYosuksehVj dsckj sesafn; sx, fuEufy f[ kr dFkuksaesal sdkS ul k@dkS ul sl R; gS @gS a
\
(A) i zkIr fd xbZoksYVr k i fj l j vf/kdr e gksxht c l Hkh?kVd Js.kh esat q M+sgq, gSA
(B) i z kIr fd xbZoksYVehVj i fj l j vf/kdr e gksxh t c nksi zfr j ks/kd r Fkk , d xsYosuksehVj Js.kh esat q MsgS ar Fkk nw l jk
xsYosuksehVj i gy sxsYosuksehVj dsl ekukUr j esat q M+
k gS
A
(C) i z kIr fd xbZ/kkj k i fj l j vf/kdr e gksxht c l Hkh?kVd l ekukUr j ea st qM+
sgSA
(D) i z kIr fd xbZ/kkj ki fj l j vf/kdr e gksxht c nksxsYosuksehVj Js.khesat q M+
sgSAr Fkk; sl a; kst u i zfr j ks/kdksadsl kFkl ekukUr j
ea
st qM+ k gSA
Sol. A,C
V = Ig (Rg + S)
if Rg and S is large V 
 Rg 
I  Ig  1  
 s 
if s  Rg 
Then I 
11. In the circuit shown below, the key is pressed at time t = 0. Which of the following statement (s)
is (are) true ?
40F 25k
–
V
+
50F 20F
+ –
Key 5V
(A) The voltmeter displays –5 V as soon as the key is pressed, and displays +5 after a long time
(B) The voltmeter will display 0 V at time t = In 2 seconds
(C) The current in the ammeter becomes 1/e of the initial value after 1 second
(D) The current in the ammeter becomes zero after a long time
uhps:fn[
0744-2209671,
kk, x, i fj IkFkesal 08003899588
e; t = 0 i j cVu| (key)
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AfuEufyf[ kr esal :info@motioniitjee.com
dksnck; kx; kgS sdkSul k@dkS
ul sdFku l R; gS
@gS\
40F 25k
–
V
+
50F 20F
+ –
Key 5V
(A) cVu dksnckr sgh oks
YVehVj –5 V fn[ kkr k gSt cfd y a csl e; dsckn oks+5 V fn[ kkr k gSafter a long time
(B) l e; t = In 2 seconds i j oks YVehVj ' kw U; oksYV fn[ kkr k gS
(C) 1 second dsckn vehVj es a/kkj k i zkj fEHkd /kkj k dks1/e xq . kk gksrh gS
A
(D) y a
csl e; dsckn vehVj esa/kkj k ' kw
U; gkst kr hgS
Sol. A,B,C,D
0V 5V
25k at t = 0 25k
5 – 0 5 – 0
V V
+ +
50F 50F
A A
(a) 5V  0V
+ – + –
Key 5V Key 5V
40F 40F
5 0 5 0
2.5V 2.5V
(b)
5V 5V
V = 5 (1 – e–t/RC)
RC = 1
V = 5 (1 – e–ln(2))
V = 2.5 V
 Potential difference is zero.
(c) I = I0(e–t/RC)
RC = 1
at t = 1 sec.
I = I0/e
(d) at = 
I=0
12. A block with mass M is connected by a massless spring with stiffness constant k to a rigid wall
and moves without friction on a horizontal surface. The block oscillates with small amplitude A
about an equilibrium position x0 . Consider two cases: (i) when the block is at x0; and (ii) when
the block is at x = x0 + A. In both the cases, a particle with mass m(<M) is softly placed on the
block after which they stick to each other. Which of the following statements (s) is (are) true
about the motion after the mass m is placed on the Mass M ?
M
(A) The amplitude of oscillation in the first case changes by a factor of , whereas in the
m+M
second case it remains unchanged
(B) The final time period of oscillation in both the case is same
(C) The total energy decreases in both the cases
(D) The instantaneous speed at x0 of the combined masses decreases in both the cases
, d nzO
; eku&j fgr fLi a
zx] ft udk nz<+
r kxq
. kka
d (stiffness constant) k gS
] ds, d Nksj i j M nzO
; eku dk , d xq
Vdk t q
M+k
gS
] r Fkk nw
l j sNksj dksnz<+nhokj l st ksM+ k x; k gS
A ; g xq Vdk , d l er y ni Z . k ?k"kZ
. k&j fgr l r g i j , d l arq
fy r fLFkfr
x0 dsfxnZNks Vsvk; ke A l snksy u dj r k gS A ; g¡k nksi fj fLFkfr ; kaekfu, %(i) t c xq Vdk x0 i j gSvkS j (ii) t c xqVdk
x = x0 + A i j gS A nksuka
si fj fLFkfr ; ksaesanzO
; eku m(<M) ds, d d.k dksxq Vdsi j /khjsl sbl i zd kj j [ kk t kr k gSdhog
rq
ja
r xq Vdsl sfpi dst kr kgSAd.kdksxq VdsdsÅi j dsckn xfr dsckjsesafuEufyf[ kr esal sdkS ul k@dk
S
ul sdFku l R; gS@gS\
M
(A) i gy h i fj fLFkfr esanksy u dk vk; ke , HkkT; (factor) l si fj ofr Z
r gksrk gS
] t cfd nw
l j h i fj fLFkfr esa; g
m+M
vi fj ofr Z
r j gr k gS A
(B) nks uksai fj fLFkfr ; ksaesanksy u dk va fr e l e; dky l eku gS
(C) nks uksai fj fLFkfr ; ksaesal Ei w
. kZÅt kZde gkst kr hgS A
(D) l fEefy r nz O; ekuksadhx0 i j r kR{kf.kd xfr nksuksai fj fLFkfr ; ksaesade gkst kr hgS
A
Sol. A,B,D
(a) M
MA = (m + M) 'A'
K k
M A  m  M  A'
M Mm
A' M

A mM
M  m 
(b) T  2
k
Time period remain same in both case. After m mass is pla ced on both block.
13. While conducting the Young’s double slit experiment, a student replaced the two slits with a large
opaque plate in the x-y plane containing two small holes that act as two coherent point sources
(S1,S2) emitting light of wavelength 600 nm. The student mistakenly placed the screen parallel to
the x-z plane (for z > 0) at a distance D = 3 m from the mid-point of S1S2, as shown schematically
in the figure. The distance between the sources d = 0.6003 mm. The origin O is at the intersection
of the screen and the line joining S1S2. Which of the following is (are) true of the intensity pattern
of the screen ?
Screen
O
y
S1 S2
x
d
d

(A) Straight bright and dark bands parallel to the x-axis
(B) The region very close to the point O will be dark
(C) Hyperbolic bright and dark bands with foci symmetrically placed about O in the x-direction
(D) Semi circular bright and dark bands centered at point O
, d fo| kFkhZus; ax nksfy LV oky si z;ksx (Young’s double slit experiment,) dj r sl e; nksfLy Vksadht xg , d cM+ h
l er y vi kj n' khZi V~
Vhdksx-y r y i j j [ k fn; kA bl i V~ VhesanksfNnzgSat ks600 nm r j a xnS /; Zi zd k' k mRiUUk dj usoky s
nksdy kl ac} fca nqL=kksrksa (S1, S2) dsl eku gS a
A fo| kFkhZusxy r hl si nsZ (screen) dksx-z r y ( z > 0) dsl ekukUr j
S1S2 dse/; fca nql sD = 3m dhnw j hi j j [ k fn; k] t S
l k dhO; oLFkk&fp=k esafn[ kk; k x; k gSA L=kksrksadschp fd nw j hd =
0.6003 mm gS A S1S2 dkst ksM+ usoky hj s[kkt gkai nsZl sfey r hgSogk¡i j ew y fcanqO gS A i nsZi j r hozrki zfr : i (intensity
pattern) dsfy , fuEufy f[ kr es al sdkS ul k@dkS ul sdFku l R; gS\
Screen
z
O
y
S1 S2
x
d
d
(A) fca
nqO i j dsfUnzr v/kZoÙ̀kh; nhIr r Fkk vnhIr i fV~
V; k¡
(B) x-v{k dsl ekukU r j nhIr r Fkk vnhIr l h/khi fV~
V; k¡
(C) fca
nqO dk fudVr e {ks=k vnhIr gksxk
(D) x-fn' kk es
afca
nqO dsfxnZl efer Qksd l ksadsl kFk vfr i j oy f; d (Hyperbolic) nhIr r Fkk vnhIr i fV~
V; k¡
Sol. B,D
(b) Fringes will be semi–circular.
d 0.6003  103
Now, 
 600  109
d 1
 103 
 2
So, the region very close to O is dark.
(d) Semi circular bright and dark fringes will be formed.
14. A rigid wire loop of square shape having side of length L and resistance R is moving along the x-
axis with a constant velocity v0 in the plane of the paper. At t = 0, the right edge of the loop
enters a region of length 3L where there is a uniform magnetic field B0 into the plane of the paper,
as shown in the figure. For sufficiently large v0, the loop eventually crosses the region. Let x be
location of the right edge of the loop. Let v(x), I(x) and F(x) represent the velocity of the loop,
current in the loop, and force on the loop, respectively, as a function of x. Counter-clockwise
current is taken as positive.
× ×
× ×
× ×
× ×
× ×
× ×
× ×
× ×
L × ×
v0 × ×
× ×
× ×
× ×
× ×
x
0 L 2L 3L 4L
Which of the following schematic plot(s) is(are) correct ? (Ignore gravity)
v(x)
I(x)
3L 4L
x
(A) (B) 0 L 2L
x
0 L 2L 3L 4L
I(x) I(x)
(C) (D)
x x
0 L 2L 3L 4L 0 L 2L 3L 4L
, d oxhZ; vkdf̀r oky k r kj dk nz<+Qa nk] ft l dsHkq
t k dhy ackbZL , oai zfr j ks/k R gS
] x-v{k dhfn' kk esa, d fLFkj xfr v0
l sbl dkxt dsIy su i j (palane of the paper) xfr eku gS A l e; t = 0 i j Qa nsdk nksfguk fdukj k 3L y ackbZdsfLFkj
pqa
cdh; {ks=k B0 esai zos'k dj r k gS A pq a
cdh; j s[kkvksadhfn' kk dkxt dsIy su dsy a cor ~va
nj dhvksj gS¼ tSl k fp=k esan' kkZ
;k
x; k gS
½| v0 dkeku i ; kZ Ir gksusi j va r r ksxRokQankpqa
cdh; {ks=kdksi kj dj r kgS A eku y hft , dhQa nsdhnkfguhHkq t kLFkku
x i j gS
A Qansdhxfr ] Qa nsesa/kkj k , oaQa nsi j cy dhx i j fuHkZ
j r k dksØe' k%v(x), I(x) , oaF(x) l sfu: fi r fd; k x; k
gSA okeor Z/kkj k dksi ksft fVo y saA
× ×
× ×
× ×
× ×
× ×
× ×
× ×
× ×
L × ×
v0 × ×
× ×
× ×
× ×
× ×
x
0 L 2L 3L 4L
fuEufy f[ kr esal sdkS

ul k@dkS
ul sO
; oLFkk fp=k l ghgS\ (xq
: Rokd"kZ
. k ux.; ekus)
v(x)
I(x)
3L 4L
x
(A) (B) 0 L 2L
x
0 L 2L 3L 4L
I(x) I(x)
(C) (D)
x x
0 L 2L 3L 4L 0 L 2L 3L 4L
Sol. A,B
d
 
dt

dA
B
dt
dx
  Bl
dt
 = Blv

i
R
B2l2
F k
R
dv B2l2
mv  k
dx R
v x    B2l2
v0
dv 
0  Rm
dx
B2l2
v  v0  x
mR
PARAGRAPH1
A frame of reference that is accelerated with respect to an inertial frame of reference is called a
non-inertial frame of reference. A coordinate system fixed on a circular disc rotating about a fixed
axis with a constant angular velocity  is an example of a non-inertial fram of reference. The

relationship between the force Frot experienced by a particle of mass m moving on the rotating

disc and the force Fin experienced by the particle in an inertial frame of reference is
 
 
    
F rot  F in  2m  vrot     m    r   ,
   

where vrot is the velocity of the particle in the rotating frame of reference and  r is the position
vector of the particle with respect to the centre of the disc.
Now consider a smooth slot along a diameter of a disc of radius R rotating counter-clockwise with
a constant angular speed  about its vertical axis through its center. We assign a coordinate
system with the origin at the center of the disc, the x-axis along the slot, the y-axis perpendicular
 
to the slot and the z-axis along the rotation axis    k̂  . A small block of mass m is gently
 
^
placed in the slot at 
r = (R/2) i at t = 0 and is contained to move only along the slot.
, d funsZ
' kr a
=k t ks, d t M+
Roh; funsZ
' kr a
=k dhr q
y uk esaRofj r gks] vt M+
Roh; funsZ
' kr a
=k dgy kr k gS
A fLFkj dks.kh; osx l s
?kw
er hgq
bZfMLd i j c} (fixed) funsZ ' kr a
=kvt M+
Roh; r a=k dk , d mnkgj .k gSA m nzO ; eku dk, d d.k ?kw er hgqbZfMLd i j

xfr eku gS
A xfr eku d.k fMLd i j c} funsZ
'k ra
=k ds l ki s{k cy Frot r Fkk , d t M+
Roh; funsZ
'k ra
=k ds l ki s{k cy

Fin dksegl w A Frot vkS
l dj r k gS 
j F in dschp dk l a
ca
/k fuEufy f[ kr l ehdj .k esafn; k x; k gS
A
 
 
    
F rot  F in  2m  vrot     m    r    ,
   
; gk¡ i j vrot ?kw
er sgq
, funsZ
' kr a
=k esad.k dk osx gSr Fkk r d.k dk fMLd dse/; fca
nqdsl ki s{k fLFkfr l fn' k (position
vector) gS A
ekfu, fd R f=kT; k dh, d fMLd] ft l esaO ; kl dsl ekukUr j , d ?k"kZ

. kj fgr [ kka
pk gS
] , d fLFkj dks.kh; xfr l svi usv{k
i j okekor Zfn' kkesa?kw
e j ghgS
A , d funsZ
' kr a
=k ekfu, ft l dk ew
y fca
nqfMLd dse/; fca nqi j gS, oax-v{k [ k¡kpsdsl ekukUr j
 
gS eusoky hv{k dsl ekukUr j gS   k̂  1 m nzO
] y-v{k [ k¡kpsdsvfHky Ec i j gS, oaz-v{k ?kw ; eku oky s, d NksVsxq
Vds
 
dksl e; t= 0 i j r = (R/2) î fca

nqi j /khjsl sbl r j g l sj [ kk t kr k gSfd oksfl QZ[ k¡kpsesaghpy l dsA


m
R/2
15. The distance r of the block at time t is

R t R
(A) (e  e–t ) (B) cos t
4 4
R 2 t R
(C) (e  e–2 t ) (D) cos 2t
4 2
l e; t i j xq
Vdsdhnw
j hr dk eku gS%
R t R
(A) (e  e–t ) (B) cos t
4 4
R 2 t R
(C) (e  e–2 t ) (D) cos 2t
4 2
Sol. A
dv
mx2 = mv
dx
2xdx = vdv
v2 = 2x2 + C
R
At x = , v=0
2
 R2 2
O= +C
4
2 2
R
C=–
4
2R 2
 v2 = 2x2 –
4
2
R
v =  x2 –
4
dx 2 R2
= x –
dt 4
dx
 x – R2 / 4
2 
=  dt
On solving, we get option (A).

16. The net reaction of the disc on the block is

1 2 2 t –2 t ˆ ˆ 1 2 t – t ˆ ˆ
(A) m R(e – e )j  mgk (B) m R(e – e )j  mgk
2 2
(C) –m2R cos tj ˆ – mgk ˆ (D) m2R sin tjˆ – mgk ˆ
xq
Vdsi j fMLV dhusV i zfr fØ; k (net reaction) gS
%
1 ˆ
ˆ  mgk 1 ˆ
ˆ  mgk
(A) m2R(e2t – e–2 t )j (B) m2R(et – e– t )j
2 2
(C) –m2R cos tj ˆ

ˆ – mgk ˆ
ˆ – mgk
(D) m2R sin tj
Sol. B
Net reacn of the disc on the
block is obtained by
using
      
Frot = Fin + 2m( Vrot ×  ) + m(  × r ) × 
as
1
m2R(et – e–t) ĵ + mg k̂
2
PARAGRAPH 2
Consider an evacuted cylindrical chamber of height h having rigid conducting plates at the end
and an insulting curved surface as shown in the figure. A number of spherical balls made of a
light weight and soft material and coated with a conducting material are placed on the bottom
plated. The balls have a radius r << h. Now a high voltage source (HV) is connected across the
conducting plates such that the bottom plate is at +V0 and the top plate at –V0. Due to their
conducting surface, the balls will eventually collide with the top plate, where the plate and are
repelled by it. The balls will eventually collide with the top plate, where the coefficient of restitution
can be taken to be zero due to the soft nature the material of the balls. The electric field in the
chamber can be considered to be that of a parallel plate capacitor. Assume that there are no
collisions between the balls and the interaction between them is negligible. (Ignore gravity)
h ÅapkbZoky sfuokZ fr r (evacuated) , d csy ukdkj d{k dsnksuksaNksjksi j nksnzo (rigid) pky d i fV~ Vdk, agSvkS j ml dk
oØi `"V vpky d gS ]t Sl k dhfp=keesan' kkZ ; k x; k gSA de Hkkj oky heq y k; e i nkFkZl scuhgq ; hdbZxksy kdkj xksfy ; k¡] ft udh
l r g i j , d pky d i nkFkZdhi j r p<+ hgS] uhpsoky hi fV~ Vdk i j j [ khgq bZgSa
A bu xksfy ; ksdhf=kT; k r << h gS A vc , d
mPPk oksYVr k dk L=kksr (HV) bl r j g l st ksM+ k t kr k gSfd uhpsoky h i fV~ Vdk i j +V0 , oaÅi j oky h i fV~ Vdk i j
–V0 dk foH ko vk t kr k gS A pky d i j r dsdkj .k xksfy ; k¡ vkosf' kr gksd j i fV~Vdk dsl kFk l efoHko gkst kr hgSft l dsdkj .k
osi fV~
Vdkl si zfr df"kZ r gksrhgSA var r ksxRokxksfy ; ¡kÅi j hi fV~ Vdkl sVdj kr hgS ] t gk¡i j xksfy ; ksadsi nkFkZdheq y k; e i zd f̀r
dsdkj .k i zR; oLFkku xq . kka
d (coefficient of restitution) dks' kw U; fy ; k t k l dr k gS A d{k esafo| q r {ks=k dksl ekukUr j
i fV~
Vdk oky sl a /kkfj =k dsl eku ekuk t k l dr k gS A xksfy ; ksadh, d nw l j sl si kj Li fj d fØ; k , oaVdj ko dksux.; ekuk t k
l dr k gSA (xq : Rokd"kZ . k ux.; gS A)
A
–V0 e=0
–
V0
+
+V0
17. Which one of the following statements is correct?

(A) The balls will stick to the top plate and remain there
(B) The balls will bounce back to the bottom plate carrying the same charge they went up with
(C) The balls will bounce back to the bottom plate carrying the opposite charge they went up with
(D) The balls will execute simple harmonic motion between the two plates
fuEufy f[ kr esal sdkS ul k dFku l R; gS\
(A) xksfy ; k¡ nksuksai fV~
Vdkvksadschp l j y vkor Zxfr fu"i kn dj sa
xhA
(B) xksfy ; ¡k Åi j h i fV~Vdk i j fpi ddj oghaj g t kr hgS
a
(C) xksfy ; ¡k ft l vkos'k dsl kFk Åi j t kr hgSaml hvkos'k dsl kFk mNy dj fupy hi fV~ Vdk i j oki l vk t kr hgSA
(D) xksfy ; ¡k ft l vkos'k dsl kFk Åi j t kr hgS
aml dsfoi j hr vkos'k dsl kFk mNy dj fupy hi fV~
Vdk i j oki l vk t kr hgS
A
Sol. C
A
–V0 e=0
–
V0
+
+V0
Balls placed on +ve plate become positive charge and move upward due to electric field. These
balls on colliding with negative plate become negatively charged and move opposite to the direc-
tion of electric field.
18. The average current in the steady state registered by the ammeter in the circuit will be
(A) zero (B) proportional to the potential V0
(C) proportional to V01 / 2 (D) proportional to V02
i fj i Fk esay xk, vehVj esaLFkk; hvoLFkk esavkS
l r /kkj k
(A) V02 dsl ekuq i kr h gksxh (B) dk eku ' kw
U; gksxk
(C) V01 / 2 dsl ekuq
i kr h gksxh (D) V01 / 2 dsl ekuq
i kr h gksxh
Sol. D
qv
F  qE 
d
qv
ma 
d
qv
a
md
1 2
 d at
2
1 qv 2
d t
2 md
1
t2 
qv
 qv
1
t2 
v2
1
 t
v
q
 i
t
i 0 v2

[CHEMISTRY]
19. For the following electrochemical cell at 298 K,
Pt(s)|H2(g, 1 bar)|H+(aq, 1M)||M4+(aq), M2+ (aq)|Pt(s)
[M2  (aq)]
Ecell = 0.092 V when = 10x
[M4  (aq)]
0 RT
Given : EM4 /M2 = 0.151 V; 2.303 = 0.059 V
F
The value of x is
(A) –2 (B) –1 (C) 1 (D) 2
298 K i j fuEufy f[ kr oS
|q
r &j kl k; fud l sy (electrochemical cell)]
Pt(s)|H2(g, 1 bar)|H+(aq, 1M)||M4+(aq), M2+ (aq)|Pt(s)
[M2  (aq)]
dsfy ; sEcell = 0.092 V t c [M4 (aq)] = 10x
RT
eku y hft , fd : E0M 4
/M2 = 0.151 V; 2.303 = 0.059 V rc
F
x dk eku D; k gks
xk \
(A) –2 (B) –1 (C) 1 (D) 2
Sol. D
Anode
M+4 + H2 M+2 + 2H
M2 
0.06  
Ecell = E°cell – log  4 
2 M
 
M2
0.092 = 0.151 – 0.03 log
M4
M2 
 
= –0.06 = –0.03 log10 M4 
 
M2 
  [M2  (aq)]
M4  = 10
2
[Given = 10x]
  [M4  (aq)]
10x = 102
=x=2
20. THe qualitative sketches I, II and III given below show the variation of surface tension with
molar concentration of three different aqueous solution of KCl, CH3OH and CH3(CH2)11 OSO3 –Na+
at room temperature. The correct assignment of the sketches is
II
Surface tension
Surface tension
Surface tension
I III
concentration concentration concentration
(A) I : KCl II : CH3OH III : CH3(CH2)11OSO3–Na+

(B) I : CH3(CH2)11OSO3–Na+ II : CH3OH III : KCl
(C) I : KCl II : CH3(CH2)11 OSO3–Na+ III : CH3OH
(D) I : CH3OH II : KCl III : CH3(CH2)11 OSO3–Na+
uhpsfn; sxq . kkRed j s[kkfp=k I, II r Fkk III l kekU; r ki i j KCl, CH3OH r Fkk CH3(CH2)11 OSO3 –Na+ dsr hu fHkUu
t y h; foy ; uksadh eksy j l kUnzrk (concentration) dsl kFk i `"B r uko (Surface tension) dsi fj or Z u dksn' kkZ
r sgSa
A
j s[kkfp=kksadk l gh fufnZ "Vhdj .k D; k gS\
II III
i `"B r uko
i `"B r uko
I
i `"B r uko
l kUnz
.k l kUnz.k l kUnz.k
(A) I : KCl II : CH3OH III : CH3(CH2)11OSO3–Na+
(B) I : CH3(CH2)11OSO3–Na+ II : CH3OH III : KCl
(C) I : KCl II : CH3(CH2)11 OSO3–Na+ III : CH3OH
(D) I : CH3OH II : KCl III : CH3(CH2)11 OSO3–Na+
Sol. D
According to theory
21. In the following reaction sequence in aqueous solution, the species X, Y and Z, respectively,
are
Ag+ Ag+ with time
S2O32– X Y Z
Clear White Black
Solution Precipitate Precipitate
(A) [Ag(S2O3)2]3–, Ag2S2O3, Ag2S (B) [Ag(S2O3)3]5–, Ag2SO3, Ag2S
(C) [Ag(SO3)2]3–, Ag2S2O3, Ag (D) [Ag(SO3)3]3–, Ag2SO4, Ag2
t y h; foy ; u esafuEufy f[ kr vfHkfØ; k vfHkØe esa
] Li h'kht (species) X, Y r Fkk Z Øe' k%gS
%
&
+ +
Ag Ag with time
S2O32– X Y Z
l kQ l Qsn dkyk
foy; u vo{ks
i vo{kis
(A) [Ag(S2O3)2]3–, Ag2S2O3, Ag2S (B) [Ag(S2O3)3]5–, Ag2SO3, Ag2S
(C) [Ag(SO3)2] , Ag2S2O3, Ag
3–
(D) [Ag(SO3)3]3–, Ag2SO4, Ag2
Sol. A
Ag  with
S2O32–   X Ag
 Y 
time
Z
clearsol white ppt Black PPt
3
X =  Ag S2O3 2  clearsol.
y = Ag2S2O3 white ppt
22. The geometries of the ammonia complexes of Ni2+, Pt2+ and Zn2+, respectively, are
(A) octahedral, square planar and tetrahedral
(B) square planar, octahedral and tetrahedral
(C) tetrahedral, square planar and octahedral
(D) octahedral, tetrahedral and square planar
Ni2+, Pt2+ r Fkk Zn2+ dsveks fu; k l a
dq y ksadhT; kfefr ; k¡ Øe' k%gS
a
(A) v"VQy dh; ] oxZl er y h r Fkk pr q"Qy dh;
(B) oxZl er y h] v"VQy dh; r Fkk pr q"Qy dh;
(C) pr q
"Qy dh; ] oxZl er y hr Fkk v"VQy dh;
(D) v"VQy dh; ] pr q"Qy dh; r Fkk oxZl er y h
Sol. A
2
Ni2+  Octahedral  Ni NH3 6 
2
Pt2+  sq. planar  Pt NH3 4 
2
Zn2+  Tetrahedral  Zn NH3 4 

23. The correct order of acidity for the following compounds is
CO2H
CO2H CO2H CO2H
HO OH OH
(I) (II) (III) (IV)
OH OH
(A) I > II > III > IV (B) III > I > II > IV (C) III > IV > II > I (D) I > III > IV > II
fuEufy f[ kr ; kS
fxdksadhvEy r k dk l ghØe gS
CO2H
CO2H CO2H CO2H
HO OH OH
(I) (II) (III) (IV)
OH OH
(A) I > II > III > IV (B) III > I > II > IV (C) III > IV > II > I (D) I > III > IV > II
Sol. A
– –
O O
CO2H H H
C
HO OH O O
+
(I) –H
– –
O O
CO2H H
C
OH O
+
(II) –H
CO2H
(III) (–I)
OH
CO2H
1
(IV) Acidity  (–I) 
(M)
OH
24. The major product of the following reaction sequence is

O
(i) HCHO (excess)/NaOH, heat

+
(ii) HCHO/H (catalytic amount)
O OH
O O O O OH O O
HO
(A) (B) (C) (D)
OH
fuEufy f[ kr vfHkfØ; k vfHkØe dk eq
[ ; mRikn gS
O
(i) HCHO (v f/kd ek=kk)/NaOH, Å"ek

(ii) HCHO/H (mR i zsjd ek=kk)(Catalytic amount)
+
O OH
O O O O OH O O
HO
(A) (B) (C) (D)
OH
Sol. A
25. According to Molecular Orbital Theory,

(A) C22 is expected to be diamagnetic
(B) O22+ is expected to have a longer bond length than O2
(C) N2+ and N2 have the same bond order
(D) He2+ has the same energy as two isolated He atoms
v.kqd{kd fl ) kUr (Molecular Orbital Theory) dsvuq
l kj
(A) C22 i z
R; kf' kr : i l si zfr pq
Ecdh; (diamagnetic) gS A
(B) O2 dh vkca
2+
/k y EckbZ(Bond length) i zR; kf' kr : i l sO2 dhvkca
/k y EckbZl sy EchgS
A
(C) N2 r Fkk
+
dhvkca
N2 /k dksfV (Bond order) l eku gSA
(D) He2 dh Åt kZnks, dy (isolated) He i j ek.kq
+
v ksadhÅt kZdsl eku gS
A
Sol. A,C
According to M.O.T.
C22– does not have any unpaired electron
N2+ & N2– has 2.5 (same B.O.) B.O.
26. Mixture(s) showing positive deviation from Raoult's law at 35°C is(are)
(A) carbon tetrachloride + methanol (B) carbon disulphide + acetone
(C) benzene + toluene (D) phenol + aniline
feJ.k t ks35°C i j j kmYV fu; e (Raoult's law) l s/kukRed fopy u i znf' kZ
r dj r k gS¼
dj r sgS
a
½
(A) dkcZu VsVªkDy ksjkbM+ esFksukW
y (B) dkcZu Mkbl YQkbM + , l hVksu
(C) cs
Ut hu + VW kYohu (D) QhukWy + , fuy hu
Sol. A, B

27. The CORRECT statement(s) for cubic close packed (ccp) three dimensional structure is(are)
(A) The number of the nearest neighbours of an atom present in the topmost layer is 12
(B) The efficiency of atom packing is 74%
(C) The number of octahedral and tetrahedral voids per atom are 1 and 2, respectively
(D) The unit cell edge length is 2 2 times the radius of the atom
?kuh; fufcM l adq fy r (cubic close packed) (ccp) f=kfoeh; l a j puk dsfy ; sl ghdFku gS
@gSa
(A) , d i j ek.kqt ksl oks
Z
Pp i j r (topmost layer) esami fLFkr gSml dsfudVr e i zfr osf' k; ksa¼ i M+
ksfl ; ksa
½dhl a
[ ; k 12 gS
A
(B) i j ek.kqdh l adqy u {ker k74% gS
(C) v"VQy dh; r Fkk pr q "Qy dh; fj fä ; ksadhl a
[ ; k i zfr i j ek.kqØe' k%1 o 2 gS
(D) , d dksf"Bdk dsdksj (unit cell edge) dhy EckbZi j ek.kqdhf=kT; k dk 2 2 xq
uk gS
A
Sol. B, C, D
A=9
B = 74%
C = O.V and T.V. per atom are 1 and 2 respectively
D = r = 2 a
2 × 2r = 2a
a= 2 2 r
28. Extraction of copper from copper pyrite (CuFeS2) involves

(A) crushing followed by concentration of the ore by froth-flotation
(B) removal of iron as slag
(C) self-reduction step to produce 'blister copper' following evolution of SO2
(D) refining of 'blister copper' by carbon reduction
dkW
i j i kbj kbV (CuFeS2) l sdkW
ij ¼
r k¡ck½dsfu"d"kZ
. k esa
sD; k l a
fy Ir gS¼
gS
a
½\
(A) ny u r Fkk Qsu&Iy ou (froth-flotation) } kj k v; Ld dk l kUnz.k
(B) y ks
gsdk /kkr q
ey ds: i esfu"dkl u
(C) SO2 fudkl dsi ' pkr **QQks y snkj r k¡csa
** (blister copper) dsmRikn dsfy ; sLo%
&vi p; u dk i x
(D) dkcZ u vi p; u } kj k **QQksy snkj r k¡csa
** (blister copper) dk ' kks/ku
Sol. A, B, C
29. The nitrogen containing compound produced in the reaction of HNO3 with P4O10
(A) can also be prepared by reaction of P4 and HNO3
(B) is diamagnetic
(C) contains one N–N bond
(D) reacts with Na metal producing a brown gas
HNO3 dh P4O10 dsl kFk vfH
kfØ; k esamRikfnr ukbVªkst u vUr foZ
"V ; kS
fxd
(A) P4 r Fkk HNO3 dhvfHkfØ; k l sHkh cuk; k t k l dr k gS
(B) i z
fr pqEcdh; (diamagnetic) gS
(C) esa, d N–N cU/k vUr foZ "V gS
(D) Na /kkr ql svfH kfØ; k dj , d Hkw
j h(Brown) xS l mRikfnr dj r k gS
Sol. B, D
P4O10 + HNO3  H3PO4 + N2O5
Dehyrating agent
(B) Diamagnetic
(D) Na + N2O5  NaNO3 + NO2

30. For 'invert sugar' the correct statement(s) is(are)

(Given: specific rotations of (+)-sucrose, (+)-maltose, L-(–)-glucose and L-(+)-fructose in
aqueous solution are +66°, +140°, –52° and +92°, respectively)
(A) 'invert sugar' is prepared by acid catalyzed hydrolysis of maltose
(B) 'invert sugar' is an equimolar mixture of D-(+)-glucose and D-(–)-fructose
(C) specific rotation of 'invert sugar' is –20°
(D) on reaction with Br2 water, 'invert sugar' forms saccharic acid as one of the products
^vi or̀ ' kdZ
j k^ ('invert sugar') dsfy ; sl ghdFku gS
@gS
a
(fn; k gS%
(+)-l w
Økst (sucrose), (+)-ekW YVkts (maltose), L-(–)- Xyw d kst (glucose) r Fkk L-(+)-ÝqDVkst (fructose)
dk t y h; foy ; u esafof' k"V /kq
zo.k (specific rotations) Øe' k%+66°, +140°, –52° r Fkk +92° gS )
(A) 'vi or̀ ' kdZ
j k' ekWYVkst dsvEy &mRizsfj r (acid catalyzed) t y &vi ?kVu l s(hydrolysis) cuk; k t kr k gS
(B) 'vi or̀ ' kdZ
j k' D-(+)-Xy w d kst r Fkk D-(–)-Ýq DVkst dk l ev.kq d (equimolar) feJ.k gS
(C) 'vi or̀ ' kdZ
j k' dk fof' k"V /kzq
o.k ?kw
. kZ
u –20° gS
(D) Br2 t y l svfH kfØ; k dj usi j 'vi or̀ ' kdZ j k' mRiknksaesal s, d mRikn ds: i esa
]lS d sfj d vEy (saccharic acid)
cukr h gS
Sol. B, C
According to theory
31. Reagent(s) which can be used to bring about the following transformation is (are)
O O O O
C O C
H OH
O O
COOH COOH
(A) LiAlH4 in (C2H5)2O (B) BH3 in THF
(C) NaBH4 in C2H5OH (D) Raney Ni/H2 in THF
fuEufy f[ kr : i kUr j .k dsfy ; sfdu vfHkdkj d (vfHkdkj dks) (reagent(s)) dk mi ; ksx fd; k t k l dr k gS
¼
gSa
½\
O O O O
C O C
H OH
O O
COOH COOH
(A) (C2H5)2OesaLiAlH4 (B) THF esaBH3
(C) C2H5OH es
aNaBH4 (D) THF esaj kus(Raney) Ni/H2 esa
Sol. C
BH2 in NaBH4
32. Among the following, reaction(s) which gives(give) tert-butyl benzene as the major product is
(are)
Br
Cl
(A) (B)
NaOC 2H5 AlCl 3
OH
(C) H2SO4 (D) BF3OEt2

fuEufy f[ kr esaVVZ
&C;w
fVy csUt hu (tert-butyl benzene) eq
[ ; mRikn ds: i esansusoky hvfHkfØ; k(; s) gS¼
gS
a
½
Br
Cl
(A) (B)
NaOC 2H5 AlCl 3
OH
(C) H2SO4 (D) BF3OEt2
Sol. B, C, D
AlCl3
For 'B' Cl
+AlCl4
1, 2 Hydride
shift
For 'C'
H+
PARAGRAPH 1
Thermal decomposition of gaseous X2 to gaseous X at 298 K takes place according to the following equation :

X (g)   2X(g)
2
The standard reaction Gibbs energy, rG°, of this reaction is positive. At the start of the reaction,
there is one moe of X2 and no X. As the reaction proceeds, the number of moles of X formed is
given by . Thus, equilibrium is the number of moles of X formed at equilibrium. The reaction is
carried out at a constant total pressure of 2 bar. Consider the gases to behave ideally.
(Given : R = 0.083 L bar K–1 mol–1)
v uq
PNsn 1
298 K i j xS
l h; (gaseous) X2 dk xS l h; X esaÅ"ek&vi ?kVu (thermal decomposition) fuEufy f[ kr l ehdj .k

X (g)  
 2X(g)
2
dsvuq l kj gksrkgS
A bl vfHkfØ; kdhekud vfHkfØ; kfxCl Åt kZ(standard reaction Gibbs energy), rG°, /kukRed
gSA vfHkfØ; k dsi zkj EHk esaX2 dk 1 eksy gSr Fkk X ughagS At S l s&t S
l s; g vfHkfØ; k c<+ r hgS] fufeZ
r X dseksy ksadhl a
[ ; k
} kj k nht kr hgS A bl i zd kj ] l kE; koLFkk i j fufeZ
r X dseksy ksadhl a [ ; k equilibrium gS
A vfHkfØ; k 2 bar dsfLFkj dq y nkc i j
dht kr hgS A eku y safd xS l savkn' kZO; ogkj dj r hgSA (fn; k x; k gS: R = 0.083 L bar K–1 mol–1)
33. The equilibrium constant Kp for this reaction at 298 K, in terms of equilibrium, is
82equilibrium 82equilibrium 42equilibrium 42equilibrium
(A) (B) (C) (D)
2  equilibrium 4  2equilibrium 2  equilibrium 4  2equilibrium
298 K i j bl vfHkfØ; k dk equilibrium dsi n esal kE; koLFkk fLFkj ka
d (equilibrium constant) KP D; k gksxk \
82equilibrium 82equilibrium 42equilibrium 42equilibrium
(A) (B) (C) (D)
2  equilibrium 4  2equilibrium 2  equilibrium 4  2equilibrium
Sol. B
X2  2X(g) G° > 0
1 0
1  eq 2 eq –RT lnKeq > 0
RT lnKeq < 0
 2

2.303RT log  2 2
. 2 < 0
1   / 2 
22 82equilibrium
kp = =
1  2 / 4 4  equilibrium
34. The Incorrect statement among the following, for this reaction is
(A) Decrease in the total pressure will result in formation of more moles of gaseous X
(B) At the start of the reaction, dissociation of gaseous X2 takes place spontaneously
(C) equilibrium = 0.7
(D) KC < 1
bl vfHkfØ; k dsfy ; sfuEu esal svl R; dFku gS
(A) dq
y nkc ds?kVusdsi fj .kke Lo: i xS l h; X dsvf/kd eksy cusa xsA
(B) vfHkfØ; k dsi zkj EHk esaxS
l h; X2 dk fo; kst u Lor %i zofr Z
r (spontaneous) gksrk gS
A
(C) equilibrium = 0.7
(D) KC < 1
Sol. C
2.303 × 0.083 × 298 log (kp) < 0
82
<1
4  2
9 2 < 4
2 < 4/9
< 2/3
k c  RT < 1
Kc < 1/RT
Kc < 1
PARAGRAPH 2
Treatment of compound O with KMnO4/H+ gave P, which on heating with ammonia gave Q. The
compound Q on treatment with Br2/NaOH produced R. On strong heating, Q gave S,which on
further treatment with ethyl 2-bromopropanoate in the presence of KOH followed by acidific tion,
gave a compound T.
(O)

v uq
PNsn 2
; kS
fxd O dhKMnO4/H+ l sfØ; k usP fn; k] ft l usveksfu; k dsl kFk xeZdj usi j Q fn; kA ; kS
fxd Q usBr2/NaOH ds
l kFk fØ; k dj us i j R mRikfnr fd; kA i zcy : i l s xeZdj us i j Q us S fn; k ft l us , fFky 2-czkseksizksisuksv ksV
(ethyl 2-bromopropanoate) dsl kFkKOH dhmi fLFkfr es avkxsfØ; kdhft l dsi ' pkr ~vEy hdj .kus; kS
fxd T fn; kA
(O)
35. The compound R is
O O O
NH2
Br NHBr
NBr
(A) (B) Br (C) NHBr (D)
NH2
O O O
; kS
fxd R gS
O O O
NH2
Br NHBr
NBr
(A) (B) Br (C) NHBr (D)
NH2
O O O
Sol. A
(O)
(T) Alanine
36. The compound T is

(A) glycine (B) alanine (C) valine (D) serine
; kS
fxd T gS
(A) Xy kbl hu (B) , y kuhu (C) oS
y hu (D) l sjhu
Sol. B
(O)
(T) Alanine

[MATHEMATICS]
PART - III : MATHEMATICS
SECTION – I
Single Correct
 1 0 0
 
4 1 0
37. Let P =  and I be the identity matrix of order 3. If Q = [qij] is a matrix such that P50 –
16 4 1
q31  q32
Q = I, then equals
q21
(A) 52 (B) 103 (C) 201 (D) 205
 1 0 0
 
4 1 0
37. ekuk fd P=  vkS
j I r hu dksfV (order 3) dk r Rl ed vkO
;w
g (identity matrix) gS
A ; fn Q = [qij] , d
16 4 1
q31  q32
vkO
;w
g bl i zd kj gSfd P50 – Q = I gS
] rc q21
dk eku gS
A
(A) 52 (B) 103 (C) 201 (D) 205
Sol. B
 1 0 0
 
P   4 1 0 Q  qij 
16 4 1
P50 – Q = I Q = P50 – I
0 0 0
 
P  I  4 1 0 0
= I + 4R
4 1 0
P50 = [ I + 4R ] 50 = I + 50( 4R ) + 50C

2(4R)
2 +........
0 0 0  0 0 0
where R2  0 0 0 , R3  0 0 0
 
1 0 0  0 0 0
 P50  I  50  4R   50  49 .16.R 2
2
= 200 R + 19600 R 2
 0 0 0  0 0 0  0 0 0
     
 200 0 0    0 0 0   200 0 0
800 200 0  19600 0 0 20400 200 0
q31 = 20400 q32 = 200 q21 = 200
q31  q32 20400  200 206

 
 q21 200 2 =103
38. Let bi > 1 for i = 1, 2, ...., 101. Suppose loge b1, loge b2, ...., loge b101 are in Arithmetic Progression
(A.P.) with the common difference loge2. Suppose a1, a2, ....., a101 are in A.P. such that a1 = b1
and a51 = b51. If t = b1 + b2 + .... + b51 and s = a1 + a2 + .... + a51, then
(A) s > t and a101 > b101 (B) s > t and a101 < b101
(C) s < t and a101>b101 (D) s < t and a101 < b101
38. ekukfd i = 1, 2, ...., 101 dsfy , bi > 1 gS
Aeku y hft , fd loge b1, loge b2, ...., loge b101 l koZ
var j (common
difference) loge2 oky hl eka
r j Js.kh(A.P.) esagS
A eku y hft ; sfd a1, a2, ....., a101 l eka
r j Js.khesabl i zd kj gSfd
a1 = b1 r Fkk a51 = b51 ; fn t = b1 + b2 + .... + b51 r Fkk s = a1 + a2 + .... + a51 gS a
] rc
(A) s > t vkSj a101 > b101 (B) s > t vkS j a101 < b101
(C) s < t vkSj a101>b101 (D) s < t vkS j a101 < b101
Sol. B
b1, b2, b3 ...... b101  G.P. CR=2
a1, a2, a3 ....... a101  A.P.
a1 = b1 ...(1) a51 = b51 = b1 . 250 ...(2)
a51 = a1 + 50d = b1 250 ...(3)
(1  251 )
t = b1 = b1 (251 – 1) = 50d
12
51
s= [2a1  (50)d]
2
51 
=
2 

2b1  b1 250  b1 
 
51  2 
= 2b1  (250.b1  b1 )
2  2 
51
s= [2b1  2b1 (250  1)]
2
51
= [b1  250 b1 ]  st
2
now a101 = a1 + 100 d
 b1 250  b1 
= b1 + 100  50

 
= b1 (251 – 1)
b101 = b1.2100
 a101  b101
13
1
39. The value of 
k 1   (k  1)    k 
is equa lto
sin    sin   
4 6  4 6 
(A) 3  3 (B) 2(3  3) (C) 2( 3  1) (D) 2(2  3)

13
1
39. 
k 1   (k  1)    k 
dk eku gS
sin    sin  4  6 
 4 6   
(A) 3  3 (B) 2(3  3) (C) 2( 3  1) (D) 2(2  3)

Sol. C
  k   (k – 1)  
13sin   –  
 4 6 4 6 
2 
k 1 sin
  (k – 1)    k
4  6  sin  4  6 
   
13
   k 
2  cot  4  (k – 1) 6  – cot  4 
k 1
6 
       12    13  
2 cot – cot     ......  cot    – cot   
 4 4 6 4 6  4 6  
     
2 cot – cot 2   
 4  4 6 
    
2 1 – cot    
  4 6 
  1 
 1 – 
3 
2 1– 

 1 
 1 
 3 
 3 –1
2 1 – 
 3  1 
 3  1 – 3  1 2 3 –1
2  =2× × = 2( 3 –1)
 3 1  3 1 3 –1

2
x2 cos x
40. The value of  dx is equal to
 1  ex

2
2 2
(A) 2 (B) 2 (C) 2  e / 2 (D) 2  e / 2
4 4

2
x2 cos x
40.  dx dk eku gS
A
 1  ex

2
2 2
(A) 2 (B) 2 (C) 2  e / 2 (D) 2  e / 2
4 4
Sol. A
 /2 x2 cos x
f(x) = 
– / 2 1  ex
dx
0 x2cosx  /2 x2cosx
f(x) = 
– / 2 1 e x
 
0 1  ex
x = –t
dx = dt
0 t2 cos t  /2 x2 cos x
f(x) = –   /2 1  e–t
dx + 
0 1  ex
 /2
f(x) =  x2 cos x dx
0
 /2
[x2 sin x]0 / 2 – 2  x sin x
0
 /2
2   /2 
– 2  –x cos x 0  
0
cos xdx 
4  
2
– 2[0 + 1]
4
2
–2
4
41. Area of the region {(x, y)  R2 : y  | x  3 |,5y  x  9  15} is equal to
1 4 3 5
(A) (B) (C) (D)
6 3 2 3
41. {ks=k (region) {(x, y)  R2 : y  | x  3 |,5y  x  9  15} dk {ks=kQy (area) gS

1 4 3 5
(A) (B) (C) (D)
6 3 2 3
Sol. B
A B C
–9 –4 –3
3 1
1 1 
Area =
2
· 10 · 2 —  ·5·1 –
 2 

4
(x  3) dx – 
3
(x  3)

3 1
5 2 2
= 10 – + ((x  3))
3 /2
– (x  3)3 / 2
2 3 4
3 3
5 2 2
= 10 – – [0 – [1]] – [8] – 0]
2 3 3
15 2 16
= – –
2 3 3
45  4  32 5
= =
6 2
45  36 9 3
= =
6 6 2
42. Let P be the image of the point (3, 1, 7) with respect to the plane x – y + z = 3. Then the equation
x y z
of the plane passing through P and containing the straight line   is
1 2 1
(A) x + y – 3z = 0 (B) 3x + z = 0 (C) x – 4y + 7z = 0 (D) 2x – y = 0
42. ekuk fd fcUnq(3, 1, 7) dk] l er y x – y + z = 3 dsl ki s{k (with repect to), i zfr fcEc (image) P gS
Ar c fcUnqP
x y z
l sxq
t j usoky svkS
j l j y j s[kk   dks/kkj .k dj usoky sl er y dk l ehdj .k gS
A
1 2 1
(A) x + y – 3z = 0 (B) 3x + z = 0 (C) x – 4y + 7z = 0 (D) 2x – y = 0
Sol. C
x  3 y  1 z  7 2(3  1  7  3)
  
1 1 1 3
x 3 y 1 z 7
   2  2 x = 3 – 4, y = 1 + 5, z=7–4
1 1 1
(–1, 5, 3)
x y z
1 5 3
=0
1 2 1
x(5 – 6) –y(–1 – 3) + z(–2 – 5) = 0

– x + 4y – 7z = 0
x – 4y 7z = 0
x
  n  n  n
 nn  x  n  x   ...  x   
  2  n 
43. Let f(x) = lim
n  , for all x > 0. Then
 n   2 n2  
2
 
 n! x2  n2  x2  ...
 
4 
x   
n2  
 
1 1 2 f ' 3 f ' 2 

(A) f    f 1 (B) f    f   (C) f ' 2   0 (D) f 3  f 2
2 3 3    
x
  n  n  n
 nn  x  n  x   ...  x   
  2  n 
43. ekuk fd l Hkhx > 0 dsfy , f(x) = lim
n 
gS
Ar c
 n   2 n2  
2

 n! x2  n2  x2    ...  x  2  
4  n 
 
1 1 2 f ' 3 f ' 2 
(A) f  2   f 1 (B) f  3   f  3  (C) f ' 2   0 (D) f 3  f 2
         
Sol. B,C
x
 n
 nn  n
   x  r  
 
lim
f(x) = n   2 n2  
 n!  x  2  
   r  

x
 1  
n


  

n 
r / n  
lim 
= n
  2 n2  
  

x  2
r  

x 
  n  r   n2  
=  ln  x  –  ln    ln  x2  2  
(r / n)  n  r  
n   
1  1
1
 1 
 ln  x   dt – ln t dt –  ln  x2  2  dt 
nf(x) = n  t  t  
0  0
 
1 1 
 ln(xt  1)dt – ln(x2 t2  1)dt 
f(x) ×   

0 0 
x
 1 z 
ln f(x) ×  ln  1  z
1
2 

dz
>0 0<x<1
f '(x)  1 x 
x(x) = = ln  2 
f(x) 1  x 
<0 x>0
(D) 0 1 2 3
3
(C) f'(2)= f(2) ln  5   0
 
 1 x 
f'(x) = f(x) ln  2  < 0
1  x 
44.
3
 3

Let a,b  R and f : R  R be defined by f  x   acos x  x  b x sin x  x . Then f is 
(A) differentiable at x = 0 if a = 0 and b = 1
(B) differentiable at x = 1 if a = 1 and b = 0
(C) NOT differentiable at x = 0 if a = 1 and b = 0
(D) NOT differentiable at x = 1 and a = 1 and b = 1
44. j f : R  R, f  x   acos  x3  x   b x sin  x3  x  l si fj Hkkf"kr gS

eku fd a, b  R vkS Ar c f
(A) x = 0 ij vody uh; (differentiable) gS; fn a = 0 vkS
j b=1
(B) x = 1 i j vody uh; gS; fn a = 1 vkS
j b=0
(C) x = 0 i j vody uh; ughagS; fn a = 1 vkS
j b=0
(D) x = 1 i j vody uh; ughagS; fn a = 1 vkS
j b=1
Sol. A,B
f(x) = a cos (|x|(|x2 – 1|)) + b|x| sin|x| |x2 + 1|
a=0 b = 1 f(x) = |x| sin|x| |x2 + 1|
a=1 b = 0 f(x) = a cos(|x| (|x2 + 1|)
45. Let f : R   0,   and g : R  R be twice differentiable function such that f" and g" are continuous
f x  g  x 
functions on R. Suppose f'(2) = g(2) = 0, f " 2   0 and g' 2   0 . If lim
    = 1, then
x 2 f ' x g' x
(A) f has a local minimum at x = 2

(B) f has a local maximum at x = 2
(C) f"(2) > f(2)
(D) f(x) – f"(x) = 0 for at least one x  R
45. ekukf : R   0,   vkS
j g : R  R , sl snksckj vody uh; (twice differentiable) Qy u gSfd R i j f" vkS
j g" l a
rr
f x  g  x 
(continuous) Qyu gS
A eku yhft , fd f'(2) = g(2) = 0, f " 2  0 vkS A ; fn lim
j g' 2  0 gS     =1
x 2 f ' x g' x
gS
] rc
(A) x = 2 i j f dk LFkkuh; fuEur e (local minimum) gS
(B) x = 2 i j f dk LFkkuh; mPpr e (local maximum) gS
(C) f"(2) > f(2)
(D) de l sde , d x  R dsfy , f(x) – f"(x) = 0 gS
Sol. A,D
f : R  (0, ) ; g : R  R
f'(2) = g(2) = 0 ; f"(2)  0 g'(x)  0
f(x)g(x)
lim =1
x 2 f '(x)g '(x)
f(x) g '(x)  f '(x) g(x)

lim 1
x 2 f "(x) g '(x)  f '(x) g"(x)
f(2) g'(2)
 1  f "(2)  f(2)
f "(2) g'(2)
 1   1 
46. let f :   ,2   R and g :   ,2   R be functions defined by f(x) = [x2 – 3] and g(x) = |x| f(x)
 2   2 
+ |4x – 7| f(x), where [y] denotes the greatest integer less than or equal to y for y  R . Then
 1 
(A) f is discontinuous exactly at three points in   2 ,2
 
 1 
(B) f is discontinuous exactly at four points in   2 ,2
 
 1 
(C) g is NOT differentiable exactly at four points in   2 ,2 
 
 1 
(D) g is NOT differentiable exactly at five points in   2 ,2 
 
 1   1
46. ekuk fd Qy u f :   ,2   R vkS
j g :   ,2   R , f(x) = [x2 – 3] vkS
j g(x) = |x| f(x) + |4x – 7| f(x)
 2   2 
l si fj Hkkf"kr gS
a
] t gk¡ y  R dsfy , y l sde ; k y dscj kcj dsegÙke i w
. kkZ
a
d (greatest integer less than or equal
to y) dks[y] n~ okj k n' kkZ
; k x; k gS
Ar c
 1 
(A)   2 ,2 esaf Bhd r hu (exactly three) fcUnq
v ksai j vl a
r r (discontinuous) gS
 
 1 
(B)   2 ,2 esaf Bhd pkj (exactly four) fcUnq
v ksai j vl a
r r gS
 
 1 
(C)   2 ,2  esag Bhd pkj (exactly four) fcUnq
v ksai j vody uh; p (differentiable) ughagS
 
 1 
(D)   2 ,2  esag Bhd i k¡p (exactly five) fcUnq
v ksai j vody uh; (differentiable) ughagS
 
Sol. B,C
 1   1 
f: – ,2  R; g : – ,2  R
 2   2 
f(x) = [x2 – 3] : g(x) = |x| f(x) + |4x – 7| f(x)
g(x) = |x| ([x2] – 3) + |4x – 7| ([x2] – 3)
 1
–x(–3) – (4x – 7)(–3) ; – 2 x  0 1

 –3x  3(4x – 7) ; 0 x 1
1 2
=  –1
x(–2) | 4x – 7 | (–2) ; 1  x  2


15x  7
= 
 9x

 1 
47. Let a, b  R and a2 + b2  0. Suppose S = z  C : , t  R, t  0 ; where i = 1 .
 a  ibt 
If z = x + iy and z  S, then (x, y) lies on
1  1 
(A) the circle with radius and centre  , 0  for a > 0, b  0
2a  2a 
1  1 
(B) the circle with radius – and centre   , 0  for a < 0, b  0
2a  2a 
(C) the x-axis for a  0, b = 0

(D) the y-axis for a = 0, b  0
 1 
47. ekuk fd a, b  R vkS A eku y hft , fd S = z  C : a  ibt , t  R, t  0 , t gk¡i =
j a2 + b2  0 gS 1 gS
A ; fn
 
z = x + iy vkS
j z  S gS
] r c (x, y)
1  1 
(A) ml oÙ̀k i j gSft l dhf=kT; k vkS nzfcUnq 2a , 0  gSt c a > 0, b  0
j dsa
2a  
1  1 
(B) ml oÙ̀k i j gSft l dhf=kT; k – vkS snzfcUnq  2a , 0  gSt c a < 0, b  0
j da
2a  
(C) x-v{k i j gSt c a  0, b = 0

(D) y-v{k i j gSt c a = 0, b  0
Sol. A,C,D
 1 
s  z  c : z  : t  R : t  0
 a  bti 
z = x + iy
a  bti a
x  iy   x 2
a2  b2 t2 a  b2 t 2
bt
y
a2  b2t 2
a2  b2 t2
x2  y2  2
a 2
 b2 t2 
x
x2  y2 
a
1 1
g , f = 0, r 
2a 4a2
1  1 
=  2a ,0 
2a  
48. Let P be the point on the parabola y2 = 4x which is at the shortest distance from the centre S of
the circle x2 + y2 – 4x – 16y + 64 = 0. Let Q be the point on the circle dividing the lie segment
SP internally. Then
(A) SP = 2 5
(B) SQ : QP = ( 5  1) : 2
(C) the x-intercept of the normal to the parabola at P is 6
1
(D) the slope of the tangnet to the circle at Q is
2
48. ekuk fd i j oy ; y2 = 4x i j P , d , sl k fcUnqgSt ksoÙ̀k x2 + y2 – 4x – 16y + 64 = 0 dsdsUnzfcUnqS l sU; w
ur e
nw
j hi j gS
A ekuk fd oÙ̀k i j fcUnqQ , sl k gSfd og j s[kk[ ka
M SP dksvka
r fj d foHkkft r dj r k gS
Ar c
(A) SP = 2 5
(B) SQ : QP = ( 5  1) : 2
(C) i j oy ; dsfca
nqP i j vfHky Ec (normal) dk x-va
r%[ k.M 6 gS
1
(D) oÙ̀k dsfcUnqQ i j Li ' kZ
j s[kk dh<ky (slope) gS
2
Sol. A,C,D
y2 = 4x
dy 4 2
let P(x1, y1) then = = y
dx 2y 1
y1 y1  8 y2=4x S (2, 8)
 mNr at P = – = x 2 Q
2 2
P
y1 8  y1
= 2 ×4
2 y1  8
y13  8y1  64  8y1

y1 = 4  x1 = 4
 P(4, 4)
now SP = (4  2)2  (4  8)2
= 4  16  20  2 5  (A) 
& SQ : QP = 2 : (2 5  2)
= 1 : ( 5  1)
= ( 5  1) : (4)  (B) ×
equation of Normal
y – 4 = – 2(x – 4)
y + 2x = 12
 xint = 6  (C)
1
Now tangent at Q will be  r to the common normal y + 2x = 12 is slope of tangent will be =
2
 (D)

49. Let , ,   R. Consider the system of linear equations

ax + 2y = 
3x – 2y = 
Which of the following statement(s) is(are) correct ?
(A) If  = – 3, then the system has infinitely many solutions for all values of  and 
(B) If   – 3, then the system has a unique solution for all values of  and 
(C) If  +  = 0, then the system has infinitely many solutions for  = – 3
(D) If  +   0, then the system has no solutions for  = – 3
49. ekuk fd , ,   R gS
A bu j S
f[ kd l ehdj .kksadsfudk; (system of linear equations) i j fopkj dhft ,
ax + 2y = 
3x – 2y = 
fuEufy f[ kr esal sdkS
ul k dFku l ghgS\
(A) ; fn  = – 3, r c vkS j dsl Hkhekuksadsfy , fudk; dsvuUr (infinitely many) gy gS
(B) ; fn   – 3, r c  vkS j dsl Hkh ekuksadsfy , fudk; dk vf} r h; (unique) gy gS
(C) ; fn  +  = 0, r c  = – 3 dsfy , fudk; dsvuU r gy gS
(D) ; fn  +   0, r c  = – 3 dsfy , fudk; dk dks bZgy ughagS
Sol. B, C, D
a, ,   R
ax + 2y = 
3x – 2 y = 
(A)  = –3
– 3x + 2y = 
3x – 2y = 
if     solution  (C)
If    no solution  (D)
(B)   3
ax + 2y = 
3x – 2y = 
non parallel lines hence unique solution   & 
1 ˆ ˆ ˆ
50. Let ˆ be a unit vector in R3 and
û  u1î  u 2ˆj  u3k ŵ  (i  j  2k) . Given that there exists a
6
 3
 
vector v in R such that û  v = 1 and ˆ ˆ  v)  1 . Which of the following statement(s)
w·(u
is(are) correct ?

(A) There is exactly one choice for such v

(B) There are infinitely many choices for such v
(C) If û lies in the xy-plane then |u1| = |u2|
(D) If û lies in the xz-plane then 2|u1| = |u3|
50. j ŵ  1 (iˆ  ˆj  2k)

ekuk fd R3 esaû  u1î  u 2ˆj  u3kˆ , d ek=kd l fn' k (unit vector) gSvkS ˆ gS
A fn; k gq
v k gSfd
6
 
R3 esal fn' k v dk vfLr Ro bl i zd kj gSfdû  v= 1 vkS
j w·(u
ˆ ˆ  v)  1 gS
A fuEufy f[ kr esal sdkS
ul k dFku l ghgS
\
(A) bl i zd kj ds v dsfy , Bhd , d (exactly one) p; u l aHko gS

(B) bl i zd kj ds v dsfy , vuUr (infinitely many) p; u l a Hko gS
(C) ; fn û , xy--l er y i j gSr c |u1| = |u2| gS
(D) ; fn û , xz--l er y i j gSr c 2|u1| = |u3| gS
Sol. B,C
ˆ
û  u1î  u2ˆj  u3k
1 ˆ ˆ ˆ
ŵ  (i  j  2k)
6
 
ˆ  v | 1
|u ˆ ˆ  v)  1
w·(u
ˆ | |u
|w v | sin Q cos Q = 1
ˆ || ˆ
cos Q = 1
 Q = 0º

 ŵ is  to plane containg û and v

Þ ŵ is to û as well as v
Paragraph for Question Nos. 51 to 52

Football teams T1 and T2 have to play two games against each other. It is assumed that the
outcomes of the two games are independent. The probabilities of T1 winning, drawing and losing
1 1 1
a game against T2 are , and , respectively. Each team gets 3 points for a win, 1 point for a
2 6 3
drawn and 0 point for a loss in a game. Let X and Y denote the total points secored by teams T1
and T2, respectively, after two games.
v uq
PNsn Question Nos. 51 to 52
Qq
VckW
y ny ksaT1 vkS
j T2 dks, d nw
l j sdsfo#) nks[ ksy (games) [ ksy usgS
a
A; g eku fy ; kx; kgSfd nksuksa[ ksy ksadsi fj .kke
1 1
, d nw
l j si j fuHkZ
j ughadj r sAny T1 dsny T2 dsfo#) , d [ ksy esat hr us]cj kcj gksusvksj gkj usdhi zkf; dr kØe' k% ·
2 6
1
vkS
j gS
A i zR; sd ny t hr usi j 3 va
d ] cj kcj hi j 1 va
d vkS
j gkj usi j 0 va
d vft Z
r dj r kgS
A ekukfd nks[ ksy ksadsi ' pkr
3
ny T1 vkS
j ny T2 ds} kj k vft Z
r dq
y va
d Øe' k%X vkS
j Y gS
A
51. P(X > Y) is

1 5 1 7
(A) (B) (C) (D)
4 12 2 12
51. P(X > Y) dk eku gS
1 5 1 7
(A) (B) (C) (D)
4 12 2 12
Sol. B
1 1 1
P  T1w   , P  T1D   , P  T1L  
2 6 3
3 1 0
x>y  1| 2
T1
1 1 1
P  W, WD    
2  2 6 

1 6  2
= 
2  12 
8 1
= 
24 3
1 1 1
P D and W =  
6 2 12
1 1 4 1 5
 P(x > y ) =      B
3 12 12 12 12
52. P(X = Y) is
11 1 13 1
(A) (B) (C) (D)
36 3 36 2
52. P(X = Y) dk eku gS
11 1 13 1
(A) (B) (C) (D)
36 3 36 2
Sol. C
x=y
for T1
P(W, L) + P ( L, W) + P ( D, D)
1 1 1 1 1 1
= 2  3  3  2  6  6
     
1 1 1 1 1 13
  =  
6 6 36 3 36 36
Paragraph for Question Nos. 53 to 54

x2 y2
Let F1(x1, 0) and F2(x2, 0), for x1 < 0 and x2 > 0, be the foci of the ellipse +  1 . Suppose
9 8
a parabola having vertex at the origin and focus at F2 intersects the ellipse at point M in the first
quadrant and at point N in the fourth quadrant.
v uq
PNsn Question Nos. 53 to 54
x2 y2
ekuk fd F1(x1, 0) vkS
j F2(x2, 0) (ft l esax1 < 0, x2 > 0) nh?kZ
oÙ̀k (ellipse) + 1 dhukfHk; k¡(Foci) gS
a
A
9 8
ekuk fd , d i j oy ; (parabola) ft l dk ' kh"kZ(vertex) ew y fcUnq(origin) i j vkS
j ukfHk (focus) F2 i j gS
] nh?kZ
oÙ̀k dks
i zFke pr q
FkkZ
a
' k (first quadrant) esaM i j vkS
j pr q
FkZpr q
FkkZ
a
' k (fourth quadrant) esaN i j i zfr PNsfnr dj r k gS
A
53. The orthocentre of the triangle F1MN is
 9  2   9  2 
(A)   10 , 0  (B)  3 , 0  (C)  10 , 0  (D)  3 , 6 
       
53. f=kHkq
t F1MN dk y a
cdsUnz(orthocentre) gS
 9  2   9  2 
(A)   10 , 0  (B)  3 , 0  (C)  10 , 0  (D)  3 , 6 
       
Sol. A
3 
 , 6
 2 
M
Q R (6, 0)
F1
(–1, 0) F1
(1, 0)
N
3 
 ,– 6 
2 
8 1
e2 = 1 – =
9 9
82
y2 =
9
1
e=
3
y2 = 4x
x2 4x
+ =1
9 8
8x2 + 36x = 72
2x2 + 9x = 18
2x2 + 9x – 18 = 0
3
(2x – 3)(x + 6) = 0 x=
2
6 –2 6

mF1N = 5 5
–
2
5  3
y– 6 = 2 6  x – 2 
Put y = 0
15
–12 = 5x –
2
15 15 – 24 –9
5x = – 12 = =
2 2 2
9
x=–
10

54. If the tangents to the ellipse at M and N meet at R and the normal to the parabola at M meets the
x-axis at Q, then the ratio of area of the triangle MQR to area of the quadrilateral MF1NF2 is
(A) 3 : 4 (B) 4 : 5 (C) 5 : 8 (D) 2 : 3
54. ; fn nh?kZ
oÙ̀k dsfcUnq
v ksaM vkS
j N [ kha
phxbZi j Li ' kZ
j s[kk, ¡(tangents) R i j fey r hgS
avkS
j i j oy ; dsfcUnqM i j vfHky a
c
x-v{k dksQ i j fey r k gS
] r c f=kHkq
t MQR ds{ks=kQy vkS
j pr q
Hkq
Z
t (quadrilateral) MF1NF2 ds{ks=kQy dk vuq
i kr
(ratio) gS
(A) 3 : 4 (B) 4 : 5 (C) 5 : 8 (D) 2 : 3
Sol. C
Eqn to normal
y2 = 4x
dy
2y =4
dx
dy 4 2
= =
dx 2. 6 6
Eqn to normal
– 6
y– 6 = (x – 3/2)
2
y=0
6
– 6 =– (x – 3/2)
2
3
2+ =x
2
7
x=
2
7 
Q =  2 ,0 
 
1  7 1 5 5 6
MOR =
2
× 6  6 – 2  = 2 6 × 2 =
4
1 5 1
MF1NF2 = 2  6  2  – 2 6  2 
   
1
= 2 6 (2) = 2 6
2
5 6
MOR
4 = 5/8
MF1MF2 =
2 6

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Fastest Growing Institute of Kota (Raj.

JEE MAIN + ADVANCED

QUESTION WITH SOLUTION

The measured masses of the neutron, 11H, , 15

(A) 2.85 fm (B) 3.03 fm (C) 3.42 fm (D) 3.80 fm

2. An accident in a nuclear laboratory resulted in depostion of a certain amount of radioactive

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, d i r y sr kj PQ dsNksj Q dksvU; i r y s r kj RS dsNksj R i j Vka d k y xkdj t ksM+

l = 1.2 × 10–5 × 65 = 0.78mm

nksofuZ; j dSfy i l Zbl r j g l sgS

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(A) e decreases with increase in  and ph

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dkeki kx; keku Øe' k%(60 ± 1) mm r Fkk(10 ± 1) mm gS Ay xkr kj i ka

0.52  0.56  0.57  0.54  0.59

0.036  0.016  0.014  0.004  0.036

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fuEufy f[ kr esal sdkS

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ekfu, fd R f=kT; k dh, d fMLd] ft l esaO ; kl dsl ekukUr j , d ?k"kZ

dksl e; t= 0 i j r = (R/2) ^i fca

15. The distance r of the block at time t is

On solving, we get option (A).

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16. The net reaction of the disc on the block is

(C) –m2R cos tj ˆ

17. Which one of the following statements is correct?

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concentration concentration concentration

(A) I : KCl II : CH3OH III : CH3(CH2)11OSO3–Na+

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24. The major product of the following reaction sequence is

(i) HCHO (excess)/NaOH, heat

(i) HCHO (v f/kd ek=kk)/NaOH, Å"ek

25. According to Molecular Orbital Theory,

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28. Extraction of copper from copper pyrite (CuFeS2) involves

(D) Na + N2O5  NaNO3 + NO2

30. For 'invert sugar' the correct statement(s) is(are)

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36. The compound T is

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P50 = [ I + 4R ] 50 = I + 50( 4R ) + 50C

q31 = 20400 q32 = 200 q21 = 200

q31  q32 20400  200 206

(A) 3  3 (B) 2(3  3) (C) 2( 3  1) (D) 2(2  3)

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(A) 3  3 (B) 2(3  3) (C) 2( 3  1) (D) 2(2  3)

41. Area of the region {(x, y)  R2 : y  | x  3 |,5y  x  9  15} is equal to

41. {ks=k (region) {(x, y)  R2 : y  | x  3 |,5y  x  9  15} dk {ks=kQy (area) gS

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x(5 – 6) –y(–1 – 3) + z(–2 – 5) = 0

1 1 2 f ' 3 f ' 2 

44. j f : R  R, f  x   acos  x3  x   b x sin  x3  x  l si fj Hkkf"kr gS

(A) f has a local minimum at x = 2

f(x) g '(x)  f '(x) g(x)

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If z = x + iy and z  S, then (x, y) lies on

(C) the x-axis for a  0, b = 0

(C) x-v{k i j gSt c a  0, b = 0

y13  8y1  64  8y1

now SP = (4  2)2  (4  8)2

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49. Let , ,   R. Consider the system of linear equations

50. j ŵ  1 (iˆ  ˆj  2k)

Paragraph for Question Nos. 51 to 52